SCIENTIFIC ABSTRACT TALIK, T. - TALIPOR, SH.T.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001754730010-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

/ffie reaction of 2-sub.stit-ated- -dediv-S&W of 4Z
.dine with nitrous acid. IV. 2-Methoxy4-amitto-
_Lutunopyq i
ka
pyridine. Tadcusz TaliL and Edwiu PL-tick (Politechni
WrocLaw, 1`6317ma)~~ocviiki Chvij7'3SM43-8( (A/ 2)
inan stuntuary); cf. CA 50, 120451; 53, 18954d.---4-Ajnijio-
2-methoxypyridine was able to be diazotized. 4-Ilydroxy-
(in. 1351, yield 59.8%,). 4-iodu- (bl, 106*, 31.7%), 4-chloro'-
(tit. 26*, b. 177-8*, 30.6%), 4-bromo- (b,, 87*, --iG.4%),
4-thiocyanato- (tit. 62-3', 11.2%). and 4-cyano-2-methoxy-
pyridille (1) (tit. 95*, 32.4%) were ubudiwil frmu th~ diazo-
lutlillcolupd. Thus, substitution ofa first-order group (no
double or setuipular boud) in 2-positiou made the T-aminn
group like a norinal aroma fica mille. Ilydrolysii of I g:,vc
* A. Kr~glewhLi--
oxyisoulvt it i I tic aeid.

TALIK, Zofia; TA-LIK, Tadeusz
On the reaction of 2-halogen and 3-halogen-4-niltropyridine
11-ox-ides with phosphortrihalogenides. Rocz chemii 36 no.3:417-423
1. Katedra Ghemii Organicznej I. Politechnika, Wroclaw, i
Zalaad Chemii Organicznej Katedry Ghemii, Wyzsza Szkola
Ekonom,czna, Wroclaw.

Ir
5/061/62/0-0-1/021/022/069
Ta.lil, , Tauleusz , Ta~ iK
U: Preparation of some of 4-nitro-pyridine N-oxide
1, 1 ".'u IP Arefe-rativny-.- zhurnal . '-:.h imi ya no 21 , 196 2
173, abstract
21Zh163 'Roczn. chem., t:. io, no. 5, 1962, 539-544 [Pol -
summary in cer.- )
'--:,KT: The action of a mixture of (CH.C0 0 and H 0 on pyridine,
2 2 2
a-picoline, 2,6-llutidine, 2-chloro-, 2-bromo-, 2-iodo-, 3-chloro-,
.1-bromo-, and 3-iodo pyridine (Ta--O. ~o-cwed by nitration,yields the
L ~L
'l-OXiae-3 of 4-nit-ro-I (11a-i) - Th!--, 3 -1r;,-. c t-u i:e of I Iq , i was conf irmed by
,conversion with aniline to the ef -~-,tnilino-4-nitro-pyridine (III).
50 g lk~ dissolved in 150 ini (CH co),)
0 150 mi. receives an addition of 30%
0
t;2()2in pomions, the solution is 'Left to stand for 5-6 hrs at 20 C and is
til(ln kept for 30 hrs at 60-65 0G, the excess of reagents is evaporated in
vacuo f.L 600C, the residu- is d4siolv,-i in 50 ml concentrated H and
L 2s0 4

S,A2611621000102110221069
;-'reparation of scme derlvativ,3s B"I 1 IB1 01
-deu in oortions to Lt .-.1ix, --e crated H.,SO
-.i. 'L 4 2 0 m I Z Q,~4
C.ima.nc,, sulfuric acid, and 120 m., conce-,*..r~.ze, n. ~-Z 'd
~ .-j k' 1.1~2); the mixture
90 min at 1`00- , cooloi~ 1,
- - nto ice, neutralized to
4-5 .4 1 t 11 s G 11 id , N la is separa
'Y 1705V ted with concentrated
.,0H, yield ui~: M.P. lb2(C (from LiKewise substance Il is
octained. '\yield in M.P. in 171)
155; C, 76.5, 156; d (here and
Welovi, 190 Lill 11 202 is addeu ;-tna trie mixtur-2 heated Cor further 30 hrs~
C-,-
,J) - e , 62 . 5 , 14 5; f , 61 5 6; V CrIH 5 "i 90-) (oaparated by
L 1',tC t i On W i t h k-iiCl 6--, . C, i 0) (obtsjLned
3
tG
!a' , r16 . ii -n Lh, eeluzion of 1 9 119, 3 g aniline,
ant,: 1`0 ;:-,1 alcohol which is oo 1 e (i v ttrs and cooled, III, C11 H 9 N 3 03' is
1.7 -, j,1.1). 0-
rQ:-,, k1cohol). Aria! c, 1-ously , !I! is
r, e u f roa 1 11i ani 5 g i~ n i I I n, 0 m 1 a I c o h o 1 by boiling for
;-,rs, jield 0.0 C. A v, a t rac " e r 0 t e o --pl, e -. e -~ ran a 1 a t i on . I

s/oai/62/000/0211/023/o6q
B141/B101
Talik Zofia, Talik Taat~usz
~_'%-ect o, perzi-j!,'ur~,_ a~;;~d on some 4-aminopyridine
CD1~:AL: Re"aratIvnvi zhurnalL. Khioiya, no. 21, 1962,
Y 173, bstract
~I'Zhlo"4 v. 36. no. 3, 1962, 545-548 0l..
- LP
summary in
am 4. n o py r J_ r, c1, 3-bromo-4
t': 7;hen 5-chloro-4- -aminopyridine (II), and
~'I ~' T .0 L into reaction with H S 081
1 2 2
tae products are (IV 5-bromo-4-nitro-pyridine
V a f A 2 - b r o in on i t r o - Tpy r L. d i nespdctively. Under analogous con-
ditions, 2-chloro-, 2-iodo-, and 3-iodo-4-aminopyridine do not react with
W I - -ic added dropwise
t' ')S"od 2o 50 iTLI 20,~~ fuming s u I I't, 2acid 20 ml H 0 is
2 2
UnUE!r C00iing by a mixture of icq and salt., then 2-5 9 1 dissolved in
7.5 ml concentrated H SO, "a introdu,~et4 at 00 C, the mixture is left to
2
stand for 24 hrs at aid neutrali%ed with solid
Ci.xd 1"'2

S/k'J61/62/000/021/023/069
Efi'uct of per.,u i fu ric i j on B-I 4 1 /13101

r t n e
p r e c i
and evaporation ci I he
f
t
S i Ve 1l t rOdIA C e d tne 0 vield 71.2~1~1 m.p. 25-26 C
2
l- 0 n ---' oo u 3y V
is obtai
ned from 2.F, v II
e, a M. ~). rj()-r .-0 ',V.~,? n 77' bro ~,
U'.j, t i to reacti n i t i
r1 0 W I
H so d S 0 row i 2 m 1 2 &,;'~ fuming sulfuric acid)

2 4
2 a ,
ob t a i. n e d , yieid from alcohol FAbstracter's
C' 0 G-., 1) , e t e t ra -is 1 a L i on

W=4CZC)REK, Jan gylwestar5 TALIK, Tadeusz
Preparation and some reactions of 3-bromo-4.5-diaminopyridine.
Rocz chemii 36 no.5:96V-970 I"
1, Katedra Cheraii Organicznej 1, Politechnika, Wroclaw,, i
Katedra Chemiis, Zaklad Chemii Organicznej, Wyzsza Szkola
Ekonomiczna, Wroclaw.

TALIK, Tadeuss
k, in X 4 R~- 7
Certain reac'iors o-f 3-:halogen-4-n-it-7opyrid e I'- d z;
I - I ,
chemii 36 no.10:1465-1475 t62.
1. Katedra Chemii Organicznej I Politechnika, Wroclaw, i Kated--a
Cheinii, Zaklad Chemii Orgaricznej, Wyzszu Szkola Ekonomiezria ,
wroclaur.

Or
dI jr~ r I j
te
C 7 1

TALIK, Tadausz
Some reacttions of 3-halogen-4-nitropyridines. Rocz chemii 37
no.1369-74 763.
1, Zaklad Chemii Organi,.,znej, Wy~mza Szkola Zkonomiema.,
Wroclaw.

TALIK Tadaut-z; TALIX) Zofia
Reaction of 2-hydraxy-4-aminopyridine with nitrous acid. Rocz
chemii 37 no.1:75-80 163. 1
1. Zaklad Chemii Organicznej, Wyzsza Szkola Ekonomiczna,,
Wroclaw.

IALIK. 1---dl.~u3z
i. 3 ~- -- A, --'= asid=
. I~j - -- =-
cli,-I-iidi "''t no"-495-4.97 363.
1. 'il,Klad Organdcmej, Wyzsza Szkola Ekonomicziia, Wroclaw.

