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SCIENTIFIC ABSTRACT BAKANOV, S.P. - BAKANOVICH, G. I.

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December 31, 1967
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5(4) SOV/69-21-4-1/22 AUTHOR: Bakanoyj,.S__7, and Deryagin, B,.V. TITLE: On the Theory of Thermoprecipitation of High Dispersion Ae.rosol Systems. PERIODICAL: Kolloidnyy zhurnal, 1959, Vol XXI, Nr 4, Pp 377-384 (USSR) ABSTRACT: This ia a study,of thermoprecipitation of high dispersion aero- sol systems, in which the measures of the suspended par- ticles are considerably smaller than the medium length 04, the free run of the gas molecules KwJ. Under atmospheric pressi e, this corresponds quantitatively to aerosol particles of lcii~ im and less in size. The authors consider this high dispersion aerosol system, in which a small temperature gr-r.,- dient is maintained, as a mixture of two gases (in reality it is a mixture,of gas and dust). The separation of the mixture, therefore, is carried out through the separation of tro gases by thermal diffusion# The stud,r of the authors is divided into 41wo parts. In the first they determine the rate of moven5~_-i` of Card 1/4 the particles with regard to the center of gravity of the to- SOV/610-21-4-1/22 On the Theory of Thermoprecipitation of High Dis-perrion Aerosol Systemr,,. tal of gas molecules. For this purpose, they use the Chapn,~n- Enskog formula(l), which was obtained as a result of the so- lution of the Bolzmann ("Bolttsman") kinetic equation. An -~qu- tion (12) shows that the rate of thermal precipitation r do~-,,~ not depend on the dimensions of the particles. Tt is invorsl.ly proportional to the square root of medium temperature and gas pressure. The magnitude u hglds for atmospheric pres;7,ure, 1P (absolute temperature) = 300 C and grad T = 300clem for air of the category 0.25 mm/sec. The authors observe that Einstein obtained a similar formula (13), the coeffi3ient of which 's approximately threefold smaller than that of the authors' la. In the second part of the article, the authors app-roach the problem with another method analogous to that which was used by them for the solution of a problem concerning diffusional particle transport. This method consists in the computation of the resultant force,by which an unevenly-heated gas acts cn a Card 2/4 suspended particle. The use of this method resulted in the ascertainment of a well-re,.,ulated additional velocity compo- I SOV169-21-4-1122 On the Theory of Thermoprecipitation of High Dispersion Aerosol Systems. nent'T (equations (41) and (42)) of a suspended particle, which does not noticeably disturb the velocity distribution of the gas molecules. The velocity component '&, which has to be added to the velocity of the Brownian movement, is due to the effect of the collision of the molecules. The magnitude of t is proportional to the value of grad T, inversely pro- portional to the gas pressure and also to the square root of medium temperature and molecular weight of the gas. It does not depend on the dimensions of the particle. The numerical value of thermophoretic velocity depends, under the assumption of stability of the other conditions, in the character of interaction of --as molecules and particle surface. This velo- city is identical (if the absolute velocity values are pre- served) during elastic and diffusional reflection of the mole- cules and by 25% less in the case of diffusional dis- Card 3/4 persion of the molecules. There are 4 references, 2 of which SOV/69-21-4-1/22 On the Theory of Thermoprecipitation of High Dispersion Aerosol Systems. are German, 1 Soviet and 1 English. ASSOCIATIONs Institut fizicheskoy khimii AN SSSR, Moskva (Institute of Physical Chemistry of the AS USSR, Moscow). SUBTdITTED: 15 July 1958. Card 4/4 8A09 B/020/60/135/006/025/037 A B004/BO56 AUTHORBi Deryagin, B. V., Corresponding Member AS USSR, Bakanov, S,. P., and Kurgin, Yu. S. TITLEi The Influence of Monomolecular Layers Upon the Evaporation of Drops PERIODICALt Doklady Akademii nauk SSSR, 1960, Vol. 135, No. 6, pp. 1417 - 1420 TEXT: The authors develop a theory of the influence of monomolecular layers upon the evaporation of drops, which takes two effects into accounti 1) the quasi-steady evaporation of a drop covered by an insoluble film of a different substance, and 2) the nonsteady evaporation of a drop covered by such a film. For 1) the following is taken into account: a) the steady diffusion of liquid molecules through the film, b) the steady diffusion of liquid molecules from the film into the air. The following relations are written for these processesi C 1 a A,/r + Bj; a< r< a + 6; C2 - A 2/r + B2; r> a + 6 +;L. C, denotes the number of liquid molecules Card 1/3 6?40~' The Influence of Monomolecular Layers Upon the Evaporation of Drops S/020/60/135/006/025/037 B004/BO56 per cm3 of film, C2 the concentration of vapor in the air, a the radius of the drop, 6 the thickness of the film, % the thickness of the layer of air immediately adjoining the film. AV A 2' Bil B 2are coefficients. On the basis of the boundary conditions for diffusion on the boundaries r = a + 6 and r a + 6 + ;~_ the following relation is derived for a film (6( )~ holds for the surface of the sphere. -U>is the gas velocity at 0 --;- infinity, r 0 is the unit vector in the direction -r". Ti e + X i) Card 1/2 S/020/62/147/001/019/022 Theory of the thermophoresis... 13101/23144 holds for the JQmperature distribution within the sphere. Outside the sphere T e- -(-97)/(2x e + Hi) vihere %i is the thermal conductivity of the sphere, %e that of the gas. If % i~% e , then according to F. Epstein (Zs. Phys., 54, 537 (1)29)) QIT ' -(-~/2Q)j-p/dz from which it follovs that v = -(Z/2QT)j-T/dz. If % i is of the same order of magnitude as xe , the velo of thermophoresis is expressed by vT ~?-~t4e -' 0.5xi)/, (2 Re + %djwQ T)dT/dz. The experimental data are better expressed by this equation than by that of P. Epstein. It also explains the experimentally observed dependence of QvT/7~ on the nature of the gas. There is 1 figure. ASSOCIATION: Institut fizicheskoy khimji Akademii nauk SSSR (Institute of Physical Chemistry of the Academy of Sciences USSR) SUBMITTED: July 20, 1962 Card 2/2 7 ->n- 4/ 7_7 _Vro_ T7Nb- I O/P9.. 4//Pt-7'/Pi ACCESS DD 4' NP.: k~;5016560 .,AUTHM BakunpV, S._ Yq_l J1 2ME: Hxeftption of waves in plasma media in an external electric q I eld 48. - no,.