SCIENTIFIC ABSTRACT ZINOVYEV, V. YE. - ZINOVYEVA, I. S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002065220017-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

RAXITSKIY, G.A.; ZINOVITZT, T.Ye,
Wider utilization of reconstitute& wool. Tekst.prom. 20 no.9:13"
15 S .160. (KIBA 13:10)
1. GlavW inzhener fabriki imenL:Oktyabr'skoy revolyutaii (for
Rakitaki.v). 2. Rqchallalk tekhnicheskogo bywo fabriki inen!
CktyabrIskoy revolytitali. (for UnOvIyev).
(Woolen azd worsted manufacture)

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BOIMAREVS G.I.;.-~INOVIYEV, Ye.3h.;NEPOKLONOV, Yu.A.; YF-,Pjf,,CjVjj,.SKkyA, I.S,
Energy expenditure of fishery workors on trawlers fiohing In
the Barents Sea and North Atlantic. Vop. pit. 21 no.6,-40-43
N-D 162, (1,11IRA 17-5)
1,, Iz Tsentrallnoy nalaiflmo-isaledovatel'skoy Inboratorij
gigiyeny vodnogo trarsporta., Moskva.

BONDAREV, G.I.; ZINOVIYEV, Te.Sh.; IfBPOKWNOV, Yu.l.; YEND07ITSKAYA,, LSII,
Supply of vitamins C, B.1, B2 and PP for fiWprocadlsing
workers on fishing craft in the North Atlantic. V0 it
22 no.5:58-.60 S-0 163, W&A !P74
1. Iz otdala, gigiyany pitaniya (sav. - kand. mad. nauk
G.I. Bondarev) TSentrallmoy nauchno-iasledov~tallgkoy
laboratorii gigiyeny vodnogo transportal Moskva.

ZINOVIYE-Vj IU. - A ~. 26/0T94 I

ZINOVIYEV, Yu.
"The Input Circuitg of the Receivers 'Rekord-471 and 'ARZ-491,11 JUdlo, No. 6#

TAYSBERG, N. (Sverdlovsk); YESMAV, M. (Sverdlovsk); ZINOVIM, Tu*(Sver;diovs,k);
MOW. N.Overdlorsk). -Wmmtzl~
("The economics of the socialist., chemical induatx7." )t.1F.K*lVqkovf Sele
Vaishein. Reviewed by Mal berg and others) Von. ekon ino.7:150-153 JI
'56. (Chemical induNries) (KM 919)
(KRImykov, 11ji,)
(Valshein, S.A.)

ZINOVITEV, YU.I., lnzh.
Investigating the method of applving fluidized soil bad ror the
separatioa of potatoes from clods and stones. TrWy HIKPASKH
12:49-66 D. (N-,,Rk 13:9)
(Potatoeo-rilarves t i ng)

ZINOVIYZV, inzho
Studylug the fluldisqd soil.bed as a mad-Itm for separatIng potatoes
form olodo an4 stonsil. Trakt. i eillkhosma~. D '159s
(Potato digger (Machine)) OrU 13:3) ~

ZT11OVIVY1 Yu. T.1 CAnd Toch Sai (diss) - "The uepnratlon of potato tubers.
from soil lumps and stones in a suspended layer of fine soil". 14oscow, 19"9.
15 PP (Min Higher aqd Ifiter Spec Educ RSFSR) Moscow Inst of Mechanization and
Electrification of kric), 150 copies (KLWo 9, 19S0, IP5)

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ZINOVIYEV~ YU. Id.
USSR/Chemistry - Sulfonation Sep/0--t 1947
Chemistry - Mefins
"Sulfo-Chlorination, a New Method of Sulfonation of Alkenes Properties:amd Uses of
Alkene Chlorosulfonides, nA. Ya. Yakubovich, Yu. M ZinovIyev, Moscow, 17-1- pp
"Uspekhi Phimii" Vol XVI, No 5
Classic reaction of sulfonation ranks with the reaction of rdtration as one of the
basic processes as a result of which aromatic carbohydrates Iare Ohanged, into their:
various resultant products. Gives detailed and comprehensive acoount.of chemical
reactions which occur and illustrates various steps by means of chemical formulas.
FA4OT5

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cWtUm (In Russian.) A.
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31., Zinqy1ev. UspekAi Khimii (Progress In Chemig:'
try), v. 10, Sept.-OcL 1947, p~ 581-598.
Available literature data and theoretical Wes oft 00*
the rraction are reviewed. Properties and op
t
asibilities of (g
'r
cations of the products and pow
research are Indicated. 40 ref.

Is

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004 Woridles. (In Russian.) A. m. Yakubovich and Yu-
0*0 M. Zi 'ivy. UspeW Xhimii (Proams In Chemis-

581-15M
1947
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Available literature data and, theoretical bases tit!
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cations of the products and possibi
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00 Russian.) A. Yx. Irmkolkivich anti Vu, AL. zilli
0-4 4 Am"d Obabehri Khimh (Journml of GerwralWom
istry), v. 1709). Nov. 1947, p. ZWO-2ou
00 Results of a study of the structum of the aWve
00 indicate the prvoence of rosonanm- Reacdom with
Othylene, prupylme, and vinyl chloride at low
teralmratures in the Proonce of catalysts such am
4D 40 sul(ur O'loricks aild IlYridint- imv investigated.
Data are vibulattd. IS ref.
Al
r
A$A.tLA AIIALLUROICAL W14AILO CLASINKATICH
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At K) .11 Er to I, tv 44 At gi It st it! is ti
loop 0 0 0 a jo 10 0 00 040 0 Oe 0 0 40 411
0 00 40 Oslo

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OD 9 ~Ii~ I
The SOM mmical. Its Structure 184 MWOOMU (IJA
Russian.) A. Ya. YakubQvIch antl Ya, S1, Zinorlett,
*0
tharrital Obskeikof KbimU (Journal of G#mirml (Iwrh-
00 Wry), v. 17(79), Nov. 1941, p. 20213-20A
UnultA of a study of the structure of the 4botv
V
49z Indleats the premnc* of rownatt4ce. RearMons with
athyleno, propyleme. and vinyl chloride at low
temporuturts, in the py"ence of catalysts suth Ap
Sulfur chlarioles and pyridine werv InytsUpud.
Vata are tabulated- 114 ref.
LIM
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v.: to 41
ia,%L A AtIALLOCKAL LIT9441W CLILIUVICA1616
It
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....... I -- I....
ONOVIYEV, Yu. M, SOBOROVSKIY, L. Z. and 14. A.
"Formation of the Phosphorus-Carbon bond In the Couplud 3eaction of Hydroparb6na.,
Phoolhorus Trichloride, and Dxygen", Dokl AN SSSR, Vol. LXVII, No.'21 I%p 293-2~5.v 1949.
Translation W-16087,, 3 Jan 1951

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.......... . ......
L. Z.; ZINOWYEVA YU.- M. INGLIN.. No A.
SOBOROVSKIY
Poluchenie Foafororganicheakikh Soedinenii Pri Iteaktsii Wekhkbloristogo Fasfora
i Kisloroda a Uglevodorodami, Ikh Mlorproizvodnymi i s Prostyrd Efirmi
(Preparation of Phospho-organic Compotmds by the Reaction of'llbosphorus Trichloride
and Oxygen with Carbohydrates, the Halogen Derivatives, and with,ordinary Ethers),
Doklady Akad. Nauk. SSSR (Reports of the 0 USSR, V01. 73, PP 333-336, 11,)~O).

