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SCIENTIFIC ABSTRACT VIZELMAN, L.M. - VIZGERT, R.V.

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CIA-RDP86-00513R001860210005-8
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December 31, 1967
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SCIENTIFIC ABSTRACT
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VIZZLIKAH, L.M., innhener; KWKOV, A.P., inzhener. AiAomatic vendipC machines for vegetable oil@. Izobr. Y SSSR 2 no.6: 14 is 157. (MIRA lOt8) (rending machines) (Oil and fats. Idible) AUTHORS: Vizellman,L.M., and Slutskiy,L.Ya, SOV/19-59-6-3'63/695 TITLE: A Measuring-ro'pper (Dozator') PERIODICAL: Byulleten' izobreteniy, 1958, Nr 6, p 81 (TJS'-R) ABSTRACT: Class 42b, 16. Ur 113725 (583945 of I Oct 1957).. Submitted to the Committee for Inventions and Discoveries at the I'Mn- isters Council of USSR~ A measuring hopper for liquid, equipped with a hermetically sealed measuring container with a drain pipe closed by an electromapnetic valve open- ing with a time delay; including an electronic time relay consisting of chains of capacitances and controlled resist- ance8 connected by a switch into a circuit with a relay for opening the electromagnetic valve and for starting and stop- ping the vacuum pump sucking liquid into the measurinp con- tainer. Card 1/1 VI ZzLY) G. "Changing of axeload due to drive in laco,-~,otives." p. 106. (KQZLiZ-;,'b SZEUE, Vol- 3, no- 3, Mar. 1195 ?3. Budapest.) SO: Monthly List of East European Accessionss Vol. 2, #3, Library of Congress August, 1953, Uncl- VlZrLYT, Gy. I'lleur 2,()CO-TIP Di.esel-Electrlc Joconotive". P. -4.0. (ITZI07D rj,.dnre5t, ESTLT-01-I'M MEI-F, Vol. 4, No. 7/8, JulY/kc- 1`54) 1 Hungary) SOs Yonthly List of East Eumpeen Acccf~sioris, (EFAL), Lrj 1101- 4) No. I., Jan. 1955, Una!. of ftLwsl conceritric gvrirgs with C CU 3r Croff cc I- cc recurrence Fnelliod 'LL-- zrv~ lation of each t-rm "i ll~ II~o s--Oy-,-; HEGYTI A. Swing characteristics of the series V- 55,001 electric locomotive of the Hungarian State Pailroads. P1193. (JAPMUTIEK ES CEPEK, Budapests Vol. 1. no. 7p July, 1954) SOt Monthly list of East European Accessions (EEAL), LG, Vol. 4, No. 1, J!'n'- 1955, U~classified. 49, Chsalits 404 to drive In the axle pressur.! of railway niallys p"er. - I/a/ldt oisian pirtlp,7 SY004-411ards MSSW OGNIAJ jdrjUO4W1A -0,7c;ly. Vimly. (Ndentific Review id Communication - tdjrAt4U-.""1 111110-blyi Ste"Ill -- Val, J. 9953, No. 2, PP,'57-65, NO, 3, IT, 100-112" is flull.) Itailway ruolivo ix)wcr w10% different driving pars tile comprLA front tho xMisilpaint. of chnnges In x0o pressure occurring during traction (starting) and.braking. As.a result ot these Investigation,% the various_LXRM.2L_- Motiva power and 4mvicet ate listed, in which changq~ in axle pte"Uto due to e and braking cause serious Hapgari4n ToolitUO&I Abot. shortcomings in service. Sinco changcs in axle pressuse Vol..*6 No- 1 f.1 owing to drive are the most detrimental to electric &W. dloW-eLicttic kx*mUves with Individual axle ~drive .1954' hauling litivy:trains; or'traveling heaty, trades, over the articla deals In detail with methods for eliminathig the chaelles In axle pressura,due Ao drivi. of locomotives fitted with pose-auspended motors. The first stop in' .attaining -this gisial Is to ensure -by proper dosigulng a minimum change 14 axle pressure and . thereby Me Optiniqui exploitation factor. The next step " whermtr necessary In Ose,electrical balancing of changes In axle 14tom be"". IQ the Optimum fixpwtaticn,~ of t4., J711P ~O VIZ11.14, I., & I'l , Vizen, E. M. - "On cert.nin properiles o' firuarm. woiunds to, the peri;ihiered nerv-,15 sy,stem during thr.- Great PatrioLic ~Jarl', Trudy (lZileV. j~0!;. JI"d. -;n-t), Vol. VI, 1911"', P. 55-5). SO: U-hlIO, 17 jr-aly ", (Letopis lZhurnal InyVh Statey, No. 19, 19L9). VIZZL0, E. 1-I., PROF UMMediolne - Spaom Jul/Aug 48 Medicine - Nervous System "Criticism of Prof D. T. Kiumovle 'New' Phenomenon 'Yagodiahn.yy Klonual," Prof E. M. Vizen, 1 p "Nerropatol I PalkhIat" Vol XVII, No 4 "Wevropatologlya I Palkhtatriya" No 4, 1947, published article by Wmo7 in which he cWmed to have disco7ered a new phenomenon called "Yago- diohikyy Klonus.* Vizen points out that'same pheaccenon was described in 1915 by Joffroy under name Heluteal apase and Investigated by Vizen at Odessa. Editorial aarees with Vizen and qaotes other references to wnew" phenomenon. AM. 14/49T77 FA 1~,/~-,9777 C%I Md/Meacine - Brain - Dissaaes War/Apr 49 Mealcine - Cysticarcesis *Cysticarcosis of the Brain," Prof Te. U. Vizen, Dir, Clinic of Nervous Diseases, lzhevak Pe& Inst, 1 P "Revropatol i Paikhlat" No 2 Variable local infection and fluctuation in the morbidity rate of this paraoitic-disease depict wiltiplicity and atypical mature of Individual symptoms and the %rhole clinical picture of cysti- cercosis of the brain. Characteristic development of the pathologico-anatemic process of this disease 61/49T52 Brain - Diseases Jkr/Apr 49 (Contil) explains rapid appearance of initial symptoms and sritdden exacerbation. gosinophilia of the blood and humor is not alwayp the determining factor in & the I ~the diagnosis of cysticercoal-a of ormin. Sub- nitted 8 mar 47. 