POL.
'~,'Synlheacz ~oL2nWlpjLavalogs of p-arnhwulltylk "W.
11
PU
A
rm.
C's Pokx.
-
19U Eng ~~'.Q'y the KollwSchn"
method. modified by Afarasse (Ger. 73XO and 711,70).
2-amlno-&hydroxy-W)- (1). and 3--amino-"Aroxy-GUY

ridineca boxylk acki (H) have been prepd. I Is obiabW
F
n78.5% yield by beating 2-agnino4-hydranypyridim w*h
anhyd. KsCO, under a M atm. in an autockvt 34 km
at about 200% treating the mixt. with hot HsO, Sted"..
ki
d
d
h
l A
OH
it I
dMk
h
l
l
l
in
s
uct w
t
ac
a
c
'an
pptg. t
;
r
g
e 8ro
i
ld
l
t
C
I
CHCI
t
" d
d
o-
-.So
.
n co
ace
one,
H, . a
e.,
J, an
J
9'
-comp. 165*. By the same procedure (reaction t1m 7-9.
furs
) 3-amino-"ydroxy
isolakd an the
yridine yields IT
.
.
p
Cusalt, which with H*S soln. gives 57% free a. M. 9".
sw
Inhat
sL
,
Oinsol
inak
dC
BatkaelftaftW
l
H
.
.
i%
t.
&
,
.,
i
.
acti tubercle bacilli. Nfichad Dymift

TALIK, Zofla; PLAZEK, Idwin
Preparation of chloridea of 2- and 4-p7ridino sulfonic acids and
of 2- and 4-p7ridonosylfonamides. Acta Poloniae pharm. 12 no.l:
5-12 1955.
1. 1 Katedra Chemii Oiganicznej Politechniki Wroclawakiej. Kierownik:
prof. dr H.Plazek.
(PInRDIDINES, preparation of
ahloropiperidineBulfonic acids & chloropiperidinesulfonamides)
(SULFONAMIDES, preparation of,
chloropiparidinesulfonami.des)

of pyTidinesulfohydrozarnk acids. Z-. Talik-
tlTn!iTTZ, tPolytech., Wroclaw, Poland). k-,-% PA,~j-
Pharm. 12, 21 3--22(l956X English summ.ary).-2-,3-. d"d
4-Pyridiw-mlfohydroxamic Icids (1), (U), mcl (M),'resp..
prepd. by the reaction of the corresponding sulfony! chlorides
with hydroxylamine showed only a sciail tuberculostatic
activity in experiments i7i, Oro. Na (2 g.) is dissolv-~-d in 30
mi. -A~-- EtOH and added below 40* to 7 g. NH20H.FICI
OV):ni.A.water. To the jr ~ te red solit., 2-pyridinesultonyl
chloride [obtained from 4 g -ereaptopyridine (cf. ibid.
5_12)] is added in portioits Twlow.30* and the mixt. -:cpr 10
ruin., the F'.OH is distd~ invocuo, 5 Mi. water added thesoln.
heated w:th C at 90* and filtered, and the plit. cr~std. from
water to give 1, tn. 11 is rbtaiaed by
adding 13 ~. r; in 10 mi. oi water to a soln. of 4.25 g. Na in
60 ad. abs. EtOH at 40', filt,!ring off the XaCl. PddinE- 3-
pyridinesulfonyl chloride To the filtrate, filtering off IV,
evapg. the. filtrate and recrystg. the residue Gom water; 11m.
14D- '51' (decompn.). III is obtained similarly (-Io m.p. is
rep5.qSd).

11, k_Hoczni!~t herai I) no.
r-caw, Fclari~-:
SG: :-Ionthly inulex of E-East -~urcpean Vol. 7, no.
i.pril Y)5'

Synthesis of cetcain derivatives of thlocyanoxcetic acid
'hydrazide. 7-ofia Talik and Edwin Plaiek (kqL
Wroclaw, PoLmd)-.~dczzniki TWaii-.-J37 379-95C~
(otrm"In suintuaryj-Attempts to prep. NCSCIIICONH-
Nil, M were unsuccessful, but 3stable At r4rolleANCScHr
CONIINXI-111. (11), of I lv,-rc obtainediaA clescribcd hdow.
Into 3.0 g. I1hCII:NNI-Ij in to ml. CjIlON at -30' was
dropped 3A g. CICII,COCI in 20 ml. Lt,O, the mixt. then
poumd into 400 ad. H,0, and the solid filtered off and re-
crystd., front HIG-EtOH to yield 3.4 g. CICIICONIIN:-
CHR (M) (R - Ph), nx. 16-0. Similarly were obtained
the analogs III (R - vi-O~NC#114), in, -007 , and III (- R
o-HOC4110, m. 198-9'. 111 with KSCN in Me'CO gave
11 (It = Pit), tn. 251' (alc-), 11 (it = m-O!NC.H,), m. 278'
(AcOll); and 11 (R - m. 295' (dtfcompri.)
(C&I-14N). Ila (R = Pit) anti Ilb (R - n;-O~A'C1j1')
sliowedstror)gtubL-rculostaticactioii it; vitro. Doublehydra-
zidits of chiorc,, in. Ifil', and thiocyatioacetic acid, decorup.
2W', %vere also prepit. KrqgfmY--k-i-
+k-?l
(A/

r
TALIK, Z.; PLAZEK, E.
Investigations on 2-chloro-3,5-dinitropy-ridine. I.Exchange reactions
of the halogen atoms. II.Experiments comparing the movability of the
halogen atom. III.Possibilities of using 3,5-dinitro-2-chlorpyrifline
in investigations oil protein adsorption and amino acids. Bul chim
PAN 8 no.5:219-230 t60. (EEAI 10:9/10)
1. Katedra Chemii Organicznej I., Politechnika, Wroclaw. Presented
by T. Urbanski.
(Chloro-dinitrol7yridine) (Halogens)
(Amino acids) (Proteins)

:!~ ~, "M ~K:-Lt- -- ,.- -
. I 'i~~ - - r

TALIK, Zofia
Research on 2-chloro-3,t-dinitropyr:Ldine. II. Reactions with animes.
Rocz chemii 34 no.2:465-474 6o. (EEAI 10:1)
1. Katedra Chemii Organicznej I Politechniki, Warszawa.
(Chlorodinitropyridine) (Amines)

TALIK, Zofia
Investigations on 2-chloro-3,5-dinitropyridine. III. The relative
reactivity of halogen. Rocz chemii 34 no.3/4:917-924 '60.
(EEAI 10:3)
Katedra Chemii Organicznej I Politechniki, Wroclaw.
(Halogens) (Chlorodinitropyridine)

Talik,
8/081 ) 1600/013/015/054
B158/B144
TITL6: jubstitution of a halogen and a itro-group in 14-oxides of
?-halo
~-ij ob I ~1'ii L: heferativnyy zhurnal. Khimiya, no '/ 13, 1962, 245, abstract
(Bull. Acad. .Ser. sci. chim. , v.
polon. sci L
~J , 1"16 1 , 56 1 -565 )
ff
TE,~ T -. '-'or the study of the mobility of a halogen and the 110 nroup ill
2
N-o-lio-?,; of 2-halo,~en-4-nitropyridine (I 4-nitropyridine), t,ie latter were
0
NaOCH,, Lnd NaOC2H5 at 20 C. the NO 2 group being easily
ut~.d an the a11;ox~,1-;'-- IN" "Y
i e ha oGen was not very active under these
Conditions. In a reaction of 1 maole of the starting substance with 2
mole--s of' NaOCH3under severe conditions (boilind), the halo6en may be
I't"i,lace,d by an alkoxyl. In a reaction with Fe(OH)2 or PCl 3 (heating), the
11-oxides of 2-haioien-4-alkoxypyridines lose the 0'atom. Under the

S/081 /62/0001/0 13/015/054,
-and a BI 58/Bl 44
j or N-oxides of 2-ha-ioeSen-I are easily
2 5 2
11-oxides of dialkylamino-I, wnich by reactin., witli -eCl- in
r, i:r~nvevted to 2-dialkylaciino-I; the latter are converted to
~;::ino-4 -minopyridine) by ztrcn~,., reducing
.0,,yl,4dines (1! 4
t. "2 :1 IT-oxides of 2-halo~-en-I are reacted v,-it'-, ITH NH 'H 0 i,
2 2 2
J Ic orio 1 rious mixtur,.~_,~ are formed; only in onf~ case is it possible t a
1;,? t~' -,jxj.de of 2-iodine-II. By the et!2ods descril-J, the
ol-lowin.-_ vere obtained (product obtained, yield ;, m. p. in 0C
o ~;icra e ( s u:) ement s in brao ke ts ) are -iven 1; -oxid e of 2 -chi oro -
U
i O.K'. wj-ridine (117 4-Methoxy Pyridine), 84.1, 82 (from benzene-
lit]; IN-oxide of, 2-bromo-III, 85-4, 55, (from benzene), 145;
::-oYidt_ ol 2-iodo-III, 86.6, 89 (from water), 142; 2-chloro-III, 83.4
~~29-2500C)' -, 168; 2-bromo-III, 74.6 (b. p. 121 0 C/10 mm), -, 115;
74.6, 35 (from benzene), 154; N-oxide of 2,4-dimethoxy
pyridive, 72.1, 65 (froin benzene), -; 2j4-dimethoxy pyridineg 62.6 (b. p.
200-201 G C\ n -ethoxy pyridine, 66
Card 2/ .4 ), -, 159; 2-cKoro-4 -4j 55-57 (from