-:6 -~SOURCE:. -elk koy zikl,~ _v. Plasma- "Os'- a blict e t ma el c ro guetit--fie 4LI-1- romagnetic wave, -Do-O"let leftec"t ABSTRACT: Excitation 0 low-frPqi~en- t i ~,18 'he L011ision 'ntegral inLroduced by D cvvdov (ZhFTF, v. 7, 1937, 1069). T'l c 3ispe rsion equa tion f,-r small c '.".z' -. i-E i': iP t a C' r!, y wn e e P c tr-~ z vel )cltle8 exceerl the phase i wa%u iizalle~' LO Erie drift. In tn i s case buil6up of the oscillations is due to the change in the sign of the higb-obl.-I Card 1/2- 1ACCESSIM (c AT 21678-66 _)ATC L FAC.C NRt' AP6004872 - - - SOURCE CODE: UR/000/66/036,/001/0007/0012 AUTHOR: Bakanov, S-P-; Rukhadze, A.A. ORG: PhYflics Institute im. P.N.Lebedev, AN SSSR, Moscow (Fizicheskiy institut AN SSSF0 TITIX: On the oscillations of a plasma in constant external electric and magnetic fields SOURCE: Zhurnal tekhnicheskoy fiziki, v. 36, no. 1, 1966, 7-12 TOPIC TAGS: plasma stability, electric fieldi semiconductor plasma, plasma oscillation, constant magnetic field, ionized plasma, electron plasma, electromnnn~-tic wave oscillationt propagation velocity ABSTRACT: . The authors (ZhETF,.48, 1656j 1965) have previously discussed.the excita-, tion uivler~the influence of a constant electric.field of low frequency electromagnetic oscillaticns in a weakly ionized electron-ion plasma and in the electron-hole plasma of n semiconductor. In the present paper they consider the.influence on these oscillations of a strong external magnetic field parallel to the electric field. [Abstracter's note: The results and notation of the previous paper are employed with- out redefinition of the symbols; it Is accordingly difficult to follow the argument without reference to the earlier paperg It is shown that the magnetic field does not stabilize the noise oscillations that arise In arbitrarily weak electric fields. It Card 1/2 UDC: 533*9 L 21678-06 NRt AP6004872 is found that In a plasma -having 'unequial numbers of carriers of the two.signs there can arise.drift waves with a propagation velocity close to the drift velocity., CorWitions for the stability of these waves are derived and it is shown that these conditions do pend on the longitudinal dimension of the plasma. This phenomenon can be employed to design n somiconductor microwavo.amplifier. The-authors also discuss the influence -of the -magrietic-lield -on the-'stability of the waves propagating transversely to the drift at n velocity considerably exceeding the drift velocity, the possible existence of which they demonstrated in tie earlier paper. The authors thank V.M.lAvin for discussing the results and for critical remarks. Orig. art. has: 17 formulas. SUB CCOE: 20/ SUBM DATE: lomay6s/ 011IG REF: OD6/ OrH REF: 000 Card 2/2 -,-L 11-119-67 13V1 (I )-IJP-CG ACC Nki AP6031267 SOURCE CODE: U'P,/0057/66/036/009/1639/1648 iAUTROR: Bakanov,S,P.;_Rq dankovich,L,S,; Rukhadze,A,A. 411 IORG. Physics Institute im. P.H.Lebedov,_AN SSSRt Moscow (Fizichoskiy institut AN SPSR) TITI4,E: On the excitation of electromagnetic oscillations in a plasma beam bounded by pla .' conducting walls SOUVE: Zhurnal tekhnichoskoy fiziki, v. 36, no. 9, 1966, 1639-1648 TOPIC TAGS: plasma stability, plasma oscillation, plasma electromagnetic wave,plasma magnetic field, betatron, uhf amplifier, extreme high frequency ABSTRACT: The authors discuss the stability of a ylasMa uniformly filling most of the- space between two plane parallel conducting walls and carrying an electron current in the direction of an applied magnetic field that is parallel to the walls. The calcu- lations were undertaken because of their practical interest in connection with negativ absorption amplifiers and plasma betatrons. The walls were assumed to be plane and parallel to facilitate the calculations; it is presumed that the results are qualir tatively valid for the technically interesting case of a plasma beam in a cylindrical enclosure with conducting walls. The calculations are based on a dielectric tensor derived by linearizing hydrodynamic equations for the electron motion, which include the self consistent field and the effects of collisions. The calculations are there- fore valid for waves whose phase velocities are high compared with the electron thermally -Card_ 112, UDG: 533.9 L 11 419-67 XCC Nk, AP6031267 velocities. Dispersion equations are derived for the limiting cases of weak and strong,, ixternal magnetic field, and the logarithmic Increments of the oscillations are calcu- Lated. It Is found that in a rarefied plasma in a weak magnetic field there develops a p--riodic convective instability that is carried by the electron current, and that 5uch a system can amplify. The instability persists in a weakly ionized dense plasma, In which collision effects are predominant, and a strong external longitudinal magneti. Cield reduces the logarithmic increment in a collision-free plasma but does not sta- Alize it. The frequency band that can be amplified increases in width with incressinq wall conductivity, but the length of the tube required for a given gain also increases;- It is concluded that the optimum wall conductivity for a negative absorption amplifier is 1013 or 1014 ,sec-i pnd the optimum plasma density is such as to provide a colliiion frequency of 10 or 10-L3 see-I. Under these conditions frequencies up to about 10 2 iz can be amplified. it is found that under the conditions of the plasma betatron experiments of A.hT.8tef3novskiy (Yadernyy Bintez, 5, 215, 1965), the Instability dis- cussed here develops during the course of several microseconds. This time is much longer than the observed acceleration times and is also longer than the time that would be required for acceleration of the electrons if the acceleration were not interrupted. It is therefore concluded that the instability associated with wall conductivity cannot explain the observed interruption of acceleration in the plasma betatron and will not in itself prevent the operation of such an accelerator. The authors thank V.P.Silin, who instigated the work. Orig. art. has-, .31 formulas and 1 figure. SUB 'PODE: 20 SUBM DATE: 28Jun65 ORIG. M: '006 OTH REF: 001 2/2 Card bab ACC NRa AP6036027 SOURCE CODE: IJR/0057/66/036/011/1955/1958 ATITHOTI: Bakanov, S. P.; Lovetskiy, Ye. Ye. ORG-.' Moscow Institute of Physics and Engineering (Moskovskiy inzhenerno- fizicheskiy institut) TITLE: Theory of the instability of current plasma confined between conducting walls SOURCE: Zhurnal technicheskoy fiziki, v. 36, no. 11, 1966, 1955-1958 TOPIC TAGS: plasma, current plasma, unstable plasma, j0*4ah+mo===mt plasma fr44"UZI *1 ABSTRACT: A study is made of the effect of conducting walls on the stability of charge plasma in relation to the buildup of potential fluctuations. High- conductivity metal walls greatly reduce the instability region of charge plasma. This results in a considerable reduction in the accelerating electrical field necessary for tl slipping through" the unstable region. A buildup of surface waves is possible on .the boundary between the charge plasma and vacuum. It is shown that in the Card 1 / 2 UDC: 533.9 1 ACC NR' AP6036027 I presence of conducting walls this instability can be stabilized, which indicates that conducting walls substaintially ease the conditions of unimpeded electron accelera- tion in a plasma betatron. [Authcrs' abstract.] [SP] TEREMV, A.A., kan(I. takhn. nauk; BAKANOV, V-I-,.