61/49T.52 MEN) E. ~". Vizen E. 1.1. "Sano resultr of the work of a co-i:-,iiltant-nouropatl~olo,,ist in evacur,"'J"JI'l y - )-jonpj,tnI..n,'f Tnrly II,'e(Jinqtitiita r.on. ned. in-t), Vol. VII, 1~1;9, p. IJ42-,ri: 1. SO: U-3f",50, 1~- June 53, 'ZInurnal IrWkh Statq,-) 111'0. 5, 1~41~) VIZEN E. M. 1030. VIZEN 2. M. Neurolog. Clinic,, Mod. That., rj*vsk Cerebral cyaticarcosis Neuropathology and Psychiatry, Moscow 1949" 18 /2 (50-51) T"* diagnosis of the disease is very difficult. Observation of three cases. The diagnosis in the first case was tumour of the 17th ventricle, in the second meningoencephalitis or brain tumour and in the last brain tunour, The fact is underlined that there are no characteristic signs of eysticercosis., but the first cere*L:al symptoms appear not only with unusual rapidity,, but they also become rapidly more acute. There is very often no eosinophilia. Teyschl - Brno (XX, 6, 8) So. NEURODDGY & PSYCHIATRY Section VIII Vol. 3 1 Jan-Jm 1950 Excepts. Medica VIZEN, Ye.M.; YILIPPOVICH, 1-11~w?",--,"-1~2,-~'! Acute seasonal serous 29-33 )(r-AP '50. A.N.; SHORINA. Y.K. meningitis. Revropat.paikhiat., Moskys, 19 no.2: (GLML 19:3) 1. 1zhevsk. vizm'(11. ,m. - ~ I ........ [Headaches] GolovWs boll. Izd. 2. Moskva, Medgiz, 1951. 65 p. (MIRA, 6;9) (Headache) VIZEN, B.M.. professor. . ..... The course and clinical features of neuroffyphilis. Sov.med. 19 no.10:59-63 0 155. (MLRA 8:12) 1. Iz kliniki nervnykb bolezney Izhevskogo meditsinskogo inatituta. (STPHILIS pathol. & clin. aspects) VIZEN., E.M. Atypical forms of tick-borne encephalitis. Ziazr. nev-.. -1 63 no.10 1462-1466 163. WIRA 17:5) 1. Kafedra nervnykh bolezney (zav. - Prof. E.M. Vizen) Permskogo maditsinskogo instituta. 7'r t c. z tiL VIZEN,, E.M.,, prof.j GOLOFASTOVAY Ye.Ya. (Form') Tick-borne encephalitis in the western Urals; according to materials from the Clinic of FervouB Dioeases of Perm Kedtcal Institute. Klin. med. 38 no.3246-52 Mr'60. (MIRA 16;7) 1. Iz kliniki nervn7kh bolezney (zavo - prof. E.M.Vizen) Perm- skogo meditainskogo instituta (dir.- prof. I.I.Kositsyn). (URAL MOUNTAIN REGION-ENCEPHALITIS) (TICKS AS CARRIMS OF DISEASE) VIZIN, 1114. fessor (Molotov) Acute seasonal serous meningitis Oiandulant viral maningooncephalitle) Klin.med. 34 no-9:51-56 S 156~ (MLRA 9:11) 1. Iz kafedry nerwnykh bolesney (zav. prof. R.H.Vizen) Molotovskogo meditsinakogo instituta (dir. prof. I.I.Kositayn) (NNNINGOIRN(MPHALITIS viral. seasonal) VIZEN,, E.M.; KNYAM, A.N. Case of laboratlory Infection in =a with the virus of tick-boime encephalitis* Zhur. nevr. I psikh. 62 no.3: 333-338 162. (MIRA 15:3) 1. Kafedra nervxWkh bolezney (zav. - prof. E.M. Vizen) i prozektura (zav. - dotsent A.K. KUazev) Permskoy gorodskoy infektsionnoy bol,nitoy. (ENCEPHALITIS) (TICKS AS CANUFM OF DISLW) USSR /* Virology- -Viruses of Man and Animals; Viruses of E Transmission Infections Abs Jour: Ref Zhur-Biologiya, No 21, 1958, 94867 Author : Vizen, E. M. Inst : Molotov Medical Institute Title : Diaphasic Meningoencephalitis Virus Orig Pub: Tr, 1.1olotovsk.-m6d. in-tal 1957, vyp. 27, 207-214 Abstract: No abstract. Card 1/1 VIZRN, N.H. (Molotov) - Some problems in teaching neuropathology in medical schools. Zhur. novr. i paikh. Supplement:52-53 f57- (MIRA JI-.J) (16CUROPATHOLOGY---SUTDY AIM TEACHING) SMAGIN-j A.G.; VIMWv. P-L. -- Ur's bm of OR cut for vnderground smaillatorso In* 1. v , tskb . no.548-;Nt (KU 17 V ) [ACC NRs AT6020235 SOURCE CODE't U11/2569/65/000/077/0056/6061 AUTJ10RSs Smagin, A. G.; Vizent F. L. ORG: none TITIX,.- Quartz bars out along the X9009 -y-direction# for underground quartz Generators SOURCEt USSR. Komitet standartov, mer i izmeritelInykh priborov. Trudy institutov Komitetal no-, 77(137)p 1965- Iosledovaniya v oblasti izmereniya vremani i chastoty (Research in the field of time and frequency measurement), 58-62 TOPIC TAGS: quartz, quartz clock, quartz crystal, vibration frequency ABSTIUCT: Precinion crystal quartz frequency generators for use in well thermostated- .(-+ 0.0001C) conditions, i.e., underground positionalwere developed. The generators are made from quartz bars out along the X900, V direction (Ya. Groahkovokiy. Generix.ovaniye vysokochastotnykh 'kolebanik i atabilizatBiya chaototyp M., IL# 1953)- The temperature dependence of the frequency of thequartz bars and the magnitude of the frequency coefficient NO) were determined as a function of the angle (see Figew- 1 and-2), where the frequency coefficient 11(~) in given by N AC:~ ~jR, AR, 202;)j 17 ell $9 0 a fm /1# 00 ffe Fig. 1.