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SCIENTIFIC ABSTRACT VLATKOVIC, V. - VLCEK, A.A.

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CIA-RDP86-00513R001860320006-5
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December 31, 1967
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SCIENTIFIC ABSTRACT
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KON,Mirko; J3VRIC,Sava;,V7ATKOTIC,Vida Sedimentation of the erythrocytes (31) in pulmonary tuberculosis after a load, %berkulozarBeogr. .11 no.4:538-540 O-D I-SI. 1. Institut za tuberkulozu JIM, nacelulk: san. pukovnik prof. dr J. Studio. (TUBIRCULOGIS PUMONARY blood) (BLOOD SIDIMIMTION) 4AT~Ni(-' V BOZOVIC, ialsa,'San. pukovnik dr.~~~~ @an* kapetan dr. w Came of balooned caverns yoj~ Ban, pregio, Beogr. 14 no.3: 143-146 %r 57. 1. Grudna klinikL VMA. (TUBIRCUIDSIS,'PULMDRARY, case report balooned cavern (Ser)) HE vountry : v-U'.OSLAV'T-A G a t c_,4 o ry;riaru Aninz7~~Is. Q-5 :L",, 19" 74156 A'.-,.,3. Jour 5 Author VI-a7t_'-CovIph, B. D. Inatitut. Title E03el of the Sjenio& Dale and Pestera Plateau and tl,:~ Oonditio--v; Prevailing in Apicul"L-11re. OriS Pub. Acta veterJr.. , 195?.,'r, , No 22 -~-18 Abstract Data are ppeseated on 15ha bloiantry of local bees (Svrlpla) as rmll a-3 a list of hor-ey 1 aP-t s Card: 1/1 VLAYAKHIM, L.Ya.; WHROKHOTOV, V-11. Farther investigations on the topography of mitosis of mouse carcinoma; structure of mitotic foci, Doklady Akad. nauk SSSR 81 no.6:1143-3.145 21 Doe 51. (CLIG 21:5) 1. Prevented by Academician A.I. Abrikosav 30 October 1951. 2. Institute of Experimantal Biology, AcRdemy of Medical Sciences USSR. '7 cliev.A (Eafzineer) A U"NVOR V la, A~ atpmdardlrsi5~v Bu4garian glider, '1965, 2 SOU'Rct.- A~iatsiya i kosmonavtilm, no. 3, tv)PIC no: ormunce , aircraft specification aircraft perf jYT*.PA,,-,m -Duriag 1957 the Centroal Con,-mittee of DOSO annotunced a contest for the aesignin-gr of a single-seater glider of high. perfornimce. Docent L,-ruber. Panov and i docent Dimit"r Pauchovsl~d wrlDn the c:~ -grtition- fRa&!d on this (lesip, ~--he ~A Orf, ce peerso~ (Lyuben Panwi, Dlurld""'r PanchwbU. Razil'-.0 A%-mdr~-'y a final design of the "Fa, eta-standart," on which was bazed ychev) cam-e up vItn M tl- neyt version the Kom"-Ila-2. FiLzLIV, ir. 1965 tte last tYPe, the Fameta-3, -waz ng, 7;-~' n k"t-,riS tj C C :-jrg6PP.!U , I" . jqge -Cdurzed. It hzu- the follluri 6.65 M,, iring lifting - siurface 12.21, m. ,-Ing load Speed km/h-r' T carc I ~ n".1mv, G. 01. "Stability of Plant Bending in an !-Beam Under CoiVlw. jzads." Gand Tech Sci, Kiev Construction Engineeriing Inst, 26 ilov %. (PU, 14, 11ov %) Survey of Scientific and Technical Disoertations Do.,-.ended at US3,q Higher Educational Institutions (11) .1 SO: Sw. 11o. 521, 2 Jun 55 WAYKOV, G. G. Application of the principle of sWerposition (additivit7) in problem involving the stability of plane deformation. Takh.molod. 22 no.1:436- 441 Ja 154. (NLU 7:1) 1. Kfivolkly inxherno-budivellni7 Inetitut. Predetaviv diyuniy chlen Akademii neuk Ukrainalkoi R.SR. (Deformations (Mechanics) VLAYUK, P.A., akademik Gontribution of Ukrainian scientists to agricultvre. Nauka i zhyttia 11 no.8:2?-30 Ag 'L. (MIRA 14:12) 1. AN USSR; Vsesoyuznaya akademiya soI'skokhozyaystvennykh nauk imeni V.I.Lenina; Ukrainskaya akademiya sellskokhozyaystvennykh nauk; prezident Ukrainsk)y akademii sel'skokhozyaystvennykh nauk. (Ukraine--Agricultural research) VLAZHEVICHI I. V., Cand. Veterinary Sciences Central Scientific Research Lab. for the Search of New Medicinal Substances, Ministry of Animal Husbandry,(RSFSR). "About the role of sheep in transmission of malignant catarrhal fever of cattle." - SO: Veterinariia '24(2). Feb. 1947 p. 20 25M FHAM I BOOK MaWITATION sov/2454 Sergey Vasil Iyevich Podgornov, Valerly Mikhay- 3VDlazuev Yevg lovich Chernyshev, and Petr Gavrilovich Shelashov. NormalizovamV7e Btanochnyye prisposoblenlya; spravocbn1k konstruktora (Standard ifachi~e Tool Fixtures; Designer's Mmmal) Mosc'ov,, Obarongiz, 1959. 439 P. 12,000 copies printed. Reviewer: Kh.L. Bolotin, Candidate of Technical ScienceBj Ed.: V.V. KhzImin, Engineer; Ed, of Pablishing House: I.A. Suvorova; Tech. Ed.: W,A. Pukhlikova. PURPOSE: This m-gymal is intended for designers of machine tool fixtures and engineers and technicians, It may also be useful to ptudelits of machinery- .construction vuzes and tekbnik=s, COVERAGE: The manual presents data on the standard structural design of ma- chifie tool fixtures. Reference material, materials used in manufacturing fixture componentsi standard types of fixture components, basic elenents of fixture components, standard fixtures, hydr=lic and air-operated actuating Card 1/13 ~av e~nilv~anovic~h; PODGORNOV, Bergey Vasillyevich; CHERNYSHEV, Valeriy Mikhaylovich; SHALASHOV, Petr Gavrilovich; GLIKW, G.S., inzh., retsenzent; BOGOMOLOVA, M.F., red.izd-va; PUKHLIKOVA, N.A., tekhn. red. [Standardized machine-tool attachments) Normalizovannye ata- nochnye pris'posobleniia; spravochnik konstruktora. Izd.2. pa- rer. i dop. Moskva, Oborongiz, 1963. 504 p. (MIRA 16W (Machine tools-Attachments) a; LITV11, Gr-1gorjy J!",j;*hj IV. g1tvj gp tek-h-D. Itauk, 9W. rp,-,,; red, [Co.1lection of problems on construction machines) Sbornik zadach po strf7dtellrWm mashinam. Kharlkovp lzd-v3- Kharl- kovskogo univ.p 1965. 50 P- (MIRA 18s7) USSR/Diseases of Farm Anim'als. Diseases Caused by R-1 Viruses and RickettsiaP Abs Jour : Ref Zhur-Biol., No 1, 1958, 27351 Author : Bogach I., Eednarzh B., Vlaznichka F. Inst : Not given Title : Nonbacterial ~'nfectious Diseases which Comp- L rise the Complex of the so-called "Grippe" in ffogs. Orig Pub : Za sots. s-ih nauku, 1956, A5, No 4, 385-396 Abstract : Piglet diseabes which are clinically manifested by retarded aevelopment, exhaustion, and infec- tion of theforgans of respiration and blood cir- culation were studied. Occasionally there was an affectio of the nervous system manifested by atypical epLeptiform attacks. Greatest morbitity was obsevied in piglets during the weaning period Cai,d 1/3 _VLAZNXV. Yevgeniy Ivanovich; PODGORHOV, Sergey 'fasillyevich; CHIMSHEY, Taleriy Mikha7lovich-, SHALASHOT, Petr Gavri1avich-,-'BOLOTIK,_Kh,L.. kand.tekbn.nauk, retsenzent; XMIMIN, V.V., inzh., red.; SUVOROVA, I.-A., isdat.red.; PUKEELIKOVA, N.A., takhn.red. [Standardized machine-tool attachments; manzwl for designers] kormalizovamiye stanochnyo prisposobleniia; spravochnik konstruktora. Moskva, Gos.izd-vo obor.promVshl., 1959. 