-inch.; IOZINSKIT, V.N., inzh.; ozHiGov, Tu.S.,'inzh. New nelf-dumping motorcar. Vest. TSNII M 18 no.7:53-56 N '59. (MRA 1312) (Mine railroads) POTAPOV, V.S., inzh.; JB ~~ .1., inzh. ,A)~, V Results of the testing of the industrial 26El electric locomotive. Vest.TSNII IAPS 22 no.6:35-39 163. (MM 16:10) ASHKENAZIP Yefrem. Abramovich, kafid. takhn. nauk; IOV, Vladimir-- Ivanovich., tvwhu; FETROVAO V.L., red.; VOROTNIKOVA, L.F., te ~. -re-d-. (Fields of epplication of the various types of ti-actic-.~ in industrial ratlroad transportatioil. Sfery primeieniia raz- lichnykh vidov tiagi na promyshlennom zheleanodor6zhnom. trans- porte. Moskva, Trdnszheldo-rlzdat, 1963. 133 p. (MOISCOWO Vsesoiuznyi nauchno-issledovatel'skii inatitut z4Ieznodorozh- nogo transporta. Trudyp no,263). i (MIRA 16:4) (Railroads, Industrial) (Locomotives) RAKANOV, V. N. "Increase in the Food Value of Grass Mixtures and Succulent Fod- ders by Means of Advanced Agricultural Techniques." Cand Agr Sci, Moscow Agricultural Acad, Moscow, 1953. (RZhBiol, No 4, Oct 54) Survey of Scientific and Technical Dissertations Defended at USSR Higher Educational Institutions (10) So: Sum. No. 481, 5 May 55 WWWWAIM.- USSR/Farm Animals - Gnicral Problu:~i,:,. q-1 Abs Jour : Buf ""Wr - Biole', No 1, 1959, 2621 Author : La!~anov, V.N. Inst : joscow Agricii1tural Acadmy Launi K.A. Ti)airynzcn Title : ljicr,~iasing the Pro4oin of Gre= Fod&~,,- by ..~-,ring AgricUtural T~,c*,~11.1qUOSs Crig Pub : Dolzl. !.bsk. r,.-kh. almd. L.i. K.A. Tmiryazova, 1957, vro, 30, ch, 2, 27-33. Abstract : Th~-, effect of -the suwil,--L-at-ation of the nutrition of L~~- 0 C,:r;,i-:Lnation of vc,~C!I-graia .~ - ftxturcs with mineral zcrs uoon their choi:iical awposi-Lion and nutritiv~.,n,~ss v,as studiud, The int*ro(f,'Lic`v.,--ion of phosphate and nit-ro&-, nous fizxl-lilizers incr~~ascd content of protein and p:,os- Vhat-o co-mounds in gror-ii fodd,,x. The green par'. of thc: Card 1/2 forat;e plants assimilatxi 5Wv of the nitrogcn byttrodiic,~(I KMJM, Adenek; SAKANOV, N.A. [translator]; BAUNOV, Y.N., red. [Antibiotics in the feeding of farm animals] Antibiotiki v kormlenii sellskokhosiaistyennykh zhivotnykh. Pod red. V.N.Bakanova. Moskva, Izd-vo inostr.lit-ry, 1958. 184 po Translated from the Czech. (MM 14:1) (Antibiotics) (Feeding) BAUMVAV009 kaDd.selskokhozvaystvennykh nauk, starshiy nauchnyy sotrid-~n Affect of clutivation practices on the content of protein, calcium, and phosphorus in votch-oat mixtures [Vith summa y in English]. Izv. TSMA no.4:56-68 16o. (MIRA 13:9) (Vetch) (Oats) (Tillage) BAKATIO !~E~.V'N',_Ootsent, kand. sel'skokhoz. nauk; KUZYURIN, A.N., zaslu- zhennyy agronom RSFSR; MAMAYEV, V.A., aspirLnt Use of corn silage in intensified dairying. Izv. TSKHA no-5: 178-196 164. % (MIRA 18:5) 1. Kafedra kormleniya sel'skokhozyaystvennykh zhivotnykh Moskovskoy ordena Lenina sel'skokhozyaystvennoy akademii imeni Timiryazeva. 2. Direktor uchebno-opytnogo khozyaystva imeni Kalinina, Michurin- skogo rayom , Tambovskoy oblasti, Moskovskoy ordena Lenina sellsko- khozyaystvennoy akademii Imeni Timiryazava (for Kuzyurin). GORBOV, V.F.-, ZOWTUKHIN. Ye.S.LLA1,1AW, Ye.D.; NOVIKOV, G.S. mv-A:1-14W Automatic machines for superfiniabing ball races. Suggestion by V.P. Gorbov and others. Prom.energ. 11 no-7:16-17 JI 156. (MLRA 9:10) (Ball bearings) (Metalworking machinery) GHULIN. V.1111.; 'BAKA-14.0n, Ye.,I-. - -~- Pressure-drop signal indixtor with explooi,on pmtention. Transp. i khran. neftl i nolteprt-d. no,435-:36 164 (14IRA ) 1. Spe-b-sialtnoye konstruktorskoys byuro "Transn6V4rav4.matikaO. -_ RAKANOU, A., sameetitell predeedatelya. Struggle for metal. Rabotnitea 31 no.7:6-7 J1 153. (MLRA 6:6) 1. UvIcom Moskovskop,,o artomobillnogo zavoda imeni Stalina. (Metal induBtries) BOV2o-121-1-17/55 AUTHORS: AlItshuler, L. V., Bakanova, A. A., Trunin, R. F. TITIC: Phase Transformations Mien Water Is Compressed by Strong ShockWaves (Fazovy,!e prevrashcheniya pri szhatii vody oil'- nymi udarnymi volnami) P-RIODICAL: Doklady Akademii nauk SGSR, 1958, Vol- 121, Yr 1,pp. 67-69 (us S,-q) ABSTRACT: This paper gives a report on the shock-like COMDression of water in the range of Diescures from 20 000 to 800 000 at- mospheres. On this 006asion the Idnematic parameters of the chock wave, namely, its velocity of propagation D and mass velocity U of matter behind the wave.front, were measured. -Because.of the laws of conservation of mass and momentum these parameters are connected with the density of the shock- like compression Q DAD - U) and with the pressure Q P = Q DU; Q denote; tRe density of matter before the com- 0 0 pression. The method of investigation can be simplified very much when the shock wave is-lead to the layer of 'the substance Card 1/9- to be investigated through shields of a material with known .30V/2o-121-1-171/55 Phase Transformation '.'J'hen Water Is Compressed by Strong Shock '.7aves Hugoniot (Gyugonio) adiabatic line of the shock compression. The quantities measurable by experiment are the speed of the shock waves in the shield and in rater. The dynamical adia- batic line of water consists of two sections which with their ends fix the region of phase transition. The existence-of th- phase transition is also proved by the decrease in trans- parency of water when a shock wave of sufficiently high amplitude of pressure P > P I goes through. In the case of shock waves with an amplitu e of pressure P < P the trans- parency does not change. There are 4 figures anl 5 referencesp 1 of which is Soviet. PRESENTED: ~JBnuary 17, 1958, by Yu. B. Kharitonov, Member, Academy.of Sciences, USSR - SUBMITTED: November 26, 1957 1. Water-Pressure 2. Water-P~roperties 3. Phase transitions 4. Shock waves-Velocity 5. Shock waves-Physical effects Card 2/2 5/056/60/038/03/14/03~ BOO~/BO14 AUTHORS% Alitshuler, L. V.p Kormer, S. B., Bakanova,_A. k.,_Truning R._P- -31 71 TITLE: Equation of State for Aluminum, Copper, and Leadlin the High- pressure Range PERIODICALs Zhurnal" sperimentalinoy i teoreticheskoy fiziki, 1960y Vol- 38t No- 39 PP- 790-798 TEXTs In