S/081/62/000/013/015/054
,Jub~~ f i on of a ha I o.en and a ... B158/13144
4 38 (from benzine), 115;
2-bromo-4-ethoxY PYridine, 0.5,
pyridine, 09.2, (b. p. 1450C/11 mm) 133; :I-oxide of
:7~ 'I j0 - 1, 74.8, 126 (from benzine-benzene), li-oxide of
62.3, 90 (fron benzene-benzine), -; 2-dimethylamino-I,
UuIrIZInfl-bonzene), -; 2-diethylamino-1, 75.8, 35 (from
iylamino-II, 62, 151 (from water, 216 (various);
Y (fro-, ac;ueouti alcohol', 172; N~oxide of
7U.7, 11 -
L
iju.b' 110 (vlar`ous; from watter), 189. The solubilities of the
enu::ie.%,ceci compounds in water, alcohol, C 6H6 and CHCl 3are given.
0
,oxide.; of 2-halo!7en-J'1I are unstable in air, at 0 q they can be
U
pr._-o.3rveu for a lonL; period, at 20 0C they rapidly decompose, and at 100 0C
tKey i-nite; 2-halo',i:r.-z!-alkoxy pyridi.nesare completely- stable. Results
azre ,iven of a quantitative study of ti-le mobility of the haloE'~n
(det-,rmin,~,d by Volhard's met.liod) and of the NO 2 group (conditiohally, fror,
' v~ - 1, 4. 0
- .4.,qun~ of NaOCH 3 consumed) in reactions with NaOCH 3 at 20 C and with
uailinb in alcohol and witn Nff(c 2 H5)2 (with boiling in alcohol); these
card -5/1Xj

S/06 I /6210U01O1 3/015/054
Z~ub ,, t i t u: i a n o f a nal oCen and a. . .B156/B144
'6r',e 4-*,'0,, ~-roui., -iz; considerably Tore reactive towards NaOCH
I I - u - 3
i.,j tL?e pyridine rinp, Of the halodens, in relation to
il~aGCH, t.,,e most mobiia~ -is C1, t",,e ie~tst mobile I; a difference in the
:;iooility of Cl, Br and 7is observej (at a relatively hit;h. reactivity) also
rEspect to NH(C HJ ; the most mobile is Br, the least mobile
2 2
6 refer,tices. lAbstracter's note: Complete translation./
Carfl 41/4

TALIK, Z.
Substitution reactions of halogens and the nitro group in 2-halogen-4-
nitropyridines. Bul chim PAIT 9 no-9:567-569 161.
1. Katedra Chemii Organicznej I., Politechnika, Wroclaw. Presented
by T. Urbanski.

TALIK, Z.
The relative mobility of the halogen atoms in 2-halogenj)7ridines and
11-oxides of the 2-halogenpyridines. Bul chim PAR 9 no-9t571-571+ 161.
1. Katedra Chemii Organicznej, Politecbnika, Wroclaw. Presented by
T. Urbanski.

TALIK, Zofia.; TALIK, Tadeusz
On the reaction oil 2-halogen and 3-haloge-,i4-ni-,.ropyridirz
N-oxides with phosphortrihalogenides. Rocz chemii 36 no.3:/+17-423
,6~.
1. Katedra Ghemii Organicznej I. Politechnika, Wroclaw,
Zaklad Chemii Organicznej Katedry Chemii, Wyzsza Szkola
Ekonoraczna, Wroclaw.

s/o8i/62/000/021/022/o6g
B141/B101
T ad e u s z , ~T a, ik , Zo 1* i a
T J'! 1,,7,: Preparution of somo d~~r-,vlltives of il-nitro-pyridine N-oxide
Re fe ra t i VnYY ZI-M rn".t I .Kinimiya, no. 21 , 1962,
I I - 173, abotract
5, 1962
21 Zhi 6 3 (Roczn. chem. , v. 5b , no 539-544 .[Pol.;
summary in Cer.
-X T
I.E. The actio--. of a m4xture of (CH1,00) 20 and H2 02 on pyridine,
a-rico4l-ine, '2' 6-luti dine, 12-chlcro-, 2-bi-or:I(J-, 2-iodo-, i-chloro-,
~1),rom"o-, and 5-iodo pyridine (Ia-l) , f-3'lowed by nitration, yields the
N-Oxiclea Of 4-nitro-I (11,a-i 'Phe structure of IIg, i was confirmed by
c,-,)riversion with aniline to the N-oxide of -)-anilino-4-nitro-pyridine (III).
50 g !a di-sgolved in 150 M! (CH 5co.112 C, 1~Ci ml. receives an addition of 30~
HI)G2in porTions, thu solution is ieft to stand for 5-6 hrs at 20 C and is
0",
~heri kept for 30 hrs at 60-65 ' , -he excese of reagents is evaporated in
vaGUO at 60 0C, the residu,:~ is riissol'i-~d in 50 m" concent--ated H 2 so4and
C 4i ~ - d/12

s/m/62/000/021/022/069
:~reparatlon of some derlvativ--?s ...
lilkl--,j in ~.ortions to a icnc-2ntrated If so C-0 ml 2~T,,',-
2 4'
furmin,- suifuric acid, and 120 ml conce~-itrated ENO (d 1.52); the mixture
;L Kept for '40 min at 100 c o,,.)
ilnikl poured onto ice, neutralized to
Ni th eo, id
N 11" 0,, T~a is separated with concentrated
C., if ,yield 65~., m.p. '1620C ( from wtttl-r) Likewise substance !I is
o .c,tained ~yield in vld, M.P. in 0 c! 5, 155; c , 76 - 5 , 1556; d (here and
e 0 -,v 501 i. 11 3 ail, Iff 0 Ls atilded and the ni-.xture heateo --or further '10 hrs)
2 2
19,' 62 - 5, 14 5; f C i I IN 0 (aeparated by
- 1 5
L
uh C'E'C' d"' - 5 i r il3 IN90) (obtained
at ~,.jj S L T I a) 56.a Fr ,T, ile ~;olution of I E, JIg, 5 g aniline,
~--id "G mi aLco-r-ol whien Is o o i cl f ti r0 and cooled, IITI C IT N C. i
9 3 39
e 0.7 'ruj-' alcoho'). Analogously, III is
A
an I L -I r:
-~/ot-tlned frort I lii-an," ci n 4 0 ml alcohol by boiling for
---s, yield 0.0 g. Abstrall-Ler's noLe: ComDlete translation.]
11,;.-, rd

5/061/62/000/021/023/069
B141/B101
T a 1 i k Z oi a , Ta 1 -L'~ Ta I
;,f--ect o~ uerqulfur-c acld on some 4-aminopyridine
derivatives
iefarativnyy ztairnal - 'KhA.L,,Jya, no. 21, 1962, 173, qbstj' -act
21ZhI6ij ~~Ronzn. chem, v. 36", no. 3, 1962, 545-548 .~Pol.;
summary in Ger.J.?
(1) . i-bromo-4-aminopyridine (II) , and
2-bromo-14-a-linopyriciine (Ilf are into reaction with H.S2081
are 5-Cii' 1 , 4
the 110 (T',j), 5-bromo-4-nltro-pyridine
products
V a,-.d 2-bromo-4-ni i '~ respec t ivelY . Under analogous con-
_cas , 2-chioro- , 2-ioqo- do not react with
S, ~i '7'o 50 mi 2&~~ fuming
2
unaor cooiing by a maxture Q~'
fal Conceiatruted H-So, 1C.
sland for 24 hro aL 203(',
su-ir)-u
;Ct? ;1,~011
acid
sait,
at
'0 mi if 0 is added dropwise
2 2
I dissolved in
then 2-5 9
00C, the mixture is left 4-n
,ind nertralized with solid
Carfi

S/081/62/000/021/023/069
E, 1, 1, o C tIo e r 3 u i1-1 r i C a Co n .3 -141/BlOl
I a t h e r ,and evaporation of the
4
e [I t 1-0 dl~ C6 t n e .2%, m.p. 25-26 C
C 0 M, D o I I n yield 71
rom Analo~-,ou3~-i V is obtained from 2.5 g III
Y n u 6 - o b r o u g, I i t
~i o into reaction wi th
u- H-SO ana 10 s"0 12 ml 20~i furning sulfuric acid),
2
V! -'s obtalned, yj-pld 7 ti - 71!"im rom alcohol't . FAbsLracl.erls
n 0 '. e :Complet-.e trans lal-,1'0"1
'2 12

TALIK, ZOfia
Research on tll- relat-ilre mobility of halogen atoms in 2-halogen
jrjridines and 2-halogen pyridine-N-oxides. Rocz chemii 36
no.7/8:1183-11"Q9 '0/2.
1. Katedra Chem-ii Orgariczriej !, Politechnika, Wroclav.

