SCIENTIFIC ABSTRACT TITOV, A.G. - TITOV, A.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001755820016-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

A
TITGV 5 r, . -1.11 .
Tito-v --.i.. G. - YA region of colored stones," (The Illmen state forest imerd V. !.
leninj -Georrafiya v 5:~!-cle, 19LI5, No. 2, - . 2-;-Y-F
SO: U-453b, 2~ Oct 53, ~Letopis 'Zhurnal Inykh "tatey, No. 16, MS)).

17., -i nrf., n';'I -.1J, zrt-- gm, r,
i r irT
rlpnr fika iT,- all" ,

TITOW,--A.I. [T~tov, A.I.] prof.
Ionocomplex mechanism of nitraticn of aroaat~- and unsaturated
compounds. Wiad chem 15 no.12:741-811 D 161.
1. Panstwowy Instytit Naukowo-Badawczy Organicznych Polproduktow
i Barwnikow w Moskwie.

TITOV. A.I.
Primary loss of weight and some features of water exchange in
newborn infants. Vop.okh.mat. i det. 1 no-3:19-23 XY-Je 156.
(MLRA 9:9)
1, Iz kafedr7 gospitallnoy pediatrii (zav. - daystvitollny7
chlen Akademil meditsinskikh nauk SSSR prof. A-F.Tur) Leningrad-
skogo gosudarstvennogo pediatricheekogo meditsinskogo instituta.
(INFARTS (NAMB11))

TITOV, A.I.
Chronaxy during the first days of life in infants born prematurely and
at term. Pediatriia 39 no-5:11-13 S-0 056. (MIRA 10:1)
1. Iz kafedry gospitallnoy pediatrit (zav. - daystvitelinyy chlen
AMN SSSR zasluzhennyy dayatelf nauki prof. A.F.Tur) Iseningradekogo
pediatricheskogo meditsinskogo institute kdir. - prof. H.T.Shutova)
(NNRVOUS SYSTRU. physiology.
chronazy in premature & normal newborn inf. (Rua))
(INFANT, NEWBCRN, physiology,
chronaxy (Rua))
(INFANT, PRMATURX, physiology,
same)

FUn.TNTSOV, V.I., nolkovnik mad. sluzhby; BARONOV, V.A., -p-olkovuik mad. sluzhby;
T)olkovnik mad. sluzhbv, dots. ; FIALKOVSKIT, Y.V., Polkovnik
mad. sluzhby; SM.IRMOV, K.K., -)olL-ovnik mad. sluzhby, kand. med. nauk;
DOVZlb4NKO, G.I., polkovaik mad. sluzhby; DIVN39W, P.G., polkovaik mad.
sluzhby; GORYUSHIN. G.S.. T)odpolkovnik mad. nluzhby; SHC~EKOV, N.I.
podnolk6ifiik mad. sluthby;,ZMK, Ye. G., r)odpolkovnik mad. E;Iuzhby; BUTOMO,
N.V., maycrr 'Ged* sluzhby; P]BOBRAZNEBSKIY, P.V., mayor mad. slnzhby;
TUMONOV, K.B., mayor mad. sluzhby
Clinical manifestations in subjects exposed to prolonged ionizing ir-
radiation. Voen. vied '. zhur. noi.2:40-43 F 157 (MIRA 12:7)
(RADIATIO11S, effects, A
clin. manifest. In subjects exposed to prolonged ionizing
irradiation (Ras))

TUR, A.F., prof., zasluzhannvy deyatell nauki, otv.red.(Leningrad);
VCLOTOV, A.H., dotBent, red. (Leningrad); EVASHATA, L.G. , dotsent
red.; KOTIKOV, Tu.A., prof., red.; LIBOV, A.L., prof., red. (Leni~-
grad); MALYSHEVA-H&SIKOKOVA, Te.S.. dotsent; red.: MIRONOVICH, V.K.,
dotsent, red. (Leningrad); TMUIOVSKIY, S.D., prof., red. (Moskva);
TITOV, A.I., kand.med.nauk, red. (Leningrad); IIATAROVA, N.V., red.;
LIVS11TS, D.A., tekhn.red.
[Proceedings of the Seventh All-Union Congress of Pediatricians in
Leningrad, 1957; abridged stenographic report] Tmdy VII Vsesoyuzno-
go s"ezda detskikh vrachei; sokrashchennain stenogramma. Otv.red.
A.F.Tur. Leningrad, Gos.izd-vo med.lit-ry, Loniiigr.otd-nie, 1959.
654 P. (MIRA 13:5)
1. Vsesoyuznyy suyozd detskikh vrachey, 7th, Leningrad, 1957.
2. Deystvitellnyy chlen Akademii meditainakikh nank SSSR (PGr Tur).
3. Chlen-korrespondent Akademii meditsinskikh nank (for Torno'7skiy).
(PEDIATRIGS-COITGRESSES)

TITGVj A.I.v kand.med.nauk- POTANIN, N.V.2 kand.med,nauk
I
Case Of erroneous diagnosis of --osinaphilic reactions in rhildren.
Sov.med. 24 no.U:I-U-114 11 160. (MIRA .14:3)
1. 1z kafedxj gospitallnoy pediatrii (zav. - deystvitellnyy chlen
A14N SSSR prof. A.Pi.Tur) Loningradskogo pediatriohookogo meditainskogo
Instituta (dir. - prof. N.T.Shutova).
(=INOPHILES) (LEUK124IA)

