SCIENTIFIC ABSTRACT VINOGRADOV, A.P. - VINOGRADOV, A.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001859910009-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Irofes--or P. A. Paneth
at Mainz. In recent years
coamochemical problems. Ile
national organizatiom and
conferences. His studies
the geochemistry of
terminations etc are of
SOV/7-59-1-14/'14
he mainly studied geochemical and
was a member of various inter-
participated in numerous scientific
in the fields of radiochemistry: of
inert gases, of absolute Lf:e de-
lasting value.
Card 2/P

3(0) SO11/7-519-2-1/14
AUTHOR: Vinogradov, A. P.
V
TITLE: Academician A. Ye. Fersman (Akademik A. Ye. Fersman)
( 75th Birth Anniversax-j) (k 75-letiyu so dnya rozhdeniya)
PERIODICAL: Geokhimiya, 1959, Nr 2, PP 103-104 (USSR)
ABSTRACT: Aleksandr Yevgenlyevich Fereman was born in St. Petersburg
on November 8, 1883. During big studies at Moscow University
he applied himself particularly to the study of geochemistry.
At the said university he met V. I. Vernadskiy, who became
his closest friend. Having finished his studies he did post-
graduate work at several foreign universities and came to
know a number of European ore deposits. In 1911 he returned
to St. Petersburg Akademiya nauk (Academy of Sciences), but
found his field of work at the mineralogicheskiy muzey Ake-
demii nauk (Mineralogical Museum of the Academy of S efices)
0
too narrow. During the years prior to the October Re4tion
he traveledthroughout Russia in search of new ore deposits.
His talents became especially apparent after the October
Revolution. He mainly carried out investigations.in the field
of geochemistry, in fact, he and V.-I. Vernadskfy are regarded
Card 1/2 as the founders of this branch of science. Besides his four-

Academician A. Ye. Fersman ( 75th Birth A=1var*arY~ SGOT17-59-2-1114
volume book"Gookhimiya"("Geochemistry") he has published
various books on geochemical and mineralogical prospecting
methods.of foreign mineral raw materials and precious stones.
Ile departed almost a decade and a half ago, but his students,
collaborators, and friends remain under the spell of hi3
strong personality.
Card 2/2

50) 3(9)
AUTHORS! V.: /13
Kutyurin, V. M., 3011/7-59-1
Zaf-c;'ozhnyy, 1. K.
TITLEs Fractionation of the 13;~tcpos cf Atm3sphario Oxygen
(F~7aktsioni=vaniy~ iz.,~tv;*v stmosfernego kia.loroda)
PERIODICAL: Geokhim'Lya, 19s.:9, Nr 1, !-P 195-205 (USSR)
ABSTRAM Compared with the axygen of tha hydz3sphare an4i of phcto-
synthesis, atmcapher:L~3 oxygen has a higher oontent of the
isotope 0 16 (Table 1). The p.raeant papor was written for
the parpose of explaining tt:18 differ.-anca. The two-beam mass
spectrometv-,r MS-~_, was ussi foz~ aeas-arements, and atmospheric
oxygen was used as standaza. Investigations were carried out
of the oxyg4n of th2 photointhitsis of diatum algae carried out
at the ~Sevastopallpkva b_~olcg~,-haakaya stantsiya (Chernoye
more) (Sevastopol' Statf.--n (Black Sea)) and of the
fresh.-wat.:,r plan`., car-acz:nzi5 (Tabla 2). Heraf-om results
a rueffioient of 0 IQ e-rinhm-)nt --*n tla-., atmcaphs-ra of 1.018.
Moreover, fract1#:r-a'1.4,,n .1.-_ 1-.1.9 t7rL! -was A
mjinimum effe,,t (a-0,997) c-!.-vvrrfve. only '.n the vase vf consider-
Card 1/3 able hzz_,id:Lt-. A t~ gat ~on w.,i,3 coarvied cut of

Fractionation cf the Iestopee of Atlmc~apharlc SOV/"-5c,--3.--/3
Oxygen
fracticnat4c,n in the -.;rean. TL9 eampiss ware colleated during
tha sezQnd vDyage of the Morskaya Antarktioheska7a akapeditsiya
na d/& "O-Z's" (Antaratii Sea Expe-I.-Ition rf the D',esel-olectric
vegssl I~Obl"). Tho whitra, samples were taken are shown
on a chart. Samp'-.3s were t.~,xen fzom vari-jus dGpths at each
Pl,'I.-,O (Tabla 1)3 f,:r 5 placas the vtriaticn cf ths tols.2. oxygen-
and .0 i8 c,.ntent --Ith lapth L,, g?,iph:L-,P-`,y raprasenzed (Figa 2-6).
Tha fraut4-o;at-:,-m ~Ls 1,0110'I thir is not sufficient
in jriir to t9 abli zc sxpl.s,..n the high 0 o-ntsnt of the
atmosphera. tc tho a-ithors this omiltent is a function
of the CO~ ...:;ontant cf the a,;n,,)9pb927a. The reascn for this
is tha. dliqv~,.,iat4on -.wf SO2!n that stratcaphore. This would
ri,o"7ide the of draw.-ng o orvilus ions from the isotope-
v
ratio in fcanils with respvc;t to "he c3neontraticir of CO 2 in
Thar,~ figure-3, 3 tablesp and
13 reforer.-.ief,, 5 -,t rh-*,.,-,h Sovket.
Carl 2/3

Fractionation of the Isotopes of Atmospheric SOV/7-59-3-1/13
Oxygen
ASSOCIATION: Institut geokhimii i analiticheakoy khimii im. V. I.
Vernadskooo AN SSSR: Moskva (Institute of Geochemistry and
Analytical Chemistry imani V: I. Ve-rnadakiyAS USSR Moscow)
I
SUBMITTED: January 14, '959
Card 3/3

VINOGRADOV. A.P., almdamik
Paadamental problems of radlochomistry.
418-422 159.
(Radiochemistry)
Kblm.nauka I prom. 4
(NIRA 13:8)

o\) -A
3(5) ?- -a-
AUTHORt None Given SOV/7-59-6-15/17
TITLE: Abstract of the Most Important Articles From "Geochimica et
Cosmochimica Acta"t Vol 15, Ur 1/2, 1958
PERIODICAL: Geokhimiya, 1959, Nr 6, PP 564 - 567 (USSR)
ABSTRACT: A short abstract is given of the following articlest
Hitoshi Sakai and Kazuo Sato: Isotopic composition of the
common lead of Japan
P. W. Richardson and H. E. Hawkes: Adsorption of copper on
quartz
R. Coulomb, M. Goldsztein, and M. Is Merciers Uranium in some
French granites
A. E. Ringwood: The constitution of the mantle - II. Further
data on the olivine-spinel transition
Marjorie Hooker; Data of rock analyses - IV Icelandic periodical
and serial literature. Bibliography of rock analyses
H. Sakai and H. Nagasawat Fractionation of sulphur isotopes in
volcanic gases
R. W. Stoenner and J. Zdhringers Potassium - argon age of iron
meteorites
Card 112 H. F. Phillips and 1. A. Bregers Isolation and identification

Abstract of the Most Important Articles From 307/7-59-6-15/17
"Geochimica et Cosmochimica Actall, Vol 15, Hr 112, 1958
of an ester from a crude oil
R. F. Conley and W. M. Bundyi Mechanism of gypsification
G. Kullerud and G. Donnay: Natural and synthetic ferroselite. A
roentgenographic mimesis of ramme-lbbolV"41.
A. P. Vinogradov: The isotopic composition of rocks of the earth
and of meteorites
Helmut G. F. Winkler and Hilmar von Platen% Experimental meta-
morphosia of rock - 11. Formation of anateotic granitic melts
in the metamorphosis of NaCI-containing clays that are free
from lime.
R. M. Garrels and C. R. Naeser: Equilibrium distribution of
dissolved sulphur species in water at 250C and 1 atm total
pressure
H. T. Evans, Jr. and R. M. Garrelss Thermodynamic equilibri,a
of vanadium in aqueous systems as applied to the interpretation
of the Colorado Plateau ore deposits
Card 2/2

3(l) SOV/11-59-10-2/16
AUTHORs Ti~jjbgra4ov, A. P.,
I __ I - I .. . .
TITLE: Meteorites and the Earth's Crust
PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geologicheskaya, 1959,
No- 10, PP 5-27, (USSR)
ABSTRACTi Problems of origin of various types of meteorites in comparison
with the origin of volcanic rocks of the earth are treated in
this article. All the meteorites can be divided into two
groups, chandrites and achondrites. Chondrites containing
chondrules of various dimensions are divided into unchanged,
recrystallized (changed) and carbonaceous, containing carbon,
water and, in some cases, a chloritic mineral. On the aver-
age, all meteorites of this group contain about leo iron and
6% troilite. Their body is composed of olivine with ensta-
tite, bronzite and hypersthene (table 1 and 2). Achondrites
are divided into two groups different by their structure and
mineralogical and chemical composition, the feldspar-contain-
ing group and that without feldspar (Tables 1, 2). Feldspar-
Card 1/11 containing achondrites usually contain anortite, and their

sov/11-59-10-2/16
Meteorites and the Earth's Crust
structure and mineralogical and chemical characteristics corres-
pond to the characteristics of gabbro-diabases. Their breccia-
like structure is a special feature of all achondrites. Accord-
ing to the author, the formation of all meteorites occurred in
zones of feeble gravitation: the porosity of meteorite bodies
proves it. As to the rare elements in meteorites and in the
volcanic rocks - their content in meteorites is much lower
than in volcanic rocks. The general alkaline content de-
creases from chondrites to feldsparless achondrites, which in
turn have the highest SiD content. The Ca/Sr relation in all
stone meteorites and duniies varies from 1000 to 2000 owing to
a small Strontium content, whereas in volcanic rocks this con-
tent varies from 50 to 200. The author also gives variation
diagrams of content of other rare elements (figuresl-4). A
decrease in the alkaline content in meteorites can tentatively
be connected with the high temperature differentiation pro-
cesses of meteoritic substance into various types of meteor-
ites, though the degree of such a differentiation is only
Card 2/11 alight. Thus, the differentiation process of meteorites is

