USSR/Organic Cheiiiistry - Synthetic Orpnic Memistry
E-2
.~bs Jour Referat. Mur - Kaimiya, No 2, 1957,
1 4317
siibjected to sublitiation (180-2000, 1 hour), the
content
in IV is detcrirdned 'by the di:.ference. By
sublirmtion
of the residue (300-3200, 1.5 hourj) a determination is
made of the content in II, Correctn(~ss of the
aeterrdna-
ticn of the cbntent cf the ac,.ds by sublimation is
confir-
med by determinaticii of acid value. Yields of T.1) III
and IV depend on the conditions of the reaction. Here-
inafter are listed tile amount of CrO in grams,
duration
4. 3
of the ad4ition of the oxidiz,rg agent, in minutes,
dura
tion of the reaction, in minutes, temperature internal
of
the reaction in oc) and the yields ef 11, 111 and IV
in %:
20, 120, 150, LO. 5.6, M, 31-; 40, 60, 210, 5o-6o,
32.10,
6-1, 3-
Card 2/2 - 48 -
AUTYAN, T.D.
"Qyntheeis of
Anatian. Inv.
157..
heterocyclic compounds."' Part 1.
AN Arm. 38R. Bar. khS,m. nauk v.10
(Heterocyclia compounds)
RAvieved by V.D.
no-5069-370
(MIM 11:1)
AUTUN, V.D,.; INUTAN, G.T.
Inveotigatioas of sulfonic acid estera. Report Ko.4:
Synthesis
of n.-chlorophonyl esters of various aliphatic
sulfonic acids.
Izv.AN Arm. qSR- Xhim. naiflcl 11 no.5:369-372 158.
(MIRA 12:1)
1. Institut tonkoy organicheakoy khtmit AN A-rmSSR-
(Si~lfonic acids)
AZATYAN, V.D.
`-_-I 1 , I
Cyclic trimerization of phanyacety:'.ene. Dokl. AN ARM. SSR 27
no.1:37-39 158. (MIRA lltq)
l.Khimicheekiy institut AN ArmSSR. Predstavleno A.L. Mndsihoyanom.
(Benzene) (Polymerization)
AZATYAN, V.D.
Alkylation of aromatic compounds J.n the presence of metals. Dokl.
AIIArm.SSR 28 110-1:7-10 '59. (MIRK 1217)
1. Inatitut organicheskov khImli AS ArmSSII. Prodstavlono
chlenom-korresponaentom AN ArmSSR VATaretyan.
(Aromatic compounds) (Alkylation)
AZATTAN, V.D.
Synthesis of ketones in the preconce of notallic
aluminum.
DokLAN Arm.SSR 29 no.31111-114 '59- (MIRk 13:2)
1. Institut organicheskoy kbimii AN ArmSSR.
Prodstavleno
aka.demikom AN ArmSSR A.L.Modshoyanom.
(Aluminum) (Ketonos)
AZ-ATYAN, VOD.
Scientific chemistr7 in Soviet Amenia. Iz ist. efit. i
tekh.
103-98 160. (MIRA 16:12)
AZATTAX, V.D.
Use ot metallic allumimm in organic synthesis.
Report Xo,5:
AlkylWon of phenol by mondbromo ebqle. Izv. AN Arm.
SSR nim.
nauki 13 no.2/3:181-185 160. (mrRA 13t10)
1. Institut orCanicheskoykbimil Mt ArmSSR.
(AlUMMM) (Alkylatiovi) (Phenol)
AZATYANI-N.Da; - YESAYAN, G.T.; CALOYAN, G.A.
InvestIgation in the field of sulfortic acid esters.
Report No,,8.
Syntlkesi~q of y.)-ohlox-ophenyl esters of some aliphatic
and
cycloaliphatic suIfonic a.cids. Izv.AN
Arm.SSH.KhIm.na,ukI 14
no.167-62 161. WIRA 15 z 5)
1. Institut organichoskoy khimii AN Armyanskoy SSR.
(SUfonto acrid) (Etiters)
-,.AZAT.YANj,-V,---- -
Brief news. Izv.AN Am,SSR.Khim,rukuki 14 nools8l-83 161.
(M3M 150)
(AcadenW of Soienoes of the Amenian S.S.R.)
AZATYAW, V.D.;_,GlPLI-K9VYJfW, R.S-.
Synthesis tmd transformations -of ditertiary
V-glycols
of the, cyclooctatriefie series. Izv. AN Am,SSR.
Khim.nauki
14 no.5:74.51-.467 161. (MIRA 15: 1)
1. Institimt organicheakoy khimii All Armvan3koy SSR.
(Glycols)
rAu
14214IU41j'~ tz'
PHASE I BOOK EXPLOITATION SOV/6195
Nauchnaya konforentelya inatitutov khImii Akademiy nauk hzerbayd-
shanskoy, Armyanskoy I aruzin6koy SSR. Yerevan, 1957.
Materialy nauchnoy konferentail institutov khimli Akademiy nauk
Azerbaydzhanskoy, Armyanskoy I Oruzinskoy SSR (Materials of the
Scientific Conference of the Chemical Institutes of the Academics
of Sciences of the Azerbaydzhan, Armenian, and Georgian SSR)
Yerevan,
Izd-vo AN Armyanskoy SSR, 1962. 396 p. 1100 copies printed.
Sponsoring Agency: Akademiya nauk Armyanskoy SSR. Institut organi-
cheskoy khimii.
Reap. Ed.: L. Ye. Ter-Minasyan; Ed. of Publishing House: A. 0.
Slkuni; Tech. Ed.: G. S. Sarkloyan.
PURPOSE: This book Is intended for chemists and chemical engineers,
and may be useful to graduate students engaged in chemical re-
search.
COVERAGE: The book contains the results of research In physical, I
inorganic, organic, and analytical chemistry, and In chemical
engineering, presented at the Scientific Conference hold in
Yerevan, 20 through 23 November 1957. Three reports oftparti-
.oular Interest are reviewed below. No personalities arp mentioned.
References accompany individual articles.
AZATYAN, V.D.; VASILIYANI M.V.
SyntheAs of diteritary a0tylenic 114glycols frox saturated
methyl, ketones and of tetratomic acety4nic alcohol from
diacetDne alcohol in a benzene meditm. Izv.AN
Arm.SSR.Khim.nauki
15 no*5:493-494 162. (MIRA 16:2)
1. Institut, organichaskoy khimii All Armyanskoy SSR.
(Acetylene comPounds)
(Glycols) (Ketone)
4ZATYAN,-V.D.; VASILYA14t M.V.; YESAYAN, G.T.
Derivatives of acetylenic alcohols, 1(-glycols, and
polyWric
alcohols. Report No.lr Synthesis ofvilfoethers of
tertiary acet4
ylenic-j'~-glycols and polyhy4ric alcohols. Izv. AN
Arm.SSR. Khid.
nauki. 16 no.3:257-261 163. (MIRA 1712)
1. Institut organicheskoy khimii AN Armyanskoy SSR.
AZATYAN, V.D.; YESAYAN, G.T.; 9TEPARYAN, A.A.
Sukl'onic acid eaters. Report No. 12t -Chloroetbyl
eaters
of vulfonic acids. Izv. AN Arm. SSR. Kbim. nauki 16
no.5:
461--464 163. (MIRA 17:1)
1. Institut organichoskoy khimii AN Armyanskoy SM.
ACCM510N VR: AP500851 /64/n 17/00A /V06/0708
AUTHOR- Azatyan, V.1'D.
mth ..(trJv -cytlooctatrlenti
TITLE. Sy
iSOURCE: AN AnnSSR, lwvastl.pa.~ XhImiv)Wdye nauki,, v. 17, no. 6,
1964, 706-709
',TOPIC TA6S amic rithes3sl' di-1 trio i ~yl) _cyclow Itatrienti
cyclic. coppound,
rs '-$y
~jm
STRACTv' D1- (trial lyl -cytloc ~6 tatj~lene was syntheslized thmugh
the Intoracti on
iol trl thy.1chlaronilanO an
VA me P0 . - 17
PMA
isqcio'
'?r1;wtby1ch1DrcnA1ama 1-~ tbi'
w~mmt of,52 g (0.6 mol based 6n 80% fomation of,
iadded -at -rom tenperatiftv - in a 45-minutc-period-to-
prepar~d~~ftvm~31.2~ (0.3 Tmij) of Stclooctate e d
dilithitimcyclooV btr or tra nelan
,4.2 g (0. 6 gro "L~ D:F metall.ic lithium in 200 ml of absolute
other in.awet-
Card 1/2
L V60"5
ACCESSION XR: AP60078P
Mospbere of- natrogo,n v. iLe riiattion~pl~oceed6-onergcllti~citi-iv
vith~:a_spontailebu In
cx,ease in the terperature of 'tbe reagent solution to ~.33. 50. '~
After additional two.;.
bour mixing the mixture ~vas Itelt for the nigbt; then '75 vA of
water were; added vi+h.
mixing. 'The ether lqyeil~ was ~ &~~ydr~t & over hydro%;
sodim's-sulfate anti-the etht'
-an
dr. ff
was I iven o- . Throug)i evaporktion of -the -remainderl in
a-viicuum, 4.2-g of a
imixture of cyclooctatetraene ma cyclooctatriones an~ two,_fnictions
of a gold~
yellow colored liquid mav clotalned which had boilinq points which
differed by 8-90.:
;The yield of both fractIons was 0.5% of the theoratical. 01,1g. art.
has: I
11 figure, I table, I equation.
