5(4) SOV/69-21-4-1/22
AUTHOR: Bakanoyj,.S__7, and Deryagin, B,.V.
TITLE: On the Theory of Thermoprecipitation of High Dispersion
Ae.rosol Systems.
PERIODICAL: Kolloidnyy zhurnal, 1959, Vol XXI, Nr 4, Pp 377-384
(USSR)
ABSTRACT: This ia a study,of thermoprecipitation of high
dispersion aero-
sol systems, in which the measures of the suspended par-
ticles are considerably smaller than the medium length 04,
the free run of the gas molecules KwJ. Under atmospheric
pressi e, this corresponds quantitatively to aerosol particles
of lcii~ im and less in size. The authors consider this high
dispersion aerosol system, in which a small temperature gr-r.,-
dient is maintained, as a mixture of two gases (in reality it
is a mixture,of gas and dust). The separation of the mixture,
therefore, is carried out through the separation of tro gases
by thermal diffusion# The stud,r of the authors is divided into
41wo parts. In the first they determine the rate of moven5~_-i` of
Card 1/4 the particles with regard to the center of gravity of
the to-
SOV/610-21-4-1/22
On the Theory of Thermoprecipitation of High Dis-perrion
Aerosol Systemr,,.
tal of gas molecules. For this purpose, they use the Chapn,~n-
Enskog formula(l), which was obtained as a result of the so-
lution of the Bolzmann ("Bolttsman") kinetic equation. An
-~qu-
tion (12) shows that the rate of thermal precipitation r
do~-,,~
not depend on the dimensions of the particles. Tt is
invorsl.ly
proportional to the square root of medium temperature and gas
pressure. The magnitude u hglds for atmospheric pres;7,ure, 1P
(absolute temperature) = 300 C and grad T = 300clem for air
of the category 0.25 mm/sec. The authors observe that Einstein
obtained a similar formula (13), the coeffi3ient of which 's
approximately threefold smaller than that of the authors'
la. In the second part of the article, the authors app-roach
the
problem with another method analogous to that which was used
by them for the solution of a problem concerning diffusional
particle transport. This method consists in the computation of
the resultant force,by which an unevenly-heated gas acts cn a
Card 2/4 suspended particle. The use of this method resulted
in the
ascertainment of a well-re,.,ulated additional velocity compo-
I SOV169-21-4-1122
On the Theory of Thermoprecipitation of High Dispersion
Aerosol Systems.
nent'T (equations (41) and (42)) of a suspended particle,
which does not noticeably disturb the velocity distribution
of the gas molecules. The velocity component '&, which has to
be added to the velocity of the Brownian movement, is due to
the effect of the collision of the molecules. The magnitude
of t is proportional to the value of grad T, inversely pro-
portional to the gas pressure and also to the square root
of medium temperature and molecular weight of the gas. It
does
not depend on the dimensions of the particle. The numerical
value of thermophoretic velocity depends, under the
assumption
of stability of the other conditions, in the character of
interaction of --as molecules and particle surface. This
velo-
city is identical (if the absolute velocity values are pre-
served) during elastic and diffusional reflection of the
mole-
cules and by 25% less in the case of diffusional dis-
Card 3/4 persion of the molecules. There are 4 references, 2
of which
SOV/69-21-4-1/22
On the Theory of Thermoprecipitation of High Dispersion
Aerosol Systems.
are German, 1 Soviet and 1 English.
ASSOCIATIONs Institut fizicheskoy khimii AN SSSR, Moskva
(Institute of
Physical Chemistry of the AS USSR, Moscow).
SUBTdITTED: 15 July 1958.
Card 4/4
8A09
B/020/60/135/006/025/037
A B004/BO56
AUTHORBi Deryagin, B. V., Corresponding Member AS USSR,
Bakanov, S,. P.,
and Kurgin, Yu. S.
TITLEi The Influence of Monomolecular Layers Upon the
Evaporation of
Drops
PERIODICALt Doklady Akademii nauk SSSR, 1960, Vol. 135, No. 6,
pp. 1417 - 1420
TEXT: The authors develop a theory of the influence of
monomolecular
layers upon the evaporation of drops, which takes two effects
into
accounti 1) the quasi-steady evaporation of a drop covered by
an insoluble
film of a different substance, and 2) the nonsteady
evaporation of a drop
covered by such a film. For 1) the following is taken into
account: a) the
steady diffusion of liquid molecules through the film, b) the
steady
diffusion of liquid molecules from the film into the air. The
following
relations are written for these processesi C 1 a A,/r + Bj; a<
r< a + 6;
C2 - A 2/r + B2; r> a + 6 +;L. C, denotes the number of liquid
molecules
Card 1/3
6?40~'
The Influence of Monomolecular Layers Upon
the Evaporation of Drops
S/020/60/135/006/025/037
B004/BO56
per cm3 of film, C2 the concentration of vapor in the air, a
the radius of
the drop, 6 the thickness of the film, % the thickness of the
layer of air
immediately adjoining the film. AV A 2' Bil B 2are
coefficients. On the
basis of the boundary conditions for diffusion on the
boundaries r = a + 6
and r a + 6 + ;~_ the following relation is derived for a
film (6( )~ holds for the surface of the sphere. -U>is the gas velocity
at
0 --;-
infinity, r 0 is the unit vector in the direction -r". Ti e + X i)
Card 1/2
S/020/62/147/001/019/022
Theory of the thermophoresis... 13101/23144
holds for the JQmperature distribution within the sphere.
Outside the
sphere T e- -(-97)/(2x e + Hi) vihere %i is the thermal
conductivity of the
sphere, %e that of the gas. If % i~% e , then according to F.
Epstein
(Zs. Phys., 54, 537 (1)29)) QIT ' -(-~/2Q)j-p/dz from which it
follovs that
v = -(Z/2QT)j-T/dz. If % i is of the same order of magnitude as
xe , the
velo of thermophoresis is expressed by
vT ~?-~t4e -' 0.5xi)/, (2 Re + %djwQ T)dT/dz. The experimental
data are
better expressed by this equation than by that of P. Epstein.
It also
explains the experimentally observed dependence of QvT/7~ on
the nature of
the gas. There is 1 figure.
ASSOCIATION: Institut fizicheskoy khimji Akademii nauk SSSR
(Institute of
Physical Chemistry of the Academy of Sciences USSR)
SUBMITTED: July 20, 1962
Card 2/2
7
->n- 4/
7_7 _Vro_ T7Nb- I O/P9.. 4//Pt-7'/Pi
ACCESS DD 4' NP.: k~;5016560
.,AUTHM BakunpV, S._ Yq_l
J1
2ME: Hxeftption of waves in plasma media in an external electric
q
I eld
48. - no,.-:6
-~SOURCE:. -elk koy zikl,~ _v.
Plasma- "Os'- a blict e t ma
el c ro guetit--fie 4LI-1-
romagnetic wave,
-Do-O"let leftec"t
ABSTRACT: Excitation 0 low-frPqi~en- t i
~,18 'he L011ision 'ntegral inLroduced by D
cvvdov (ZhFTF, v. 7, 1937, 1069).
T'l c 3ispe rsion equa tion f,-r small c '.".z' -. i-E i': iP t a C'
r!, y wn e e P c tr-~ z
vel )cltle8 exceerl the phase i wa%u iizalle~' LO Erie drift. In
tn i s case buil6up of the oscillations is due to the change in the
sign of the higb-obl.-I
Card 1/2-
1ACCESSIM
(c AT
21678-66 _)ATC
L
FAC.C NRt' AP6004872 - - - SOURCE CODE: UR/000/66/036,/001/0007/0012
AUTHOR: Bakanov, S-P-; Rukhadze, A.A.