- Dependence of the temperature Fig. 2. Dependence of the frequency of a zero thermal frequency coeffi- coefficient of Xg,,, P -cut quartz cient on the angle of cut bars and the angle of cut in which K is the orde'r of the harmionic,P densiVy of quartzp S OE elasticity 2,2 - constantf ,P - the lerigth of the bar. In additiong the dependence of the Q-factor on the pressure was also determined (see Fig. 3). ~t in concluded that X9009 ~V -cut quartz bars may be used for the construction of quartz frequency generators having a zero thermal frequency.coefficiento The authors thank Yu. 1. Shmin for his help. 0-, ftg. 3. Dependence of the Q-factor of Xgoop I -gut quartz bar an the pressure Orig. arto, hasi 2 tables, 11 gmphog and 2 equatims, SUB COVES Ogg Ii/ SM D=s '--juo62/ ORIO Mrs 002/ Org IUW 1001 Card vizial, 1. P.ormanently re-olected committea prosidont. Muot.ugl. 8 no.2: 13-14 F 159. (MRA 13: 10 (Sukonnikov, Awrooli Ivanovide) SOLCDIKO, D.. prokhodchik; ZkKHA.ROV, A., rabochiy ochistnogo saboya; 7ADOHOZHATYY, K., vzryvnik; KOVIKOT, V., rabochly ochistnogo zaboya; X&SLIKOV, D.. baril'shchik; YURCHKNKO. I., gornyy master; ZAIU=ITO P.. brigadir elektrikov; USSWOV, L.. lituotrudnik shakhtnoy gazety; VIZEN, _I,;, DOEICIIAYBV, A. Our inspection raid. Kasteugl- no-10:11-13 0 159. (MIU 13:3) 1. Reydovaya brigada zhurnala "Master uglya," 2* Literaturnyy sotrudnik zhurnala Naster uglya." (for Vizen, Dokilchayev). Oonete Basin-Coal mines and mining) (Mine management) VIZENI 1. Mineral captain. Mast. ugI. 7 no. 5-13 MY 159. (,'4r?,A 11:?) (Siniagovskil, Patr Lfimovich) VIZIN, 1. Gorlovka miner. Maet.ugl. 8 no.1:19-20 Ja 159- -AMIRA 12:3) (Donets-Basin--Coal miners) k . 6 VIZENP'I. Dp*. , Yruit of brotherly friendship and cooperation. Mast.ugl. 4 no-5:30-31 MY 155. (KIRA 8:7) (Hungary--Coal mines and mining) VIZIIN, I. Photo report: A base of advanced engineering. Kast.ugl.2 no.11:7-8b N 153. (KULL 6:11) (Korkino--Coal mines and mining) (Coal mines and mining--XDrkino) VIZEN, I. Iron mines. Mast. u91. 5 no.8:8 Ag 156. ()WA 9:11) (Donets B&GIn-Coal mines and mining) VIZIN, I. -MUlbi Pol'shchikov- Mast. U91- 7 ne.11:14-15 N '58. (KMA 11-.12) (41'shchikov, Pantelei Mikhailovich) VIZEN, I. To Nicholas Vz-mai, nSevernava".mine nO.2, Krasnodon. Mast. ugl. 7 no.8:10-11 Ag 158. (MIRA 11:9) (Mamal, Ilikolal IAkovlevich) - -VIZEN, I. Noble purpose. Wat. u91. 7 no.9:24a-24b,25 S 158. NIRA 11:10) (Coal miners-Dimeanes and hygiene) V IZEN, I. ExcWllent minor from Krasnodon. Hast.ugl. 7 no.4:8-9 Ap '58. (Donets Basin--Coal miners) (MIRA 11:4) (Russia--Politics and government--Biographies) -:-- T, I#- --- - "Minor's light.* Mast.ugi. 6 no.9:8&-8b S 157. (MIRA 10.11) (Coal mines and mining-lquipment and supplies) JZ_ f -7 ~ ./ -, / /Q~ / x VIZEN, I. - Named in honor of Illich. Mast.ugl. [61 no.11:8-9 X '57 (XIRA 10:12) (Donate Basin--Coal mines and mining) VIZEN, I.-I.-I.- . A brigade leader from Novevolyusk. Ykst. ljgl. 8 nc.7:10-11 Jl '59. (Novovolynak-Ocal miners) (KIRA 12:10) VIZEN, 1. UNWAiN Donets Basin. Kast. ugl. 6 no.8:8-10 Ag '57. 01MA 10:9) (Donets Basin--Coal mines and mining) 19(5) SOV/127-50/-71-13/22 AUTHOR: Vizentall, I.B., Engineer TITLE: The Central Controling High-Frequency Communication Net in NllininC Enterprises (Dispetcherskaya vysokochas- totnaya sv-yaz1na Cornorudnykh prodpriyatiyakh.) PERIODICAL: Gornyy zhurnal, 1959, Nr 3, PP 50-53 (USSR) ABSTRACT: The Konstruktorskoye byuro Tsvetmetavtomatika (Design Office of Tsvetmetavtometika) (KB Tsl-.!A) developed the following series of installations for high frequency communications in mines: a central control installation VChS-123 for electric locomotives, VChS-122 for exca- vators, and a broadcasting and enq,,iiry station VSO-124. These devices were installed in the Kapitallnaya Nr 2 pit of the Degtyarka Copper Mine, where two controlling posts were organized, one general dispatcher for the pit and the second - for transportation operations. The VChS-121 control installation is a transceiving station with selective abonents1calling, a feeding Card 1/3 block. The VChS-122 and VChS-123 installations dif- SOV/1-27-59-3-13/22 The Central Controling High-Frequency Communication I'let in L.'ining Concerns. fer only in feeding systems. The first is fed from an a.c. riet of 127 or 220 v and the second -from the contact d.c. net of 250 v. Each installation is composed of a transceiver with a loudspeaker, a feed- ing block, and a microphone with a signalling bulb. The broadcasting and enquiry VSO--124 station can be installed in different parts of the pit. Its power- ful amplifie-r- ald loudspeaker make it audible over long dist-inc~:S- 1.