TALIK. 70tia
Certair reactions o--;' 2-halocren-4-nitropyridine. Rocz c' !--Mii 36
no.9~-1313-1320 162.
1. Katedra Chemii Organicznej I., Poli-t/zchnika, Wroclaw.

TALIKY Tadeusz; TALIK, Zofia
MOMMOOMM29MOI) i
Reaction of 2-hydraxy-4-eminopyridine with nitrous extd. Pocz
chemii 37 no.l.-75-80 t63.
1. Zaklad Chemii Organicznej, Wyzsza Szkola Ekonomiczna,
Wroclaw.

I
. d.med.naul, (71,
an '-'allir, ull. R-)-cpa,
-P.14, A.A.
L
bl' a b! o,-,,k use of lystenonp. Vest. khlr.
J J 41 n k
1:7 SSR 011--- me,2. nauk
rodskcy -rx
cy
Os, Tn n a

TA , :~, t*.. z ; RAFO I OLLD! I ~' , S. V. ; I K. A.
I cnveyor3 willh a loushing-roller ~'-ain. Ferm. --' a, prt.;m, "I)
1.
. 1 -. '
- - ( ,I I r-~j~ 1'7 . '
no. L,:3~2-33 164.
1. Ryazanskl,y likero-vodoclm3r
y zavod.

TALIKOV, !!.A.,
- -- . ..... .. - --- -
Fathop-enesis nf pathological processes in the kidneys in pulmonary
tuberculosis. Sbor. trud. Uz. nauch.-issl. tub. inst. 3:184-r-190
'57. (MIRA 14-5)
(TUBEIRCULOUS) (KIDITEYS-DISEASES)

T.1-LIKOV,
ala -s1
5, 4* 0
K af da~y
za
~,rcf. R I 1~ 7t-

YAN3.AY-FV,
^'in:i oanal-~m-1,:a!
Ag 16-2
(KfRA 17-61
Tz
bollnit~y np:~rlcrlnn~.j
prnf. Masumov: ,,',qv,,%7y vr.,ic- iasluzzh,:~rmyy vreac.n

TALIXOWA, Zofia
Chemical Abst.
461. 48 No. 3
Feb. 10j 1954
Organic ChemistrY
ciiew-l~ Zoflata~lkowa (1114hert
.. , ~ojdl, M -1
ItJ4-88(1U&3)--,TRe iotMoTTRj"oIps are reviewed:' Sb;tl"
t u tion reav t i of Is of ~Yrid I n e I -o x Id c (1), chetp. propettles *of
substituted 1. and reduction of the nitro deriv. or I with and;
without the eIcqvRge of M
nond. 35 references.
AdatnSporsyAski

CICHCCKI, T.; RUTA, R.; TALIKOWSKA, H.
The distribution of some hydrolytic enzymes 4n the z:ephridium of
the earthworm (Lumbricus terrestris L.). Folia biol 11 nc.l:
69-83 163.
1. Department of Histology, Medical Academy, Krakow. Head:
J.Ackermann, Ph.D.
-1
4

GOLDSCHMIED, Aleksand~r; RAKAISK&. Zofia; TALIKOWSKI, Waclaw; BODZINSKA, Irena
PIffect of 4-atra-oral bile on the course of infectious Jaundice. Polski
tygod. lek. 12 no-34:1319-1320 19 Aug 57.
1. (Z Oddzialu zoltaczek Kliniki Chorob Zakaznych A.M. w Lodzi; owczeany
kierownik Kliniki: prof. dr A. Goldschmied). Adres: Warszawa, ul.
Kas-nrzaka 17; 111 7.~klad Chorob Wewn. Instytutu Doak. i Specj. Kadr lak.
(BILB, thernpeuticuse,
henatitiag infect., intra-oral admin. (Pol))
(04PATITIS, INMCTIOUS, therany,
bile, Intraoral admin. (Pol))

TALIMAA,, R.Yu.
Data from a study of specific and nonspecific reactivity in
patients with tuberculosis of' the lungs during combined treatment
with antibacterial preparations and tuberculin. Probl.tub. 38
no,703-59 160. (MIRA 14t1)
1. Iz Institute. tuberkuleza (dir. - chlen-korrespondent AMIN SSSR
V.A. Shmelerg nauchnyy rukovaditell - d6ktor med.nauk F.L.
Elineon) MI SSSR.
(TUBERCULOSIS)

TALIMAA, R. Yu., Cand. 1,1edic. Scl. (diss) "Chansres of Allergical
U
1-'~eactLvlty In Patients with Tuberculosis of Lun,--,,s with Treat-
ment iViti-bacterial Preparations and Tuberculin," Moscow,
1961, 23 pp. (Acad. Med. Sci. USSR) (KL Supp 1-0-61, 289).

TALIMAh, ft. ~, med. m. kand.
An automatic spirograph without the -ater spirameter. Sveik.
Apsaug. no.309-43 164.
1. Liatuvos respublikinis tuberk-uliozes mokslinio tyr-imo
4-ristitutas.

TALIMA4. Ov- med in kand.
J,
An automatic spirograph from a common water spirometer.
Sveik. apsaug. 9 no.3:39-43 Mr'64
1. Tulaerkuliozes m.t. institutai;.

TALD4-Y T
i-~ i-ation of atypical :,v~..~rtarr ",)acteris. Zhur.miKr?,'ni,)l.
r' - ii 3un . 23 no,'P:95--,
gosudarstvenLc.,!-~ unIversitela,
;:identif teat i~-,u ~)L strains by b`oui~-,r. &

TA It , E. i's; Rr, I IPF, TK .. T A.
S-Itlidy of ~Uhe rathogemir promrties of sone fres~dy
eat,ercpathoge~ic Eacheric'hi~ col-i of varicue serolog-'cal t7p-as.
- 0-
Zhirr. mik-Tobicl., epid. i imun. 42 no.7~21-24 Jl NS5~
(RI RA 18. 1.11 )
1. Tw.--l- sk2-- y gosudarstvennyv universi tel
vi;

K:H:7
K
1 4 ani ezakric:.-vaniia lopasti na lr~i2r2kter-
-stiki avtoz: J, r~. osr.,, J, 314 diagm.
no. 3~16
o-,, r, n, 31
W* ')Iade tvls' on t'r,,n aercd-riaric ci.:tmcttris-
c s, o:~ nit iro.
no. 39(,
in Tibr-r-, cf

---
TALIN, A.A.
Continuous action horizontal sterilizers. Kons. i ov. prom. 14
no.10:23-24 0 159. (MIRA 12:12)
l.Izmaillskiy konBervnyy kombinat.
(Sterilization)

TAL lN, A. jl~ ; SLYUSAICOKO, If - A.
Production of grape Juice at the Izmayl Cannery. Kons.1 ov.prom.
15 no.10:6-8 0 160. (MIRA 13:10)
1. Izmail'Bkiy konaervnyy kombinat.
(IzmELyl-Grape juice)

TALIN, A.0.
Aseptic preservation of food in the United, States. Khar.prom.
no.2.-91-94 AP-Je 162. (MIRA 150)
1. Izmaillskiy konservnyy kombinat.
(United States-Canning and preserving)

7 GIUCo'l, Tit I t N,-- Yit, USH~I~Wi, 'z.P.
3 i -outbreaks nf -'otkints diseene in child-en's ins'titu-icrE
Scr. .,re` 19 r,.- . 12 -D 04L-P~t lc.,:g)
I
L, Iz Irstitutn vimsr.IozU t'-414 ',USSR i Illoskovskogo -blestnr?.o
klirlchesko,i~o insti'lits imeni M.F.
V1.9 0 f m 1 r E:k ^F:o

