SCIENTIFIC ABSTRACT KAMAY, G.KH. - KAMENOGRADSKIY, N.E.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002201210010-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: July 20, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR UDC 547.242+5ff6.19:546.221
KAMAY G. Kh. (Deceased), CHELNOKAL'SKIY, B. D., and UVENSHTEYN, 1. B.,
KazZ17"Ilstitute of Chemical Technology imeni S. M. Kit-ov
"Feasible Mechanism for.the Reaction of Tertiary Arsine Sulfides With
Alkyl Hatides"
Leningrad, Zhurnal Obshchey Xhimii, Sep 71, Vol 41, No~9, pp 2015-2020
Abstract: The purpose of this study was the synthesis of alkylarsonium salts
and other products of the reaction R3AsS+A:kI-IR3AsAIkjT. it is shown that
the formation of quaternary arsonium salts by the reaction of tertiarv arsine
sulfides with alkyl halides is common fo~- both triaryl- and trialkyl arsine
sulfides. The other reaction products, in addition to tertiary arsines and
arsonium salts, include dialkyl disulfides and trial,kylsulfonium halides.
The conversion of aikylthioarsoaium to tertiary arsinelis effected by the
halogen anion. The mechanism of the reaction i,,; discussed.

---7777777::
USSR UDC 547.26'118
V,IVMIN, V. S., KRUTSKIY, L. X., EMAZAROV, and,&.
The Reaction of Diethylamidoethylphosphonous Acid Chlorides and Ethyl-
(ILchlorophosphine, With the Orthof ormic Ester and Acetic Ald.ehyde Diethyl
kcetal"
Leningrad, Zhurnal Obshchey Khimii, Vol~XL, No 12, Dec: 70, pp 2560-2563
Abatract: For a comparison of the electrophilic properties. of the diethyl-
amidoethylphosphonous; acid chloride and.those of the halides of trivalent
phosphorus, the authors studied the above reaction.
It was found that ethyldich2orophosphine reacrs vigor(,usly with the or-tho-
formic aster, to form the ethyl ester of ethyldietho>qrmethylphosp~inic acid,
and with the diethyl acetal of acetaldehyde to form (depending on the ratio
of reagents) the ethyl ester or the acid chloride of i&thyl-l-ethoyyethyl-
phosphLnic acid. Alcohols react with the latter to produce the esters of
ethyl- I-etho)r4ethy lphos phinic acid, and also the aci& itself. It was also
found Chat the die thylamidoethylphosphAni c acid chlorl.de, as distinct frcm
eth-yldichlorophosphine, reacts with the' orthoformic ester, but is prac-
tically inactive with respect to the diacetal of acetaldehyde.

IjSSR UDC: I,:.47-34,.L.26,1i8.o7
FRIELAND, S. V.,, CHIRKUNOVA, S. K., =4AY) G Kavari' Institute of
Chemical Tle-chnology imeni S. M.
"A Viethod of Synthesizina/9 -(/!5 -Chloralkoxy)vinylphosolionic Acid a2rivatives"
Moscow, Otkrytiya, izolbreteniya, promyshle e obramtsy, tovarnyye znak-i,
=yj
No 15, Yhy 71, Authcr I s Certificate No 302344, Division C, filed 6 Jan 70, Pub-
lished 28 Apr 71, P 80
Translation: This Author's Certificate introduces: 1. A method of synt-hesiz-
ing/9-' "-cliloralkoxy)viviphosphonic acid derivatives of the general fonnula
0
R--Cl I-CI 1--ocit--clip
CI RI
where Z is chlorine, OR"; R and RI are hydrogen, alk-jl. An a distinguishing
feature of the patent, substituted 2-nethyl-1,3-d:Uiydxoyycyclc)pentane reacts
with phosphorus pentachloride in an organic solvent such as benzene, followed
and isolation of the
by sulfur dioYide treatireit of the resultant product
final- product or conversion to the corresponding ester by conventional LV-4thods.
A modification of this method distinguished by the fact that the phosphorus
1/2

USSR
FRIMAND, S. V., et al., Ctkrytiya, izobrateniya, promyshlennyye obraztsy.,
tomntrnyye znak-i, 110 15, Y;wr 71,
pentachloride and substituted 2-nethYl-1,3-dihydroxycyclorentantl,- are talken in
a ratio of 3:1, respectively- 3. A modification of this method distinguished
by the fact that the rocess is carried out~at 5-100C With subsequent tempera-
p
ture.increase to 300C.
'?/2

USSR UDC 547.341
FRIDLAND, S. V., CHIRKUNOVA, S. K., KATAYEVA, V. A., and Kh.,
(Deceased), Kazan' Chemiciil-Technological~Inatitute imeni S. M. Kirov
"Reaction of Phosphorus Pentachloride With 2-Methyl-1,3--dioxocyclopentanes-1"
Leningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 3, liar 71, pp 554-556
Abstract: Reaction of phosphorus pentachloride with 2-methyl-1,3-dioxocyclo-
pentanes takes place with a break in the cyclopentyl ring to give dichloro-
anhydrides of a-( S-r-hlorcialkoxo)vinylphoi;phonic acids. 200 g of phosphorus
pentachloride was added irt portions to 28 g ethyleneacet.al in, 150 ml absolute
benzene wIth vigorous atirring, keeping the reaction temperature at 5'. Then
the mixture was heated for- one hour at 300. The complex fortnA was decomposed
rafter 12 hours with oulfur dioxide to given, 40% of the dEchloroanhydride of
6-S $ -chlt)roethoxy)viiiylpil.osplionic acid, b.p. 141-142*/~ =I$ djO 1.4868,
n2 1.522. The dichlorides obtained react with secondary amines, alkaline
;scohols, and alkoxides to yield corresponding amides mad esters.
1/1

saw=-
USSR UDC 542.945+542.957.2+547.852.7
:GAVRILOV, V. I., CHERNOKAL5-KIY, B. D., and K.OU&Y (deceased), Kazen'
C
chemical-Technological Institute imeni S. .14. Yarov
"Arsenic.-Carbon Bond.Break in Derivatives of 5,10-Dihydroiphenarsazine During
ReactionH With Hydroiodic. Acid"
Leningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 3, Mar 71, pp 560-564
Abstract: Reaction of 10-alkyl-5,10-dihydrophenarsaziLie oxides with hydroiodic
acid leads to a bond break between arsenic and carbon otoni yielding 10-ioda-5.
10-dihyd-cophenarsazine. Hydroiodic acid also breaks dcnm 10-isopropyl-5,10-
-dihydrophenarsazine oxide-yielding diphenylamine. On heating in benzene the
diiodidesi of 10-alkyl(or aryl)-5,10-dihydi~ophenarsaziues sire converted to
10-iodo-3,10-dihydrophenarsazins. Reaction of ethy1dibrotioarsine with 10-
ethyl-5,~10-dihydrop-henaraaziue yields 10-bromo-5,10-di~ydrop~-~:narsazine.

USSR UDC 547.852.'7+542.945+-942.957.2
GAVRILOV,, V. I., BATINA, L. CHERNOXAL'SKIY, B-. 1D., :and
(deceased), Kazan' Chemical-Technalogical~.Institutet.i.mbni S..M. Kirov
Reaction of Tertiary Arsine Oxide of the*DihydrophenarsaLine Series With
Acids"
Leningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 3, Mar 71, pp 564-567
Abstract: It was determined that the hydrochloric, hydrobromic and trich-
loroacettc acids as well as pentachlorop4enol Iorm addticts with 10-alkyl-
(aryl)-5,10-dihydrophenat-oazine oxides (4).in.aqueous MIcohol medium or in
benzene. To a heated ethanol solution of (1) the aborve reagents were added
in 10 ml water; the solution was heated for 15 min, the: volume was concen-
trated to 1/2-1/5 and cooled. A colorless crystalline product was obtained
the adduct mentioned above --, it was~filtered, dried and recrystallized
from ethanol. It was also shown that (I):c(ould be titrated with KC1 in a
mixture of acetic acidacatic anhydride..
40

USSR UDC 547.242+546.19:546.221
'SKIY, B. D., LEVENSHTEYN, I. B., and.EMY
CHERNOKAL .1
(deceased)
Kazan' Chemical-Technological Institute imeni S. bf. Kirov
"Synthesis of Alkylthioarsonium Salts"
Leningrad, Zhurnal Obshchtey Khimii, Vol 41 (103), No 3, Mar 71, pp 557-559
Abstract: Reactions of trie-,hyl- and tripropylarsine sulfides with alkyl
halides.were studied at room temperature either in benzene or in an excess
of the alkylating reagent. Reactions lasted,from 5.5 krs to,several days,
yielding trialkylalkylthioarsonium salts - hydroscopic crystalline com-
pounds soluble in acetone and methylene chloride but imsoluble in ether
and benzene. Above sulfides as well as the triphonylarsine sulfide react
vith trisakyloxoniumtetrafluorobotates forming alkyl-thimirsouium salts.

UZC .542.0
Ga Y- -1 KA-;-A, G . KI., (dece .ased a nd I

'tu~-,! of
1 ris. t c- arA rnysical Chenistry jmien~ ,.I-bu v
Or n
~-c:enoes USSR
A,2 ad e my
"Rea-ation o f the Alkyl V',sters of Pentavalent acids `;Ii.11
liiorc apt an E
Illosco"", iz Akademii Nalik, Se O.Y a, ~%_o jul 70,

1) 16.40
P

Atstrac in contrast "o the I,eacti6n of rivalent ai
-senic acid

e.9tel'S VVIZI var:Lous s~ + e s o~ pi--ntavalent
mercaptans, Mn e n 'he alkyl e
ac.-J. were reacted vii-h me~rca tans voro proc"e.-Isr-s too"', Pleace:
-As (V) was 1-edUr-ed to As (III) and the: allkoxy Ojvoup ,L,,-~_s; replaced by
the thio &;-aup, fon-rir,,,x respective Chibacid asteri~ the ~.rivalent
1

rse Hn 7~)
4
k; - due to the
some cases no pure product could be, ob alned.

f 4.
'hat on distillation azeotropic. mixtures: we
xv being fo=,.ed. The

reiaction was
usual.ly exothermic and consisted of: M -he reagents,
ixing

removing t6h. e 10
solvents and redistilling;the pi duc.i
;.