~nderground. All. general dispatcher's orders, or enquiries can be broadcast through this statixi. Disturbances in the high frequency communi-a'.'-nn L4n--s are- eliminated by trolley filters Card 2/3 FTZ-209 ano. -1-C,~0MOtive Mters FEZ-208, as well as SOV/127-59-3-13/22 The Central Controling flif-h-Frequency Comnunication Net in Mining Concerns. by the hiji frequency connector VP-87. The seri&l production of the above devices is being organized at the Tsvc.,tmetDr1box- Plant in Nallcliik. There are 3 pho-os and 2 hac.-O"'Iflo. ASSOCIATION: TsvetmetavLomatika, Mloscow Card 3/3 VIZEVTALI, I.B.,, inzh.; SIAMASHVILI, Zh.G,,, inzh. Testing machine for detecting defects in steel hoisting ropes. Gor.zhur. no.5:49-50 My 161. (MIU 14 g6) 1, TSvetmetavtomatika, Moskva. (Wire rope-Testing) (Testing machines) KUTSMAM,, Arpad, oklevolen vill.mornoki 1EPERE, Judit, okleveles vill.mernok; RIBEhM , Andras, okleveles vill.mornok; VIZLR?_Jonoj okleveles vin.mornok Voltage coupled semiconducting logical circuits. Meres automt 10 no.8:238-47 162. 1. Elektronikus Meromuszerok Gyara. I PAPP . Andrea , dr. ; Ilona, dr. ; VANIOS , Goza, dr., VIZER, Klara, dr. Experiences with tubercu-Icsis patients treated for the lot tJmo. Tuborkii1ozis 17 no.gj:130-136 My 164. 1. Az Allawd Fcdor Jozsef TBC Gyogyintezet kozlemenye. KAZDOBIN, A.S., inzh.; SHIMN, N.A., inzh.-, VIZERIN, I.V. inzh. . 0--- i~ Floating KSP-2,7 mowing machine used In obtaining reed for ensilage. Trakt. I. selikhozmaRh. no.11-16-17 N '58. (MIRA 11:11) 1. Gosudarstvennoye spetsiallnoye konstruktorskoye byuro po sellkhozmasbi- nam pri Gosplane USSR. Nowing machines) (Reed (Botany)) i - . I I- 4- 1~ t ' ! - t- II I _1 ~ - , ~ EL , V VIZJWTAL I , Ye. Pashkinskiye Gory. Za rul. 15 no.7:2Z JI 157. (XIBA 10:9) (Pushkinskiya Gory, Pskov Province--Description) VIZER i VIZER, J. Sainfoin. P. 343 Vol. 8, No. 8, August IS56 AGRARTUDOMANY AGRICULTURE Budapest SO: EAST FUROFFAJ4 ACCESSIONS, Vol, 6, No. 3, March 1957 -- ~ I.-- - ..-~ 1 -1 It ~ 11 MMEMMMME --- - - -- - - - - -- --- - - PAPP, Andrs-3, dr.; ILLES, Ilona, dr.; VAMOS, Geza, dr.; VIZER,,Klara, dr. Pathogenic significance of calcified foci of tuberculotic origin in the lung: the cavernolith. Tuberkulozio 15 no.12066-374 D 62. 1. Az Allami Fodor Jozsef The Gyogyintezet kozlemenye. (TUBERCULOSIS, PUU40NARY) (CA.LGULI) PAPP, Andras, dr.; ILIES, Ilona, dr.; VIZER, Klara, dr.; VAMOS, Geza, dr. Remote re3ults of drug-induced cavity closure. '1`uhl~.rkulozis 17 no.6:-174-176 Je 164. 1. Az Allami Fodor Jc)zsef Tbc 02iogyintezet kozlemenye. -----V v 2 C k 1// - - --- -- - BLITSYKIN.Ya.; VIZERSKIY,B. Gontinuous work schedules are the basis of success, Mast. ugl. 4 no.1:5-6 A 155. (MLRA 8:6) 1. Naohallnik uchastka [no.361 (for Butsykin). 2. Pomoshchnik nachallnika uchastka (no.361(for VizerskiA.- (Coal mines and mining) 15375* 1"Neslignilon fit OIL (Erglish 1, 1 irig ind M Vi- t Ada Clififfew 4cfdembla ~ilp-orjlllorl qfe,tij of four diiij,vto,iiin,icr Indri ~,d 1 2 tT-fZj,- b7 ZW4 (2-07)i 241:5 M.5 T! F TZ, P, VIZIRSY, H. NInvestigation of the Spectra of Diastereo-Isomare.11 In EnglAsh. P. 1, Bmlapest, Vol. 4, No- 1, 1953- SO: Ust 3kropsan, Accessiona List, Vol. 3, No. 9, September 1954, Lib. of Congress KOSA SOMDOYI, latvan;_~IU-SY, Maria Phosphorescence of FeC13 containing dimethylan.11.1ne Jrradlr-*Is~-d at low temperature. Koz fiz kozl YTA 12 no.4z287-297 164. 1. nAntral Reanarch Institute of Phyuics, HungarJan Acader-7 of Sciences, Budape8t. VIZGALOV, V.M, - Choosing a map scale for calculating cloudburst runoff. Avtodore. 24 no-.6:26 Je 161. -r (mm 24:7) (Ra-iji iind' rainfiill) VIZGALOV, V.14. Results of the observution of traffic intensity on road crossings at various levels. Avt.dor. 25 no.4:15,-16 Ap 162. (MIRA 15:5) (Traffie engineering) VIZGALOV VX inzh. t Tarious Operational ebaracteTistics of bighway crossin s a levels. Avt. dor. 26 no*.1218-20 Ja 163. T;,;~ 3AW (Reads) All. ma MAOMR, Rqrzyy-AR!R BOUOM, Ya.P.; VIZGPM, R.V. Raters of 4,41-dioxydiphenyloulf one. PfLrt 1. Synthesis of esters of 4,41-dioxydiphenyloulfone and aliphatic acids. Ukr.khtm.shur-17 no.2:264-269 '51, (KLRA 9:9) l.L'vovskiy politekhnicheakiy institut. (Acids, Patty) (Sulfone) RKMAN, Ya.P.; VIZG fA--jk V414WIMMR~I' b Rotors of 4,40-dioxydiphanylsulfous. Part 2.Synthesis of asters of 4,41-dioxydiphenylsulfons and aromatic acids. Ukr.khim.shur. 17 no.2:270-273 151. OWA 9:9) l.Livovskiy politekhnichaskiy institut. (Bulfous) (Acids, Fatty) -,~rlmutic sulfouic acid"; asclaor? ITI~-,t to! III cr; '-f-mt, T. ri 4~ Eslard )f4,4~-dL'iydt4xydiphenyt.-uYoue. IV. Sytiffirs-fs of Inconi-lete ustea of 4,41-dihydrotydpI:e1yI s-5Ifo:M Wilh - -d- i c cF&JoxTff, -sc a -.03'$e iuld arent-At , i! :4 ,fill .11C i: in. P. ao", R. V. ILVIV - -Ir Ah) Z~4;~ (in Ru~,J,,n); cf. C.A. 43, MrZOr.