~-S~
ITSELIS, F. G.; YAMPOLISIUYA, E. I.; ZALPJIZO?-I, Ye. S.; MIL'NER, B. I.;
ROZENBAIN, G. I.;-TAL1US9AYA---A.j.
Focus of mixed diseases due to poliom,7elitis and Goxsacl-.ie
[viruses] in a children's collective. Pediatriia no.6:15-19
162. (MIRA 15:6)
1. 1z sanitarno-epidemiologicheskoy stantsii Moskvy i Instituta
pediatrii Ministerstva zdravookhraneniya RSFSR.
(POLIOMYELITIS) (COXSACKIE VIRUSES)

GRIVIRVICH, A.G., TALIPOV, B.T.
Sensiti'v-lt7 Of Streptojo a di a-:. a t Li a:, t 4--3 ~ al tal~es t --~ gamas
ray-a. U2,b. biol. z1hur. '? zlaa-43'42-&~ 36--', (KIRA I -
1. L-istitut bot-saij:ic--' AN E,-z-:SS&

KARG1111, V.A.; SOGOLOVA, T.I.; TALIP~,_V, G.~~h.,-
PlaF;ticization of crystalline polmers. Part 1: Plasticization
of isotactic polystyrene and polyethylene terephthalate.
Vysokom.soed. 1 no.il:1670-1677 11 '59. (MIRA 13:5)
1. F1.ziko-khimicheskiy institut imeni L.Ya.Karpova.
(Styrene) (Terephthalic acid)

0~7
;.',-r Tin, V. p Academician, Sojoiova, I. and Talipov, G
TITLE'; Struc~.ure formation in cryatolline Doly--tyrene
R DO D I ~.'t L natil., SSSR. Doklailv, v. 142, no. 3, 1962, ()27-(,')28
X'I' :The -witn~)rs studied the formation of supermolecular structures in
crystalline, isotactic nolystyrene. The sanple .,,as fosed onto an object
.-lass, brou--htt to test -temnerature (120, 145, 1750C) in a thermostat,
and the strLict(ire formation was investigated and n`iotographed in polarized
light .,,it!, 20() - 600fold magnification b.,,.r means of an !-IOH-8
microscope. The structure formation vias found to be a comDlicated orocess,-
riot ceasinl- '.'i ith t~-,e formation of spherolites. Snherolites both grow and
agErel-ate. ~t hir7h temnerature and orolonFed crys tall i zation, the number
)f laroztl, cEntero is small, and regmlar spherolites are formed without
disturbance.,~- ..it low temperature, the growing rate is low but the number
of conters is lar~,e. in this case, ag-re-11-tion to bands taken place
'learth 25 - 5-0'u, vL,Jth 1 - 120~i). So"Ierolites united tf.) only

2) 0 2,:, 2 ""D
11027
r-1; s t Ll e . . .
ri So in c'~ne so, u n nae arc- r,-)rz-.ed
t hi e -1 e b a n-11, z; i n o, i p I am na a r e o rd e I, e i b, .-1 1 r
ODS! L 10r.
L!, superlm-po,-.ed larainae die', not coincii,ie. T,,je 0,. CrygZalliza'-ion
has "he same efftc' on thle formation of sur)err,,o1ec!i1o1r sLr*ucture as
temnerature 11-nut, -ilus, systerns of a desired structure can be prod~Jced.
No molecules o~- uiclecule oackaFes bUt ~i.olierolites of tne order of
ma-itude -)f co'lloitial n-irticles act is structural units in ool-,7,-.er
S,ystems. i-, -7imilarity ~%ith t~,.e formation of gels an,34 is assu
~ Z- ie 1 31 med.
7'-e re a re 4 refe N'!Ice s So vie t and 1 n.-)n-Sovi e t ~ The reference to th e
I,.- n S'jj;j.-: e r), 1 r I C, I t i r ea: I F, a s Co I c, -e; s - F D, i n n u s so G 7o r - t
A S'S Fj k,(-) - ns ti Lilt J 1. Ka r va C
cz~ie,.~icnl lnsf~itute ~:7eni L. Ya, Kar-.,-)-,,,

S C,
r4 /2-0
57 P C
AUT 'IORS Kar~,,in, V.A Academic,-an. Sozojo,j3, T a n;,~ 7-
TITLE: Structure formation in plasticized crj5t.alline I S
P r--R 10 ~ I C A L :Akaaeaiiya naul- SSSR. Doklady, no 4j
T-'-XT: Investigations of the supermolecul-1.1. structure of
polystyrene /D-kN, 142, rio. (1962)) shc;-N--,d that secondary llrur*,ui-~7,
bandsor lamellas., composed of spherolites, developed be-,ween '!0 ar.,--- 2'r-,--
The effect of ulasticizers on structure formation ana. mecharzi~-%al
of polistyrene (PSt) was now investigated by the same melhod -;;t
and 175C The following data were founc. -for the spherolite d e -.s 10 rls
(in microns): ti 1 Concentration of plasticiz by
Luration )f Ini er, v C, laz
crystalliza- Pst A
tion. min 8 20 15 2~; 12 1j3
10 15 11 i
30 8 60
55 -~5 C,
92 67
17 110 70
0 40 300 230 2 60 3c~ C,

S 2.,~ 1 -11 2, " C
Z%j;77,Are formation in, 0; 13 0
A cr,~ ty I chloride ; B = dimethyl 1-1-h-thala t T h,
ar. it: iz-~ of the spherolites
ion o[ t-inds or 1~jmellas , especially abovi~ -VC b R i .11.7 ~J
The ~;ffent of plasticizers was less marked
075 2~5()C) since under such conditions the
i it-, non-plasticized PSt The
c v -- a n ed Lncr-easi-n~; plasticizfr corten- X va
i 4- t 1;3 Ian d .1astic.zed PSt showed only sli7r.~ -J,-ff-----S
the r-ffec~ of cla--,ticizer does not consist'. In a C1,
inc lo' the s;~herolite' of I b Ut
cryst,ill structure
q 102-1 C! S ~ ruc tur(--- f orima t ion T h . s s o -S, a
o u ci a r:/ - s t
st rentr',11 r.-h :ch was linves t i :,at ~~d a t a mq- ra - ur e
vitrific-ion tem,.:erature.. There are Z, filsurel- ta'ti a-,
refercnc-?s-
AS'SOCLMM F--ziko-k1-imicheskiv insttut -n L. K~ar:
chemical Institute iLteni L Ya K a L,::; v
5 UB Y IT T.-:"D Ocf ober 26 , 1106,
C.-I r -~ - ~ 1

ACCESSION N'R. T1,007979 S/0190/63/005/012/1809/1616
AUTHO?S- Kar,-in) V. A.; So-olova, T. I.; Talipov, G. Sh.
T'-TLZ,.-. Supermolecular structure of plasticized and n n, plasticized crystalline
polystyrene
SOW~CE: Vy%;,-soi~coi-iole~ctLlyariiyi,,ye soyedinentiya, v. 5, no. 12, 1963, 1809-1816
TOPIC TAGS: polyrar, polystyrene cryst;iliine, polystyrene, ?las'icized crystal-
line polysty-ri:,,ne, plasticization, plasticizer, Secondary stnucture, -Ilobule,
spaerolite, bundle, rod, supermolecule structure fLormation, plasticized polystyrerw
,:,o:!chanical prope-:,y, poI'Irriker meeftanical property, plithalic acid dimetliyl ester,
cez,yl chloride, suparmolecular structure
~3511'.LLICT: 1"11P, SLIP erimo'16cular st.ructure of plasticized (dLimethyl-phthalate and
cet.yl chloride plasticizer) and nonplasticized cr-jstalline polystyrene has been
stucied in ~cmnerature intervals fr~m 110-215C, arA at crystallization durevions of
10 to 2.50 m-inutes. The s-,ructure-foriaLn- process was observed under a polarizlng
microscoDe ',,aN-6 with a 200-600 rragm, ation
A ne,,r type of structuralif zation vas
discovared, in wh--ch spherdli~es serve as initial structure units, commensurable
Card 1,/'

A~--ESSION Nit: APL,307979
in dimension -.,rith the colloidal particle size. It was found 'that the plasticizer
has a substantial effect on the nature and dimensions of crystalline 2.01yrar
secondar- U U
y structure, and a definite correlation was established between plasticized
polyir,er macrostructure and its mechanical properties. Orig. art. has: 16 micro-
photwographs and 1 chart.
A,"~5001AT1071'1: Fiziko-11dAmicheskiy institut im. L. Ya. Karpova ( Physicochemical'
in"itute)
SUBIKI'.MD: 24A.)r62 DATE ACQ: 2ojan64, ENCL: 00
SUB CODE.- MA NO REF SOV: 004 OTHER: 001
Card 2/2

r7. r i-;,-:
11+3 - 14* Sl 60,

SUKHOVA, M.N.; ZAIROV, K.S.; GVOZDFVA, I.V.; ANDRETEVA, A.I.; NMULIAYEV,
D.Kh.; TA.LMV,-,M.Z.-; MDSUNOV, V.B.; STOROZHEVA, Ye.M.; . '.MSONOVA,
A.M.; SHAMIRZAYEV, N.ru.; AKMURZAYEV, T.A.
Fly control and its organization In Uzbekistan. Med.zhur.Uzb.
no.3:3-14 Mr 162. 0 (MIRA 15:12)
1. Iz TSentrallnogo nauchno-issledovatellskogo dezinfektsionnogo
instituta Ministerstva zdz-avookhr'anerdya SSSR (dir. - prof.
V.I.Vashkov) I sanitarno-epidemiologicheskoy organizatsii
Uzbekistana (glavnyy gosudarstvennyy sanitarnyy inspektor-
kand.med.nauk K.S.Zairov).
(UZBEKISTAN-FLIES--EXTERMIXATION)