439 p. (MM 12:5) (Machine tools--Attachments) I MACAT, JoBef, inz.; VLAZNY, Antonin Technical development In repairing railway rolling stock. Zel dap tech 10 no-2:33-34 162 , , -1 i ~--; :~ ! ~, -~ - ;~:I. 7-. - -, 'i: - -: . --1. 0 0 0 0 0 0 * 0 0 0 0 0 F a 10 it 11 If 14 If 14 It IS 11 h ~ 11 a 43 At a A If 30 3 111,11.114ZISOMPQ 41 It 6t AA ACC OP U4-1- 0- -4- t -A .40 Y IVID it The camposition find evaluation of enzyme hates. A. VLkvc~. i,',rtwp 53, '-Mr. !I. C 00 4 T t Q Cab 0 zo 0 00 0 00 J, 40 0 go 0 *:.It 1 -00 0" 'JI 00 00 91 too 100 U 0 11 Do* wit lt%t of u tt it Of 14 aw 0 Ana 0 0 0 0 0g, 0 0 0 0 0 0 0 Go 0 0 0 16 0 0 0 0 0 IN 0 0 0 0 * 0 0 0 0 0 0 a I I '19 - 0 0 0 0 6 0 0 4 0 0 a 0 0 0 0 0 V I I 1 10 6 0 0 0 0 41 0 0 0 0 03 1) 14 )1 4 1? of JD A J? A A I.L. 11 W IJ U A b 1) Ji JI D 9 0 L K I I L 't Ai 0 of %Vtl A A Z 41 0 410 00 , - -- +~ Of -.0 'Oo The SaTpwitian ud traluallm of twime betm A. Cmf ktA. 19, W.-S -so OQW): d. C. A. 24,1246.-A biblkqmpby is includcd. G.,VmDuct)jtv -00 -~* 00 0 .00 04 -00 0 X0 0 00 too 09 so 0 ;71 , , * am C.. It, -- , - - -- - . - u at .0 A 4 i #A I t a cht i i a r v t 1 't art x t , 0 00 o o 0 0 0 0 1 lI a 4 4 to 0 0 0 0 0 0 0 0 0 0 0 6 4 0 0 6 0 09900 0 0 0 0 0 0 0 a o0 , 0 0 60040 0 00 0 0 a * 0 o Or 0 19 0 4 0 .0 o o 0 4 I,R a A 25 It 27 a ?v a 11 U U U a a V a At Q 41 49 a c 1 -1. A _1~4 9 24 A Ch- hfjr1a'yy With* thrAy"I"d jvPXT". -00 j0duv-pity with a 'S 0 '400 A* t:o 0 -r --ir-i, -9-11 41.M w epipff OW&C Ora Ica nun 11a wn 141 0 0 0 4e14 A _00 0 : 0 go 0 ~ov~! -0 $- 0- -0 o -0 ; -0 OOA so Ustweuk$lv w Dolt va Ofs ICU ic ifyda. I I o 0 #10 o POLICISS491 ANO V4001ttlit ~hDfx 1 4 A doe C! If - 4p . T. -00 I-go goo 1 too owl 0 0 0 0 0 0 0 0 04 000 6 0 16 09 C 0 0 0 6 0 4 1 A '; 11 q it . It . U A if AD V a 13 J. a J6 It JI .1 in It v 11 k A IL 1 P P 5 A I 1 1 Y JA OP It; w 15 k . 0 0 go goa !.so -00 Aring of en#WC tannery batec &AVel'. Ttthmjfk,J JWJ4 lefflaskil 1932, 804r2; C" Obza, 8, Abstratt i =Go he"y and mecha- seci., 191-2;c(. C. A~ 27,6214..-The 0o IIL%III (if aging of entyrnic launcry Wn are Iltivirn. ~00 KlIhIs 0 zoo 0 00 -a 00 00 4=00 0::: go not Os 0 tie 0 : 0 AS fUltUPOICAL Ulf-alLit (LA$$IFIC&TIFIl boo 04 WOO loo JL U 'W:~13 0 rw 0 -1 04 o o 0 0 0" 0" 0 0 0 *10 9 0 0 09 * 0 * 0 0 0 0 0 a 0 a 0 0 0 * 0 0 & 0 0 0 0 0 0 a 0 0 0 4 0 6 0 0 6 0 0 0 0 0 e # o 0 & 0 0 o 0 o 00 PIE. 0#00000*0000000 0 S 49 'A' .- 14 111. 01111111114 000000 0 so of a s6 t9 ire *a, 1 3 41 1 41 1 1 0 If of U I) w 111 16 If Is It )I a a A b to so so it It As m 16 AS P 4 0 10 so I to. jo- a A I tL, 1. _j_A_ JAA W-M W I, --------- le-P 'q4 0* ,,Twwery beta*. U. The C*MbiDAtiOD Of PILACIV400 L, hm substance. A.AWA and J. i'mosilid, Giorher. 39, w-100, C. A. 37, b2ic-The ..91111 ability of wiles Powder to Ps="t14 km sq. It 11114% flAllki that the Visit nite 4, Ii%WII -"I Cowin III mossit-Im., us), loclucirvatill issollm vsr.it lifeally flor"regird by 411.1wing 2,M) ve, to[ 1116, last" Ill It4lid Ill I with O,Vi, 8.1) K. 44 fm 3A mill. 11 gas irl".11tcl7nop. 71tiq wss taken Ill indicate that the losAwrt-sitin was in suaw way butiful toy the hide sidmiatser. Sinsy 200 IlwAl'Ttvasmor ill risiviolis: activity WOVII.V4, 'ZO 0 Inn"'irtilookal to$ Or &"it, ill hidu J.,vost's- sited. it "as s-l"l. Zito 0 .1.1. ed thAt velfalls flw-fim~ of Ilse Imlinvoltill C.4111oilled fit 0 s, moose: irmottly with the told, mitooswjv. .14,. ."w ijj~tlvssl *so appews adtNuals, low dog. the qtrrsigib awl IllitAblilty bm !-I rill 0 vact'k-A use ill vixymc pvt pits. amed as tannery thates. 411110 *0 A:-:1 -!T 14.11. A ONTALLURGOCAL LITM 1`110C CLA *4 Mod is die to; #AD,, To 0.0. t I tow 4 of i, sit 4 1 11 rw 0 it ill- -0i 91- aU It AV $a it is A, As to It x ,a so woo 0,4 6 0*71 *0 0 0 0 a 4, its 0 0 0 0 0 0 0 46 0 A 41. Pi I a a a 9 _ _ 0 0 0 0 00 0 00 0 oil 81 a ho' I I I ~; .~ I '. " , it v 11 1 M n R TF7fN 'fj 1. 1 ft If Is I 1; 4. o-I* . A 111 91 k 6 Itj L L A fit r 4 1 1 v C 14 AA M LL IX1 It I so 00 00 00 Potato 1,111,11.,it .4 Ow 1,11 ..10 41'. -IitAfI14I *,.I Itaphle studies in leather chentlittly. lVisto ' -00 I.11 I It!.), IN-bilf I-. 1111I.11Y.111, u bracho, cirtratts. A. X, Vkvi,, - 0.01Q " .""Y"Os 11 1101 1itmar KirkoMi-vit. 1*#Wb.L IflUka rise convii. 44 pyrotraltiv Avid mul IIIAY 1W U~Il Girr IjuAnI . 00 %I Id an . . , XA,1mt,k.l 19, Ill-Ut(1043). It. Polarograms of Although it-lo- FOilbut" Halt. to I & Aqueous solutions of pyrocatirchol. Ibid. W-41-N-V and .11-Irl'A 41 Imill file "if. i(~ did ota -11". Wf y 00 Ill. Polistrogrammol FrAilk MAI-1- aqueous sWuU*ns of I zoo 000 attle acid and phloroglucinol, A. K. Vl&k anti I,. 1 W A -Dilute (IMM4-0.01 f) and 0 - Ibid. IIIII- 0 0 tPuffeml U)III.- of pyrogallic arid Yielded An AnOdiC OXM4- 11, w4vr VVIIIA runs go4ralirl if) the firti stageo) 031darlon 00 of pyrogalfir schl. The half-wave potentUl was a lisicar "I age 0 zoo 00 It' 'to 0 k it -.i 5-7- A U N At 20 A 4 S a tp Is It 12 it 01 it IN it PC U n It Iwo 4 411111,1149104 1, ~ 0 16411 too 0 0 04 0 0 is 40 a 0 0 0 0 0 0 7.009 4*4 0-00-0 0 0 0 0 0 too 0 *s et PolarographIc deterfmination of trues of iodide In common K-WhArles MAY- Prague). Callrdion "ft. A.. A,,Al& Cmiloslop. 'Chet". LOM"Uns. 15. KXI-F4 1950)(in HnI1611); Owsm. Lissy 44, 7-,(IVN0.-TrAm4 of I - in NACI are deld. by oxitlizing the V to Kh- with fir In dif. IjsW,. i4difinig eavw INA01f. and recording the polarogriult of the buln. The drop time must be at least 4 we. to clitnillate file "water wave" (Orhmusus and Kollhoff, C-4. 36, 31051; Hass% anal Yon Stackelberg, C.A. 44, 6=1); if it is not, 0.01-00270 gelatin nuy be achicti. The analysis is m;uie by a Kandard eAdn. technique by using file smallest possible atut. of addett "it to avoid significant changes in the char- actTrof the 144 nx)rting tlectrulyte. Resultsare2-H% lower this is a"Ilrd to file effor in the latter conied by true" of rnidual Hr. which does nof interfere In the polarographic mr-tsurrments. I-M. C/f Ida In Com- ktm, LWy all iscidic ,oln. to iodate. which h detd. pularographicAlly in w~tkly idk. suln, In coned. (IN)%) sotas. of NACI, all allornalon., wave (water wave) occurs, which interfries. it can bc %=1byusinga lowflowratent JIC(l - 4.6~c , m - 1 ave.). or by adding a drolA 1) 51"a ~0111. of KVI'llill in a I(Mul. sample. Muolve 10 X. of cinumon ~Jt in 441 "ll. JxjjjjjjX watef, Add 1-2 nil. 0A V llh';A), to Aightlyarid .tiou, and 3 drljIA fir. Remove rikvm fir ljy buffifig, .