-To 21-5 s,. drat;y-liphtryl julfe- (1) (it 4 int. A(-Off was ad,liA f r. 11,1.0 followcd by 6 ud- pyridine added t1topwi3c Willi Attr whicli the mixtur W11.1 kcpt at M' tintil I3r.CI hA c fe;ji:tM, s-.,it h dil. 1175C)i gayq a M~,Vly cr)gull- RzItig oil, 'ihidi was eltd. -.~itlk C~11, aild the evapd. cxt. kivt! t, i, "".crlyt 1, m. 1404,2* (cf~idr-), in. 151-3.. W!,ic- 1i oil of I -i6lh 0,65 mol-, ArCl bi the pri-,ictice of pytidine gave au 01 which apjwucit to he pmdy the inourt-sle dcriv., which erywallittA al(ce cowdiderable time cold wa,; Idendcal with the ab)ve. Itcaction of A u. I Willi LBS g. BzCI and 15 t-il. pyridiiie- gave 0,9 1. di~-Bx 1, in, 2-15-7*, and OA X. lamo-Rd 1. M. iW-200 , which ww., s,,p4l. by extri. with rtoij (dIT i dt., iv. 1,.t Insol.). Ittaction, of I ~itl% MCI In Liv prr-wucc of 105'& &011 gave 37% dl-Ilt. dtify. and 20 f O juorle-1lz deriv. Reaction of 2.6 S. with 1.18 C. PhS , lit 10"0 NaOIT gave 4370 p-BAL5GCfH4SO-C4fftO11-P (11V -C1- t IM-S' (f i1 v d i MOM 31% l . i ). m ar ra.s prep tom , a y P s coff"Pondial; P-Br andoc, M. M0-2 (from C4114), an 0 cl corr"pondbig nt-OiN amakC. m. 168-430 (from Ht- 23 / Off - Monoinnyoyl I and PhSOXf Iv. 6170 NaOlf pve a ~ 101ir yield of p-1,'--OW1,SOCj14Oj,5PA-p, m. 144--0 ;. the szrna 1VIM oblairwd from 11 and BzCL G. M. Kmolamlf V'Aa fniucai-e of the alwhol domtituerlt 0a tho r8to of (,P, Vl'~" Y'l 16 *4' and a V. ra. Zhw-ft- ~W 1", N., T1 2 fn~ Ian .--:!he rate of alk. hydrolysil, 'ITT 14, red for Etoll (Q, PhOH (U), 4-I1OC#H#SOjC,114- DIOR ill a snixt. %u I< 13 < Ill - C1 > lir > E. Gay G'f'l fL VIZGRRT, R.V. Hydrolysis of esters of aromatic sulfo acids. Ukr.khim.zhur. 20 no.3: 272-278 '54. (MLRA 7:8) 1. Llvovskiy politakhnicheakiy Inatitut. (Hydrolysis) (Esters) (Sulfonic acids) ~ I'll- I A gR 140!~ tii T~t,t7~- T -MTTT, -IT-.! 1 -777; VIZ 7, -, -G.14TV 14V.; A.;-. i~!F.111111A, 1.~:. lnfram~ ab3orpticr, of esto~;r:~ of --mbrtit-ute-i b~nzer..-:,- oulfordc acido and pilipriol. Mir. fiz. zh~Lr. 8 N 164. (ILiA 17:9) 1. Institut fiziki All Ukr33J.9 "iyev. VIZGXRT BAVCHUX, Ye.K. Hydrolysis of aromtic sulfouic acid eaters. Part 3: Hydrolysis of phenyl esters of substituted benzenesulfonic acids. Zhur. ob. We. 26 no.8*.2268-2273 Ag 156. (KLRA 10:11) 1. Llvovskiy politekhnicheakiy institut. (Benzerkesulfonic acid) BIJW,GV, S. N. VI""GBRT. R.V. Effect of the characteristics of alcoho.- cr.=orients on the rate of r-br-ali hydrolysis of complex ethers. Part 2: HydrolyRin of phenol ethere and benzyl alcohol@. Zhur. ob. Mix. 27 no.4:QO9-913 AD 157. (mLRA ib:9) 1. LIvovskly meditainekly, inatitut i Llvovskiy politekhnicheskiy institut. (Benzyl alcohol) (Ithers) (Ikydrolyeis) 79-28-5-7/5/69 AUTHORS: Baranov, S. N., Zhoglo, F. A., Viz&LZJ~ Complex TITLE: Synthesis of Some/Esters of the 4,41-Dioxydiphenylsulfone and of Carboxylic Acids(Sintez nekotorykh slozhnykh efirov 4,4'-dioksidifeniloullfona i karbonovykh kislot) PERIODICAL: Zhurnal Obahchey Khimiiv 1958, Vol,; 20, 11r 5, PP~, 1274 - 1276 (USSR) ABSTRACT: The authors aimed at synthetizing the full asters of the 4,41-dioxydiphenyl2ulfone and of some oarboxylic acids of the aliphatic, aromatic and heterocyclic verios. In refer- ences there are remarks concerning the synthesis of the asters of 4p4l-dioxydiphenyloulfone by its condenzatiorr with acids in the presence of phosphoroxychloride (Reference 3). The came method was used here. The products necessary for the synthesis were taYanoready mada'or according to the me- thods described in references. The purity was checked accord- ing to chemical constants and in soma cases also ana- lytically. For the synthesis of the asters the dry dioxyd- Card 1 iphenylsulfone was carefully crushed with the acid ( i part -6r 79-2P--5--'5/, C0111ple, Synthesis of Some/Estero of the 4,4'.-Dioxydiphenylaulfane and of Carboxylic Acids 3ulfone: 2 parts acid), the mixture was heated in the flask to 12o - 1400C and into this the- calculated amount. of phosphoroxychloride was addedin drops The whole was heated to the complete removal of hydro~-en chloride; then cooled and treated with 51~1~ coda solution; the organic and inor-anic acids~ as well as the above~r~entioned aulfone which did ~ot enter reaction,were removed. The final product ` the eater, was recrystalli'zed. Furthermore the ester of the a-bro mi.oovalerianic acid and of the dioxydipheny1sulfone were ob-, tained on heatino the bromoanhydride of the same acid with the sodium salt of the dioxydiphonylsulfone. All synthetized esters are white or light-yellow Rollery products; they are difficultt,,,3 disscive in water an(V" ~3 Ysoluble in alechol, acetone and dioxane., They hydrolize on heating with lo% alkali solution., The properties of the 14 synthetized esters Card 2117A are mentioned in a table, There are I table and 4 references,, .