KHAMRABAYEV, I.Kh.; TALIPOY, R.M.
Some results of biogeochemioal- (geobotanical) recearch in- western
Uzbekletan. Uzb. geol. zhar. no.5:3--il. 160. (MIRA 13:11)
1. Instlt-ut geologii AN UzSSR.
(Uzbekistan-Ore deposits) (Phytogeography)

- TAiJPOV, R,,',',.
--- - -* Is
,11-4--~q!-~3zicE of ~~-e r,-4' metals in the so--
P.11.-; P',ar,~.q of thc- . -nd .ala,-h regions (Uzbekistan), Ggo-
k-1--AmLLa Mly 164,, (%1IRA 18,-7)
.I. . I ta'a ell Gec~--'opr/ bind G--iophysics, Ac&de.-jr :f
Sov! -14- SO,71ii'i R-ftil""bl 1-.

TA.I,IP',)V; 3.
` e 1,; -,rejsl' 2n
1.1.1;i-,;?r 3 or 'he petrol,i,rn and ga!i f I - - .-i r,." ',n9 'a! ' ~. dr-11, -
. r,
lzv , lrys , vineb, z a -r~ - nti '~. ~ '- as z 6 r0, '. ` ~ 'I-! - !
I -~ . ~1. ~. - I /
1. Mr3s~rov:3,Kjy recftekh~-mtiheskoy i gazovoy proaVshionnosti
im,

i R'OE.Ov, V
Waters and brines of -~he Mle-sozz ~,i
'Pajik Depressic;n in connection w-t-
Nefl,-~gaz.geol. i geofiz. no.12:1-'-.
1. Moskovskiy ordena Truclovogo Krr;~.
i 3ftekhiraichesk(yjr i gazovoy prc,my:-,h ;n:

TALIPOV, S.~ VAGIN, S.B~; SHUGRIN, V.P.
Gas content characteristics of waters of the Mesocenozoic sediments
in the southern Tajik depression. Izv. ys. ucheb. zav.; neftl i
gaz. 7 no.10:15-18 164. (MIRA 18s2)
1. Moskovskiy institut neftekhimicheskoy i gazovoy promyshlennosti
Im. akad. I.M. Gubkina.

TALII-'C;17, S.
Bromine a.-.d lod-*ne conient of underground waters in the I-tuilbarek
group of oil and gas fie.7a's. Dok-1. AN Uz. SSR 21 no.9:44-46 164.
19. 1 )
1. institit, geologii i razrabotki neftyanykh i gazovykh mestc-
ronhdeniy Gosudarstvennogo geo-logicheskogo komiteta SSSR.

PA." ux I u
v G I U' TX. -A--
--- , A
r sell ]JUN DU PA 3.1w 414241 ad
I i I -

T 0. u n

6
* Alt
o12
*0
0e
0

0 0

jad .1 puv

tj~110;vd~s joi ua4al
wav it! .41N
9-0,014 PUV IV tue
d
"
I K Pum VI) XUGJJ OU it) U014vjv

"tuol')
oil) . 98 Kol "N8H'11
.1 riv .%XVIQ
Mix? -jtnfl)-..k"j vuvj'
~~
6oduwa eawaU 10 -a
-Vuv tvaTu'~R3 UT 00
00
00
.00

00- 00
Ir

-
-
-
I W-M, W w 00
11
5
4 W
y
" 11 " 19 T r n
09 is* 0 * 14 4
F
i
0 0 go 0 0 0 0 0 0 a a At A
mmb~~~ ~

A
0 0 19 to 0 0 0 0 * to 7 0 ': I ~96 W air -1 -W1
0 0 0 0 0 4 _~Jrmivl Tele a 0 0 to e 0 0 t 0 0 a
1 a I 1 10 1, 11 It U is as iris 192111z; D24is hzyxz~ I)JI &In on a. 11 is 61
C A I P -k-A-A-A-L a-A r . Q. It 1. 1-M. V., LK X- T . L 14, K " W Et 1-1- i~ J-' s J- -I -
O*tmisminatim of jalunsimum in the (Wallis W Cryout..
IV. T&ns"'v &mi h. 'ndipa,v. /.",kaw L,h. S. ;.') 7
tHM-Al was 'trial. both its KaAIF. And "[F, In
drig. Al as NaaAlFs a tirfifolf *MI. ol .1.4% NmF An.
41#04111 to ppi, all llw Al I* eddril in tile Wit Slid Altrr
1 -tillifulf4l. Thf Olm mailli. is
1 2 his. IW "mit"N Air 14
shaken with 0,4% NO "411. &fill "rottiltis"I. All" 2-3
I -r Willi 'Wlr~ jar
-urh andling 1,
until live all 1:14) Ito ,
wt. In order to effect Coolpleir plain. tile %Alio of N&F
AICIisboutdla atkn4tti.5-7. The variall-rus bet w"n
t be called. and nd Na.AIF, ranged from O-MVd U ().OtrX)
a. its expts. in whicial the solos. were filleted instrali of
the diffg. at.% twtwern the caled. atrid found
Ns&Alp. vasird Iran" 0.11414114 to 0.11OV-4i g. In them rapis.
t he plat. anti filter palwr lur ignited in is I't crucible tivri a
stualf fliune without melting the trial. fit adding AIC4
to N&F it was found that if The ratio N&FIAICIs is It.) the
ppl. conmarts prwtikallv entirely of Na.AlF.. Thi, ron.h.
tion prrvailed up to a Nsl-'IAICI, intio of 40. In drig. e
thr Al a. K.AlF, the method of Adding K F in the AICI.
was not applicable brvmoj~ liar rrm,114 obtained wrte 14.0
low. In adding AICIO to the KF good results were obtained
with a KFIAICI, ratio of 12 and higher. The diffetences
0 0 9
0
44
J1.
.31,
'31
0
0
0
between the AI#Osas taken anti found experimentally varied
from OAN)l to 11) 011(r, 9. In drig. At its the presence tit
tit the following procerfurr wm.~ adopled: A inixt. of Al
..d He hkilaides . adl-f 1. A N.F j.. jil,l. go 7.$-M)
mi.. the soln. is thoroughly mixed and After 1-2 hri. the 7
-Ali. is carefully siphoned off and the plat. together with
Imurt of the moln. is erntrifugrd, thrice washed Willi 0..5%
NaF muln. and then with All. mic. (I - 1). The pill. is tit"
SO-IL A OITALLUNGKAt LIT111.1UNI CL
and ucit.11H " N&.All'.~ The ma%. difference betwern
the exill and ralat-d. NasAIFA was 1) IWO a. it. Z. K.
.."1, .1. 4.1 a,
I a -0-a 0 -4 -6 -1-
0 0111010111,1111 all we MOP, it.
0 0 0 00000 a so 0 9,411010 0 4 a 0 0 6 Of 0 4
I I-
- - - --
0 4 0 0
&j a) .3 P
-60
ago
1:1
age
Iwo*
i tool
see

1. fl t. t, It of Ii m I v it u I) w 11 4 It 4 19 It v I ) a ro
r u u 1 A
j L I, 1 0 N LE tv It k 11,
, , 00

tile dry res.,hic file f-1111114 MIMI.. 1. 00
00 4 F%PfX
Wrl`f? Al~j I1vtf,kktj,,Ij I,, file drill d III, ..Iy.
i:
Na.Al . and .I %, ti.
*
00 atilt IIXI
fill- -ly "I m 'd ill, -all
00 Ill,(