TITOV, A.I.
Erythrocytometric data in anemia in premature children. Vop. okhr.
mat. i det. 6 no. 1:22-25 Ja '(A. (MIRA 14;,4)
1. 1z kafedry gospitallnoy pediatrii (zav. - de7*stvAel'v*y -.
chlen AMN SSSR prof. A.F. Tur) Leningradskogo pediatrichookogo
moditainskogo instituta. (dir. - kand.med.nauk Ye.P. Semenova).
(INFANTS JfREMAVM)-DISEASES) (ANEMIA)
(ERYTHROCYTES)

DYMSHITS, L. A., prof.; DROZDOVAP M. V.P dotsent; BELEVSKIY, A. G.,
kand. med. nauk; TITOV, A. I.
Lesion of the eyes in marble disease (Albers-Schonberg disease).
Vest. oft. no.2:52-55 162. (MIRA 15:4)
1, Goopitaltnaya pediatricheakaya klinika (zav. - deystvitel'n7y
chlen AMN SSSR prof. A. F. Tar) i kafedra glaznykh bolezney
(zav. - prof. V. I. Grigorlyeva) Leningradskogo pediatricheskogo
meditsinskogo instituta.
(BONES--DISEASES) (E;YE--DISEASES AND DEFECTS)

TITOV., A.I.; BARYSMIrKOVA, A.1-1.
Chlorosulfichlorination and ---h! orosullfochJ orinat ion ,f
ethylene. Conversion of -Ihlotoetharm3ulfinic acid 4o
'Itio ethe:?. Dokl. AN SSSRP, I. - 'j I
51 no.l.-139-1142 II
(MIRA 17,8)
1. Predstwi-leno akadamikom M,M. Shem7akin-ym.

AUTHOR: Gitell, P. Titov, A. 1.; Sizova, M. V.
!TITLE: A method for p-r-)d,-lc!n- B-chl~)rallryl fal~-n-! -4-*~~il,.~r,-~~-"I-su,.h.Inq~,. 1 -1 S,~;
N.D.
;SOURCE: Byulleten' iz,Dbreteniv i tovaniyL-h znako-.,, no. 1'~65, 20
TOPIC TAGS- aklyl phosphine, chlorinated organic compound
1ABSTRACT: This Author's Certificalle
4r-
n-n
SLPMITTED: 014E-=c62 OC GG
Cart!

SHILOV, P.M.$, doktor tekhn.nauk; KRIVOSHEYEV, A.Ye., doktor tekhn.zlauk;
DEMIDOVICHI N.S., kand.tekhn.nauk; RUDNITSKIY, L.S., kand.tekhn.nauk;
FLOROVI K.V., kand.tekhn.nau-k; SHAIPOVAL, I.M., kand.tekhn.nauk;
OLEYITICHENKOI V.G.' inzh.,- ZAIKIN, N.A., inzh.;_TTTOY, A.I., irzh.
Replacing alloyed steels by high-strength cast iron in manufacturing
machine parts. Mashinostroenie no-4.,59-61 JI-Ag 165. (MIRA 18:8)

L 5409-66 E~.'T(l),"E,,IT(m)/i/giP(t)/DIP(b)/DIA(c) IJF(c) JD
ACC HR: AP5027386 SOURCE CODE: UR/0181/65)'007/011/315913162
AUTHOR, AbrLpyan, 1. A..; Lavrov V. P.; Titov 1.
ORG: Leningrad Polytechnic Institgto (Leningradskiy politekhnicheskly Institut
im. M. I. Kalinina) TT
TITLE: Secondary emission of germanium bombarded along various cyrstallographic
axes by potassium ions
SOURCE: Fizika tverdogo tela, v. 7, no. 11, 1965, 3153-3162
TOPIC TAGS: semiconductor single crystal, single crystal, secondary emission,
_germanium single crystal
-~~ 71
ABSTRACT: The ion-electron emission of germanium sin le crystals is studied to
determine the effect which the crystal structure of the target has on secondary
emission. Germanium specimens were bombarded with potassium ions at energies up
to 7 kev, and secondary emission. was measured as a function of the angle of inci-
dence. It was found that the coefficient 60.1 (the ratio of the number of ions
reflected from the target at energies greater than 0.1 kev to the total number of
Card 1/2

L 5409-66
ACC MR: AP5027386
:primary particles incident on the target In the same time intervial) has a strong
Airect relationship to the temperature of the target. At 7500 %diLth primary parti
,,cles in the 0.5-1.5 kev range, 60.1 = 6-7.5% at angles of incidence between -30
.and +240.
The experimental data show that the angle of ion incidence affects se-
.condary emission in the semiconductor single crystals In a mannej7 similar to that
lobserved in the case of metals. It is suggested that aU single crystals regard-
!less of conductivity type (insulators, semiconductors and conductors) or type of
i -
~chemical bond should show a non-monotonic relationship between the angle of incl-
t
'dent radiation and secondary emission. The authors are grateful to ff. A. Yeremeyevi6-.r
and N. N. Petrrmwlov constant interest In the work and useful camultation. Orig.
lart. has: 2 fig
[SUB CODE, SS/ SUBM DATE: 23reb65/ ORIG IREr-. 006/ QrH REF: 003
VK
!Card 2/2