JASSOCIATION: Ingtitut organicthnakoy' khimli M A4>R (Institute !)f
OrgenIc
.Cbemistry, AN ArOSR)
SUBHITTED: 25Sep63 ENCL: 00 SUS CODM GC' Oc
NO REP SOV:. 004' OTHER- 005
J,
~~fj 212~
;~NAYI*,UIWX, A.I.; WiGUMli, I.G.; AZATIll, If.G,,
D-Isordors of heriodpianics in stenosis of the
atrioventriculla,
or'Ticc of the heart. Izv. lj~' Arn.S3R. Blol.
nauki 17 no.U:
55-62 N, 164 18:2)
1. In,,,titut kardiolor.1i i verdeclmoy !:MlrLLCii
ilu'll' SSSR.
Determination of the Rate Constant of the :3/020j6O/132/O4/36/O64
Reaction of Atomic Oxygen With Molecular 3004/B007
Hydrogen
are grapbically to be determined. The exporimente were carried
out in a
vacuum vessel. Fig. 1 shows the dependencs) of the flash point
for mixtures
of 2CO + 02 + XH2 at different temperatures, and Fig. 2 the
dependence of
PPO2 on 1/p PH 2 *Herefrom it was possible to determine tan a and
b (pig. 3).
For the conste~nt kjjI, kIII o 1*5,10- 10 exp(-, 12,100+400 ) cm
3.mole-I seo -1
RT
was found. Thore are 3 figures and 11 referenoesi 6 Soviet, I
British, and
1 German,
ASSOCIATIONs Institut khimicheskoy fizikl~ Akademii nauk SSSR
(Institute
of Chemical Physics of the Academy of Sciences, USSR)
SUBMITTEDt February 9, 1960
Card 2/2
30918
S/'195/61/002/003/003/009
'9 E1.11/E130
AUTHORSi Azat3ran, V.V., Voyevodskiy, Ar.V., and Nalbandyan,
A-B~
TITLE: Dete3'mination of the rate constant for the reaction
of atomic oxygen with molecular hydrogen
PERIODICAL: Kine-tika i kataliz, v.2, no.:S, 1961, 340-349
TEXT: The :reaction of atomic oxygen with molecular hydrogen
to give the hydroxyl radical and atomic hydrogen often occurs
in
the oxidation process, sometimes playing an important part.
This
reaction has not been sufficiently studied and there are no
reliable published data on its rate constant. The authors have
used a new method for making this determination. The velocity
constants were measured by observing the flame boundaries in
the
burning of carbon monoxide in the presence of varying small
concentrations of hydrogen. A conventional type of reaction
apparatus was used, but it was found that the quantities
reacting
could be increased by coating the walls of the reaction
chamber.
NaCl and KC1 coatings gave a several-fold increase, but ~JgO
gave
an increase of about fifty times, and therefore all work was
done
with magnesia-coated chambers, since much sharper flame-edge
Card 1/ 4
30918
S/195/61/002/003/003/009
Determination of the reaction ... Elll/E130
-,Confirmation of the correctness of the approach used was obtained
by independent calculations using diffusion in coefficient values.
The*rate-constant values for the reaction 0 4' H2 =: Oil + It was
found to be 1.11 x 10- 10 e - 11700/11T
and'for It + 02 = Oil 01 1.30 X 10 10e - l5qOO/R'r
3 -I -I
cm ,molecule .sec
L.I. Abramenko, R.V. Lorentso, V.N. Kondratyev and N.S. Yeni-
kolopyan are mentioned for their contributioils in this field.
There are 8 figures, '3 tables and 30 refoi,encos: 13 Soviet-bloc,
I Russian translation from non-Soviet publication, I English VIK
translation from a Soviet authors and 15 non-Sovict-bloc.
The four most recent English language references read as followst
Ref.20: D.R. Warren, Trans. Faraday Soc., v-53, 199, 1957.
llef.21, D.11. Warren, Trans., Faraday Soc., v-53% 2o6j 1957.
Ref. 22: - I. G. Greaves, J. W. Linnet, Trans. Faraday Soc. , v. 54
1323, 1958.
Ref.29- P. Gray, Trnn.s. Faraday Soc v. 55, 408, 1959-
Card 3/11
AZATYA AKOPYANp L.A.; NALBAVDYAN, A.B.
Electron para-mgnetic resonance metbod used for detecting
atomic hydrogen in a rarefied flame of a moist mb-ture of
CO and 02, Kin.i kat. 2 no.6:940-94-1 W-D 161. (MIRA 14:12)
1. Imstitut khimicheskoy fiziki AN SOSSR.
(Hydrogen-Spectra) (Carbon monoxide)
(oxygen)
S/02 61/139/C-05/016/021
131 03YB220
AUTHORS: Gorban' N. 1. Azatyan, V. 11.9 and Nalbandyan, A. B.
T I T L Determination of the recombination coefficient of oxygen
atoms
on the surface of quartz oovored by potasaium tetraborate
PERIODICAL: Akademiye, nauk SSSR- Dokladj, v. 139, no. 51 1961,
1141-1144
TEXT-_ A new method of determining the reco:nbination coefficient of
oxygen
atoms is suggested, since the methods used go far (W. V. Smith, J.
Chem.
Phys~, 1-10 3' 110 (1943); J. W. Linnet, Tra-is. Farad. Soc-,.~2, 8,
1323
(195 ).and others) are inadequate. The authors selected a system in
which
-the concentration of 0 atoms is at least normensurable with that of
H atoms
to study the effectivity of heterogeneous rocombination of oxygen
atoms
by measuring the inflammatiRn limits. In such a system, the branching
process of the chains should be dependent oa the reaction rate of
atomic
-oxygen. Such a system with a well-known reaction mechanism is the
low-
temperature combustion of GO in the presenco of small admixtures of
H The `Olt
2; ~_"F
authors present the following equation for -he mechanism of this
reac ion
'in t`ip neighborhDod of the first inflammation limit:
.Cal -1 1/6
rd
,/61/1139/005/0161,121
S/020
Determination of the recombination ... B103/B220
pCO T/2k,,-1C,19](1 + k T 19. pCO (2). If reactions (IV) and (V)
02 - [k4 - 5 N-10 R2
proceed in the kinetic range, it follows from (2) that the
dependen'~e of
pCO on I/pCO at constant temperature is linear. The straight line
02 H? 19 1
representing this function cuts the ordinate in: b - k T/---k -10
Here, t-ana i. (k T/2k 1 C1 JQ 4 2
010 ')[(kT/k '10 ')k3 W is valid. Thus, it is
4 2 3
possible to determine tana and b by measuring the:initial.
inflammation limits
of CO-O mixtires (with small admixtures if q,,, ai various
temperatures.
2 1
Based on the known value of k 3v k 5 car be determined from (4).
The
coefficient (,E0) is :Ierived from k 5 0vo/d (5), where v0 is the
thermal
velocity of 0 atomaj and. d Is the diameter of the vessel. if j 0
0e-E5/RT
in the temperature range studied, the eqliation
log tana/bTl.5 _ og k 0/k 0.-'019 -j (E E )/2.3RT (6) can easily
be derived
5 3 3 5
Card 3/6
S/02 61,/1,39/005/016/02'1'
Determination of the recombination B103YV220
surface condition prove that (IV) and (V) tak,~ place in the
kinetic range.