%filitt ulk. with I inf. 1.6 X N.I()If, filter, aild make ull 113 .10 HIL POW01faph it ilkfll. kullille affer IC111111-111C 0 by a sirruin of N. Add OAJ 4 mL MIA,% &if, Kit), and reg6ter the htandird curvv. About OA -.7 ing. K I Jkx. Is'aCl can this% bc- &W. M. lludlicki. C=H/2433 24(2,4) PHASS I BOOK Expr4rTATION -4 international PolarorraPhic Congress. let, Prague, 1951 Sborn& Z. Mezinaloddho polarografick4ho 814=du. D11 3: Hlavni referaty prednesene na aje.-du. Ppocee4ingS ... Vol 3z Rovlawa Read at the Congress. Praha. PrIrodov.decke vyd-vj7 11952) T74 P. 2,000 copies printed. Rasp. zd,t jir'~ xoryta, Doctor; Chief Fd~ of PubllstLlng Housal Milan skalinf1k.Doctor, Tech. Ed.s Old ich Dunk-m. PURPOSEs The book in Intended for Chemists, chemical enginatrs. and physicists. COVERAGE% The book is a collection or reviews and artgInal papers read at the International Polarographl- Congress held In Prague In 1951. Uses of polarography In orgazile and Inorganic analyals, biachomistryv medicina# and Anduatrial chemistry are discussed. In "t sd tion. Reviews Read at %-he Congress, Russian and either Carman or English translations of each rev~-em &re presented. In the section, Original Papers Read at the Congraz3, only thoa& translations in Russian, German, and 2-iglish which ve not been Published in Volume I are presented. Thec=~-, following scientists paLrticipftted 1, the Opening of the Congress& Professor Wiltor Kemula, Dean or the -Faculty of Sciences. Wareaw. Doctor Jarcmir DolaLnsky. r.4niater of Planning; Professor Jar0slav Herovaiqr. Chal-mein of the Congress; and Professor Jarosla, Fukatka, Ch&lrtnan or the Center for Scientific Research and Technical valopment. RarerenaeB follow each Paper. Vr-J--Apparstus for osaill4grsphle Pole- RUNDlAn Transiatlon3 og"Ptly 241 0*ru&n Translation) 250 1 e 259 -Say-to"Y2, J. Oncillogr Phic Pojsrtgr,,-:a Puss -A-"'T-Anslation 273 LE"911sh Translation 219 Drdlcka R 'UnOt'cs Of Electrode Processes in Polar, 286 Card 3/14 POILrographic Study or Basic Trlv<nz Chromium Salt Systems J 395 Krivanak, M. IComplexes or Iron with SlecZarnse 399 DrAtovsky, M, and 4 -JC~*Ft. Effect Or GtIatitj and jhymol --OW-C&-t?=rF'DePO5itiOn of Cations at a D-OPP!pg mercury Electrode Russian Tranalationj 404 [Gam&') TranslatIon 407 Kuta 410 JStudy or Kydrogen Overvolt'91 "Ith A Mercury -"ec~z~~e With Controlled Dropping Time 413 .1 , -.Dvorak,..J--- Effect of Capillary Constants 0. the Xazim. ar-bi7gen Russian Translation] 418 I arm& Tram. .1,,] 421 0"is. Vavruch, 1. Attempt to Classify Reflnj Sugars by the 423 .7P0I1r6gr&Ph1c Method ftuoelan Translation) 427 fOOM&ITransiat--cmj 2B6 OR!alXkL PAPERS READ AT THE CONOR.ZS 33Z --falOuacy- X., and A-Ta.Ckatcjn. V,,,,. Equation 1" the Deduction Of the or the N . . . t Vi rographic W... F,,a_ 359 A.A. POlarography in COhOentrated 3ulfkuric Acid 366 T"79*rmn Tran:Utlonj MnSllsh Tram 2atjmj 370 -Valenta, p. study or Current Discontinuity Appearing on 373 a.Calom.1 Be" Electrode na'?"N ~-. Discontinuity_ on Curves Obs-,~ 377 .VULK, A. A. Lzech L-A: 47:11030 Central Polarographic ~nz-t., Prague, Czech. 'lPolarography in concentrated sulSuric acid.?' Sbornik Mezina"rod. Polarog. Sj'ezdu Praze, Ist Congr. 19551, Pt. ill, Vr-oc-, 366-9 (in Czech), 370-3 (in Russivil), 373-6 (in Engiish). 1,11 0,P M VIM- - Antonin A* ated sulfcic aciit. 11. Ca- PolarogTaphy in coticentri in r,111rd. 52.5 it farad.; cm. - . : .. 7 hl half-wiYOPOtOntiats Z: ureinent; ali. 9 ft f --h'itlott. V1, colleffi, CA - 48,1328- -NEW ovid equation for Tiql3rogr-A ~^11VT114 validity a 116 YE". Yrag")- - . .1 1 ~ rts- pmed that ffiese o7nd4iow were fulfilled: (1) P,--rf-ct mobility equff., (3) a w1n. completely free of surface-active "Substances, (3) sufficient exccsq of the Indifferent clectrulyte, (4) moderate conen. of the depalarizer, (5) a application of the max.-frei system, and (6) ust: of a capil 4r q of diam, O-N--Q,OSMM. ons ~tn,ilkoirWs c4u~.tiott could be caused by 3 l4ctors, (1) tkjl6lo current ijjj;s during the Hg drop time; [12) neglect b( OM curvature of the OeOrode surface, And (3) itstalicient exclusion of the turbulent currents. At small ilmpping sed by the chanke of the specils, die deviations wtst caw dropping speed during the lig drop time and by atransler. t of the Cotten. polarit-ation train oac drop otheother. Thit transfer bepa at the s" of the drop formation. At high dropping speeds the disturbing factor was due to the turbu- fent ciorrents. The development of the -current Was Inde- pendent of the drop time In the presence of the gelatin, A the deviations were grta;~ because tile con -T I transfer *as more intensive. Gelatin was d&.1 _-- w sutface4edve substances were pnmazt, Aft the dey Vrere much higher tha6n ammed If sphak diffuslad *xV for the change of droppitir for I > 0.1 V.We In aaefrrrent the llkovi~ equation. VLC-CK, ANTON11VA. -'ii~i~;Oaravhlc half wive Rotentlab. 1, MethodofmL'25-- F--.. .. -afflum. Antonin A. PolarogrAfieW listay ~SA' - vl&-k Tj -V., Pra le Ire --Tmr?r 48,1W-WJ(1Q5.11 Bymemns t C ectr e ting the half-, system litlacompensa Prave potentials .1 the 71+ ion in 4 media were detd, with anaccuracyof +1 mv.: In OJAf KCI -494,0 mv., in OAM NaNOz -493.0 .so, -wj.G mv., auff in 0.1 Af N114CI. jjjv_ ill O.IAf Na- NI(joll -501.0 mv, against a noTmal IfgCls electrode at F. Redft %and h V70" the JQ113 (Cf, G are ba-A d oil d n5 bY gid Ti, C haff-wagg -rflt~ '6~ jujj~!J~' 11. Effect of the supporting e!ecrrolyte' tild cxlri~64c"*ed hAt-wave potential. and the normal oxidatton-m-ductirn po1cnIIal,_,&U.QiWj BD -Tile dq,,cod- clice of tile i~ -df-wav,~ pkitentials EI., cW the 7*11 and III) I I iani or Cie concTi. all(] ji-ature of the support ek0rolyte W32i df'!d. At IC)--V COTlen3. Of tile .11111POrt efCCtfOl"tC tile depc-a'le-ov, of Et'.E - %/ji (g. vvas the tonic strength) was lim:ar .11111 could be emtr"potut!Ld to p - 0. A 1wrillal llAenflal miler curent-flow Ec(l) was tll'~Fmcd' arid tile tile kill"i-I of tile elldfoje pruc%!5-1. From tile b"A'O.-v valuu of the frce and tomplex. fulls, the therillc. Yllarnic congts. of Complexity couid tie (Icid. Tim VKlueg. (api!lit a norm-I catolud 6xtry,dii) were: TI+ - 4M 013 r-,I-+?., - it e mv., freu, Ilb'0 -4, and plumb, t ions -810 mv. V'rom theic vqttif-.4 for tile plumbate. PIC, - IM15. Thi, rv)rmal potential of Pij In plumt-atc noln. vm3 calcd. ft-c-in vaIu,-,,) P-3 -53' niv -1. t Tionnal It elcc- Ill" Albit . W, d AD valocs Is:,It, 'l~ 2", e their f t" Vie polarographic sird I i c I ) Q 11 ; k v i - Tr f l lit, L~' ; ~jj.