KON,Mirko; J3VRIC,Sava;,V7ATKOTIC,Vida
Sedimentation of the erythrocytes (31) in pulmonary tuberculosis
after a load, %berkulozarBeogr. .11 no.4:538-540 O-D I-SI.
1. Institut za tuberkulozu JIM, nacelulk: san. pukovnik prof. dr
J. Studio.
(TUBIRCULOGIS PUMONARY blood)
(BLOOD SIDIMIMTION)
4AT~Ni(-' V
BOZOVIC, ialsa,'San. pukovnik dr.~~~~ @an* kapetan dr.
w
Came of balooned caverns yoj~ Ban, pregio, Beogr. 14 no.3:
143-146 %r 57.
1. Grudna klinikL VMA.
(TUBIRCUIDSIS,'PULMDRARY, case report
balooned cavern (Ser))
HE
vountry : v-U'.OSLAV'T-A
G a t c_,4 o ry;riaru Aninz7~~Is. Q-5
:L",, 19" 74156
A'.-,.,3. Jour 5
Author VI-a7t_'-CovIph, B. D.
Inatitut.
Title E03el of the Sjenio& Dale and Pestera Plateau
and tl,:~ Oonditio--v; Prevailing in
Apicul"L-11re.
OriS Pub. Acta veterJr.. , 195?.,'r, , No 22 -~-18
Abstract Data are ppeseated on 15ha bloiantry of local
bees (Svrlpla) as rmll a-3 a list of hor-ey
1 aP-t s
Card: 1/1
VLAYAKHIM, L.Ya.; WHROKHOTOV, V-11.
Farther investigations on the topography of mitosis of mouse carcinoma;
structure of mitotic foci, Doklady Akad. nauk SSSR 81 no.6:1143-3.145
21 Doe 51. (CLIG 21:5)
1. Prevented by Academician A.I. Abrikosav 30 October 1951.
2. Institute of Experimantal Biology, AcRdemy of Medical Sciences USSR.
'7
cliev.A (Eafzineer)
A U"NVOR V la,
A~
atpmdardlrsi5~v Bu4garian glider,
'1965, 2
SOU'Rct.- A~iatsiya i kosmonavtilm, no. 3,
tv)PIC no: ormunce , aircraft specification
aircraft perf
jYT*.PA,,-,m -Duriag 1957 the Centroal Con,-mittee of DOSO annotunced a contest for the
aesignin-gr of a single-seater glider of high. perfornimce. Docent L,-ruber. Panov and
i docent Dimit"r Pauchovsl~d wrlDn the c:~ -grtition- fRa&!d on this (lesip, ~--he
~A
Orf, ce peerso~ (Lyuben Panwi, Dlurld""'r PanchwbU. Razil'-.0 A%-mdr~-'y
a final design of the "Fa, eta-standart," on which was bazed
ychev) cam-e up vItn M
tl- neyt version the Kom"-Ila-2. FiLzLIV, ir. 1965 tte last tYPe, the Fameta-3, -waz
ng, 7;-~' n k"t-,riS tj C C :-jrg6PP.!U , I" . jqge
-Cdurzed. It hzu- the follluri
6.65 M,, iring lifting - siurface 12.21, m. ,-Ing load Speed km/h-r'
T
carc I ~
n".1mv, G. 01.
"Stability of Plant Bending in an !-Beam Under CoiVlw. jzads." Gand Tech
Sci, Kiev Construction Engineeriing Inst, 26 ilov %. (PU, 14, 11ov %)
Survey of Scientific and Technical Disoertations Do.,-.ended at US3,q Higher
Educational Institutions (11)
.1
SO: Sw. 11o. 521, 2 Jun 55
WAYKOV, G. G.
Application of the principle of sWerposition (additivit7) in problem
involving the stability of plane deformation. Takh.molod. 22 no.1:436-
441 Ja 154. (NLU 7:1)
1. Kfivolkly inxherno-budivellni7 Inetitut. Predetaviv diyuniy chlen
Akademii neuk Ukrainalkoi R.SR.
(Deformations (Mechanics)
VLAYUK, P.A., akademik
Gontribution of Ukrainian scientists to agricultvre. Nauka i zhyttia
11 no.8:2?-30 Ag 'L. (MIRA 14:12)
1. AN USSR; Vsesoyuznaya akademiya soI'skokhozyaystvennykh nauk imeni
V.I.Lenina; Ukrainskaya akademiya sellskokhozyaystvennykh nauk;
prezident Ukrainsk)y akademii sel'skokhozyaystvennykh nauk.
(Ukraine--Agricultural research)
VLAZHEVICHI I. V., Cand. Veterinary Sciences
Central Scientific Research Lab. for the Search of New Medicinal Substances,
Ministry of Animal Husbandry,(RSFSR).
"About the role of sheep in transmission of malignant catarrhal fever
of cattle." -
SO: Veterinariia '24(2). Feb. 1947 p. 20
25M FHAM I BOOK MaWITATION sov/2454
Sergey Vasil Iyevich Podgornov, Valerly Mikhay-
3VDlazuev Yevg
lovich Chernyshev, and Petr Gavrilovich Shelashov.
NormalizovamV7e Btanochnyye prisposoblenlya; spravocbn1k konstruktora
(Standard ifachi~e Tool Fixtures; Designer's Mmmal) Mosc'ov,, Obarongiz,
1959. 439 P. 12,000 copies printed.
Reviewer: Kh.L. Bolotin, Candidate of Technical ScienceBj Ed.: V.V.
KhzImin, Engineer; Ed, of Pablishing House: I.A. Suvorova; Tech. Ed.:
W,A. Pukhlikova.
PURPOSE: This m-gymal is intended for designers of machine tool fixtures and
engineers and technicians, It may also be useful to ptudelits of machinery-
.construction vuzes and tekbnik=s,
COVERAGE: The manual presents data on the standard structural design of ma-
chifie tool fixtures. Reference material, materials used in manufacturing
fixture componentsi standard types of fixture components, basic elenents of
fixture components, standard fixtures, hydr=lic and air-operated actuating
Card 1/13
~av e~nilv~anovic~h; PODGORNOV, Bergey Vasillyevich; CHERNYSHEV,
Valeriy Mikhaylovich; SHALASHOV, Petr Gavrilovich; GLIKW,
G.S., inzh., retsenzent; BOGOMOLOVA, M.F., red.izd-va;
PUKHLIKOVA, N.A., tekhn. red.
[Standardized machine-tool attachments) Normalizovannye ata-
nochnye pris'posobleniia; spravochnik konstruktora. Izd.2. pa-
rer. i dop. Moskva, Oborongiz, 1963. 504 p. (MIRA 16W
(Machine tools-Attachments)
a;
LITV11, Gr-1gorjy J!",j;*hj IV.
g1tvj gp
tek-h-D. Itauk, 9W. rp,-,,;
red,
[Co.1lection of problems on construction machines) Sbornik
zadach po strf7dtellrWm mashinam. Kharlkovp lzd-v3- Kharl-
kovskogo univ.p 1965. 50 P- (MIRA 18s7)
USSR/Diseases of Farm Anim'als. Diseases Caused by R-1
Viruses and RickettsiaP
Abs Jour : Ref Zhur-Biol., No 1, 1958, 27351
Author : Bogach I., Eednarzh B., Vlaznichka F.