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submatted V " y ~

IV t' V pl~- YJ Lt M
Aqi subiitWA441104.~i
f ins.0 by L Z Soborovskity, Yu. M. Zinov'yev, an(l L. I.
Muler, Doklady Akademii Nauk SSSR. Vol 109, No 1, Jul 56,
pp 98-100
Oxidative chlorophosphon!Ltlon is defined as the reaction between
-drocarbons (or their derivatives), oxyg6n and phosphorous
-richloride
(or products where part of the chlorine1a substituted~b
y oriaa~c groupqv
e.g., PC12R or PClR2). In the case of vinyl chloride, this reaction 9
found to proceed in two different directions:
CHCIpCHgOC12 (30-'350)
C~2 CH Cl 2 PC1 3-f-02
+ PPC13
C%ClCHClPOCl2 (65-70%)
_:The yield of the reaction product in the oxidative chldropho6phohati
On
--6f- alIFL c~~4p ~was-~ too low,_to. sayXori sure that the lreact~PM vroceede&,-,"'
CM-MORMS AMON - ..MIN 119UH11 Fffl III 11111MI
El 1. _j:'_ L I I ~I Sili-A I;- ~iO t 11;i I- ~H: 1 1: WHILOP4, . 441"
4 4W

AUTHORS: Zinaviyev, Yu. M.; Kulakova, V. K.; Soborovgkiy, L. Z.
TITLE: Reaction of Phosphorus Pentachloride with Certain 11alogeno
Olefines (Vzaimodeystviye rtikhloristogo foBfora s
nekotorymi galoidolefinami
467,
PERIODICAL: Zhurnal Obahchey Khimii, 1957, Vol. 27, No. 1, pp.' 151-156 (U.S.S.R.)
ABSTRACT: The possibility of adding phosphorus pentachloride to certain
chlorine-substituted olefins - vinyl chloride, vinylidene and
allyl chlorides - was investigated. The reaction carried out
under soft conditions (200) showed that the PCl has practically
not reacted with the Noro-olefins listed but in a more rigid
reaction (heated to UO under pressure and without a solvent)
the PC15 reacted in 100%, but the reaction ndxture showed no traces
of organo-phosphorus compounds. The reaction of vinyl chloride
with PC15 yielded, in addition to the non-reacted olofins, I'M
: 3
1,1,2-trichloroethane and a chlorinated hydrocarbon with doub16
number of carbon atoms Which was identifiod as the hitherto unknown
1,1,4,4-tetrachloro butane. From allyl chloride~with 1,2,3-
trichlopropane, by an analogous method, 2,5,6-tatrachlorahexane
Card 1/2 was obtained. The formation of olefine. chlorination products

467,
Reaction of Phosphorus Pentachloride with Certain
Halogeno Olefines
with double bond is easily explained by the chlorinating effect
of PC15 - - The possitility of the f ormati on of ~ such polychloro-
alkanes with double the number of carbon atoms from phosphorus
chloralkyltetra chlorides was proven by thermRl decomposition
of P-2-chlorpropyltetrachloride obtained from propylene PC15'
Upon heating this tetrachloride to 100-1100) the reaction products
showed P0131 1,2-dichloropropane and hydrogen chloride plus a
small amount of tetrachlorohexane. The latter,could have been
formed as a result of chlorination of the alkyl radical at the
phosphorus, separation of the C - P bond and combinittion of the,
newly originated radicals into a molecule with doabled carbon
chain. By dehydrochlorimtion of 1,1,4,4-tetrachlorobutane, the
authors obtained now 1,4-dichlorobutadiene-lj3 and 1,1,4-trichloro-
butene-3.
One graph. There are 13 references, of which 5 are:Slavic.
ASSOMATION:
PREONTED BY:
SUBMITTED: January 28, 1956
AVAIIABLE:
Card 2/2

AUTHORS: __ZJxzx'*ex, ZuJ4,,4,_~ulakoval Y. If., 0()V/ 79-20-6-25/63
Soborovokiy~ L. Z,,
TITLE: The Synthesis of OrCanophosphorus Compounds of llydrocarbdne &nd
Their Derivatives (Sintez fosfororganich4akikh soyadineniy it.
ugleyodorodoy i i1ch proizvodnykh) VIL Oxidizingr Chloro boophi-
nation With 11koxy- and Dialkylamidodichiorophosphinos MI.
Okinlitallnoye khlorfoifinirovaniyo allkoksi-i dialkilamidodi-
khlorfoafinami)
PERIODICAL: Zhurnal obshchey Ithimii, 1958, Vol. 26,# Mr 6p
PP-, 1551 - 1554 (USSR)
ABSTRACT: Contrary to the method (Ref.1) employed in an:earlier paper by
the authors they nov prove that alkoxydiohlorolphosphinas'an&
dialkylamidodichli)rophosphines can be used as,phosphination
agents, ie. compounds in which the hydrocarbon radicalis com-
bined with the phosphorus by means of a third-element:
RH+2R'XPC12+0 2 --> RP(O)(XR')Cl+RIXP(O)Ci 2+1101, where IR amd R1
are hydrocarbon radicals and where X is equal to 0 or to H, By
means of the mentioned reagents the ox1dizina chlorophosphination
Card 1/15 of cyclohexane with othoxydichlorophosphine and vinylehloride

The S~ntheais of Organophosphorus Compounds of 30-VI79-28-6-25163
Hydrocarbons and Their Derivatives. VIL Oxidizing Chloraphoaphination With
Alkoxy- and D ialkylaniidodichlorophosphines
with methoxydichlorophosphine and dimethy1amidadichlorophosphine
was carried out. The corresponding chloriiie anhydrides containing
a phosphoruohydrocarbon bond weVe separatod as final products.
The chlorophosphination of cyclohexane with ethoxydichlok6phonphine
lead to a mixture of compounds the separation of which by: o
fractionation was difficult. In order to,provesthat this~reaction
actually takoo placo according to tho aboli-ri moTitionad ochttme the
mass obtained was hydrolized and the eyclohexp-nephosphinie acid
was separated from the products of hydrolysis. Also with the
compounds of the ethylene series oxidizing chlorophosphination
'
;to
with alkoxydichlorophosphines takes place-in a-manner siailar
the reaction carried ou" with phosphorus trichloride; the.vinyl
chloride was used for this purpose. The chlorine anhydrido and j"
the ethyl ester of dimethylamidodichloroethaneoh6sphinic acid-p
the dimethyl ester of dichloroethanephosphinic*aoid and the mothyl
ester of dichloroothanachlorophosphinic acid w4r* syntheiited"
There are 3 references, which are Soyiet.
SUBMITTED: May 12, 1957
Card 0

The Synthesis of Organophosphorus Compounds of SOV/U-20-6-25/63
Hydrocarbons and Their Derivatives, VII. Oxidizing Chlorophoaphination, With
Alkoxy- and Dialkylamidodichlorophosphines
1. Phosphorus compounds (organic-Synthesis 2. kydrocarlx)ns--0homical rea.0tions
Card 3/3

AUTHORS:
TITLE:
V/'
:
3, 39-28-6-45/63
Baranayev, M. K., Zinovlyev, Yu. M.,, Mrxipach, T. K.-j
Soborovskiy, L.
bons
The Synthesis of Organophosphorus Compo~nds Prom HydrootLr
and Their Derivatlives (Sintez fosfororgsunichaskikh soy6.+.
dineniy iz uglevodorodov i ikh proizvodnykh) VIII. The:In-
vestigation of Oxidation of PhOSDhorustrichlaride With: Oxygen
(YIII. Izucheniye okisl,-:tniyatrekhkbl-ciri-stogo foefora kislo-
rodom)
.pp. 1628-1631:
PERIODICAL: Zhurnal obshchey khimij.: 19587 Vol- 28, Nr 61
(USSR)
ABSTRACT: There are, in fact, very few papers dealing with the oxida-
tion of phoaphoras trichloride with or7gen. Only Remsen~.(Rem-
zen) points to the possibility of oxidiving thl's chloride .
with ozonized oxyger.. It0patent is mertibned (Ref 9) in which
the "combustion" at 15o of a gas m--*xtuxlr-. c)f PC1 and oxy-.'
gen is desc-ribed (molar ratio 2 : 1). The observations made;
by the authors show that the o;cJldatlonof phosphox-is tri- ~
chloride as well a3 that of the compounds synthesized from.
Card 1/3 it, which correspond to the f.-)rmula XFC1 2(where X=chlorino,

sov 79--28-6-.45/63
The Synthesis of Organophosphorus Compourada Prom Hydrocarbons and The~ir
Derivatives. VIII. The Investigation of Oz.'Llation of Phosphar-astrichloride
With Oxygen
aryl- and alkyl radicala2 alkr~xyl-q dialkylamine- and*qthev
monovalent organic groups) with a sinjI6 pa;313aSe of gaseous
oxygen or air can be obta-.J;'.nGd 'by meano,of thi-1 mentioned; re-
agents~ Earlier the assumption was made that''o-he oxidation~:
chlorophosphinal,Ion ar) well as the oxidatiom i:if phosphorus
trichloride havo radical character. Accbrdir,',v to this ansump-
tion in the oxidation of phosphoi~ts trichloride first~the
binding cf oxygen to this subetanl,e -takes plaqe4 The formed
compoutid can be either reGarded a* biraai~al (Cl POO) or aq
bipolar ion (Ci P06).PCI + 0 -4 01 PO& Th~-s addu:et
3 3 2 3
convzrts immediately with q ee,.;Ord mole-oule. sM and fdrms.
,
h
I C', .
* ?PO a~b dro-
phosphcroxychlorid6. CI k0 ~ PCI --;
en I
'
~
1 3
l
Ule rea..Jt-
1
carbon (RH) is prese it
~Qn it caa be
n
included in the rea,,,tion.-The biradical Cl, P06 forms the
organic radical Rs and the radical 6H:01 R6 ~~ RH --->Pocl
. 3 31.
+ Rj-+ 6H on the occasion of the coLlision Yrith the molecule
RH. Either of these radicals can lead to ths formatio!I of
the chlorine anhydrides cf the corresponding alkanephosphinic
Card 2/3 aoide. The initial stage of the oxidatlcin vf phosphor.uo' tr.i-