~2 PML117-4111, WAS 'I'll,% s~:tvri :X:. indal-ativilgant gave a ie-. w-ave and was o:~cillographicdly revez-Abb-7. , Thr rt:vuiiIAIiIy of Nil,' ion was provtd. Tilt: ImIf v.~iv~t pottoth-di of alk. metab in 1, 1, 0.1.1f (elli '5 Rgaiiit a normal Ific.cit TA f - "'P" V. N' k V'; K + j'~I' ~ - 12.16~1 v.; 6i --l"o, V, The "'xtrap- otau-cl pot,utial, sv,,ru identlell with tile rLarrunt o~idatlovi-rkadmtioii putvntiat; under current flow within th-.! Limits of exvtl. error. Erd63 ~V*"' VLCEK, A. Polaroggraphic half-wave potentials. IV. Proce6ure for comparing half-wave potentials in different solvents. p. 1863 Vol. 48, no. 12, Dec. 1954 C-FEMICKF LISTY Praha, Czechoslovakia So: Eastern European Accession Vol. 5, No. 4, 1956 n between th6 electronic structure an jrapblc beb~~ -of inargault, d . 11, as ~C =av CSAV 49, 10092f. 9-Em C;21 , t7 -%zmr -my Colkaia q C~,r ka ilm. Ckem. Cc aa q 1. i P" " ~A (Imnan).-Sce C.A. N. IW-k. 11plaroqaIlIlh: behavior OQl;dxA_;=,tA slonarlucou" Sol: V~nts~ IL - 90fittlans tif strong acith I%_afjaML ~kirVi,'.k (PoLivigraftM 6A:,v I~SAV. Pfuguc)~ --OVOT'.- With int-reahig 011101.0iBROJI, (lit toward miire poi, values. The total change represented 0-'17 V. ;* showo Z,.!l the poLaTographic curves of tile SYA01l* MOIL + 1110 + fICI(IIC1O,) and In pre-ience of MLjNCl or UCI. Thh value was c4led. from tha "K potential -scale." tile values of-which were indelleudent of.the couca. arptsi of EtOHvgrlcd fit the same inatinpr;u of 1P ILI these gains. Flora the Chan" or the half-Walve tncutw and from the uormal potential of 11 electrode ia r -to, +0, 1 Y,. was detd. r.3 tile 11 overvoltage in EtOH. Comparison of known values In various soNimts showed the Ii overvoltage to be ielated to the promplucis with which Im haimi- of "tmaujum An 6OW Ong a A. A. VI&k (Poh Z=10 ~ftAv -ESAV. Prague).-T "___Z;WyZV0, 2tMI955).-A soln. of Tal0t in lip, po~r(rphcd in a suppartbig electrolyte that is satil with F mntg. 157 X 10-2.41 lip at least, give-,, a weli developed wave of a height directly proportion3l to the conen. of Ta. The half-wave votmtkil Is -0.95 v. MORN X,tl~5. Tila akorption WTUam of the AEX14- ~.Ill. Siva EsYmmetric Pbaarptiun zone ha-' v-mg Lhe a 3.- V I t Trar.7 ank; p. jft_ -WKK,_A.A. "Advances in inorganic chemistri! nd radiochemistry4l edited by H.J.Emeleus., A.G.Sharpe. Vol. 3. Reviewed by A.A.Vlcek. Chem listy 57 no. 5:547-548 My 163. "Progress in inorganic chemistry" edited by F.A.Gotton. Vol. 3. Reviewed by A.A.Vlcek. Ibid.:548-549 ir .4, ~ fa~, .- -.-, . "-- -. - 4 ~ - -~ -. - -, - - - - . - . - . -: . - , .-. --I-- . -1 ~, . , . z ; -- - -.- --- - - - -1. . . , - .- . I ". --: ~'.. i:L,.-. - ": 7,~- i6 '. " i.' . Z~ 4~ -, : . - lr,~~ i ~ Z- - :.. .: .. , . . . :1- ~ , ~,; i 1, - . -,%~ - ---k -1 - . I . I - ~~ , -~-, !;~ 4", ~ VLCa, A. "Effect of basic electrolytes on the polarographic behavior of nickel ions; a preliminary cormunication." p. 828 Institute of Applied Physics. , (Czcchsolovt,~~ Acade-,.;y oC Scienc(-;S.) Vol. f'C, ro. 5, 1~v 19 56. FPf S1- SO: Monthly Index of,,,European Accession (EEAI) LC, Vol. 7, Noll 5 May 1958 VW EK p A. VLCEK, A. Tables of half-wave ootentials of inorganic depoarizers. po 400. Vol- 50, no- 3. Mar. 1956. CHEVICKE LIWf. Praha, Czechoslovakia. SOURCE: East European Accessions "ist (EE.AL) Vol~ 6., i~o- 4--April 1957 Fo ation and reduction of Zero-valent co ex q studir"' cdaI#'_,gravIfWcaIIj-M~. Efft-T, Prague) --7 r-7-Uansition metals are polarograpbic-Aly reduced to u zero-valent complex (1). r ruay be stable, may, decompose_ to the inctal, or may he reoxidittd to another complex. Far example, Ni(CN-),-- in O.Ut NaCN` b reduml to Ni(CN)j ---- ; this with lrjO yicJds 14 and 1 which is irreversibly oxidized at the anode. Complexes of Ni(II) Nvith bipyridyl, (NIT-CITI)2, pyridine, Nil,, and Cl- in5MCaCl;showed the same behavior. Fe(CO),inUAI Ms),NCI in abs. EtOll is reduced'at - 1.7 v. vs. tile IgCt electrode to P4CO)4--, which is oxidized in 2 succes- "sive steps to prcduct% otber than- Fe(CO), and Fe&(Cohl. Obwrvationswese made by oscillographic polarogtaphy and, a Kalousek commutator. K. G. Ston" ki I-C L I-T- P - //-I - - - - - CZEI-HOSLOVA-E:EA/R-y~-.~l..-:rj. Onpiq~st-ry Fle-troahemis try. Abs jr,-u7 Rof Zh,.i-- No 5, 1958, 13913 Author A.,~' Inst Title betwe~;c(-. the El-,%ctronic Structur~: of Imorgqmic Den A. .Lolaxizers am-d "Meir Pc-lF-::-ograph-'c Behavior. IZ C,;~P-hides of Orig -Pub St. khl.m. rabot-, 1957, 22, No 3, 948-960 Abstrafitt Sz:,-5 RZO-111im. 1957., U0780. Card 1/1 VLCEK' A.; IMOVSK-f, J. .2=W-- Significance of ti,-~- Il~ovic equation in electrochemistry. p. 3. (Matematicko- FyzikaIny Casopia-, Vol. 7, No. 1, 1957, Bratislava, Czechoslovakia) SO: Monthly List of East European Accessions (EEAL) LC, Vol. 6, No. 8. Aug 1957. Uncl. CZECHOSLOVAKIA/Physical Chenistry. Electrochez:Listry. D-12 Abs Jour: Ref Zhur-Khim., No 13, 1958, 42705. Author Vlcek A. A. Inst Title Rela ~en the Electronic Structure and Polaro- graphic Behavior of Inorganic Depolarizers. III. Electrode Processes Involving Unstable Intermediates. Orig Pub: Sb, chekhool. khim. rabot, 1957, 22, No 6, 1736-1746. Abstract: See RZhKhim, 1957, 44188. Card : 1/1 ~ ) It. A symposiur on rare elements. P. 2ci5 (Chemie, Vol. .0, no. 2, Apr. 1957, Frahj, Czechoslovakia) Monthly Index of &ast European Accessions (':!-'IT) 1C. Vol. 7, rc. 2, Februai-y 1~ 1178 VICEK., A. InorFanic oxidation and redi.,ction excharij:e P. 305 (Chemie, Vol. 'is no. 3, June 1957, 1'r-rihn, Czechoslovakin) I-Ilonthly Index of F--.st Luroz:ean Accessions (EEAl) I,C.' VOI - 7.9 no, 2. February 1958 VLCEK, A. I "Relation between the electron structure of inorganic depolarizers and their polarographic behavior. II. Complex nickel cyanides. In English." N 948 (Collection of Czechoslovak Chemical Communications. Sbornik Chekhoslovatskikh Khimicheskikh Rabot.) Vol. 22, no. 3, June 1957. Prague, Czechoslovakia SO: Monthly Index of East Furopean Accessions (EFAI) LC. Vol. 7, no. 4, April 1958 Distr: 4E2c(j), - A I/NlaroMRJiy of the cobalt-blPYTIdIne C n I h* I : l P i~f o t Vl6 aroy -5 M'-"'1CFfZ: -51 -The 143~ olaro so ~ 1958 . g~ , p -31`1 defined com lex h well Co(di 0 a ;i th MC10 ) , r 4 j 3 , e , py p y p I disclased 3 waves. whose behavior in OAM NaNOI is dc- scribed in detai), The first wave, Ft/, - +0,09 Y. vs. satd. calomel electrode (S.C.R.) and coacn. independent, had a limiting current which showed 2 small adsorption waves at '.