Since
k4/2k 2 - [011' where [Of 2 is the 02 concent.ration at the first
inflammatiort
limit of the H 0 mixture, the right side of Eq. (3) may be replaced
by
H2 2 2
PO2 T, a means tnat the section which is --u-, off by the straight
lire
PCO-1/pCO cn the ordinate equals the partial prRasure of oxygen at
tho first
2 R2
inflammatior limit of a H '0 mixture. The correctness of Eq. was
found
2 2 Co C
graphically owing to the dependence cf p on I/P 0 and nonfirmed
02 Ho
experimentally, The value of E 3-E5 was caliulated from the slope
of the
straight line on the basia of (6) and is 5.6 0.2 kl,al/tmole. Since
E a
3
1 1 -7 1 0.7 kcal/mo:,e , E6. .0 kcal/mo-' k.. On the basis of (6)
~Lnd (7)
E0 war, oalcu2ated !'rom and k 1.1-i0- /m~Aetn~la,sez- and was
0 3
Card 5/6
S1020161/13910G510161021
Determination of the recombirazior B-.03/n220
2 1
'oriBequently, E0 A5-10-" '00 !OOO)'/RT
1.65'10- sec C, e'(6 sclo ,~ i n,
the temperature range studied,. ~, (recombination coefficient of
H 4-.~z5 cr,
the'wall of the vessel) was calculated fr3m the graphically
obtained vali~as
of b and from-k 2 ~y using an equation analogous to (5):
6H . 9-10-14L, (5400 -, 10001/RT values Ire in good agreement
I .. The latier
with those of A~ & Nal.bandyan and. 8, M. Shubina, (ZhFKY., 2.0,
1249 (1946';i
and N. N. Samenov (0 riekotorykh problemakii khimiQheskoy
kilr~,3'.-,Kll i
reaktaionnoy sposobnr)at! (Some proKems of ,chemical kinet.13s
and r,?a-.t!v1-'Y).9
Izd. AN SSSR, '958)). There aze 3 figures and 16 referen:~es: 9
S.~-.iet
and 7 non-Soviet.
ASSOCIATION: InstJ.t-,z-. khimiaheakoy fi3iki Akademii nauk SSSR
(I-Ist.1tute of
Chemical Physics of tiie Academy of Sciences USSR)
PRESENTED: March 30, 1961 by V. "., Kondratlyev, A-~.demlician
SUBMITTED: March 25, 1961
Card 616
30031
S / 0 2-0' '61/1AI/00!1/0'6/0-11,
Detect-ion of' oxygen atoms in the ... B1,10/B101
ur, Ito 7,11, of H2, at a volume rate of 82 =5,'min (I
.n,--4ai- rate c4 19 mAsen,)
Ryid a pre,-sure )f 5.5 mm Rg. The temperatitre va-Aed
between 607 and 67,0"'C.
Under conditions, an epr signal of 0 consisting of ono
ocnen~ wu," deeterm'Aned., with a g factor of Tho value of
ihi~
is i, aj~reemi~nt Nvith that publiahed for atc,mic oxygen.
The conientraticii
Cleterminationq of atomic 0 and H were condt,cted Tho de-
ppnL~vnQs of the concentration oT atomic H Fnd 0 -in that of
H LOnta~ned
2
ill I-lie CO - 0. mixture, was also determined at 610'-C. The
mea;ured
I
show thfit, ',-ho -~~ciicentration of 0 atoms is
co;zmensurabAe with !,hat ,A H
atoms, arvi !hat the. two concentrations increase as the H,
-,ontent
2
Thc ratio O/H decreases from 4-5 to 0.9 wit.-i an increase of
the H, con-
~E-Y.t from to 6.,) 16. A temperature incr,~ase from 607 to
6r)OOC at an H,.
~(Jnfsnl of 3,& !,o causes a conoc,ntration in,:rease of
atom-ic 0 and H I r OM
2.91'01 4 to "1.1*10 1.4 oart3cles/CM3, and fro" 4-6'10 14 to
7.6'10 i 4,)a I: t
C I e -R,/ C -,I respectivelly, The results show that the sum
of partiai
C a r d 2,
AZATYAN, V.V.1 AKOPYANp L.A.; IIALBANDYAN, A,B.
Detection of free hydrogen, oxygen, and deuterium atoms
in rarefied
flames of carbon monoxide using the 6lectron
paramagnetic resonance
method. Dokl. AN ArnA SSR 35 no..'4123-128 162. (HIRA
l6s6)
1. Institut khijdcheakoy fitiki AN IIISSR. 2.
Chlen-korrespondent AN
Armyanskoy SSR Oor Nalbandyan).
"(Car-bon monoxide)
(Paramagnetic resonance and relaxation)
N.
-AZATYAN_,__U. '.; NAMANDYAN, A.B.; TSUY PEN-YUANI
[TSIui 14;ng-jian]
Determination of the rate constant of the reaction
betveen
atcmic oxygen and ethane. DAL AN SSSR 147
no.2061-364
N 162. (MIM 15:11)
1. Institut khimicheskoy fiziki AN SSSR.
Predstavleno
alutdomikcm V.N. Korxlratlyevym.
(Ox7gen) (Ethane)
(Chemical reaction, Rate of)
VOLOKHONOVICH, I.Ye.; MARKEVICH, A.M.; KAS-EROVOY,
I.F.; AZATYAN, V.V.
Nonisothermal processets. Thermal cracking of
methane. Dokl.
AN SS3R 146 no.2:38?-390 S 162. (MIRA 15:9)
1. Institut Ichimicheskoy fiziki AN SSSR.
Predstavleno akademikom
N.N. Sernenovym.
(Methane) (Cracking process)
12 7- 3
L
86 6 EIIAIEPRIFCS(t)IEWP(J)IE;Fr(C)IEW'e(41131)SIE.S(s).-2 AeDC/AFFTC/
RPL/pSD/A1PX Paa-4/F1s-4/Pc,-4/Rr-4/Pt-4 Rm/BW/WW/jW
ACCEMION NR% AF3002633 3/017.V63/016/003i'0201/0203
AUTHCIR: Azatyan, 1'. V.; Gerahen7or., Yu. M#
--Nall)andyan,-A.-V,~-,-Tolui-l~en-.Nluan-
TITLE: Discovery of free bydrogen U oxygen atorno in vavaum-flaminq,
of mi7tureg
of carbon monoxide & oxygen in the pronence of Eriall additions of
ethyl,~.nte
SOURM XZ ArmSM-. Izv-. Khimicheskiye nauki, v. 16, no. 3, 196. -203
3, 201
TOPIC TAGSs free 0 atom, free H at=, etbylene, relf-combustion
ABSTIRACT: To verify the meehanism of CO combustiJin the preaence of
0t~i1_e-z1eA'
the concentration of free 0 and H atoms , ~sdet~erMned by elec"rort
pztra~m- ' gnetic
resonance moaa-urement. '.Etlrjlene accelerates 00 combustion and
lourers the limV
of self combustion; the athylene concentration, at which 0 content.is
maxitrim Is
also the concentTatl,on at which the lover self -caftstion Iiialt is
minitum - about
0.2'. 0 and F. cohccntra~, ions increase with etivlil-ne increase (to
abot ~ and
& it 2.
0.4%. respectively) then decrease. ~Increase In 11amperature
increasos'~ content
faster than H conce;trat~,.on. Orig. art. hast I 1~
ag=e aid 8 formulas.
ASSOCIATION: Institut kUmicheskoy Fiziki AN SSSE (Inatitute of
Chemicil-ptiLe-BL-
AN SSSR)
Card
MAMVICIp A.M. (Markovich, A.M.); AZATIAN, V.V. (Azatyan, V.V-1;
SOKOLOVA, N.A.
Ad4bati~-'coiqpression as a resoore*h method of the chemical process
in nonstationary corAitiona. Analele chimie 18 no.20.05-113 AP-J*
163.
'
T.