ORG: PhYflics Institute im. P.N.Lebedev, AN SSSR, Moscow (Fizicheskiy
institut AN
SSSF0
TITIX: On the oscillations of a plasma in constant external electric
and magnetic
fields
SOURCE: Zhurnal tekhnicheskoy fiziki, v. 36, no. 1, 1966, 7-12
TOPIC TAGS: plasma stability, electric fieldi semiconductor plasma,
plasma oscillation, constant magnetic field, ionized plasma, electron
plasma,
electromnnn~-tic wave oscillationt propagation velocity
ABSTRACT: . The authors (ZhETF,.48, 1656j 1965) have previously
discussed.the excita-,
tion uivler~the influence of a constant electric.field of low
frequency electromagnetic
oscillaticns in a weakly ionized electron-ion plasma and in the
electron-hole plasma
of n semiconductor. In the present paper they consider the.influence
on these
oscillations of a strong external magnetic field parallel to the
electric field.
[Abstracter's note: The results and notation of the previous paper are
employed with-
out redefinition of the symbols; it Is accordingly difficult to follow
the argument
without reference to the earlier paperg It is shown that the magnetic
field does not
stabilize the noise oscillations that arise In arbitrarily weak
electric fields. It
Card 1/2 UDC: 533*9
L 21678-06
NRt AP6004872
is found that In a plasma -having 'unequial numbers of carriers of the
two.signs there can
arise.drift waves with a propagation velocity close to the drift
velocity., CorWitions
for the stability of these waves are derived and it is shown that these
conditions do
pend on the longitudinal dimension of the plasma. This phenomenon can
be employed to
design n somiconductor microwavo.amplifier. The-authors also discuss
the influence
-of the -magrietic-lield -on the-'stability of the waves propagating
transversely to the
drift at n velocity considerably exceeding the drift velocity, the
possible existence
of which they demonstrated in tie earlier paper. The authors thank
V.M.lAvin for
discussing the results and for critical remarks. Orig. art. has: 17
formulas.
SUB CCOE: 20/ SUBM DATE: lomay6s/ 011IG REF: OD6/ OrH REF: 000
Card 2/2
-,-L 11-119-67 13V1 (I )-IJP-CG
ACC Nki AP6031267 SOURCE CODE: U'P,/0057/66/036/009/1639/1648
iAUTROR: Bakanov,S,P.;_Rq dankovich,L,S,; Rukhadze,A,A.
411
IORG. Physics Institute im. P.H.Lebedov,_AN SSSRt Moscow (Fizichoskiy
institut
AN SPSR)
TITI4,E: On the excitation of electromagnetic oscillations in a plasma
beam bounded by
pla .' conducting walls
SOUVE: Zhurnal tekhnichoskoy fiziki, v. 36, no. 9, 1966, 1639-1648
TOPIC TAGS: plasma stability, plasma oscillation, plasma
electromagnetic wave,plasma
magnetic field, betatron, uhf amplifier, extreme high frequency
ABSTRACT: The authors discuss the stability of a ylasMa uniformly
filling most of the-
space between two plane parallel conducting walls and carrying an
electron current in
the direction of an applied magnetic field that is parallel to the
walls. The calcu-
lations were undertaken because of their practical interest in
connection with negativ
absorption amplifiers and plasma betatrons. The walls were assumed to
be plane and
parallel to facilitate the calculations; it is presumed that the
results are qualir
tatively valid for the technically interesting case of a plasma beam
in a cylindrical
enclosure with conducting walls. The calculations are based on a
dielectric tensor
derived by linearizing hydrodynamic equations for the electron motion,
which include
the self consistent field and the effects of collisions. The
calculations are there-
fore valid for waves whose phase velocities are high compared with the
electron thermally
-Card_ 112, UDG: 533.9
L 11 419-67
XCC Nk, AP6031267
velocities. Dispersion equations are derived for the limiting
cases of weak and strong,,
ixternal magnetic field, and the logarithmic Increments of the
oscillations are calcu-
Lated. It Is found that in a rarefied plasma in a weak magnetic
field there develops
a p--riodic convective instability that is carried by the
electron current, and that
5uch a system can amplify. The instability persists in a weakly
ionized dense plasma,
In which collision effects are predominant, and a strong
external longitudinal magneti.
Cield reduces the logarithmic increment in a collision-free
plasma but does not sta-
Alize it. The frequency band that can be amplified increases in
width with incressinq
wall conductivity, but the length of the tube required for a
given gain also increases;-
It is concluded that the optimum wall conductivity for a
negative absorption amplifier
is 1013 or 1014 ,sec-i pnd the optimum plasma density is such as
to provide a colliiion
frequency of 10 or 10-L3 see-I. Under these conditions
frequencies up to about 10 2
iz can be amplified. it is found that under the conditions of
the plasma betatron
experiments of A.hT.8tef3novskiy (Yadernyy Bintez, 5, 215,
1965), the Instability dis-
cussed here develops during the course of several microseconds.
This time is much
longer than the observed acceleration times and is also longer
than the time that would
be required for acceleration of the electrons if the
acceleration were not interrupted.
It is therefore concluded that the instability associated with
wall conductivity cannot
explain the observed interruption of acceleration in the plasma
betatron and will not
in itself prevent the operation of such an accelerator. The
authors thank V.P.Silin,
who instigated the work. Orig. art. has-, .31 formulas and 1
figure.
SUB 'PODE: 20 SUBM DATE: 28Jun65 ORIG. M: '006 OTH REF: 001
2/2
Card bab
ACC NRa AP6036027 SOURCE CODE: IJR/0057/66/036/011/1955/1958
ATITHOTI: Bakanov, S. P.; Lovetskiy, Ye. Ye.
ORG-.' Moscow Institute of Physics and Engineering (Moskovskiy
inzhenerno-
fizicheskiy institut)
TITLE: Theory of the instability of current plasma confined
between conducting
walls
SOURCE: Zhurnal technicheskoy fiziki, v. 36, no. 11, 1966,
1955-1958
TOPIC TAGS: plasma, current plasma, unstable plasma,
j0*4ah+mo===mt
plasma fr44"UZI
*1
ABSTRACT: A study is made of the effect of conducting walls on
the stability of
charge plasma in relation to the buildup of potential
fluctuations. High- conductivity
metal walls greatly reduce the instability region of charge
plasma. This results
in a considerable reduction in the accelerating electrical field
necessary for
tl slipping through" the unstable region. A buildup of surface
waves is possible on
.the boundary between the charge plasma and vacuum. It is shown
that in the
Card 1 / 2 UDC: 533.9
1 ACC NR' AP6036027
I
presence of conducting walls this instability can be
stabilized, which indicates that
conducting walls substaintially ease the conditions of
unimpeded electron accelera-
tion in a plasma betatron. [Authcrs' abstract.] [SP]
TEREMV, A.A., kan(I. takhn. nauk; BAKANOV, V-I-,.-inch.; IOZINSKIT,
V.N., inzh.;
ozHiGov, Tu.S.,'inzh.
New nelf-dumping motorcar. Vest. TSNII M 18 no.7:53-56 N '59.
(MRA 1312)
(Mine railroads)
POTAPOV, V.S., inzh.; JB
~~ .1., inzh.
,A)~, V
Results of the testing of the industrial 26El electric locomotive.
Vest.TSNII IAPS 22 no.6:35-39 163. (MM 16:10)
ASHKENAZIP Yefrem. Abramovich, kafid. takhn. nauk;
IOV, Vladimir--
Ivanovich., tvwhu; FETROVAO V.L., red.;
VOROTNIKOVA, L.F.,
te ~. -re-d-.
(Fields of epplication of the various types of
ti-actic-.~ in
industrial ratlroad transportatioil. Sfery
primeieniia raz-
lichnykh vidov tiagi na promyshlennom
zheleanodor6zhnom. trans-
porte. Moskva, Trdnszheldo-rlzdat, 1963. 133 p.
(MOISCOWO
Vsesoiuznyi nauchno-issledovatel'skii inatitut
z4Ieznodorozh-
nogo transporta. Trudyp no,263). i
(MIRA 16:4)
(Railroads, Industrial) (Locomotives)
RAKANOV, V. N.