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
not identical with proc6sees occurring in the Earth's crust
such as liquation, fractional crystallization, etc. As the
dunites in the volcanic rocks contain still less rare ele-
ments, the author thinks that dunites are residual rocks
from the melting out of the light fraction (the Earth's
crust) of the Earth's mantle substance by its composition re-
sembling the chondrites. Studying the isotopic composition
of meteorites and volcanic rocks, the author states that the
sulfur contained in different meteoS~te ~4 is absolutely iden-
tical by its isotopic composition S /S - 22.20, which in-
dicates a reducing character of the medium in which the
meteorites were formed. The isotopic sulfur composition in
dunites is either near or identical to that of meteorites,
but is considerably different from the isotopic sulfur con-
tent of volcanic rocks, particularly of granites (tables
8-9). The same tendency of increasing dispersion of iso-
topic composition is observed for the oxygen content in vol-
canic rocks from the plutonic dunites to the outcropping
Card 3A1 granites (tables 10-12). The isotopic oxygen composition

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
in meteorites is identical and the isotopical 0 16 /0 18 composi-
tion in dunitee is the nearest to that of meteorites (Table
13)- Only carbonaceoue meteorites are an exceptiogA their
isotopic oxygen composi 1~ on shows an increase in 04 j (tables
14-17). The isotopic C /C13 composition in volcanic rocks
and meteorit 13 is almost similar. There is a tendency to in-
crease the C content in more acid rocks of the Earth's sur-
face. The isotopic carbon content in dunites is again very
similar to that of meteorites (table 18-19). In general,
taking the isotopic compositions of sulfur, oxygen and car-
bon as a whole, their correlations in all meteorites are very
similar, and dunites, more than other volcanic rocks, are
comparable to meteorites (chondrites) by their isotopic cor-
relation. This proves, according to.the author, that the for-
mation of meteorites occurred in reducing conditions and at
higher temperatures than those observed in the Earth's magma
differentiation processes and that the processes which gov-
erned the formation of meteorites were quite different from
Card 4/11 those on the Earth. To determine the character of distribu-

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
tion of elements and isotopes in meteorites, the author sub-
jected a thin rod cut out of a meteorite to so-called zonal
melting. If a narrow part of this rod is heated to a melt-
ing point and the heater is repeatedly moved along the rod
in the same direction so that the menisc of the liquid phase
always passes over the hard phase, then the substances low-
ering the melting temperature will pass into the liquid phase,
and those increasing the temperature will remain in the hard
phase. The smaller is the distribution coeffictent
Khard phase
KU ---------- the more effective is the differentiation.
KLiq. phase In this case, the silicate phase of a
meteorite was subjected to the zonal melt-
ing. The analysis of the meteorite was
made by L.S. Selivanov separately for the m:..,-%etic and non-
magnetic fraction. By a repeated demagnetization, 11% mag-
netic and 89% non-magnetic fraction was obtained. The compo-
Card 5/11 sition of the non-magnetic fraction is as follows: SiO 2 -

SOV11-59-10-2/16
Meteorites and the Earth's Crust
44-83%; TO 2 0.12%; Al 0 - 1.80%; Cr 20 -0-71%; FeO -
14-46%; Cao 2.33%; Mgo2_327-43%; Mno - 6 39%; Na 20 - 0-56%;
K20 - 0.10% and P20 - 0-74%. Not taking into account the de-
tail of chemical CoAposition of an average chondrite, these
chondrites are composed of two main molecules, the olivine
molecule Mg 2SiO (Fe SiO content 25%) and the molecule of a
rhombical pyroxine jg2S104 (FeSiO content 25%). The phase di-
agram of the MgO Byatem, which gives the 2MgOSiO 2 and
MgOSiO2 phaefis i;Swieh known. In this system, the 2MkOSiO 2
melts at 18000, and the lowest temperature of the liquid
phase of this system corresponds to the MgOSiO 2 composition
which incongruently melts according to the formula
2MgSiO 3 ' M92S'04 + Sio 2-
All other components of the silicate phase are distributed
in the Mg SiO and SiO 2 phases. The more or less exact con-
tent of oliviAe and pyroxene in the chondrites is given
(table 20). The amount of CiO 2 content obtained by the melt-
Card 6111 ing of a chondrite is calculated, according to W. Wahl (us)

UOV/11-59-10-2/16
Meteorites and the Earth's Crust
in %: The Composition of Pyroxenes (in %)
CaSiO 3 - 2.26 0-58 S102
MnSiO 3 - 0-51 0-14 11
MgSio 3 - 16-50 4-93 of
FeSiO 3 - 7.36 1.67 It
26.23 7-3
Consequently, 7.3% of S102 is for the chondrite, and the oli-
vine fraction is in this case MgSiO 30.67 + Fe SiO 13-65
44-52% of the whole chondrite. Thui a maximum i-3%40f Sio 2
(plus admixtures) could be melted, of a chondrite, at a temper-
0
ature of 1557 . The results of zonal melting, described in
detail, of the silicate fraction of a meteorite are given
(table 20). From it, it can be seen that about 2% of SiO 2
was squeezed out from the silicate fraction. The amount of
volatile components in the silicate fraction is extremely low
Card 7/11 and only sulfur is volatilized and deposited on the walls of

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
the quartz tube. If a volatile component F is added to the
silicate fraction, at a temperature of about 16000, mainly po-
tassium is volatilized, then uranium and other elements
(table 21). Supposing that the Earth's mantle is composed of
substances which by their composition are close to the chon-
drite substance, and that the formation of the Earth's crust
is the result of the melting out, and degasification of the
mantle is analogous to a vertical zonal melting coinciding
with the Earth's radius, then the possible thickness of the
Earth's crust can be tentatively calculated. The zonal melt-
ing and subsequent calculations show that the maximum thick-
ness of the Earth's crust will be 7% of the thickness of the
Earth's mantle. The dunites are a residual product of the
Earth's mantle melting and, as a rule, contain about 2% of
pyroxene. Thus, if the whole mantle substance were melted,
about 6% of fusible silicate material would be obtained. It
explains, says the author, why the Earth's crust is relatively
so thin. The thickness of the Earth's mantle can be approxi-
Card 8/11 mately calculated for the determination of the concentration

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
of a given chemical element in the crust. Obviously, the melt-
ing and degasification process in the Earth's mantle and the
differential process is continuous. Isotopic composition of
various metals show that (even for the same metal) the process
of their separation from the magma occurred at widely differ-
ent epochs. Two different differentiation processes must be
considered in the formation of meteorites: one for the forma-
tion of chondrites and iron or stone-iron meteorites and an-
other for-the formation of achondrites. In the first process,
the similitude in the dimensions and mineralogical and chemi-
cal composition of chondrules indicates the existence, at some
stage of evolution of the meteoritic substance, of a differ-
ent phase of this substance. Presumably, it was in a state of
nebula formed by the drops of liquid silicates, agglomerated
with Fe after many recondensation and purifying processes,
when passing the zone of 1,8000, and forming the chondrules.
These meteorites wore formed as a result of agglomeration of
separate chondrules and of loose parts of chondruleD dostroyod
Card 9/11 during collisions in space. The chemical composition of achon-

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
drites without the feldspar indicates that their formation
occurred in small spatial bodies without the participation of
volatile components, and at higher temperatures than observed
in the Earth's crust. The author compares the process of for-
mation of feldspar-containing achondrites to the regenerating
process of Dinas bricks used for lining in open-hearth fur-
naces and which were for a long time subjected to high temper-
atures. Zones of various composition were formed in these
bricks and the transitory zone was characterized by the accumu-
lation of Al 20 ; CaO and TO 2 as in feldspar containing achon-
drite. Thus t;o basic processes can be observed in the forma-
tion of meteorites; 1) mixture and agglomeration of silicate
chondrulea with iron masues and troilites from whict, chon-
drites and iron-stone and Dtone meteorites were formed and
2) the formation of achondrites from the chondrites on celes-
tial bodies of small dimension, which explains the absence of
volatile elements. The name of A.V. Trofimov is mentioned in
this article. There are 22 tables, 4 graphst 4 photographs
Card 10/11 and 32 references, 15 of which are Soviet, 9 English, 4 Ameri-

SOV/11-59-10-2/16
Meteorites and the Earth's Crust
can, 2 German,l French and 1 Swiss.
ASSOCIATION: Institut geokhimii i analiticheakoy khimii im. V.I. Vernadskogo
AN SSSR, Moskva (Institute of Geochemiatry and Analytical
Chemistry imeni V.I. Vernadskiy of the AS USSR, Moscow)
OUBUTTED: January 10., 1959
1
Card 11/12