-O,B5and-lMv.vs.S.C,E..rcsp. Itconespondstothe reduction of the Co(dlpy).'~ t+ ton. to bivalent Co, and Nvas not completely reversible. The second wavc..Eij, S.CB. jar 10- Co'md shifting to more, pos. potea. !Y~ Co' u, had a dl~tbsulty at i Alals withfiiocr T e- mt- d Id oce - Martu 3 = Wh A&.it i.4 = r a r2 ' cr st VMVC, =std, with respect to that of the fit of 1.6 at 2 X 10~ljf~ Co to. 1.0 u;10-*.kf Co. Thif vrave "CorrespoiAs to the reversible reduction of the bivalmst Co Ao tmlvDJMt CO.' The formed In the first third'Waye. --L34 v. v"Tcxi I., lo-W. Co and shifting to., -*ith iocrca~g Co conca., appzared: per. patebtiah o Y a-V nt the higher cm=s.! It ProWbIY Cafresp( 9 to the f further reduction of piut'of the WnItat Co'-aad in dicates 1 ' ' ar of thd latter is 110t k~ lhat conapte tile coff ndin iptivated on =rUjo wrfa4e~. The'pro"e micitantsm pf,the- electrode Procip is t4borated and, colained in Wras Zbwuerm=,- ligand R. Y- themy K_ V Map 6-0 Distri 4E,2c Relation between the electronic structure of Iflorgansc; depolarizers and their polarographle behavior. V. CobalL k A NNek (Polarograf. 6stav C.A. akad. Prusim). 1460--7(IOUS); et, C.A. 52, _134&1a.-Cc-(CO~ (1) :11ve3 a reduction %mve at -0.35 V.* -Vs. sattl. calomt:l Clectrodc Cc(C%- which N the reduction product of I gives an anodic wave of the carre- Isponding 119-coulplex.st.the same potential and an oxid3- tion wave at +0,12 v. mt. S.C.E. The waveof I is Identical* with the reduction wave of Hg(Co(CONJI. From the po- flarographic behavior the cariclusions aboot the electrosic . "structure of the studi s b ta d d e su s were ma e n~ c Uj- i~ ", C e r i o cd c, 11 C': CK'Z~ Li 1 . Vi (" I-- Rclati3n be-tween polaro,--rapAc bc.`.avLo; . 1`1 V ol - 5 2, n o2, !~c 5 :Lf.e electnin oi -lectroc:u pi-oce: 3e-L: -:;, whicil: (n-2)f olectrol.-L take part. List of East 11j'Urircaii Aeceszdons (----d ) LC-, Vol. -no. 3, "arch, 1~5~, - Uncl . A- fi bill' 0 om '01"" 0 "C4 er a e cad t d - ~2 c.. i.. P-T ion 0, and 1~',h 6e,ed Cfl . w f of som yp* W 17- v..- - th di in th and. emi in 't,e = ~b- Plot - at. S miiar.~, 0 .V straig t line. Similarly, the vati s1ra' e e was W" 4 was of the Utl.. of these complexes Duo owed '=Wfy th plot. On the bub,31 this observation a model of the clec-* trode process was developed. In the course of 01C elec- trode process a change in the electronic configuation of the complex takes place which is proportional to the tetragonal ling cause split. A by the ligand X. The ligand X Influences idao the ligand to the trans position to itself. this babig more influenced by the,ttectrode field. S. R* CZECHOSLOVAKD~ / Physical Chemistry. Electrochemistry. B-12 Abs Jour: Ref Zhur-Khimiya, No 23, 1958, 76832. Author V Inst ot given. Title The Relationship Between Electronic Structure and Polarographic Behavior of Inorganic Do- polarizers. IV. Eloctrodo Procossos Involv- ing the Participation of (n-2) f-Electrons. Orig Pub: Chem Listy, 52, No 2, 214-227 (1958) (in Czech). Abstract: As a rule, the oxidation of Eu2~ions proceeds at Mo:r'q.positive E values than the reduction of Eu~rions, i.e., the reaction is irrevers- ible. The difference between the half-wave potentials of tho cathodic and the anodic waves as well as tho form of the waves depends on the background. Halides produce a shift in El/2 Card 1/4 CZECHOSLOVAKIA / Physical Chemistry. Electrochumistry. B-12 Abs Tour: Ref Zhur-Khimiyay No 23, 1958, 76832. Abstract: and also affect the slope of the waves. At high halide concentrations (e.g., 7M 5i2c cl- or 0.05M I ) the difference between the E 1/2 of the anodic and of the cathodic wave is so small that a single anodic-cathodic wave is obtained, the slope of which however differs from that required by the theory. A single reversible wave is obtained only in the case of ethylenediaminetatraacetic acid solutions. The current in the lower portion of the anodic and of the cathodic wave is of kinetic character fd-iffusion curreng at constant.E. As the time between drops increases the half-wave potential of the cathodic wave is shifted in the positive direction while that of the anodic wave is shift- ed to more negative values. The slope of the cathodic wave decreases with decreasing time Card 2/4i 57 CZECHOSLOVAKIA / Physical Chemistry. Electrochemistry. B-12 Abs Tour: Ref Zhur-Khimiya, No 23, 1956, 76832. Abstract: electrode and the central ion. The presence of excited EU2~ ions at the electrode is as- sLuned. Card 4/4 58 VIZEK, A. "Progress in the chemistry of complex compounds." P. 376. CHEMICKE LISTY. Praha, Czechoslovakia., Vol. 53,, no, 4,t Apr. 1959, Yonthly List of East European Accessions (EEAI),, LC., Vol. 8p No. 8j, August, 195~. Uncl. VLCEK ; KIJBAL, J. "Present problem of photographic chemistry." P. 365, CHEMCKE LISTY. Praha, Czechoslovakia, Vol. 53j.no, 4., Apr, 1959, Monthly List of East European Accessions (ERAI), LC, Vol. 8, No. 8, August, 195 9. Uncl. COO'. 4-TR Y, C zec Kilo slovakd a CAL,,GORY AB3. JOUR, RZIUlila-, NO- 21 1959, No. 74373 it U T.1 0 A Vlcak A, F,7:3) T Not given T i r2.1:1 Relationship Bet-R-een Electronic Structure and Polarographic behavior of Inorganic Depolarizers. IV. Electrode ProcaLsoaa Involvingr (n-2) f-Elect ORIG PUB Collection Czechoslov Chem Commun, 24, No 1, 181-197 (1959) ABSMACT See RZhKhim, 1958, No 25, 76832. CARD: 1/1 trons 59 vu,-!~x, A. "Relation between electronic structure and the rolarographic beiiavior of incr- ganic depolarizers" IV. Electrode -processed, in which (n-21)f-electrons take part. In German. P. 181. CCLLECTICN C*F CZEChCSW,,'j1J, C110JGAL CG1H~,fbV!IQTIC1'S, Praha, Czech. , Vol. 24, 111o. 1, Jan. 1959. Monthly List of East European Accessions (EEAI), LC, Vol. 8, No. 6, Sept. 59, Unclassified Reseflon kinetics of the decomposition of in ethanol solutions. AmOa4. VIM& (Tsc 41"0' -1 chen Akad. Wiss., Praffwef,-Jrn";R- 4-.-Rgem- 7~~94, 7 1959).-The polarographically . detd. over-all rate of decompa. of Coj(CO~ at 22 in EtOff soins. can tir 16, '2-67c CoHe b given, by the tctuition: riLte - Mki[Xil 7~ -.gCote(:6~1. Aere,X, Wan Idn or ruoL (Cl-~ J~H.. iHXH3',CN ctbioyridyl)foriningacomplex,withCo*+" ki Is the corresponding rate coast. In 46 absence 01 ocanplex-forming species the rate comstAs 0.3 X 10~1 we-*; From the stoichfametry and kinetics a *reaction mechan r6'i is proposed, the Ist arid rate-dctg. step of hi WW w at action of co~(Coh with the complexil es, to give co~co~x' which then cli3rM mates t CO),- and ~"O'(CUX. - -: , .:. 