"Increase in the Food Value of Grass Mixtures and
Succulent Fod-
ders by Means of Advanced Agricultural
Techniques." Cand Agr Sci,
Moscow Agricultural Acad, Moscow, 1953. (RZhBiol,
No 4, Oct 54)
Survey of Scientific and Technical Dissertations
Defended at USSR
Higher Educational Institutions (10)
So: Sum. No. 481, 5 May 55
WWWWAIM.-
USSR/Farm Animals - Gnicral Problu:~i,:,. q-1
Abs Jour : Buf ""Wr - Biole', No 1, 1959, 2621
Author : La!~anov, V.N.
Inst : joscow Agricii1tural Acadmy Launi K.A. Ti)airynzcn
Title : ljicr,~iasing the Pro4oin of Gre= Fod&~,,- by
..~-,ring AgricUtural T~,c*,~11.1qUOSs
Crig Pub : Dolzl. !.bsk. r,.-kh. almd. L.i. K.A. Tmiryazova,
1957, vro,
30, ch, 2, 27-33.
Abstract : Th~-, effect of -the suwil,--L-at-ation of the
nutrition of L~~- 0
C,:r;,i-:Lnation of vc,~C!I-graia
.~ - ftxturcs with mineral
zcrs uoon their choi:iical awposi-Lion and nutritiv~.,n,~ss
v,as studiud, The int*ro(f,'Lic`v.,--ion of phosphate and
nit-ro&-,
nous fizxl-lilizers incr~~ascd content of protein and p:,os-
Vhat-o co-mounds in gror-ii fodd,,x. The green par'. of thc:
Card 1/2 forat;e plants assimilatxi 5Wv of the nitrogcn
byttrodiic,~(I
KMJM, Adenek; SAKANOV, N.A. [translator];
BAUNOV, Y.N., red.
[Antibiotics in the feeding of farm animals]
Antibiotiki
v kormlenii sellskokhosiaistyennykh zhivotnykh.
Pod red.
V.N.Bakanova. Moskva, Izd-vo inostr.lit-ry,
1958. 184 po
Translated from the Czech. (MM 14:1)
(Antibiotics) (Feeding)
BAUMVAV009 kaDd.selskokhozvaystvennykh nauk,
starshiy nauchnyy
sotrid-~n
Affect of clutivation practices on the content of
protein,
calcium, and phosphorus in votch-oat mixtures
[Vith summa y
in English]. Izv. TSMA no.4:56-68 16o. (MIRA 13:9)
(Vetch) (Oats) (Tillage)
BAKATIO
!~E~.V'N',_Ootsent, kand. sel'skokhoz. nauk; KUZYURIN, A.N., zaslu-
zhennyy agronom RSFSR; MAMAYEV, V.A., aspirLnt
Use of corn silage in intensified dairying. Izv. TSKHA no-5:
178-196 164. % (MIRA 18:5)
1. Kafedra kormleniya sel'skokhozyaystvennykh zhivotnykh Moskovskoy
ordena Lenina sel'skokhozyaystvennoy akademii imeni Timiryazeva.
2. Direktor uchebno-opytnogo khozyaystva imeni Kalinina, Michurin-
skogo rayom , Tambovskoy oblasti, Moskovskoy ordena Lenina sellsko-
khozyaystvennoy akademii Imeni Timiryazava (for Kuzyurin).
GORBOV, V.F.-, ZOWTUKHIN. Ye.S.LLA1,1AW,
Ye.D.; NOVIKOV, G.S.
mv-A:1-14W
Automatic machines for superfiniabing ball races. Suggestion
by V.P. Gorbov and others. Prom.energ. 11 no-7:16-17 JI 156.
(MLRA 9:10)
(Ball bearings) (Metalworking machinery)
GHULIN. V.1111.; 'BAKA-14.0n, Ye.,I-.
- -~-
Pressure-drop signal indixtor with explooi,on
pmtention.
Transp. i khran. neftl i nolteprt-d. no,435-:36 164
(14IRA )
1. Spe-b-sialtnoye konstruktorskoys byuro
"Transn6V4rav4.matikaO.
-_ RAKANOU, A., sameetitell predeedatelya.
Struggle for metal. Rabotnitea 31 no.7:6-7 J1 153. (MLRA 6:6)
1. UvIcom Moskovskop,,o artomobillnogo zavoda imeni Stalina.
(Metal induBtries)
BOV2o-121-1-17/55
AUTHORS:
AlItshuler, L. V., Bakanova, A.
A., Trunin, R. F.
TITIC:
Phase Transformations Mien Water Is
Compressed by Strong
ShockWaves (Fazovy,!e prevrashcheniya
pri szhatii vody oil'-
nymi udarnymi volnami)
P-RIODICAL:
Doklady Akademii nauk SGSR, 1958, Vol- 121, Yr 1,pp. 67-69
(us S,-q)
ABSTRACT:
This paper gives a report on the
shock-like COMDression of
water in the range of Diescures
from 20 000 to 800 000 at-
mospheres. On this 006asion the
Idnematic parameters of the
chock wave, namely, its velocity
of propagation D and mass
velocity U of matter behind the
wave.front, were measured.
-Because.of the laws of
conservation of mass and momentum
these parameters are
connected with the density of the shock-
like compression Q
DAD - U) and with the pressure
Q
P = Q DU; Q denote;
tRe density of matter before the com-
0 0
pression. The method of investigation can be simplified
very
much when the shock wave is-lead to the layer of 'the
substance
Card 1/9-
to be investigated through shields of a
material with known
.30V/2o-121-1-171/55
Phase Transformation '.'J'hen Water Is Compressed by Strong
Shock '.7aves
Hugoniot (Gyugonio) adiabatic line of the shock compression.
The quantities measurable by experiment are the speed of the
shock waves in the shield and in rater. The dynamical adia-
batic line of water consists of two sections which with their
ends fix the region of phase transition. The existence-of th-
phase transition is also proved by the decrease in trans-
parency of water when a shock wave of sufficiently high
amplitude of pressure P > P I goes through. In the case of
shock waves with an amplitu e of pressure P < P the trans-
parency does not change. There are 4 figures anl 5 referencesp
1 of which is Soviet.
PRESENTED: ~JBnuary 17, 1958, by Yu. B. Kharitonov, Member,
Academy.of
Sciences, USSR -
SUBMITTED: November 26, 1957
1. Water-Pressure 2. Water-P~roperties 3. Phase transitions
4. Shock waves-Velocity 5. Shock waves-Physical effects
Card 2/2
5/056/60/038/03/14/03~
BOO~/BO14
AUTHORS% Alitshuler, L. V.p Kormer, S. B., Bakanova,_A.
k.,_Truning R._P-
-31 71
TITLE: Equation of State for Aluminum, Copper, and Leadlin the
High-
pressure Range
PERIODICALs Zhurnal" sperimentalinoy i teoreticheskoy fiziki, 1960y
Vol- 38t No- 39 PP- 790-798
TEXTs In the present paper, the authors discuss the conclusions
applying to
aluminumg co?perp and lead, as result from an equation deviating
from the
Mie - GrueneiBen solid-state equation. The equation considered by
the authors
deviates in that it holds within a wide pressure- and temperature
range, and
that the thermal electron components of energy and pressure are
taken into
account. Moreoverg data are furn shed concernin- dynamic
compression of
aluminum up to pressures of 2.10 atmv and results of new
measuTementg of
the compressibility of copper, lead, and iron at 106, 2.106, and
4.10 atm
are offered. Numerous theoretical and experimental details
conaerning the
adiabatics of these three metals are discussed in the
introduction, with
special regard to the collision adiabatics (Ye, I. Zababakhin, Yu.
F. kA-
Card 1/3
824!5
Equation of State for Aluminum, Copper, and Lead
S/056/60/038/03/14/033
in the High-pressure Range B000014
Alekseyev). An7satzes for the equation of state and internal energy
have the
form P - Pint :I. Ptherm + Pexc and E - Eint + Etherm + Eexc (2).