L 18754-66 &C(l)/:-24T(M)/EWP(t) IJP(c) JD/JG/AT
;ACC NR: AP600377(0 SOURCE CODE: UR/0181/66/008/001/0111/0114
1AUTHORS.~ Abroyan, I. A.; Makarova T. N.; Pukshanskiy, A. L.;
itov, A.
JORG; Leningrad Polytechnic Institute Im. M. I. Kalinin
(Lening.radskiy politekhnicheskiy institut)
ITITLE: Excitation of electrons In aermaaiu by alkaline metal ions
-f, V/I 15 ') ~- 7
-7
SOURCE: Fizika tverdogo tela, v. 8, no. 1, 1966, 111-114
TOPIC TAGS: germanium, single crystal, alkali metal, ion bombardment,'
electric conductivity, pair production, electron interaction
ABSTRACT: The authors investigated the increase in the conductivity
of germanium single crystals upon-excitation 'of electron-hole pairs
by lithium and sodium ions of energy up to 6 kev. The induced con-
~ductivit, was investigated by a pulse technique described in detail
earlier 4TT v. 4.. 27191 1962), The target preparation orocedure is
also described elsewhere. To compare the pair-production efficiencies:.,;,-
of electron and ion bombardment, two guns, one emitting electrons and~'-
Card

L 18754-66
iACC NR: AP6003770
Ithe other ions, were Installed in the apparatus. The germanium used
was n-type with resistivity -u38 ohm-cm. In all' cases when the Ion
beam struck the surface of the germanium, its electric conductivity
increased. The total number of electron-hole pairs excited by an ioni
of given energy before It Is completely stopped In the target is e3-
timated with the aid of Fermi-Dirac statistics at -500 pairs when
lbombarded with 3-keV sodium Ions and v2000 pairs when bombarded with
Mthium ions of the same energy. The number of pairs is-found to
decrease with increasing atomic number of the bombarding ions and to
increase monotonically with increase in the ion energy. The values
l
Iobtained experimentally agree with the theoretical estimate. Orig.
;art. hass,..3 figures and 2 formulas.
jSUB CODE: 20/ -SUBM DATE: Oljul6.5/ ORIG REF: 004/ OTH REF: 001
2 2

TITOV inzho
Y
Compensation of
capacitance of
Vest. TSNII MPS
try with the aid of 'he
the 701tage diEBY=4,~~ - .
the DPR (two additional wIreB-ra,,-I) .3ystem.
24 n0.6:40-43 165. (MIPLA 18-9)

A S 1 C11 11 AP5021~',!'
A U"11HOR -Gitel', P. 6. ; Titov, A. i.; Sizova, M. V. 4.1
TITLEE: A method for producing ~-chloralkyl ~--Ikenyl-') _d-irhIer,~.-ph-sph; nes
SOURCE: Byulletenl izobreteniy i tovarnvkh 7,naYov, no. 13, 1965, 20
TOPIC TAGS: aklyl phosphine, chlorinated organic compound
~ABSTRACT: This Author's Certificate introduces a method for prod'icing 9-ch1or;31kv1
1(alkenyl) lic-h1orophosphines. ~'r--jsphor~is is w,,*k the
!clefin r-r 11A n-lon I-,- P
AScSOOTATION: on e
,NO REF SOV: 000
Card J/l

L 56o4g-65 EWT(mVEP;(c)/-E'z--(jj )/T 17C-11
ACCMSION MR: AP5018360
AUTHOR: Titov.-A. I.; Sizova, M. V.; Gitel', P. 0.
TITLE: Neu reaction for producing beta-chloroalk)rliichlorophos)ihineFli,
according to an ionic mechan"sm
P Y.
UP,/OID20/64/159/002/(,38r,-/Y'C)3M
i'-otr Olefinz
SOURCE: M.' SSSR. Doklady, v. 159, no. 2, 1964, 385-388
TOPIC TAOS: chlorinated organic compound, organic phosphorus ccmpDund,
ionization. readtion mecharnism
ABSTRACT: B---ta-chlorGalkyldichlorophosphenes ,mre produced by additioin of
PG1 6 olefins in tbA presence of aluminum cliloride, onalogotioly 11() the
a r. hme o Ets e I e c t r o nn a
Card 1/2

NP -. AP
XESST011
PGi3 and olefbi were used to shfft the equiltbrip. Lr, thf~ ner-p-s9sry dfrectt(lmi.
S p -:7 iF jr r v 7~ c t~ t9 Tic c, 1 s c
ASSCCUTIGN. none
SUBMITTED: 06May64 MICL: 00 SUB CODE: OC, Gr-
UR REF SOV: 006 OTHER: 003 J PRS
r-~, -
Card 212