Sj~)Ir/T3-28_6_45/63
The Synthesis of Organophosphorus Compounds From Hydrocatbons an& Their'
Derivatives. VIII-4. The Investigation of Oxidation ;of'Phosiphorustrichloride
With Oxygen
chloride with oxygen is a heterogeneous pr6cess dependent
on the velocity of solution of the oxygeno,fte oxidation
velocity of. phosphorus trichloride. with gs.sepus oxygen does
in no case-!dependlon the~temperatureiThe,aotivation.energy
of this oxidhtion is very, small which fao-t~ points to the
assumed frea-radical character- of this" process., There are
4 figures and 11'references-, lo,of which 9xio Soviet.
SUBMITTED: May 29y 1957
1. Phosphorus chlorides--Oxidation
Card 3/3

AUTHORS: Zinov'yev, Yu. M., Soborovskiy, L. Z. SOT/79-29-2-55/71
TITLE: Synthesis of Phospho-organic Compounds~From.Hydrocarbons and
Their Derivatives (Sintez foafororganioheaklich soyedin7oniy'iz
u gle vodorodov i ikh proizvodnykh). IX, Oxidizing Chloro- '
phosphination of Butene-19 Butene-2, and Cyclohexene (IX,,,Oki&-
litellnoye khlorfosfinirovaniye butena-1, butena-2 i tsiklo-
geksena)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, lir 2--3 pp 615-619 (USSR)
ABSRACT: In their earlier paper dealing- with the re-a.(Itidn of hydro-
carbons with PC1 and oxygen the authors poinated out that
butone -1 is transformed by the reaction intO chloriC
anhydride of the chlorobutane phoophini ,c ac,id (Ref 1) with
the structure remaining open. In the preaert paper this
anhydride is shovim to be a mixture of isomaric.compoun0s.,
On expelling relatively large amounts of this product
(500 gr) fractiona were separated having the same compooil~ion
but different boiling temperatures. Oxidizln,g eblorophouphi-
nation of buterte-2 led to the same chioric.anhydride.
However, it boiled within narrow limit-9. Constants am'd
Card 1/3

Synthesis of Phospho-organic Compounds From Hydro- SOV/79-29-2-55/7-1
carbons and Their Derivatives. IX. Oxidizing Chlorophosphination of~But.ene-l,
Butene-21 and Cyclohexene
composition of the separated fractions are specified'in the
table. For a comparison also chloric anhydrides of isomeric
chlorobutane phosphinic acids, obtaiDed L~y oxidizin&chloro-
phosphination of I- and 2-chlorobutaite are shown the~re. The
tyro reactions indicated may be the cause of' the formation of
isomeric compounds in the oxidizing.rlxlorophoopliination. it
is probably the second one, in which the aubstitution. of one
of the hydrogen atoms by POC1 take a place, in conn.e.ctidn with
the affiliation of the formini J[C1 to the:dotible bond, a re-
action procedure that occurs Re, well with unsaturated oom-
pounds in the case of a substitutiori reaction (Ref 3)- The
boiling temperature of one of the fraotiona of chloric
anhydride of chlorobutane phosphinio~acid obtained from
butene-I agrees with the boiling teinperature of the products
formed from butene-2. The introduction of POC1 into the
2
methyl group proceeds more difficultly in the oxidizing,
chlorophosphination of. araffins than it would in the case
of the methylene group ~Ref 2). In so far.as there are no
Card 2/3 CH2 -groups in the butene-2, the second reactianshould less

Synthesis of Phospho-organic Compounds From Hydro- SOV/79-29-2-55/71
carbons and Their Derivatives. IX. Oxidizing ChlorophospMnation of:Batene-1,
Butene-2, and Cyclohexere
probably apply to it. For this reason in these compou.nds:the
structure of chloric anhydride must be ascribed to 2_~ 'chloro-
butane phosphinic acid-3. Thus in the oxidizing chlorophosphin-
ation of butene-1 the above compound may forra only 40,00rding
to scheme 2. The other traction 18 appftrelltly a mixtura trom
the chloric anhydrides of 2-chlorophonphino-I and I_c6loro-
DhosDhinic acid-29 forming according to scheme 1. The~table
show; that reaction 2 predominates. Also isomeric chloria
anhydrides of cyclohexene-and chlorohexane phosphinic acid
were synthesized. There are I table and 7 rcferences, 5 of
which are Soviet~
SUMUTTED: January 3, 1958
Card 3/3

50)

AUTHORS: -2
Soborovskiy, L. Z., Zinovlyev, Yu. M.' SOV/79-29--.4: 11/71
Spiridonoval T. G.
TITLEs Synthesis of Organo-phoaphorus Compoukids F110M.
Hydrocarbons and Their Derivatives (Sintez:
foafororganicheakikh aoyedineniy iz ulglevodorodov
i ikh proizvodnykh). X. Oxidation Cblorophosphination
of Some Ethylene Derivat-ives, (-X.' Okielitell noye
khlorfoofinirovaniye nekotorykh proizyodnykh etilena).
PERIODICAM Zhurnal obahchey khimii, 1959, V61 29, Nr 4, PP 1139-il4l.
(USSR)
ABSTRACT: In addition to some reports on the.ccidatu'm'*-,~chloroph6sph-ination
'l
(Refe 1 - 3) the authors,were able tb
introduce into.*his~
reaction also ethylene derivatives which cdntain bromine,-
chlorine, fluorine and a rather complex group such as.the
sulfofluoride radical. The oxido-chlorophosphination of
1,2-dichloroethylene, vinyl bromide,vinyl-fluoride,
if2-fluorochloroethylene and vinyl sulfoflaoride yielded

Card 1/3 the acid chlorides of the corresponding substituted alkyl
phosphinic acids. As is known, this oxido-ohlorophoophina~tion

Synthesis of Organo-phosphorua Compounds.From SOV/79-29-4-W77
Hydrocarbons and Their Derivatives. X6, Wda#ft'~17
Chlorophosphination of Some Ethylene Derivatives
of vinyl chloride under
the formation of isomers which
,
differ from one another:by the relative poiaition of:
chlorine and the radical P001 2(Ref 2). Theise acid
chlorides synthesized in this paper a pparently form also
a mixture of two isomers of the struc ture VII clrHv(o)cl
2 2
and CHCIXCH2 P(O)OI .. In~particular for the product of tho
reaction of vinyl fluoride with phosrnorus trichlori(le and
oxygen experimental data are available onAhe occurrence'of
isomers, the separation of which will be the subject,of
a special report. The reaction product of::the
oxido-chlorophosphination of vinyl bromid4 was divided
by fractionation into two fractions Which,differ nct,Lonl~r
by the boiling temperature but also by their composition.
The low-boiling fraction proved to be thelacid chloride.'
of bromo-vinyl-phosphinic acid, while the-higher boiling
one was the acid chloride of chloro-bromo-ethane phosphinic
Card 2/3 acid. The formation of the first compound probably results

Synthesis of organo-phoophorus Compounds From SOVT9-29-4.207
Hydrocarbons and Their Deriyatiy6o. X,,- Oxidat.104
Chlorophosphination of Some Ethylene Derivatives
from the second dehydrogenation of the acid
chloride of chloro-bromo-othane 101 M.- 34nie ~aoid in th6
distillation. Reference 2 confirms ITT the low-boiling
product is the 2-bromine-substituted.likibstanooo whiled
forma the higher boiling, one the I .--jvt.?-Iro-2-Umdbit-derivative,
and accordingly thoir formulae are .1RW*-CHP(O)Cl 2 and
CH2 BrCHClP(O)Cl 2 (Table). As by -ogsioMi I of the reaction of
chlorine with vinyl bromide the 1,,Z,,~hlorobromide ethane
hitherto unknown was obtained. A-)*i4stjUntly, the synthesis
covered the acid chlorides of I -cLb1.,),zs=2-brono-,, 1 2,2
trichloro- f luorochloro-, f M., loro- , and chloro-
(fluorosulfo~-eth
e
h
hi
i
I
C
an
n
c
oop
aee are
table
p
and 5 Soviet references.
SUBMITTED$ March 3, 1958
Card 3/3

dRa"Hwo W- ...... ............
....... .... .............