The first
terms-of these sums characterize the interaction of atoms at OOK,
the second
t'PJA are thermal ones determined by lattice vibrationst and the
third terms
are',01etermined by the thermal excitations of electrons. In the
following,
the various terms are written down explicitly; and finally, the
following
explicit expressions are obtained for pressure'~apd temperatures
C 1/12 2
P P int+Z.2vv'p [T-TO+Eo/Cvp] +0 Po (v,,/v) T and
vok 1/2 2
E P dv + E + C (T-T + -1 %(vvo) T .According to equation (1)
int 0 vp 0 2
for the dynamic adiabaties, PG dynamic experiments permitted
2:ak(6,_ 1)k'
1
a determination of pressure'PG and also of an rgy EG . BO + tp
(;(V0- V).
Results of computations for aluminum are given in Table 5, for
copper in
Table 6, and for lead in Table 7. As is shown by Figs. 1 and 2,
thermal
Card 2/3
Equation of State for Aluminum, Copp,:r, and Lead
in the High-pressure Range
S/056/60/038/03/14/033
B006/BO14
pressure plays an impox~iant part.in the compression of
metals by strong shock
Faves. For the pressures 216.1010 bars (Al), 368-1010 bars
(Cu), and
401-1010 bars (Pb)p the thermal pressure components amounted
to 59-10 10
115-10109 and 124-10 10 bars. For the same pressureso the
thermal energy com-
ponent was 57% (Al), 60/. (Cu), and 69% (Pb). Finally, the
authors thank
A. I. Funtikovp R. V. Malyshevy and 1. P. Dudoladov, as well
as Professor
K.-A.-Semendyayev for their assistancep advicep and
discussions, T,, D. T,Pndau
is also_~nentioned in this article. There are 2 figures, 7
tables, and
14 references, 4 of which are Soviet.
SUBMITTED: October 7, 1959
Card 3/3
Li 5 00 JJA,4~1 (111 160, 1 4~2' I O's 26693
,j/- U:)6/6 i/tj4l/005/008/038
1,1210 1961, B109/B102
AUTHORS: Alltshuler, L. V.,Kormer, S. B., Bi~kanovaj A. A.,
Petrunin,
A. P., Funktikov, A. I., Gubkin.
TITLEs Irregular conditions of oblique collision of shock waves in
solids
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki, v.
41,
no. 501), 196,1, 1382 - 1393
TEXTr On the basis of papers by V. Blikney, A. Taub (3b. Voprosy
rake Inoy
~Iekhniki, 1, 1951), L. D. Landau, Ye. M. Lifshits (Mekhanika
sploshnykh
sred - Mechanics of Continuous Media, Gostekhizdat, 1954), 0. S.
Ryzhov,
B. A. Khristianovich (PMM, 22, 566, 19580a. B. Zelldovich,
Gandellman,
and Ye. A. Feoktistova (D"---5SSR, 136, 1325, 1961) the authors
describe
a method of producing and recording irregalar conditions for the
collision
of shock waves in solids. The experimental arrangement is shown in
Fig.
2a. The detonation waves which enter the specimen at a slant cause
shock
waves with amplitudes of between 3 and 4 .105 atm. Another
arrangement
allowed reaching shock waves of 1 - 1.8 .106 atm. The parameters of
the
Card 1/3
26693
S/056/61/041/005/008/038
Irregular conditions of oblique .... B109/B102
three-shock configuration forming as a result of the collision
of the
shock waves, are given for aluminum, lead,iron, and copper
bodies. Near
the critical angle at which a shock wave can still arise
pressure was
found to rise by from 6 to 8 times. When the waves have greater
amp!Litudes,
pressure in the collision region rises up to 4 1o6 atm in
aluminum. In
steel, copper, and lead it may even reach 7 -jo6 atm if the
waves collide
at right angles. The results are analyzed by means of the method
of the
iihpact polars. it is shown that the picture with only one
tangential
discontinuity cannot be employed in describing the irregular
conditions of
the oblique collision of weak shock waves in the metal. The
authors
present a method of determining pr 'essure and density
behind*the reflected
wave front from the parameters of the three-shock configuration.
Pressure
and density for the collision of strong shock waves in aluminum
were
calculated as iexamples. It was found that the incident and
reflected waves
increase the density of aluminum up to 6.12 g/cm3. M. P.
Speranskaya, N.
S. Tenigin (deceased), A. N. Kolesnikova. M. S. Shvetsov, L. N.
Gorelova,
and M., V. Sinitsyn are thanked for assistance and information.
There are
14 figures, 3 tables,and 9 Soviet references.
SUBMITTED: May 18, 1961
Card 2/3
34ooo
S/056/62/042/001/015/048
Poo B104/B102
AUTHORS: Alltshuler, L. V., Bakanoval A. A., Trunin, R. F.
TI TLE: Shock adiabats and zero isotherms*c;f seven metals at high
pressures
PERIODICAL: Zburnal eksperimentallnoy i teoreticheskoy fiziki, v. 42,
no. 1, 1962, 91-104
TEXT: The wave velocity D and the mass velocity U behind the shock-wave
front were measured in Fe, Ni, Cu, Zn, Cd, Sn, and Pb. Pressure and
degree of compression were determined from P = Q 0DU and a = D/(D-U). By
passing from the shock adiabat to the zero isotherm, the following
simple
equatdons were obtained for pressure and energy:
P% (6) = Q 16% exp (q (I
(6) (3Q/pok) Iq -exp (q (I Val
where Q and q a2e unknown constants, v0/v, v being the specific volume,
Card 1 /10
34000
5/056 62/042/'001/015/048
Shock adiabats and zero isotherms... B104,IB'102
and v0 = v at P = 0 and T = T0. In the*case of ionic
compounds, the first
terms in (5) determine the ionic repulsion potential and the
second terms
determine the Coulomb attraction. In the case of metals, the
positive and
the negative term in (5) express the repulsive and the
attractive forces,
respectively. Simzilar equations were obtained for transition
metals in
the same way. Shock adiabats and zero isotherms were
approximated by a
suitable combination of Q and q (Figs. 5 and 6).Using the
equation
Px,extra b + B (or a)n' the zero isotherms were extrapolated
into
pressure and density ranges, to which quantum statistical
methods are
applicable. The extrapolation constants are presented in Table
8.
K. K. Krupnikov, M. I. Brazhnik (ZhETF, 3A, 886, 1958), S. B.
Kormer,
V. D. Urlin, L. T. Popova (FTT, J~ 223, 1961), V. S. Zharkov,
and
V. A. Kalinin (DAN SSSR, 135, 811, 1960) are mentioned. V. N.
Zuburev is
thanked for his assistance in interpreting experimental data,
1-1. 1. Brazhnik, A. A. Gubkin, and I. P. Dudoladov for their
help in
experiments and calculations, and S. B. Kormer and V. D. Urlin
for
discussions. There are 9 figures, 8 tables, and 14 references:
Card 2/,6
34000
S/05 62/042/001/015/048
Shock adiabats and zero isotherms... B104% 102
9 Soviet-bloc and 5 non-Soviet-bloc. The four most recent
references to
English-language publications read as follows'. R. G. McQueen,
S. P. Marsh. J. Appl. Phys. 31, 1253, 1960; J. M. Walsh et al.
Phys~ Rev.
.LOS, 196, 1957; J. J. Gilvarry. Phys. Rev. 102, 317, 1956; j.
s. Dugdale,
D~ K. McDonald. Phys. Rev., PI, 832, 1953.
SUBMITTED: August 10, 1961
Table 1. Experimental results. Legend: (1) shock-wave
parameters.
Table 2. Experimental results. Legend: (1) material of impact
massi
(2) velocity of impact mass.
Table 8. Extrapolation constants.
Fig. 5. Shock adiabats and zero isotherms of Ni and Zn.
Fig. 6. Shock adiabats and zero isotherms of Fe,
Card 3~~
AD Kr. 971-19 20 VAY
IMPACT COMPRESSIBILITY OF Ti. Mo, Ta, and Fe (USSR)
TCrupnikov, K.K A__A_Jj-jjan& -6
a Vs - M. 1. Brazhnik, and R. F. Trunin. IN:
Akademiya nauk SSSR. Dohlady, v. 148, no. 6, 21 Feb 1963, 1302-1305.