5(0)
AUTHORS: Vinopradov A* P' , Alimarin, 1. P.v SOV/32-25-2-78/78
Tanana;lev, Dymo v , A Te re n t I ye,,r, It, , P
Lurlye, Yu,,~ Yu. p Chernikhovj Yu. A. , Koronnan, 1.
Kuznetsovt'V. I., Gellmant 7". E., Klimovr~, V. A.,
Shevele'va, 1"o Sot Chunache.-Oco, M. 11T., !leventtyeva, Ye. Ao
and others
TITLE; Mirra Osipovna Korahtin (N-drra Ooirovna Korchun)
PERIODICAL: Zavodskaya Laboratoriya, 1959, Vol 25, Nr 2, p 255 (USSR)
ABSTRACT: Mirra Osipovna Korshun, one of the leading acientisto in the
field of the microanalysin of orpanic compounds, died on
De'ecriber 1, 1958. The deceasod L;raduated in 1029 from the
II MGU where she had studied chemintry. In 1933 zhe became
head of the analytical group. From 1935 onward she was Head of
the Laboratory for Microanalysen at the Institut organicheskoy
khimii (Institute of Organic Chemistry) and, in recent years at
the Institut olementoorganiche3kikh coyedineniy All SSSR
(Institute of Elemental -Organic Compounds, AS US311). moreover,
she was a Member of the Komissiya po analiticheskoy khimii pri
Card 1/2 Prezidiume All SSSR (Commission for Analytical Chemistry

Mirra Osipovna Korshun
SOV/32-25-2-78/78
With the Presidium of the AS USSR). In 1956 she -,,as appointed
Member,of the Komitat po Mikrokhimicheakim metodam
Mezhdunarodnogo soyuza po chistoy i prikladnoy khimii
(Committee on Micro-Chemical Eethods of the International
Association for Pure and Applied Chemistry). .!. 0. Korshun
introduced into oreanic analysis the principle of
11pyrolytic combustion" in the empty tube which makes it
possible to determine simultaneously several elements
contained in one Reighed portion of complicated or.,---nic
compounds. The school of orGranic microanalyais founded by the
deceased is still being further developed in the USSR in the
sp~.rit. of her work.
Card 2/2
USODMM-DC-60750

$0 D
C; AT~7;'GIQRY :Cor--moc n,.,ffis V. r-f .oeocapnistry. HydrocherniBtry
j0thq
ABS No. 21 1959, No. '14525
RZKham
.
, . ,

TugurLnov, A. Zh. , Zftirova, V.
L, 0--.17 na ILI _(a,. V."
:Not ,71,jen
T I T :On tne fige of Graniti- and Ore Occurrences in Saxony
O'R, !C- 'P U B :Freiber?er Forschungsh, 1959, C, No 57, 73-85
ASSTRACT rVae authors have anslyz-~d 15 samples of metemorphic
roc'Kz and granites from Saxony and from Czechoslo-
vakia. The following comeonition ranges were a')-
served: Ar,(4.2-9.52),I0 5 in rocks and (8-11.6)-
10 5 cm3 /trm (from a samples) in micaG; K, 2.72-
5.59 and r,,.3-9.90,a, respectively; age by the Ar-
method, 200-61.)0 and 2_80(?)-380 million years. The
uranium pitch [sic] of various gerarationn con-
tained 53.5-70.3%, U and 0.104-2.68% Pb. The
isotope composition of PU in the oldest uranium
CARD: 1/4 )kZybov, S. A., Knorre, K. G., and.Lebedev, V. 1.

COUNTRY GDR
CAT.,',",GORY
,IBS. JOUP.. ,~o.
n 1959, lio.
71#525
ORIG. PUB.
A",2. 'I T RA C-4., foifi,,j to be: .2b 2o4 0.44,
Ph 2"C', Pb
72.';
ev,t'mated age (frem the rut-Jor, Pb 20?/Pb ~-~o6,
Ph 206-/TJ 23,",, -Pb I-L)'//U 255) 180 million years.
Two other z;.-.kmple& sl-o-nt-d Pb 204 0.'/ and 1.00,
Pb 206 60.01i and 66.91S, Pb 207 13.10 and 21.75,
Pb 20 26.1~: and ~~/7.47, ret;pectlvely; cFe 100 and
'-,ion year:~,. The fl'- from F,-alen-tc aeposits
in Eaxrny und -in Thurinria (9 s-mple-s) wz;s found

: " -. " .1
3 TaUji. R"Khm. NO. ?i 1959, Io- '/4525
AUT-11 0 R
MIT,
.r1
! ITL?
ORIG . FIJI R
AS P; T RA. OT to have trio i*oto-ve composition: Pb 2o6/11b 204
Fb '20?/Pb 2o4 P'o 2o8/
Po 204 146-77-37-45. The anthors conclude that
Saxcny ha;i been the scene of at least three in-
tt"Isive c.-Icles 3z')0-3qO, 300-320, and about 200
ritllion yearF, ago. The ore deposits in Saxon,,
have been subJected to hydrotbormal metamorphism
at least twlce; this has led to the regeneration
of the ores duriLg the Cretaceous Period (about
100 million yeari3 ago) and in the Upper-Tertiary
3/4
71 3

'JOUNTRY 4. GDR
J'ATMIORY
kB3. JOUR. 21 1959, k;O-
q
74525
)RIG. PUB.
The aul.nors
r fl~ 'ferous
Of -,VC t~La~L the Devortian-Garbon-
Periou tin the geoLopic- rtme scalp ohould be modi-
oy ma,!iriE the Carboniferous P2riod downwards
-Ari tho Permian-Triasnic Period to 'younger' times
R. Khmcilnitskiy
CAF,D: 4/4

,AUTHORS: Academician, Kutyurin, V. IC.;SOV/20-125-5-54/61
Mubekova, M. V., Zadorozhriyy, L K.
TITLEs The Isotopic Composition of Photosynthetic oxygen (17,otopnyy
sostay kisloroda fotosinteza)
PMODICALt Doklady Akademii nauk SSSH, 1959, Vol 125, Vr ~5., PP 1151-1153 WSR)
ABSTRACT% The,oxygen mentioned in the title occurs in water and is the remlt
of dehydrogenation (Refs 1,2). The attempt was made to interprets
the difference between the isotopic composition of oxygen occurring
in water and obtained from the photosynthesis (1 - 2.50 as a
methodical mistake or by an exchange between oxygen separated in
the photosynthesis and cellular water (Ref 3)-.Without knowledge
of the mechanism of oxygen separation in the photosynthesis the
probability of such an exchange could not be denied (Ref 3). This
exchange was, however, soon refuted: in the electrolysis (Ref 4)
as well an in the case of the catalase effect (Ref 5) no exchange
IlLkes place between 02 and H20 , OR, HOOR as well as -0-0-. Since it
was therefore necessary to define precisely the composition
Card 1/3 mentioned in the titleg especially for marine organisms, the authors

The Isotopic Composition of Photosynthetic Oxygen MY/2D-125-5-54/61
investigated the topic mentioned with the water weed (Elodea
eanadeneis) (fresh water), on the one hand, and with phytoplankton
(mainly Diatomacoas algae, sea water), on the other hand. The
photosynthesis took place in water treated with argon free from
oxygen (0 -content 0-3-1 ml/liter) at m=y weather and under
optimum oonditions. Table 1 shows the results. The disturbing
effect of the residual respiration oxyge
($, which was heavier in
consequemoe of preferred absorption of f was eliminated as far
as possible by repeated extraction of the oxygen produced by
photosynthesis. The method used for fresh water and the water weed
had to be replaced by that of Winkler for marine plankton since
the extraction of oxygen weakened the intensity of the photosyntheais.
The average value of the isotope content of the photosynthetic -
oxygen of marine phytoplankton (0.2002) (0 18 related to 017; the
small content of 017 was neglected) is higher only by 0.0009%,
i. e. higher by 1.0 r than that of sea water (mass-apectrum
determination in Table 2). This means that 90% of the
photosynthertic oxygen occurs in water. In the case of the water
Card Z/3 weed a similar calculation yields 82%. In the experiments with the

The Isotopic Composition of Photosynthetic Qcygen M7/20-125-5-54/61
water weed the respiration intensity wan not determined. By
eliminating the respiration the isotopic composition of
photosynthetic oxygen approaches in all cases that of water so
far that undoubtedly the total photosynthetic oxygen occurs in
water. Inconsiderable deviations of the isotope content in
photosynthetic oxygen from the inotopic composition of water In
the experiments with the water weed and in the experiment Nr 2
with marine phytoplankton resulted from the deviation of the
fractionating coefficients of the oxygen isotopes in the
respiration from the assumed average value. There are 2 tables
and 8 references, 2 of which are Soviet.
BUMMED: January 16p 1959
Card 3/3

ALIKARIN, Ivan Pavlovich; PETRIKOVA, Kira Nikolayevna; VIHPqRAPQV,__A.P.,
akedemlk, oty.red.; VAGINA, H.S., red.izd-va; MAXOGONOTA,
takhn.red.
(Inorganic ultramicroonslysiol Neorganichaskii ulitramikroanalls.
Moskva, Izd-vo Akad.us'uk WSR, 1960. 151 1). (KIRA 13--B)
(Kicrochomistry) (Chemistry, Analytical)