the present paper, the authors discuss the conclusions applying to aluminumg co?perp and lead, as result from an equation deviating from the Mie - GrueneiBen solid-state equation. The equation considered by the authors deviates in that it holds within a wide pressure- and temperature range, and that the thermal electron components of energy and pressure are taken into account. Moreoverg data are furn shed concernin- dynamic compression of aluminum up to pressures of 2.10 atmv and results of new measuTementg of the compressibility of copper, lead, and iron at 106, 2.106, and 4.10 atm are offered. Numerous theoretical and experimental details conaerning the adiabatics of these three metals are discussed in the introduction, with special regard to the collision adiabatics (Ye, I. Zababakhin, Yu. F. kA- Card 1/3 824!5 Equation of State for Aluminum, Copper, and Lead S/056/60/038/03/14/033 in the High-pressure Range B000014 Alekseyev). An7satzes for the equation of state and internal energy have the form P - Pint :I. Ptherm + Pexc and E - Eint + Etherm + Eexc (2). The first terms-of these sums characterize the interaction of atoms at OOK, the second t'PJA are thermal ones determined by lattice vibrationst and the third terms are',01etermined by the thermal excitations of electrons. In the following, the various terms are written down explicitly; and finally, the following explicit expressions are obtained for pressure'~apd temperatures C 1/12 2 P P int+Z.2vv'p [T-TO+Eo/Cvp] +0 Po (v,,/v) T and vok 1/2 2 E P dv + E + C (T-T + -1 %(vvo) T .According to equation (1) int 0 vp 0 2 for the dynamic adiabaties, PG dynamic experiments permitted 2:ak(6,_ 1)k' 1 a determination of pressure'PG and also of an rgy EG . BO + tp (;(V0- V). Results of computations for aluminum are given in Table 5, for copper in Table 6, and for lead in Table 7. As is shown by Figs. 1 and 2, thermal Card 2/3 Equation of State for Aluminum, Copp,:r, and Lead in the High-pressure Range S/056/60/038/03/14/033 B006/BO14 pressure plays an impox~iant part.in the compression of metals by strong shock Faves. For the pressures 216.1010 bars (Al), 368-1010 bars (Cu), and 401-1010 bars (Pb)p the thermal pressure components amounted to 59-10 10 115-10109 and 124-10 10 bars. For the same pressureso the thermal energy com- ponent was 57% (Al), 60/. (Cu), and 69% (Pb). Finally, the authors thank A. I. Funtikovp R. V. Malyshevy and 1. P. Dudoladov, as well as Professor K.-A.-Semendyayev for their assistancep advicep and discussions, T,, D. T,Pndau is also_~nentioned in this article. There are 2 figures, 7 tables, and 14 references, 4 of which are Soviet. SUBMITTED: October 7, 1959 Card 3/3 Li 5 00 JJA,4~1 (111 160, 1 4~2' I O's 26693 ,j/- U:)6/6 i/tj4l/005/008/038 1,1210 1961, B109/B102 AUTHORS: Alltshuler, L. V.,Kormer, S. B., Bi~kanovaj A. A., Petrunin, A. P., Funktikov, A. I., Gubkin. TITLEs Irregular conditions of oblique collision of shock waves in solids PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki, v. 41, no. 501), 196,1, 1382 - 1393 TEXTr On the basis of papers by V. Blikney, A. Taub (3b. Voprosy rake Inoy ~Iekhniki, 1, 1951), L. D. Landau, Ye. M. Lifshits (Mekhanika sploshnykh sred - Mechanics of Continuous Media, Gostekhizdat, 1954), 0. S. Ryzhov, B. A. Khristianovich (PMM, 22, 566, 19580a. B. Zelldovich, Gandellman, and Ye. A. Feoktistova (D"---5SSR, 136, 1325, 1961) the authors describe a method of producing and recording irregalar conditions for the collision of shock waves in solids. The experimental arrangement is shown in Fig. 2a. The detonation waves which enter the specimen at a slant cause shock waves with amplitudes of between 3 and 4 .105 atm. Another arrangement allowed reaching shock waves of 1 - 1.8 .106 atm. The parameters of the Card 1/3 26693 S/056/61/041/005/008/038 Irregular conditions of oblique .... B109/B102 three-shock configuration forming as a result of the collision of the shock waves, are given for aluminum, lead,iron, and copper bodies. Near the critical angle at which a shock wave can still arise pressure was found to rise by from 6 to 8 times. When the waves have greater amp!Litudes, pressure in the collision region rises up to 4 1o6 atm in aluminum. In steel, copper, and lead it may even reach 7 -jo6 atm if the waves collide at right angles. The results are analyzed by means of the method of the iihpact polars. it is shown that the picture with only one tangential discontinuity cannot be employed in describing the irregular conditions of the oblique collision of weak shock waves in the metal. The authors present a method of determining pr 'essure and density behind*the reflected wave front from the parameters of the three-shock configuration. Pressure and density for the collision of strong shock waves in aluminum were calculated as iexamples. It was found that the incident and reflected waves increase the density of aluminum up to 6.12 g/cm3. M. P. Speranskaya, N. S. Tenigin (deceased), A. N. Kolesnikova. M. S. Shvetsov, L. N. Gorelova, and M., V. Sinitsyn are thanked for assistance and information. There are 14 figures, 3 tables,and 9 Soviet references. SUBMITTED: May 18, 1961 Card 2/3 34ooo S/056/62/042/001/015/048 Poo B104/B102 AUTHORS: Alltshuler, L. V., Bakanoval A. A., Trunin, R. F. TI TLE: Shock adiabats and zero isotherms*c;f seven metals at high pressures PERIODICAL: Zburnal eksperimentallnoy i teoreticheskoy fiziki, v. 42, no. 1, 1962, 91-104 TEXT: The wave velocity D and the mass velocity U behind the shock-wave front were measured in Fe, Ni, Cu, Zn, Cd, Sn, and Pb. Pressure and degree of compression were determined from P = Q 0DU and a = D/(D-U). By passing from the shock adiabat to the zero isotherm, the following simple equatdons were obtained for pressure and energy: P% (6) = Q 16% exp (q (I (6) (3Q/pok) Iq -exp (q (I Val where Q and q a2e unknown constants, v0/v, v being the specific volume, Card 1 /10 34000 5/056 62/042/'001/015/048 Shock adiabats and zero isotherms... B104,IB'102 and v0 = v at P = 0 and T = T0. In the*case of ionic compounds, the first terms in (5) determine the ionic repulsion potential and the second terms determine the Coulomb attraction. In the case of metals, the positive and the negative term in (5) express the repulsive and the attractive forces, respectively. Simzilar equations were obtained for transition metals in the same way. Shock adiabats and zero isotherms were approximated by a suitable combination of Q and q (Figs. 5 and 6).Using the equation Px,extra b + B (or a)n' the zero isotherms were extrapolated into pressure and density ranges, to which quantum statistical methods are applicable. The extrapolation constants are presented in Table 8. K. K. Krupnikov, M. I. Brazhnik (ZhETF, 3A, 886, 1958), S. B. Kormer, V. D. Urlin, L. T. Popova (FTT, J~ 223, 1961), V. S. Zharkov, and V. A. Kalinin (DAN SSSR, 135, 811, 1960) are mentioned. V. N. Zuburev is thanked for his assistance in interpreting experimental data, 1-1. 