-ATHOR: Vizgert, H. V. T Hydrolysis of the Esters of Aroinatin , .:ulfe ("Lir-' efirov aromaticheskikh sullfokislot) V. The -f the Esters of Benzonesulfo 'Acid and of :;ub-,!titut--,,d -hcria-1 (V. Gidroliz efirov berizolaullfokisloty i zam,,sh,~,-,Onnt,,-J -'iIODICAL: Zhurnal obshchey khimii, 1958, Vol. 28, Nr 7, p!-1.1f37.-;-11`7B (USSR) ABSTRACT: A great number of factors exerts an important influ~-ncc on the mechanism of the hydrolysis of estera: 1) The hydro]yzis conditions (catalyst, solvent etc.(Refs 1-3)); 2) The c-cil properties of acidous and alcoholic components (Ref 41); 3) The presence of the spatially ramified substituents in the acyl- and alkyl radical of the ester Oefs 5-7). The ill- crease of the acid properties, of the ecid as well as of th,~, alkaline component, does not only increase the velocity of hydrolysis (Refs 8-10) but also often changea the mechanism of hydrolysis. In the eBters of fatty acids with aliphatic- aromatic alcohols and phenols the break of binding occurs at Card 1 the acyl Olefs 11-13, 35). The entere of the acid of m,~an SOV/79 - 2 8 -7 -32 1/~(,A Hydrolysis of the Tsters of Aromatic Sulfo Acida. 7. The Hydroly~i3 of tf~- Esters of Benzenesulfo Acid and of ;'ubstituted --henol strength (e.g. phosphoric acid, nitric acid) and of' the ali- phatic alcohols hydrolyse at the acyl and alkyl depending on the medium, the esters of strong acids (e.g. of HC10 (Ref 4), of benzenesulfo acid) and aliphatic alcoholp, An,;"- ever, hydrolyze only at the alkyl. It was of interest to find out which, influence could be excerted.by the introduction of substituents into phenol on the velocity of reaction and the mechanizm of hydrolysis of the aryl sulfonates. The veloc~;ty. of the alkaline hydrolysis of six enters of benzenesulfo .' -,Cic and of the substituted phenol were investigated. The incrl?a:7C, of the acidity of the substituted phenols.increaeos the v-,Ioci- ty of hydiolysis of the corresponding estere of benzene2ulfo acid. The electronegative substituents in the alcohol r-n.-:,i,,.)- nent are of great influence on the velocity of hydroly-10. Ortho-Bubstituents in the benzene ring of phenol do not. P.-fert any influence. There are 5 tables and 35 references, K c,' ,which are Soviet. Card 2 AUTHORS: Vizgert, 2. V., SLvchuk, Ye. X. TITLE: Hydrolysis of the '"stere of the Aromatic '*ulf onic ;.ciis (Gidroliz efirov aromuticheakikh %ul'Pokislot) VT. and Aqueous Hydrolysis of the Nitro-l,ubntituted Compounf"s of Aryl Sulfonatee (VI. Shcholochnoy i vodnyy gidroliz nitro- zaineshchennyk-h arilaullfonatov) PERIODICAL: Zhurnal obahchey khimii,.1958, Vol. M, 11r 6, pp. 2114-2119 (USSR) ABSTRACT: In previous reports which deal with the investigation of the kinetics of the aryl sulfonates (Refs 1, 2) was shown that the presence.of electronegative substituents shorten the time course of the hydrolysis of the aryl eulfonatee in benzene sulfonic acid as well as in phenol (Ref 3)v compared to the not substituted esters. The nitro-group exercises the greatest accelerating influence of all electronegative subatituents. The influence of its position on the time course of the hydro- lysis of the nitro-oubatituted aryl sulfonatee is not equal and depends on t 'he fact whether the nitro-group is incorporat- Card I/L ed in th+enzene sulfonic acid or in phenol. The nitro-groups SOV/79-28-0-26/66 Hydrolysis of the Esterg of the Aromatic Sulfonic Acids. VI. ilkaline and Aqueous Hydrolysis of the Nitro-Substituted Compounds of Aryl Sulfonates in the orthoposition of the benzene sulfonic acid prolongate the durstion of hydrolysis and accelerate the latter, if they are contained in phenol. It was inter;sting for the authors to investigate to which an extent the increase of the number of the nitro-grou a in phenol and in the benzene sul- fonic acid can influencetthe course of the alkaline hydrolysis, an well as to find out rhOther the nitro-substituted aryl sulfonates may be subjected to a hydrolyois in viater, eince it is knorm from publications that phenyl-banzene siAlfonate is not hy4rolyzed by water (Refs 2, 4). Table 4 showe that the introduction of several nitro-groups accelerates the alkaline hydrolysis, compared to the monosubetituted eeters. 6 dinitro-substituted aryl oulfonatea were synthesized and the course taken by their alkaline and aqueous hydrolysis was tnvestigated. The experimental results of the course of the hydrolysis were compared with those of the nitro-sub- sti-tuted aryl sulfonates which rere obtained earlier. Thus it was proved for the firat.time that the hydrolysis of aryl sulfonates with water is passible. There are 5 tublee and Card 2 11 references, 8 of which are Soviet. -Vizgert' R. V., Berkm?n, fa. r. On the Reactions oi the sters of the !