AC'a?~~ION NR: AP 5 0172 90 i,,p /rI nri-, I or)-,
AUNIOR: Abroyan , I. A. ; T i tov A. I
TI TLE: Induced conductivity in gemaniyn~jduring homt,ardmpnt by pntas;ium ionis in
differi-pt crystallographic directions -k
,SOURCE: Fizika tverdogo tela, v. 7, no. 7, 1965, 2007-2012
JOPIC TAGS: anisotropy, electrical anisotropy, electric field, electric conductivity,
semiconduct ermanium
~ -tor,A
iABSTRACT: The induced conductivity in single crystals of gerranium was investigated
as they were boml-,arded with potassium ions with energiGs up to 7 kev. The experi-
menta! device consisted of a sphere with two mutually perpendicular -?Xtensions. One
r)f these a sourt:~e of alkaline ions whi le L~e other contained the sinRle
ryst;3' germin i,im. target The tar;7e' , wa cri e7 n wa,,, ~~,31 c-t I
e r C
---I Ce
~'l iciv'~E~y oeelffl was varied by rotating the target. A flat ~5creen cr)ver--,! with
"Wille-mite wa'; -~Ja -1 ir. fr.-3n+ of the target a:i,~' canzzroiledl by an ele,:tromagnet.
Caj-d 1/2

R 74-65
4~110!1 RR: AP~0172' 0
A
,This made it possible to observe the ion L-oam. vici inrl p!rvc-ntt--I t~:r-
tinitri)rtion of iho whor "hr- w;i,i
lifted on1y whilt- thp ~-!irvont p~iise r. ~,I Mee d 5 A,~ 11 1 S 0
pr3ter:~e~! the S-'r-4-L-ce 7;F -ne fr% fr-
_J
cuiiductiviry corresponds to the direction of maximum crystal "transparency"
to the ions. "The author-- ar-- grateflu, to M. A. Yeremnyev for Constant intems~ irl
work and tt~7pf~il advice, and t--~ 'N'. D. f-r ir measline-
me ri t S
,rrig. 3r,. has. 5 f-gureL.
,ASSOCIATION: Leningradskiy pcilitekhnicheskiy institut im. M. 1. Kalinina (Leningrad
Pol-technic institute)
ISUBMITrED. 2gDec64 ENCL: 00 SU13 COVE: NP, EM
NO REF SOV! 003 OTHER. 005
Card 2/y

1. Ti-rov, A.I.
2. USSR (600)
4. Agriculture
7- Production of butter of improved quality, Moskvp,. Pishcheproudzd!t,1952
9. Monthly List of Russian Accessions, Library of Congreso, March,1953.Unclassified.

nt
o0 -It'asllit~f C'.'. k~ ~dai ~U& 'Fli~O~'V:-
4.
Tislidonitfl. MOO
dy V .. Y 'V5
,t ,To. 13, 3949; Rtferal. &ur., KhOn. 1954, No. 37129.
'-Fresli butter, put to storage just after its prepa., preserves
its arlzi:nal qualities for a long period of time when stnted at
lemps. not higher than +I*. Melled butter is best stated
at tempi. approx, -5'; at lower temps. the undesirable
pistachio-jTeeu color cau be developed, at high temps. the
'11qpidphasecuutbesevd. Milk fat Knd refined butter have
to Lie titnrrd at temps. not lower thau -5*, and not higher
1han 8'; under these covd(t1=s the atorage can he as long
u 2 years. Pasteurized butter can be stared for 3 yean at
tctap3. not higher Unn 6'; when the butter is made from
(at + millt it can bt btorcd for 2 years at minus temps. only.
The product made from fat + -%alt water Ij st2ble also at
3 talopi. us) to a *; such 14 product Is umally net attacked
m&4da, ry butter xt4nx%J lit hermetk-ally scaled can,
t4 Dmierves its n4turl freshilem for 12 months avtu
when ept at 19-20*; 'at lower temps. It I, Atable for 16
snant ". When butter contains yeasts It can be stored
14mnt cliatiges for
Alp"t any awl 2 yemv..

7_17-06 A),_2,
'AUTHORSs Titov, A.I.; Vlodavets, I.N.; Rebinder, P.A. 69-20-1-13/20
TITLEs The Processes of Structure Formation in Milk Fat andTheir
Significance in the Manufacture of Butter (Protsessy
strukturoobrazovaniya v molochnom zhire i ikh znacheniye
dlya proizvodstva slivochnogo masla)
PERIODICAL: Kolloidnyy Zhurnal, 1958, Vol XX, # 1, pp 92-101 (USSR)
ABSTRACT: A study has been made of the strength characteristics of
milk fat and butter. It was found that in order to satisfy
the consistency of butter)the fat must form a mixed crystal-
lization-coagulation type of structure with the coagulation
structure predominating. The specificities of structure for-
mation in the production of butter by churningjand by the con-
tinuous chilling of high fat content creamjhave been examined.
Two major ways have been indicated for improving the butter
consistencys controlling the crystallization temperatur3 of
the milk fat, which allows changes to be made in the total
solid phase content of the system, and regulating the me-
chanical treatment in the hardening process, which allows
changes to be made in the character of the structure formed
Card 1/2 so as to bring it closer to the crystallization or to the