1: [chard M I a A -'D istrs-. 4Pc(i) .......... /7' V Substitution riactions of cobaltic cam Kuta- a (C-sRb adsorption Am qod J A . . . "r2 -9 N161-P ~6-A(IOWT---Tfic tate of redo IT ~ I . .. -AXI ions at a dropping Hg electrode varies with the [CarNH In the order SO,-'rC CIO,- < on ortintleltctrBol~~ < - < as shown by shift of the half-wave =tIal. At some min. halide coacn. CI-. Br-, and some- I- cause a new redn. wave to occur with a relative b ht Increasing with hafide conca. Ills Is attributed to a 11 rMA : ,adsorption catalyzed reaction at the HS sudke to l+* form a halide com l B i b f 1l P(NH ) ex, u o owix r # & , p y 'Me relative hei redo ht of this wave ives the reaction . g g .rate const.: Br- replaces X substituents In the order NOa- < N14 Lq F- < ozalate tm ONO- < OAc- < H&O < NO R M wl~ ~m . c . & CATEGCRY ABS, JOMs ITT "llop M10, PUBj, ABSIVACT -ia t,o 6lov ak Tized4up floe 5 1960,p No. VIcok, A. A. 110u ~ivllr. h e r(ClatLonship Between the Kipctronic 9truc[.u-.,-* Pol - I a n dt'L-Ic- I- c Behavior of Inoreani (; De- polarizers. V. Cobalt Carbonyl. j Collection Czechoslov Chem commun, 24, No 6, 1748- 1756 (195-59) t See RZhKhi-M, 1959, No 18, 63845. UPI: 1/1 VLCEK' A. Relation between electronic structure and polarographic behavior of inorganic depolarizers. VII. Determination of activation energ7 of electrode processes. In English. Coll.Cz.Chem. 24 no.11:3538- 3$47 N '59. (EMAI 9:5) 1. Polarographic Institut, Czechoslovak Academy of Science, Pzague. (Polarograph and polarography-) (Electrons) (Inorganic compounds) (Electrodes) (Depolarizers) BERAN, P.; VLGEK, A.A. P~larographic control of substitution reactions of Inorganic complexes, I. Reaction of AUC14 tone with ethylenediamine. In German. Goll.Cz.Ghem. 24 'no.1l.-3572-3578 N '59. OMAI 9--5) 1. Inatitut flu~r analytische Chemie, Karlsuniversitat und Polarogrphi- sches Institut, Tschechoslowakische Akademie der Wiseenschaften, Prag. (Polarograph and polarography) (inorganic compounds) (Ions) (Ithylenediamine) (Gold chlorides) VLCZK, Antonin A. - - - --- - - - - - -- - "Polarography as an Indirect Method of Investi-ation of the StructAire of Coordination Compounds," Prague, Chemicke Listy) No. 12, Ded 60, p. 1237. Affiliation: Polarographic Institute, CSAVI Prague. 66907 Do 64) 6 j 0 CZECH/8-59-12-2/15 AUTHOR: Anton:(n A. Vlvcek TITLE: Rea i Mechanism of Substitution Reactions of Inorganic Complexes-1 PERIODICAL:Chemicke" listy, 1959, Nr 12, pp 1139-1247 ABSTRACT: This article was given as a lecture on July 2, 1959 at a conference on inorganic chemistry at Bratislava. The chemistry of solutions of inorganic substances is basically the chemistry of coordination. The question of stability and composition of various complexes in solution has, in the past, been paid considerable attentions/ with the result that present knowledge in this field is, on the whole, satisfactory. Somewhat later and in less detail, the studies of mechanism of reaction of complexes in solution were commenced; they have practical as well as theoretical significance. The instantaneous reactions, involving inorganic complexes in solution, have been reviewed in the previous paper (Ref 1). The reviewer, here deals with relatively slow reactions. Kinetic parameter values are very often missing, eg temperature Card 1/5 dependence data. Recent collections of data suggest a 66907 CZECII/8-59-12-2/15 Reactivity and Mechanism of Substitution Reactions of Inorganic Complexes parallelism between substitutions In organic reactions and in inorganic complex compounds. The Ingold classical concepts of organic substitutions (Ref 2 and Eq 1). Nucleophilic reactions may proceed by two mechanisms -SN1 and SN2- In the course of an SN1 type mechanism an activated complex is formed without the participation of a ligand substitution, eg with a reduction of coordination number whilst characteristically an SN2-mechanism directly involves ligand substitution in the activated complex formation. In the latter case, the formation of an M-Y bond weakens the M-X bond. It is difficult to decide whether an SN' Or SN2 mechanism is involved. This is then considered further. Fig 1 illustrates the course of substitution via mechanisms SN1 and SN2. Taube (Ref 3) , using expanded Pauling models, differentiated between labile and inert complexes according to d orbit occupation. Table I gives the electronic configurations of labile and inert complexes after Ref 3. SNI and SN2-mechanisms are then considered Card 2/5 in the light of this and Taube's work is considered to be 66907 CZECH/8-59-12-2/15 Reactivity and Mechanism of Substitution Reactions of Inorganic Complexes of qualitative value only. The basic shortcoming of Taubels scheme is then dealt with. Table II gives the velocity of hydration_for complexes of the configuration d2d2d2D2sP3; kH20 (S 1) at pH 1; 250C (after Ref 3). More fundamental explanations of the relationship between velocity and structure has been advanced on the basis of Basolo and Pearson's (Ref 4) theory of crystal poles. Theoretical calculations of simplified examples have been produced and Table III gives the change of stabilization energy (in Dq units) for reactions of complexes of the transitional metals under conditions of the so-called strong crystal pole (after Basolo and Pearson (Ref 4) ). Activation energy of the processi Ea - (a-b).Dq. But even this theory does not suffice since it only allows a more detailed estimate to be made along the lines of Ref 3. The author advances the hypothesis, taking into consideration the connection between structure of the complex and its reactivityg that the activation energy of the reaction will be linked in a Card 3/5 certain way with parameters describing the given complex 66907 CZECIf/8-59-12-2/15 Reactivity and Mechanism of Substitution Reactions of Inorganic Complexes in Its basic or excited state, or in certain cases with those describing the change between the basic and excited states. The relationship Q = const (Ebasic - Eexcited) is found to hold for a series of closely related complexes (Ref 5). Fig 2 gives the dependence of hydration activation energy for various series of complexes on their excitation energyt a. Series of trans - Co en2X2 + H201 Q = 0.64; b. Series of CO(NH3)5X + H20, Q = 0.474; c. Series of Cr(NH 3)5X + + H20, Q - 0.42V. Various aspects of substitution are