S125216310361001100 02
D,403/D307
'
AUTHORS:
' V
'B
-A
A
a V
t
Nalb
d~i
C
di
-
., _-
z
samn 4
ark
an-#
.
orrespon
.j
r
01 the., A
of - the -,&Aiaenian'SSR, and -To ui-
eng.-
Vidn
reac.,
Do at 01 o the of the
teimiU f v6
locity con tants
, L
,
of atotm, ~C oxygen vith propane'and~n-butano
tion-
I
PERIODICAL:
-Akedemiya A
rmyaiisk6y--SSR.-Doki~dy-,-,V.-36
v 3-29,
TMT
Thii fi6&,&~ ol
t oped earlier f or the,detemination~
reaotior~s -between--atomic-
W-92
of rate. eqnstarits _in~ n- and - hydrogen
, c
~ the -lower,
'es
entil
:cont n
of measurin
com
ounds
all
nsistin
g-
s
l
o
g
p
g
#
y
limit of comNistion of 001n~o_x
ygenin the prese4ce of the hydrogen
donor was-
and
applied to theroe'etions t. Kt
O~
4 C3H8 = OR 007
'0 Go,
0
robabl'o chanis is discussed.
M
me
.~It:vhs f ound thit,~
C ard, 1/2"
-1-16287-63.-.. FC3 (f MINP 0 )/EFI'(O)/EWP
5~0/9&~,MVBPS An'TC/ASD PC-4/Pr-4
feqlwwlj-D Fw 2 149/005/011/018
ATUHCR: A=tyan,mv. V., Nalband~n,.:.i, A. B.; and,; To lui Meng-Yii--a
TITLE: De"IerpUnation of reaction! rate constarts when atomic
LL-rogen ancl
oxygen rimet vith ethyleno
P.nIODICAL- Xlcacllemm ytt nv.W~. SSSR. Doklad v. 149 no. 5, 1963,
1095-IU98
T.l*,X'T* The authors -nvesti&-ite the reaction rate iconstants for
reac"4ons of
atomic hydroC;en and Oxygen with et thylone in the temperature range
5'[0-60oOC on
the basis of :-.,.ea surer tents of the initLal liipdts of
spontancoils ioiition of
:,-J.mtures and ruxtures of carbon moroxide with oxyGen in the
presenca of small am--imts of ethylene. They determine st E- r- 7,200
cal. the
activation energy of the reaction of e~tovic h,~droGm with ethylene,
ftn6ina it
~tc differ c3nsilderably from the corresponding valu,~,, obtained at
lower tempera-
tures. Ev.-Ldently, at hiG'h tempereturres the mechanlsm of
interact'-on changes.
For vhile at 1-014 tenzeratures t1he nrL-3.omInatirS reaction is that
of the com-
bination of atomic h)~drogen with ethyle-ic, at low i'.ernperat Cs
lho lZedominating
r
reaction is -,.",at leading to the foimatf-on of vinyl radical and.
molecular hydro-'
gen. Th~-~, actIvation energy at low temporatureG for the m ction
o4L-* at*o-mic
oxygen with c-thylene also is much lower than that obtained~=y the
aut:,.ors- There
are 3 fi6'Iwcs-
ASSIOMIT10j,',~: Tnstitut khimicheskoy flziki Akaclemii nauk SSSR
Institute of
............
Ca:,,d 1/21
AZATYAN, V.V.; GERSHENZON, Yu.M.; NALBANDYAN:, A.B.; STUY-PEN-YUAN'
Detection of free hydrogen and oxygett atoms in a rarefied flame of
carbon monoxide and oxygen mixtures In the presence of amall amounts
of ethylena additions. Izv. AN Arm.S.11R. Xhim.nauki. 16 no-31201-203
163. (MRA 17:5)
1. Institut khimicheskoy fiziki AN SSSR.
AZATYAN, V.V.; KALBANDYAN, A.B.; UY MEII-YUAIV (TS'ui
Mgng-y~anj
Determination of the rate constants of the reactions of
atomic
oxygen vith propane and n-butane. Dokl. AN Am. SSR 36 no.l-.
23-29 163. (MIRA 17:1)
1. Institut khimicheskoy fiziki AN SSSR. 2.
Chlen-korrespondent
All Amyunskoy SSR (for Halbandyan).
AZATYAN, V.V.; NALBANDYAN9 A*B,,; TSUY H&li--YUAN'
[TS'ui Meng-yuan]
Determination at the rate constant oi the resation
of atomic
oxygen with methane. Kln. i kat, 5 no.W01-210 Mr-Ap
164.
(MM
1, Institut khimicheakay fixiki AN SSSR,
-65 M'F(o )/.;~ZIQ )/.gIT (ra) Pc-4/Pr-4 PTL Tin/ 1w/
j
ACCESSION 7M. AN-00383 5/0ri'1/64/017/002/0LL7/0j2j
AUMOR: Azatyan,-Y. V.,* llnlbanaYan, .61' lakhtaryt4, N. T
TITIZ: Investigation of th ~~f atvmic crAygen and J~Vdrogea v;tth
e reaMo-,L
prolrylene
SCURCS: rMwn. Izvestiya, NhirticbeoMyo jmuki v- 17, no. 2., 1!~64,
117-121
MPIC TAGS: oxygea propy1ene reacition, hydropgn propyleno ivarction,,
:rtnetion
'rate, rate constant) MUCA1 f0ITMiUn, cmbust:~Cn limit method,
cumb.otion rechvi-
nism
ABSIMM Reactioiw of atomic oxy$,,en ana hydrogen vith propy1cne merit
investigated
by tbe, c4ombivtion UAA-tii tathod. The follwing equatioas reiavoont
tho Mechanism
Jf 00 combustion u1i 1w pressures In the yrezence of propjluv:
OR + CO a C-02 + H iii
R + 02 '1 OR + 0 2
0 + VP6 OR + 039
Card
7 ME
-7..L
L 23942-65
A=WXON HR: AP4030383
A + vall v texz=ti1,Dn
0 + vall- ip terzd ti n 5j
a + C3A6 22 + C3~5 63
11+0 34- 'h 66
11,0 +
'0~ -00:R, + c u 3
+
H + C#6 6&~
C395
H + 0-~96 CA 6b
On incressing the amunt of pvpylene in the 2CO + 02 mixture the ignition limit
is reduced,, indicating reacti-,= 31 awl 1. UM a f~ztber L'ItTesse In
propy."Lena
t-be Undt is raised, showing reacti~= of hydroge-xi with pa~opylom-e to foTM
b-Aza
active radica,12 ~relwtlonj) 6" and The )T-ef~curv (P, of' t.t-p- jpEu
mAxture fo-
2/4
ppo. (KO T2..N U., 4- 14~, " .1 1. , -
+ 0-Y
Ir 1-2K.
vbere Y, ure the ral;e cirnstants for the respective reactlow, and 1b2 and
PIC-,~16 axe the Yartilk! Pmzsuyes Or C-2 and proyylvne- Thit equation
fox the li~r",r
igUtlca Unit during the cordbustim of 00 in thi, presence of -projo-lena:
Pco Piro (KO 71.5 T2,;
+ 10"K, .01llPcUPcjjl(~
ytp~opf;o. 10*
wvl~ -
Tho roU eonstauts fm eq%zatlv,6s 31 ~zd 6 for ptv,%.fleno at NAXIO ve:re.-
Card 3/4
a mn
~R
1, 213/94?-65
ACCEMS1011 NH: AAD.30383
X13 a 1.2 x 10-3-1., K6 so 4.& X 10-13 CM3 Doliec-1 CCC-1- The
rtaction rates of
oxygen and of bydroir n Y.1-th proirflone are futer thm with ethylene.
Orig. art
Se v
bas: 3 Iligures azA 14 equittions.
ASSOCIAVION; lusUitub- M1412' akqy-fizlkl~ An. VOR (lustitutv of
Chemital- Bi-ca
e
AZATYAJ4, V.V.; NALBAIJDYA14, A.B., akademik;
0GAN&SYMI, K.T.
Reaction between oxygen atoms tuid viothyl
alcohol. Dokl. AN
SSSR 157 n0-4:930-933 Ag 161+ (MiiiA 17:8)
1. Institut khi-michesRoy fiziki AS SSSR- 2, AN
ArmSSR (for
Vlalbdwdyar~.
ox
L 2141~- 5 EWT(M)j41PF(jC)A~VP'J) ft-4/Pr.,4--R
Nil- AP-10415104 S/001.tO/64 1,156 C01/0!790181
AUTHOiR _B.(Ac&k1emieia11 AN Am-S-W.)-
7 V..; Nalban
Jb dy.