Inst : Not given
Title : Nonbacterial ~'nfectious Diseases which Comp-
L
rise the Complex of the so-called "Grippe" in
ffogs.
Orig Pub : Za sots. s-ih nauku, 1956, A5, No 4, 385-396
Abstract : Piglet diseabes which are clinically manifested
by retarded aevelopment, exhaustion, and infec-
tion of theforgans of respiration and blood cir-
culation were studied. Occasionally there was
an affectio of the nervous system manifested by
atypical epLeptiform attacks. Greatest morbitity
was obsevied in piglets during the weaning period
Cai,d 1/3
_VLAZNXV. Yevgeniy Ivanovich; PODGORHOV, Sergey 'fasillyevich; CHIMSHEY,
Taleriy Mikha7lovich-, SHALASHOT, Petr Gavri1avich-,-'BOLOTIK,_Kh,L..
kand.tekbn.nauk, retsenzent; XMIMIN, V.V., inzh., red.; SUVOROVA,
I.-A., isdat.red.; PUKEELIKOVA, N.A., takhn.red.
[Standardized machine-tool attachments; manzwl for designers]
kormalizovamiye stanochnyo prisposobleniia; spravochnik konstruktora.
Moskva, Gos.izd-vo obor.promVshl., 1959. 439 p. (MM 12:5)
(Machine tools--Attachments) I
MACAT, JoBef, inz.; VLAZNY, Antonin
Technical development In repairing railway rolling stock. Zel dap tech
10 no-2:33-34 162
, , -1 i ~--; :~ ! ~, -~ - ;~:I. 7-.
- -, 'i: - -: . --1.
0 0 0 0 0 0 * 0 0 0 0 0
F a 10 it 11 If 14 If 14 It IS 11 h ~ 11 a 43 At a A If 30 3 111,11.114ZISOMPQ 41 It 6t
AA ACC OP U4-1- 0- -4- t -A
.40
Y
IVID it The camposition find evaluation of enzyme hates. A. VLkvc~. i,',rtwp 53, '-Mr. !I.
C
00 4 T
t
Q Cab 0
zo 0
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'Oo The SaTpwitian ud traluallm of twime betm A. Cmf ktA. 19, W.-S -so
OQW): d. C. A. 24,1246.-A biblkqmpby is includcd. G.,VmDuct)jtv -00
-~*
00 0
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0 0 60040 0 00 0 0 a * 0 o
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0 19 0 4 0 .0 o o 0 4
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c 1 -1. A _1~4 9
24
A Ch- hfjr1a'yy With* thrAy"I"d jvPXT". -00
j0duv-pity
with a 'S 0
'400
A*
t:o 0
-r --ir-i, -9-11 41.M
w epipff OW&C Ora Ica nun 11a wn 141
0 0 0 4e14
A
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go
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POLICISS491 ANO V4001ttlit ~hDfx
1 4 A
doe
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. T. -00
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goo
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owl
0 0 0 0 0 0 0 0 04 000 6 0 16 09 C 0 0 0 6 0
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Y JA OP It; w 15 k
.
0
0 go
goa !.so
-00
Aring of en#WC tannery batec &AVel'. Ttthmjfk,J
JWJ4 lefflaskil 1932, 804r2; C" Obza, 8, Abstratt
i
=Go
he"y and mecha-
seci., 191-2;c(. C. A~ 27,6214..-The
0o IIL%III (if aging of entyrnic launcry Wn are Iltivirn.
~00
KlIhIs
0 zoo
0
00 -a
00
00 4=00
0:::
go
not
Os
0 tie 0
:
0 AS fUltUPOICAL Ulf-alLit (LA$$IFIC&TIFIl boo
04
WOO
loo
JL
U 'W:~13 0 rw 0 -1
04 o o 0 0 0" 0" 0 0 0 *10 9 0 0 09 * 0 * 0 0 0 0 0 a 0 a 0
0 0 * 0 0 & 0 0 0 0 0 0 a 0 0 0 4 0 6 0 0 6 0 0 0 0 0 e # o 0 & 0 0 o 0 o 00
PIE.
0#00000*0000000 0
S 49 'A' .- 14
111. 01111111114 000000 0 so of a s6 t9 ire
*a, 1 3 41 1 41 1 1 0 If of U I) w 111 16 If Is It )I a a A b to so so it It As m 16 AS P 4 0
10
so I to. jo- a A I tL, 1. _j_A_ JAA W-M W I,
--------- le-P
'q4
0* ,,Twwery beta*. U. The C*MbiDAtiOD Of PILACIV400
L, hm substance. A.AWA and J. i'mosilid, Giorher.
39, w-100, C. A. 37, b2ic-The ..91111
ability of wiles Powder to Ps="t14 km sq.
It 11114% flAllki that the Visit nite 4, Ii%WII
-"I Cowin III mossit-Im., us), loclucirvatill issollm vsr.it lifeally
flor"regird by 411.1wing 2,M) ve, to[ 1116, last" Ill It4lid Ill
I with O,Vi, 8.1) K. 44 fm 3A mill. 11 gas
irl".11tcl7nop. 71tiq wss taken Ill indicate that the losAwrt-sitin
was in suaw way butiful toy the hide sidmiatser. Sinsy 200
IlwAl'Ttvasmor ill risiviolis: activity WOVII.V4, 'ZO 0
Inn"'irtilookal to$ Or &"it, ill hidu J.,vost's- sited. it "as s-l"l. Zito 0
.1.1. ed thAt velfalls flw-fim~ of Ilse Imlinvoltill C.4111oilled
fit 0 s, moose: irmottly with the told, mitooswjv. .14,. ."w ijj~tlvssl
*so
appews adtNuals, low dog. the qtrrsigib awl IllitAblilty bm !-I rill 0
vact'k-A use ill vixymc pvt pits. amed as tannery thates.
411110
*0
A:-:1
-!T
14.11. A ONTALLURGOCAL LITM 1`110C CLA *4 Mod
is
die to;
#AD,,
To
0.0. t I tow
4 of i, sit 4 1 11 rw 0 it ill- -0i 91-
aU It AV $a it
is A, As to It x ,a
so woo 0,4
6
0*71 *0 0 0 0 a 4, its 0 0 0 0 0 0 0
46 0 A 41. Pi I a a a 9
_
_
0 0 0 0 00 0 00 0 oil 81 a
ho'
I I I ~; .~ I '. " , it v 11 1 M n R TF7fN
'fj 1. 1 ft If Is I
1;
4. o-I*
.
A 111 91 k 6 Itj L L A fit r 4 1 1 v C 14 AA M LL IX1 It I
so
00
00
00
Potato 1,111,11.,it .4 Ow 1,11 ..10 41'. -IitAfI14I *,.I
Itaphle studies in leather chentlittly. lVisto
'
-00
I.11 I It!.), IN-bilf I-. 1111I.11Y.111,
u bracho, cirtratts. A. X, Vkvi,, - 0.01Q
"
.""Y"Os 11 1101
1itmar KirkoMi-vit. 1*#Wb.L IflUka rise convii. 44 pyrotraltiv Avid mul IIIAY 1W U~Il Girr IjuAnI .
00
%I Id
an
.
.