AUTHORS: 13yetrova, R. I., Zinov'yevj Tu. -M., BOY/79-29-6-6e/72
Soborovskiy? L.
TITLE: Synthesis of Organo-phosphoric Compound's From Hydrocarbons and
Their Derivatives (Sintez fosfororganicheskikh soyedineiiiy.iz
uglevodorodov i ikh praizvodnyich). X1. Oxidi~,iag Chlorophosphi-
nation of Nitriles (XI. Okialitellnoye khlorfoEfinirtyvaniye
nitrilov)
PERIODICAL: Zhurnal obsbchey khimii, 1959, Vol 29, 11r 6, pp 2088-2 092 (USSR)
ABSTRACT: In the reaction of the oxidizing chlorophosphina.tion 6f;! hydro-
carbons and their derivatives the C-P-linkalte rosultd;:, at the
same time acid chlorides of corresponding alkane-phonphinio
acidsare formed. The reaction was carried out by halogen
substituted paraffin hydrocarbons and by hilogen olefins. The
oxidizing chlorophosphination of alkoxy'oubstituted hyd~o,
carbons of ethers (Refs 1,2) is also poBsiblu-.~In the present
paper the authors analyzed the reaction of phosphorus tri-f
chloride and oxygen with cyano substituted para'ffins (nitriles
of carboxylic aci&a). It vras shown,that the oxidizing chloro-
phosphination of nitriles may proceed in two directions. The
Card 1/3 acid nitriles wit h 4 and more C-atomn per molecule form. acIid

Synthesis of Organo-phosphoric Compounds,From Hydro-,~ ~SOV/'19-29-6-68/72
carbons and Their Derivatives. X1. Oxidizing Chlorophosphination of Nitriles
chlorides of the cyan alkane phosphinic. acids Cn' El 2n (CN)JR(o)~C1 22
i.e. of compounds containing a C-P-linktwe. The first links of
the nitrile series (acetonitrile, propionitrile), as well as
benzonitrile, form in the.reaction with PCI and 0 compounds
3. 2'
which contain the P-.N.-linkage:, i.e. derivatives of acid: chlo-
rides of the imido-N-phosphoric acids, which norrespond to the
formula RCC1-NP(O)("12& Adid chlorides of thp oyanoprQpane and
the cyanobutane-phosphinic acids have been aynthesized.:Two
acid chlorides of the imido-H-phosphoric acid have been obtained
whose structure corres~ohds probably to the formulas
C H CCl_1TP(0)Cl and C H CCl-NP(O)qi The acid chloride
2 5 2 6 5 2'
of the imido-IT-phosphoric acid; which~ii~ forned from a0to-
nitrile, could not be separated in pure state. For the hitriles
of carboxylic acids, which contain more than thrce C-atoms, the
oxidizing chlorophosphination Is carried out:a ccording .to
acheme (1), and for the acetonitrile, propionitrilep and benzo-
nitrile acoording to scheme (2), and leads to the P-N-linkage.
Card 2/3 The spectroscopic analyset~ have been carried out~'by

1;1 fill Ill 1.11111"; JI'li,
Synthesis of Organo-phosphoric Compounds Fxom Hydra-. S04/79-29-6-1618/72
carbons and Their Derivatives. XI. Oxidizing Chlorophosphination of Anitriles
N. P. Rodionoya, S. S. Dubov, and V. V. Fedotlava. There are
1 table and 5 Soviet references.
SUBMITTED: March 3, 1956
Card 3/3

50)
AUTHQRSt Soborovskiy, L. Z.f Zinovlyev, Yu. M. 07/79-29-7-1 1'0183
TITLE: Allyl Esters of Some Alkane-t Alkene-I and Chloroalkane'
Phosphinic Acids (Allilovyye ofiry neko,torylL~ alkan-t~alken- i
kh,loralkanfosfinovylch kislot)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29t,h'r 7t, pp 2152-21,54 OUR)
ABSTRACT: Allyl alkane phosphinates are of importance as initial,products
for the nynthesia of various polymer pvoducts Up to now some
alkane and alkene phosphinates have belin obtained by causii.ig
allyl alcohol to react with acid Oilorides of-the corresponding
phosphinic acids (Refs 1, 2) or, according toArbuzov (Ref 3),
from triallylphosphite and alkane halides. Allyl ootanq
phosphinate ras synthesized according to XeteTOnCe 4. Kamay and
Kukhtin (Ref 5) described allyl chloroalkano phoaphinates, In
the present paper some allyl alkane, allyl alkene, an&,allyl
chloroalkane phosphinates wore synthenized. The acid dichlOriden
of the corresponding acids rhich had boon obtained by oxidizing
chlorophosphination of paraffin and olefin Lydroaarbona .
(heptane, cyclohexane, propylene) butaria-l).vere used as initial
Card 1/2 substances. As far an some acid dichloviden obtained by this

Allyl Esters of Some Alkane-I Alkene-, and S.OV/79-29-7700/63
ChIproalkane Phosphinic Acids
method were mixtures of isomeric coMpouivIsg:the reaul-t4nt'
estero aloo consisted of isomers whiA'diff6red by the'~Position
of the phosphorus-containing residue in the,hydrocarbon. radical
(Refs 7P 8). Moreover, the acid chloTiaa of:pTopene phosphinic
acid was obtained by dehydrochlorination. of'.the acid chloride
of chloropropane phosphinic acid. This acid chloride 66uld be
transformed into allyl propene phosphinate which probably
contains an admixture of isomeric compounds. The constants_.of
the compounds synthesized are tabulated. There are I t6bleand
8 reforences, 6 of whiah are Soviet.
SUBMITTED; May 15, 1957
Card 2/2

'573 S 0';/ 7 9 --6: 40/81
29
AUTHORS: Soborovskiy, L. Z.
TITLE: Synthesis of Organo-phosphorus Compounds; From Hydrocarbons and
Their Derivatives.XII. Oxidizing Ch.loraphosphination of Halo-
genated Alkanes
PERIODICALt Zhurnal obahchey khimii, 1959, Vol 29, Nr Bf:pp 2643-2646 (usn)
ABSTRA.CT: In the present paper, the,reaction of phosphorus triefiloride
and oxygen with 1,1-di- and 1,1,1-triahloro-,ethane, 2-chloro-
butane, and 1-fluoro-2-chloro-ethane an well.as with the ropre-
sentatives of the monofluorine, bromine and iodine derivatives
of the paraffins was investigated. All these haloren alkanee,
excepted the iodine derivative, are subject to the oxidizing
chlorophcyd~hination, and yield the acid chl6rides of the
corresponding halogenated alkane-phosphinic.acidst
GnH2n+lHal+2 FC1 3 + 02 -),CnH2n Hal P(O)C1 2+Pocl 3+HCl..
The alkyl iodides apparently contain a small amount of iodine
Card 1/3 which inhibits the oxidation of PC1 3 with oxygen (Ref 2). Thus,

S,,nthesis of Organo-phosphorus Compounds Prom Rydrocarbonn 507/79-29-8-4.o/8!
and Their Derivatives, XII. Oxidizing Chlorophosphination,of Halogenated
k1kanes
the butyl iodide does not enter into th4s! above-mentioned
reaction, and even hinders the oxidatioh of rcl into the
1 3
phosphorus-oxy-ohloride. Table 1 gives the rdsults of the oxi-
dizing chlorophosphination of the halogo'n alkanes used, ' and
characterizes the acid chlorides of the halogen-alkane-phosphinic
acids. The acid chlorides (V) and (VI) could not be separated
as such. Their formation in the oxidizing chl*or,ophosphination of
the above-mentioned chlorine derivatives of ethane had1o be
confirmed by transformation of (V) and.(VI) into the diethyl
esters of the corresponding di- and tric'nloramethane-phoaphinic
acid. When treating compound (V) with water, it is not only
converted into the free acid, but at the tame,time the duahydro-
chlorination of the 2,2-dichloro-ethyl radical takes place,
probably according to scheme 2. It was p,~esible to carry.out~
the oxidizing o:ilorophoaphination of bromine-lazd fluorine-sub-
stituted paraffins as well as of some mono-, di- and triOhloro-
alkanes. The acid chlorides of the 1-bromo-butlane-7 2-flubro-
Card 2/3 propane-r).fluoro-2-chloro-ethane,
2-chloro-butanL-,.-,2.;Qj.'4
I ~ 47t, ~ -