-TITLE_Discovery ofatornic oxygen in the -cold flilme oxidation of
carbon di.sul-
'fide by inolecular mc,~gen
SOURCEO: AN SSSR, :Doklady* v. ~.no. -1 1964, 179-181
TOPIC, disulfide. -gen, 61d flame oxid
ation atoinid
WS: carbo, 4t mic(oxy
D_
P~
P r ation, lo~v tem -ratt)re-combustion., VPR spectra
-ABSTRACT:_ Th 0
e 1-0t temperature cornbustion reg, tion of carbon- disialfI6 *It-h-_
Molecular waif subjected to ET,R studies to [determine the fa rmati'On
of,
atomic oxygen and tho deoendence of its con6entra~*,ion on-reaction-
condition-s-. in-
0. 8-14 (v~=[O
reuc ions run with ot 2,fQS23) at 2(19-271C under 5-6
pressure, the EPR signal for atomic oxygena ppeared atot b2. 5. In
rew.,Aions at
-370C, no atomic oxj, en was formed Jat 2. 2; s~tomic oxygen formation
start
9
ed az cx 2.2- 2. 5 and its 0-oncentration Increask: with Iner,ease
ina, to ii -Oaxi-
2 1/2
d-_
L 21415.65,
ES N NRi. -AP4Q45l04`:,
CC SID
A
bt cz
mum-InAe -L --rajige, tindLthen-,d,6i
-
.rtttse-d.~:-Wtl,
n-,mblec~llar-hy4ri~geii~ i as
adze d to
1he CS + 02 i'mixti re; the EP
2
R signals fo;4 atomic "c hydr -4
oxygen atom
L o
r e-re ident
.::-gen and hydroxyl ra&~als ifj
,
.
!ledo 0
-H H + OH. Addii-ion-vof '570.(0n
molecular-,
oxygen t,
tion" of mO
'
1ecular-bydrbgen..-e_duc _d
e atoxhic-.oxygen... 4
concentr4tion 3 timesi
m ';!
The:
eoncentra J
t
! 'f CS radicals
on 0 was the revcirse]:ot the
atomic oj~ygen concenl
ration: rCSJ
incii-eased as o -idecreased below 2. 5, ~~nd CS
.
-~-disappeaP datq72.
e 5 ii
s [0.14ricre as-e'- -d
-Orig.- 'airt.-',
~has: -3, figures -
OCIATIOW
Ins
i
, cheskoy fi
na*
Ilk
l~iki Akadev qSSR-(Instituie "of Chem-
it~ al Physics,Acad6rny~!
--- ---
of Sci4mces SSS~)
SUBMIT TD: O6Apr64
J
N,b- 00 -SUB
COD13: G
C
Tim ~'RE F sov: 006
0 RER: 0 17
i 7~
212
CW4
W
0 (m IETV, 0q)
SOURCE WDE: Bib-,~-51 -6-IFO
ACC NR
6 7/0(12/0362/0363
AMOR: 44'. V 'V
1j)'$1 t j t,-'kbiMir
ch6skoy Wzik
T1 111r. ne Ye
act, or%,the UK
'vtud 6f Lias e te a
S 011 RCE Kinet-3 `2:~p -l9~
-363-
11~
TOPIC TAGS 0: us V on U am s L ud v electron p a i atna gne t i
cresonance, propulaion
ABSTRACT: r A n16%4 typ)~' oIf reaction vesael is propo4:ed.for the
study of rarefied flameis
by the electron para *nagnetic resonance method. Tl~e application of
this vessel type
makes it possible to lower substantially.the flaul(I pressure, and
thus improve the
resolution of Ithe sp,~ctral lines. A apecial heati.ng system for the
vessel enables
the flame to be located in the resonator zone of the spectrometer
during measurements
of EPR signals determined by magnetic as well as clectrical-dipole
transitions.
Experinvtnts were conducted with mixtures of carbori disulfide and
oxygen containing
small mriounts (up to 10%) of hydrogen, When the tipper part of the
vessel was heated
to 400C, it was possIble to maintain a flame at 0, 3-0.4 mm, instead
of 2-3 min.
Card 1/2 UDC: 542.2:662.611
---L 22059-66-
ACC NRt AP6013354
b"
-Fig. 1. Reaction vessel with the Fi g. 2. a upper cover assembly
(1) and re-
upper resonator cover action vesse't (2) with a wide upper section;
b - with heating in the wide section:
I - narrow, heated section; 1 - platinum wire; 2 capillaries
2 - wide sectioa located in the
resonator; 3 upper cover
When the platinum wire heater was activated, the flame entered the
resonator cavity,
increasing the signal strength by a factor of 2-1. Orig. art. has: 2
figures. [VS]
SUB ODDE; 21/ SUBMDATE: 23Aug65/ ORIG REF: 1)04/ OTH REF.- 0021 tTD
PRESS:
Card 2 / 2
ACC NRj AP601168E; SOURCE COD
AUTHOR: Azatyan, V. V. (Candidate of chemical sciences);
3~44andyan, A. 11. (Academiciai
AN Armh77---~. SW
ORG: none J6
19
TITLE: Determination of the rate constants of elementary
reactions by the flammability
limit method
SOURCE: Vsesoyuznoye Ichimicheskoye obsVv2hestvc~. Zhurnal, v.
11, no. 2, 1906, 162-168
TOPIC TAGS: chemical reaction. reaction rate, reaction
mechanism, flammability limit
ABSTRACT: In this article tho authors survey anddiscuss various
methods of determining
the rate constants of elementary reactions. Using 1ho method of
flammability limits, the
authors state that at the flammability limit the differential
equations describing the change
of concentrations of the reaction components can be reduced to
algebraic equations describ-
ing the boundaries of the region of chain combustion. By the
simultaneous solution of these
equations with the use of the values of the limiting
concentrations of the starting substances
it is proposed to determine the rate constants of tho reactioqs
pqrticipating in the competition
Card 1/2 UDC: 541.036
L 34042-66 EWT(m)/Z9PQ)?~E 1~~611!VJWD VE ~!
ACC NR. AP6019532 SOURCE: CODE: UR/0020/f.6/168/004/0851/0853
AUTHOR: Gershenzon, Yu. M.; Glebova, 0. N.: Azatvan' V. V.;
Balakhnin, P.;
-NalbandvZ A. B. (Academician AN ArmSSRF
ORG: Institute of Chem -cal Physics,Academy of Eciences SSSR
(Institut khimicheskoy
fiziki Akademii nauk SSSR)
TITLE: Detection of the OH by the EPR method in the rarefied
flame of carbon
monoxide in the presence of small amounts of hydrogen
SOURCE: AN SSSR. Doklady, v. 168, no. 4, 1966, 851-853
TOPIC TAGS: carbort monoxide combustion, carbon monoxide flame,
hydrogen donor,
hydroxyl radical, 1:PR method 3
ABSTRACT: The basic processes of the propagation and branching
of combustion of CO
in the presence of a small amount of 112 are the following:
~CO + OH COs +,If; (1)
it + 02 Oil + 0'.
0 +11l -*OII+Ho
L 34042-66
W6_CWk~ AP6619532
For small amounts of 11 reaction (III) is rate determining.
Earlier, the EPR
method was applied to ieltect noticeable concentrations of
oxygen and hydrogen atoms
in the rarified CO flame in the presence of hydrogen donors
Stich as H2, CH4, CP4,
H20, etc. For direct detection and determination of all three
active species, i.e.,
hydrogen and oxygen atoms and the OR radical, the absorption
cell was specially Mide
to fit completely into the space in the resonator and was
placed in close proximity
to the reaction furnace. Measurement of the absolute
concentrations of OR radicals
was made with respect to molecular oxygen according to the
formula:
Noll IV Q01I.L.
0. q- -
0. 1.
where N is the concentration; Q is the numerical coefficient
varying with the absorp-
tion bands, e.g., ranging from 40 to 200 for oxygen; and f+ and
1+ are the space
factors for the magnetic and the electric fields,
respectively.. The results of the
measurements are given ir the form of two graphs which indicate
the dependence of the
concentrations of active ;enters on the time of contact and the
amount of added H2.
Card
34042-66
ACC NRt AP6019532
detemining step. The OR concentration is the amallest because
the rate constant
of reaction (I) is.the largest. Orig. art. has: 2 figures.,.