J -7
U3SR UD' 54 .118
ILU-111! T. 'Lt., and
FRIDUND, S. V.Y I (deceatled), 1~3i.=t ert
of Ttchnolos~';- of Basic Orrvanic and Petrochemical Svnt~~-,sis Kazan' institute
of Chemacal L=ni S. M. Kirov
"Study of the Reaction Phosphorus Tricholor-fte an,-' o~Allyl-p-Cresol"
Ivanovo, Izvestiya Vysshikh Uchebnykh Zavedeniy, niji~'4ya i laiimicheskaya
TehhnoloCiy-n, vol. 13, no. 12, '110, i)P 17760-1761
Abstract: The reaction of o-allyl-p-cxesq idth phosphorus trichlor-'ric ass
I
,;,Ji,ion (),
tile rp y1f,
'ti.or
bc!cn atiulted.
form, tWo fractiono -- cl-;".ucid C!31ori.de 0 f O-allyl- p - C 1 .11 t;Y).-i'-' 0~,
-~-10:1COUU; P- I j.
T:,
and the acid chloride o.'L' di(o-allyl-p-cr.eoyl) phosphorous --cid (H). L-c
reaction was conduct-ed in equivolar ratios and the faviT~-.tian of proo."Act, H 7~zy
be ex-oiainecl as fhe reaction of nucle-ophilic substitution o:~ t1-.--- cocond
Tie obtained aci.,-,,'
chlorine atom as well as by concurrent disproportion~,.tton. U
c4lo-mide.5 ---_e collorless trarsmarent sliZdAl~y f=-in.: (~fb air)
-aii cl 1' -i~i cKo--J, ---- - -r-
an odor , cmlia~, to h1oridec. Me at~
alcohol in die"Ilvl ether in the prer-k-me: of triet-hyl-anime for cC:-i,1ir,-. -k;he
liberated hydro.--cn chloride. This reaction, as well mi; all other operations
1/2

a
L75SR
FRIDIXIMY S. V., 4&,g~-
V~rssh-*kh.Uchebn,,[kJi,ZaN-eOr--i,.iy, nimiyla i
Khimicheskaya Teldmologiya, vol- 13, no* :12, 70, PP It60-1761
C, +
oil-
TICt 1-11ci
J
'Cl t>1000
C I I
for separatlrC: es'p-rb, were coalucted in an iaert I:as rilv- sepamlv-d
esters, including their properties,, are liotild In a tablic! in the orildrial
article.
2/2

USSR UDC: 632-95
-Y, L and e
TSIVUNIN, V. S., KRUTSfa N.1 frazan' Chemical-T chnolo-
gical Institute im. S. M. Kirov
"A Method for Preparing Alkylalko-xyalkylphosphinic Acid Esters"
USSR Author's Certificate No 258307, filed 16 Dec 68, published 28 Apr 70
(from RMi-I[himiya, No 22, 25 Nov 70, Abstract No 22 N639 P by T. Ya. Ogibina)
Translation: A method -Ls suggested for preparing physiological].y active ethyl-
ethOXYMethylphosphinic acid esters (I). A mixture of 0.12 mole of diethylamide
chloride of ethylphosghonous acid and 0.12 mole of chloromeLhylmethyl ether
is heatc-d to 50 to 60 for- 7 hours and then decomposed with a weak current of
SO . 1C0 ml of ether is Oded, HC1 (gas) pasned throtif-1h, soid after about 16
holus 11.6 g of the acid. chloride of I (II) removed) 01,51111,C102P, boiling point
20 20
91-930, n D 1.1h642, d 1.1513. 0.1 mole of MeOH istadded to a solution of
h 0
0.053 mole of II in 40 ml of C-H at 20 The mixtul,e is kept at about 26'
4 ~ ester,*9 boiling point 9
for 20 min, producing 4.65 g o~ 6-70/3,
2 20 A503P
OD 14385, d 1.0521;. 1 ethyl ester., C Ff 0 P i ]wepa~ed in a similar
n 4 7 17
fashion, boiling point 92-3 /2, n2% 1-4364P d 1.02.'12.
4

USSR uoc. 547.242
CHMN10KALISM, B. D., GELIFOND, A. S., and KAMAY, GILPAE, Kazan' institute of
Chemical Technology imeni S. A. Kirov
"Kinetics of the Reaction of Aryldialkylarsine Oxides ut-ith Betyl Iodide"
lAmingrad, Zhurnal Obshchey Khimi-i, Vol 40, No 1, Jan 70, pp 151-156
Abstract: Heating (p-substituted Dhenyl) diethylarsino oxides, where a nitro-
group, bromine, or iodine are the substituents, with methyl, ethyl, or iso-
propyl iodicLes in acetone vielded a precipitate, after-24-30 hours, aryldiethyl
(aryldiethylhydroxjarsoxy) arsonium iodides (1), which crystallized in Z5-69~
yields. A similar reaction of (p-dimethylaminophonyl,',iiiethviArsine oydde (II)
with isopropyl iodide gave a different producL, (p-di,,-~f--thllaqijiopienyl)
diethylhydr~xyarsonium iodide in 64~ yield. Reactions of phenyldiethylarsine
oxide or its p-tolyl analog with alkyl iodides gave nowrystallizing syrups.
Kinetic measurements, carried out at .10ol indicated seco'nd- and third-order
kinetics.
22

Mq1
USSR UDC.-541.127 +547.242 + 547.224
CHEPMXAL1SKiY, B. D., BAYRAMOV, R. B., Ar Id KAHAY, GIL':M, Kazan' Institute of
Chemical Technology imeni S. m. Kirov
"Mechanism of the Reaction of Triphenylarsine Oxide with Butyl Iodide"
Leningrad, Zhurnal Obshchey Khimii, Vol 40, Ao 1, Jan 70, pp 143-148
Abstract; A study was made of the mechanism of triphen:yl- (triphenylhydroxyar-
sojW) arsonium iodide (I) formation from.triphenylarsine oxide and butyl
iodide. The experimental electroconductivity data of the equimolar mixtures
of,reactants in acetone solution made it~possible to co)
-1clude that the reac-
tion proceeds in two steps. In the first (a) step triplienylbutoxyarsonium
iodide (11) is reversibly formed. Subsequentl 11 irreirersibiy reacts (b
I Y .4.
step) with an additional mole of triphenglarsonium oxide to form 1. The fact
that concentration of I in acetone at 50, remained constant during the six
hours oll' pazsing 1-butene through the. solut on was seem as confirmation of
i
irreversibility of step b of the reaction,

USSR UDC 542.91+ 547.2-97 + 547-558.2
USACdEVA. G. 14.. and KkAAY, G. IM.. (Decreased), Institute oZ' Organic and
Physical Chemistry -tfjv tAcad. Sc. USSF.
"Reaction of Acetyl Bromide With Triphonylarsino.0xide
Moscow, Izvestiya Akademii Nauk SSSR, Seiiya Khimichesxaya, No Jan ?1,
pp 168-169
Abst::-act: Tize reaction of acetyl bromideL With triphenylarsi-ne oxide, taken
in a 2:1 ratio, in toluene yields triphanylarsine broa~.de and acetic annydride
as wall as unreacted starting matorials Triphenylarsfune broraide is hydro-
lyzed easily to triphellylhydro;(yarsine oromide. 'In tho infrared triphenyiar-
sin bromide exhJbits absorption bands at.1003, 10Z7, 4.076, 145d, and 1560

U&M UDC 547-26'119
GIGAIJ-H, R. D., KAIKAY, G. Kh. (deceased), and UGULAVA, t'i. A., Kazan, Chemical
Teahnological. IATM"IM ... S. 11. Kirov and Tbilisi S~~ate University
"Synthesis of Tri-sec-Al~-jl Arsenites and Their Reactims With Acetic Anhy-
dridell
Leningrad, Zhurnal Obshchey Khimil, Vol 41 (103). No 2, Feb 71, pp 336-337
Abstract: Tri-sec-alki me
rl arsenites are for d in good yields in the reaction
of arsenic triodde with correspondinc alcohols, the water for.,--ed being re-
moved azeotropically. A mixture of 25.4 g 1 of. arsenic 't. io;dde, 10~) g 4-octanol
and,30 ml of octane was heated for 6-7 hrs in a flask equippel with a Dean-
Stark trap yielding tri 4-octy! arsenite (1).a-fter 6.2 g of water had been col-
lected in the trap. Reaction of (I) with acetic anhydride gave dialko;garsinyl
:acetate.

-USSR
UDG 547-341
FRIDLAND, S. V., TSIVUNIN, V. S., PRIDLAND, D. V., KAMAY, G. KH.
(DECEASED), Kazant Chemical-Teahnolo'gical Ins tit ut 9-U-eJW--S-."-Pr.
1Urov, Kazan, Ministry of Higher and -Se.condar7: Specialized Educa-
tion RSFSR
eactions of cc-Haloesters With Phosphorus Pentachloride"
Leningrad, Zhurnal Obshohe;Z Khimil,,L, Vol 40, No 9, Sep 70,
P-p 1993-199,5
Abstract; Reaction of~)(-chloroethylbutyl other with PC15 is
;xothe ic, leading to a white complex which upon treatment with
SOj gives butoxyvinylphosphoriio acid dichloride, When reacts
PC-15
wi h- oC-chloromethylalkylethers, no phospho3-ylatod products are
obtained: only chlorinated ethers. Rettotion of o(-cj,,1oroethY1viny1
etle-r W'tt' PG'5 y1olds 2-o1x1oro-2-(1-eh1oroihtho-x1 )-othylphosphonio
acid dichloride (1), which can be obtained,, however, only when
&ILstillation of tRe product Is carried out at 6 wri pressure or
below; at higber temperatures hydrogen chloride is split off. One
Molecule of HG1 is also split off upon treatment;w1th one mole of
1)2

USSR UDC;547.Z4Z 546-19;546.ZZI
CHERNOYCALISKIY, B. D., LEVENSHTEM, 1. B. G. Kh., Kazan' Institute
of Chemical Technology imeni S. M. Kiroir
"Products of the Reaction of Triphenylarsine Sulfide with Alkyl Halides"
Leningrad. Zhurnal Obshchey Khimii, VoIV, No 1, Jan 70, pp 148-151
Abstract: The mechanism of the title reactions was studied, because stability
ol the arsenic-aryl bond in pyrolytic processes is higher than that of the
arsenic-alkyl bond. The main product of the reactions of triphonylarsine sul-
fide with methyl, ethyl, or propyl iodides was alkyltr4phenylarsoniiii tri-
JA)dide (I). Alkyltriphenylarsonium iodide crystals were also separated, along
With 1, but in lowor yJ 'e.
Ids from the reaction products with methyl nd otnyl
iodides. bi one instance, 5;~ triphenylarsine was sepaiated in the reaction
With ethyl iodide. All alkyltriphenylarsonit)-m icdides were obtained in
crystal form. Triiodide I heated with mprc *ury in acetone gave after several
haurs crystals of alk~jitriphenylarsoniiza:triiodomercura'te (11) in 42-78~
yields. Also, methyltrilihenylarsonium tetraiodomercurate crystals were
separated (yield 22.%) from the reaction';product, probably because of dis-
proportionation of II during crystallization. mLelting point's of the above
compounds were determined.
IA

USSR UDC 542.914- 5k7,297* 547.558.2
USA.CHEVA, G. M,f KAMAY Institute of Org
anic and Physical
imen Ye. Arbuzov, Academy of;Soiences USSR
Chamistry
eaction of r a Oxide"
1IR Acyl Chloride With Triphonyla sin
Moscow, lzvestiya Akademii Nauk SSSR, Serin Hktimicheskaya, No 6,
Jun 70, i3p 1432-1433
Abstract., The reaction of acyl chloride with triphonylarsine oxide
Ta-Lk-en-Tn- a2:1 ratio In anhydrous toluene yields triphenylarsine
dichlaride (I) and a mixture of acetic. anh chide, toluene, and the
starting acyl chloride, The structure of was asaigned on the
'basis of IR spectroscopic data and mixed maltinT point determination
vit:la independently synLhesized (1), 'Also# (1) waa hydrolyzed to
triphenylarsinehydroxychlor do (Il).whoso IR spoetrum and melting
potat is identioal with indepondent~,F~syntheaizod (11).