KORMIMAN, Izraill Kironovich;_VINoGRADOV,_A.P._,_akridemik, glnvnyy red.;
BUSW, A.I., prof., red.toms; ALIMARIN, I.P., red.; BABKO, A.K..
red.; VATHSHTM, B.Te., rpd.; URKIKOV, A.W., red.; KU 9
V.I,, prof., red.; PALEY, P.M., red.; RTABCHIKOV, D.I., red.;
TAIIANATEV, I.V., red..- CHERNIKHOV. Tu.A., red.-. VCLYNETS, K'F.'
red.izd-va; KASHIRA, P.S., tekhn.red.
(Analytical ch3mistry of thalliuml Analitichesksia khimiia
talliia. Koskva, Izd-vo Aked.nauk SSSR, 1960. 170 p iMIRA 14:3)
(TbB1li-azm---AnsIysie )

TINOGRADOT A,F., otv.red.; SAUKOT, A.A., red.; TLASOT, K.A., red.;
I
SHCHERBINA, T.T., red.; KKITAROT, H.I., red.; OTCHINNIKOTA, S.T.,
red.izd-va; BTKOTA, T.T., tekhn.red.
(Geochemical cycles] Gookhimichookie taikly. Moskva, Goa.
nauchno-tekhn.izd-vo lit-ry po gaol. i okhrane nedr, 1960.
186 p. (miRA 14:3)
1. International Geological Congress. 21st, Copenhagen, 1960.
(Ge ochomiatry--Congre ass 9)

RTAWHIKOV, Dmitriy Ivanovich; GMIBRATKH, Tevgeniya Kea 'yanovna;.-WOGWOY,
A.F.-, skademik, glavs&yj, red.; ALDURIN. I.P., red.toma; PALIT. P.N.,
ii-Ltoua; BMO, A.K., red.; BUSXV, A.L. red.; VATNSHTM, 1.76.ired.;
MIWKOV, A.M., red.; KUZWSOV, V.I., red.; TANANATZV,,I,V,,,red,;;
CHLUIXHOV, Yu.A.. ied.-, TRUONOV, D.H., red.izd-ve; POISNOVA. T.P..
takhn.red.
(Analytical chemistry of thorium] Analiticheekais khimiia torlis,
Moskva, Ixd-vo Akad.nauk SSSR, 1960. 295 p. (MIRA 13:10)
(Thorium--Analysis)

STARIK, I.Te., otv.r9d.; SHOMMAKOV, D.I., akademik, zamestitall otvored.;
BARANOV, V.I.. Prof.. zamestitall oty.red.; MUTSKIY, I.S., aka-
demik, red.; PCLXANOT, A.Ao, skademik, red,; 1110GRADOT, A.-P.,
akademik, red.; AFARASITSV, S.D,, red,; WMING, CC, prof** red,;
PMRSKATA, T.B.. kand.goologo-mineral.nauk. red.; IVANOV, B.V.,
red.izd-va (deceased); GUSSTA, A.P., takha.red.
(Transactions of the sixth session of the Committee on the Deter-
mination of the Absolute Chronology of Geological Yormations,
May 22-27, 19571 Trudy shastoi sesaii komiesii po opredslaniiu
absoliutnogo Yozrasta geologichaskikh formataii-, 22-27 maia 1937 g.
Moskva, 1960. 306 po (MIRA 1):7)
1. Akademiya nauk SSSR, lomissiya po opredelinlyu absolyutnogo
vosrasta geologichaskikh formately,
(Geological time

PHASE I BOOK EXPLOITATION SOV/4164
Vsesoyuznoye soveshchaniye po splavam redkikh metallov. .1st, Yoscow, 1957
Radkiye metally I splavy; trudy... (Rare Metals and Alloys; Transactions of the
First All-Union Conference on Rare-Metal Alloys) Moscow, Metanurgizdat, 1960.
1+38 P. 3050 Copies printed.
Sponsoring Agencies: Akademiya nauk SSSR. Institut metallurgii; USSR
Komissiya po redkim. metallam pz-i nauchno-tekhnichookom komitate.
F,d.t I.K. Shapovalov; Ed. of Publishing House: O.M. Kamayeva; Tech. Ed.:
P.G. Islentlyeva.
PURPOSEt This collection of articles is intended for metallurgical engineers,
physicists, and workers in the machine-building and radio-engineering industries.
It may also be used by students of schools of higher education.
COVERAGE: The collection contains technical papers which were presented and dis-
cussed at the First All-Union Conference on Rare-Metal Alloys, held in the In-
stitute of Metallurgy, Academy-of Scionaes-USSR In November 1957. Results of
investigations of rare-metal alloys, titaraum 3and copper-base alloys with ad-
ditions of rare metals are presented and discussed along with investigations of
rhenium, vanadium, niobium_,and their alloys. The effect of rare-earth metals
Card 11V9.-

Rare Metals (Cont.) SOV/4164
on properties of magnesium alloys and steels is analyzed. The uses of rhenium
as a dehydrating catalyst, electroplating material, and matezial suitable for
making plugs for automobile electrical systems are discussed. Alsop the er-
fact of the addition of certain elements on the properties of heat-resistant
steel is examined and alloys with special physical properties (particularly
semiconductive alloys) are discussed. No personalities are mentioned. Soviet
and non-Soviet references accompany some of the articlee.
TABLE OF CONTENTS:
Opening Spewh of A.P. Vj22&t&jqX,,Member of the Academy of Sciences USSR 3
The Letter of I.P. Bardin, Member of the Academy of Sciences USSR 5
PART 1. THE PRESENT STATE OF INVESTIGATION OF
RARE-41ETAL ALLOYS
Savitskiy, Ye.M. The Present State and Problems of Investigations of Rare-
Metal Alloys ?
C a r d 2'/1_W

STARIK, I.Te., oty.red.; SHCWMAKOV, D.I., akademik, tamestitell otv.
red.; BARANOV, V.I., prof., samostitell otytredo; V11100RADOV, A.-P.,
akedemik, red.; NUMOV, A.A., akademik, red.; SHATSKIT, H.S.*
akademikl red.; AIPANASIYXV. G.D.: GERLING, Z.K., prof.0 red.;
PMRSKAYA, T.B., kand.gool.-miner.nauk, red.; SIMKIN, S.M., red.
isd-va; KAKWI, Ye.V., tekhn.red.
(Transactions of the Seventh Commission on the Determination of
the Absolute Chronology of Geological Formational Trudy Sed'moi
seseii Komissii po opredelenii-a abaoliutnogo vozrasta geologicheakikh
formateii, 8-12 maia 1958 g. Moskva, 1960. 432 p. (MIRA 13:6)
1. A.kademiya nBuk SM. Komissiya po opredeleniya absolyatnogo voz-
rasta geologichaskikh formatsiy. 2. Chleny-korrespondenty AN SSSR
(for Starik, Afanaelyev).
(Geology, Stratigraphic)

VERNADSKIY, Vladimir Ivanovich; VINOGRADOV. A.P., akademik, otv,red.;
LICHKOV, B.L., doktor geo -m Ona 0 -kid.; YZODO!PIYZV, I.M.,
red.izd-va; NOVICHIOVA, N.D., takhn.red.
[Selected works] hbrannye sochineniia. Moskva. Izd-vo Akad.
nauk SWR. Vol.4. Book 2. 1960. 651 p. (NDU 13:10)
(Water, Underground) (Mineralogy)

VIRUADSUT, Vladimir Ivanovich, akademik;,VIHQaRADOV, A,P., akademik,
otv.red.; MANSKATA, S.M., doktor biolog.nauk, red.; PRO23)OVA,
T*T,, rad.izd-va; NOVICHKOVA, N.D., tekhn.red.
[Selected works) Izbrannyo sochinaniia. Moskva, Izd-vo Akad.
nauk SSSR. Vol.5. ig6o. 422 p. (MIRA 13:5)
(GROCHWISTRY) (LIVA (BIOLOGT))

FERSHAN, Aleksandr Yevgenlyevich, akadem1k; SMYUCHMO, D.P., doktar
gool.-mineral.nauk, otv.red.; B=V, N.Y., akademik, red.; ,
-VINOGRADOT, A.P., _pkademik, red.; SHCWMAKOT, D.I., akade4k.
red.; SAUKOT, A.A., red.; SHCHMISA. V.V.. doktor gool.-mineral.
nauk, red.; KUN, I.R., red.izd-va; AWROV, A.V., red.izd-va;
KASHOA, P.S., takhn.red.
[Selected works] Izbrannye trudy. Moskva. Izd-vo Akad.neuk SM.
Voi.6. 1960. 742 'D. (MIRA 13:11)
1. Chlen-korrespondent All SM (for Saukov).
(pegmatites) (Granite)

VINOOPADOV, A. P. Dir., Inst. Geochem. and Analy-tical Chem. im. V. I. Vernadskiy,
AS USSR
"The Role and Responsibilities of Scientists."
paper presented at the Pugwash Conference on Disarmament and World Security,
Moscow, 27 Nov-6 Dec 60.