(BNJI
SUB CODE: 21, 07 SUBM DATE: 30Aug65/ ORIG REF% 009/ OTH REF: 008/
ATD PRESS: 6'0/4~
4/4--,r
USSR / Human and 4nimal llorpholopy, Normal and
Pritho- s'
T Sys tim
logic -- Cardiovascull
hbs Jour: ll,f Zhur-Blol., Ho 13, 1956, 59859
-Author : Dzhagaryzn, A. D. and
Inst : Not givcjn
TitlQ : Exporimontal Mod,l of Ccarctition of thv lmrta
with Botallo's Duct Opuri
Orig Pub: Ekspurim. khirurgiya, 1~)56, No 6, 13-16
Abstract; Thu thoracic cavity vis op~,nud in 12 dogs
7nd th,
.7o:.nta trans,,;ci;Qd at thc. aortic isthmus. TIx
onds
of thu aort,~ ivtr~.; t,i,,.;n .-orincetud with a
tubot I-Illi-
n,h hid a branch tub~~ connjeting with tlik~ pulmon-
ary artQry. For cocirctation of th, norta nbov,~ tho
orificu of Botallo's duct, thQ constrict,~d portion
Ccrd 1/2
ALUMV, G.A.; AZAY11V, S.S.
S161-areatu-res -o-f-peat- type Bolls of the Alpine
sore.
W.A. AN Azerb. SSR 5 no.5:407-kiO '59. (MIRA 12:8)
(Shakhdi~g Mountain,--Peat soils)
ACCESSION NRI, AR4023763 0/0274/64/000/001A068/A068
SOURCE# RM Radiotekhnika L *L*ktrosvY,w'j, Abe# IM39
AUTHOR: Azazyan, A* A,
TITLEt New methoi of constructing a pulso generator with delayed
feedback
CITED SOURCEs Tr. In-ta kibernetiki. A07 (',ruzSSR, v. 1, 1963,
137-141
TOPIC TAGS: pulse generator, nanosecond pulse generator,
delayed
feedback generator, delay line, multiple reflections in line
TRANSLATION: A now method is described fc,r constructing a
nanosecond
pulse delayed-feedback generator differing in the fact that ~he
delay--
line employed is it line segment shorted on. one end. In-addition to
delayed feedback, there direct positive feedback is unavoidably I
realized in the cjonerator and contributes to the formation of steep
Card 1/2
ACCESSION NRt AR4023763
pulses. 'The pulsix travels along the line four times each period
and reverses polaxity twice when it is reflected from the short-
circuited end. The effective utilization of the reflections of the
pulse in the line makes it possible to reduce the delay-line length
to one-quarter. Bibliography, 4 titles* (From the author's
isummary)'..
DATE ACQs Mar6dl SUB CODEt GE, SD ENCL3 00
Card 2/2
WORAledicino - Literatwe mar 49
VAdiefte - rood Poisoning
01 "Berviev of Book, 'Problms of the
Etiopathoa-ensis of
Food Poisonings andthe Pathogenic
Slgaifleance of
344 Bwteria of the Colonic Grorp, I Bdite?.
by Profebsoft.
a.- A.- ftb~. ~ 3orkigU AmdM7ib;f
Xm1cal SelAmcab U3ML abd
Azb;2ev, li
i San" No 3
A:u=ber of chapters of this 108-page collec
tizaitt,
discuss pathogenic significance of Intes I
,:Lli.
Points out certain shortce-Ings. Sections
include
"T=ic Effects of Foods Contaminated by
Intestinal.
59/49T40 t
UWR/Uedicine - Ilterature (Coritd) Mar 49
Type B. Coll. Mutabile," and "The
Characteristics
and. Peculiarities of Food Poisoning During
the .
Siege of Leningrad." Considers the
collection an
Intensive and very productive work based on
the
activity of the Leningrad Hygiene and
Sanitation
V-aA.
A" ~.
'4'AiW
AZBEL'p A.G.; BURLOIVA, L.Ya.; LEBOLVA, A.F.
Some palliative measures to reduce the harmful
affect of
the iribration of blanking and stamping hanimer-dies
on workera
bodias. Trudy LSGMI 75:125-131 163. (MIRA 17:4)
1. KILfedra gigiyeny truda. s klinikoy
profe,ssionallnykh
zabo',.evaniy (zav. kafodroy - prof. Ye.TS.
Andreyeva -
Galanina) Leningradskogo sanitarno-gigiyenichoskogo
ine-
dits-*.nskogo instituta.
BYKOVAJO N.K.1 -A-Z~Ul, A.Ya.
~tratlgraphic correlation of Haihop sediments in
the Buzachi
Penirsula based on foraminifers. -Trudy VNIGRI
no.1903375
397 162. (MIRA 1611)
(Buzachi Penineula-Geology,j Stratigraphic)
(kzachi Peninsula-Foraninifera, Yossil)
MILO, B.; 11TVISM, V.L.
lor speeding up housing constructioa. Sote.trud
n0-11-101-107
11 '57. (KIRA 10:12)
1. Nachallnik sektorm oreanizateli -mida TSentrallnogo
normatlyno-
lealstovatellakogo byuro Glavmoastroyri (for Asball). 2.
lachallulk
Rostovskogo oblastnogo upravlaniya ct,,-ovmaterialov pri
oblispolkotas
(for laitvishko).
(ConstraWon Industry)
AZBEL, B., inth.; TUTOV, P., inzh.
-. -1- i
-general construction brigades should work in three
shifts. Ila stroi.
Moak. 1 no.4:24-26 Ap '58. (MIRA 11:9)
(Moncow-Building)
SHAMSHANOVICH, I,, insh.; AEBIL', B., Inth.
New system of wages for workers eagaged in installinge,
the electric
wiring. ITa otroi. Most. I no.8:20--21 Ag '58. (MIRA
11;10)
(Wapi)
KA7A IN, V.. :Inzh.: AZBELI. B.. inzh.
Pay witgas to t )r crano oporators accordirg to a
pince-rate
system. Na atroi.Mosk. 1 no.9:22-23 S 158. (MIRA
11f12)
(wages)
1 7 - , - ~-r 1-11 gt=W~!L~
AZESLI izh.; DIVAN, D.
General construction brigades and construction vith bricks
taken
directly from trucks. Zhil. stroi. no,5'.Zl-23 '59.
(MIRA 12:8)
I.TSeintralluoye nauchno-iseledovatollskoye byurc Moestroy,
(for.Azbell).
2.Ste,rahiy proizvoditall rabot atroitellnogo uchastlca NO.6
tresta
Mosstroy No.1 (for Dikman).
(Building, Brick)
AZBEL I,_. Boris.. &ievywich"psh. I RCOALISKIY, Doi-is
lzrailevich, insh.;
-9- .1011A, L.I., red.1 PEREDERlY, S.F., tekhri. red.
(Training assemblers and zrasons in advanced work
methods) Obuchenie
montassluilkov i kamenohchikov peredovym metodam truda.
Moskva, Vses.
uebabno-pedagog. izd-vo Proftekhizdat, 1961. 141 p.
(MIRA 14:10)
(Building)
AZBELI, B.M.
[Advanced forms of organization of work in
constructionlFere-
dovyo forvq organizateii truda v stroitellstve.
Foakva.. Gos-
stro:lizdat, 1961. 31 p. WIRA 15:7)
(Construction industry-Production methods)
i - FEDOTYCHEVA, O.S.; BERSHINKIY, A.Kh.P
B.M.; MINDLIN, B.B.,
kind. tekhn. nauk; SHIHNOV, B.L., karid. tekhn. wuk;
PEMOVA,
V.V.0 rDd. izd-va; NAUMOVA, G.D., tel:hn. red.
[Recommendations on the development and utilizat.lon
of standard
calculations for piecework assignments in
cozistriiction of apart-
ment ho-ises according to standard
plans]Rekomendittaii po razra-
botke i primeneniiu tipovy~h kaillculJatsii dlia
akkordrWkh na-
riadov pri stroitellstve zhilylch zdardi po tipov.,mi
pi-ocktam. Mo-
skva, GDsatroiizdat, 1962. 129 p. (MIRA 15:12)
1. Akaderdya stroitellstva i arkhitektury SSSR.
Hnstitut ekonomi-
ki stroltellstva. TSentrallnoye
normstivno-issleclovatellskoye
byuro. Z. TSontrallnoye normativno-iEsledovatelInkoye
byuro Insti-
tuta ek,)nomi),i stroitolistva Alkademil
stroited'alma i arkhitektury
SSSR (for Azboll, Mindlin) Fedotyche-va). 3.
Vaucimo-issledovatell-
skiy in5titut ekonomiki stroitellstva (Bershidsk-'~v,
Smirnov).
(Piecework) (Arartnient houties)
NOVIK, M.G. (Novosibirsk, Akademicheskaya u1., d.2-b,
kv.2); FROFILOV, GJJ.;
SHERD'JKALOVA, L.F.; AZBELI, D.I.