1 69-20-1-13/20
The Processes of Structure Formation in Milk Fat and Their Sifnificance in
the Manufacture of Butter
coagulation type.
There are 6 figures, and 15 references, 11 of which are
Soviet, 3 English and 1 Dutch.
A.SSOCIKTIONt Vsesoyuzayy nauchno-i5sledovatellakiy institut molochnoy
promyshlennosti, Moskva (All-Union Scientific Research Insti-
stute of the Milk Industry, Moscow)
SUBMITTEDt July 19, 1957
AVAILABLEi Library of Congress
Card 212

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4P 0 be explained bY I Ile extrrmelY unall vorwrt. of satd. %Wns.
all I acids In the nuboxyllar acials IV) at the It. p, of the don- 11,NAjS(hhl + RCOH = R0CNffArS(hM
00 latter. and the improtabuity ftm the t HO. At a ttom. of the casboxylate Ndt vxct-finat the
hermod=mlc oraifonate -all (VII be- zoo
virwtvinf o( Itair reaction., *JfiNArfi0j- + RC X - I M the coff"Ponding smin
.&,,be, with the free I acid: If,N-
ROCNIMMAoll + 11.0. Th.. Xnn-u P;t " at times to Z; 0 0
+ Na" (+ RC )') j-t ll,NM4~!~* (04n.) a-
mily. ad I Acids In V evidently W elaporiv related it) list edit A,90. 4100
formation Iiietwern tbo Nil. and 01,11 vuul,4. it 6 WJid tall. The frauld"S decrease rd tIW Vs CIMCII. Ma"
greater Inv MOM than for AcOll. Enfirrlir different calm a retardation of lht ,-action; ""' Can "0;U" IjL_ i : *00
relations exist In the psimorrarr ut the same adit2 of v in tho~ jeally strong to th-k the s"Cletating at-tinn of furtbri
old .4 ooln~ At th# twilinj temp. of V the *Ievirolylic div*wn. dClu.. .1 V it* to spite of the Increasing I)WIDS lernp. Of
in
J Thar cu of the tvisclioca vidd
o(thrir edim fit very t he r*Wkxl mixt. a
-ansid"able. l4tv,* the maxi: Stroto- OA, "men. 4howa, that lin' Pr
bwrrat-'%4n orith ah"Sillan"Ma tain. of thr2actitv Itlaticarl to No
joe III finihi f.In. if 'qatjA-. 0- 0401
I Z" Z. =0 'a
.11ALLLPGOCAL LITEROURt Ck"It"KAT10" ire
00
09 8 WXY1 40
"a- 11 L
43 is'; to W at a ft It So
0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0
0 0 * 0 0;0 # 0 0 0 0 9 9 0 9 0 0 0 1* 0 0 0 Ogg 0000000 0 0 0 et~

a 9 0 0 0 0 0 0 1 0 0 0 0

00
00 00
*0 00
00 ifternizing Imp. $lolls ftyrictstro the a4titut, And Ow #9
00 Virld. after reaching & UIM., tW9i114 (41 hNIVOW, 1 411416 *0
00 in), giving va-". Piahs. gave no in*%. flocauocifthr 00
-411ins-4mt. effect of the cations o( V mits, the AcrtYLAti.141
p(mluct Is gradually ppid.: ROCNIfAr.SO,- + No. 10
00 f+RCOO-) rj ROCNUAt$O..';& rz mWid saft. Thiv 00
action esums a shift toward the Ak*AIAW " (d the r"W.
** tim: ffsNArSChN& + RCOvff r-f R(X:NHArl*'hN4 0*
41111111 (+ HWO) - Now mit. making It p-acticable to hwtr*w 0111
the yieW abov that possible by the co"ditionq o( the
so il.luaborixigenousmedhim. Theamelersibigarlion 00
he catiom of V safts dwesses in the order tA K, No.
m
00 The rate of acylallon 6 sornewhat influenced by the
Za
00 t;!~tum of I acids, and Inctrava with the greater ccm%t%. 00
0 4111 of electrolytic dissorn. of I acids. Thme. smylalkm of U $9
(Ko - 6.2 X 10-1) Procerth at a stealer vvkwity thAll
0* tbat of M (Xgo . 1,96 X 10 -4). The resction of fonnyls. 00
so lion VNceedii at a greater mte than acetylation, bm-awir 00
of the greater shift of the equil, towwd the eight %Ide,
041 Tbe catam. of HiNArS(h Ion canw; attain the main. point
00 at which VI we solicit out by the carkmi of V Wis. The 00
PPM. of famylated products Prociettis as in the MW of the
00 afttylatim products. Chas. Blanc to
00 00
00 0
l

09
90

M 0
oi
~ 0 0 0 0 0 9 0 0 0 0 0 0 0 0 0 O's 0 0 0 0 I

0 o 0 0 6 fit 0 4 0111 0 0 0 0 0 0 0 0 04
Got 0 0 0 0 0 0 $0 6 0 0 0;0
II 1AAJ-- ALILLI-L Is'.. Alt As It 0 it a 1) 0 Pa Is is I
44
in
rills, t",,, `41iW ail
time of P1
IC, IV) I. nitr
slightly m