t
USSR UDC: 547.241
NURTDRIOV, S. Kh., TSIVOIN, V. S., K.MAYRULL114, R. 3.,.1KAS._-1TA1'!OVA, V. G.,
and WRY, G. Ki., liazan' Institute, of Chemical TechnologY"`
"Reaction of Ethyl- amd Phenyldichlorophosphine with Acetone"
A.
Le ninara(i, Zhurnal Obshchey Khimii, Vol 40, No 1, Jan 'jO, pp 36-40
Abstract: Liquid. hletterocycac co,-,~aouncls, 2-keto-2-ethyl-(or Ph-,nY1-)-3,__j,5-.
~trimethy -1-oxa 2,4-phospholenes ZI), were obtained in 67-70,', y.-*Lelds by
heating for 10-ZO hours in a sealed, tube mi:xturos; of etriyl- or phc-nyidichloro-
phosphine with acetone at ?5-.800 or 1000, ro~pectivcly,' Fhyc5ical coxi5tanLs of
I are giren. The structLro or 1 was deter mned from 1R and i.41R sDectra. Heat-
ing, I with meThanol at 70-1500 in a sealed Woe gave et,iyl- or phenyl 1,
1-dimethy.*~'-3-keTobutylnho:3DnLiites (II) in 49-73,'o' yields. All !I co.-pounds
but one .
mre 1:,quids. Sinilarly heating I at 1100 ,rith water slighUy acidi-
fied vrith hydrochloric acid gave 52-51~* yields of ethyl- or phenyl-1,1-
-dimethyl.-3-ketobuty:,.r,.Iio--Dhi-nic acids, crystalline solids with meltin.v, point
132-130 azad 1210, mepectively. The structures of the phenylketobutylpiaos-
ijbinic ac,~Ld,_ T ~md UT were detemume-i from IP. spectra.
C

USSR UDC 547.242+546.19:546.221
CHERNOKAM.SKIY. B. D., LEVENSIFTEYN, 1. B. , an 11 ----7- 0
CH OH, and the second isomerp cis-confornation with a p "e N 0 axial C
2 H201[
1/2

.......... ....
burrl OZUCFI--E:
USSR UDC 617-001.17-00-~-939.6
h F,, Prof., and ORLIKt V. A., Docent, Chair of Faculty Surgery,
KAJ,1AW
.8liatrics and Stomatology, L'Yowliedical Institute L'vov
."Disturbances of Protein Itietabolism in Patients With Burns"
Moscow, Klinicheskaya Eeditsina, Vol 49, Re 4, Apr 71, pp 83-88
Abstracti A study carried out on 45 patients with deep burns covering more
than 1N or the Doay surface indicated that the protein netabolism of the
patients vms disturbed to a conside3~~blo,6xtdnt.. This itas riani ested by a
the total content of protein in the blood, developizent of dyspro-
decrease in
tainemia, and a raised elimination of total E*g, amine and tyrosine with
the urine. The Increased elimination of msino IN and tyrosinb. indicated Uat
2
in addition to an increase in the decomposition of protein in the orgafti=
and decrease Jm its synthesis marked disturbances In the enzym~ltic oxidation
of amino acidE. had taZien placa. The. results showed that the wiount of
tyrosine e1W.rated could be used as one of the indicou af d.oviations fron
normal of -.~--teabolic anci enzymatic processev in the. orCaxiisn and, also as a
moasure of the extent to which the therapeutic methods a~pplied had been
effective. Adxdnistration of synthetic hormones with anabolic action (USSR
1/2

- :- -- 37_--_ --

U2 :020 UNC LASS I ~pmbCES~ING DATEI-04DEC70
JITLE EFFECT OF THE SALT CONTENT IN WATVER~ON EVAPORATION IN SOLAR STILLS
--u
K.B.i ACHILOV, a.,Meii KAMAEVAt G.:
"COUN74Y OF INFO---USSR
URCIE--GELIOTEKHNIKA 1970, (2), 83-5
c-0 AT EPUBL ISHED ------- 70
'..SUBJECT AREAS--MECH., IND.t CIVIL AND MARINE ENGR
00 1 CTAGS--SOLAR DISTILLATtONv DISTILLATION EQUIPMENT9 METAL CORROSIO."ll
SEA WATER DESALTING, EVAPGRATIONg EVAPORATORt WATER PURIFICATIONP
SALINITY
TROL MARKING--NO RESTRICTIONS
.00CUME.4T CLASS-UNCLASSIFIED,
~,PRQXY 'iREELIFRAME--3007/0460 STEP NO--Uk/0377170,/0001002/0083/0035
CIRC ACCESSION NO--AP0135923
UNCLASS I F LEO

1/2 Oil UNCLASSIFIED PROCESS !NG OArF--20NOV70
TITLE-USE LF THE METHGD OF CROSS SECTIGNS TO STUDY THE rwo PHA5E- LIQUID
-S*FATE I N' COViENSED FOUR COAPOWENT SYSTEMS -U-
-;Z-(03)-;,,ER' 'AMA VSKAYA, J,.A., NIXURASHIPtAt Nolo
AUTHIG rSLIN, R.V., P. E
_CCUNTRY 0 F1NFC---USSR
SCUACE-Zh. FIZ. KHM. 1970t. 44(1)o 719-82
BA T 1: PUBL ISHE C----70
SUB-JECT AR-cAS--CHEMISTRY
~TGPIC TAGS-PHASE EQUILIBRIUMIr FLUID STATIE
CONTROL MAki',ING
--NO RESTRicr[CNS
DOCUMENT CLASS-UNCLASSIFIED
~PROXY kEEL/FRAt'E--30C5/U,)07 STC-P N(]--Uk,; 0076/70/(04/001/0079/0082
CIRC ACCESSICP4 ND--AP0132307
'14-A A' SJ
1A 1-1 -

212 Oil :jNC LASS I r- I ED KIOCESSING DATE-20NOV70
P
CIRC. ACCESSICN N-J--APC1323,'.17 :
'ABSTRACT/EXTRACT--(U)
GP-0- AUSTRACT. A R
G E NE R A LGRAPHICAL METHOD R THE
HIM*-, OF THE COMM. OF EQUIL. PHASES IS L.ESC-RIBEI). FACILITY:
:SARATCV. GOS. UNIV. IM. CbEANYSHEVSKOGOv SARATGVs~ USSR.

UDC 612.821
USSR
BEKHTEREVA, N. P., AROVA D. K., and.MATVLrYFV, Yu. K., Division of Applied
Neurophysiology, InStWRTMee-VII0 ntal Medicine, Academy of Medical
Sciences USSR, Leningrad
"Functional Characteristics of Links in:Cerebral Systems for Control of Mental
and Motor Functions in Man"
Leningrad, Fiziologicheskiy Zhurnal SSSR imeni I. M. Sochenov, Vol 56, No 8,
Aug 70, pp 1,081-1,097
Abstract: The impulse activity patterns in neuranal structures of the brain
were studied during motor and psychological tests administered under ordinary
conditions and after administration of neuretropic druis. Areas of character-
istic reproducible impulse patterns were discovered in various brain structures
of patients vith Parkinson's diBeaso. Gold clactrodes wercused for chi! mea-
sure=nts, and the impuLae activity was calculated by cowmitional means and
by computer. To study the distribution of active neurons, the "specific
activity" (i.e., the number of impulses per unit volumm. and unit time) was
used. Comparison of impulse activity prior to and during the test and of
the effects when the test waa repeated maile it possible to clearly define the
activity and to refine the links of the,faystems of cehLral c6ntrol for various
1/2
7:

------------ -- ---
USSR
BEKHTEREVA, N. P., et al, Fiziologicheskiy Zhurnal SSSR imeni 1. It. Sechenov,
Vol 56, No 8, Aug 70, pp 1,081-1.097
forms of activity. It was shown that during psychological tests the discharge
CX
frequency increased not only when the number of active neurons increaged but
also when it decreased. It is proposed that the phenomenon of lateral inhibi-
tion is of importance in the activity of n*uron groupsi When neurotropic
drugs (deseril, L-DOPA) had been administered, the background frequency
shifted as did the pattern of impulse aepivity during fMYCILOIogical and motor
tests, A fo4 links of the brain~systems;for ment.al anti motor control could
be more clearly defined by the 1'inclusioii"~or. 1'exclusion" brought about by
the neurotropic drugs.
2/2

USSR VDC 616-98.1-718-078.7
KAHBARAW11 KUDELINA, R. I.1 and ARTISHCHEVAI L, I., Orenburg Medical
~tiGie, Orenburg.; Institute of Epidemiology and Microbiology imeni Camaleya,
Academy of Medical Sciences USSRt Moscowl~and OrenburgOblast' Sanitary
Epidemiological Station
"Use of a Soluble Rickettsia burneti, Antigen as Allergen. for the Diagnosis
of Fresh Cases of q-Fever in Han"
Hoscog, Zhurnal Mikcrobiollgli# Epidemiol~gii I ImWunoblologii, No 4. Apr 71,
PP17-18
Abstracti It was reported in a preceding paper that soluble antigen prepared
according to Boivin from Rickettsia burneti, phaze 1, -= be used for the
retrospective diagnosis of Q--fever in human beings. In the present study
this antigen in an anount of 0.1 ml was used in tests on 32 Q-fever vatients
on the 5th to 24th day of the diseaze. Beginning with the 5th day of the
disease, an allergic reaction was observed upon intracwtameous application of
the aatigen, that genexally reached a maximum 24 hrs after application arA
subsided within 48 hrs. The antigen did not cause allergic zeactions in,
control patients with other cL-Lseases# not- did It cause Tormation of complement-
fixing antibodies. The antigen can be recommended for the diagnosis of recent
cases of Q-fever.

W 017 vNCL ASS IF It 0i' PROCESSING DATE--30OCT70
TITLE-INDIVIDUAL HYDROCARBON COMPOSITIONS OF THE BENIENElTOLUENEvXYLENE
FRACTION OF LIGHT PYROLYSIS TAR -rU-
"AUTHOR-031-BOGDANOVAr T.A.v KHALILOVA, SH.A., KA14BAROV, YUoG.
CCUNTRY OF INFO---USSR "e
~SbURCE-NEFTEPERERAB. NEFTEKHIM. (MOSCOW) 1970v (Zip 28_1~
;.-~~'_OATE PUBLISHED-------70
~-,~_~SUBJECT AREAS-CHEMISTRY
,JOPIC TAGS--HYDR0CAR6ONv BENZENE, TOLUENEt XYLENE# KEROSENE, GAS OILS
PETROLEUM FRACTION, STYRENE*- PYROLYSIS
GNTROL'
MARKING---NO RESTRICTIONS
~.,_.~,_WXUMENT CLA S S-LINCLA SS I F: EE0
REEL/FikAME--1997/0790 STEP NO--U.9/0,318/~70/000/002/0028/0029
C 19 CACCESSIUN NO--AP0119697
UNC LA SS I F If: 0

1.1ming.10.1.111
2/2 '017 dNCLAssiFIED PkOGESISING DATE--30OCT70
CIRC ACCESSION ND--AP0119697
GP-0- ABSTRACT. A MIXT. OF CRACKING KEROSINE AND
STRAIGHT RUN GAS OIL WAS SUBJECTED TO PYROLYSIS AT 740DEGREES AND 3 SEC
CONTACT TIME WITH 11PERCENT STEAM, GIVING ZOPERCENT LIGHT TAR. THE
LATTER YIELDED 38.08PERCENT FRACTION,8. SMALLER THAN OR EQUAL TO
-145DEGREES AND CONTG. C SU86 H SUB6 374-1:29~PHME 32.05p XYLENES 11.1,26,
PHET,.3.39i STYRENE 1.31, AND 1407 WT. PERCENT NONAROMATIC HYDROCARBONS*
LN. THE FRACTIONr,68 COMPONENTS- WERE OETO., 48 OF:~WHJCH WERE IDENTIFIED.
UNCL4SSIFIED
..........