S/020/63/1481006/012/023
The impact compressibility of Ti, Mo, andTaatpressur6s upto5,106atm,
and of Fe at a pressure of - 9,10 6 atm, has-been determined. The
pressure was
:-generated-by shooting aluminum plates -at a velocity of 5600 m
/sec or stee1 pins
at a velocit of 8640 or 9100 m/sec: onto test specimens 3-4 mm thick
whi h
y Ic
were shielded by an Al or Fe shield. The pressure and the degree of
compres-
sionwere calculated from the experimentally determined velocity D of
the shock
wave. The state of impact compression and the values of pressure P
and mass
velocity behind the front of shock wave U were determined
graphically. The
compression density p was calculated from the equation poD = p(D-U),
where
PO is the initial density. From the obtained shock-wave parameters
the adia-
batic curves for, shock waves and zero isotherms were calculated and
plotted.
Card 1/1.
55117-65
v7~~rI
Lr~id o L ado-; Y
r F s !z c 8- 1 '.M Ieta'
IP
SOURM Fivilm tye-rdogn tels, V. 7, ~6c;, 1615-1622
no.
4 Iftbl-tira, sod Um, p6titaltm, zero lvothe=, ccrm-
pression cw-ve, alka'! meta, shock,.
Tile of iaj, M., and K were ivvestiga-ted An. tbe-
U
Tresswe ramge- 30w--95-0 kbar~- b p-le xi,~a
us ng as -as a Akmdavd. The exper etts vere
carried out uri'!~ +` set-up shown in Fig. 1 of the Enclosure, the
samples being c-yl-
4aders 12 and mm in diameter and 4 or 6 mm high. The pressures and
the densi-
ties of the shock mapression were determined bv A r-flectlon
M-_t~~Ud by
Zn L) --of r - " 'I. -;. -:- .1 w 4 ,-, ~,!. I , - I
Ly re
-vA wt~vra in rne iffveszigaled and In the control sawles of
&luminx-n or
A maxiimm shock-wave amplIt-ader tbt greatest Inc-reape in dentity
Vat
R 'nr',G- of L ~- &rid Nzi). 'Die cccnzpreasion
CUT"-VeB at a'ueo.Lute zero are derived on the basis of The
experimentRI data. T%e
ccrl !/'
ACCESSION h'Ri
Ap5c.14552
p --mr-Ar-i with q-fn~,
r
6 FZ f0,-j 2()0o L64
RFF 60-v: 00K~
VW L
~.=F, R
L
-32,21o-66 E' TO )/ZWPW IN SOURCE CODE:-
im/0386/66/003/012/0483/0487
ACC NR; AP6620795 (A)
;iunw: AlItshuler, L. V.; Bakanova, A. A. - Dudoladov
oRd: none
TITIY,: Peculiarities of shock compression of lanthanides
SOURCE: Zhurnal eksperimentallnoy i teoreticheskoy fiziki. Pis'ma
v redalctsiyu,
Prilozheniye, v- 3, no. 12, 1966, 483-487
'TOYL-C TAGS: lanthanide series, lant-hanum, cerium, namarium,
dysprosium, erbium.,
second order phase transition, adiabatic compression, high
pressure, critical
pressure, mechanical shock resistance
ABS MICT: The authors report the first results of an
investigation of the dynamic
compressibility of La, Ce, Sm, Dy, and Er up to 3.5 Mbar
pressure. The shock-
compression parameters were obtained by the reflection method (L.
V. Alltshuler,
Uspekhi fiz. nauk v. 85, 1,97, 1965 and earlier) using apparatus
described else-
where (ZhETF v. 38, 790, 1960 and Piz. tverdogo tela V. 5~ 279,
1963),. The
directly measured quantities were the velocities d of the shock
wave'in the in-
vestigated metals. These were used to determine the mass
velocities U, the shock'
compression pressures P, and the degrees of compression a. The
d-u plot of each
of the lantbanides, obtained from the experimental data, is
represented with high
,Card 1/2
. L 32210-66
~AGC NR. AP6020795 (A)
accuracy by two straight-line segments of different slopes. The
slopes and inter-:
cepts of all the segments are determined and tabulated. The
shock adiabats were
also plotted fol Sm, Dy, and _Pz, for which the change in slope
of the d-u plot was
most pronounced. The adiabats exhibit kinks near the critical
pressures, indi-
cating the presence of a.second-order phase transition.. The
more gently sloping
sections of the adiabats are probably determined by the
compression of the ex-
ternal low-density 6S shells and by the simultaneously occurring
redistribution
of the electrons among the bands. The change in slope at the
critical pressure I
signifies the completion of these processes and the formation of
low--
compressibility electronic configuration. A more complete
interpretation of
the data calls for calculation of the energy spectra of the
compressed metals.
The authors thank Corresponding Member of the Academy of
Sciences SSSR, Professori
N. P. Sazh:Ln,' as well as Engineers L. A. Dolomanov and V. M.
MuravIyeva for in-
terest and collaboration. Orig. art. has: 2 figures, 2 formW s,
and 1 table.
SUB CODE: 20/ SUBM DAIE: 2~Apr,66/ ORIG REF: 008/ OTH PXF: 003
r-r,4 P/2
.. 4 ~ .: - . -.
ARST RACT: The aaUium-gallium phosph; de Evs,.r-m, was
studied, and the temp-
dot-
fir
1- 10. 5at-n. 2-16. 2atm.(L. I. Marina, A. Ya. Nashel'skly,
S. V. Yakobson,
FIWjANG, Yevgeniy Vladimirovich; BAKANOVA, I.P., red.
[Electrostatics. Direct current; lectures in
physics] Elektro-
statika. Postoiannyi elaktrichaskii tok; lektaii po
fizike.
Moskva, Mosk. poligrafidbo'n i in-t,,1961. 100 p.
(MIRA 16:9)
(Klectrostaties) (Electric currents)
Ok
GENKELIP P.A.; BAKANOVA,.L.V.; SAMYGIN, G.A.
_7 - -
Freezing of plants with a low frost resistance.
Fiziol.rast. 12
no.1269-75 Ja-F 165. (MIRA 18:3)
1,, Institut fiziologii rasteniy imeni, Timiryazeva AN
SSSR, Moskva.
GOKET.-ly BAKANOVA ,
Surface characteristics of the cell prctoplasts of
plantc- in
the state of dornancy. Fizlol..rast. 12-
no.4.-659-664 JI-Ag 165.
(MIRA 18:32)
1. Institut fiziologli rastenly imen!
K.A.Tiuii7azeva AN SSSR)
Mcskva. Submitted March 31, 1965.
BAIWIOVA, 11. 1. , Engr
"An 7Lnvestigation of the Relation of the Productivity
of a Dredge to
the Operation of Washing-Concentrating Equipment." Cand
Toch Scl, Hoscow Inst
of Nonferrous Metals and Gold imeni 111. 1. Kalinin, 29
Nov -54. (VM, 16 Nov 54)
Survey of Scientific and Tec',inical Dissertations
Defended at TJSSR Higher
Education&I Institutions (11)
SO: Surn. 1-10 - 521, 2 Jun 55
I I
"W/f
/'//ifl4t./~D'.D.; RAKAIIOV.A, V.P.
Cutnneous renction with diphthorinl toxin in determining
diphtherinl
immunity. Zhur.mikroblol.eDid. i iTimun.28 no.12:54-55 D 157.
(MMA 11:4)
1. Iz kliniki detakikh infektsiy II Moskovokogo meditsinakogo
instituta im. N.I. Pirogova.
(CORYMACTIRIUM DIPHTHERIAE,
Itoxin, cutaneous renction in immun. determ (Rua)
X7(8);(12) sov/16-59-9-4/47
AV1"M.- BakanovA, N.P., and Apanashchenko, N.I.