-Synthesis of Organo-phosphorus Compounds From Hydrocarbon" SOY/79-29-6-4o/81
and Their Derivatives. XII. Oxidizing Chlorophosphination of Halogenated
Alkanes
chloro-ethanej
,; and 2,2,2-trichloro-etharie-ph6sphinic acid were
synthesized. The diethyl esters of the 2,2-dichloro- and 2,2,2-
trichloro-ethane-phosphinic acid were obtainad, Table 2'shows
that on the oxidizing chlorophosphination the 1-bromo-bUtanc
behaves in exactly the same way as the.1-chloro-butane and
I-cyano-butane. There are 2 tables and 6 Soviet references.
SUBMITTED: May 15, 1958,
Card 3/3

3/036/60/06Q/008/013/613
B021A954
AUTHOR: Zinov'yev, Yu. M., Doctor of Chemical Sciences
.........................
Organophosphoru
TITLE: 21monomers and Polymers
PERIODICAL: Vestnik Akademii nauk 58SR, 1960, No. 89 !pp. 144-144
TEXT: This is a review of the book by ~.e. L. Gefter: Ponforarganichesilye
monomery 1. polimery, published by the izdaniFe -AN 6SSR (Publishing House
AS USSR) in 1960. The book comprises 286 pagesq the edition 6,000 copieslp
and the price is 18 rubles 90 kopecks. The abstracter states that the
issue of collective volumes on the chemistry of organic-phosphorus
compounds~oan be regarded as useful in view of the great number of
individual. papers which have been published duxing the past 10 years. The
issv-e* of the book is the more useful since a similar collective volume : /
by V. M. Plets was published in 1940 and is considered outdated. Ye. L.~
Gefter's monograph consists of 2 parts; The first part doals with organo-
phosphorus compounds from which high.-molecular, phosphorus-containing
substances can be prod-aced. The i3e-nond part gives publication data on
high-molecular organophQsphorue compounds and their Mod" of applicationq
Card 1/2

OrganopAosphorus MonomerB and Polymers S/030/66/00,0/008/013/0.13
B02-1/BG54
The author classified all data of Doientific and patent publioations on
organophosphorus monomers and polymers which appeared until 1959. The
abstracter regrets that the 7th section ofthe monograph.dealing with the
use of hi~h-molecular organ opho sphoru s compounds is written irt ouch a
concise O?M, ana stresses that nothing has been said on.the 1kractical
use of monomeric organic phosphorus compounds. Among othezs, the
abstracter indicates the following shortcomings of the bcok: Poor
selection of material; some well-known papers like those,by M. 1.
Kaba.chnik and P. A. Rossiyskaya are not mentioned although they had been
published in the "Izvestlya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk" 1959, P. 1398; unusual technical. tserms' are usei in the book. In
spite of some deficiences, Ye. L. Gefter's collecti-ite volume is oonBidered
absolutely useful, not only for experts in 41his field but also! Cot a wide
circle of investigatora in the fields of el amen t al.. organLo compounds, and,
of organic chemistry in general. There are 3 references: 2 Soviet and I
British.
Card 2/2

3/079j6O/O.30/05/34/074
B0051BO16
AUTHORS: ZinovOyev, Yu. M.. Boborovskly, L. Z,
TITLE: Synthesis of Organophosphorus Oompoun-161prow *droqarbons~an&
Their Derivatives-. X-N. 0xid-afiv-e-t=0rophosphination of4finil
ChloridaiWith Methyl-diohlor'o Phosphine and Preparation of
Some Nst~rs of Dialkyl-phosphinic koids.1
PERIODICAL: Zhurnal obehohey khiaii, 1960p Vol- 30, Nio- 59:PY- 1571457Y
TEXT: In the present paper the eynthesis of some ohloro-substituted.ilkyll
e6ters of dialkyl-phosphinto acids in described. 10 o6lapounAs of the.
K
following 3 types were synthesized:
CH OR CH xC R CH OR$ R CH
3 *\ -, 3\ 5 3
P P n,-C4a9 Ca (CH3")
Cl H C 0 Clog-CH 0 a H 0 C9 CH(CH
2 3 2 3 7 2
(A) (C) X 0 or 3, R1 - CH Cff:C3,
2
CHOH~
2 2.
Card 1/3

Syntbesis of Organophoophorus C*mpounds From S/079/60/03Q/05/34/04
Hydrocarbons and Their Derivatives, XIV. 0xidattva BOO5/B016
Chlorophosphination of Vinyl Chloride With Methyl-
dichloro Phosphine and Preparation of Some
Esters of Dialkyl-phosphinic Acids
The acid chlorides of nothyl-dichloro-ethyl-phosphinic.':acid;T(I)O:methyl-2-'
chloro-ethenyl-phosphilkic acid (I1j, and methyl-propyli-phosphinic acid:
(III) were used as initial products for these syntheses. Thos, e acid
chlorides were esterified with the corresponding alcohols. The acid
chlorides (I) and (II) were first prepared by the authors by' oxidative,
chlorophosphination of vinyl chloride with methyl-dichl=,phosphine in' tbe' tX\
presence of oxygen; the third acid chloride was described previously,"
(Ref. 2). On distillation of the products of the aforo-men~ioned reaction
of vinyl chloride with methyl-dichloro phosphinep a pttrtial bydrogen
chloride separation from the acid chloride (1) is likely to occur, td.give
the acid chloride (II). On oxidative chlorophoophination of vinyl chloride
with phosphorus trichlorideq the acid chlorides of is6merio dicbloro-~
ethane-phosphinic acida result (Ref. 1). Therefore, isomeric products are
also likely to result on oxidative chlorophosphination of vinyl chloride
with derivatives of phosphorus trichloride of the IRPC12 ty:pe, for instance
with the methyl di-chloro phoop-hine discussed. Accor4inglyp it seens,very
Card 2/3

Synthesis of Organophoophorus Compounds Prom B/C)79/00/030/05/34/074:
Hydrocarbons and Their Derivatives. XIV.Oxidative 2005/3016
Chlorophosphination of Vinyl Chloride With Methyl-
dichloro Phosphine and Prepare,tion of $one,
Esters of Dialkyl-phosphinic Acids
probable that mixtures of isomeric. eaters were obtained~in the eater
synthesis fromthe said chlorides prepared~bj chlotophosphinition which
howeverp were not separated. In a table, all compounds eynthei sized by the
authors (the 2 acid chlorides (1) and (XI)o 6 eaters of4ype;(A), 2
esters of type (B)p and 2 eaters of type (C)) are limtedo Yield, boillits
pointv densityg refractive index# and molecular refraction are given for
each of these compounds. In an experimental part, the WithosAm of the
individual compounds is described. For all'subetances sypthenized, the
results of the ultimate analysis are givan. There are I table and 4
references: 3 Soviet and I 'Azterican.
SUMITTED: May 289 1959
card 3/3

ZINOVIYZV, Th.M., doktor khimicheskikh nauk
Mosphorus organic nonowers and ~polylsers by XPlArdt6r. Uvieved
by IU*K.Zinoy lev. Test.Al $$$R )0 no,8:142-1W Ag 160.' (KM ii.-8)
(Phosphorus organic compoun4s)
(Gef %or, ILL.)

i~cl-
SOMM cmg.-
AMMOR: Go-'Olobov, Tuo G.;
DpZ
to I
sou.-,,S~Z a-urnad ac)~Szlo-ae-, ;C:.,
F77
s
j
naterla.1 for 0,5
aikervil aster I O'~l t re ac 1. o f rn ou Lj
In the presenee of 1,;t N vinyl. - 'Outeiny:.--l cni"...)rophocphate
(17) Bj tr,es,.t1nC-, wl.t~. aratylaamtone In th(ij prevEincia of
Et 11) the oompotind

BlItCHM010 0 Or)
GH2mlC'HO_
was obtained, which 1 :1 rhe CIL-r -ut phcisphorl.,~ aold viter
~-,a 11 ev ve rr. i v e )a 1, o-
rgaotlor, of

mill;

Ccrd -2/2
RILJ U
f~71 ~--gvffg ~~Mdnlnl M- ~, p, I I'll 'IM-11-Ift-limn ftmr-a-l"Int-

L 41353-66 EWT~m)zEr#P(,j
ACC NRi AP 6021421 SOURCE CODE-. UR/O~-I,

INVENTOR: Ivin, S. Z.; Zinov'yev, Yu* M.; Kulakova, V. I.; Droad,___ .