then considered further. Fig 3 gives the dependence of the velocity constant of a complex series [Pt(NH 3)4-nC-n] 2-n (after Grinberg, Ref 6). %HKI[PtC14] , B3 K[PtNH3CL3], C: [Pt(NH3)2Cl2 , D: [Pt( 3 3C11C1. The author claims that the experiml ntal dependences-found may be generalized and a hypothetical model process for substitution reactions Card 4/5 of complexes proposed. These are then examined in the 66907 CZEcH/8-59-12-2/15 Reactivity and Mechanism of Substitution Reactions of Inorganic Complexes light of the theories of Ref 4. The relationship between activation energy of the reaction and the polarizability of the complex are then examined (cf Ref 8). The trans effect (Ref 9 cf Ref 7) is then dealt with briefly, Table IV gives the representation of various stereoisomers in the reactions of certain complexes (after Basola,Ref 4).L The author deduces that these results show that the activation process occurs via two mechanisms which lead to different stereoisomers. Ref 3 envisages the course of the SN1 mechanism as that of Eq (2) to (4) for alkaline hydrolysis but the author concurs with Ingold (cf Ref 2) in that he considers the mechanism to be SN2- in this case. There are 3 figures, 4 tables and 9 references, 3 of which are Czech, 4 English and 2 Soviet. ASSOCIATION:Polarograficky" U"Stav 6SAV, Praha (Polarorraphic Institute, Czechoslovak Academy of Sciences, Prague Card VWEKJ A.A. The 6th International Conference on Cooridination Chemistry in Detroit, 1961* Vestnik CSAV 71 no.l:.130-332 f62. f v KONRAD, D; VLCEKq A. A; Czechoslovakia Department of Inorganic Chemistry, J. E. Purkyn6 Universtiy, Bmo and Folarographio Institute Czechoslovak Academy of Science -- Prague - efor all) Prague, Collection of Czechoslovak Chemical Communications, No 4, 1963, 17P W8--IM7 "Study of the Cobalt (II)- Cobalt(III) Ethylene- diamine System." KONRAD~ D,; VUU., A.A. Potentiometric study of the Co (II)-Go(III)-ethylenediamine aysteas CoU Ca Chen 28 no.3.-595-604 Ur 163. 1. Polarographic. Institutep Czechoslovak Academy of Sciences,, Prague, -!A R!~ICFL, J.; iOCI Set V'--j, A in5titute of Phyiolo,, Do J, ~y of m- estic lininnls (Ustav 1-Py6iolo-le Hosnodarslcyca Zvirat) A /-Ab- breviation not explaineL7 Faculty (F), College of AgriouYlture (ITSZ), Brno; Poultry ilescarch Institute (Ilysi-cumny Ustav pre Chov Hydiny), Ivanka pri D=aaji; Research Institute for Fodder Mater- ials (Vyziatiny Ustav Krmivarsky), Pohorelice. "Study of Energy Values of Poultry Fodder." I-Prague, Cesizoslovenska. -Pyniologie, Vol 15, No 5., Sep 66, pp 388 - 390 Abstract: Experiments were conducted with white Plymouth chickens L-5 weeks old. Intake of d-zy imaterial, protein and calories was determined. The intake and retention of the materials increased with an increasing ratio of calories to proteins, and decreased when the content of cellulose of the fodder was increased, 2 Western references. Submitted at 11 Days of Physiology of Domestic Animals at Liblice, 9 Doc 65. 1/1 L 1226-66 EWP(d)IT RM ACCESSION NR: AP5025846 CZ/i=8/65/059/005/0561/0577 AUTHOR: Vicekl Antonin A. TITLE:, Reactions of coordination compounds v SOURCE: Chemicke lists' - 59, no. 5, 1965, 561-577 TOPIC TAGS: coordintion chemistry, chemical reaction 'Abstract: All the reaetions of coordination compounds may be ied in 4 big groups: 1. The reaction of the introduction., ,or exchange of a ligand (primary change located on the central ,,atom); 2. reaction of a combined ligand (primary change located on ligand); 30 isomerisation reaction$ racemization ( only stereo-: ,,Chemical changes take place in the complex); 4- oxidation-reduction. ;ireaetiona ( the primary change concerns only the number of eleo- rons, but this of course can induce a series of further changes :in the complex part). Coordination reactions are.obaracterized by :,the following 9& the ligand entering into.a reaction remains a idiscrete structural particle throughout the reaction; the ligand is'~ Card 1/2 ACCESSION VR: AP5025846 a stable unit in the-given medium, or*Is eleitz-6nioally saturated ;in the original condition; the reaction produces coordination com- pounds with orbits Of Sigma symetX7. Only...reaotions that were -real- '!ized are discussed in the article* Orig. art. has 49 formulas -Heyrovskeho CSAVI Prague ASSOCIATION: Polarograficky ustaw J. Institute of J. Heyrovsky, Czechoslovak AcadenW of Sciences) SUBMITTED: 00 FNCL: 00 SUB CODE: GC NO REF SOV: 002 OTHER: 031 JPRS Card 2/2 VLCEK, Antonin A.- .Reactions of coordination comound3. Chan 19 I , - 577 MT 165- 1. J.Heyrov3ky Institute of Polarography of the C?.echoslovak Academy of Sciences, Prague. VLCEK A.A.. . " , , x ~., 7 1 ic rge r 56 '. . "OrIc ! t & 1, -- i n at, -,,- s a n~i r -- U.-I e n " b" .',' 'a~ '! :..I I -,,j. - by A.A.V!2ek. r"Ill ~,-- -rlf-;Q Z9 py ~ VLCEK, A. A. "file tal X -complexes with di- and oligolefinic ligands" by E. 0. Fischer, H. Werner. Reviewed by A. A. Vleek. Chem listy 58 no. 2.242 F 164. "Progress in inorganic cheinistry.11 Reviewed by A. A. Vlcek. Ibid.: 243-244. "Advances in inorganic chemistry and radiochemistry.'' Reviewed by A. A. Vlcek. Ibid.: 244. VLONK I A. A. "Introduction to ligand field theoryl by C.J.Ballhausen. Reviewed by A.A.Vleek. Chem listY 57 no.lOilO84-1085 0 163- VLCEX, A.A. -- "Absorption spectra and chemical bonding in complaxes" by G.K. Jorgenson. Reviewed by A.A.Vlcek6 Chem listY 57 no.8:854-855 Ag 163. IT 09 it 11 r L t 11 J) of A )1 14 17 ill A 11 1) It 0 A hi p It 6 F a to k of u $I w are I 6 -X A-A L 4, .6 4 - - Two siooiwtanocq~i iakft - "ns-72, low -4 WO), 1114-21(IM). 27, C0119911 Mau, diagram, are di-AIJ%Wll and fnf a Wluj;r wri" (if liquid. XaL~ and wilstj minbinalkals lll~wttickl (undallsentat, arr CV14vrd FRANK MAIMP611 Zee 00 t 0 0 f =00 0 0 - jog o 11 it w 94 of It it 91 11 to it 11 111 0 0 a 9 0 0 A 0 9.00 009 00000 004 0 0 0 0 0 0 0 0 a 4 0 00 0 es 0000 0 0 so a 0000 0 MRAD, D.; VLCEKj A.A. Folarographic study of the cobalt(Il)-cobalt(III) othylenediamine system, Coll Gz Chem 28 no-4-.808'-828 Ap 163. 1. Polarographic Institute., Czechoslovak Academy of Sqences, Prague. $1 11k w X x 0 r a a 4 Al a u 41 me 0 1 L 1- a a & 00 go, 'r 0 bqft It MAW21% I Ar Of B., IM 1105). A W. .00 ago '0041 00 06 00,3 coo moo got 2 voij see i 11 t I i I go* A%A-%L-h afULLUKUKAL LITINAIV41 CLASIOPKA140N 4O.