S/ /C5 1161,100-0/C - VC-21 /1 6,-~
B102/Bl 38
AUTHOR: Yja2&KAdg P~
-Y,--&,
TITLE: Geochemical cycles of lead isotopes (Short statement
[report] )
PKIRIODICAL: Referativnyy zhurnal. Khimiya, no. 17, 1961, 93 - 94,
abstract 17rT6 (Sb. "Geokhim. tsikly". M. Gosgeoltekhizdat.
1960, 5 - 15)
TEXT., Ore formation processes are considered on the basis of the isotope
composition of Pb enclosed in minerals or rock. On the basis of about
1200 published ore analyses a histogram is constructed, from which it may
be seen that the isotopic composition of native Pb for each continent does
not form a continuous spectrum, but typical groups which correspond to
metallogenetic periods, which differ for different regions to a known
degree, Of these defined cases, about 20% refer to anomalous Pb, the
origin of which lies mainly with the processes of plutonic metamorphism of
rocks with disturbed Th:U ratio. Examples are given of the determination
of the U, Th and Pb contents and the isotopic composition of Pb in three
Card 112

S/08 1/61/OCC/Ci 7/0-2 1/- 64,
Geochemical cycles of lead... B1021BI 38
stony meteorites. three basalts, and 17 acid rocks. The ratio U238 ?b 204
quite considerably varied within each group. Fluctuation of the Pb:U
ratio was also observed within the bounds of one Intrusive compl-~x (ec--
the Altay, Kazakhstan, Baltiyskiy shield). Since rock with different
genesis may be the origin of native Pb, it is impossible to construct a
continuous curve for the system Pb 206 :Pb 204-Pb 207:Pb 204 for a vgivr-n
territory (continent or region). The problem consists in finding the
mechanism of the separation of Pb from the rock by means of the data on
the Pb isotope composition. There are 17 references. [Abstracter's note:
Complete translation.]
ca r (I

YINOGW
, PV,-A- P. ; TARASOV, L. S. ; ZYKOV, S. I.
-w. 1.
Isotopic composition of leads from pyrite deposits of the Urals.
Geokhimlia no.61475-489 160. (MIU 13:10)
1. Institut geokbimii i analiticheskoy khimii im. V.I.Vernadekogo
AN SSSR, Moskva.
(Ural, Mountains-Lead-Isotopes)

VINOGRADOV, A.P.; TUGARINOV, A-L; ZYXOV. S.I.; STUPHIKOVA, N.I.
Age of rocks of the Aldan Shield.. Gookhimiia no.7:563-569
,6o. (MIRA 13:11)
1. V.I.Vernads1W Institute of Geochemistry and Analytinal
Chemistry, Academy of Sciences, U.S.S.R., Moscow, and Chair
of Geochamistry of the M.V. lomonosov Moscow State University.
(Aldan Plateau-Rocke-Ages)

. VINOGRADOV, A,P,
Foreword. Trudy kom.anal.khtm. 10:3-4 160. (milu 13:0
(Gases in netals)

VINOGRILDOV,-, A.P.
Genesis of biogeochemical provinces. Trudy Biogeokhim. lab. no.11:
3-7 160. (NUU 14-- 5)
1. Ifistitut geokbimii i analiticheskoy khi-ii imeni V.I.Vernadakogo
AN SSSR.
(GEOGHEMISTRY) (BIOCHEMISTRY)

3,911o .2989i
S/.169/61/000/009/053/1056
0 D2213/D30'4
AUTHORs Vinogradov, AZ PO
TITLEs Some statistical patterns in the course of Pc- and
Pt-type short-period fluctuations of the earthis
electromagnetic field from observations in the period
of the IGY and IGU at Irkutsk. Communication I
FERIODICALi Referativnyy zhurnal~ Geofizika, no. 0, 1961, 28,
abstract OG224 (Geologi.ya i geofizfka. no. 129 19609
100-111)
TEXTs The daily and yearly distributions of abort.-pe-riod fluctuations
of the eartb-current field (of the F---tTpe mid the relation of the daily
distribution of Pc to the activity le-gel of the geomaLmA-tic field are
examined from the observational data of the Bayanday and Uzur stations
(near Irkutsk) at the time of the IGY and IGU. In all seasons of the
year, the appearances of Pe are most frequently observed around the
midday hours--local time.--and least frequently observed around the mid-
Card 1/3

29891
S/1 69/61/000,/009/053/056
Some statistical pattern#,,., D928/D304
night hours. The maximum for the diurnal variation of Pc (S I Pel ) is
at 9 - 11 hro., the minimum being at 23 - 01 hrs~ los.,al time. The ampli-
tude of S(Pc) grows in summer, and, moreover, the timg interval favorable
for the appearance of Pc also increases In summer. The amplitude of
Pe is greater in the nocturnal hours. The daily change in the mean-
hourly amplitudes of Pc and S(]Pc) shove a close correlation. The re
recorded at Uzur by equipment with a higher sensitivity than that at
Bayanday display a more even distribution for the hours of the day. The
form of S(rc) to some extent depends on the sensitivity of the equip-
ment; daytime Pc (the most intenee) may be detected even in the record-
ing4 of low-sensitive equipment, but the sensitivity of the equipment must
be increased for registering the week, nocturnal Pc,, The number of
cases of Pc grows, and the duration of the period favorable for the
appearance of Po becomes greater, as the activity of the geomagnetic
field increases. On disturbed days, Fe with periods of 10 - 16 sec. ar'.
more often observed, while on quiet days, the corresponding period Is
20 - 30 sec. The yearly distribution of the frequenzy of Fe appearances
and the yearly variation of the mean-monthly amplitudes of Pc have the
Card 2/3

2985r.L
S 169/61/1000/000/053/Ow
Some statistical patterns... D4083304
form of a simple wave with a minimum in December and a maximum in July.
There is a certain parallelism between the yearly changes in the number
of cases of Pc and the K and C indices of geomagnetic activity.
The investigation of the statistical patterns of Pe may be useful when
carrying out electric-prospecting work by the method of telluric currents
and magneto-telluric profiling. fAbstracter's note,- Complete trans-
Card 3/3

VINOGRADOV, A.P., akademik; ZOOROMET, I.K.; KNMIM, X.G.
Argon In meteorites. Hateoritiks no.18.092-99 160.
(MM 13:5)
(Noteorites-Analyisle) (Argon)

VINOGRAWY, A.P., akademik; 7UGARINOV, A.I.
Some determinations of the absolute age serving as reference data
to the world geochronological scale. Dokl. AN SSSR 134 no.5:1158-
U61 0 160. (MIRA 13:16)
1. Institut geokhimii i analiticheakoy khimii im. V.I.Vernadekogo
Akademii nauk SSSR.
(Geological time)

84662
S102016011341006,1031103t
-BO16/BO67
AUTHORS8 Vinogradov,__A_--Z.-, Academician, Kutyurin,, Ve M.~
Ulubekova, a9 and Zadorozhnyy 1. K. -
121,
TITLEi Isotopic Composition of the Oxygen of-Photosynthesis and
Respiration
PERIODICAM Doklady Akademii nauk SSSRp 1960$ Vol. 134, No. 6.
PP- 1486-1489
TEXTs In an earlier paper (Ref. 1) the authors had arrived at the con-
cl-asion that the difference betveen the isotopic composition of the oxygen
of photosynthesis and of water oxygen can be explained. This is due to
the fractionation of the oxygen isotopes during respiration, which en--
riches the oxygen remaining after respiration with 016 thij.9 making 'At
heavier. Since photosynthesis and respiration take place simultaneously,
the oxygen analyzed Is that which was not consumed In --espiratLon. Its
isotopic composition depends on the ratio of the lntensltl,,~A of those tw-7
processes, furthermore on the fractionation coefficient of the oxygen
isotopes during respiration. The authors are of the opinion that the mear.
Card 113

84-662
Isotopic Composition of the Oxygen of S/020/60/134/006/031/031
Photosynthesis and Respiration BO16/BO67
value of this aoeffinient c~ - 1.018 assumed in publications (Ref. 3) can
hardly be used for the calculations in thq individual case. To determ1na
the quantitative influence of respiration on the isotopic compoaitior of
the oxygen of photosynthesis they tried to determine simultaneously the
V( of' respiration and the Isotopic composition. For this purpose they ljss~d
cultures of Scenedesmus obliquus and the water plant Elodea canadensis
which were investigated In an apparatus (Fig. 1). Fig. 2 shows the ap-
paratus used for the purification of the gas. The experiments with both
types of plants were made with an exposu~re of 5500 Ili% and at pH 7. The
remainin conditions are given in Tables 1 and 2. The data obtained
(Table 1~ show that the fractJonation coefficient of the oxygen inotopes
during the respiration of both plants depends on the physiological. state
of the plants. In endurance teats 06-.?o h)j when plants are etarvIng,
the respiration Intensity is reduced to 1/5 to 1/10, while the coetftcl,4nl~
c~q however, rises, i.e., the degree of fractionation in~rease3 under
unfavorable conditions. This recalls the metaboliao of aulfur ba,~teria
(Re-f- 7). The difference between the fractionatior -,cefficient of
Scenedesmus and Elodea indicates the 5pe,,difity cf the oxygan metabolism
in different types of plants. This confirms the above mentioned d-,ubte
Card 2/3