Clinical aspects of anesthesia in tronchial. emuninations.
Vest. khir.
92 no.,3:116-121 Mr 164. (MIRA 17:22)
1. Iz anesteziologicheskogo otdeleniya (zav. -
Ye.I.Stadnikova),
legochnogo otdoleniya (zav. - dotsent M.I.Perellman) i
laboratorii
klint-zheakay fiziologii (zav. - T.S.Vinog -.dova)
Institute. ekspari-
mentallnoy biologiil i meditsiny (dir. - prof.
'le.N.Meshalkin)
Sibirskogo otdeleniya AN SSSR.
WICIMPETIL I NT(OVt
14.111 kand. takhn. naukl AZBFLl, D.I., insh.
ralcula-l.ion of the effectiYaness of the isprovement of heat
networks.
..'Mek. ata 36 ro.6t4l-44 Je t65. (MIRA 18%7)
82775
SOV/184-59-5-2/17
AUTHOR: Azbel', D.S., Engineer
Tl=: The Mechanism of Ebtrainment of Liquids In Columns Under
Conditions
of Frothing
PERIODICAL: Khimicheskoye mashinostrDeniye,, 1959, Nr. 5*,, pp. 4-6
(USSR)
ABSTRACT: The mechanism of the entrainment of liquids in
rectification and
absorption columns is discussed. The work of V.G. Gleym (Ref. 1)
and other authors in this field is mentioned. The attemDts of ex-
plaining the entrainment In industrial equipment by thesc called
"bubbling conditions" are not suitable, since the latter are not
characteristic of plate-type columns. Research carried out by the
Kal' 'edra protsessov I apparatov MIKhMa (Department of Processes and
Apparatuses of MIMiM) shows that the even work of a sieve plate
colnoides with the beginning of frothing and that the most effective
work is characteri,,,ed by a wash-out of the upper froth border. 'The
author discusses the mechanism of entrainment in detail. A bubblo
osoillates after arriving at the liquid surface which reaults In
volume oscillationo of the gas Inside the bubble. For simpl1fic-ation
it Is assumed that the gas ozz;illates within a solid, :spherical
Caril 1/4 shloxll, The theory of such oscillations has been
developed by
82775
sov/i84.59-5-2/17
The Mechanism of Kntrainment of Liquids in Columns Under
Conditions of FrothLig
Rayleigh (Ref. 2). The liquid flowing off forms a slightly
curved
liquid membrane In the upper part of the bubble cupcla. The
radius r of this membrane is equal to or smaller than the
radius of
the bubble R. This membrane will oscillate in any case under
the
influence of the volume oscilla.tions of the gas in the
bubble. If
t.'ne natural frequency of Uhe membrane coincides with the
frequency
of volume oscillations of.the gas, a resonance phenomenon
results,
and the membrane cillapses, producing the micronlo component
of
entrainment (Ref. 7 and 9). The lowest frequency of the
volume
oncillations of the gas is Ci 01,;:-4404 Cc The free
oscillations
of a plane membrane fixed at the circ~m`Fe~ence are
204
ro
where CO velocitir of sound; r() - radius of the membrane;
0'- sur-
fa.ce ten ion; Sp. h - surface density; P1 - density of the
liquid;
h - thi:kness o nembrane. Tho resonAce and consequently the
destruction of the film occurs at (j- &.1 . The total volume
of the
entrained liquid in determined 1'rom the volume of' the film
of one
Card 2/ 4 bubble at the moment of destruction x
82775
so-v/i84-59-5-2/17
The Mechanism of Entrainment of Liquids in Columns Under
Conditions of Frothing
Vr 2 h 2 4 ) 2 R2 (1)
0 VWj T--.
JP I - 0
and the average number of bubbles bursting in a second,
WF
T5-XR-57- (2)
where F free croms-section of the column, W - velocity of gas
In
cm/sec. The total volume of th4t entrainment is'Q V (3)
or, after substituting the value from equations (1) and (2)
Q 2 R2 WF Y, "1 (4)
4/3 Ir R-"
where K 0,297 P1 0 2!
C
V - WF. 71
Tho equation (4) applied to the conditions of frothing gives
for
tho entrainment Q 62v1 0,297 V.
Card 3/4 P I Co'
82775
SOV/04-59-5-2/17
The Mechanism of Entrainment of Liquids in Ckilumns Under
Conditions of Frothing
Observations show that the radius of bubbles reaches under
condi-
ticna of frothing approximately 1 om. Thus the entrainment is
insignificant (it consists of adcronic drops) and can be
neglected.
Also larger drops originating Jn the depth of the fluid break
through the froth. However, crtly few drops penetrate
through the
froth barrier into the free, inter-plate spaca. The larger
drops
loose a good deal of their kinotic energy. It was found that
the
larger drops do not rise higher than 5-1 cm above the upper
froth
boundary and do not reach the next plate. There are I
diagram and
9 references: _3 Soviet, I German and 5 English.
ELBSTRACTERIS WOTEs Subscripts 1 (liquid) and f (film) are
translations Of the original W (zhidkost') andIn (plenkaj
card 4/4
Al"'BEL I f DC';O
Mcxleling of the processes of liquid-phaeo oxiCation of
KbI.m. prom. 40 no.9:689-693 13, 164. 0'411M 17:11)
I
otZB. V , J-
Investigation of the entrainment process in sieve-olate
columns.
ajii.nash. no.6:14-21 V-D 160. (MUU 13:11)
(Plate towers)
AZBEL', D. S.
Cand Tech Scl - (diss) "Study of the wearing away process in columns
with screen plates." Moscow, 1961. 4 pp of diagrams; (Ministry
of Higher ani Secondary Specialist Education RSFSR, Mcr-cow Order
of Lenin Chemical Technology Inst im.?ni D. I. Mendeleyev); 150
copies; price not given; (KL, 6-61 s-jp, 2121)
PlANOVSKIY, Aleks"r Nikolayevich; GUREVICH, Danitil
Abramovich; MMANOV,
N.Lp retoenzent; ROUNKOV, P.G.0 doktor Ukhn. nauk,
prof.., re-
teenzont; PAVLUSHMKO, I.S.,, kand. khim. nauk, dots.p
retsenzent;
PASSM') B.V., kand. khim. nauk,, retsenzent; AZBELI,
D.S., red.;
SHFAK, Ye.G., tekhn. rod.
(Apparatus for the industry of orgmAc intamediate
products and
dyes) Apparatura prouWahlennosti orilanichesldkh
poluproduktav i
krasitelei. Moskvap Goakhimizdat, '.,.961. 504 p.
(RIP-1 15:6)
(Dyes and. dyeing-Appexatus)
(Cherical apparatus)
AZBEL'p D*B*
liydrodynamice of bubbling. Xhim.prom.
no.11:851+-857
N IW. (MIR& 16t2)
(Fluid dynam Lee)
(Plate tovers) (3ubbles)
EWP(
7
Aernwin -
AP.1~
56
YMM. 527-
_
AUVOR::-
"
rrla:
"NOV
bklbb
procassiosk, in lo
~orqj
&a-L Pr4m nOW, ho.,z71, -
wshl~n
64)
Topic -~ksi! lv;ftv"
an, i c-a
sloO bubl
Ij-ng
teri~4d-! y highl
%
i
the aie:',~syer and-byi
llow redpc4~
~
g3n!velpcltl,eb_._
(Fr
VrO~si mted. Thi
e
dize -of
Al
4aj
bublIto i* * 06
bublle,layiei
i
be aVed in udva~nlo,
loAaAer
'~tn
4-- the; gai -Contaut."
d 6,lb.4.rive-d _1 ntroductic
A
liquid-- i Me'reasea
l the- potenti-al
oner f th
-
.Is
4ram s-f err~(l t0 It
Oe ki DOU C eAlk;%7 *,Ft~e _AZ
cend
ing
i I itiuld iitl,owi The
a),labwlc iwterh~~t
on --Wf 41U id a rAl gas
~ lend* i
06t
I~oalebcomte
fttjAD It
of S~s blavlAOSP i
Ns a IM,3ult,of wbich.mRrv ._#
j..ble bi
ibblps
-:fo- bi- --- I- - 41 f
-aro nji!d, in b V 4) ujex:~1-7 Orig. -art. ~a
o~vwlau, 5 snphs.
Cc
L'523314 J
A13
A
P IbI
-
SUBUTTIM.,
"M 00-
ENC
w sbt
-IRS
i 7
A7BEV, D.S.; L.A.