ORG: none
TITLE: Preparation of alkoxyalkyldifluorophosphortn-eg-.I Class 121
No. 182158 57
SOURCE: Izobreteniya, promyshleanyye obraztsy, tovarnyye znaki,
no. 11, 1966, 21
TOPIC TAGS: organic synthetic process, organic phosphorus compound,:
fluorinated organic compound
ABSTRACT: The subject of this invention is a method tor the prepara"
tion of alkoxyalkvldifluorophosphoranes by reaction of alkylphosphonous
difluorides with alcohols at -35 to -50C and in the,presence of.
tertiary aminea, e.g., dinethylaniline. (JKI
SUB CODE: OT/ SUBM DATEt 26Feb65~
X A, I I
11b,
UDC: -54T#4194407

1 1 V

ZINOVIYEV, Yu.M.; SOPOROVSrLIY,,, L.Z#
Interaction of tatraethyllead with phosphorus trichloride or
methyldichlorophosphine and oxygen. Zhur. ob. kli:Lm. A no. 3.1
929-932 Mr 164. (14IRA 17:6)

ZlNGVIYEV, Yuriy Elikolayevich
(Analysis of potentialities for reducixg the cost of
coke] Analiz rezervov snizhenlia sebestolmooli ko?,sa.
Moskva, Metallurgiia, 1965. 105 p. (MIRA 18-.4)

I IIH IHIP 11 1 Ill ',l 11*1 ItIJ!
1AY, 137-1958-3-4835
Translation from: Referativnyy zhurnal, Metallurgiya, 195,8, Nr 3, p56 (USSR)
AUTHORS: Zinovl yev, Yu. N., Benuni, A. Kh.
TITLE: The Problem of Comprehensive Utilization of Ural Copper
Ores (K voprosu o kompleksnom ispolIzovanii mediiykh rud
urala)
PERIODICAL:' Tr. Ural' skogo politekhti. in-ta, 1957,N~. 66, 160-169
ABSTRACT: Bibliographic entry

ZBOVEVA, A.
Kratkii Tekhnicheskil SpravochnLk-.. Chest Vtorata (Tech. Fortmilai-I u)4 Beferemce
Book- Part 2), 768 P., bbscow and Leningrad,, 10,50.

ZINOVIYEV, YuoN*p kand.ekon=.nauk; VAYSBERGp NoS., kand. ekon. nauk~
Raise the level of the training of chemical engineers
in economics. Zhur.VKHG 10 no-42451-452 1654
()MA 18:11)

4-1-11111 -1 A 11 .1,
ZINOVEVAO A.
Fratkii Tekhnicheskii Spravochnik- Chast PerveLia (Technical Formulary and
Reference Book- Part 1), 532 p., Moscow and Leningrad, 1949.

Structural changes in the stalk and leaves of Zea mays L.
during Bot,zhuro 45 rLO#3:400-404 Mr 160,
(KIRL 13:6)
1. Vitabskiy-pedagogicbeskiy Institute
(Cor7n Maize)) (Inoilage) (Botarq-Anatomy)

ZINOVIIEVA,,A.D.; ISURDIA,-RIJ.
Making visual aids on batany in Us ~club of young naturalists.
Biol. v shkole no,5:82.-83 S-0 161. (mA 141-9)
1. Vitebskiy pedagogicheskiy institut.
(Botark~--Audio-visual aids)

9-INUMEVA, A.D.
Anatomical changes in 1-he iitrl- --'k of chev'l. Bot.~ ilv,.q:~. Eel.
otd. V130 no.5i!79-181 ~63. 1,74-5) ~
q

KqcrokineLias of Iiit-trogennoiis processes over moving catalysts.
Trudy VNII NP no. 9t'4168~-273 163, (ICB-PL 17t6)

S/065/60/000/012/001/607
zo3o/z4l2
AUTHOR: ZiD0vfY"A,_A,.~
TITLEs Transient Response Characteristics of Sono Types of"
Chemical Reaction
PERIODICALt Khimiya I tekhnologiya topliv I masPi, ig6o, No.121;
pp.1-10
TEXT: In order to assess the feasibility of anlautomatic, protess
control system, a mathematical comparison is drawn bitween fi~r~t
order physical processes (such as scrubbing or washing) and, firsts'
and second order chemical reactions. The first two,involve,
relationships linear in the concentration of reactants and the la.s
Involves a quadratic relationship. However, similarities ifi,;
behaviour occur and become apparent on introducing a imensionl.efss~ t/
parameters for the ratio of residence time to,physical time.;
elapsed within a reactor, the initial to final,concentratiori in the
system, and the initial to the asymptotic concentration for!
infinite time in the system. Similar curves may t,hen be &awn,
relating the relative time required,for completion of each 'Process
to the non-dimensional residence time parameters, or alternativily
to the non-dimensional degree of conversion in:a finite time-.
Card 1/2

S/065/60/006/012/001/007:*:
Transient Response Characteristics of Some Types~of Chemical
Reaction
For systems with complete mixing and high degroem~of qonversion
there is considerable inertia in the This, together
with the aid of the curves referred to, enable mathematical mode la
for feasible process control systems to be envimaged. There Are
figures, 2 tables and 6 references: 2 Soviet and 4 non-Soviat#
Card 2/2
lam. wNMA!iIM
........... ............ .
.. ........

H, ai i I ~

Fundamentals of Synthesis Technology (Coat.)
1. Acetylene manufacture (P.A. Tesner] 113
1. Thermodynamics and kinetics of the process of acetylene forma- v
tion from methane 114
2.
Processes of acetylene manufacture 116
*
3. Extraction of acetylene 121
II. Conversion of hydrocarbon gases for hydrogen manufacture
(A.G. Leybush] 124
1. Conversion of hydrocarbon gases 125
2. Thermodynamic equilibrium 126
3- Catalyst for conversion of hydrocarbon gases
4. Kinetics of the reaction of methane interaction with steam
over a nickel catalyst
- 131
.of-the conversion process of hydrocarbon gases
5- Flow sheets 131
6; Comparison of flov sheets 137
7- Conversion of hydrocarbon gases under increased preigaure 130
Ch. IV. Separation of Fractions and Technically Pure Hydiocarbons
From Hydrocarbon Gases and Liquid Petroleum Products, 143
I. Division of hydrocarbon gases into fractions [AJ. UnOvIyeval 143
Carr"

Fundament als of Synthesis Technology (coat.) SOV/4659
I.- Preliminavy preparatioa of hydrocarbon gas mixt ures 144
2. Purification fran mechmical impurities
3- Purification from sulfar compounds 146
4. Removal of acetylene 150
5-. Dehydration of gases 153
6. Division of gases into fractions (fractionation) 157
7. Extraction of the propine-propylene fraction and separation of
propylene.froupropane 159
8. Extraction of ethylene and ethane 163
90 SepamtIon of matItene 175

100
Adsorption stripping ot gas miAwme 17.6

U. OUM
fracti
Scm physicochemical problems of hydrocarbon gas
181
,
Ii. Division of Uquid p'stroleun products into fracticas, [A*I. Skablo.
and V.A. Skoblo) 18
Adsorption 183
1. Nature of the adsorpticm process 184
P. Characteristics of adearbents 99

3.
Adsorption stripping cd' hydrocarbon AixtureO +
4. Regeneration of adsorbents
Card 5A

I Hr I14 -1 'jy,p 1411, 1 1 11 'jw~
OHOCHKO, D. I. ZINOTIVITA. A.P,
Developing a theory of chemical reactorao Xhim#i tnkhotoiasi
masel 5 no.4:49-53 AP 160. (HLM 13.- 6)
1. Voesoyuzrq7 nauchno-iseledovateVskiy inatitut p0 perarabotke
nefti i gaza i poluchenlyu iskusstvennogo zhidkogo topliva.
(Chemical apparatus)

ii ri11 m, i ir ii -i r,
EINOVIYZVA, A.P.
Transient dynamic chavacterist~cm of certain types of chsmical
reactions. Xhim-.1 tekh.topl.i masel 5 no. 12: 1-10 D 160.
(~IIRA 13:32)
(Chemidal. reaction, Rate of)