1. Brazhnik, A. A. Gubkin, and I. P. Dudoladov for their help in experiments and calculations, and S. B. Kormer and V. D. Urlin for discussions. There are 9 figures, 8 tables, and 14 references: Card 2/,6 34000 S/05 62/042/001/015/048 Shock adiabats and zero isotherms... B104% 102 9 Soviet-bloc and 5 non-Soviet-bloc. The four most recent references to English-language publications read as follows'. R. G. McQueen, S. P. Marsh. J. Appl. Phys. 31, 1253, 1960; J. M. Walsh et al. Phys~ Rev. .LOS, 196, 1957; J. J. Gilvarry. Phys. Rev. 102, 317, 1956; j. s. Dugdale, D~ K. McDonald. Phys. Rev., PI, 832, 1953. SUBMITTED: August 10, 1961 Table 1. Experimental results. Legend: (1) shock-wave parameters. Table 2. Experimental results. Legend: (1) material of impact massi (2) velocity of impact mass. Table 8. Extrapolation constants. Fig. 5. Shock adiabats and zero isotherms of Ni and Zn. Fig. 6. Shock adiabats and zero isotherms of Fe, Card 3~~ AD Kr. 971-19 20 VAY IMPACT COMPRESSIBILITY OF Ti. Mo, Ta, and Fe (USSR) TCrupnikov, K.K A__A_Jj-jjan& -6 a Vs - M. 1. Brazhnik, and R. F. Trunin. IN: Akademiya nauk SSSR. Dohlady, v. 148, no. 6, 21 Feb 1963, 1302-1305. S/020/63/1481006/012/023 The impact compressibility of Ti, Mo, andTaatpressur6s upto5,106atm, and of Fe at a pressure of - 9,10 6 atm, has-been determined. The pressure was :-generated-by shooting aluminum plates -at a velocity of 5600 m /sec or stee1 pins at a velocit of 8640 or 9100 m/sec: onto test specimens 3-4 mm thick whi h y Ic were shielded by an Al or Fe shield. The pressure and the degree of compres- sionwere calculated from the experimentally determined velocity D of the shock wave. The state of impact compression and the values of pressure P and mass velocity behind the front of shock wave U were determined graphically. The compression density p was calculated from the equation poD = p(D-U), where PO is the initial density. From the obtained shock-wave parameters the adia- batic curves for, shock waves and zero isotherms were calculated and plotted. Card 1/1. 55117-65 v7~~rI Lr~id o L ado-; Y r F s !z c 8- 1 '.M Ieta' IP SOURM Fivilm tye-rdogn tels, V. 7, ~6c;, 1615-1622 no. 4 Iftbl-tira, sod Um, p6titaltm, zero lvothe=, ccrm- pression cw-ve, alka'! meta, shock,. Tile of iaj, M., and K were ivvestiga-ted An. tbe- U Tresswe ramge- 30w--95-0 kbar~- b p-le xi,~a us ng as -as a Akmdavd. The exper etts vere carried out uri'!~ +` set-up shown in Fig. 1 of the Enclosure, the samples being c-yl- 4aders 12 and mm in diameter and 4 or 6 mm high. The pressures and the densi- ties of the shock mapression were determined bv A r-flectlon M-_t~~Ud by Zn L) --of r - " 'I. -;. -:- .1 w 4 ,-, ~,!. I , - I Ly re -vA wt~vra in rne iffveszigaled and In the control sawles of &luminx-n or A maxiimm shock-wave amplIt-ader tbt greatest Inc-reape in dentity Vat R 'nr',G- of L ~- &rid Nzi). 'Die cccnzpreasion CUT"-VeB at a'ueo.Lute zero are derived on the basis of The experimentRI data. T%e ccrl !/' ACCESSION h'Ri Ap5c.14552 p --mr-Ar-i with q-fn~, r 6 FZ f0,-j 2()0o L64 RFF 60-v: 00K~ VW L ~.=F, R L -32,21o-66 E' TO )/ZWPW IN SOURCE CODE:- im/0386/66/003/012/0483/0487 ACC NR; AP6620795 (A) ;iunw: AlItshuler, L. V.; Bakanova, A. A. - Dudoladov oRd: none TITIY,: Peculiarities of shock compression of lanthanides SOURCE: Zhurnal eksperimentallnoy i teoreticheskoy fiziki. Pis'ma v redalctsiyu, Prilozheniye, v- 3, no. 12, 1966, 483-487 'TOYL-C TAGS: lanthanide series, lant-hanum, cerium, namarium, dysprosium, erbium., second order phase transition, adiabatic compression, high pressure, critical pressure, mechanical shock resistance ABS MICT: The authors report the first results of an investigation of the dynamic compressibility of La, Ce, Sm, Dy, and Er up to 3.5 Mbar pressure. The shock- compression parameters were obtained by the reflection method (L. V. Alltshuler, Uspekhi fiz. nauk v. 85, 1,97, 1965 and earlier) using apparatus described else- where (ZhETF v. 38, 790, 1960 and Piz. tverdogo tela V. 5~ 279, 1963),. The directly measured quantities were the velocities d of the shock wave'in the in- vestigated metals. These were used to determine the mass velocities U, the shock' compression pressures P, and the degrees of compression a. The d-u plot of each of the lantbanides, obtained from the experimental data, is represented with high ,Card 1/2 . L 32210-66 ~AGC NR. AP6020795 (A) accuracy by two straight-line segments of different slopes. The slopes and inter-: cepts of all the segments are determined and tabulated. The shock adiabats were also plotted fol Sm, Dy, and _Pz, for which the change in slope of the d-u plot was most pronounced. The adiabats exhibit kinks near the critical pressures, indi- cating the presence of a.second-order phase transition.. The more gently sloping sections of the adiabats are probably determined by the compression of the ex- ternal low-density 6S shells and by the simultaneously occurring redistribution of the electrons among the bands. The change in slope at the critical pressure I signifies the completion of these processes and the formation of low-- compressibility electronic configuration. A more complete interpretation of the data calls for calculation of the energy spectra of the compressed metals. The authors thank Corresponding Member of the Academy of Sciences SSSR, Professori N. P. Sazh:Ln,' as well as Engineers L. A. Dolomanov and V. M. MuravIyeva for in- terest and collaboration. Orig. art. has: 2 figures, 2 formW s, and 1 table. SUB CODE: 20/ SUBM DAIE: 2~Apr,66/ ORIG REF: 008/ OTH PXF: 003 r-r,4 P/2 .. 4 ~ .: - . -. ARST RACT: The aaUium-gallium phosph; de Evs,.r-m, was studied, and the temp- dot- fir 1- 10. 5at-n. 2-16. 2atm.(L. I. Marina, A. Ya. Nashel'skly, S. V. Yakobson, FIWjANG, Yevgeniy Vladimirovich; BAKANOVA, I.P., red. [Electrostatics. Direct current; lectures in physics] Elektro- statika. Postoiannyi elaktrichaskii tok; lektaii po fizike. Moskva, Mosk. poligrafidbo'n i in-t,,1961. 100 p. (MIRA 16:9) (Klectrostaties) (Electric currents) Ok GENKELIP P.A.; BAKANOVA,.L.V.; SAMYGIN, G.A. _7 - - Freezing of plants with a low frost resistance. Fiziol.rast. 12 no.1269-75 Ja-F 165. (MIRA 18:3) 1,, Institut fiziologii rasteniy imeni, Timiryazeva AN SSSR, Moskva. GOKET.