,
XA,1mt,k.l 19, Ill-Ut(1043). It. Polarograms of Although it-lo- FOilbut" Halt.
to
I
& Aqueous solutions of pyrocatirchol. Ibid. W-41-N-V and .11-Irl'A 41 Imill file "if. i(~ did ota -11". Wf y
00
Ill. Polistrogrammol FrAilk MAI-1-
aqueous sWuU*ns of I
zoo
000 attle acid and phloroglucinol, A. K. Vl&k anti I,.
1
W A
-Dilute (IMM4-0.01
f) and
0 - Ibid. IIIII-
0 0
tPuffeml U)III.- of pyrogallic arid Yielded An AnOdiC OXM4-
11, w4vr VVIIIA runs go4ralirl if) the firti stageo) 031darlon
00
of pyrogalfir schl. The half-wave potentUl was a lisicar
"I
age 0
zoo
00
It' 'to 0
k it -.i 5-7- A
U N At 20 A 4 S a
tp Is It 12 it 01 it IN it PC U n It Iwo 4 411111,1149104
1,
~
0
16411 too 0 0 04 0 0 is 40 a 0 0 0 0 0 0 7.009
4*4 0-00-0 0 0 0 0 0 too 0 *s
et
PolarographIc deterfmination of trues of iodide In common
K-WhArles MAY- Prague). Callrdion
"ft. A.. A,,Al&
Cmiloslop. 'Chet". LOM"Uns. 15. KXI-F4 1950)(in HnI1611);
Owsm. Lissy 44, 7-,(IVN0.-TrAm4 of I - in NACI are deld.
by oxitlizing the V to Kh- with fir In dif. IjsW,. i4difinig
eavw INA01f. and recording the polarogriult of the buln.
The drop time must be at least 4 we. to clitnillate file
"water wave" (Orhmusus and Kollhoff, C-4. 36, 31051;
Hass% anal Yon Stackelberg, C.A. 44, 6=1); if it is not,
0.01-00270 gelatin nuy be achicti. The analysis is m;uie by
a Kandard eAdn. technique by using file smallest possible
atut. of addett "it to avoid significant changes in the char-
actTrof the 144 nx)rting tlectrulyte. Resultsare2-H% lower
this is a"Ilrd to file
effor in the latter conied by true" of rnidual Hr. which does
nof interfere In the polarographic mr-tsurrments. I-M.
C/f
Ida In Com-
ktm, LWy
all iscidic
,oln. to iodate. which h detd. pularographicAlly in w~tkly
idk. suln, In coned. (IN)%) sotas. of NACI, all allornalon.,
wave (water wave) occurs, which interfries. it can bc
%=1byusinga lowflowratent JIC(l - 4.6~c , m -
1 ave.). or by adding a drolA 1) 51"a ~0111. of KVI'llill
in a I(Mul. sample. Muolve 10 X. of cinumon ~Jt in 441
"ll. JxjjjjjjX watef, Add 1-2 nil. 0A V llh';A), to Aightlyarid
.tiou, and 3 drljIA fir. Remove rikvm fir ljy buffifig,
.%filitt ulk. with I inf. 1.6 X N.I()If, filter, aild make ull
113 .10 HIL POW01faph it ilkfll. kullille affer IC111111-111C
0 by a sirruin of N. Add OAJ 4 mL MIA,% &if, Kit),
and reg6ter the htandird curvv. About OA -.7 ing. K I Jkx.
Is'aCl can this% bc- &W. M. lludlicki.
C=H/2433
24(2,4) PHASS I BOOK Expr4rTATION -4
international PolarorraPhic Congress. let, Prague, 1951
Sborn& Z. Mezinaloddho polarografick4ho 814=du. D11 3: Hlavni
referaty prednesene na aje.-du. Ppocee4ingS ... Vol 3z Rovlawa
Read at the Congress. Praha. PrIrodov.decke vyd-vj7 11952)
T74 P. 2,000 copies printed.
Rasp. zd,t jir'~ xoryta, Doctor; Chief Fd~ of PubllstLlng Housal
Milan skalinf1k.Doctor, Tech. Ed.s Old ich Dunk-m.
PURPOSEs The book in Intended for Chemists, chemical enginatrs.
and physicists.
COVERAGE% The book is a collection or reviews and artgInal papers
read at the International Polarographl- Congress held In Prague
In 1951. Uses of polarography In orgazile and Inorganic analyals,
biachomistryv medicina# and Anduatrial chemistry are discussed.
In "t sd tion. Reviews Read at %-he Congress, Russian and
either Carman or English translations of each rev~-em &re
presented. In the section, Original Papers Read at the Congraz3,
only thoa& translations in Russian, German, and 2-iglish which
ve not been Published in Volume I are presented. Thec=~-,
following scientists paLrticipftted 1, the Opening of the
Congress& Professor Wiltor Kemula, Dean or the -Faculty
of Sciences. Wareaw. Doctor Jarcmir DolaLnsky. r.4niater
of Planning; Professor Jar0slav Herovaiqr. Chal-mein of
the Congress; and Professor Jarosla, Fukatka, Ch&lrtnan
or the Center for Scientific Research and Technical
valopment. RarerenaeB follow each Paper.
Vr-J--Apparstus for osaill4grsphle Pole-
RUNDlAn Transiatlon3 og"Ptly 241
0*ru&n Translation) 250
1
e 259
-Say-to"Y2, J. Oncillogr Phic Pojsrtgr,,-:a
Puss -A-"'T-Anslation
273
LE"911sh Translation
219
Drdlcka R
'UnOt'cs Of Electrode Processes in Polar,
286
Card 3/14
POILrographic Study or Basic Trlv<nz
Chromium Salt Systems
J 395
Krivanak, M.
IComplexes or Iron with SlecZarnse 399
DrAtovsky, M, and 4
-JC~*Ft. Effect Or GtIatitj and jhymol
--OW-C&-t?=rF'DePO5itiOn of Cations at a D-OPP!pg mercury
Electrode
Russian Tranalationj 404
[Gam&') TranslatIon 407
Kuta 410
JStudy or Kydrogen Overvolt'91 "Ith A Mercury
-"ec~z~~e With Controlled Dropping Time 413
.1 ,
-.Dvorak,..J--- Effect of Capillary Constants 0. the Xazim.
ar-bi7gen
Russian Translation] 418
I arm& Tram. .1,,] 421
0"is.
Vavruch, 1. Attempt to Classify Reflnj Sugars by the 423
.7P0I1r6gr&Ph1c Method
ftuoelan Translation) 427
fOOM&ITransiat--cmj 2B6
OR!alXkL PAPERS READ AT THE CONOR.ZS 33Z
--falOuacy- X., and A-Ta.Ckatcjn. V,,,,.
Equation 1" the Deduction Of the or the N . . . t
Vi rographic W... F,,a_ 359
A.A. POlarography in COhOentrated 3ulfkuric Acid 366
T"79*rmn Tran:Utlonj
MnSllsh Tram 2atjmj 370
-Valenta, p. study or Current Discontinuity Appearing on 373
a.Calom.1 Be" Electrode
na'?"N ~-. Discontinuity_ on Curves Obs-,~ 377
.VULK, A. A.
Lzech L-A: 47:11030
Central Polarographic ~nz-t., Prague, Czech.
'lPolarography in concentrated sulSuric acid.?'