OROCINO, D.I., ZINOVIYFIVA, A.L
Principles for the control of the operatlon ofireactors used
lu large scale catalytic processes, Kin. i kat. 1 aa.1-.162-169
Yq-Je 160. (MIRA 13p,-8)
1% Laboratoriya khimicheskikh reaktoroy Vsesqytinnoga nAuchno-
iseledovateltakogo inatituta po pererabotke nefti I gLzov i po-
luchenlyu lskusetvennogo zhidkogo toplivae
(Catalysts):

ZINOVIUTA, A.P.
Means of determining tezpevit~rda oqul~aent to average rs=,.Ivu
rates of nonisothermal processes in flow reaetoirs. KUm i*tekh,~
topl. I masel 3 no,3:34-42 Ur 158,
OIIRA 11:3)
(Chemical reaction, Rate of)
(Temperature)

- ------ ------
CROCHED, D.I., prof.; MELIX-AXMWAROT, T.&., kandtekhn.nauk;
ZIN071YEVA, A.P*
Reaction vessels for chemical processes in a fluldized bed.
Shim.nauka i prom- 3 no.6-.694-703 '58. 1 (MA 12-.2)
Fluldiution) (Chemical eTwineeriu&-Aquipment~: anct

UT!'ORSt Orochko, D.I., Prol,.'essor, Melik-Akhriazaroitt T.Xh. ,C-iindi;idt t61*
Technical Science3j, Zinovlyevap AoP,
TITLE: Reactor Installations for Chemical Processes in the Boiling
Layer (Reaktornyye ustroystva dlya. khimicheskikh protses~'Q'v v:
kipyashchem sloye)
PERIODICAL: Khimicheska a nauka i promyshlennost', 1958, Vol.III, Nr6,
pp 694-703 ~USSR)
ABSTRACT: The method of pseudo-liquifaction of finely ground reagent s,
catalysts, etc by means of a boiling layer hasaroused. con'-
siderable interesti A diagram of a usual~regenerating reactor
in catalytic cracking is shown in Figure 1. In *many cAs~9 tho
now technological processes caused no changes in the exi3ting:
equipment (Figures 3-7)- In reactors with continuous regqnera-
tion of the cataly-sts the system may be even simplified (P
.Igul~-e~
,
It is used in the highly exothermic catalytic synthesi,.:
hydrocarbonz from CO and H2. The unwanted circulation with-
ir, the reactor i3 ~tliminated by dividing it into sections.
This seationalization complicates the reattor constructions,
Car; 1/3 but f6~cilitates thet realization of many chemical processeEl in,

Reactor Installations for Chemical Processes in the Boiling -L!iyer
industry. The introduction of thL high:--y r pactive componen t
into the riaction zone by .9mall portions has the same effoot
as sectionalization. Another method is the use of a counter-
flow of the 3olid material and the steam-gas components. It
has bcen shown that the oxidation regeneration of catalysts
under the conditions of a step-wise countexflow in accelerat~'d
10 - 11 time,_ The catalytic cracking of oil distillates
under the same conditions is accelerated 2'- 4 times. The
heat transmicaion f:,-om the boiling layer of thelpowder-like
materials to the cooling boiling water reaches 250 - 300
kcal/m2 per hour anti OC. Reactors with parallel *ectional-
ization (Figure 12) have been tested in the reduction pro-
cesses of ore3 with loy: sulfur content. In these reactors~,the:
equal removal of the material wtth low suli'ur content from the.
various secticna is most importaht. Diagrams of the interior
installationn of ono-section reactors with boilipg layer used
in catalytic cracking are shown in Figures 13 and 1,1. The,de-.
C-Ird 2/3 vice for the removal of excess beat of reaction is very importn.nt

Reactor Installations for Chemical Processes in the Boiling Layer
for satisfying operation. 'The described methods and ine'tal~-
lations find a large application in atomic and nuclear~trans~--
formations (Figure 17)-
There are 17 diagrams, I tablep and 26 references, 17 of which
are Soviet and 9 English.
Card 3/3

06
00
00
00
00 9
06
00 a
drAwomill un g4mie am*mmmLql
N 0
rd ,a
tke On cc cadeflotwo d
aEFAIP. =7 rs.,
M. C. h1l"Iftr

lot

qoo
:00

cool

StUUMCAL UMAtWl MAIMCAVIM
A
06-,-41 t.. w 0
tc
It te aW~4 4
0:60::06606086648*0* : 00.
00 00000*9*00swole

.......... . ............ .. ......... ...................
OBRYADCHINOV. S.M.; OROCHKO. D.I#; ZINOVITSTA. A.P.
[Pbtrole= technology] part, 2. Tekhnologiia neffl. Ind.3-0, pere'r.1
dop. Pod red. i a dopolmouiLani D.I.Orochkogo. Moskva,%*. nauchnoi-
tekhn. isd-vo neftiazol I gomo-toplivnoi lit-ryf 1952, 408 PO
(Petroleum--Rafining)

USSR General Biology. Physical and Chaio&l Iialogy,
Abs Jour j Ref Zhur Biol., No 2. 1958, No 4738.
Autho r s Graevakiy, E. Y%., Zinolrleva, E.G.,

Inst 3 Not given
Title 2 The Effect of small %wati ties of: Tonizing Radie~tion jala~
rmaecium Caudatum tn Radio -Stirk.ulation)
Orig Pub t Dokl. AN SSSR, 1956, 110, No 3, 379-382
Abstract iThe effect of =an :Aodes (0.005,:0.05, 0.5, 2~$ azd 10i
rep per hour) of radioactive emanati6ns was at~aied 6 n~ the
re6te of Par=aeci= caudatum division. The mdi&tion was
conducted uninterruptedly Ib r 71 days. 335 (irc U& f orm, of
N%0350
4) at a dose of,0.02 rep p(br hour and 113'1 (ini ibe.
form of Nall3l) at dosels of 0.05 5 rep per homr yWdod
Card 1/2

f A #110111111444it-w-4 A- 14 ~Al IT, 11 fit If:
60 4W moriv still the cakiam cuntitat to
sca" of sAbbide d v9pertmoatel athorifficlitiosilm
00 It
cl 'twectitlind
N'libml' Ind JAY%.-cfi6t. ifiallarst ill lk likomil 4,41110%,
inii-valvati dwwod no dinvOulaticso to the
of the 44horowlenoilm in file CXWI. SolnMIS, 11tt intivam,
ill litt Co walml dutifig thq %mm- ul the !"velitillationt
11 WTI citmulft-94ill with flit pr~wrfsis #4 the 00
00
"wt hil values thowed fit) 41i'lilAcrort fit. All 't
i4fitinsof the above In"Itio"'d (111411fifirl, ~bfmrfj to
Y%64. claracgo ilot~~ftt:' u;xx; lilt- tirtle ~'r food W, J
M. G. Stfillff. offi
00
fee
ji
Wit "IFOR
0 IV
u &V 00
to ff it it it x it of It of it U is it !W
000 0 0-110 * 9 0 0 *:; 0 00 ::~: : : 0
~404 on 00~0*m go"
000 lilso 0 0 0 4 P- 0 0 0 0 0 o
0.0

SOURCE CODEj UR)
1ACC NRo A%66546
AUTHOR., Zalftsman, G. L.s Zinovtyeva, 1. Sq_ytch, A. 8alivr~,4. 1.
ORG: none
TITIE: The functional state of nervous system centqrs in humans and animals during
the formation of convulsive reactions tobnQroxia (Paper presented.at the Conference
on Problems of Space Medicine held in. Moscow from 24 to 27 may 19661
SOURCE: Konferentsiya po:problemam kosmicheskoy maditainy,,1966. Problemy
kosmicheskoy meditsiny. (problems of space twdicine); materitily konreren
Mosco-e, 1966p 176-177
TOPIC TAGS: hyperoxia# central rtarvouB system, oxygen induced convulsion,
electroencephalography
ABSTRACT:..A complex study was made of higher nervous activity, Mats and EW~,
:(electromyograms) and-cardiovascular and respiratory system parameter
-measurements in human subjects who breathed high-pressure (3. 5 and 4 at)
ioxygen until'the Initial pathological epileptoid symptoms appeared. Experi-
,ments beyond that point utilized dogs and rabbits. In the animal experiments',
,,electrodes were implanted in various parts bf the brain, including dee'p
'structures, and electrograms were made during respiration of oxygen at I
pressures up to 5 at various stages of the formation of the convulsive
'reacti n,
Y12