-ly BAKANOVA , Surface characteristics of the cell prctoplasts of plantc- in the state of dornancy. Fizlol..rast. 12- no.4.-659-664 JI-Ag 165. (MIRA 18:32) 1. Institut fiziologli rastenly imen! K.A.Tiuii7azeva AN SSSR) Mcskva. Submitted March 31, 1965. BAIWIOVA, 11. 1. , Engr "An 7Lnvestigation of the Relation of the Productivity of a Dredge to the Operation of Washing-Concentrating Equipment." Cand Toch Scl, Hoscow Inst of Nonferrous Metals and Gold imeni 111. 1. Kalinin, 29 Nov -54. (VM, 16 Nov 54) Survey of Scientific and Tec',inical Dissertations Defended at TJSSR Higher Education&I Institutions (11) SO: Surn. 1-10 - 521, 2 Jun 55 I I "W/f /'//ifl4t./~D'.D.; RAKAIIOV.A, V.P. Cutnneous renction with diphthorinl toxin in determining diphtherinl immunity. Zhur.mikroblol.eDid. i iTimun.28 no.12:54-55 D 157. (MMA 11:4) 1. Iz kliniki detakikh infektsiy II Moskovokogo meditsinakogo instituta im. N.I. Pirogova. (CORYMACTIRIUM DIPHTHERIAE, Itoxin, cutaneous renction in immun. determ (Rua) X7(8);(12) sov/16-59-9-4/47 AV1"M.- BakanovA, N.P., and Apanashchenko, N.I. TITLE: Determining the Susceptibility of Children to Diphtheria by the Skin Method. II. Using Purified Stabilized Toxin for the Skin T~ast PERIODICAL: Zhurnal mikrobiologii, epidemiologii i immunoblologii, 1958, Nr 9, pp 19-22 (USSR) ABSTRACT: In Part I of this work the authors published the findings of their investigations into the susceptibility of children to diphtheria, determined by-the skin method and performing the Schick test at the same time. Here,.in Part II, the authors describe the effect of using purified diphtheria toxin with a glyoe'rine-gelatine stabilizer, pre- pared according to the method evolved by P.V, Pavlov and A.G. Leonoya at the Institut imeni Gamalei (Institute imeni-Gamaleya). Some 357 children aged from 6 months to 13 years were vaccinated and kept under observation. Both the skin test and the Schick test were used. It was found that the coincidence in the'lresults of the two tests in- creased directly with an increase in the concentration of the diphtheria -toxin. At a*ooncentration of 100 Dlm/ml the coincidence reached 98.8%. Card 1/2 This was much better than when unpurified toxin was used, The method SOV/16;.;59;..g;.;4/.47 Determining the Susceptibility of Children to Diphtheria by the Skin Method. 11. Using Purified Stabilized Toxin for the Skin Test was found to be quite harmless for children. The purified stabilized diphtheria toxin retained its specific action on animals for 2 years. The authors recommend further work on the efficacy and practical ad- visability of this method. There are 2 tables, 1 graph and 3 Soviet references. ASSOCIATION: Kafedra detskikh infektsionnykh bolezney II Moskovskogo meditsinskogo, (Chair of Children's Infectious Diseases instituta imeni Pirogova of the II Moscow Institute imeni Pirogov); Institut epidemiologii i mikrobiologii imeni Gamalei AMN SSSR (Institute of Epidemiology and Microbiology imeni Gamaleya of the AMN USSR) SUBMITITD: February 25, 1959 Card 2/2 BAKANOVA, V.P., APANASFCHF.NKO, 17.11. Skin test in determinRtion of susceptibility of children to diphtheria* Zhuremikrobiol, epid, i ivmun. 29 no.6:38-43 Ja 158 (MIRA 11:7) 1. Iz kafedry detskikh infektsionnykh bolexney II Reditsinskogo institute Imeni Pirogova I Institute epidemiologii i mikrobiologii imeni Gamalet AMN SSSR. (PIPITM 1A, immunO1097, sk1n test in detem. of mmeeptibility (Rua)) BAKIJLEV~ A.F.) rtlcademik, glay. red.; ZAVALISH.M. N.I., prof., zam. glav. red.; TII.-AKOV., V.D.p prof., zam. glav. red.; IL'ICRU, K.I., starshiy nauchnyy red.; OBYSGVA, U.S.., starshiy nauch- nyy red.; PAVLOVA, A.A.,, starshiy nauclinyy red - BAYWiOVAI T D na chnyry red.; GRISHINA, L.A.p starshiy ;e~.Fre ~.~ (Large medical encyclopedia]Bol'shaia meditsinskaia entsiklo- pediia. Glav. red. A.N.Bakulev. Mosim, Gos. nauchn. izd-vo "Savetskaia en'tsiklopediia.11 Vol.26. P6t'*Bbki - professional- nyi otboi. Izd.2-9 - 1962."'-!:1256 bolumns. [List of articles and tenrs forthe letter IT" (26th vol.)_.7P~rec~enl statei i terminov na bukvu UP" (dvadtsat' shestoi t60'4 P. (Phono- graph record for the article YHeart defects" (Aortal defects of the heart))Gramofomaia plastinka k statle "Poroki serdtsall (AortalInye porokd serdtsa). (KIRA 15:10) (MEDICIU,DICTIONARIES) BAKULTEV, A.14., akademik, glav. red.; ZAVALISHIN, N.I., prof., zam. glav. red.; TDIAKOV, V.D., prof., zam, glavo red.; ILIICHEVA, K.I., starshiy nauchrjyy red.; OBYSOVA, Ye.S., starshiy nauchrWy red.; PAVLOVA, A.A., starshiy nauchriyy red.; PAKANQVA, T-D--, nauchryy red.; LEBEDEVA, A.K., red.; GRISMA, L.A.,, tekhn. red. [Large medical enc-clopedia]Bollshaia meditsinskaia entsiklope- diia. Glav.red. A.P.Bakulev. Moskva, Gos.nauchn. izd-vo "Sovet- skaia entsiklopediia.0 Vol.27. ProfilaktJka - Reverden. Izd.2. 1962. 1224 columns [List of articles and terms for the letters "Pu and "R115-erechen' statei i terminov na bukvy "P11 i IIRO (dvadtsat'se&moi tom) 4 p. _[Phonorecord appended to the article "Heart defects" (Combined heart def-ects)]Granofonnaia plastinka k stat'e "Poroki serdtsall (Kombinirovannye poroki ser- dtsa). Vol.28. Revmatizm - RunWniia. Izd.2. 1962. 1248 columns. _[List of articles and terms for the letter nRH]Pe- rechent statei i terminov na bukvu nRII (dvadtoat' vosImoi tom) 4 P. _ (Phonorecord appended to the article "PlWchogenia"] Gramofonnaia plastinka k statle "Psikhogenii" (psikhogennye psi- khozy) (MEDICINE~-DICTIONARIES) (~aRA 15:12) SOKOLOVA, N.I.;,Rk-WQVA,,V-A-; SHABAROVA, Z.A.; PROKOFIEV, MI.A. Isolation of pyrimidine deoxyribonucleosides and the production of their aminoacyl derivatives. Biokhimiia 27 no.6:1079-1084 N-D 162. (MIRA 17: 5) 1. Laboratoriya khimil br;l:ca Gonudarstvennogo universitata, imani Lomonosova, Moskva. SOKOLOVA, N.I.; BAONOVA, V.A.; SHABAROVA, Z.A.; PRPKQFIYEV, M.A. Aminoacyl deri4atives of nucleosides. Part 6: Synthesis ands properties of aminoacyl derivatives of deo*rib6nucleosides Zhur. ob. khim. 33 no.8s2480-2486 Ag, 163.. (MIRA 16:11) EAKANOVA,,V.V., assistent Accuracy of relief mappihgs on 1:2000 maps prepared Ir7 stereotopographic surveying. Izv. vys. ucheb. zav.; geod. i aerof. no.4:75-81 163. (MIRA 17:9) 1. Moskovskiy institut inzhenerov goodezii,serofotosllyemki i kartografii. 