Sbornik Mezina"rod. Polarog. Sj'ezdu Praze, Ist Congr. 19551, Pt. ill, Vr-oc-, 366-9
(in Czech), 370-3 (in Russivil), 373-6 (in Engiish).
1,11 0,P M
VIM- - Antonin A*
ated sulfcic aciit. 11. Ca-
PolarogTaphy in coticentri
in r,111rd.
52.5 it farad.; cm.
- . : .. 7
hl half-wiYOPOtOntiats Z:
ureinent; ali.
9 ft f --h'itlott.
V1, colleffi,
CA - 48,1328-
-NEW
ovid equation for Tiql3rogr-A
~^11VT114 validity a 116
YE". Yrag")- - . .1 1 ~ rts-
pmed that ffiese o7nd4iow were fulfilled: (1) P,--rf-ct
mobility equff., (3) a w1n. completely free of surface-active
"Substances, (3) sufficient exccsq of the Indifferent clectrulyte,
(4) moderate conen. of the depalarizer, (5) a application
of the max.-frei system, and (6) ust: of a capil 4r
q of diam,
O-N--Q,OSMM. ons
~tn,ilkoirWs c4u~.tiott could be caused by 3 l4ctors, (1)
tkjl6lo current ijjj;s during the Hg drop time; [12) neglect
b( OM curvature of the OeOrode surface, And (3) itstalicient
exclusion of the turbulent currents. At small ilmpping
sed by the chanke of the
specils, die deviations wtst caw
dropping speed during the lig drop time and by atransler.
t
of the Cotten. polarit-ation train oac drop otheother. Thit
transfer bepa at the s" of the drop formation. At high
dropping speeds the disturbing factor was due to the turbu-
fent ciorrents. The development of the -current Was Inde-
pendent of the drop time In the presence of the gelatin, A
the deviations were grta;~ because tile con -T I
transfer *as more intensive. Gelatin was d&.1 _-- w
sutface4edve substances were pnmazt, Aft the dey
Vrere much higher tha6n ammed If sphak diffuslad *xV
for the change of droppitir
for I > 0.1 V.We In aaefrrrent
the llkovi~ equation.
VLC-CK, ANTON11VA.
-'ii~i~;Oaravhlc half wive Rotentlab. 1, MethodofmL'25--
F--.. .. -afflum. Antonin A.
PolarogrAfieW listay ~SA' -
vl&-k Tj -V., Pra le Ire
--Tmr?r 48,1W-WJ(1Q5.11 Bymemns t C ectr e
ting the half-,
system litlacompensa Prave potentials
.1 the 71+ ion in 4 media were detd, with anaccuracyof +1
mv.: In OJAf KCI -494,0 mv., in OAM NaNOz -493.0
.so, -wj.G mv., auff in 0.1 Af N114CI.
jjjv_ ill O.IAf Na-
NI(joll -501.0 mv, against a noTmal IfgCls electrode at
F. Redft
%and
h
V70"
the JQ113 (Cf,
G are ba-A d oil
d
n5
bY
gid
Ti,
C
haff-wagg -rflt~
'6~ jujj~!J~' 11. Effect of the
supporting e!ecrrolyte' tild cxlri~64c"*ed hAt-wave potential.
and the normal oxidatton-m-ductirn po1cnIIal,_,&U.QiWj
BD -Tile dq,,cod-
clice of tile i~ -df-wav,~ pkitentials EI., cW the 7*11 and III) I I
iani or Cie concTi. all(] ji-ature of the support ek0rolyte
W32i df'!d. At IC)--V COTlen3. Of tile .11111POrt efCCtfOl"tC tile
depc-a'le-ov, of Et'.E - %/ji (g. vvas the tonic strength) was
lim:ar .11111 could be emtr"potut!Ld to p - 0. A 1wrillal
llAenflal miler curent-flow Ec(l) was
tll'~Fmcd' arid tile
tile kill"i-I of tile elldfoje pruc%!5-1. From tile b"A'O.-v
valuu of the frce and tomplex. fulls, the therillc. Yllarnic
congts. of Complexity couid tie (Icid. Tim VKlueg.
(api!lit a norm-I catolud 6xtry,dii) were: TI+ - 4M
013 r-,I-+?., - it e
mv., freu, Ilb'0 -4, and plumb, t ions -810
mv. V'rom theic vqttif-.4 for tile plumbate. PIC, - IM15.
Thi, rv)rmal potential of Pij In plumt-atc noln. vm3 calcd.
ft-c-in vaIu,-,,) P-3 -53' niv -1. t Tionnal It elcc-
Ill" Albit . W, d
AD valocs Is:,It, 'l~ 2", e
their f t" Vie polarographic sird
I i c I ) Q 11 ; k v i - Tr f l lit, L~' ; ~jj.~2 PML117-4111,
WAS 'I'll,% s~:tvri :X:. indal-ativilgant gave a ie-.
w-ave and was o:~cillographicdly
revez-Abb-7. , Thr rt:vuiiIAIiIy of Nil,' ion
was provtd. Tilt: ImIf v.~iv~t pottoth-di of alk. metab in
1, 1,
0.1.1f (elli '5 Rgaiiit a normal Ific.cit
TA f - "'P" V. N' k V'; K +
j'~I' ~ - 12.16~1 v.; 6i --l"o, V, The "'xtrap-
otau-cl pot,utial, sv,,ru identlell with tile
rLarrunt o~idatlovi-rkadmtioii putvntiat; under current flow
within th-.! Limits of exvtl. error. Erd63
~V*"'
VLCEK, A.
Polaroggraphic half-wave potentials. IV. Proce6ure for comparing half-wave
potentials in different solvents. p. 1863
Vol. 48, no. 12, Dec. 1954
C-FEMICKF LISTY
Praha, Czechoslovakia
So: Eastern European Accession Vol. 5, No. 4, 1956
n between th6 electronic structure an
jrapblc beb~~ -of inargault, d . 11, as ~C
=av CSAV
49, 10092f.
9-Em
C;21 ,
t7 -%zmr
-my
Colkaia q C~,r ka ilm. Ckem. Cc aa q 1. i P" " ~A
(Imnan).-Sce C.A. N. IW-k.
11plaroqaIlIlh: behavior OQl;dxA_;=,tA slonarlucou" Sol:
V~nts~ IL - 90fittlans tif strong acith I%_afjaML
~kirVi,'.k (PoLivigraftM 6A:,v I~SAV. Pfuguc)~ --OVOT'.-
With int-reahig
011101.0iBROJI, (lit
toward miire poi, values. The total change represented
0-'17 V. ;* showo Z,.!l the poLaTographic curves of tile SYA01l*
MOIL + 1110 + fICI(IIC1O,) and In pre-ience of MLjNCl
or UCI. Thh value was c4led. from tha "K potential
-scale." tile values of-which were indelleudent of.the couca.
arptsi of EtOHvgrlcd fit the same inatinpr;u
of 1P ILI these gains. Flora the Chan" or the half-Walve
tncutw and from the uormal potential of 11 electrode ia
r
-to, +0, 1 Y,. was detd. r.3 tile 11 overvoltage in EtOH.