84662
Isotopic Composition of the Oxygen of S/020/60/134/006/031/031
Photosynthesis and Respiration B016/BO67
as to the usability of a mean coefficient t~ for all plants. As to the use
of this coefficient for each type of plant the authors hold the opinion
that the influence exerted by respiration on the isotopic composition
( on the example of Scenedeamus and Elodea) can be determined by de-
termining ok under the conditions of photosynthesis. The authors arrive at
the conclusion that the opinion expressed In the beginning concerning
the "rendering heavier" of photosynthssiB oxygen by xespiratlon is correct,
and they derive equations (1) and (2) for the isotopic composition of the
oxygen remaining after respiration as well as for the respiration in-
tensity. K. Po Florenskiy is mentioned (Ref. 4). Therp are 2 fignres,
2 tables, and 10 referencest 4 Soviet and 3 US-
ASSOCIATIONs Institut geokhimli i analiticheskoy khimft im. V. 1. Vernad-
skogo Akademii nauk SSSR (Institute of Geonhemistry and
Analytical Chemistry imeni V. I. Vernadskly or the Acad-my
01 bclences,, USS
SUBMITTEDt July 29, 1960
Card 3/3

YPLOA,TUWML,-A,Y,, akad.,- DEVIRTS, A.L.; DOBKINA, E.I.; MARKOVA, N.G.;
MARTISHCMKO, L.G.; MERGASOV, G.G., red. izd-va; POIYAKOVA, T.V.,
takhn. red.
(Determination of absolute age by C14 using a proportional counter;
description of the const;Vction method and results] Opredelenie ab-
soliutnogo vozrasta po CI4 pri pomoshchi, proportsionallnogo acbet-
chika; opisanio metoda konstruktsii, i rezul'tatov. Moskva,, Izd-vo
Akad. nauk SM, 1961. 57 p. (MIRk 1411-1)
(Radiocarbon dating)

SEREMANNXY LeR. I MXgG~RAD p-AJ-,7. akademikp otvo red,; NEYSHTADT, M.I.,
doktor geogr. nauk.. red.; SMGINA, L.I., red. izd-va; VOLKOVA, V.G.,
tekbn. red.
[Radiocarbon dating and its use for the study of Quaternary palao-
geography; for the Sixth Congress of INQUA in WarsawP 19611 Radio-
uglerodnyi ;Detod i ago primenanie dlia izueheniia paleogeografii
chetvertic*ogo period&; k sheotomu kongressu IftA v Varshave 1961.
Moskva) Izd-vo Akad. nauk SSSR) 1961. 225 p. (KIRA 14:9)
(Radiocarbon dating) (Paleogeograpby)

TAUSON, L.V.;--V1NDGHkDOVp A.P.j akademik, otv. red.7 KOPIN, LZ., red.
izd-va; GOUJBI, S.P.,v tookhn. red.
(Geochemistry of rare elements in granitoids] Gookhiniia red-
kikh elementov v granitoidakh. Moskvap Izd-vo Akad.nauk SSSR,
1961. 229 p. (MIRA 15;1)
(Metals.. Rare and minor) (Geochemis-try)

PHASE I BOOK EXPIDITATION SOV/5777
Vinogradov, A. P., Academician, and D. 1. Ryabehikov, Doctor of
Ch-dihre-AI-S-C feces, ProfessorReap. Eds.
Metody opredeleniya i analiza redkikh elementov (Methods for the
Detection and Analysis of Rare Elements) Moscow, Izd-vo AN SSSR,
1961. 667 p. Errata slip inserted. 6000 copies printed.
Sponsoring Agency; Akademiya nauk SSSR. Institut geokhimli i
analiticheskoy khimii im. V. I. Vernadskogo.
Ed. of Publishing House: M. P. Volynets; Tech. Ed.: 0. GusIkova.
PURPOSE: This book is intended for analytical chemists and for
students of analytical chemistry.
COVERAGE: The handbook was published in accordance with a decision
of the Vsesoyuznoye soveshchaniye po analizu redkikh elementov
(All-Union Conference on the Analysis of Rare Elements) called
Card 1/5

Methodolbr the Detection (Cont.)
SOV/5777
together by the Gosudarstvennyy nauchno-tekhnicheskiy komitet
Soveta Ministrov SSSR (State Scientific and Technical Committee
of the Council of Ministers of the USSR) and the Academy of
Sciences USSR in'December, 1959. The material is arranged in
accordance with the group position of elements In the periodic
s_vstem, and each section is prefaced by an article discussing
the analytical methods most used in the Soviet and non-Soviet
countries. Each section deals with the physical, physicochemical,
and chemical methods for the analysis of raw materials, semi-
products, and pure motals, and is accompanied by an extensive
bibliography listing works published in the field in recent years.
The following are mentioned for th6ir help In preparing the book
for publication: I. P. Alimarin, 6. N. Bilimovich, ... I. Busev,
E. Ye. Vaynshteyn, M. P. Volynets, V. G. Goryushina, A. M. Dymov,
S. V. Yelinson, 0. Ye. Zvyagintsev, 0. M. Kolosova, Ye. K.
Korchemnaya, V. I. Lebedev, G. A. Malofeyeva, B. N. Melentlyev,
V. A. Nazarenko., I. I. Nazarenko, T. V. Petrova, N. S. Poluektov,
A. I. Ponomarev, V. A. Ryabukhin, N. S. Stroganova, and Yu. A.
Chernikhov.
Card 2/5

Methods, for the Detection (Cont.) SOV/5777
TABLE OF CONTENTS:
From the Editors
3
Vinogradov, A. P. Problem of the Purity of Materials 5
Sazhin, N. P. Industrial Quality Requirements of High Purity
Metals and Materials for Semiconductor Technology 11
Poluektov, N. S., and V. T. Mishchenko. The Present State
of the Analytical Chemistry of Lithium, Rubidium, and Cesium 37
Goryushina, V. G. Present State of the Analytical Chemistry of
Beryll~um 79
Poluektov, N. S., and V. T. Mishchenko. Present State of the
Analytical Chemistry of Strontium 108
Ryabehikov, D. I., and V. A. Ryabukhin. Preagnt State of the
Card 3/5

Methods,for the Detection (Cont.
SOV/5777
Analytical Chemistry of the Rare Eart. Elements, Scandium and
Yttrium. 128
Busev, A. I., and V. G. Tiptsova. Present State of the Analytical
Chemistry of Thallium 182
Busev, A. I., and L. M. Skrebkova. Present State of the Analyti-
cal Chemistry of Gallium 201
Melent Ivev, B. N. , and A. I. Ponomarev. Present State of the An-
alytical Chemistry of Titanium 238
Yelinson, S. V. Present State of the Analytical Chemistry of
Zirconium and Hafnium 303
Hyabehikov, D. I., and D. I. Korchemnaya. Present State of the
Analytical Chemistry of Thorium 374
Card 4/5

Method for the Detection (cont. SOV/5777
Yazarenko, V. A. Present State of the Analytical Chemistry of
Germanium 400
Zolotavin, V. L. Present State of the Analytical Chemistry of
Vanadium 462
Alimarin, I. P., apd G. M. Bilimovich. Present State of the
Analytical Chemistry of Tantalum and Nioblum 487
Busev, A. 1. Present Stateof the Analytical Chemistry of
Molybdenum 537
Troitskaya, M. I. Present State of the Analytical Chemistry of
Selenium and Tellurium 58o
Ryabehikov, D. I., and Yu. B. Gerlit. Present State of the
Analytical Chemistry of Rhenium 628
AVAILABLE: Library of Congress JA/rsm/ec
Card 5/5 12-1-61

fAf r T--T /f 1
V-
19, 1
N j
A
Gla 111
52 13 1
ik~ .0
9 .9
Nn!
j4,
fj It
A
lip
cK 3; &Ila it
al-
F3
91
.4 Ila

VIRLMUIDUVI 1%. r.
"Geochemical cycles of isotopcs of lead"
Paper submitted at the International Geological Congress XXI SwwAon
46960 (Reports of Soviet Geologists) Problem No. 1t 15-24 Aug. 61
'))t'd')'tZLe (!,-I I -.#-, 0- -,,

~,VINOGRADOV) A.P.
Origin of the matter of the earth's crust. Report No. 1.
Geokhimiia no.1:3-29 161. (MIFLA 14:3)
1. T. I. Ternadzky Institute of Geochemistry and Analytical
Chemistry, Academy of Sciences U*S*S*R*j Moscov,
(Geochemietry)

VINOGRADOV, A. P., KUTYURIN, V. M., (USSR)
"The Mechanism of Dehydration of Water in
the Process of Photosynthesis."
Report presented at the 5th Int'l. Biochemistry Ccngreasp
Moscow, 10-16 Aug 1961o

29394
?"-YYO (10104-1-1y) S/007/61/000/011/001/003
-3.17oc, (0-T7,114fro) B!07/BI47
AUTHORSs Vino P., Lavrukhina, A. K., Revina, L. D.
A. _
TITLE: Nuclear reactions in iron meteorites
PERIODICAL: Gookhimiya, no. 11, 1961, 955 - 966
TEXT: The authors report on a radiochemical analysis of the fission
products of iron bombarded with 660-Mev protons, They attempted to
clarify the cosmogenic formation of various isotopes in iron meteorites.
The synchrocyclotron of the Laboratoriya yadernykh problem Ob"yedinennogo
instituta yadernykh issledovaniy (Laboratory for Nuclear Problems of the
Joint Institute of Nuclear Research) was used to bombard 100 to 500 mg of
iron powder with about 10 12 protons/seecm 2 for 0.5 to 2 hr~ The resulting
isotopes were identified according to half-life, kind and energy of radia-
tion. A simplified magnetic beta spectrometer and a gamma scintillation
spectrometer were used for this purpose. A total of 38 isotopes with
atomic numbers 4 - 27 and half-lives from 8 min to 3 years were found.
The production cross sections and yields of stable and undetected radio-
isotopes were calculated by interpolation (Fig. 2), On the strength of
Card 1 /1-1
) 1~7