5(1,,3), 3o(l) SOV/153-2-4-29/32 AUTHORS: Berlin, A. A., Bakanova, Ye. G. TITLE: Production of Stable Emulsions, Having a Washing Effect, Prom DDT PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. R'himiya i khimicheskaya. tekhnologiya, 1959, Vol 2, Nr 4, pp 622 - 625 (USSR) ABSTRACT: The use of aqueous dispersions of insecticides in various branches of industry, agriculture, and medicine has been in- creasing (Ref 1). In this connection, the discovery of eco- nomical production methods for stable emulsions, of DDT so- lutions in petroleum, and other solvents rith washing pro- perties in addition to highly insecticide effects has become necessary. In order to solve this problem, the authors tested the following emulsifiers and stabilizers: polyethylene-glycol esters of alkyl phenols (OP-4, OP-7, OP-lo, OP-2o, etc), more- over, emulsifiers produced from protein waste, technical starch, sulfite lyes, oxyethyl- and carboxymethyl cellulose, sodium alginate, the diethyl-aminomethyl-derivative salt of alkyl- phenol-polyethylene-glycol ester (eaualizer A). Among the stabi- Card 1/3 lizers mentioned, water-soluble keratin (keratein) is Pro,duction of Stable Emulsions, Having a Washing Effect, SOV/153-2-4-29/32 From DDT -` especially interesting. Figure 1 characterizes the surface activity of the emulsifiers investigated. Hence it appears that the most active ones are: OP-4, OP-7 and keratein (disso- lution product of waste containing keratin in 3-100%j sodium- sulfide solutions, or in 1-3~'. alkali solutions at 6o-601,Ref 2). Table 1 shows the effect of the addition of OP-4 to keratein on the properties of the emulsions (turpentine in water). Hence it appears that the stability and emulsifying capacity of keratein rapidly increase by a 0.1 to 0.01~0 OP-At addition. Comparatively highly disperse, stable emulsions are formed. They did not dissociate into layers, even after a three-month stora-e (Fig 2). In order to obtain maximura homogenization of the emulsification of DDT-solutions, they were put into an ultrasonic field. The best results were obtained with P_ frequency of 2o-300 kilocycles (Ref 3). The emulsions were sufficiently stable (Fig 3). The washing capacity was tested by means of artificially soiled cotton samples in hard rater for 20 minutes. The rinsed and dried samples were photometri- cally recorded. Tables 2 and 4 show the results. Thus, the Card 2/3 addition of OP-4 to kerittein increases the stabilizing effect Production of Stable Emulsions, Having a Washing Effect, SOV/153-2-4-29/32 From DDT as well as the foam-forming capacity of the protein. The same emulsifier rendered possible the production of concentrated aqueous stable suspensions of DDT- or hexachlorocyclohexane solutions in turpentine with a content of active substance of 6o-65%, 2o-25% of fatty acids in soaps may be substituted by keratein. Soaps thus modified have a higher foam-formation- and washing capacity. Thus, considerable amounts of edible fats can be obtained from the soap industry, and can be used for consumption. There are 4 figures, 2 tablea,and 5 Soviet refer- ences. ASSOCIATION; Moskovskiy tekhnologicheakiy institut myasnoy i molochnoy promyshlennosti; Laboratoriya vysokomolekulyarnykh soyedineniy (Moscow Technological Institute of Meat and Milk Industry, La- boratory of High --molecular Compounds) SUBMITTEDs June 11, 1958 Card 3/3 Organic - insectofung-l'ides. XVIII. Now method of VP_,P - of t. Of chloTo- and idchlorotblopbospboric .,id, g. NI kzjjava Ya. A. 11.1andel'baurn, N. N. Niel' nik d E. 1. ventsitskil. Zhur. ObAZAA Kbim. 6, X!~Ian,); ,f. C.A. 59, 2415d.-Rtfluxing fine At wb~c in 2-4 fold excess of abq. EtOlf in the pmence of 0.1 g. kig(OAc)~ and a little iodine foT activation of Al, until all Al goes into soln. results in a rapid prepn. of AI(Ollt~. 11rith an equimolar amt. of EtOH. C*Ho is used as a diluent and the reaction is much s3ower. To 17 g. PSC13 there was added with coc4ing a suln. from 0.5 g. At and 3 g. EtO-11 in 8 mi. CJ10; after 3 hra. at W the mIxt.,vw washed with Ice-4 acidified with IICJ. drW, and distd., yielding 40m- EtOPSCII, bt~ 689, d: 1,3M, Pty IAW To 34 S. PSK v= added with cooling a soln. from 2 S. Al and 25 ml. EtOH;, after 2 hrs. at "0 the cooled mixt. was washed with cold: 1110. acidified with-. RCI, yielding 42%. (EtO)jPSCII ba k1bod. _7 of dikhlopbophorit atid.rontalulng a ii amWe group IUL- thot Aliphatic irter'ndlcal.' Shvetsovs Afel .11 N.N; 'nikovsfidN.T. arteml- W d. ~Ajjropfiate aldehydts and - estjrrs of carbande acid were 7itmed and-- treated with (ROV,%H; 7afterstinding 14 days at iroaan tcmp,_ the* products were extd.~wM C*Hj. Imshed with H.O. dfled:abd distd. No other detaili are 'given _41115, were prepd.. (J?OV,(S)SCHN.R'COjR'~ IR', %yield,b.p.. dn, and r.V givtn). %30Z, (RjR Me,H, F JAM; Fr, Hj Ef, 60.7, b", 82% LOW6, 1.4912; iso-Bu, H. P-1, 46.6. ba-175 122-4', (m. 22*); Es, Me, Ej. 20 8 'N-is 107-14* 1.1814, 1.6041; Bu, Me, Et, 53.7, b,.,3 522 I.W75. IAM; iso-Bu, Me, EI, 57,5, bt., 12+--i-, P~ 5- V. W 7~ -Ot ke- t4 ll,*~Z. SIMMeAs a I mle-"Mv oi r7r~dim, 7t v rn"U= --. Elf s-.t, -~,- .. ~;v 1 1. - - I I 4 I b,11 MELINIKOV, N.N.; MANIELIBAUM, Ya.A.; SVENTSITSKIY, Ye.I.; Ekr--UTOVA, Z.M. On organic insectofungicides. Part 271 New method for the preparation of eaters of chlorothiophosphoric acid. Zhur.ob.khim. 27 no-7:1908-1910 JI 157. (MIRA 10:10) 10'Nauchnyy institut po udobreniyam i insektofungisidam. (Insecticides) (Chlorothiophosphoric acids) M&LINIKOV, N.N.; MANDELIBAUM, Ya.A.; SHVETSOVA, K.D.; BAKANGVA, Z.M. LOMA.KINA., V.I.; ZAKS, P.G.; KLISHTEYN, I.M.-,-,-POPOlT,-T-.-T.--,- PONROVSKIY, Ye.A.; BDGHAROVA, L.P.; SEDYKH, A.S.; UKRAINETS, N.S. Improved technologj for producing thiophos, metaphos, chlorophos and other phosphorus organic insecticides and investigation of new insecticides and fungicides derived from the esters of phomphoric acids. [1~rudy] NIUIF no.164:11-14 '59. (KRA 15:5) (Insecticides) (Fungicides) 5 (3) AUTHORS: Mandellbaum, Ya. A., ?Aellnikov, N. N., SOV/79-:29-445/77 -Bakanova, Z. 1.T. TITLE: From the Fi~ld of Organic Insectilcides-and Fungicides (Iz oblasti ortanicheskik.h lnsek~oiunti,tsidov). XLI. On the Reaciion of Dialkyl-ohlOr07thiothoaphatea and Thiophosphorus-trichloride IWIL'th Phenols in the Presence of Tertiary Amines (XLI.'O vzaimodeystvii dialkilkhlortiofoafatov. i tiotrekhkhloiistogo fosfora s'fenolami v prisutstvii tretichnykh aminov) PERIODICAL: Zhurnal.o.bshclie~i khlmfi,-1959, Vol 29; Nr 4, PP 1149-1151 ~ (USSR) ABSTRACT: In connection.with.the papers mentioned in the references 1-5 the.authors especially in vesti`g~ied the.reactions of ditilkyl-chl8ro-thiophosphates xy'ith phenols in the presence of tertiary amines. This reaction proceeded already at room temperature in good yields and produced the corresponding dialky-aryl-thiophosphates. The solvents were.of no importance, and thd reaction proceeded also without solvents, but in this case the stirring of the reaction mixture is dard 1/3 difficult owing to the crystallization of ammonium chloride. From the Field of Organic'Insecticides and SOV/79-29-4-25/77 Fungicides. XLI. On the Reaction of Dialkyl-chloro-thiophosphates and Thiophosphorus-trichloride With Phenols in the Presence of Tertiary Amines Dialkyl-aryl-thiophosphates are obtained in good yield also in alcoholic solution, which indicates that the reaction with phenols proccods more rapidly than with alcohols. The authors inva~!ttigated the reaction of dialkyl-chloro-thiophospheLtes with phenols in the presence of triethyl amine. 