Comparison of known values In various soNimts showed the
Ii overvoltage to be ielated to the promplucis with which
Im haimi- of "tmaujum An 6OW Ong a
A. A. VI&k (Poh Z=10 ~ftAv -ESAV.
Prague).-T "___Z;WyZV0, 2tMI955).-A soln. of Tal0t in
lip, po~r(rphcd in a suppartbig electrolyte that is satil
with F mntg. 157 X 10-2.41 lip at least, give-,, a weli
developed wave of a height directly proportion3l to the
conen. of Ta. The half-wave votmtkil Is -0.95 v.
MORN
X,tl~5. Tila akorption WTUam of the AEX14- ~.Ill.
Siva EsYmmetric Pbaarptiun zone ha-'
v-mg Lhe a
3.- V I t
Trar.7 ank; p.
jft_
-WKK,_A.A.
"Advances in inorganic chemistri! nd radiochemistry4l edited by
H.J.Emeleus., A.G.Sharpe. Vol. 3. Reviewed by A.A.Vlcek.
Chem listy 57 no. 5:547-548 My 163.
"Progress in inorganic chemistry" edited by F.A.Gotton. Vol. 3.
Reviewed by A.A.Vlcek. Ibid.:548-549
ir
.4, ~ fa~, .- -.-, . "-- -. - 4 ~ - -~ -. - -, - - - - . - . - . -: . - , .-. --I-- . -1 ~, . , . z ; -- - -.- ---
- - - -1. . . , - .- . I ". --: ~'.. i:L,.-. - ": 7,~- i6 '. "
i.' . Z~ 4~ -,
: . - lr,~~ i ~ Z- - :.. .: .. , . . . :1- ~ , ~,;
i 1, - . -,%~ - ---k -1
- . I . I - ~~ , -~-, !;~ 4", ~
VLCa, A.
"Effect of basic electrolytes on the polarographic behavior of nickel ions; a preliminary
cormunication." p. 828
Institute of Applied Physics. , (Czcchsolovt,~~ Acade-,.;y oC Scienc(-;S.) Vol. f'C, ro. 5,
1~v 19 56.
FPf S1-
SO: Monthly Index of,,,European Accession (EEAI) LC, Vol. 7, Noll 5 May 1958
VW EK p A.
VLCEK, A. Tables of half-wave ootentials of inorganic depoarizers. po 400.
Vol- 50, no- 3. Mar. 1956. CHEVICKE LIWf. Praha, Czechoslovakia.
SOURCE: East European Accessions "ist (EE.AL) Vol~ 6., i~o- 4--April 1957
Fo ation and reduction of Zero-valent co ex q
studir"'
cdaI#'_,gravIfWcaIIj-M~. Efft-T,
Prague)
--7 r-7-Uansition metals are polarograpbic-Aly reduced to u
zero-valent complex (1). r ruay be stable, may, decompose_
to the inctal, or may he reoxidittd to another complex.
Far example, Ni(CN-),-- in O.Ut NaCN` b reduml to
Ni(CN)j ---- ; this with lrjO yicJds 14 and
1 which is irreversibly oxidized at the anode. Complexes of
Ni(II) Nvith bipyridyl, (NIT-CITI)2, pyridine, Nil,, and Cl-
in5MCaCl;showed the same behavior. Fe(CO),inUAI
Ms),NCI in abs. EtOll is reduced'at - 1.7 v. vs. tile
IgCt electrode to P4CO)4--, which is oxidized in 2 succes-
"sive steps to prcduct% otber than- Fe(CO), and Fe&(Cohl.
Obwrvationswese made by oscillographic polarogtaphy and,
a Kalousek commutator. K. G. Ston"
ki I-C L I-T- P - //-I - - - - -
CZEI-HOSLOVA-E:EA/R-y~-.~l..-:rj. Onpiq~st-ry Fle-troahemis try.
Abs jr,-u7 Rof Zh,.i-- No 5, 1958, 13913
Author A.,~'
Inst
Title betwe~;c(-. the El-,%ctronic Structur~: of Imorgqmic
Den A.
.Lolaxizers am-d "Meir Pc-lF-::-ograph-'c Behavior. IZ
C,;~P-hides of
Orig -Pub St. khl.m. rabot-, 1957, 22, No 3, 948-960
Abstrafitt Sz:,-5 RZO-111im. 1957., U0780.
Card 1/1
VLCEK' A.; IMOVSK-f, J.
.2=W--
Significance of ti,-~- Il~ovic equation in electrochemistry. p. 3. (Matematicko-
FyzikaIny Casopia-, Vol. 7, No. 1, 1957, Bratislava, Czechoslovakia)
SO: Monthly List of East European Accessions (EEAL) LC, Vol. 6, No. 8. Aug 1957. Uncl.
CZECHOSLOVAKIA/Physical Chenistry. Electrochez:Listry. D-12
Abs Jour: Ref Zhur-Khim., No 13, 1958, 42705.
Author Vlcek A. A.
Inst
Title Rela ~en the Electronic Structure and Polaro-
graphic Behavior of Inorganic Depolarizers. III.
Electrode Processes Involving Unstable Intermediates.
Orig Pub: Sb, chekhool. khim. rabot, 1957, 22, No 6, 1736-1746.
Abstract: See RZhKhim, 1957, 44188.
Card : 1/1
~ ) It.
A symposiur on rare elements.
P. 2ci5 (Chemie, Vol. .0, no. 2, Apr. 1957, Frahj, Czechoslovakia)
Monthly Index of &ast European Accessions (':!-'IT) 1C. Vol. 7, rc. 2,
Februai-y 1~ 1178
VICEK., A.
InorFanic oxidation and redi.,ction excharij:e
P. 305 (Chemie, Vol. 'is no. 3, June 1957, 1'r-rihn, Czechoslovakin)
I-Ilonthly Index of F--.st Luroz:ean Accessions (EEAl) I,C.' VOI - 7.9 no, 2.
February 1958
VLCEK, A.
I
"Relation between the electron structure of inorganic depolarizers and
their polarographic behavior. II. Complex nickel cyanides. In English."
N 948 (Collection of Czechoslovak Chemical Communications. Sbornik
Chekhoslovatskikh Khimicheskikh Rabot.) Vol. 22, no. 3, June 1957.
Prague, Czechoslovakia
SO: Monthly Index of East Furopean Accessions (EFAI) LC. Vol. 7, no. 4,
April 1958
Distr: 4E2c(j),
-
A
I/NlaroMRJiy of the cobalt-blPYTIdIne C n I
h* I
:
l
P
i~f
o
t
Vl6
aroy
-5 M'-"'1CFfZ: -51
-The
143~
olaro
so ~ 1958
.
g~
,
p
-31`1
defined com
lex
h
well
Co(di
0
a
;i th
MC10
)
,
r
4
j
3
,
e
,
py
p
y
p
I
disclased 3 waves. whose behavior in OAM NaNOI is dc-
scribed in detai), The first wave, Ft/, - +0,09 Y. vs. satd.
calomel electrode (S.C.R.) and coacn. independent, had a
limiting current which showed 2 small adsorption waves at
'.-O,B5and-lMv.vs.S.C,E..rcsp. Itconespondstothe
reduction of the Co(dlpy).'~ t+ ton. to bivalent Co, and Nvas
not completely reversible. The second wavc..Eij,
S.CB. jar 10- Co'md shifting to more, pos. potea.