00 VAI And V

0 q0titt'llity f tile doobli, Iloofl,tva of shintintiell arid 12 NW, 11 7MI. It ?'do, if ojj~,, Ilk
'
t
l
the basic fill-tall I I Al'Almr, .11,41 I
ml
i'M 1'. I
l, -1V .I JV ..(
00 11.14, 7j t11:1111). - All HLI)II
1- t
*
,
I", tile Inepta of NA.AlF., KsAII;. milli at-11 :-I
, "it., If 0
041 J; v.Wfr.Ik,fId exactly Ilk tht,ir Ili.- %afi,- I.., ill, _IV. Ilk,
On o -Nil,
,:; IzL,011-1 ill It thvim-tat
IkvI1
Ih IlehlIvhkk,4,NII_AIF.t,'
-0,111tv kill, 1" 4
-
,
i - " 1, 1'.0- Ili*. .0. -
I I
It-m trVII. A -1-1 ii..,t Ill.. 09
00 l
m
. 11.1 hall I~Cl, I'll"lled
, I1,
Ait ~- 'I'I if
00 .
,
....... .
1-1 Ilk, allksly.l. "I
d ..1 lilt fl,li,hir *,j~ Jim- 1, 00
u
4 '.1 lit" .1 I'll, I
d
00 '
.... ..... a 0*
00 r K. 1,10 1111-Y v,pl, It'll

g lillittly - t"guther, kir,", tqml z-.* 0
e
0 E uIld K,AIF. fill, -1v ~j ", 11 Ill, _
1116

DO w-v ad, I., 'let file anit. of INA and X by zoo
3 ,bl,. And 3 MfVr-
'
elll
_ A" W. W Henn

.10., A. A-
VpNai %J 4 t1*9
.

to 0
7:

el A, .0 1%
1`101 Karl Ireq 4
1 4 '11 Aa I k a
40 a I :to 1 4

n*
an
0 0 0 0 0 0 0 0 0 0 * 0 4 0 0 0 0 0 0 0 0 0 a 4 0 0 0 0
0 0 0.0 0 0 0 0 0 0 0 0 * 0 0 0 0 * 0 a 0 0
to 0 0 a 0

0

a 11 r
44 A 1 4 V'i v A 1-4 M be (A Lip
"

00 Selliaratim W fitaxilurn (rain aluntInum and
fluodiles. Sb. T. Talipov and Z. T. Stdclkov.
-
7iiiiiii4sps Lab. IJ
Asiatic State Uniij
(IW).-It is proposed to utilize the differenci
:0 for NajiFs. Va.AIF& and NasPeFs in scpg~
AlunclFe. Towp.TifrO1TiAl.&ddtnthcneu(t
AIC4 and TiCl,34 times " much.NaF a4 requir
00 AIF.-. Filteroff the NaklFppt. and wish with 4
-oln,nnd finally with EtOll. Filter and drv to co
00
To the filtrate add IIC1 or HSO,.
alxmt 50 w1.. and ppt. the Ti with cuplerro
'Vith 211- cuplerron soln.. ignite, and weigh
'
o
00 , Fe can be sepd. fr-n Ti with the Fi
similarl
y

09 Na,FtF.. In the filtrate, the Ti can be dctd. I
. to dissil nff the F as 11,1411., is
11",A)" evap
f'
-.1., of 7
09 00141141f 0 0 O'w
I
a with
Middle
816-19
n x4y.
i from
w4n. c4
o Gwri z0 0
-~ Na F
. wt. at ;00
-ap. to
Wish
zo o
Ti(-)~.
)td. as ZO
adding
finally
-A.

f
A

t:00
zoo
lie
['r 6,9 5, u K it It If 64 kL* n I An L 0 IW 0 0 il 1 9 54
0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 a 0 0 0 0 0 o;0 0 0 0 0 * 0 a * 0 0 0 0 0 a 0 0 0
0 0 00 0 *to 0 0 0 0 0 0 * 0 000 09-0 00001060460 000 0000000 00 0 ii~

TAL-IFOV, SH. F.
28936 Potenpiometricheskom Titrovanii Ftortdov. Soobshch, 2. Zavodskave Laboratoriya,
1949, No. 9 S. 1031-34-Bibltogr: 9 fiazv.
SO: Latopis' Zhurnallnykh Statey, Vol. 39, Moskva, 1949

nc;
MonthLy Llst or Russtan Accessions, Library of Congress, Unc 1

S h i Al"T I P"'t
Ob
Mnl-fl~h Toljc~,,--tv Zn, -I, C:), Cv, Cd
v P-:,-!,Itst.,.rii Rotshkh Kolich~:estv Khn-x. D(,*:-' -'y --Ilk I /I cc:~, low), T;Q
I ' ".-9 zyu.-- -., 3U,byek. Ya---?ibliof-r: s.
7,7' 21

TALIPOV, Sh T.
U'V_ -

t
l Ab New method of "titheab of Sh. T.
.
-
.
s
Chemica I - .1 MOW
141;m3fond
Vol. 48 No. 4 _
D a MISS Z.Z. K.
Feb. 25, 1954 27-9(in Russian).-Pure CrO. (40 ir.), 240 10% HF, 17 g.

eniC Chemistry
Ilior glucose, and 30 mi. EtOH, added in that order with aWita-,
tion
until a s
ot test a
w
filte
h
d
g n
r paper s
o
s green e
,
ges, gave
p
CrFj.3H.-O in the soln. The latter was coned. an a steam
bath to a paste, stirred with 50 ml. warm HIO, kept over-
night, filtered through a Pt Bfichner funnel, washed with
EtOH and cold H-0, yielding 85-90% of product after 2
recrystris. Purity ofOO.60% was established byanaly.4is.
G. M. Kosolapoff

W-WWWWwwwwave V 4V 0- dc
00 a 0 0 0 0 0 0 a a OW 0* 0
Sal II . 1 4 1 4 1 4 1: it 11 it 11 1& it 4 HI V It A )d 7) )a al It U u U At U V is I* of it it di 0 .1 C 0
AAL 11 _1~ tI_j__A 6 a N 11 9, A I A U IL-1., I AA N U W Uff i I A I k I ft 1 0 A it
00 '. 1., , II. .(,- I HE, 0101 ,S - I 1 -1 .- , . ; 06
PNOCISM ko
4
Potentimettic titmdw of f1wddes. Sh. T. TalijKry
f
tntl 1. L. Teodorovich. Zolbky. L.~b. 15. - Z;4i4
-(1949).-In the potentiometric titration o( F mith FcCls,
00
so A
00 1
go x;
0 0
go
00
90
the potentkil break Is not precisely at the equivalence 00
Itaint; it should be located by a graphic method given by 00
Chirkov (C.A. 41, 37W). The size of the break can b.
Iniprovol by TreodwON invilloel (C.A. 40. 1117*) ljy
"filling 0.7 ing. tot PcClt 1wr tit). Addii. of NjWl and KJlr
al.- improves the tritgnitude of the Imptential ljft~jk. lo.
dides; must be ul~nt but Br, sulfate, and nitrate do not
interfere. The FcCls soln. should be standasdized directly ROO
'4gailitt known NAP soln.
dZ
A I A. I L A otTALLUIRGICAL LITEUTURE CLASSIFICATION
................. ...
oolt
00 It. A
UUAt
: n p P, It It
0 9 9 0 01 91 : : : 0 0 0 0 0 a a 0 ale 0 0 0 Ole 0 0
000Ogg! 00 0 0 0 0 41 a 0 0-0 0-00*10 0 0
00
0 0
760
'100
i40
SOO
00
E Z 00
S V PW 0 10 V If W 0 All 0 11 1 V
0 0 0 0 0 0 0 0 0 0 4 a 0 0:
0_0 00 00 9 go 0 0 0 0 0 0 oj~

Polonflonisirk
r.,iiixiv aod i.
Irrif-ml(IRM, ti C,wl. 4), OhMI, Ill,- I--'
Fe'll/l/ell with tile shirpro poicalki WrA i-
t3-5. addn. oft).1 fill. of ~oln. whirli i~ 0,11:1.1 .11 1., 1
,1,10,W2, Al in Fecl! per lu-~.Ifl fill. of tr,t -111.
"Ol ffiv. 'ful. irtentlal break at tile
tltratiofl~ of "If'. ;Which 'Ire AN)m 'P.2 J/ In fill"ll-Ir'.
T)rPical fitratior, curv- a.- 41-11. G M. K.