...........
L 10948-67 - -
-kit Rs AT 036566
It was found that in the initial stage of hyperoxia, high voltage:dis-
.charges appear on the EEG of hurnans and the electrosubcorticogram of
These shifts are compensated in this stage and do not affect be-
havioral and sympathetic reactions,, which show adaptive changes only.
In the final stage of high pressure oxygen breathing the precursor
;period whole groups of subcortical and cortical structures are recruited
'into the.process, and dysfunctions ofthe motor, cardiovascular, respira-
tory, and other systems of the orgardsm simultaneously app0ar.
This precursor stage is followed by the onset of chronic convulsions
due to profound disturbance of the normal'processes of cereb.ral reffula-
tion. and the appearance in all structures of epIlleptoid pathological
rhythms. [W.A. No, 22; ATD Report 66-U61,
Sun CODE: 06 SUBM DATE9 0014ay66
Card

ZINOTIYVA, I
Method for a rapid tentative determination of bilirubiti. lab.delo, 5
no.5:19-21 S-0 159i
1. Iz biokbimicheakoy laboratoril (sav, - prof, L,G,,~ Shirnova) Fau*aa.-
Iseledovatellskogo inotituts. akasheretva i ginakologli Niulsterstya:
sdravookhranonlya RST'SR, Moskva.
(BrLIRTJBIN) (BLOOD-11FAMINAN ION)

IVANOV. I.I.; UAMOVA, HIROVICH, N.I.; XOISNWA, T'PP.;
FARS1111a. N.A.; TMOINSKIT, S.Te.i"'watymv, ir.A.
7ractional compoeition of proteins and contraotile function
of various muscle typos. Biokhlmila. 24 no-3,.451-458 Xy-Je
'59. (HLU 12-.9)
1. Biochemical laboratory of the Institute of Obstetrics and
Gynecology, Academy of Medical Sciences of the U.S.SI-R.,, Chair
of Biochemistry of tho Pediatric Medical Institute, arA the
Institute of Blood Transfusion, Leningrad.
(K=Lv.
fractional composition, eff. an musco COD-
traction (Rua))

ZINOVITRVA I.P.
Contractile proteins of the uterus. Akush. i. gin. 35 noo2:43-
49 mr-Ap '59. (MIRA 12:5)
1. Iz laboratorit biokhimii (Sav. - rof. L*G.Smirnova)
Institute, akusheratva i ginskologil Mr. -,clots. L.G,.
Stapanov) Hinisterstva zdravookhraneniya RSVSR.
(PHNGWOT, metab.
contractile proteins (Hug))
(PRMINS, metab.
contractile, of uterus in pregn. (Rue))

t AdC'N& AT6036568 SOME CODEs UR/OOW/66
X.;THORO. Zinov1z!Va, 1. P.; Rubashkina, L. As
Kosting V. K.
none
TITLE., Blood transaminase as an indox of htursan tolerance to landing iz~pact
accelerations &aper presented at the Conference on Problem 61 D Medicine' hold
----Wom 24 to 27 May
in Moscow 19667
SOURCE: Konferentsiya po problemam. kosmichaskoy meditsiny, 1966. 11~-oblemy
kosmicheskoy- meditziny, (Problems of space madicine); materibly konforentsii.,
Mostow, 1966, 177-178
TOPIC TAGS: space medicine -space physiology, blood chemistryt impact accelerationo
biologic acceleration effect, human physiology
ABSTRACT: A "tolerance criterion't.of,impact accelerjation is blood transaminase
:activity. The literatbr6 sh&Ws that the -activity of* thei~e bnzymes inctdas &s
,'.as a result of injury to tissues.
in this study, a change in the ILCtiVity of glutamic-alanine, and glutamic-
aspartic transaminase was studied. Human subjects were exposed to landing
accelerations with various buildup rates (2500-6000 G/sec'and higher)
acting along the longitudinal or transverse axes of the body; in 32 experiments.;
-It was found that large accelerations (32-42 G),with a build ate'l-0,
Vcaii 1/9 ... Up, r, _F:

09 9-67
-4(-f C-N i -AT 66Y6 5TA_
2500 G/sec (chest-back) and 22 25 G accelerations (head-pelvis) with a
'buildup rate of 2500-6000 G/sec. (7. 6 m/sec landing velocity), increased
transaminase activity by a factor of 1.5-2.0. The activity of these: enzymes
'Was occasionally accompanied by fresh erythrocytes in the urine. At lower
rnagnitudes, enzyme activity was not altered. The highest indices of . t~ana -
aminase activity occurred 24 hr after exposure to acceleration. After
A-5 days, these indices ret-arned to normal. In the majority of cases,
the increase in transaminase activity, which reflected diarupted tissue
~integrity, preceded other functional changes and indicated that acceleration
.,,which could be well tolerated. These tests showed that the activity of
'transaminase enzymes during impact accelerations is a sufficiently sensi-
tive index by which tojudge the reaction of the manism to a,,~ ra C
_ppli d
:22; -ATD
SUB CODE: 06 SUBM DATM~ OWv66
LCard 2
lawn

GRINZAYD, M.I.; ZINOVIYEVA, 'I.S.; IVANOVA, N.M.; VOSTRIKOA, E.P.
Contont of pathogtinJc ntaphylococci In tho fecen of' (-JiLldven wttn 16-
tastinal clLseases. Zli,jr. mikroblol., apid. J. inum. 41, no.1101-35
165. (MrRA 180)
1. Kaybyahevskly institut, epidemiologil., mikroblolcgll igigipmy.

Use of fluorescent serum for the rapid diagnosin of dysentery.
M=# mikrobiol.p apid,, i hmm, 33 nosl2t112-115 D 1624
(KIRA 16:5)
1, Iz Kuybyahmkogo imstituta epidemiologiip mikrobiologii i
gigiyany. (DYSEVTERY) (SEMI DIAGROSU~

KOVALEVSKAYA, I.L.; MHTL?YU-LITVAK, R.V.; DMITMEEVARAVIKOVICH, Ye.M.;
KURNOSOVAj, N.A.; SHCHEGLOVA, U.S.; FMINAIM, U.K.;
KHCMIK, S.R.; MAMMINOVSM, L.P.; PETROVA..
GOLUBOVA, Ye.Ye.; 0011CITAROVAl I.I.; SARMAIEM, A.P,;
SIZINTSEVA, V.P.; FI-inimali uchantiye.- MEDYUXHA, a.A.;
OSOKINA,, L.A.; RACHKOVSWA, Yu.K.,- GSOVTSEVA, 0.1.;
DEDUSE14KO., A.I.; KOVALEVA, P.S.; KARASIMVICH, Vj.;
CHEBOTAREVICH, N.D.; CHIGIRIf T.R.; SKULISSAYA, S.D.;
KECHETZHIYEV, B.A.; DEVINA, A.S.; ZUSIMO, R.~T.; YESAKOV, P.L,;
SYSOYEVA, Z.A.-I Z3:N'OVIYEVA SO-P FALICHEVSKAYA, A.A.;
DENISOVA, B.D G.; STRKASOVA, A.V.-
LYANTSMAN., S.G.
Reactivity and immnologioal and apidomiolagLoal 01"Veotivene"i
of alcoholic typhoid and paratyphoid fover vaccines in stchool
children. Zhur. milrobiol., epid. i immn, 33 no#7:72-77
Jl 162. (14IRA 3-7: 1)
1. 1z Moskovskogo, Rostovskogo, Omskoga institutov epidemio-
logii i mikrobioloali, Stavropollskogo instituta vaktsin i
syvorotok i Ministerstva zdravookhraneniya RSFSR.:2. Rostovalkiy
institut epidemiologii i mikrobiologii (for Kovalava).
3. Stavropol'skiy institut vaktsin i syvorotak (for S~rsoyeva)-
4. Kuybyshevskiy institut epidemiologii i mikrobiologii (for
Zinov'yeva). 5. Saratovskaya gorodskaya sani-tarno-epidemiolo-
gicheskaya stantelya (for Lyantsman).

SINOTI-ENAl I.S.) SHPAGINAr H.K.
B(Lateriological characterlotics of acute gasUventerltislu
Kuybyehev. Zhur. mikrobioli, epido i i=mn* 31 no* 507-98
IV '600 (MIRA 1340)
1. Iz Kuybyshevskogo epidamiologii, mikrobialogiii gigiyazy.
(KM7SHEV-,WTROn7ERITIS)