!Y~
Co' u, had a dl~tbsulty at i
Alals withfiiocr
T
e-
mt- d Id
oce - Martu 3
= Wh
A&.it i.4
=
r
a r2
'
cr st VMVC,
=std, with respect to that of the fit
of 1.6 at 2 X 10~ljf~ Co to. 1.0 u;10-*.kf Co. Thif vrave
"CorrespoiAs to the reversible reduction of the bivalmst Co
Ao tmlvDJMt CO.' The
formed In the first third'Waye.
--L34 v. v"Tcxi I., lo-W. Co and shifting to.,
-*ith iocrca~g Co conca., appzared:
per. patebtiah
o Y a-V
nt the higher cm=s.! It ProWbIY Cafresp( 9 to the f
further reduction of piut'of the WnItat Co'-aad in dicates 1
'
'
ar of thd latter is 110t k~
lhat conapte
tile coff ndin
iptivated on =rUjo wrfa4e~. The'pro"e micitantsm
pf,the- electrode Procip is t4borated and, colained in Wras
Zbwuerm=,-
ligand R. Y-
themy
K_
V
Map 6-0
Distri 4E,2c
Relation between the electronic structure of Iflorgansc;
depolarizers and their polarographle behavior. V. CobalL
k A NNek (Polarograf. 6stav C.A. akad.
Prusim). 1460--7(IOUS); et, C.A. 52,
_134&1a.-Cc-(CO~ (1) :11ve3 a reduction %mve at -0.35 V.*
-Vs. sattl. calomt:l Clectrodc Cc(C%- which N
the reduction product of I gives an anodic wave of the carre-
Isponding 119-coulplex.st.the same potential and an oxid3-
tion wave at +0,12 v. mt. S.C.E. The waveof I is Identical*
with the reduction wave of Hg(Co(CONJI. From the po-
flarographic behavior the cariclusions aboot the electrosic
.
"structure of the studi
s
b
ta
d
d
e
su
s
were ma
e
n~
c
Uj- i~ ", C
e r i o cd c, 11 C': CK'Z~ Li 1 .
Vi (" I-- Rclati3n be-tween
polaro,--rapAc bc.`.avLo; . 1`1
V ol - 5 2, n o2, !~c 5
:Lf.e electnin oi
-lectroc:u pi-oce: 3e-L: -:;, whicil: (n-2)f olectrol.-L take part.
List of East 11j'Urircaii Aeceszdons (----d ) LC-, Vol. -no. 3, "arch, 1~5~, - Uncl .
A- fi
bill'
0
om '01""
0 "C4 er a
e cad
t
d - ~2
c.. i.. P-T ion 0,
and 1~',h
6e,ed
Cfl . w
f of som
yp* W
17-
v..- - th di in th
and. emi
in 't,e = ~b- Plot - at.
S miiar.~, 0 .V
straig t line. Similarly, the vati
s1ra'
e
e
was
W" 4
was
of the Utl.. of these complexes Duo owed '=Wfy
th
plot. On the bub,31 this observation a model of the clec-*
trode process was developed. In the course of 01C elec-
trode process a change in the electronic configuation of the
complex takes place which is proportional to the tetragonal
ling cause
split. A by the ligand X. The ligand X Influences
idao the ligand to the trans position to itself. this babig more
influenced by the,ttectrode field. S. R*
CZECHOSLOVAKD~ / Physical Chemistry. Electrochemistry. B-12
Abs Jour: Ref Zhur-Khimiya, No 23, 1958, 76832.
Author V
Inst ot given.
Title The Relationship Between Electronic Structure
and Polarographic Behavior of Inorganic Do-
polarizers. IV. Eloctrodo Procossos Involv-
ing the Participation of (n-2) f-Electrons.
Orig Pub: Chem Listy, 52, No 2, 214-227 (1958) (in Czech).
Abstract: As a rule, the oxidation of Eu2~ions proceeds
at Mo:r'q.positive E values than the reduction
of Eu~rions, i.e., the reaction is irrevers-
ible. The difference between the half-wave
potentials of tho cathodic and the anodic
waves as well as tho form of the waves depends
on the background. Halides produce a shift in El/2
Card 1/4
CZECHOSLOVAKIA / Physical Chemistry. Electrochumistry. B-12
Abs Tour: Ref Zhur-Khimiyay No 23, 1958, 76832.
Abstract: and also affect the slope of the waves. At
high halide concentrations (e.g., 7M 5i2c cl-
or 0.05M I ) the difference between the E 1/2
of the anodic and of the cathodic wave is so
small that a single anodic-cathodic wave is
obtained, the slope of which however differs
from that required by the theory. A single
reversible wave is obtained only in the case of
ethylenediaminetatraacetic acid solutions. The
current in the lower portion of the anodic and
of the cathodic wave is of kinetic character
fd-iffusion curreng at constant.E. As the time
between drops increases the half-wave potential
of the cathodic wave is shifted in the positive
direction while that of the anodic wave is shift-
ed to more negative values. The slope of the
cathodic wave decreases with decreasing time
Card 2/4i
57
CZECHOSLOVAKIA / Physical Chemistry. Electrochemistry. B-12
Abs Tour: Ref Zhur-Khimiya, No 23, 1956, 76832.
Abstract: electrode and the central ion. The presence
of excited EU2~ ions at the electrode is as-
sLuned.
Card 4/4
58
VIZEK, A.
"Progress in the chemistry of complex compounds." P. 376.
CHEMICKE LISTY. Praha, Czechoslovakia., Vol. 53,, no, 4,t Apr. 1959,
Yonthly List of East European Accessions (EEAI),, LC., Vol. 8p No. 8j, August, 195~.
Uncl.
VLCEK ; KIJBAL, J.
"Present problem of photographic chemistry." P. 365,
CHEMCKE LISTY. Praha, Czechoslovakia, Vol. 53j.no, 4., Apr, 1959,
Monthly List of East European Accessions (ERAI), LC, Vol. 8, No. 8, August, 195 9.
Uncl.
COO'. 4-TR Y, C zec Kilo slovakd a
CAL,,GORY
AB3. JOUR, RZIUlila-, NO- 21 1959, No. 74373
it U T.1 0 A Vlcak A,
F,7:3) T Not given
T i r2.1:1 Relationship Bet-R-een Electronic Structure and
Polarographic behavior of Inorganic Depolarizers.
IV. Electrode ProcaLsoaa Involvingr (n-2) f-Elect
ORIG PUB Collection Czechoslov Chem Commun, 24, No 1,
181-197 (1959)
ABSMACT See RZhKhim, 1958, No 25, 76832.
CARD: 1/1 trons
59
vu,-!~x, A.
"Relation between electronic structure and the rolarographic beiiavior of incr-
ganic depolarizers" IV. Electrode -processed, in which (n-21)f-electrons
take part. In German. P. 181.
CCLLECTICN C*F CZEChCSW,,'j1J, C110JGAL CG1H~,fbV!IQTIC1'S, Praha, Czech. ,
Vol. 24, 111o. 1, Jan. 1959.