mi im -1 l m
-:-~,-2n 026 UNCLASSIFIED PROCESS114G DATE--040EC7C
1 C ACCESSION NO--AT0132926
~WBSTRACT/EXTRACT-_(U) GP-0- ABSTRACT. THE INTENSIFICATION
OF N CASE
:-'--.HARDENING (TO 1-5 MIN) WAS ACHIEVED BY HEATING SPEI,".IMENS OF STEEL 20 BY
~MEANS OF A HIGH FREQUENCY CURRENT. A MIXT. OF NH ~U83, AND PROPANE
'CY HE W
WAS USED. THE INSTALLATION OF A HIGH FREQUE~ ATER ALLO ED
QUENCHING OF SPECfMENS IN WATER. THE N11ROCEMENTATION WAS
OUT AT 900-1200DEGREES WITH HEATING RATES 50DEG'REES-SECi HOLDING
~SPECAMENS AT LTHE INDICATED TEMPS. FOP.,Ot-30# 150, AND 300 SEC. AFTER
NITROCEMENTATIONt SOME OF THE SPECIMENS WERE QUENCHED IN WATER FROM
WOVEGREES AND THE OTHERS WERE COOLED SLOWLY 114 A GAS SIREAM. THE
_HIGHERST MICROHARDNESS AND DEPTH OF NIT'R.lDrD LAYER'WAS PROOUCED WHEN THI--
_.~:.:~GAS;ATXT. CONTAINED NH SUB3 30PERCENT AND PROPANE:BUTANE 70PERCENT.
;--WHEAI HOLDING SPECIMENS AT 1100-50DEGREES*.FUR 150-300 SEC THE DEPTH OF
MIT FlOCEMENTE0 ALYER WAS 0435-0.55 1414, WHILE THE SAME DEPTH Wl:TH
SLOW HEATING COULD,~SE~PRODUCEO ANLY AFIER 3-5 HR. EVEN
_T -ANY- THE - DEPTH:- OF! NfTROC E MENT 5
_Wl THOW HOLDING PERIOD r_-0 L AYER WA
HM. OPTIMAL NITROCEMENTATIONJEMP. WAS 1100DEGREES. WITH
TIME 4-5 MIN WHEREBY A GOOD QUALITY:LAYER WAS PRODUCED 0.3-0.5
A14 OEEP WIT14 MICROMARDNESS 900-1000 OAN-rM IH PRIMEZ. FACILtTYz
INST STALI SPLAVOVt MOSCOW ~r L SSR
UNCLASSIFIED

USSR UDO 6130*645
and KAUDIA, G. A., Medical Institute im. S. V. Kurashov.
Zan
"Physiological and,Hygienic Evaluation of Working Conditlons*of Persons Who Work
in.Low-Intensity Light"
Moscow, Gig*,ena Truda i Professionallnyye Zabolevaniya., No 9. Sep 70, pp 16-19
Abstract. Physiological tests were administered to 412 female;5 working in a
film processing plant under red# green* or yellow light of low intensity.25 w
bulbs. Complex shifts were found in the central and autonorrLic nervous system
which included marked incroases In optical rheobase ayyJ chrcna)cy and lengthening
of the latent period of visual and motor reactions.during the course of the day.
The EEG was aharacterized by an irregular alpha rhythm, frequontly followed by
r cti ity of
more rapid low-amplitude oscillations, an indication of decreased ea v
the cortical processes. The condition of the autonomic nervous; system was judged
from shifts Jji skin temporatw-o and arterial pressuret 1~3th u.V which wore much
lower at the tind of a work sb:Ut than at the beginning.: The pbysiological data
were supported by the results of-a neurological examination which showed a large
number of functional shifts. In general. the adverse effocts were most pro-
nounced in those who worked in soft rod lijht. Yellow 1A ht Vas less irri ting
.9 ta
than greene

USSIR UDC:.534-232-46.8
/Zn-t avtomatiki--Ins
NOSOV., V. A. titute of
"Method of Excitation of Piezoelectric Radiator"
USSR Author's Certificate No 26-829, filed 28 Moroh 1968,
44 -
publish =Uly 1970--(T-rom RZhm-Elektronika i en primenenive.
No 2,.Pebruary 1971, Abstract No 2AL~&IP)
Translation: A new method is proposed for expitatiOn of a
Viezoel Fie radiator which makes.~it possiblo to Increase the
slope of the leading edge of.an ultrasonic signal. This amounts
to the fact that after the original exoitatioi~ by a positive
drop of the electrical voltage within an interval of' time, equal
to an odd number of hal-f-cycles of the resonance ascillations of
the radiator, the radiator once moro quickly gives rise to a
damped high-frequency electrical pulse with a negative first half-
cycle, the anplitude of which exceeds the voltage drop and the
duration is equal to a half-cycle of the resontance.oacillations
of the radiator. The principal circuit is presentedof the ex-
citation oscillator as wall as an oscillogram of the form of the
1/1 signal at the piozoolement. 2 illustrsti~)ns. N.B.
----- --------

USSR urc 613.645
KAMHATINOV, V. P., and ABDYLJSIMV, SH. YA., 14adical Institute imeni S.
-an
"Health and HygiLe Characteristics of Working Conditions :nnd Some Biochemical
Indices of Individuals Working in Darkness and Under Nonactinic Illumination~'
Mloscow, Giggiyena Truda i Professionallnyye Zabolevaniya, No 22, 1972, pp VI-48
Abstract: Metabolic changes in response to darkness and weak red lig-ht were
studied among workers of a film processing shop folloving a nozermal work-day
pattern and Otinea pigs subjected to darlmess.all day (group 1), dart-nec;E; for
6 hours during the dhy (grorip 2), and red light for 6 hourr, (group 3)-
Prolonged work in darlmesG caused-an increase in. chollneStenLse activity
(4.16 microxioles/mi/min vs. 2.77 in control) and blood bromine concentration
(1-90 m4l V41- 0-56 in control). Group 2' animala demxir~tratod, chan,;-,es In radox
processes arid neurcimuscular cxcitability,~. fluctlamtions in blood bromine level
=I, cholinesterase activity, and an increase in hemoglobin and erythrocyte
levels. For, individuals workin6 under red illumination, the coefficient of
urine underoxidation, ch-ilinesterase activity, and bromine level increased
(respectively the levels were 6.49 Ys. !.63 in control, 4.21 micromoles/ml/
min, and 1.14 nep). A histochemical study of retinas from Group 1 and 2
112

USSR UDC: 621.359.4
KAMCHUGOV.
SVERDLOV, A. S.
"Highly Effective Air Filters"
aniz. proiz-va (Elec-
Elektron. tekhnika. llfauah.-te-ldui. sb. Tekhnol. orr
tronic Technology. Scientific and Technical Collection. Technology and Or-
ganization of Production), ig7o, vyp. 6(j8), PP 93-97 (frcm.RZh-Radiotekh-
nika, No 6, Jun 71, Abstract No 6v432)
Translation- Highly effective air filters are developed for cleaning the
incoming air in enterprises of the radio electronic industvy. The disad-
vantages of the existing typical cleaning system atid the reasons for its
unsatisfactory operation are considered. :Data are giv(i.In on filters, their
design, filtering materials and economic effectiveness. A re-port is given
on
the results of experimental use. Resut6.
66

'one
USSR UDC: R
-0 'LOS 'LEN 0,
VOROITTSGV, V. A., GRUDNISTTY, V. V. F_X41.Z, 4 IE TIC
V. V. , RBZh a' 0, Yu. T. , and YA-SKEVICH, 2. P.
"Device for Determining the Coordinates of an Aero6iynamic Shadow
Contour on Eodies of Complex Form in Yree 1.1olecular Pluxis
Moscow, Otkryt!ya,.i--obreteniya, 11romyshiennyve obraztsy, tovarnyye
znaki, No 27, 1971, P 141, 1101(11)351113
Abstract: A parallel light beam is used to model the flw,, such that
the model can be fixed in any position. For ease of adjustment,
there is a -manual indicator showing a thread tiod to a movable
carriage. The scale of this indicator is tLsed to raeasure 11-he co-
ordinates of Doints difficult of access. A diagram of the device
is shown.
7.-A
183
--- --- -------

USSR UDC: 8.74
"Placement of Set of Job Programs for Interrelated Jobs in Machine Memory"
Prom. Kibernetika [Industrial Cybernetics--Collection of Worirks], Kiev, 1971,
126-130-(Translated from Referativny-i Zhurnal Kibernetika, No 11, 1972,
Abstract No 11V571, by V. Ostrovskiy)
Translation: This work presents an algorithm for solution of the following
problem: suppose a certain set of tasks A-{A I and P=(P I is the set of programs
for performance of these tasks (i=l* 2 ...,:n). Program P has length 1. and can
be run in time t i by a computer with memory, volume V. For interrelated tasks A
and A., we fix zil, the number of memory locations set a-side for the output data
of the ith algorithm which are used as input data by the jth algorithm. With the
condition El.>V, the problem is to divide P. into the minimum number of subsets to
p 1. . 11
be simultaneously placed in main memory. This subdivision agrees with satisfac-
tory accuracy to minimization of the time'required to perform the entire set of
:tasks.

1/2 025 UlYCL ASS IF I ED., PROCESSING DATE--160CT70
..-TITLE--A THERMOBAROCAMERA FOR OPTICAL INVESTIGATIONS -U--
'.-,UTHOR-(02?-KAMELIN, G.P., TUMANOV, V.A.:
,'~COUNTRY OF INFfJ---USSR
SOURCE--LENfNGRADv OPTIKO MEKHANICHESKAYA~PROMYSHLENN'OST'-, NO 2v FES 70v
-p 24
-25
_DAT.EPUBL lSKED------70
UB JECT AREAS--METHODS AND FQU-IPMENT
"lOPIC TAGS--THER140BAR CHAMBERt CAMERA# HEAT EFFECT
-XONTROL NARKING---lNO RESTRICTIONS.
~DOCUMENT CLASS--UNCLASSIFIED
I'PROXY~.REEL/FKAME-1996/1586 STEP NO--UR/02371'tO/000/002/0024/0025
~CIRC ACCESSION NC---AP0118571
NUH44C.'LASSIFIED

~:212 025 (INCLASSIFtEO PROCESSING DATE--160CT7C
CIRC ACCESSION NO--AP0118571
"ABSTRACT/EXTRACT-W) GP-0- ABSTRACT. A BRIEF DESCRIPTION IS GIVEN OF
DESIGN OF A THERMOBAROCAMERA FOR INVESTIGATION OF THE DISARR4t,4GE.MENT
APPARATUS AT A PRESSURE UP-TO..5 TIMES 10 PkIME NEGATIVE6 MM
;~;--,~HG AND VARIABL CONDITIONS OF HEAT EXCHANGE*