Calculation of brubb1ing-type reactor for the hquld-plia3~-
of hydrocarbons. Khim. Prom- 40 no.12:881-887 D 164.
(MIT-A 16-2)
AZBLL19 Lk
.. ....
1,
.Xorim,dest method3v and technologLeal proluction
synte= a-^ coal
clesuing in Englarid. Koko i khLm,. no.2:55-60 161,
(VI, A 14: ? )
(Groat Britain-Coal preparation)
. . . . . . . . . .
..........
ACC NRt
Kr60334,90 SOURCE CODE: UR/3231/66/000/002/0003/004G
AUTIIOR:, A'zb 1.1 , Z.Ya,,; Yanovskaya, T.B.; Keylis-Borok, V.I.
(Doctor of physico-
mathautati.cal sclonces
ORG: none
TITLE. idcUiod ol conibined interprotation of hodographs and
wnplitudo curves in studies
of thc upper mantla
SOURCE: AN' SSS11. Listitut fiziki Zernli. Vychislkellnaya
seysmologiya, no. 2, 1966.
2~-Iashinnaya interpretatsiya seysmichoskikh voln (Machine
interpretation of seismic waves
13-45
TOPIC TAGS; upper mantle, hodograph, seismic wave, Monte Carlo method
ABSTRACT: The problem of determining, the struc-.ure of the Earth's
tipper mantle from the
hodographs t (&) (if the first few arrivals lacks a unique solution.
This ambiguity may be
t markedly offset, lic-wever, if the amplitude curve A (A) or A* (A)
= log A (A) of direct re-
fracted P waves is also utilized. Travol-time curves which hardly
differ in t (A) may be
characterized by d0ferent A* (A) and analysis of tho latter can
result in a marked reduction
of the set of curves obtained. The following method of solution of
the reciprocal -problem is
i proposed: the sought travel-time curve TTC is paramotricized, i.
o. represented by a Bpecifled
1/2 UDC: 550.34-
ACC NRs AT6033690
function of the parameters. The possible ranges of %rariation
in these parameters, i.e. the
region within which the true travel-time curve existg, are
indicated, and individual TTC are
scanned, on theorelically calculating for each TTC iho data
known from observations. The dis-
crepancy between the computed and observational data then is
calculated. The set of travel-
-time curves for which this discrepancy is sufficiently small
represents the solution C
problem. Thus, the problem reduces to finding the region of the
minimum of multivariato
function (discrepancy between calculations and experiment) in
tho space of unIcnown parameters
of TTC. Finally, the set thus identified must be compactly
described, i. e*. the common
features of all the TTC thus found must be pointed otit. The
determination of the limits of the
paranieters and the selection of the type of the
paranicter-dependent function and the optimal
method of search fo:- the minimum depend on the conditions of
solution of the converse problem
in every particular ease: on the accuraoy of observa:.ional
data, typo of A (A), epicentral
spacing for which t (A) and A (A) are specified, and the nature
of the Imcmn and -UnIcnown i)ara-
meters. Thus, e.g. if constraints are imposed on bcth
velocities (according to t (A)) and volo-
city gradients (according to A (A)), of the methods uved to
search for the minimum the Monte,
iCarlo method proveb to be best. Orig. art. has: 14 figures, 31
formulas, 9 tables.-
!SUB CODE: 08,-t=-Z2, 12/ ~U:W DATE: none/ ORIG REF: 012/ OTH
REF: 003
Card - 2/2,
AZBKLI, 1.1-a.
Organising plant-wide creative work teams In the
amonis ludustry.
Xbim.p.rom. no.23110 Ur 0.54. (NLRA 7:6)
jChemical Industrias)
MUSOTMaY, A.V.; EDZLOV, L.I.; 4&=I, 1. r T T&L W
.A,6; 34ITRIYBV, S.K.; I I
I.G.; TIMONIN, S.T.
Utilizing the heat of oompreesed gas to host boiler
food water.
Suggestion by A.V.Irrasotskiiand olhare.-Prom.anarg.
11 no,4:23-25
Ap '56 a (Waste heat) (Hot-water supply) (KWA 9:7)
I
AMLI_ 0 10 &alinogorsk)
?i *
Aohievements of Stalinogorsk elsmints. XTO no.11:60
N 159. (HI" 13W
1, Predesdatell sovet& pervichnoy organizateli
khimicheskogo
obahchestva imeal D.IsMandeleyeva,
(Stalinogorek-(*ohemioala-Xtnufactilre and
inditstry)
AZBEL' I, I Oyttf
Stal.inogorsk Chemical Combine. Khim. v shkole 16
no.4:36-46
ji-its 161. (MIRA 1418)
1. hachal'nik tsentrallnoy zavodsi-oy laboratorii
Stalinogor3kogo
khimicheskogo kombinata.
(Stallnogorsk-Cliemical industry)
MUXHLENOV, I.P.; POZINS, M.Ye.; TARA7-
KUSICOVt V.K* p E-ya.; AZI13EII,l p I.Ya * VOL'b'%OVIcH
. of , S.I.;
Bibliography. Zhur. prikl. khim. 36 no.12:2788-2792 D163.
(HIRA 17t2)
T.Vil.
At a laborat-,)ry of "hE! Ncv,)r-,o,3!~ovvk
C-hemical Conbine. av.
lab. 30 no.5;63?-.6~8 '640 ( R-5, A 1-1 s 5 )
1. N~challnll~ iatontor!l khIn-ehe3kogo
koribinfita.
PO-.. .1 IM-N'. 1'1'Y I B.A.
y I I . , . V-a~s ; Nll~ I'l"I"A L.' . , PM 1- 0 ~
-11. 'I.Ye.; KOHL;-Al , P.A.;
- , -.- 4. ~ 4 - ,
Improvorterit of the coirp'lex Nrtill.zar production of
tle 1170vomcskovsk
Chenlral Combina. Zhur. prlkl. klAra. 37
no.10:20F9-20~f3 0 164-
(IlliA 17:11)
1. bmingadskiy tekhriologlehosHy Institut I?aoni
bensovetu,
Novu,noskovskiy khindelieckly kombinat.
AZBELI, K.A-.
Now data on the stratigraphy of Permian sediments in the
south-
mistern slopes of the Dzungarian. 4la-Tau. Izv. An
Kazakh.SSR.
Sor.geol. no.4:84-88 161. (MIRA 15:3)
(Dzungarian Ala-Tau--Geology, Stratigraphic)
A?'jiFl I ~ r, J ~ I f, M~h l" y ;:Vlk, M.R.
i'*-rci~an stratigraphy of the southwestern slopps
c-l' the, Dzungariltn
Alfitau. Vent. AN Kazakh, SSR 21 no.9%46-50 S 165.
(M'.Rk 1819)
14 - mvp - IN-
I Ligg. ~'m L
M--
AZBXL', L.I., TALOLO, P.M., inzh.
The first large-panal house vith .16 apartments In
Western Siberia.
Tranap. stroi. 10 no.9.21-23 S 160. (HIM 130)
1. Glavny7 takhaolog tresta, Omaktransetroy (for
Azbell)e
(Siberia, Westerzt-Apartnent houses)
AZBELIP M,
For collective farms and state farm:) in tho
repablic. Av.transp.
40 no.749-50 Jl 162* (KDA 15-.8)
1, Bashkirskoya respublikarokoye upravleniye
professionallno-
tekhnichask-ogo obruzoyaniya. -
(Bashkiria-Automobile drivers)
AZT3ZL I 1 1". 0.
Experienco .11th the Organization and ~4'ovk of the Jection
for Intestinal
lnfectionfl at the 4,ilitary 6roup i-4ecUcal Station.
-7iURiiAL(id1,1'rAHY hEi)[OAL No 3, 1' 5''. p-41
SIKISKAYA, Ye.N.; AZBEL'p H.I.1 red,
[Prob.Lem 6c populatiom of higher plants] Froblema popu-
liats.A u vysshikh rastenii. Leningradt Selikhozizdat.
No.2. (Categories and regularities of the variability in
higher plant populationsj 0 kategorAiakh i zakonorrerno-
stiakh i=renchivosti v populiatsiia:Eh vysshik1% rastanii.
1963. 122 p. (MIRA 17t11)
p
S
537.311.62
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on it wt m A mptt
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th.
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it not rebted to the'
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velod mi), thr Impcft~-.* bc4 dtfined as
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turns Out
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