IU action of altrossite di on issinezent. toluene
and chktob
sa
1
Wi ati.
ore
to give W- coned- It and it h h I nrcessitall-,
10071 CICANo
( a I Y higher tem
nitrated
V

0 n
ao.
.
tmilm
with aftMen dioxide
la the Ffeessucis Of gulfutic 9814 PholPhOrk ecide A
1 ,
p.
at 0
D. Tol
-1 will, . 4;
Vill bm
"9e
of 34.4% 1 l4
of Mixed U
C

;i; .
,
Tituv and A. N. Daryishnikovs. J. Gire. Cliesn. .(U. S,
) e
a
4
JI.NO.
Mlb- About 2j 2~"
-
oltro.

ile S. R
6. 1
141JI-60"ll. (ill the A-umptitin that It NO,,
formed toy rrdctk)a of N
l)
ill with H
R)
(111
i
th
w tie~A i. -di
t
V11 with I ,, , Ml-b 111tiord. 1ji"I""gell 11111,1
1 10111 I

,
i
.
s
e %
.
e
,
intratinS fissent when aromatic hy0tocarbon% am nitrated 1"n
CIIII), S,%'- 111-detilled
IMMUcts, if Preliminary Cc
Filov
" mm
I

0
with I let the pirvorner of 11. thir following equation. sop.
-
wited b
est
d
daraj
ff
d
l
i .
llif I K
unication
, 1 V, 41., 111 jljq~ AIA
I'll, I do,. o V 4 "., W
-
oll

.
Aci
ri
r
I
y
tuexp
a
p
n thecourstrof the
reaction: Hil INPO, + if liiO..m lft0 - RNO, J,
reat
" I Iva
1 watt, Ill
Irlop. A
,.
V, sold Vil ,, I.,0111
t IM, 1 huld,led 111t
V

IISNO, + In 1) 110).-tini + 1) UP. To attain o
,
(
A c".) bif 14 hr,
llll%t' of V1 (f) -1K. 9.). Ill the nitr
t
h

**a i
:~umplrlr utilization (if I the ratio loward the rod of the

l 't'on
at favor sli
Of Vil vo.
'" n. Of 1, 114111.41 If low
IlevalellI

0e a k trariloon
wf,*trn free It will water, too -- 1); (m f- 1), rill
lid illilloillalloll i
1"
,
' I ftc
'
the sid
,

i
0
0 ~1
tnual exceed a certain solo. valor characteristic for ruch
,onspil. The great tendency of H to transfer protons to ,
e-4
lolls
ob.11101i't
'
fill, Is riplaillea fly 111,11,1111Y .11,
"J"llor"er's' No, 10 slid t
f
f
:
*0 i consipthi. which normally in sq. otedium are not proton
l
i o u double
On the duration of the reaction and ,b"d- 1-scix-lidins
"'11edwithl
"*
e
on

0 z acrMtors exp
a
rcs its marked activating effect. Neither
unhyd. H.PO. nor 12.0, appreciably wtivates the reaction. ', 1
cn. of 1, V11
~
in iht-sdj,,n,vofill
days gives 1-21~1 still
fo,
Pl3c"Yho
tro
h

indicating that they do not react with I to form HNO~.
1 p
rriethan, 4 74--
-Adinitrotrietit:m-
B,,O (X). 11 IS% 11,11
H (Za)
To -
9.2 g. C#Ha (M), vignrously stiffed, kq added at 4W

'
liver a per
iodof:blniin.asotn
ofl3Ag
lin
19
23 if .
, and Vill. c%poloe
HIM. to d, of (he re. -ii
IrtVI illuininali
.
.
.
.
ir. I
.94%). Stirring is continued I hr. at 5W and the reac- vil ijollight or ,If un
cvleral
all o IN-
f
"

iian mixt. worked up to yield an dist
n- cul,, d
as Ws
and in the ull I -~ own VM to 4 UV`
'
1 I
111111"Inali
25-309

j-
it nitrobeniterse (IV), In. V, and 16.6 S. M. The reaction

d
b
h
h .
X 21c
on the yi,1,14
S~ 70 X. .,i 107. X1
,
VW 43
'
-!Pe
7
XU
and XU

,
.1
procee
s
eat w
en t
e cown. of free U is 79 He
-M%. -
low this corica
I does not com
kiel
t
b
hi .
and
aft ProWbly
t
eke
. d
~
"ge Of LK and X
by hysiml;

.
y rew
s
owe t
, a
p
conim. side fractions sharply lower the yield of IV. fig tt,
and oxidation of VU.
1. L
A I A. I L A 111TALLUNUCAL LITIS
IALLII
GICAL
T
l A
WE CLASSWICATIO
l
M
~
L
CZ-
fig
t JQ.. #0.1~.
Is
It
-A'
of
U"'. It a. n
It if As
Is UAT 10 It
se In I so An 1 4 of 0 If
a 0 a o o ; 0 0
sis
10 0 , , , 1111109S 0a 00
610 * 0 a 0 0 0
se to to
___e
0 0 0 0
00
.0*
-00
-00
-04110
-0411111
see
wee
0
15
aeo
Ives
t: 0 0
1900