T
Acc. Nr: jV0047351. Rjef Code:&?"
PRIMARY SOURCE: Vest-aik Khirurgikimoni 1. 1. Grakova, 1970,
Vol 164 Nr (01_4s-~'
ACUTE GASTRODUCIDENAL ULCERS AND TI-1E1R COMPLICATIONS
By V. P. J%Ieln'o ikova, V,, Lrilin if. V, Katnenchik and- M. A. Samoylova
ed P11-
The Nvork is based on the shidy of ca_,~c, reports of two recovered anti 66 di
tients in twhom acute crorion and iilcer of.the stomach and duodenum were revealed.
In 33 patients there were ibultiple, erosions ond. ulcers, in the remainder - sjng~e.l Of 44
patients with complicated acute ulcers in 28 patients these were the principal cause of
death. while in 14 patients iftey accelerated the inevitable lethal Issue. Two piatients
have recovered one after grastrectomy and th6 other- after'wturing inucosa around the
bleeding ulcer and ligation of the left gastric: artery.
REEL/FRAME
19790877

it ~7
212 026 UNCLASS7FIED PROCESSING DATE--13NOV70
-~.C-IRC ACCESSION NIJ--AP01326(15
GP-0- ABSTRACT. S TU.0 I E S: HAVE a E FN MADE ON PRE
mrURELY.' BORN INFANTS ON T H Ev IST-AND TH&JTH DAYS~;~OF ThEIR POSTNATAL
L F E 8[QELEc:r.:,lCAL ACTIvI'rY d AS RECORDED IN M.. QU'11)R'ICF.PS OF THE
T"IGH. IJ WAS DEMONSTRATED 'THAT THE INTERVAL BETWEEN STI;AULATION AND
._:Tl,~-E, ONSET OF TIHE ELECTRICAL. RIESPONSE'OF MUSCLE DECREASES I)U.RlNt-,. THE
DEVELOPMENT QF-.`PAE 11,11ATU8ELY BORN NFANT S.:, - HOWEVER THE DURATION'OF THE
w
L Ar ~r,ENT PERIOD DEPENDS NOT ONLY :ON MORPHOLOGICAL MATURATION OF VARIOUS
PXRTS. OF.-THE REFLEX ARC 5UT GIN FUNCTIONAL:CONDITIO-Al OF THE CENTRAL:
SYSTEM AS WEELL (AS INDICATED BY STUDIES- OPV MATURELY BORN [NFANTS
I.RCULA-TION#., :FACILITY:,
jURBAKES IN BRA[i~.BLOQU,~.r
OF; EVOLUTIO
NARY- PHYSIOLOGY AJND.,J3~FQ61EM~I~ TRY USSR ACADEMY OF
I ENC CS t~ LEN'INGRAD.- OF 03$TETRICS AND
LEJN~JNGR
L A SS I FIEO

USSR uDc 621-762.244
KAMENETSKAYA, N. M., ZOSOVA, 0. A.
"TI9t&i f Hermetically Sealing Microelements in Radio Equipment"
Moscow, Otkrytiya, izobreteniya, prozWshleanyye obraztsy, i;ovarnyje znaki,
No 2. Jan 71, Author's Certificate No 250490, division H, filed 10 jun 69,
published 22 Dec 70, p 169,
Translation! This Autrio-'s Certificate introduces a imthod of hermetically
sealing microelements in radio equipment by melting ~. sealant tablet.
AL a distinguishing feature of the patent, the nethocl is aesigned for
sealing articles of any configuration without using inolds, and also for
simplifying the technique. The sealing.;co#ound contains a irdxture of
thixotrepic fil-lerq e element to be i sealed i:~ placed in. a cup-shaped
tablet of this sealing compound, the coTopound is premelted at points of
cor-.tact with the element and leads at a -temperature of 70-1000C, and the
element is then presse& into the cup-shaped tablet, covered with a sealp-Tit
tablet having lower 'uhixotropic properties, and heat-treated at a tenrPera-
ture of 150�50C for 10-15 hours.

USSR UDC 616-008.6.02:615.246.91-07:61.6.8-009.836
11 A IL"
-DL, Chair of Psychiatry, Kalinin Medical Institute
"Types of Sleep Disorders in Chronic Alcoholics in the Withdrawal Period"
Moscow,,Zhurnal Nevropatologii i PsAblatrii, No 6, 1972, pp 893-897
Abstract- Study of 97 hospitalized chronic alcoholics age 21 to 55 in the
withdrawal period revealed four types of sleep disorders: (a) sensorial,
marked by dreams filled with many colors and sounds, frightful-looking animals,
and fantastic situations, and considerable motor restlessne!;s while falling
asleep and mqakening;; (b) motor, with intense motor activity throughout the
night, twitching muscles, frequent change of positions, talking in sleep; (c)
reactive, 1-ittle sleep during the night, realistic dreams, motor restlessness
exhibited only during the first two days in the hospital; (d) vestibLilar,
ve-stibulopathic phenomena in the form of vertigo with.the sensation of falling
or spinning of objects around the body accompanied by nausea, hidrosis, and
fear, nightmares in which the body feels like lead. The caloric and other
teatc Bhowed the presence of functionalAmpairment of the vestibular apparatus,
especially pronounced in, the alcoholics with the vestlbular type of dyssomnia.
53

USSR UDC 612.766.1
KAM,, ETaQ P I., Chair of Normal Physiology, Sanitary Hygiene Medical
Tn-s=,ate ana Laboratory of Labor Physiology, Institute of Labor Hygiene
Occupational Diseases, Leningrad
"Changes in the Central Nervous System and Motor Apparatus During Intel-
lectual and Physical Work"
Leningrad, Fiziologicheskiy Zhurnal SSSR, No 10, 1971, pp 1,429-1,435
Abstract: Experinenits 16rith healthy young persons 19 to 25 years of age showed
that brief mental activity (3 min) increased the lability of the visual analy-
-sor and improved the quantity and quality of the work done ill proofreading
tests. More prolonged activity (33 min) resulted in a deterioration of these
indexes. Brief mental activity also increased hand strength without causimp
tremors. Longer activity (7 and 33 m1n) had an adverse. effect on these in-
dexes. Physical exertion (work with an ergograph) for 36 qer-, I min and 17
sec, and 2 min and 36 sec decreased muscular strength, the extent varying with
the length of exertion, but it improved 04S function ~_,specially when conLillued
for 2 min and 36 sec. Muscular exertion'for 36 min bad little effect. The
results of correlation analysis revealed the existence of a definite relation-
ship between the chmges in parameters of the CNS and motor apparatus after
both mental and physical work.
1/1
29

USSR UDC 612.8+612.761-06:612.821
-y
I., Sanitax -Hygiene Medical Institute and Institute of
Labor Hygiene and Occupational Diseases,, Leningrad
"Functional State of the Central Nervous System and Motor Apparatus in
Some Types of Mental Work"
Moscow, Gigiyena Truda i Professional'nyye Zabolevaniya, No 7, 1971, pp
25-28
Abstract: CNS activity (latent period of- visuomotor reactions, critical
frequency of coalescence of light flashes, proof reading) and motor func-
tions (hand strength, tolerance for static exertion. hand tremor) were
studied in 20 bookkeepers and accounting clerks 22 to 50 years old 4 times
a day (before work, before tlie lunch break, after it, at the end of the
8-hour workday) for a week (5 days). Both the indices showed clear signs
of.increasing fatigue by the end of the shift and end of the work week,
those characterizing C16 activity being more pronounced. The deteriora-
tion was greatest 5 hours after the start of work and showed little irr.-
provement until the end of the shift. The motor changes were gr,_atest at
the end of the shift, witil only the endurance of the hand muscles showing
any significant improvement after the lunch break. Mental and pliyslcal
1/2

7777
USSR
YWMENETSKAYA, Z. I., Gigiyena Truda i Prof essional'nyve Zabolevaniya, No 7,
1971, pp 25-28
performance were best in midweek and poorest on Friday. The 2-day weekend
Droved beneficial, and both mental and physical indices were restored to
their normal levels by Monday morning.
2/2
-MM
mom
IR
MUM MR1,11IM1110111

USSR UDC 532.517.2./4
"Asmtotic Turbulent Boundary Layer at a Free Jet Boundary"
Trudy Leningradskogo Politekhaicheskogo Instituta, Aerotermadinamika
(Works of the Leningrad Polyteclinical:Iastitute, Aerothermodynamics),
No 313, 1970, pp 59-62
-ranslation: This paper contains a study of the possibility of using
the semiempirical Taylor formula for an asymptotic boundary layer, and
the conditions imposed on the law of increase In the mixing path are
established for which it is possible to obtain the.~asymptotic solution.
The solution found is compared with the experimental reuults. Here,
in contrast to the existing Tolmin solution with aifinite thickness
of the boundary layer, entirely oatisfactory comparison with experiment
is achieved in the entire region of t4e.boundary 14yer, including its
outer boundaries. There is one illustration and a~two-emtry biblio-
graphy.
1 A

USSR TJDC 532' .526
KAMENETSKIY, A. 1.
"AsYMD-totic Turbulent Boundary Layer,at the Edea of a Free Jet"
Tr. Leningr. politakhn. in-ta (Works of the Leningrod Polytech-
n1cal T stitute), No 313, 1970, pp'59-62 (.from FZh-Mekhanika,
No 8, Aug 70, Abstract No 8B905)
Trans-lation: The possibility is investigated of using the semi-
empirical Taylor formula for the asymptotic bou:adary layer, and
the conditions imposed on the.law of mixture path growth, in
the fulfillment of which the asymptotic nolutioft can
be obtained,
are establish,-~d. The obtained solution is con~pared with the
oxperimental results; then, as di3tinct from the present Tollmin
solution, with the finite thickness,of the limil~l - layer.. a com-
A. X16
pletely satisfactory coincidence with experiment is obtained in
antoire.region of the boundary layer includimg its external
bounds. Authorts abstract.

USSR UDC 532.526
YAMMT,SKI~X$ t~~ -1
"Empirical Method of Calculating the Turbulent Boundary Layer in an
Incompressible Liquid"
Trudy Leningradskogo Politeknicheskogo Instituta, Aerotern,.odinamika
(Works of.the Leningrad Polytechnical,Institute, Aerothermodynamics),
No 313, 1970, pp 62-67
Translation: The investigated paper proposes a single-parametric method
of calculating the turbulent boundarylayer which 16 based on systerqatic
processing of the existing.experimental.data. The law of~similarit7 Of
the characteristic variables is established for turbulent and laminar
boundary layers. The relations of the -characteristic varidbles are
presented in the form of graphs;and approximating formulas. There are
5-illustrations and a 10-entry bibliography.
78

'USSR UDC: 550-837
VAKULISKIY, A. A., LABZHINSKIY, S. 1. LUTSYSHIN, A. S.,
In;titute of Physical
HIZYUK, L. Ya., TIMFEYEV, V. M., YAKUBOVSKIY, Yu. V.,
Plechanics, Academy of Sciences of the Ukrainian SSR
"A Device for Aerogeoelectric Prospecting"
Moscow, Otkx-y-tiya, Izobreteniya, PrOMYShlennyye Obraztsy, Tovarnyye Znaki,
No 9, Mar 72, Airthor's Certificate No 331356i Division G, filed 12 May 69,
published T Mar 72, p 144
Translation: This Author's Certificate introduces a del~ice for aerogeo-
electric prospecting by the method of transient processes. The device con-
sista of a current pulse generator which contains a source of direct current,
a muter multivibrator, (L frequency dividero a power eg4iliflur, a current
commutator and an oscillator tank circuit.; and a metur whIcl, r.,ontrd.no fL
receiving tank circuit, it preamplifier,'a gating modul4!, an accumulator,
a DC amplifier, a registration unit, and a circuit for control and synchro-
nization of the gating module. As a distinguishing feature of the device,
interference suppression is improved, the' measurement error is reduced and
the stability of compensation of transient processes cmused by the cond~ac-
1/2
154