TITLE: Determining the Susceptibility of Children to Diphtheria
by the Skin
Method. II. Using Purified Stabilized Toxin for the Skin T~ast
PERIODICAL: Zhurnal mikrobiologii, epidemiologii i
immunoblologii, 1958, Nr 9,
pp 19-22 (USSR)
ABSTRACT: In Part I of this work the authors published the
findings of their
investigations into the susceptibility of children to
diphtheria,
determined by-the skin method and performing the Schick test at
the
same time. Here,.in Part II, the authors describe the effect of
using
purified diphtheria toxin with a glyoe'rine-gelatine
stabilizer, pre-
pared according to the method evolved by P.V, Pavlov and A.G.
Leonoya
at the Institut imeni Gamalei (Institute imeni-Gamaleya). Some
357
children aged from 6 months to 13 years were vaccinated and
kept under
observation. Both the skin test and the Schick test were used.
It
was found that the coincidence in the'lresults of the two tests
in-
creased directly with an increase in the concentration of the
diphtheria
-toxin. At a*ooncentration of 100 Dlm/ml the coincidence
reached 98.8%.
Card 1/2 This was much better than when unpurified toxin was
used, The method
SOV/16;.;59;..g;.;4/.47
Determining the Susceptibility of Children to Diphtheria by
the Skin Method.
11. Using Purified Stabilized Toxin for the Skin Test
was found to be quite harmless for children. The purified
stabilized
diphtheria toxin retained its specific action on animals for
2 years.
The authors recommend further work on the efficacy and
practical ad-
visability of this method.
There are 2 tables, 1 graph and 3 Soviet references.
ASSOCIATION: Kafedra detskikh infektsionnykh bolezney II
Moskovskogo meditsinskogo,
(Chair of Children's Infectious Diseases
instituta imeni Pirogova
of the II Moscow Institute imeni Pirogov); Institut
epidemiologii i
mikrobiologii imeni Gamalei AMN SSSR (Institute of
Epidemiology and
Microbiology imeni Gamaleya of the AMN USSR)
SUBMITITD: February 25, 1959
Card 2/2
BAKANOVA, V.P., APANASFCHF.NKO, 17.11.
Skin test in determinRtion of susceptibility of
children to
diphtheria* Zhuremikrobiol, epid, i ivmun. 29 no.6:38-43
Ja 158 (MIRA 11:7)
1. Iz kafedry detskikh infektsionnykh bolexney II
Reditsinskogo
institute Imeni Pirogova I Institute epidemiologii i
mikrobiologii
imeni Gamalet AMN SSSR.
(PIPITM 1A, immunO1097,
sk1n test in detem. of mmeeptibility (Rua))
BAKIJLEV~ A.F.) rtlcademik, glay. red.; ZAVALISH.M. N.I., prof., zam.
glav. red.; TII.-AKOV., V.D.p prof., zam. glav. red.; IL'ICRU,
K.I., starshiy nauchnyy red.; OBYSGVA, U.S.., starshiy nauch-
nyy red.; PAVLOVA, A.A.,, starshiy nauclinyy red - BAYWiOVAI
T D na chnyry red.; GRISHINA, L.A.p starshiy ;e~.Fre ~.~
(Large medical encyclopedia]Bol'shaia meditsinskaia entsiklo-
pediia. Glav. red. A.N.Bakulev. Mosim, Gos. nauchn. izd-vo
"Savetskaia en'tsiklopediia.11 Vol.26. P6t'*Bbki - professional-
nyi otboi. Izd.2-9 - 1962."'-!:1256 bolumns. [List of articles
and tenrs forthe letter IT" (26th vol.)_.7P~rec~enl statei i
terminov na bukvu UP" (dvadtsat' shestoi t60'4 P. (Phono-
graph record for the article YHeart defects" (Aortal defects
of the heart))Gramofomaia plastinka k statle "Poroki serdtsall
(AortalInye porokd serdtsa). (KIRA 15:10)
(MEDICIU,DICTIONARIES)
BAKULTEV, A.14., akademik, glav. red.; ZAVALISHIN, N.I., prof., zam.
glav. red.; TDIAKOV, V.D., prof., zam, glavo red.; ILIICHEVA,
K.I., starshiy nauchrjyy red.; OBYSOVA, Ye.S., starshiy nauchrWy
red.; PAVLOVA, A.A., starshiy nauchriyy red.; PAKANQVA, T-D--,
nauchryy red.; LEBEDEVA, A.K., red.; GRISMA, L.A.,, tekhn. red.
[Large medical enc-clopedia]Bollshaia meditsinskaia entsiklope-
diia. Glav.red. A.P.Bakulev. Moskva, Gos.nauchn. izd-vo "Sovet-
skaia entsiklopediia.0 Vol.27. ProfilaktJka - Reverden. Izd.2.
1962. 1224 columns [List of articles and terms for the
letters "Pu and "R115-erechen' statei i terminov na bukvy "P11 i
IIRO (dvadtsat'se&moi tom) 4 p. _[Phonorecord appended to the
article "Heart defects" (Combined heart def-ects)]Granofonnaia
plastinka k stat'e "Poroki serdtsall (Kombinirovannye poroki ser-
dtsa). Vol.28. Revmatizm - RunWniia. Izd.2. 1962. 1248
columns. _[List of articles and terms for the letter nRH]Pe-
rechent statei i terminov na bukvu nRII (dvadtoat' vosImoi tom)
4 P. _ (Phonorecord appended to the article "PlWchogenia"]
Gramofonnaia plastinka k statle "Psikhogenii" (psikhogennye psi-
khozy) (MEDICINE~-DICTIONARIES) (~aRA 15:12)
SOKOLOVA, N.I.;,Rk-WQVA,,V-A-; SHABAROVA, Z.A.;
PROKOFIEV, MI.A.
Isolation of pyrimidine deoxyribonucleosides and the
production
of their aminoacyl derivatives. Biokhimiia 27
no.6:1079-1084
N-D 162. (MIRA 17: 5)
1. Laboratoriya khimil br;l:ca Gonudarstvennogo
universitata, imani
Lomonosova, Moskva.
SOKOLOVA, N.I.; BAONOVA, V.A.; SHABAROVA, Z.A.; PRPKQFIYEV,
M.A.
Aminoacyl deri4atives of nucleosides. Part 6: Synthesis ands
properties of aminoacyl derivatives of deo*rib6nucleosides
Zhur. ob. khim. 33 no.8s2480-2486 Ag, 163.. (MIRA 16:11)
EAKANOVA,,V.V., assistent
Accuracy of relief mappihgs on 1:2000 maps
prepared Ir7
stereotopographic surveying. Izv. vys. ucheb.
zav.; geod.
i aerof. no.4:75-81 163. (MIRA 17:9)
1. Moskovskiy institut inzhenerov
goodezii,serofotosllyemki i
kartografii.
5(1,,3), 3o(l) SOV/153-2-4-29/32
AUTHORS: Berlin, A. A., Bakanova, Ye. G.
TITLE: Production of Stable Emulsions, Having a Washing Effect, Prom
DDT
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. R'himiya i
khimicheskaya.
tekhnologiya, 1959, Vol 2, Nr 4, pp 622 - 625 (USSR)
ABSTRACT: The use of aqueous dispersions of insecticides in various
branches of industry, agriculture, and medicine has been in-
creasing (Ref 1). In this connection, the discovery of eco-
nomical production methods for stable emulsions, of DDT so-
lutions in petroleum, and other solvents rith washing pro-
perties in addition to highly insecticide effects has become
necessary. In order to solve this problem, the authors tested
the following emulsifiers and stabilizers: polyethylene-glycol
esters of alkyl phenols (OP-4, OP-7, OP-lo, OP-2o, etc), more-
over, emulsifiers produced from protein waste, technical starch,
sulfite lyes, oxyethyl- and carboxymethyl cellulose, sodium
alginate, the diethyl-aminomethyl-derivative salt of alkyl-
phenol-polyethylene-glycol ester (eaualizer A). Among the stabi-
Card 1/3 lizers mentioned, water-soluble keratin (keratein) is
Pro,duction of Stable Emulsions, Having a Washing Effect,
SOV/153-2-4-29/32
From DDT -`
especially interesting. Figure 1 characterizes the surface
activity of the emulsifiers investigated. Hence it appears
that the most active ones are: OP-4, OP-7 and keratein
(disso-
lution product of waste containing keratin in 3-100%j sodium-
sulfide solutions, or in 1-3~'. alkali solutions at
6o-601,Ref 2).