--i-0 0-0
0 0 0 0 0 0 a 4 1 0 0 0 o0 0 0
is I a I 1 '6106
00' 'A 10 0
Pitt Fists I.n
0
Aol4** of ottiviall. 4#vdM.*ujf"*w &.44a 11 Malk.4 A
.4 Imi-709M).. C(.
kill (d IA-Ciislis(14110-
4'(
/
.5hilwitsewried
"n
in the tollossirs, tanner: the WW was dissolvcd in a hot
'he
.('A
-1d.
mid. oWn 'sGAc in 98% AcOll and the Assin. was
411.swtqllo* I IiIiiiifly) let lite entlof lite rearthan Then,
41J.'ated I 1"i".
41
Allpf slow v, .11111, Iffe I'I'l. l'"Ittril sea. 1111tit.1 alt'l 11's-
III,,Iliv 11111'" *an 41,1111 u-) III Ifir I.I.- A
I"' is'".. "as
Att . Itivilatt wills a lit.1% lkwiton 4 Air antim, &,,i,1
A
't aN&OAc. It I! ptiouble to vlfirlr~ ut about 10 upera-
S-OA1. I. p
before reaching the limit of acid ditu. The yield of
W I in"
he cytation P,.dt
Ist. latj product increased with each operation
(77=.0 o(theory), becauqeof the increawo(concti.
0: Sit
(it the AcOll at the ctmt at I he N&OAr. i. ir.. I he acyla(i(m
.3 00
sea
carried exit. Pra,11-11r. of lite cost 4 the Nnf)Av.
"I'd *11.1 fAlt,whad d4wtoll(tril IfIfIrt fro") the first III
that the arrlylaiii"i Isoitiltict is wo,fint with dil. A,WI,
ft'sm it), pr,xlwt of the Preceding "Iteration d1jillig .0
'C' its drying. The lormylatlem of the same cuttilid. by this -00
method vielded about 94% of the product. A. A. 11.
=0 0
*sW.j atTALLURCINCAL LITIMAIVIC CLASSIFICATION
:61 1 .
slow siv,v
041
1-t4"0101 ~-e- to I-j 0
or III it a 3 2 1
AT so is 11110
U Its A 1
0 U iitt a, arowa got V oft a U It OW "M
0 00 0 9
0 0 0 0 0 : 0 0 0 * 11111,411 0 0 6 0 0 9 0 0
0 0 a EOP
0 0 0 0;e 0 1111, 0 0 1111, 0 411 0 0 a 0 0 0 04 0 0 0 0 0 0 0 0 0 0 q 0 0 111111

- - - - - - - Z Q, 4 4
0 0 0 0 0 0 -44-4414~; ; ; 0 0 0 0 0 0a 0
I g I Z 4 4a,
0 0 0 0 0
It 11 1, J! it 1! L, 11 2" .1 ;4 1' It 17 1 ?1 JUH11 11 14b 16 If 1. 1,
i .1 4f0
.
h R I T VY A T I &A 14 OL W I
XLa
L A a Ii
j
. -
- -
.
00 40

00
00
00
00
velocity of acetylation of aromatic aminosul-
00 phonic acids. A-L-T=V--And A. S. 11-kRI. -00
g0 SLUNIXOVA (J. Gen. Lhatu. Rum., 1937. 7, 357-- -00

a
X 302).-The velocity of cotylstion of I and
1:7 R b. been detenninod under
'NH1'C1OH(SO3
k
different ooimlitions. R. T.

Use

I I I A A(TALLURWAL LITERATURt CLAWFICATION tz* .0
We
1
--
-
-
-
--Y-!
` 1

It 91 M K It
It R U tt a of n
N
Nr
AA N 0
I
I ji
~
M
I

00 00 00,009 00 00 00 0 0 0 6
10
0 00 oil

o 0 60
03 v to it u It is M It it IV a " all J1JU Alls Its) sops 0 u .3
III, g A I L -IL- t-A-1-6 4-4 -,,-, a
'
- &~
41
00 tu,
a the At field
t2soct). whu itia high tit lfierlz v&
of force has been attsawd. the furnset! ru
'. we nvxe
pd
09 v
.
or Itsis vienpletefy ppid. (c(. I-ROJ,
' 00
of pitrusta dl*sM* am bassaw. Wumm Wisild and Wertypircich. I
. A. 23. 4--Rij. Ndo.
ll
i
111
00 Al and tbiwolsouxentis. Ill. Skmdou witis altMiluss aside nuoiliscril, wish into 4 Itake. 'd
gradua
y
* -0
11
in this pieloesce ist Aluminum chlorldle. willsom pista-
941
; 65 g. (0315 niol.) I
bCI strul 10.72 C. 111.191 sikil, i AW4
*
A
Cl
i -00
0
1
chloddit and rugmutry stitrate. A. 1. ri(uv~ J. Gfx- 1 0
~
s was vorisp
ctely di*wjivrd when 3.74 1.
l
'N