USSH
VAKULISKIY, A. A. et al., USSR Author's Certificate No 331356
tive fuselage of the aircraft is increased by connecting coincidence gates
in the current pulse generator between the frequency divider and power ampli-
fier. Some inDUtS of the coincidence gates are connected to the output of
the waster multivibrator, and the other inputs are connected to the outputs
of the frequency divider. A band filter is. connected in the meter between
the preamplifier and the gating module, and a secondary gating block is
connected between the pulse amplifier and:the DC ainplifier. The secondai7
gating block is connected to the control and synchronization circuit, and
is made in the form of paraUel-connected compensat, ion and measurement strobe
pulse multivibrators which are connected: through a broad strobe pulse Shaping
multivibrator to the pririary gating module. Multivibrators for delay and
shaping of narrow strobe pulses [are connected) to coLncidence gates with
some inputs connected to the outputs of the oscillator frequency divider,
while the other inputs are connected to the multiv--ibrator for shaping na--rov
strobe pulses, and the outputs of these coincidence gates are connected to
the secondary gating block.
2/2

`j
USSR uDc 550.837.73
F. M., YVUBOVSKIY, YU. V., 7,11ZYUK, L. YA., VUKULISKIY, A. A.,
NEV, V. H., K114WOROV, P. P., LUTS~SHIN, A. S., BOYKO, V. P.
TD-10FL
"Device for Inductive Acroelectric Exploration by the Transient Process llethod"
Moscow, Otkrytiva. Izobreteniya. Pronyshlennwe Obraztsy, Tovarnyve Znaki, No 16,
8 May 70, p 61, Patent No 270123, Filed'19 Apr 65
Translation: 1. This Author's Certificate introduces a device far in4uctive
aeroelectric exploration by the transient process method. The device comprises
a pulse generator, a generator circuit, a receiving element, a control unit,
amplifiers, commutators,, storage elements, and a recording unit. It is dis-
tinguished by the fact that in order to:improve the noiseproofness of transient
process measurements in flight, the generator circuit.is executed in the form
of a system made up of the basic gencrator.circuit placed between the aircraft
and the receiving elp-ment at equal distances from both and two auxiliary cir-
cuits arranged one directly on the hull, of the aircraft and the other, on the
case of the receiving element.
2. A second dev'ce like item 1 is introduced, but it is distingui6hed
by the fact that in order to obtain the required power -In the basic generator
circuit directly from the low-voltage on-board network atid also to tacrealie
he steapness of the pulse fronts, the basic generator cirtmit is exacuted in

[Kill it
4Aao52G78-"
UR 0482
Soviet Inventions Illustrated, Section III Mechanical and General,
Derwent, 70
f;;ZT7 SAFM VALVE WITH TR'ANSFER SLIDE-VALVE
controlled by thealfferenceof pressure
in a throttled aperture mad':iii the slide-valve
the fluid brought from the pressure cavlty~
simultaneously to the annular belt and tothe face
of the slide valve, differilpS in having a cOnical
surface between two tylindrical:surfaces on.the
slide-valvej on which it isi.centred in the valve
body. This speeds up the operation and improves
reliability. When the pres'~,reln cavity 13 is
below the setting of ball. vslive 4. there is; -no
flaw of oil through throttling aperture 14,,and the
pressure In cavities 6,11~and 13 is equal, so the
oil pressure forces on slide- valve 2 are baXanced
hot the allde-valveis pressed-down by sprit
g: 3.
and its conical surface 10 prevents oLl pasting
fro pressure cavity 6 to drain cavity 7., Surface
10 "y be made in bush 15 pressed into body.l. if
the presaure in ibe.system is.ab-ove the setting of

valve 4, oil frcmi cavity 6 begins ta seep via
channels 12 into cavity, 11 gnd,vla aparturit 14
into cavity 13, whence itwill drain via valve 4
jmd chazmtL 16 to drain cavity 7. - The pressure
in, cavity 0 is -loweir than in caviti*s 6 *W 11
48 a result of loss-of presiurain a0exturid, 14.
The pressure acting on. alidi~-valire 21rom cavities
6,aud 11 is Sr"tiar than tfi~t from cavity 13. The
slide-vaLve rises, atlovidgioil,to drain.
22-J2.62. 809893/25-8,~BARSUXOV, A.A. and
KAMMETSKII, G.I. Metal-Cuttiug Lathes Inst.
(29.9.69) Bul. 171/14.5.69. Class 47g, lut. C1.
F 06k.

EFFECT OF BENZOHEXONIUM ON THE PHYSICAL AND CHEMICAL PROPERTIES
OF BILE IN HEALTHY PERSONS AND CHRONIC CHOLECYSTITIS PATIENTS
and &r. X. Ch rnomorets (Donetsk)
S
The effect of benzohexonium was studied on the physical properties and chemical
content of bile in 114 patients upith chronic, cholecysti tis and also in healthy subjects.
It was found that benzohexonium exerted no negative effect on 1he normal physical
properties and chemical content of bile both in the healhy persons and patients with
cbronic cholecystitis. Benzohexonium exerted a positive eifect. on. the pathologically chan-
ged 4epatic and bladder bile.
REEL/MME
198Z0386.

INN NOM
USSR We 666.972.678
Candidate of Technical Sciencesp MAYZELI, 1. L., Can-
-dldate*.of chnical Sciences# and KAMIaN,, V i: I. , i 19vF_1neer , All-Union
Scientific Research and Planning IrAtitute Teploproyekt
"Beat-InsulatIng Plastic Concrate Based on Polyurethane Foar. and Mineral
Agg"gatee
Moscowt Stroitellnyye Materialy, No 7(223), Jul ?3, PP 14-13
Abstracts The All-Union Scientific Reecarch and Planning Institute Teplo-
proyekt. produces a beat-insulating plastic concrete te.,jed on FPU--jj#3 Poly-
urethane foaa and aehy gravel on an fcaa~ glass Exagments. The concrete has
voluxetric nass of 600 to 160 kg/m~. The ashy gravel is pxoduced by the
Kashirsk Reinforced Concrete Products Plant No 3; the foam glass, by t
Gomel' Glass ftetoryl and the PPU-3s polyurethane, by the All-Union Scientific
Research Inst1tute of Synthetic Resins in Vladimir. It is demonstrated
that polyurethane foam of various volunetxic mass and various strength
irALces can be produced by changing the content of the foaming water agent.
The naterials wasess low volumetric mass, sufficient strength, insignifi-
cant flammability, and good heat arA moisture protective properties, Four
a
fv" v anct one table.

'_1/2 012 UNCLASSI'FIEO PROCESSING DATE--09OCT70
T,ITLE-FEATURES OF PRODUCTION TECHNOLOGY~AND MECHANISM OF PORE FORMATION
IN LIGHT WEIGHT PERLITE GROG CERAMICS -U-1
AUTHOP.-(05)-FAIN, I.A.9 KAMENETSKIY* S.P*j RABINOVIClip M.A., GRIGQRYEVt
MLNKOVr D.B.
.'COUNTRY.~UF INr-U--USSR
'S'(1URCE-OGNEUPURY 1970,
35(21), 3-6
TE PUBLISHED----70
AREAS-MATERIALS
_J.TQPI C'.TAGS-FOAM, REFRACTORY MATERIAL, INDUSTRUAL PRODUCTION, POROSITY
CONTROL MARKING-NO RESTRICTIONS
DOCUMENT CLASS.-.UNCLASSIFIED
~PROXY REEL/FRAME--1992/1979 STEP NO--UR/0131/70/035/002/OC)03/0006
CIRCACCESSICN NO-APO_112~943
al

.11-212 012. UNCLASSIFIED P110CESSING DATE--O9OCT70
CrRC ACCESSION NO--APOlIZ94,3
.AbSTRACT/EXTRA"---I--(U) GP-O-- ABSTRACT. BLOATING PEKLITE SAND IS
RECOMMENDED INSTEAD OF FOAM PERLITZ. IT ENABLES PRODUCING 2.3-2.4 MORE
PRODUCCTS. POROSITY OF BLOATING PERLITE 15 0.6-O.T5 KG,-C(4 PRIME2. TO
-~--PROTECT THE STRUCTURE OF PERLITE A SPECIAL HORIZONTAL MIXER WAS USED.
AL
L.^.b.1 IL fD

USSR UDO 621. ~82.7--:546.289
KUZN-qT-SOV, YU.A., KAMENETSM, M.A., $WL'SKIY, A.S.
OTYPe G11-738 Germanium Avalanche Transistor"
Elektron. 2rom-st'. Nauch.-tekhn. eb. (Electronic Intiustry. Scientific-Technical
Collection), 1971, No It, pp 40-41 (from Rlh:Elektroni a i ve,%,_~
k
_jnniye, 'No
5, May 1972, Abstract No 5B190)
Translation-. The principles of operation of a Type GIT-15~,8 tranaistor are b2sed
on the effect of carrier multiplication in the region of the space charEe of
the collector. Use of the GT-7,'~B in the circuits of generators of narrow alses
and of pulses urith a steep front of the nano- and subminonecond ram-c =3~:ac it
posBible to simplify circuits mub Btant lally and to improve their technical
characterictics. Sumna r~i.
77
"tit!
111611011111,11,11

USSR UDC 621.382.3-029.5/6
KAMENETSKIY, Yu. A., KAGANOVA, 1. 1.
"Equivalent Circuit of Silicon Microtrave Transistors with the Side Capacitance
of the Emitter Taken Into Account"
Elektron. tekhnika. Nauch.-telchn. sb. Poluprovodn. nriborv (rlectronics
Technology. Scientific-Technical Collection. Semiconductor Devices), 1970,
issue.6(56), pp 16-26 (from M--Elektrpnika i yeye 2rimeneniye, No 10,
October 1971, Abstract No 1OB195)
Translation: Using a Type 2T316 transistor as an example, the equivalent
circuit is considered of a low-power siiicon transistor operating in the
microwave range. Ass the result of a theoretical analysis it is shown that
with a decrease of the width of the base region neces~vry for increasing
the critical frequency of transfer current, the effect: of the side emitter
capacitance increases in comparison with the. depth of the endtter layer. As
a result a significant dependence of the input resistance of the emitter on
the operating frequency develops. The experimental studies,conducted demon-
strated the legitimacy of the assumptions made dUring computation. It is
probable the results obtained are aiso correct for germanium transistors of
thir same class. 9 ill. 2 tab. 3 ref. V. B.

Tr. VNII zh.-d. transp. (Works of the All-Union Scientific-
Researcli Institu-t-e-o-17-Railroad Tr4n.sportation), 1970, Issue 416,
63 (frora RZh-Elektronika i'7eye p
PP 137-1 rimez~eniye, No 2,.
February 1971, Abstract Xo 2B>bU)
Translation: A description and analysis is presented of the
'6D_erE_Lfi-FE_o_f a thyristor pulse converter which, can nmintain normal
operation of a-c eloctric rolling stock, powered from a d-c
catenary net, by using the same equipment and by maintaining the
same power and traction properties as with an~a-c net. The re-
sults are presented of an exnerimental investigation with the
d-c and a-c sup lies. The converter described satisfies the
lp
requirement for dual supply and assures a number of advantages
over existing design. 22 illustrations,,2 tables, 3 references.