Table 1 shows the effect of the addition of OP-4 to keratein
on the properties of the emulsions (turpentine in water).
Hence it appears that the stability and emulsifying capacity
of keratein rapidly increase by a 0.1 to 0.01~0 OP-At
addition.
Comparatively highly disperse, stable emulsions are formed.
They did not dissociate into layers, even after a three-month
stora-e (Fig 2). In order to obtain maximura homogenization
of the emulsification of DDT-solutions, they were put into
an ultrasonic field. The best results were obtained with P_
frequency of 2o-300 kilocycles (Ref 3). The emulsions were
sufficiently stable (Fig 3). The washing capacity was tested
by means of artificially soiled cotton samples in hard rater
for 20 minutes. The rinsed and dried samples were photometri-
cally recorded. Tables 2 and 4 show the results. Thus, the
Card 2/3 addition of OP-4 to kerittein increases the
stabilizing effect
Production of Stable Emulsions, Having a Washing Effect,
SOV/153-2-4-29/32
From DDT
as well as the foam-forming capacity of the protein. The same
emulsifier rendered possible the production of concentrated
aqueous stable suspensions of DDT- or hexachlorocyclohexane
solutions in turpentine with a content of active substance
of 6o-65%, 2o-25% of fatty acids in soaps may be substituted
by keratein. Soaps thus modified have a higher foam-formation-
and washing capacity. Thus, considerable amounts of edible fats
can be obtained from the soap industry, and can be used for
consumption. There are 4 figures, 2 tablea,and 5 Soviet refer-
ences.
ASSOCIATION; Moskovskiy tekhnologicheakiy institut myasnoy i
molochnoy
promyshlennosti; Laboratoriya vysokomolekulyarnykh soyedineniy
(Moscow Technological Institute of Meat and Milk Industry, La-
boratory of High --molecular Compounds)
SUBMITTEDs June 11, 1958
Card 3/3
Organic - insectofung-l'ides. XVIII. Now method of
VP_,P - of t. Of chloTo- and idchlorotblopbospboric
.,id, g. NI kzjjava Ya. A. 11.1andel'baurn, N. N.
Niel' nik d E. 1. ventsitskil. Zhur. ObAZAA Kbim.
6, X!~Ian,); ,f. C.A. 59, 2415d.-Rtfluxing fine At
wb~c in 2-4 fold excess of abq. EtOlf in the pmence of 0.1 g.
kig(OAc)~ and a little iodine foT activation of Al, until all Al
goes into soln. results in a rapid prepn. of AI(Ollt~. 11rith
an equimolar amt. of EtOH. C*Ho is used as a diluent and the
reaction is much s3ower. To 17 g. PSC13 there was added
with coc4ing a suln. from 0.5 g. At and 3 g. EtO-11 in 8 mi.
CJ10; after 3 hra. at W the mIxt.,vw washed with Ice-4
acidified with IICJ. drW, and distd., yielding 40m-
EtOPSCII, bt~ 689, d: 1,3M, Pty IAW
To 34 S. PSK
v= added with cooling a soln. from 2 S. Al and 25 ml. EtOH;,
after 2 hrs. at "0 the cooled mixt. was washed with cold:
1110. acidified with-. RCI, yielding 42%. (EtO)jPSCII ba
k1bod.
_7 of dikhlopbophorit atid.rontalulng a ii amWe group IUL-
thot Aliphatic irter'ndlcal.' Shvetsovs
Afel .11
N.N; 'nikovsfidN.T. arteml- W
d.
~Ajjropfiate aldehydts and - estjrrs of carbande acid were
7itmed and-- treated with (ROV,%H; 7afterstinding 14
days at iroaan tcmp,_ the* products were extd.~wM C*Hj.
Imshed with H.O. dfled:abd distd. No other detaili are
'given _41115, were prepd.. (J?OV,(S)SCHN.R'COjR'~
IR', %yield,b.p.. dn, and r.V givtn). %30Z,
(RjR Me,H, F
JAM; Fr, Hj Ef, 60.7, b", 82% LOW6, 1.4912; iso-Bu,
H. P-1, 46.6. ba-175 122-4', (m. 22*); Es, Me, Ej. 20 8
'N-is 107-14* 1.1814, 1.6041; Bu, Me, Et, 53.7, b,.,3
522 I.W75. IAM; iso-Bu, Me, EI, 57,5, bt., 12+--i-,
P~
5- V.
W 7~
-Ot ke- t4 ll,*~Z. SIMMeAs a I mle-"Mv
oi r7r~dim,
7t
v rn"U= --.
Elf
s-.t,
-~,- .. ~;v
1 1. - -
I
I
4
I
b,11
MELINIKOV, N.N.; MANIELIBAUM, Ya.A.; SVENTSITSKIY, Ye.I.;
Ekr--UTOVA, Z.M.
On organic insectofungicides. Part 271 New method for the
preparation of eaters of chlorothiophosphoric acid.
Zhur.ob.khim.
27 no-7:1908-1910 JI 157. (MIRA 10:10)
10'Nauchnyy institut po udobreniyam i insektofungisidam.
(Insecticides) (Chlorothiophosphoric acids)
M&LINIKOV, N.N.; MANDELIBAUM, Ya.A.; SHVETSOVA, K.D.;
BAKANGVA, Z.M.
LOMA.KINA., V.I.; ZAKS, P.G.; KLISHTEYN,
I.M.-,-,-POPOlT,-T-.-T.--,-
PONROVSKIY, Ye.A.; BDGHAROVA, L.P.; SEDYKH, A.S.;
UKRAINETS, N.S.
Improved technologj for producing thiophos, metaphos,
chlorophos
and other phosphorus organic insecticides and
investigation of
new insecticides and fungicides derived from the
esters of
phomphoric acids. [1~rudy] NIUIF no.164:11-14 '59.
(KRA 15:5)
(Insecticides) (Fungicides)
5 (3)
AUTHORS: Mandellbaum, Ya. A., ?Aellnikov, N. N., SOV/79-:29-445/77
-Bakanova, Z. 1.T.
TITLE: From the Fi~ld of Organic Insectilcides-and Fungicides
(Iz oblasti ortanicheskik.h lnsek~oiunti,tsidov). XLI. On the
Reaciion of Dialkyl-ohlOr07thiothoaphatea and
Thiophosphorus-trichloride IWIL'th Phenols in the Presence of
Tertiary Amines (XLI.'O vzaimodeystvii dialkilkhlortiofoafatov.
i tiotrekhkhloiistogo fosfora s'fenolami v prisutstvii
tretichnykh aminov)
PERIODICAL: Zhurnal.o.bshclie~i khlmfi,-1959, Vol 29; Nr 4,
PP 1149-1151 ~ (USSR)
ABSTRACT: In connection.with.the papers mentioned in the references
1-5 the.authors especially in vesti`g~ied the.reactions of
ditilkyl-chl8ro-thiophosphates xy'ith phenols in the presence
of tertiary amines. This reaction proceeded already at room
temperature in good yields and produced the corresponding
dialky-aryl-thiophosphates. The solvents were.of no
importance, and thd reaction proceeded also without solvents,
but in this case the stirring of the reaction mixture is
dard 1/3 difficult owing to the crystallization of ammonium
chloride.