Nuclear reactions in iron meteorites B107/B147
thunie data, the number of cosmogenic nuclei w,t3 calculate,-I, -.,,'Clich are
formed by fission of Fe56 in th(,~ center of a meteoriLe of 10 c--.i diameter
wLthill 4.5-109 years (Table 4). Results: Within the periol menLion(A,
about 10-7 g of cosmogenic isotopes per gram of meteorite ij formed,
36 38 40 4r,,.
e co n -
among them the stable isotopes Ar Ar K Sc ill.
centration calculated for these isotopes agrees with the observed concen-
tration and is about 10-9g/g of meteorite, This explains the an~Dmalies
observed in the isotopic composition of potassium and argon. S,-.ifts
toward the ratios in terrestrial rocks are to be expected also for the
isotopes of vanadium, titanium, ani other elements The eI'iuilib.-i--.-1
valuesfor the activity of long-liVerl cosmogenic nuclei in iron meteor4teS
were calculated, A comparison with values measured in various meteorites
shows deviations by a factor of t!9=5, The mean production croas section
for nuclei with an atomic weight of about 20 and about 40 was found tc be
1.2 and 0,5 Bev. The authors thitnk V, V Malyshev. L.. M Saratova. :,nd
Cu Hung-kuei for help in the experimental worki L-. K. Levskiy and
V, Kuznetsov are mentioned. There ~-re .,' fi~:ures, 7 tables, and .~O refer-
Card 245~/
~51

2V39h
3/007/61/000/011/OC)1/'003
Nuclear reactions in iron meteorites B107/B147
encest 6 Sovint ' and 24 non-Soviet. The three moat recent references to
English-language publications read as followat P.Eberhardt, J. Geiss.
Radioactive and stable isotopeein meteorites. Physikalisches Institut,
University of Berne, Switzerland, September, 19601 M. Honda, J. R. Arnold.
Geochim. Cosmochim. Acta, 23, 219, 19611 M. Honda, J. P. Shedlovsky,
J. R. Arnold. Oeochim. Cosmochim. Acta 22, 133, 1961.
ASSOCIATION: Institut geokhimii i analiticheakoy khimii im. V. 1.
Vernadskogo AN SZSR, Moskva (Institute of Geochemistry and
Analytical Chemistry imeni V. I. Vernadakiy AS USSR, Moscow)
SUBMITTEDt July 25, 1961
Fig. 2. Distribution of fission products of iron by 660-hiev protons for
each element as a function of the mass number A. Legend: (y) production
cross section 6 in mb; (o) experimental values; (t) interpolated values.
Table 4. Content of stable isotopes in fission products of iron. Legend:
(1) isotope; (2) production cross section di in mbi (3) cumulative
.production cross section e EA of nucleus A i with account of the contribu-
Card 3/5-
S

VINOGRADOV., A.P.
Goochwdstry in foreign countrioa. Izv.JX SSSR.Ser.gool. 26
no.7s3-3-1 Jl 161. (MIRA 14:7)
(Geochomistry)
i

J7- 0000
A 46 0 10 0
AUTHORS:
TITLE:
PERIODICAL:
21S75
S10201611137100310291030
B103/B208
Vinogradov, A. P., Academician, Devirts, A. L., and
increase of the content of active carbon due to nuclear
explosions
Doklady Akademii nauk SSSR, v. 137, no. 3, 1961, 688-691
TEXT: The authors studied the C14 content in the wood of certain annual
rings in the ash tree (Fraxinus excelsior) to determine the concentration
of C14 in the atmosphere of the respective years. Recently it has been
found (Ref. 1: 0. 1. Leypunakiy, Atomnaya energiya, jy no. 1, 63, 1958,
Ref. 2: A. D. Sakharov, ibid, A, no. 6, 576) that not only long-lived
isotopes, such as Sr90, but also C14 (T1/2 ' 5568 + 30 years) are respon-
sible for the aftereffects of nuclear explosions in time. So far, no
data are available on increase and distribution of C14 in the "exchange-
Card 1/5

21575
S102016111 3 7/003 /02 9103 0
Increase of the content of ... B103/B208
basin." It is, however, known that from 1953-1955 onward the C 14 content
in the atmosphere increased by 4.3-5% per year, irrespective of the place
where nuclear explosions had occurred, and increased by 25-30% until 1959.
The ash tree examined was felled near Moscow (Zvenigorod forest) at the
end of June, 1960. It had a diameter of 19 cm and an age of 45 years.
15 annual rings (years 1959-1945) were recovered from 2-3 cm thick
targets. Separate wood samples from the individual years were burned in
an oxygen stream, and ethane was synthesized from the resultant CO2 (for
methods cf. Ref. 10, authors' paper, Geokhimiya no. 8, 3, 1956 and 663,
1959)- Calcium carbide containing the carbon from the wood samples was
decomposed by distilled Artesian water from a depth of 160 m for the
purpose of obtaining acetylene and eliminating contamination by tritium
which is also due to nuclear explosions. To remove traces of radon and
its decay products, the resultant gas was stored in glass containers for
at least 25 days (. 6-7 fold T 112 of Rn which is 3.82 days) prior to
counting. C14 activity in ethane was determined in a propertional
counter filled with gas (gas pressure: 2 atm). 2 g of carbon were
contained in the whole counter. Apparatus and methods applied are
Card 2/5

21575
."/020/61/137/003/029/030
Increase of the content of ... B103/B208
described in the authors' paper of Ref 10. The wood of a 30-year-old
birch felled in Kamchatka-in-1908 was used as a recent standard, to which
the activity of the test samples was referred. Fig. 2 shows the increase
of the C14 content in the ash. A14 denotes the difference between the
activity of the ash samples and that of the standard (zero level). The
authors conclude therefrom that the C14 content in the annual rings of
the ash has rapidly increased between 1956 and 1960, 1. e., by 5.5% per
year on the average. The difference between the zero levels of ash and
birch is due to the "industrial effeot", i.e., dilution of atmospheric
CO 2 by inactive carbon owing to the intense comb-Ostion of coal and
petroleum in the course of several decades. The C 14 increase in the ash
thus corresponds to that in the atmosphere during the last few years.
The authors point out that this content may further increase by disloca-
tion froin the stratosphere into the troposphere. Though a reduced
absorption of C14 from the atmosphere by*plants was expected because of
fractionation of the carbon isotopes during-photosynthesis, the effect
Card 3/5

21575
S/020J61/137/003/029/030
Increase of the content of B103/B208
of C14 separation becomes lose clear owing to the latitude effect and,
possibly, the seasonal effect. he C14 content in plants thus increases
more than in the atmosphere. The authors express their gratitude to V. Ye.
Moskaleva, V. M. Kuty~xrin, D. F. Frantsuzov, and R. V. Bronskaya for
selection and supply of wood samples. There are 3 figures and 10 refer-
ences: 3 Soviet-bloc and 7 non-Soviet-bloo. The referenceto the
English-language publication reads as follows: Ref. 8, E. H. Willis,
Nature, 18-5, no. 4712, 552 (196o).
SUBMITTED: -January 2, 1961
Card 4/5

.21575-
3/020/61/137/003/029/030
Increase of the oontent of ... B103/B208

RYABCHIKOV, Dmitriy Ivanovich; TSITOVICH, Igor' Konstantinovich;
VIN(M~~, akademik,, otv. red.j VOLYNETS, M.P.,,
I'r DOROKHINA, I.N., tekhn. red.
re ,
[Ion exchange resins and their uses] Ionoobmennys smoly i
lkh primer#enie. Moskva, Izd-vo AN SSSR, 1962. 185 p.
(MIRA l6s8)
(Ion exchange resins)

BUSEV, AlekBey Ivanovich;-VMIOMAPOV, A.P. . akademik, glav. red.;
red.;
ALIVIAIN, I.P.p red.; BABFO, A.K.,
VAYNSHMN, E.Ye.,
red.; YEM,1AK0Vx A.N., red.; KUZI-TTSOV, V.I., red.; PALEY, F.H.0
red.; RYABCHIKOV, D.I., red.; TANANAYEV, I.V., red.; CIOUIIHOV,
Yu.A., red.; VOLYWETS, M.P., red.; MAKUNI,'1e.V.p tekhn. red,
(Analytical chemistry of molybdenum]Analiticheakaia khimiia mo-
libdena. [By) A.I.Busev. Moskva, Izd-vo Akad. nauk SSSR, 1962.
300 P. (MIRA 16: 1)
(Molybdenum-Analysis)

VINOGRADOVO A.P.
Atomic abundances of chemical elements on the sun and in stony
meteorites. Geokhimiia no.4:291-295 162. (MIRA l6t7)
1. Vernadsky Institute of Geochemlotry and Analytical Chemistry,
Academy of Sciences U.S.S.R., Molp0ii.
(Sun$ (Meteorites)' (Chemical elements)