USSR urc:
"The ALGOL Packet of the SDqJL.A-1 Language"
V sb. Issied. po rzt. -e'-on. i s7-,ezh. vopr. (Research in Matheiiatical
Economics Erd Re---Ted -z"'-le--s-collection of works), Moscou-, Moscow
University, 1971, r-, (from F.ZhA-K'ibernetika, No 1, jan 72, Abstract
No lv984)
the SII-7JLA-1 Language is a set of T)rc-
Translaticn: The AT-GCL -.acke~ of L
cedures in ILGOL-60 lar;z--age w'-ich -i-itato the possibilities of the Sj!,17L~~-l
te
language. The packet i's designed for investigating syttem's wL dise-e
eventa on computers equir-ped with translators from ALC-OL-60 larguage.

------------- ---- --
Ace. Hr.: AP0046777~ Ref .Code: 011,3
USSR UDC 629-113-075-0,01-5
PrEOVSMY, Y'J. V., L. G., and W-22401, V. D.
"Investi-mtion of the Turn of a Two-Axle 110tor Vehicla Nlith Different Types of
Drive for.the Driving
-Moscow. Avtomobil'A-4ya Prom.;~shlennostl (,',.,otor Vehicle Indtistry)otWN
22-24
P
P
Translatimi The rela'tionships det-ermining the chan;-,,,e of pou-ar use:! in t-xrn-irj
a motor vehicle -uith a 4x4 wheel forriula de-ending on t~-,G of drive for t.i-.e
driving whe!als are- annlyz~--d. Fower ch-ange ts ass-)ciated wifh the pesenc-- of
lateral forces causing tire dzift ani redistribution of torque alor~; motor vehicle
drive bridges. (2 illustrat-1--ns, 6 b-Ibllo.zef.)
Reel/-Frme

:-1/Z 010, UNCLASSI F10 FACCESSING DATE--30OCT70
~TITLE-IMPROVEO METHOD FOR PREPARING A CATALYST FOR;THE VAPOR PHASE
.,SYNTHESIS OF VINYL CHLORIDE -U-
.AUTHOR-(05J-PANFILOVv A.A.r VASILYEVA# I*B.v KAMENKOP B-L.# GAVRILCHUKt
XVARTALNOV, V.V.
~,,COUNTRY OF INFG--USSR
3,:-SOURCE-KHIM. PROM. (MOSCOW) 1970v 461319 177-1
'.~,DATE PUBLISHED-70
iSUBJECT AREAS-CHEMISTRY
JOPIC TAGS-CATALYTIC ORGANIC SYNTHESISr 'VINYL CHLORIDEt MERCU Y COMP UN
R 0 D
..iACTivAM CARBON, CHL(JRINATIDN#:ACETYLENEt CATALYST ACTIVITY
m_.CGNTRvjL- HARKING-NO RESTRICTIONS.
',_'_C0CUMENT CLASS-UNCLASSIFIED
"_.,PRQXY REEL/FRAME--200011662 STEP NO-UR/0064/70/046/003/0177/0119
CIRC ACCESSHN NO--AP0125284
t ~i i~ 4z v- r t- f)

EEL---..
212 010 UNC~LASSIFIED PROCESSING DATE--30UCT70
--AP0125284
..C-IRC ACCESSION NO
-:ABSTRACTIEXTRACT--(U) GP-0- ABSTRACT. THE ADSORPT[OPJ ISOTHERM OF HGCL
SUB2 FROM AQ. SCLNS. ON ACTIVATED C IS.PRACTICALLY LI&EAR AND fHE HGCL
SUF32 CONCN. ON THE C INCREASES FROM 0 TO 17PERCENT WHEN THE- INITIAL HGCL
I-SUB2 IN' THE SCLN. IS INCREASED FROM OTO 5PERCENr (AT ;-,.C)DEGREES); THE
~-..ADSURPTION IS FAIRLY RAPID AND A STEADY STATE IS ESTABLISHED AFTER
SIMILAR TO I HR. A CATALYST.CUNTG. 10PERCENT HGCL SU62 WAS PREPD. BY
-PASSING A 3PERCENT AQ. SULN. OF HGCL SUBZ THROUGH A COLUMN PACKED WITH
ACTIVATED C, AND DRYING THE PRODUCT INLONTACt WITH Alk HEATED TO
120VEGREES. IN THE HYDROCHLORINATION Of.C SUB2 H SU132 AT A C SUB2 H
SU32-:HCL VOL. RATIO OF 1:1.3 AND 180DEGREES THE ACrIVIlY OF THE GATALysr
INCREASED,GRADUALLY WITH TIME AND THE VAX. ACTIVITY WAS REACHED AFTER
DAYS tAT A FLUW RATE OF 1100 VOLS.~~HR); T14E MAX. ACTIVITY WAS THEN
SUSTAINED FOR UP TO 8 MONTHS*, AND THE.DgIWE OF CONVERSION OF C SUB2 H
SUB2 UNDER THOSE CONDITIONS WAS NEARLY!,60PERCtNT.:
UNCLASSIFIEV

USSR UDC 632.95
POLESHCHUK, V. D., LAXYSHEV, V. I., KAMENNOV, N. A., WLEMOVA, V. P., SMIRNOVA,
S. N., STOLBOV, D. N.
"Repellent Activity of Diethylamide and Dibutylamide of Valeric Acid with Re-
spect to Various Types of Ticks"
Sb. nauch. tr. Mosk. NII vaktsii i syvorotok (Collection of Scientific Works
of Moscow Scientific Research Institute of Vaccines and SerLms), No 22, 1972,
pp 209-211 (from RZh-Khimiya, No 15, Aug 72, Abstract No 15N504)
Translation; According to field and laboratory tests,,diethylamide and dibutyla-
mide of valeric acid have high repellency with respect to the Hyalomma plumbeum
plumbeum tick which carries hemorrhagic Crimean fever. The tissue treated with
these repellents calcul:ited at 7 grams/m2.remained repellent for 5 days. For
Alectrolobius tholorani papillipes these materials were not repellent. The
five-day repellency of tissue for Ixodes persulcatus ticks, Dermacentor pictus
and D. marginatus was achieved from a dibutyiamide dose of 55-65 g/m2. The
DETA had no repellency with respect to N. p. plumbeum, A. th. papillipes and
D. maq;inatus, but tissue treated with DETA calculated iat 40-50 gjm2 remained
repellent for 20 days for I. persulcatus ahd D. pictus.!,

USSR Loa 632-95
KMNNOVI H. A LURIK, B. B., L11MCHEVA, V. F., Central Scientific Research
-7-nstit, F`oir- ~isi;Wection
"A Method of Making Piparonylic Acid"
USSA Author's Certificate no 348_556, filed 4 Jan 70, published 8 Sep 72
(from. M-Dimiyal No W, flay 73# Abstract No 1011564P by T. A. Bolyayeva)
Traaslationt In order to increase the yield of the goi-I product and simplify
the technology of the process of tiyntheslae sodium hypochlorite Is used as
the oxidizer for making piperonylic acid by oxidizing piperonal. Examplet A
nixture of 0.2 mole of sodium hypochlorite and 40 ml of water is brought to
a boil, 199 ml of 10-11% solution of HaO01 is added by drops over a 1.~-2
hour period, the reaction is continued until drops of the reaction mass fail
to produce any color when applied to indicator paper impregnated with a 2",
solution of potassium iodide, the mixture Is cooled to a texperature of 20 0C
or lese# filtered$ acidified with concentrated hydrochloric acidp and piperonylic
lacid is separated by a Ifutsch filter, washed with water, and dried at 110-
..120 C with a yield of 80-85%. The melting point of the acid is 225-70C.

USSR nc: 632.95
Ov- P.
-Terpinene With Yhleic An)ki ride by the Diels-
Problem of Condensing Alpha
Alder Reaction"
Tr. VNII Dezinfektsii I steriliz. (Works of the All-Urjon Institute of Disin-
~fection and Sterilization), 1971, vYP- 21, Vt. 2, pp 148-151 (from RZh-
njmiya, No 15, Aug 72, Abstract No 15N448)
Translation: Condit ons are worked out. for syntbesizinq; 6-m--thYl 3-isopropyl
3.6-end~~thylena-,8 --tetrahydro-phthalic acid anhydride (I), the initial. product
for synthesizing synergistic systems with pyrethxins,.vind the raw material for
it -- 0~-terxpinene (II). Compound II was synthesized from ter-pineol by
dehydration with a 50-4,o solution of H awhile boilinj..-, the reaction nass with
-2S04
energetic agitatiQn for I hour, with an.87% -yield of the product (boiling
POJ.nt 171-30c, n~-"'D 1.4779), Compound I is synthesized by condensing compound
II with naleic anhydride, heatirk; equimolar quantitieLi of the reagents to QOOC,
waiting for the reaction to initiate, then bringing the temperature up to 2200C
and agitating at this temperature for 4 bours. The p.,roduct is distilled, ~he
fraction with a boiling point of 180-200QC is saponified while boilir4.1 with
200 ml of a saturated solution of sodal:the precipitalo is filtered out and
1/2

-USSR
KAMENNOV, N. A. and PAVLOVA., S. P., Tr. VIIII Dezinfektsii i steriliz., 1971,
vyp. 21, Vt. 2, PP 148-151
washed with water to a neutral reaction,, then dried over CaC'2,- and compound
I is produced with a yield of 65%, boiling~point 620C.Ihaptare).

USSR - uDc; 615.285.7-015.21
WRIK, B. B., VOLKOV, YU. P,~ Central Scientific
7-
Research Institute 7~ s ection, Hinistry of Public Health,
Moscow
PStudy on Insecticide Synergists. Synthesis of 'Piperidides and
Vinylogs of.PiDeronylic Acid"
Khimiko-farmatsevtichaskiy zhurnal, Vol~5, No Aug 71,
Moscow,
PP 15-17
Abstract: As part of the search for pyrethrin synergists, piper-
TUN of piperonylic acid (III) and two of its Vinylogs were
synthesized. Compound III was prepared by the oxidation of
piperonal (I) with sodium hypoehlorite to piperonylic acid (II),
and its conversion to the acid chloride, and reaction with pi-per-
idine. The Reformatsky reaction betueen I and ethyl bromoaceiate
yields B-(3,4-methylenedioxyphenyl)-B-h7droxyproDionic acid ethyl
aster (IV) which is dehydrated to B-(3,k-methylenedioxyphenyl)-
acrylic acid ethyl ester, (VI) and saponified to B-0,4-nethylene-
dioxyphenyl)-acrylic acid (V). Acid V may also be obtained by
1/2
68

U S SM
LURIK, B. B., et al, Nhimiko-farmatsevticheskiy :;burnal, Vol 5,
No 8, Aug 71, pp 15-17
condensation of I with malonic acid with sinraltaneous decarboxyla-
tion. Acid V is converted to the.acid chloride, and then to
B-(3,4-mathylonedio.-cvphenyl)-n.crylic acid peridide (VII).
The Wittip, reaction between B-(3,4-methylenedioxy-phenyl)-acrolein
and tri-ohenvlDhospho.--oacetylDipezidine is used to synthesize
DiDerine (X).* Piperidides III, VII and X synergize pyrethrins
toward Musca domestica L.
2/2

USSR UDC 632-95
GVCZDEVA, I. V., VJMX, B. B., STARKOV, A. V.t UMENNOV, N. A., POGCDINA,
L* K., and SUKHOVAp H. N.
"Search for Synergists of Pyrethrins in the Hethylene Dioxy Phenyl Series"
Tr, VNII dazinfektsii i sterliz. (Works of the All-Union Scientific Research
Institute of Dininfection and Sterilization)p 1971P vyp. 21,,t. 2, pp 101-106
(froa M-Khimiya, No 18, Sep 72, Abstract No 18N431)
Translations For purposes of studying synergtic activity, a series of
piperonylle acid esters and amides, and piperonal acetaas, were synthesized.
The synergtic activity of the synthesized,coapounds was tested In a micture
with pyrethrins in a 10il ratio by the topical:method, In tests on house-
flies# the greatest syner,3tic activity was shown by butylt nonyl and cyclo-
hexyl esters and N,11,-dipropyl amide. KoHkUsubstituted zmides Oze more
active than N-substituted asides, Anong;tbe asides synthesized on the basis
of heterocyclic amines, morpholide showed the areatest activi.ty. The most
toxic for red -ockroacbes sfere mixtures of pyrethrins with 11-iisopropjl aamide
and piperidide. Among the acetalsp the most active compounds for houseflies
were ethyl carbitolic -and butyl ca;bitolic:acetals of piperonal, and butyl and
Nptyl acetals. The acetals are weak synergists for xe(l cockroaches. An
investigation was made of the synergtic activity of the synthesized compounds
on strains of houseflies highly resistant to-DDT. T. A. Belyayeva.