-rorit.tic '.ulfonie :.ci--.' (Reaktsii efirov aromaticheskikh sullfokielot) VII. Arylatln,-- Properties of the Dinitro-Phenyl Benzene 'iulfonate3 (VIT ,',.riliruyushchiye svoystva di4nitrofenilbenzolsullfonatov) ,RIO")--CLL: Zhurnal obehchey khimii.. 1958, Vol. 28, Nr 8, pp. 2119-2122 (ITS C-'r") It must be asnumed that the aryl sulfonates chow a similcrity with the eaters of carboxylic acids in the reactions cf a nucleophilic substitution, in the case of a conversion with water, with alkali solutions, and amines. All these retctions proceed according to the acyl-oxygen mechanism. In thie cane, the alcohol radical does not loce it3 bond with its oxygen atoms (11,efa 1-11). In contrast to the aryl sulfonaten and the esters of carboxylic acids the alkyl sulfonates reect like .1kylating agents (Refs 12_ 16). Thus the fissure takes place at the alkyl in the caee of a conversion witn water, ammonia, and amines. The validity of the alkyl-oxygen mochanian for the aryl sulfonates could hardly be expected, since the oxygen 1 is closely bound to the aromatic nucleus: In the present paper, SOV/7)-20-8-27/66 ~.,i tLe "Pections o,,' the .'-Xtors of thp Aront-tic -^ulfonic .cid. '111. Arylatir4r, Prorerties of. the Di.nitro-::h(!nyl Benzene 1;ulfonatea boviever, it wv.s founO that thG dinitro-phanyl Vinzene E!ul-. fonates show a similarity with the alkyl sulfonrtec, i.e. that they may be hy-lrolyzel with water, alkali :-olution.,,, and tare not subjected to a hydrolysis with rci0v. It could be avsumed thL~t thic cimil&rity may be fount' also in other reactions of nucleophilic subotitution. In o.,,-der to examine this cave, a long eeries of e:,-periments was crrried out on the conver.-ion of e2ters from 2r4-dinitro-ph--~nol end benzene .,ul'or,ic-I 9-chlurbenzene eulfonic-, ;,nd o-nitrobenzene oulfonic acid with ammonic, aromatic amines Potassium thio- cy~,nate, and potassium iodlle. The corresponding substituted iinitro-diphenyl amines rzind the 2,4-dinitro-benzene thio-- 3yanave were obtained. The separated reaction producte in- dicate an olkyl-oxygen cleavnge of the 2,4-dinitrophonolates and of the oubt!tituted benzene cuL'onates. '-'here are --I ref- erences, 5 of which are 9oviet. A9`10CIATION: Ltvovskiy pol--;te!:-hniche-*:iy institut (Llvov !'ol-t~chnical Institute) Card 2 /~_ 5(2) AUTHDRSt Vizgert, R. V., Savchuk, Ye. K., BOY/20-125-6-22/61 -Fo -noi-a-r-c-FuW-,7' - P . TITLE: Use of 018 in the Investigation of the Mechanism of the Hydrolysis of the Nitrosubstituted Aryl Sulphonatea (Issledovaniye mekhanizma gidroliza nitrozameshchennykh arilsullfonatoy s pomoshchtyu 018) PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 6, pp 1257-1259 (USSR) ABSTRACTt The hydrolysis reactions of the esters may proceed either according to an acyl-oxygen- (Refs 1-3) or according to an alkyl-oxygen reaction (Ref 4), or finally, according to both mechanisms at the same time (rare)(Ref 5). The electric negativity of the radicals R and RI in an ester R---C 0 OR' (Ref 6) as well as the substituents influence the hydrolysis mechanism considerably if the latter produce spatial hindrances at the place of reaction (Refs 7-9). The question as to the place of rupture and for the hydrolysis mechanism (whether it Card 1/4 proceeds as reaction S Nr 1 or as S Nr 2) of the aryl esters of Use,of 018 in the Investigation of the Mechanism of BOV/20-125-6-22/61 the Hydrolysis of the Nitrosubstituted Aryl Sulphonates aromatic sulfo acids was decided after a long time in favor of the aoyl-oxygen mechanism (Ref 21) (for phenyl-n-toluene- sulphonate). The authors' investigations (Refs 22-24) confirm the method mentioned (S Nr 2) for the aryl sulphonates, If it is taken into account that the aryl sulphonates (as iell as the alkyl sulphonates) react in the above mentioned reactions under the rupture of the O-Ar-bond, it was interesting to investi- gate the alkaline and neutral hydrolysis of the nitrosubstituted aryl sulphonates by means of H 20 8. This was to explain the place of rupture in t 'he hydrolysis. In the present paper phenyl-4-nitrobenzosulphonate (1), 4-nitrophenyl-benzene-sul- phonate (2), 2,4-dinitrophanyl-2-nitrobenzosulphonate (3), and 2,4-dinitrophenyl-p-toluene-oulphonate (4) were subjected to an alkaline hydrolysis with H 2018, furthermore the eaters of the substances (3) and (4) as well as 2,4-dinitrophenyl-benzo- sulphonate. A dioxane-water medium (70% dioxane) served for this purpose. Eater and alkali (113) were hydrolyzed for six hours at 80 0 with a recooling agent. Both hydrolysis pr ?9 ucts; Card 2/4 phenol and the sulfo acid salt were analyzed for their 0 - Use of 018 in the Investigation of the Mechanism of SOY/20-125-6-22/61 the Hydrolysis of the Nitrosubstituted Aryl Sulphonates content. The phenols contained practically no excess of heavy oxygen. The