0,0-dialkyl- 0-aryl thiophosphates were found to result. The mechanism uf the formation of dialkyl-aryl-thiophosphates from dialkyl- chloro-thiophosphates and phonols in & presence of tertiary amines can be best explained in the following way: There is an exchange reaction between amine phenolate and dialkyl- .~chloro-thiophosphate, yielding the hydrogen chloride of the bLmino and of dialk.yl-aryl-thiophosphate. On the reaction of :,~Dhenols with thiophosphorus trichloride in the presence of triothylamine aryl-dichloro-thiophosphates were obtained in sufficient yield. There are 1 table and 5 references, 4 of which are Soviet. Card 2/3 From the Field of Organic Insecticides and .1 SOV/79-2(1-4-25/77 Fungicides. XLI. On the Reaction of Dialkyl-chloro-thiophosphates and Thiophosphorus-trichloride With Ph6nols in the Presence of Tertiary '-~inerj ASSOCIATION: Nauchnyy institut -Do udobreniy&m i insektofwM;itsidam (Scientific Institute of Fertilizers, Insecticides and Fungicides) SUBMITTED: M.,)rch 12,195fl Card 3/3 5.1320,5.3630 77380 SOV/79-30-1-4i/78 AUTHORS: .Mandel'baum, Ya. A., Mellnikov, N. N., Bakanova, Z. M. TITLE: Concerning Organic Pesticides. LII. Concerning the Reaction of Aryl-Dichlorothiophosphates With Magnesium Ethoxide PERIODICAL:. Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp 194- 197 (USSR) ABSTRACT: The reaction of aryl dichlorothiophosphates with magnesium ethoxide was investigated with the purpose of obtaining some new pesticides, and also in order to study the relationship between the reactivity and the structure of the chlorothiophosphoric acid deri- vatives. The reaction can proceed according to (1), (2), and (3), depending on the ratio of the reagents, the temperature of the reaction, and the time of reaction. Card 1/4 Concerning Organic Pesticides. ILII. 77380 Concerning the Reaction of Aryl- SOV//79-30-1-41/78 Dichlorothiophosphates With Magnesium Ethoxide 2 ArOPSCIS + (CI jHb0)jMg ---0-.2 Aro PSCI + MgCII (1) CIH50> 2 ArO CIH50>PSCI + (C$H50)2Mg - 2 ArOPS(OC2%)s + MgC12 (2) 2 ArOPS(GCIHB)2 + (C24&0)%Mg - 2 (C2Hb0)2PS + (ArO)2Mgl (3) Aryl.dichlorothiophosphates and magnesium ethoxide taken in stoichiorretric amounts gave chiefly alkyl aryl chlorothiophosphates or the corresponding diethyl aryl thiophosphates. Transesterificatipn (Formula 3) oc6urred only with large excess of magnesium ethoxide and on prolonged heading. Accordingly, 0.1 mole phenyl dichlorothiophosphate and 0.05 mole magnesium ethoxide on heating for 3.5 hr gave 0-ethg1 0-phenyl 4%; bp 95-100 C/0.2 mm). chlorothiophosphate (yield 6 The same reagents taken in amounts of 0.05 mole and 0.1 mole, respectively, gave on heating for 7 to 17 hr 0,0-diethy; 0 henyl thiophosphate (yield 82-91%; bp 120-122 U70 .8 rmn). 0.1 Mole 2 4,5-trichlorQphenyl Card 2/4 C j Concerning Organic Pesticides. LII. 77380 Concerning the Reaction of Aryl- SOV/79-30-1-4i/78 Dichlorathiophosphates With Magnesium Ethoxide dichlorothiophosphate and 0.3 mole magnesium ethoxide on heating at 65-70 0 C for 18 hr gave 0,0-diethljl 0-2, 4,5-tr-'chlorophenyl thiophosphate (yield 78%; bp 1300 C/ 0.13 nun); also, 2,4,5-trichlorophenol (yield 13~6; mp 620 C), and triethyl phosphate (yield 15%). Under similar conditions, 0.1 mole 4-nitrophenyl dichloro- thiophosphate and 0.3 mole magnesium ethoxide gave 0,0- aiethyl-0,4-nitrophenyl thiophosphate (yield 40%; bp 156-1580 C/O.'- mm); also, p-nJ;trophenol (yield 28%; mp 1120 C), and 0,0,0-triethyl thiophosphate (yield 30%; bP 51-520 C/0.3 mm). There are 10 references, 2 U.S., I U.K., 7 Soviet. The U.S. and U.K. references are: H. D. Orloff, C. J. Worrel, F. X. Markley, J. Am. Chem. Soc., 80, 727 (1958); h. F. Hudson, I;. Keoy, J. Chem. Soc., 1953 , 2463; T. R. Fukuto, R. L. Metcalf, J. Agr. Food Chem., 4, 930 (1956). Card 3/4 Concerning Organin Pesticides. LII. 77380 Concerning the Reaction of Anjl- SOV/79-30-1-4i/78 Dichlorothiophosphates With Magnesium Ethoxide ASSOCIATION: Scientific Institute for Fertilizers and Pesticides (Nauchnyyyinstitut po udobreniyam i insektofungitsidam) SUBMITTED: JanuarY 5, 1959 Card 4/4 MANDELIBAUM, Ya.A.; NELINIKOV, N.N.; BAKANOVAp ZAKS, P.G. Organic insecticide-fungicides. Part 612 Syathesis of some mixed ethyl mercaptoethyl thiophosphates. Zhijr.ob.khim, 31 no.120947-3949 D 161. (MaU 15:2) 1. Nauchnyy institut po udobreniyam i insektofungitaidam im. Ya.V.Samoylova, Moskva* (Phoophothioic acict) (Insectioides) MELINIKOV., N.N.; MANDELIBAUM., YA.A.; BAKANOVA., Z.M. Organic insecticide-fungiciden., Part 63s Synthesis of some derivatives of phosphinic acids. Zhur.ob.khim, 31 no,3-2Q953- 3955 D 161* (MIRA'15:~) , 1. Nauchnyy institut po udobreniyam i ineektofungitsidam imeni. Ya.Vo Samoylova, Moskva. (Phos~phinic acid) I ,Insecticides) 7-d A( )I FWTm F-c A( b AB IS, T R-A C TThis Author's Certificate introduces a method for producing new SmMll -.---i4junb2 ~WO PTF SOV: 000 -LIICT OTHER: 000 Lm- kv NO REF SOV: 000 'LCard,_U MMMMW~ OTHEP: L 1687-66 &;T(.1)/EWT(m)/EPF(n)-2 _(m)/EPA (,w)414W(t W-10 W IJP(c) JDAT ACCESSION OR: -AP5020552 UR/0294/65/003/004/0520/0523~rj AUTHOR: Bakanovich, Gj -1. Grechikhin, L.-' 1. TITLE: Use of,. -emission spectra of the co.ppe atom for diagnostics_of a plasma 6S ~SOURCE: TePl9ftika vysokikh temperatur, v. 3, no. 4, 1965, 520-623 -TOPIC TAGS: "jAdisima didgnostics, emission spectrum, copper, Stark effect, Van de'r Waals"t-quati6n, electrodes, plasma charged particle ABSTRACT: Since copper pairs formed by erosion of electrodes, exist in all typeE of plasma apparatus (plasmatrons, magnetohydrodynamic generators, arcs, etc.) the work described in the article is aimed at selection of the corresponding spec- tral. linen. at fixing their basic constants (transition probability and the Stark and van der Weals constants) at evaluating the effect of various factors on the width of the Belecied lineab and at explaining errors in the measurement of temperature and concentration of the charged Oartibles. The experiments were carried out. with a direct current arc (1 8 amp) between copper or brass electrodes under CGr.d11/2____

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