USSR UDC 616.981.551-612.014.464
BELOKUROV, Yu. N., VODOLAZOV, Yu. A., KAMENM., A. N.,, POPOV, B. V., and
KIRSANOV, H. N.
"Inhalation of Oxygen Under High Pressure for Tetanus"
Kazan', Kazan kiy IrLeditsinskiy Zhurnal, No 5~ 1971, p 93
Abstract: A 46-year-old male received a prophylactic dose of tetanus anti-
toxin as well as tetanus toxoid for gunshot wounds in the neck and back,
but his condition began to deteriorate sharply seven days after the Injury
and convulsions occurred with increasing frequency. Mien repeated injections
of tetanus antitoxin, oxygen, analgesics, antihistamine, and desensitizing
agents were ineffectual and the convulsions intensified* it was decided to
institute hy-perbaric oxygen therapy.(1-1/2 hour exposure with 02 pressure
about 3 atm. The symptoms began to subside within 24 liours and respiration
became easier. However, convulsions were provoked by the slightest movement
and another session was carried out: 24 hours later. The. patient's condition
shcrwed steady improvement and convulsions became less frequent and confined
to increasingly smaller areas. By the 15th, day from tbe time of admission
to the hospital, the clinical symptoms of tetanus disappeared completely.

........ ........ . ..
"Me
Mpy:
USSR
BEL01MOV, yu, N.) MORNMO, A. S. and MIXHAYLOV) V. Poi
Faculty Surgical C slavl Nedical,~Institute
"Treatment of Anaerobic Infection vith Hyperbaric Oxygenation"
Leningmd, Vestnik Khirurgii) Vol 105, No 10P Oct 70, PP 137-138
Translation: We have successfully used the method of hyperbaric oxygenation
ction of the extremi-
for the treatment of three patients with anaerobic infe
ties., spreading over the trunk.
In all three patients, the diagnosis -das confirnr-d bacteriologically, and
X-ray pictures showed gas in soft tissues. The treatnedt was conducted in a
chi3mber designed by Yu. N. Belokurov. During the treatment sessions, the
electrocardiogram, respiratory frequency, rheovasogram,, and blood pC~ of the
patient were recorded. Each oxybarotherapeutic session lasted 2-3 hours, and
the; oxygen partial pressure was raised to:a maxim, of.2.8 atm. Each patient
underwent from four to six of these treatment sessions.
We observed no complications from this treatment method. Detoxification
therapy was simultaneously applied and consisted of adjainiateilrig antigangrene
serum (UP to 300,000 unitil per day),, protein and electrolyte solutions, and
116

USSR
BELOKBOV Yu. et al.,.Vestnik Khirurgii, Vol 105, No 10, Oct 70,
PP 137-138
antibiotics. Even after the second therapeutic session., a norked clinical
effect was observed, with disappearance o.fsigns of gas gangrene in t-iro
patients.
The method was successful even when radical surgeryvas impossible due to
the spreading of the process over the trunk.,
1. Patient Shch, 35 years old. Delivered to the hospital on 23 January
1968~ 6 hours after trauma sustained at vork. Diagnosis: Open fracture of the
pebris; rupture. of the ampullar portion of the rectum azd the urethra; tear
wound on right buttock; and third-degree shock.
The patient was brought out of chock, a suprapublic fistula of the- urinary
bladder was rade, and the wounds were treated surgically without sutures.
Foity-four hours after the trauma) the patient's tempevLture was 400C, a swell-
ing of the right buttock developed with bt-onze-cyanotic'discoloration of the
skin, andthe wounds discharged an exudatee.of dirt and blood. Palpation
revealed crepitation in the area of the right buttock aaA the perineum. A
diagnosis of gas and edematous form of anaerobic infectLon vas made. Skin and
fa(icia cuts were made In the buttock and per1neumi and "tigan45rene serum up to
.150 000 Au per day was administered. On 26 January, the adena and gar, spread
2

over the trunk, the wounds were necrotic, and the protrucling muscles acquired
a gray color. The patient was passive; pulze rate was 120 bests per minute.
Sixty-eight hours after the beginning of the disease, the patient was sent to
our clinic for oxybarotherapys The first,itreatment was given on 26 January;
it lasted 2.5 hours, with oxygen pressure in the chanfoer up to 2 atm. On 27
Januaryo the patient's temperature was subfebrile, he vas conscious, tha hip
swelling had diminished 4 cm, and the tissue around the wounds acquired a
viable color. On the same day, the second oxybarotherapeutic treatment was
given for 3 hours, with a pressure of 2.8 atm. After that, the bronze-
cyanotic discoloration of the skin disappeared, the vountla ema&-d a, modprate
amount of a -serous fluid, and the muscles became pink and were no longer pro-
truding, The size of the right hip rapidly.diminisbed to thitt of the healthy
hipt and crepitation disappeared. Tbe temperature was aubfebrile, and the
signs of gas gangrene were gone.
2. Patient R.,, 22 years old. On 8 March 1969, the patient sustained
fourth-degree electrical burns on both vrista~and forearms from 10)000 volt
alternating current. On 13 March, he was delivered in a erious condition to
the Vologotskaya Oblast Hospital, where the folloving.dlagnosis.vas made:
3/6

H.~
USSR
BMOKUROV, Yu. N., et al., Vestnik Khirurgii, Vol 105, No 10, Oct 70, Py 137-
-138
electrotrauma complicated by anaerobic infection spreading over the ventral
surface of the neck and chest.
On 1k March, the patient was sent to our clinic in very serious condition,
with a gray-earthy face color, icteric scleraB, pulse of 120., and a tempera-
ture of 39.20C. Mere are necrosis of both wriats and forearms up to the
middle third. On the left side, the swelling and hyperemia spread to the
lateral surface of-the neck and over the subc-lavicular area. There was dis-
tinct crepitation to palpation, X-ray pictures revealed gas. Bacteriological
analysis of the wound exudate establishedithe:presence of C. I)erfringenli and
--hemlytic Staphylococcus aureuse
The patient was placed in the barochamber for four hours at a pressuxe
of 2-5 atm- Within 24 hours, the patient's condition i=promd considerably,
his temperature fell to subfebrilej owellir of th liml)s dinluished, and
ampitation disappeared. On the fallovizglayfil t~o more oxyburotherapeutic
treatments were given. N 1T March, necrectomy was perrormed In the middle
third of the left arm and the upper third of,the right forear-ma After
surgery, the patient was again placed in the barochasiber. On the following
days, the patient, impromi M7D:tdjy, His, temperature vilis sub,febrile, and
4/6

the gtLocps were gradually cleared of necrotic areas and pus imd became covered
vith granulations and epi-thelization from the edges. Me patient recovered
on 20 April, vas transferred to the Vologotakaya Oblast Hospital for
and
further treatment.
3- Patient D., 38 years old. On 15 April 1969p tbg patient had an auto-
mobile accident and sustained an open fracture in the middle third of the
right thigh and a laceration of the wall of the femoral artery. He was
delivered to the district hospital in a state of shock. After the shock was
treated, an osteosynthesiii was performed on his right thigh, end his femoral
artery was autured. On the fifth day, the edematous saL gaseous form of
anaerobic infection developed in the thigh. :Longitudlmal cuts were made in
the thigh, and the patient was sent to our clinic.
At admilssiaa on 20 April, 7ae vas in serious condition; his skin and
scleras were icteric, his pulse van 100 beats per minixte, his right thigh
vas edematous and the simlling vw spreading over 'the sliank, and the akin on
the thigh had a broz-a-e !=e extendlirg arer, the inguinml Cold. A serous pas
vas. discharging fr= the vvumd., and the nacles had a "cooked!' color. Gas was
emitted upon palpation and applicatim of ~ pressure Bacteriological analysim
5/6

IWR
BEL010MV, Yu. N., et al., Vestaik Khirurgii, Vol 105, No 10, Oct 70,
PP 137-138
of the wound content revealed the presence of C. perfringens.
On 20 and 21 April, 'two ox~taratherapeutic treatuvi3ts a(hTdnistered,
each lasting 3 hours at a pressure of 2.8 atm. The patient's general condition
improved, his temperature vas subfebrile, and the clinical signs of gas gan-
grene disappeared. On 21 Apri-1 there was a sudden msoive hewrrhage from the
wound. The patient's condition markedly deteriorated, and his pulse rose to
130 beats per ni=te. The heinorrhage vae stopped by conventional methods. On
24 April,, as a reeralt of an ischemic gangrene of the e~etremlty_, the patient's
leg was amputated at the level of the aiclUe think of the tlil&h. After surgery
tim patieut was given fbur more oVb&zvthtrapeutic tren t4wnta which considen-
-ab4 Impromd his geueral conlition. Me Tatient mvoired4.
6/6

1/2 .-015 UNCLASSIF E; PROCESqING DATE--30OCT70
-..TITLE--DIPOLE DIPOLE INTERACTION.OF SUBSTITUTIONAL IMPURITY MOLECULES IN
CRYSTALS -U-
~KONOBEEVP YU-Vo
-..AUTHOA-(02)-~~ ~DSKIY, N.E.,
-'-C.D.UNTRY OF INFO--USSR LOP
~S OURC E- P H YS I C ASTATUS SOLIOIlp 1170~,OL, NR, 1, P~P 29-37
LISHED ------- 70
~60E ~PUB
AREAS-~-~PHYSICS
T.0P IC. TAGS--CRYSTAL--IMPURITY* DIPOLE INTERACTION, MOLECULAR INTERACTION9
.,-,_..DIELECTRIC CONSTANT, CALCULATION
.-cr,NTROL MARKING--NO RESTRICTIONS
~POCUMENT CLASS--UNtCLASSIFIED
~WUXY REELIFRAME--1989/1081 STEP NO--GE/0030/70/037/001/002910037
ACCESSION NO--AP0107590
UNCLASS I F IED
10101110im"r0f m1tim, [in, mum-liffarl