Monthly List of East European Accessions (EEAI), LC, Vol. 8, No. 6, Sept. 59,
Unclassified
Reseflon kinetics of the decomposition of
in ethanol solutions. AmOa4. VIM& (Tsc
41"0' -1
chen Akad. Wiss., Praffwef,-Jrn";R- 4-.-Rgem-
7~~94, 7 1959).-The polarographically . detd. over-all
rate of decompa. of Coj(CO~ at 22 in EtOff soins. can
tir
16,
'2-67c CoHe b given, by the tctuition: riLte - Mki[Xil
7~
-.gCote(:6~1. Aere,X, Wan Idn or ruoL (Cl-~ J~H..
iHXH3',CN ctbioyridyl)foriningacomplex,withCo*+"
ki Is the corresponding rate coast. In 46 absence 01
ocanplex-forming species the rate comstAs 0.3 X 10~1 we-*;
From the stoichfametry and kinetics a *reaction mechan
r6'i
is proposed, the Ist arid rate-dctg. step of hi
WW
w
at action of co~(Coh with the complexil es, to
give co~co~x' which then cli3rM mates t CO),-
and ~"O'(CUX. - -: , .:. 1: [chard M I a
A
-'D
istrs-. 4Pc(i)
..........
/7'
V Substitution riactions of cobaltic cam
Kuta- a
(C-sRb
adsorption
Am
qod J
A
.
.
.
"r2 -9 N161-P
~6-A(IOWT---Tfic tate of redo
IT ~
I
.
..
-AXI ions at a dropping Hg electrode varies with the
[CarNH
In the order SO,-'rC CIO,- <
on ortintleltctrBol~~
< - < as shown by shift of the half-wave
=tIal. At some min. halide coacn. CI-. Br-, and some-
I- cause a new redn. wave to occur with a relative
b ht Increasing with hafide conca. Ills Is attributed to a
11
rMA :
,adsorption catalyzed reaction at the HS sudke to
l+*
form a halide com
l
B
i b
f
1l
P(NH
)
ex, u
o
owix
r
#
&
,
p
y
'Me relative hei
redo
ht of this wave
ives the reaction
.
g
g
.rate const.: Br- replaces X substituents In the order
NOa- < N14 Lq F- < ozalate tm ONO- < OAc- < H&O <
NO
R
M
wl~
~m
.
c
.
&
CATEGCRY
ABS, JOMs
ITT "llop
M10, PUBj,
ABSIVACT
-ia
t,o 6lov ak
Tized4up floe 5 1960,p No.
VIcok, A. A.
110u ~ivllr.
h e r(ClatLonship Between the Kipctronic 9truc[.u-.,-*
Pol - I
a n dt'L-Ic- I- c Behavior of Inoreani (; De-
polarizers. V. Cobalt Carbonyl.
j Collection Czechoslov Chem commun, 24, No 6, 1748-
1756 (195-59)
t See RZhKhi-M, 1959, No 18, 63845.
UPI: 1/1
VLCEK' A.
Relation between electronic structure and polarographic behavior
of inorganic depolarizers. VII. Determination of activation energ7
of electrode processes. In English. Coll.Cz.Chem. 24 no.11:3538-
3$47 N '59. (EMAI 9:5)
1. Polarographic Institut, Czechoslovak Academy of Science, Pzague.
(Polarograph and polarography-) (Electrons) (Inorganic compounds)
(Electrodes) (Depolarizers)
BERAN, P.; VLGEK, A.A.
P~larographic control of substitution reactions of Inorganic complexes,
I. Reaction of AUC14 tone with ethylenediamine. In German. Goll.Cz.Ghem.
24 'no.1l.-3572-3578 N '59. OMAI 9--5)
1. Inatitut flu~r analytische Chemie, Karlsuniversitat und Polarogrphi-
sches Institut, Tschechoslowakische Akademie der Wiseenschaften, Prag.
(Polarograph and polarography) (inorganic compounds) (Ions)
(Ithylenediamine) (Gold chlorides)
VLCZK, Antonin A. - - - --- - - - - - -- -
"Polarography as an Indirect Method of Investi-ation of the StructAire of Coordination
Compounds," Prague, Chemicke Listy) No. 12, Ded 60, p. 1237.
Affiliation: Polarographic Institute, CSAVI Prague.
66907
Do 64)
6 j 0 CZECH/8-59-12-2/15
AUTHOR: Anton:(n A. Vlvcek
TITLE: Rea i Mechanism of Substitution Reactions of
Inorganic Complexes-1
PERIODICAL:Chemicke" listy, 1959, Nr 12, pp 1139-1247
ABSTRACT: This article was given as a lecture on July 2, 1959
at a conference on inorganic chemistry at Bratislava.
The chemistry of solutions of inorganic substances is
basically the chemistry of coordination. The question
of stability and composition of various complexes in
solution has, in the past, been paid considerable attentions/
with the result that present knowledge in this field is,
on the whole, satisfactory. Somewhat later and in less
detail, the studies of mechanism of reaction of complexes
in solution were commenced; they have practical as well
as theoretical significance. The instantaneous reactions,
involving inorganic complexes in solution, have been
reviewed in the previous paper (Ref 1). The reviewer,
here deals with relatively slow reactions. Kinetic
parameter values are very often missing, eg temperature
Card 1/5 dependence data. Recent collections of data suggest a
66907
CZECII/8-59-12-2/15
Reactivity and Mechanism of Substitution Reactions of Inorganic
Complexes
parallelism between substitutions In organic reactions
and in inorganic complex compounds. The Ingold
classical concepts of organic substitutions (Ref 2 and
Eq 1). Nucleophilic reactions may proceed by two
mechanisms -SN1 and SN2- In the course of an SN1 type
mechanism an activated complex is formed without the
participation of a ligand substitution, eg with a
reduction of coordination number whilst characteristically
an SN2-mechanism directly involves ligand substitution in
the activated complex formation. In the latter case, the
formation of an M-Y bond weakens the M-X bond. It is
difficult to decide whether an SN' Or SN2 mechanism
is involved. This is then considered further. Fig 1
illustrates the course of substitution via mechanisms
SN1 and SN2. Taube (Ref 3) , using expanded Pauling
models, differentiated between labile and inert complexes
according to d orbit occupation. Table I gives the
electronic configurations of labile and inert complexes
after Ref 3. SNI and SN2-mechanisms are then considered
Card 2/5 in the light of this and Taube's work is considered to be
66907
CZECH/8-59-12-2/15
Reactivity and Mechanism of Substitution Reactions of Inorganic
Complexes
of qualitative value only. The basic shortcoming of
Taubels scheme is then dealt with. Table II gives the
velocity of hydration_for complexes of the configuration
d2d2d2D2sP3; kH20 (S 1) at pH 1; 250C (after Ref 3).
More fundamental explanations of the relationship between
velocity and structure has been advanced on the basis of
Basolo and Pearson's (Ref 4) theory of crystal poles.