salts mentioned, howeyer, contained a quantity of 018 very similar to that expected in the case of the transi- tion of an oxygen atom into the molecule of these salts. Thus, all investigated aryl sulphonates are hydrolyzed according to the aoyl-oxygen mechanism (see scheme). It may be assumed that hydrolysis takes place in consequence of a nucleophile attack of the OH-ion on a positively charged sulphur atom, A neutral hydrolysis of the eater of the 2,4-dinitrophenyl-2- nitrobenzo-sulfo acid and of the 2,4-dinitrophenyl-p-toluene- sulfo acid was not fully carried out in order to clarify the intermediate stages of the mechanism mentioned. The determined acyl-oxygen mechanism of the eaters investigated here cor- responded to the arylating effect of several of these eaters. Finally it was proved by experiments that no undesired reactions of the isotopic exchange occur under the given experimental conditions. There are 31 references, 6 of which are Soviet. ASSOCIATION: Ltvovskiy politekhnicheskiy institut (L'vov Polytechnic Card 3/4 Use. of 016 in the Investigation of the Mechanism of SOY/20-125-6-22/61 the Hydrolysis of the Nitrosubstituted Aryl Sulphonates Institute) Institut fizicheskoy khimii im. L. V. Fisarzhevskogo A,kademii nauk USSR (Institute of Physical Chemistry imen! L. V. Pisarzhevskiy of the Academy of Sciences Ukr SSR) PRESENTEDi January 15, 1959, by M. I. Kabachnik, Academiciari SUBMITTED: January 15, 1959 Card 4/4 . ..... Reactionsof esters of aromatic oulfo acido. Part 2p 4-dinitrophenyl benzenesulfonate with aliphatic khim. 30 no.10:3436-3440 0 161. 1, Llvovskiy politekhnicheakiy institute (Banzeneoulfonic acid) (Aminev) 9: Reactions of amines, Zhur.ob. (MA-.14:4) .d - . . .1 VIZGERTY.R.V. Reactions of eaters of aromatic sulfo acids. Part 10t Reactions of dinitro-substituted aryloulfonates with anIline and other nucleophille reagents. Zhur.ob.khim. 30 no.10:3"0-3444 0 161. (KIRA 14:4) 1. LIvovskiy politekhniAeskiy i~stitut. (Aniline) (Sulfonic acid) ,VIZGERTq R.V.j ~AVCHUK# Ye.K.1 PRIB9 O.A. Reactions of eoters of aromatic sulfonic acids. Part Us All-line and neutral hydrolysis of nitro substituted phenyl benzoyl sulfonates. Zhur, ob. khims,31 no.1t194--198 Ja '61. (KIRA 14:1) 1. Llvovskiy politekhnicheskiy institut. (Sulfouic acid) VIZGERT, R.V. Mzchanism of hydrolysis of aromatic mLlfochlorides. Part 12: - Zhur.ob.khim. 32 no.2:628-633 F 162; (MIU 15:2) 1. L'vovskiy politekhaicheskiy institut. (Sulfonyl chloride) (Hydrolynin) VIZGERT, R.V., SA.VCHUK, Ye.K. Effect of the polarity of the inedium on the hydrolysis of aromatic sulfochlorides. Zhur. ob. khim. 31, no.10:3396-31,02 0 164. (MIRA 17:11) 1. Ltvavskiy politekhnicheskiy institut. Mechanism of hydrolysis of phenyl eaters of substituted Zhur.ob3ehim. benzenesulfonic acid. Part 3.3. 32 no.2:633-637 F 162. (MIRA .15:2) 1. Llvovskiy politakhnichookiy institut. (Benzenexulfonic acid) (Hydrolyoie) PALIM9 V.A.; VIZGERT, R.V. Garre.lation of the rate constantS 4?1 the alkaline hydrolysis Of arOmatic oulfonic,acid esters as dependent on their structure. Doklo AN SSSR 142 no.5:1091-1091. F 162. (MIRA 1512) 1. Tartunkiy gosudarstvennyy universitet, TIvovskiy politakhnicheskiy ihatitut. Predatavleno akademikom V.N.Kond;!atlyevym. .Sulfonic acid) Mdrolysis) 'V!Zr,ER7'j R.V.; SAVCHUY, Ye.K. Effect of the strur-vire and polarity of the rrv:AiL-T. on thri ttA and mechanism of hydrolysis of aromatic sulfoch"Iorld~.i. Do?.I. LPI 4. no. 1/2:29-33 163. (MIRLA 17-6) VIZGERT, R.V.; XONONENKO, S.M.; OZDROVSKAYA, I.M. Kinetics of the reaction of dinitrophonylbenzer e/ ,~Llfonates with nucleophilic reagents. Zhur.org.kbim. 1 no.2s264-270 F 165. (MIRA 1834) 1, Llvovakiy politakhnicheakiy inatitut. VIZGERT, R.V.- MALINEV, A.F.; MIKHLINA, I.M. P Effect of the nature and position of substitutes on the infrared spectra of benzenesulfonyl chlorides and ber4onesulfonates. Izv. All SSSR. Ser. fiz. 27 no.7:969-973 163. (MIRA 16%8) (Bensenesulfonyl chloride--Spectra) (Benzenesulfonic acid--Spectra) VIZGERT, R,V Hydrolysis of 2,,4pdivd-trophanyl enter of mesitylenemilfonic acid in the presence of 42018- U"kr. khim. zhur. 29 no.2: 185-186 163. (MIRA 16W 1. Llvavekiy politekhnicheskiy institut. N66itylenesulfonic acid) (Hydrolysis) VIZGERT, R.V. Mechanism of hydrolysis of aromatic sulfochlorides of alkyl and aryl sutfonates. Usp.khim. 32 no.1:3-39 Ja 163o (MIRA 16:2) 1. Llvovskiy politekhnicheskiy institut. (Sulfonic acids) (Sulfonyl chlorides) (Hydrolysis) VIZGEHT~ R.V.; SAVCHUK, Ye.K. Mechanism of reactions involved in nucleophilic substitution at the sulfur atom in benzeneigulfonyl chloride. Ukr.khim.zhur. 29 no.3-.307-314 063. WIRA 16:4) 1. Llvovskiy politekhaicheskiy institut. (Benzeneoulfonyl chloride) (Substitution (Chemistry))

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