&AT -10 O-V 461 ---- - --------- A* 00 0 V- -1 - 01431 am Mv is, it w naiveM fold fts 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.0' 0 ; 0 0 0 a 0 0 0 0 0 0 0 0 0 000, 0000 mindi0 0 000000 00 0 00 0 0 0 0 00000 0-0 Wo 0 0 10 -41 I # W 11 li 11 14 1 x a It 11 11 it a 13 14 it Al n A it . IV it u 11 14 ft 14 ua 0 n 1 1 U A w U o il -. . - - j 00 A to 00 t 00 00 0 t);Tolopmai and K. Ckgm- OkOf at the ph&" rWc A, 0 8343(N) in E.rislillh)(1 !*"*Inv Ku&fa -40 : 40 0 Joe 00 R goo 00 9 a . I L AWALLUP1,K-L LITERA"Re SSIPICATIC Uz =00 is At so 11 All L f I Od 0 9 1 Vf P I iJ Q Y It : ft it T K [g It if a[ wo n 1 14 * O 1 , A 0 *000 0 0 0 O 0 00 0 0 0 0 4 :o 0 f 0 0 0 0 0 0 0 0 0 0 0 0 09 ' 04 -o o, 46 0-076-41 * 0 a 0 00 0 Ill a * .7 7 1. u A !4 ll W I All 0 (A M fS A *0 C4 00 9 If,() FIM AcOll and the 1,41owlill, tl,.Iit,Al _It, 0 o* ir Two coitzisfts yiMses. VT. 119 effect of the Hot- o-d- NaC1, NaBr NAl, l,Cl ' and NJ 11 0 C ~l 4b It meister sexiss on beta"exteous equilibria In quaternary s ste s nd s t di f h . olllpar . in t1wir 11'"Ittal -b1, in it effect oil the incrra.,e of %of of Il o has, I j m a ame s u es o ase curses in tertlary y P systems. A.K,Vkck. CAttint-06w,11.196201.219 . l !,, ,11, I,, p floburisirr 5erwi: Cf - < Dr - < No, < I * so ish)(I(XXI), Affusth.vindphysicin- ns and Li , Nil.* > Sa' -- K, andCa- chern. analysis of coexisting phase-% in the liquid state was NaCNS hict,im-d the voil., whcrraj the rl-ni.jillilIg made to explain the conditions of heterogeneous equil. alts in lite ~wirs dmrAw,l the %,oL if all, ;,.,. JlhA' a * D of . of 2 liquid cnexi.%ting phases (cf. C. A. 26. 4=: 27 cOotliarriii to purr 11,0. The eff"t ill tudi& %as int, r - 0 1 . 'YM, 523S) and tile results obtained were eza,,,d 'o, hi~j _ , application to the morc complicated systenut in w] 3C mediate. Tbe diffetencvs in tile iiii-S Of 114.11~1,1,14 ICIIV i ni ... I, aIr relatively larger that. those of calii,11%. All - ,o , o it=!- all components war liquids under the exptl. cDnd chlorides ciamd. dectra.,rd tile I vo . of the 11,C) The eff t f I Imp,Aunt processes of bating and dyeing of kalker are invulved bemuse the can be Viewed fTOM the stand ot t ,v o ritrwic ~rivs results ront the tnutu~l f. 14- the sy,tein the tx .,~Zoo . I ow y p ~ %" Of 2 coexisting phs The rnan:!estation of lyotro te of which is the forniation of two coexiiiiiig pf laws -00 . . p wries in the fortualiOn ;if 2 rov%isting phases is studied by . study Of Phase Curves fur tfrnazy 5YSI,nis F. prr. 70t I ),v 00 si.ean- of phase curi- a~ v,.1. tiothirmt-t of pha,~, '-'diagrittinsresuittilut the Mit:4: Nl,:,CI) < Aoill ~~ Lwil 00 go Z; changrit. The following sy5tern% were selected: 11P Nit-Oil when cotr.,:x)ntnI% uid well. mtnj~tri! as 1, 00 C.l1,-Nfc,C() TIP-CjI.-Ftoll, 11.0 C.14 AcOll. RIO - ` : Ir effect oa lite incl,eam- of vol. of lip pha, , in 29recill,nt viath Ruthinu d ~Z h -,00 0 fl~~Ft,,O-MOH, llX1i-htrO- ,f,0H and FTO NIVIC ti vs. ( . p kem 26. jvj , (vosl) Th roo 00 . e Phac Chmact,-ritic, d, t th, lwllj%ll~ "i [he component not olily it, binary ~%st,.OIN 1,ut in lif,,jr, zoo Syllents 25 well. tile phaw CJI2tjc-,F;,tj,, dkj~lld 00 ~[,JlarcntlY oil the tool. structure of th, c,ollml. it btidge '00 1% 9-t up lx:twcrn the 2 scriningly op,xr4d itl,.4s f cvpr- -:6 0 puacle chemistry and of S)hAu- chernistry evolved Ly 00 Wald in 191A, r t a I I .11AILLI.P001. LITFRITLR( CLOSIP'sCliTICK It 00 oo .11, go 0, 00 It a Ita a M I v to -) it a t 10 U it it cf It N in K it C a IT It It J.La 0 0 to 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 700~ -44 0 0 o o o o o 0 o 0 0 0 v 0 0 0 0 : ::1 : : : : 00 : 00 4 1 A I I f If it If [A w Its 16 115 a B$Ndshvm 0 a It v u m a m u At x a 41 d Q a 14 or* w -Cf. Two coexisd _vvek .11 PUUG IisJy 27 412-1 2 LKI xiI Sol, . , W13). cf C. A. i6. 423", ~~ " 00 f ifi tku ad quatclomy 20. 49W~V. preasU a c OOMIL4 eat"s into cau- Rquad MM d b f I Sol acme wWwA P y ilts, AM f"vn 11so c"ditim" 00 ta"all of IA%w(w4 PhAwl. U1. 61 S 34 V 4 1 d ).- brufts 4M1 OW 9 W-8, 73- . ( 001, d !vm the lowtimial in dimpk qu-t-my systems. ct 4 emic l wis u h d 06 00 & tit aw . p P grem &W vzfam d ai Frank Marcib ra ich f i m . or quatenmy am cqmt see 00 0 00. cool WALLILInKAL LITIMPOL4119 CLASSWICA110h It I ti AV 00 It i u o 0 0 0 0 'T I 0 IV It a a a $11 it it It It tt it 0 0 0 0 0 0 0 0 * * 0 0 6 o 'a VIA Ali AI IN Owa " * o 00 00 a 00 0 4 Ce 0 0 0 * 0 * 0 0 6 of 0 0 ball 6 s 6 1 1 9 is 11 u u w u A-A-A-LAL'A P G* A f J Fl. jL A S IN - W L A "MIALLUAGICAL LITIM U Al 10 Allps W 0 v 16 0 10 10 14 A k IF x 0 M IS pw I I . Ill., on I I A 4 4 A f V*OC#tfA$ A.0 fIVIEWS act$ "Wet& 4d-Pd- 60tkM. A. K, VW-k. I. Obsur 9, 4". 64-6(Cid in .00 goo CLASSIPICA1100 ---------- 9 Z'- ve if G-d-i6---' is, 0 An& $8000 01 GIMP10003i'l u V, 11 as I M" dfto! 0 0 0 0 0 0 0 a 0 a 0 41D *!;;;;Oooooooooo *a I I 91111filow 09 A A -1-1- L. a -X 00 00 of 00 ti 00 *0 go *0 .3 000 00 so U 00 00 0 0 0 0 0 0000900009*4~ Is It 4 " 11 A N rr W 0 - A- I -1 9 1 1, -1 t z -M 00 Two coezMq phms. IX. COOlistAnce in U uld Mu" Systs- and p-dbWty of formottim Of SO,= -00 MU Wfifid 9WOMY 411116ramns. A. X. VWJ,. CA,.. -00 6w 10. 20(1-9(in English 2M)(1034f7-rr~. A. 28, loo M51-Conditions necessary for the formation of 2 .00 existing phases In ternary systems are described and it deduced that the two-phase liquid equilibria in thew. 000 stems cannot be suitably used for the stpit. of water '00 mpevients. The system waive -phenol-avione (Schreinp. skiers, Z. physik. CAwoo, 33. 711(111(0)) Is flimcoword and :200 r,/Yalidity of the following statement CtlLiCited! Thr 400 rmation of 2 liquid phases in the system of liquid cons. m t i di i d b h 00 s con en s t one e prewnce of at least line pjir y t . limitedly miscible rornpoeornt%. In such a system a " too mall Island diagram riots above the binary crit. mp. of the mint, 1110-Pht)ff and the curvt limiting 06 r helcrogrncous Arid dors not cut the olden of the amelc. Ile possibility of the formation of the -small and" diagram through the formwe of minute quantities zoo further component is shown on a tetrahedral chart. 00 tendton is ~~ oily drawn to the qlanifirance of l: v wavy wall in t t)lldxe dinstrams with respect in the 00 blication of Hall. of at. (C. A. 21. A7444). J. Ku1VM ) F e i ~ -00 1:100 ASM.SLA AtTALLUAGICAL UYINAT CLASSIFICATIOM '00 1960 31~CT *also, a" a., Is, 0 3 U 5 Al 10 s v ad o P s I x la o a a 3 te v 4441 no if. 10, tt be 0 a 0 00000000 000000 'agegoil 11116000006000000001 900000104090090 4064909100606046046040000#0000

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