Theoretical calculations of simplified examples have
been produced and Table III gives the change of
stabilization energy (in Dq units) for reactions of
complexes of the transitional metals under conditions of
the so-called strong crystal pole (after Basolo and
Pearson (Ref 4) ). Activation energy of the processi
Ea - (a-b).Dq. But even this theory does not suffice
since it only allows a more detailed estimate to be made
along the lines of Ref 3. The author advances the
hypothesis, taking into consideration the connection
between structure of the complex and its reactivityg that
the activation energy of the reaction will be linked in a
Card 3/5 certain way with parameters describing the given complex
66907
CZECIf/8-59-12-2/15
Reactivity and Mechanism of Substitution Reactions of Inorganic
Complexes
in Its basic or excited state, or in certain cases with
those describing the change between the basic and excited
states. The relationship Q = const (Ebasic - Eexcited)
is found to hold for a series of closely related
complexes (Ref 5). Fig 2 gives the dependence of
hydration activation energy for various series of
complexes on their excitation energyt a. Series of
trans - Co en2X2 + H201 Q = 0.64; b. Series of
CO(NH3)5X + H20, Q = 0.474; c. Series of Cr(NH 3)5X +
+ H20, Q - 0.42V. Various aspects of substitution are
then considered further. Fig 3 gives the dependence of
the velocity constant of a complex series
[Pt(NH 3)4-nC-n] 2-n
(after Grinberg, Ref 6). %HKI[PtC14] , B3 K[PtNH3CL3],
C: [Pt(NH3)2Cl2 , D: [Pt( 3 3C11C1. The author claims
that the experiml ntal dependences-found may be generalized
and a hypothetical model process for substitution reactions
Card 4/5 of complexes proposed. These are then examined in the
66907
CZEcH/8-59-12-2/15
Reactivity and Mechanism of Substitution Reactions of Inorganic
Complexes
light of the theories of Ref 4. The relationship between
activation energy of the reaction and the polarizability
of the complex are then examined (cf Ref 8). The trans
effect (Ref 9 cf Ref 7) is then dealt with briefly,
Table IV gives the representation of various stereoisomers
in the reactions of certain complexes (after Basola,Ref 4).L
The author deduces that these results show that the
activation process occurs via two mechanisms which lead
to different stereoisomers. Ref 3 envisages the course
of the SN1 mechanism as that of Eq (2) to (4) for
alkaline hydrolysis but the author concurs with Ingold
(cf Ref 2) in that he considers the mechanism to be SN2-
in this case. There are 3 figures, 4 tables and
9 references, 3 of which are Czech, 4 English and 2 Soviet.
ASSOCIATION:Polarograficky" U"Stav 6SAV, Praha (Polarorraphic Institute,
Czechoslovak Academy of Sciences, Prague
Card
VWEKJ A.A.
The 6th International Conference on Cooridination Chemistry in Detroit,
1961* Vestnik CSAV 71 no.l:.130-332 f62.
f v
KONRAD, D; VLCEKq A. A;
Czechoslovakia
Department of Inorganic Chemistry, J. E. Purkyn6
Universtiy, Bmo and Folarographio Institute
Czechoslovak Academy of Science -- Prague - efor all)
Prague, Collection of Czechoslovak Chemical Communications,
No 4, 1963, 17P W8--IM7
"Study of the Cobalt (II)- Cobalt(III) Ethylene-
diamine System."
KONRAD~ D,; VUU., A.A.
Potentiometric study of the Co (II)-Go(III)-ethylenediamine
aysteas CoU Ca Chen 28 no.3.-595-604 Ur 163.
1. Polarographic. Institutep Czechoslovak Academy of Sciences,,
Prague,
-!A
R!~ICFL, J.; iOCI Set V'--j, A in5titute of Phyiolo,, Do
J, ~y of m-
estic lininnls (Ustav 1-Py6iolo-le Hosnodarslcyca Zvirat) A /-Ab-
breviation not explaineL7 Faculty (F), College of AgriouYlture
(ITSZ), Brno; Poultry ilescarch Institute (Ilysi-cumny Ustav pre Chov
Hydiny), Ivanka pri D=aaji; Research Institute for Fodder Mater-
ials (Vyziatiny Ustav Krmivarsky), Pohorelice.
"Study of Energy Values of Poultry Fodder."
I-Prague, Cesizoslovenska. -Pyniologie, Vol 15, No 5., Sep 66, pp
388 - 390
Abstract: Experiments were conducted with white Plymouth chickens L-5
weeks old. Intake of d-zy imaterial, protein and calories was determined.
The intake and retention of the materials increased with an increasing
ratio of calories to proteins, and decreased when the content of cellulose
of the fodder was increased, 2 Western references. Submitted at 11 Days
of Physiology of Domestic Animals at Liblice, 9 Doc 65.
1/1
L 1226-66 EWP(d)IT RM
ACCESSION NR: AP5025846 CZ/i=8/65/059/005/0561/0577
AUTHOR: Vicekl Antonin A.
TITLE:, Reactions of coordination compounds
v
SOURCE: Chemicke lists' - 59, no. 5, 1965, 561-577
TOPIC TAGS: coordintion chemistry, chemical reaction
'Abstract: All the reaetions of coordination compounds may be
ied in 4 big groups: 1. The reaction of the introduction.,
,or exchange of a ligand (primary change located on the central
,,atom); 2. reaction of a combined ligand (primary change located on
ligand); 30 isomerisation reaction$ racemization ( only stereo-:
,,Chemical changes take place in the complex); 4- oxidation-reduction.
;ireaetiona ( the primary change concerns only the number of eleo-
rons, but this of course can induce a series of further changes
:in the complex part). Coordination reactions are.obaracterized by
:,the following 9& the ligand entering into.a reaction remains a
idiscrete structural particle throughout the reaction; the ligand is'~
Card 1/2
ACCESSION VR: AP5025846
a stable unit in the-given medium, or*Is eleitz-6nioally saturated
;in the original condition; the reaction produces coordination com-
pounds with orbits Of Sigma symetX7. Only...reaotions that were -real-
'!ized are discussed in the article* Orig. art. has 49 formulas
-Heyrovskeho CSAVI Prague
ASSOCIATION: Polarograficky ustaw J.
Institute of J. Heyrovsky, Czechoslovak AcadenW of Sciences)
SUBMITTED: 00 FNCL: 00 SUB CODE: GC
NO REF SOV: 002 OTHER: 031 JPRS
Card 2/2
VLCEK, Antonin A.-
.Reactions of coordination comound3. Chan 19
I , -
577 MT 165-
1. J.Heyrov3ky Institute of Polarography of the C?.echoslovak
Academy of Sciences, Prague.
VLCEK A.A..
. " , , x ~., 7 1 ic rge r 56 '. .
"OrIc ! t & 1, -- i n at, -,,- s a n~i r -- U.-I e n " b" .',' 'a~ '! :..I I -,,j. -
by A.A.V!2ek. r"Ill ~,-- -rlf-;Q Z9 py
~
VLCEK, A. A.
"file tal X -complexes with di- and oligolefinic ligands" by E. 0.
Fischer, H. Werner. Reviewed by A. A. Vleek. Chem listy 58
no. 2.242 F 164.
"Progress in inorganic cheinistry.11 Reviewed by A. A. Vlcek.
Ibid.: 243-244.
"Advances in inorganic chemistry and radiochemistry.'' Reviewed
by A. A. Vlcek. Ibid.: 244.
VLONK I A. A.
"Introduction to ligand field theoryl by C.J.Ballhausen. Reviewed
by A.A.Vleek. Chem listY 57 no.lOilO84-1085 0 163-
VLCEX, A.A.
--
"Absorption spectra and chemical bonding in complaxes" by G.K.
Jorgenson. Reviewed by A.A.Vlcek6 Chem listY 57 no.8:854-855
Ag 163.
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MRAD, D.; VLCEKj A.A.
Folarographic study of the cobalt(Il)-cobalt(III) othylenediamine
system, Coll Gz Chem 28 no-4-.808'-828 Ap 163.
1. Polarographic Institute., Czechoslovak Academy of Sqences,
Prague.
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