VnIOGH.00VI A. P.
"Biochemical provinces"
To be pre-"ented at the Geochemical Society lnternati,~nal
Meeting on Organic Processes, 10-12 Sep 1962.
Inst. of Geochentstry and Analytical Chemistry imeni V. I. Vorrwlskiy, %oscow

VINOGRADOV, A ndr Pallovich--tKUTYURIN, V.M., red. izd-va;
GOLUBI) S.P., tekbn. red.
[Isotopes of o2ygen and photosynthesis] Izotopy kisloroda
fotosintez. Moskvap Izd-w Akad. nauk SSSR, 1962. 33 P.
(Timiriazovskie chteniia, no.22) WDU 15:6)
(Photosynthesis) (Oxygen-Isotopes)

RYABCHIKOV, DmArly Ivanavich; TSITOVICH, Igor' Konstantinovich-1
VIVOGRADGV A.P., akademik, otv. red.; VOIZNMS, M.P., red.;
~i i -Al, . ' tekhn. red.
[Ion exchange resins and their uses] Ionoobmennye smoly i ikh
primenente. Moskva, Izd-vo Akad.nauk MR, 1962. 185 p.
(MIRA 15:7)
(Ion exchange resins)

VINOGRADOV A.P., akademik
11) . glav. red.; KHITAROV, H.I., otv. red.;
SIILEPOVJI V.K.p red. izd-.va; VOIXOVA, V.G., tekhn. red.
[Experimental investigations of abyssal processes; from papers
of a symposium] Eksperimentallrye issledovaniia v oblasti glubin-
rqkh protsessov; po materialam simpoziuma. Moskva) Izd-vo, Akad.
nauk SSSR, 1962. 239 p. (MIRA 15:7)
1. Simposium po eksperimentalInym issledovaniyam, v oblasti glu-
binTWkh protsessov, 1960. 2. Institut, geokhimii i analiticheskay
khimii im. V.I.Vernadskogo JUI SSSR (for Khitarov).
(Earth-Surface)

AVTOMATOVA, Tatlyana Dmitriyevna.~~GR~AD~ ., akademik,, glav.
red. ; TAITANAYEV I IN. I Wcsdemik., -2,ed., tmaj HYABCHIKOV, D. 1. ,
doktor khIm. nauk, red. tora; GOLIT, Yu.B., red.; =. I-KCIVA,
L.A., tekhn.red.; GUSIKOVA, O.M., tekhn. red.
(Analytical chemistry of ruthenium]Analitichockaia khimlia
ruteniia. Moskvaj, Izd-vo Akad. nauk SSSR, 1962. 263 p.
- (MA 15. 11)
(Ruthenium-Analysis)

STARIK, I.Ye., otv. red.; SHCHERBAKOV2 D.I.,, akadeiaik, zam. otv.
red.; DARANOV, V.I.., profp zam. otv. red.; VDICGRADOV,
red.; POLKOW, A.A., akadb-mDC,-r-ecT
HARWYEV, G.D., red.; GMLIVG, E.K.., prof.', red.;
PEUM"MA, T,B,v.kAW,-geol.-min*r'� nauk, red.; ARON, G.M.,
red. izd-va; GALIGAEOVA9 L.M., tekbn. red.
(Transactions of the Tenth Session of the Commission on the
Determination of the Absolute Age of Geological Formations)
June 5-)0, 1961]Trudy desiatoi Pessii ... ; 5-10 iiunin 1961
Moskva, Izd-vo Akad. nauk SSSR) 1962. 379 p. (MIRA 15-MO
1. Akademiya nauk SSER. Kordssiya po opredeleniyu aboolyutnogo
vozi-astag?ologicheakikh formatsiy. 2, Chlen4orrespondent
Akademii nauk SSSR (for Starik-, Afanaslyev).
(Geological time)

VALYigbKO~ Mikhail GeorgiyeVicb, prof.; VINOCRADOVp A.P., akad.,
red.; NEDVEDEV, V.S., red.; red.
[Geochemical features of the formation of deposits of potas-
sium salts] GlOokhimicheskie zakonomernosti formirovaniia mesto-
rozhdenii kaliinykh solei. Pod red. A.P.Vinogradova. Moskva,
Izd-vo Mosk. univ... 1962. 396 p. (KIRA 150)
(Potassium salts)

VINOGRADOV, A.P.
zone melting as a method of studying some radial processes in
the earth. Gookhimiia no.3t269-270 162. (MIRA 15:4)
1. Vernadskiy Institute of Geochemistry and Analytical Chemistry,
Academy of Sciences, U.S.S.Ro. Moscow,
(Zone melting)

VINOGRADOV, A.P.; TUGARINOVO A.J.
Geochronology of the Pro-Cambrian, Biul,Kom.po opr&abo.vozrVgenI.
form. no.5t8-3-1 162. (WRA 1511l)
(Geological time)

Vrll()CaA.[Xlv;l A.P.,-, PE'VIRT6, A.L.; LX')13K1NAp E.I.; WFOVA, N.G.
DAteriftinatiori of the absoluta ap--3 by the r,24. Report Nc-.3.
Ceokhiz,11-a no*5:,387-402 162. (11 LRA 15: A)
1. V.I. Urnndskiy Institut of Ic!o hemistry and Analytical Chemistry~
A(-,ad,,,my r;f SkJrmces.., M.S.R.P Moscow.
(Radiocarbon dating)

-VINOGB&DUL,-AP,,
-.1
Average content of chemical elements in the main types of
crustal igneous rocks* Geokhimiia no.7:555-571 162. (MIRA 15:7)
1. Institut geokhimii i analiticheskoy lrbimii imeni V.I.
Vernadskogo, AN SSSR, Moskva.
(Chemical elements) (Rocks, Igneous)

VINOGRADOVs A.P.; VDGVYUNS G.F.
I Diamonds in stone meteorites. Gookbimiia no.8s7l5-720 Ag 162.
(14MA 16 &9)
1. Inatitat geokbimii i analiticheskoy khIm4i imani V.I.Ver-
nadakoga AN SSSR., Moskva.

VINOGRADOV A.P.; GRINMO, V.A.; USTINOV, V.I.
I
Isotope composition of srulrur-compounCID in the Black S".
Gookbixiia no.10:851-.873 162. (K= 16:4)
1. Inatitut pokhimii i analiticheakoy khUdi imeni V.I,
Vernadskogo AN SSSR, Moskva.
(Black Sea--Sulfur isotopes)

S1011162100010111001IGGI
AGo6/Aioi
AUTHOR: Vinogradov, A. P.
origin of the Earthb she'~-
TITLE: us
PERTODICAL: Izvestiya Akademii nauk SSSR, Seriya goologicheskaya, 1962,
no. 11, 3 - I?
TR7T: In a report delivered at the general assembly of the USSR Academny
of Sciences on June 30, 1962, the author investigated the origin of the Earthts
shells and their different physico-chemical nature by a new experimental approaci-L
He supports the concept of the cold origination process of the Earth. During the
whole geological history the upper layers of the E~Lrth were enriched with more
low-melting and less dense substances than those of the Earth mantle. It rnust be
considered that under the effect of heat from the radioactive decay of the pantle
(the meteorite substance) melting and degassing of the low-melting and low-vola-
tile substances take place. An analogy of this process is represented by zonal
,melting. The analogy of the melting and degassing of the mantle and of zonal melt
ing consists in the fact that the liquid (low-melting phase) passes through
Card 1/3

310 1 11621GOGGIGI 1/001/0G!
origin of the Earths shells A0061A101
multiplo diffunion through the solld phase of the mantle tuld is finally enriched
(in the zone of the Earth crust) with low-molting and low-volatile componentu.
The author performed a number of experiment:3 with substances of stone meteorites.
These experiments show that if heat pas&es through the meteorite substance (or
the mantle) at a considerable ther:i;al gradient, zonal melting causes, as a result
of melting and degassing, its differentiation Into a refractory phase - the dun-
ites i.e. the material of the mantle, and the basalts (the substance of the Earth
crust); as a result, individual compounds or chemical ele:...-.nts are corresponding-
ly distributed between these two phases. The method of zonal melting in the so-
lution of geological problems is most promising. It has proved that 1) the sub-
stance of the mantle is identical with the composition of meteorites; 2) the
thickness of the Earth's crust is a function of the planet riAlus 3) during the
whole evolution of the Earth, a grandiose, radial process of melting and degas-
sing of the mantle subs-.ance takes place under the effect of radioactive heat and
results in the formation of continents, the oceans and the atmosphere, which are
thus of secondary origin, Recommendations for further research are given. There
are 16 figures and I table.
Card 2/3

'
Origin of tho Earth'a shells A006/A101
ASSOCIATION: Institut geokhimii i analiticheskoy khimii. im. V, N. Vernadskogo,
AN S,93R, Moskva (The Moseva Institute of Geochem'istrj and Analyti-
cal Chemistry imeni V. N. Vernadskiy, AS USSR)
SUBM.ITrED: july 6, 1962
z
Card 3/3

VINOGRALDOV, A.P.
Discussion on the mechanics of the separation of radiogenic g,,e,.
Gookhimiia no.12:1108 162. (MIRA 16:9)
(Argon)
kI& ,M w ...........

- --I
VINOGRADOV, A.P.; TUGARINOVp A.I.