From the Field of Organic'Insecticides and SOV/79-29-4-25/77
Fungicides. XLI. On the Reaction of
Dialkyl-chloro-thiophosphates and
Thiophosphorus-trichloride With Phenols in the Presence of
Tertiary Amines
Dialkyl-aryl-thiophosphates are obtained in good yield also
in alcoholic solution, which indicates that the reaction
with
phenols proccods more rapidly than with alcohols. The
authors
inva~!ttigated the reaction of
dialkyl-chloro-thiophospheLtes
with phenols in the presence of triethyl amine. 0,0-dialkyl-
0-aryl thiophosphates were found to result. The mechanism uf
the formation of dialkyl-aryl-thiophosphates from dialkyl-
chloro-thiophosphates and phonols in & presence of tertiary
amines can be best explained in the following way: There is
an exchange reaction between amine phenolate and dialkyl-
.~chloro-thiophosphate, yielding the hydrogen chloride of
the
bLmino and of dialk.yl-aryl-thiophosphate. On the reaction
of
:,~Dhenols with thiophosphorus trichloride in the presence
of
triothylamine aryl-dichloro-thiophosphates were obtained in
sufficient yield. There are 1 table and 5 references, 4 of
which are Soviet.
Card 2/3
From the Field of Organic Insecticides and .1
SOV/79-2(1-4-25/77
Fungicides. XLI. On the Reaction of
Dialkyl-chloro-thiophosphates and
Thiophosphorus-trichloride With Ph6nols in the Presence of
Tertiary '-~inerj
ASSOCIATION: Nauchnyy institut -Do udobreniy&m i
insektofwM;itsidam
(Scientific Institute of Fertilizers, Insecticides and
Fungicides)
SUBMITTED: M.,)rch 12,195fl
Card 3/3
5.1320,5.3630 77380
SOV/79-30-1-4i/78
AUTHORS: .Mandel'baum, Ya. A., Mellnikov, N. N., Bakanova, Z. M.
TITLE: Concerning Organic Pesticides. LII. Concerning the
Reaction of Aryl-Dichlorothiophosphates With Magnesium
Ethoxide
PERIODICAL:. Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp 194-
197 (USSR)
ABSTRACT: The reaction of aryl dichlorothiophosphates with
magnesium ethoxide was investigated with the purpose
of obtaining some new pesticides, and also in order
to study the relationship between the reactivity and
the structure of the chlorothiophosphoric acid deri-
vatives. The reaction can proceed according to
(1), (2), and (3), depending on the ratio of the
reagents, the temperature of the reaction, and the
time of reaction.
Card 1/4
Concerning Organic Pesticides. ILII. 77380
Concerning the Reaction of Aryl- SOV//79-30-1-41/78
Dichlorothiophosphates With Magnesium
Ethoxide 2 ArOPSCIS + (CI jHb0)jMg ---0-.2 Aro PSCI + MgCII
(1)
CIH50>
2 ArO
CIH50>PSCI + (C$H50)2Mg - 2 ArOPS(OC2%)s + MgC12 (2)
2 ArOPS(GCIHB)2 + (C24&0)%Mg - 2 (C2Hb0)2PS + (ArO)2Mgl (3)
Aryl.dichlorothiophosphates and magnesium ethoxide
taken in stoichiorretric amounts gave chiefly alkyl aryl
chlorothiophosphates or the corresponding diethyl aryl
thiophosphates. Transesterificatipn (Formula 3)
oc6urred only with large excess of magnesium ethoxide
and on prolonged heading. Accordingly, 0.1 mole
phenyl dichlorothiophosphate and 0.05 mole magnesium
ethoxide on heating for 3.5 hr gave 0-ethg1 0-phenyl
4%; bp 95-100 C/0.2 mm).
chlorothiophosphate (yield 6
The same reagents taken in amounts of 0.05 mole and
0.1 mole, respectively, gave on heating for 7 to 17 hr
0,0-diethy; 0 henyl thiophosphate (yield 82-91%;
bp 120-122 U70 .8 rmn). 0.1 Mole 2 4,5-trichlorQphenyl
Card 2/4 C j
Concerning Organic Pesticides. LII. 77380
Concerning the Reaction of Aryl- SOV/79-30-1-4i/78
Dichlorathiophosphates With Magnesium
Ethoxide
dichlorothiophosphate and 0.3 mole magnesium ethoxide
on heating at 65-70 0 C for 18 hr gave 0,0-diethljl 0-2,
4,5-tr-'chlorophenyl thiophosphate (yield 78%; bp 1300 C/
0.13 nun); also, 2,4,5-trichlorophenol (yield 13~6;
mp 620 C), and triethyl phosphate (yield 15%). Under
similar conditions, 0.1 mole 4-nitrophenyl dichloro-
thiophosphate and 0.3 mole magnesium ethoxide gave 0,0-
aiethyl-0,4-nitrophenyl thiophosphate (yield 40%; bp
156-1580 C/O.'- mm); also, p-nJ;trophenol (yield 28%;
mp 1120 C), and 0,0,0-triethyl thiophosphate (yield 30%;
bP 51-520 C/0.3 mm). There are 10 references, 2 U.S.,
I U.K., 7 Soviet. The U.S. and U.K. references are:
H. D. Orloff, C. J. Worrel, F. X. Markley, J. Am.
Chem. Soc., 80, 727 (1958); h. F. Hudson, I;. Keoy,
J. Chem. Soc., 1953 , 2463; T. R. Fukuto, R. L. Metcalf,
J. Agr. Food Chem., 4, 930 (1956).
Card 3/4
Concerning Organin Pesticides. LII. 77380
Concerning the Reaction of Anjl- SOV/79-30-1-4i/78
Dichlorothiophosphates With Magnesium
Ethoxide
ASSOCIATION: Scientific Institute for Fertilizers and Pesticides
(Nauchnyyyinstitut po udobreniyam i insektofungitsidam)
SUBMITTED: JanuarY 5, 1959
Card 4/4
MANDELIBAUM, Ya.A.; NELINIKOV, N.N.; BAKANOVAp ZAKS, P.G.
Organic insecticide-fungicides. Part 612 Syathesis of some
mixed ethyl mercaptoethyl thiophosphates. Zhijr.ob.khim, 31
no.120947-3949 D 161. (MaU 15:2)
1. Nauchnyy institut po udobreniyam i insektofungitaidam im.
Ya.V.Samoylova, Moskva*
(Phoophothioic acict)
(Insectioides)
MELINIKOV., N.N.; MANDELIBAUM., YA.A.; BAKANOVA.,
Z.M.
Organic insecticide-fungiciden., Part 63s
Synthesis of some
derivatives of phosphinic acids. Zhur.ob.khim, 31
no,3-2Q953-
3955 D 161* (MIRA'15:~) ,
1. Nauchnyy institut po udobreniyam i
ineektofungitsidam
imeni. Ya.Vo Samoylova, Moskva.
(Phos~phinic acid)
I
,Insecticides)
7-d A( )I FWTm F-c A( b
AB IS, T R-A C TThis Author's Certificate introduces a method for
producing new
SmMll -.---i4junb2
~WO PTF SOV: 000
-LIICT
OTHER: 000
Lm-
kv
NO REF SOV: 000
'LCard,_U
MMMMW~
OTHEP:
L 1687-66 &;T(.1)/EWT(m)/EPF(n)-2 _(m)/EPA (,w)414W(t W-10 W IJP(c)
JDAT
ACCESSION OR: -AP5020552 UR/0294/65/003/004/0520/0523~rj
AUTHOR: Bakanovich, Gj -1. Grechikhin, L.-' 1.
TITLE: Use of,. -emission spectra of the co.ppe atom for
diagnostics_of a plasma
6S
~SOURCE: TePl9ftika vysokikh temperatur, v. 3, no. 4, 1965, 520-623
-TOPIC TAGS: "jAdisima didgnostics, emission spectrum, copper, Stark
effect,
Van de'r Waals"t-quati6n, electrodes, plasma charged particle
ABSTRACT: Since copper pairs formed by erosion of electrodes, exist
in all typeE
of plasma apparatus (plasmatrons, magnetohydrodynamic generators,
arcs, etc.)
the work described in the article is aimed at selection of the
corresponding spec-
tral. linen. at fixing their basic constants (transition probability
and the Stark and
van der Weals constants) at evaluating the effect of various factors
on the width
of the Belecied lineab and at explaining errors in the measurement of
temperature
and concentration of the charged Oartibles. The experiments were
carried out.
with a direct current arc (1 8 amp) between copper or brass
electrodes under
CGr.d11/2____