TALIPOV, Sh.T.
-
Certain general problems in the analytica chemistry of flourine.
Trudy SAGU no.15:67-84 '50. (MLRA 9:5)
(Fluorine)

TALIPUV, Sh.T.; KHAD YEV, V_A.
,
PhyBicochemical analysis of ternary aqueous solutions consisting
of alkaline earth and magnesium fluorides and alkali metal fluo-
rides. Ternary systems MgF KF H20 and K9F2 -_ NaF -- H20
at 200. Trudy SAGU no.15:89-100 150--. (K[,RA 9:5J
Ovluorides) (Solution (Chemistry))

systems of
Tor ftFr-KF-H3O Md likli't-1110-1111,0,
V. A. Kh4derv (Central A~Ln St,pt,,
Zkur. Oblikkel Xhim. (J. Gen. chelm!
20, 774-01UM). J. Gtit. Ckirm. U.S.S.R. 20. 8I.3-21
(Esigi. trAnklation). --The ternary systems were inv"11-
pied by Analyzing %aid. wpbm and wet rrsidUCS L4LCQfd-
in . list. 23". So doubic
the Sc upenwitevt methoil. all at
or siplid voins. art bruped III either vstcoi. Thr sol%.
of I;aFl in KF and in N&F was dctd. ai coucn_,. of al"Ij
fluoride up tip 0.5 .11. The cxijtl. result, algrrv well with
those prrdictril by the Debyr-Iffickel theory in its 2nd ap-
pruximation. Valurs for KF conco. (.W)arta for the m4%. of
PbFI (.11i ;are. rmp.: 11.0, UZI X I.W, x fil
d.;h) X 111--; 5.0111 X 10-1. 1.60 X 111---; 7.5 x
III -; WMOI.22 X 10-1. Thevalues-btainedfurtheoly.
of PbF, in NaF are %uniliar. 11. Terisary syslems ScIF,
KF-H,O md SrF,-M&F-HO. Ibid. 791-M.--No double
-ialo or solid "n.%. are formed in either systeen. the dia.
grairw beinIg qUJlitAtiVCIY it]CntiCUI with thoic for the coffe.
,juividing Ila minlid, 864 -v. of.,;rF, wua %tudivd at coucu..
,,( N,iF And Kv Up fit 11-411 Jf. Vafuv~ 44 Null cookli, ('11)
.,nd StV, "%. (.11) am. rc.p 11,011, 1) t12 X If)--; 1.905 x
111 4.51 )~ III. .; X 11) 'J'Atl X 111 1; 6AM-1 '-:
1-1 11.3 X 141 -; I ARM X I() A) 41 X 111 1, IWA 111~
with KF it,, inzit,&r. Arild J. Nfilkf

h SIN)" 111,111Z
111 ant!
flu 'A :;Ik.IIlfw ~:!rllj v LillI
Iollmv ni fill!"I !,I.1
Ind strolltillyn flllwit!!~ :volium fltwl V:t

TAJAPQV, Sh.T.; ALNTIPOV, V.Ye.
Investigation of solubility in the system c1hromium fluoride-sodium fluoride-
water at 300. Trudy Inst. Khim., Akad. Nauk Uzbek. S.S.R. 31 2o6-13 15z.
Mi 4? no.22:11930 153) (MLRA 6:3)
1. Uzbek icad. Sci., Tashkent.

T.LIFOV, Sh.T.; ti.NTIPOV, V.Ye.
Separation of large quantities o--- chrcni= fror. s:iali Guantities of zinc,
copper, nickel, cobalt, and cadmium. Trudy Inst. Khim.' AVmd. Sauk Uz:)ek.
S.S.R., Inst. Khim- 3, 214-22 152. (MLRA 6:3)
(CA 47 no.22:12106 '53)

T 7-
P. F.
c. 5oi.te Difficut.t to Dissolve Silver Salts in Sol'utions of 1.he
;q-,P0, -LINJK14-11,C) Fuld A(,,,,rlo,, - Fr - H G -i t 2
4 211"01; 2
T
Dol-I AN Uzb SSP, .7~,c-. 5), 19q2, pp 42-44
abs
54

T,,LIPOV, Sh.T.; LNTIPOV, V.Ye.
Investigation of solubility in the system aluminum fluoride-lit~ium fluo-
ride-water at 25'. Trudy Inst. Khim., Akad. Nauk Uzbek. S.S.R. Inst. Khim.
3, 223-9 '52. (MIdIA 6:3)
(CA 47 no.22:11929 153)

~~eterliuftiati6a 6f fluorine in insolubfe' fluciides by tall
method of I %.V., TanTTR-ev, Sh. T. Tall Z 'el-
kova, and T. B. Amirkhanova G,,,-.
7&--82LJWbZ). el. C-4. -
27, M.-W ell is bear me i was studied br detns.
of Cal?,,, the ahs~ error. wis about 'Of. The f;lf6win-
modified 'metlind -is prnposed~ Mixlyi- x, of fluorid;
wunple wid I g, fLmisilivin In it 100-hil round-bottonlrdt
Collimaed with it druppint funnel. mild
condenser; add M fill, of 12N IlrSOj through t e funnel a d
then passair into the raixti while the,flask is heated. The
distd. UtSU?si3 collected in a ffrLskcontg, KC]. Afterdbttm
is complee (as shown by a terup. of 13V in the flask and-by'
cooling (if. the delivery tube) any HSO,-in the di3tillate is!
oxidized with Is and the color is removed with NnzS:Os; the
K~SiF, is neutralized to a incthyl orange-Indigo rwmfinei
end point, and -then thiz distillate is. titrated tu a pfienol-
phthalein end point, Ak`ith this modified method the erwr
s. on: natural -
averaged only nbotit 0,307o,' resWis ofv detti
phosphates approxinitated th6se*by -the-Th inethod. Errors"
tend tobeneg., since the main _~Ourceaf -_rrorjaincDrnpIcW--
distu The changes in Ille method. (use -of
P ~,Mprlll i , -,
oz-,sa,ge ef air, inctrasiug the rtrut.'of If--SO,, cl
the'accuracy, shortened-the di~tn. time_and simplified:
treatruent of the distlill6te.,~r (11-65 mg.) was detd~ as.
above. Malcolm Anderwa

. : , . t. 1: z-_ ~r ~ --~- -.!z zi, z ,. -.
~ f ~,, - ~ ~ I -
- . ~ .
t ~~ 5N .- . -I-

~Sh.T.Tallovand

:en 0.
qa
4, 01-30
0
(
~'
`o
~
~
1" Na).sv&c phiced In tubes r Vol.
t
icns.
C
~20
ng.
,
l
n the
t 251) 1 tta
Qf satd. (Nff4)3AlVg'(!.66 g./1. a
-,olni. were centrifuged 4-5 mim T hu rna uids
were i1ccarned avil the ppts. were washed. 3-4 thncs~ with:
then 2-3 times with 1: 1 a1c -11-0. The
ppt3. ivere dried. to 120-30* and weighed iv; I&Afos Orr-
lite), Tljcmcthcxl.isripidahd,wmparableitia=um~yto
Oic sulfate method, as &vis. on mirabiIR6 I*- both methods
showed. F- ions, given hetv by hydrolysis of OrMWIF.,
%SCRs the snly. of Na3AIF,; thc presetim of 0.1 male/l. of
I? Mthices the %oly. of Ni;Alirq from I-PZ,.'< 16-3 (in Pint
11,0) to 0:3 X 1" molc4/l. Presumably the presence of
this metho(l.M
otlicr alkrdi metals intrrfercs with d.
.
-IMM

- . f II -)- ; ". . . . . . . . . ;1---
-.v 41- V
-,--/ 71 1 , 0 ~~/ - -,) -11 j , 'k t -, - - --

u s PS R
Ill. - Cf Slightly Soluble Citypr ellm Z
le, se'litti,)II-S of the sy'sterns: AgP0~--N&jIP0,--H:0-
0
id AF-P0. -K.IlPC,-fI.0 at 25 " Sh T T H yand V. F.
I',' -'. D"U"Ll. Akq'L It? 1453.
-.TU I; Kkim. 1954, No. !78-45--ne:
~olv. of A."'K., wo-i ht'I'lic-d ill sklilli. vf N41111,04 ;!nfl K..-'
HPID, ill c,in-wi. of 10-1-11 1,. ~mn. Thu ~olifl phaqv at all
(if Ilte ~itl%divd k:'.11 SI-Wrai, led rG pure A;:J10..
soly. (" * )I'ml oll ilwr~'it5ing t1w cr'jwu'
la! OIL z.) 10-1,11 b,It :11crca~4A :.t highi:r
I,:-!-wt o' Ag-l'u, irwrea-,vI from I _N*5 X 10- 1 to
ill 0..~-t'jf ull'I tc. 1.17 X ill
1; At t in 1e thc act Mit , prod ovt prau-
ifid Ivot Tik'~ 'wtiv;tv codt. mun caltd. vAL11
%i,t rif r.,- 2w,

cf* Smne Difficu-,-L-to-DI!3oolve Silvcr ~n "",lutions, ef
:..,l er Dokl AIN Uzi) ISSR, No 11 , !~-z
J, I l'i T
n
ab s
r,4

TALIPOV, Sh.T.; A V, K.S.
in memoriam Boris
'53.
(CA 47 no.17:8428
Georgie7ich Zaprometov.
153)
Kolloid. Zhur. 15,223-4
NLRA 6:5)