(U, S R 17 Wl 4 IM .W.) NO, a, ab,.ioff~l, i. r., voictly ~,isdinij -00

I to the (twulula. AC
T).
FuIthrT Ithuirvitoo of NO, fig
11 14 NUIAIIAlk' IMIFIWORIKI40%
th Ne), III the pccvetu~ -d I
'
Minvan6l tit v%M Orfili-lic- litieraii-io ,( beat. Afirt
lots v, 10.5 st
Nils
(11
114 in.4
1 (RA% tit thr
4!- AIC4 pitw%vol, by the fiatuatkin of this, twispitit AlO..-
- .
.
.
,
=)" the CUCIO-ItIlir was Irplarcil by a teduk COMWI-i
Wilfs(N(N)ONd I IV. kill [a the friseviii; d hydrocutWo.
g 0 #1 64 roni
vounc
rted with
I0% XOII
and a rurren
d its deiinipo. toy The action tit 1W) Into MCI, MX4
0
n
u i
4
x.
,
of try Cf), *#* Im"", ljormth the girlefit-like irrarlio..
d IINtV Iftipil, ditts -howed that AICL is
A
6ftdvw
l
i
I

16 by the Itictioil I-( The ants. u( NA). that wu&iW Its os
l1 heated pt*dU&IIY it? 1xi
he ikin. of IININ
ji"K.
H

ITAilliltd IM the (ol"940till tit 1, with fUItIWf Adda. of And
I in the '$J~nbcist slum"I a li-w tit 7.44 X, NOU
0 Nith the, grac "I livist-crito Ifluck k~ vis"grik-ally. RW
1 tT.44 g. rakd, aivotdinlUo lite fixtinsfit 11)). Ittv filtre WAID 0
the actitio tit Ie0 if #it" itsill-pru"Ishe to the fiRmalksti
1 tshfut gate S 2A it. of k- At -Wto thrict! in a vacuum
13 ~
4 nitto I be truction pross-4119 toy beating Its
'
drislivator at own Ictup. (14-46 C. by the fixtauts (I) I
NO
rhe fillrair contalrord 17
ll
dsl%i of mitrif ClC
2 s
the itbwnv (it 11.0 4o-or,fins to tlw h-tivida; 2AIC14 .
t.
.
.
o

:11111 1 3NP. -- :IRNO, I, 3N(K:l 4 AWWOJI)t 11)~ the altraiiiso of C.11o love attakwiti, or-ulay. 001

*
4
It is 1%youlatt's that the coussir of The Itavilimi I* vlowly fig A his 14141 the Irso"I 11111"I
ducling N004 At IlAN
40 9 votturctril with the vaFkAts phas" of coeltitinated valn. wivasird the yield of ullto prodift-le by xl%. Nistalk'"
10
A P1
11
0
d 0*9
Of AICI,, Anti that the nitivient of AICI, win
04 - toceirgioutis -
asi
#
4
wish N,0. its lir
h,
pmwncio(AICIs(aik-dtogi%lepte
Fvsulis
TheSchau:
vilth the visit is( the travtkin: lilt 4 N.O. + 2AICIs - .
.
Whinidt netbod of nittatkin of PhMe wa
o
im
d b o0
RN(N.AlCt. I AICI.iOIi).N0CI vt RNO#~AICI*(Oll) + s
vr
pf
y g

the Intritsectilorof thr-oln, If hientival the tevetris-41 order of adda. of AICII to the itsist. of Nits.
with that ril a AWL. w,hi. in the pr~-A N4WI '11w In M!". Is. 2") 41"
And 111INte. froollinf
l
Ni
l
following stitvs iof Ili* ivacliots am tvistril to
At tial
ivi ist MCI w Ih N.Ah
,
" The pree"Wir tit Mi. Natr
C" of CIV
140
,01
111
Il
Nt
i
h
, -;
Ottkally pturvvdivs sa(u. of (tit At drid al' fotv, M cv,
.
.,
,
t
, and
h w
1
a
NO, fit (1, Kave rapidly A Ila it 1 0 t and at I..".

Mill"11. Iw rirfirrAtatril fir the whirtn"; RN(N-A" +
AICI
0
Z
Assive-like itailim. ;Ldox at bous.
SIO a

;-
Rif - AICltOIV.t2R.N0,)(NOCI);
~j
O
am altm ste"14117" ve beagavie. foluit" "d
144 .
Wl + NA #- kit -* AICI Ohl urld.l.
1011)
400"11F
O IFIC 0
T
11110 T
IC -ciptnimb onts
clikrobvilsainair. IW,IW17 72, -M~4
AL
A S a . S 1, 4 O
ALLM
W
Ww- a a W-twirviling subvilluml. XWO; " j0h " Okhyde %90
~
Stroups. do " FrAWt with NgOi tvm am*f prefoute oil

'
'1
uvat V K) I i
I'
n
4
w
w
0 1
0
0
IT
u - - a s- ;

~
0
e 0
*
00
9
16 00 0 0 1111114 *0 0 0 '
0 4 0
s q
0
o
o
010 00 # 19 0 0 4 *
0
6 016 0 0 6 0 0 't 0 0 0 A L*- ~
'
* 4111

,il III- slid Inaurn ctwnpdm~ Is Gwily rile,,1_1 wah.Np, is,
'
11i
h
f f
i
11
80
f 00
t
e presentee o
um
.
nck. I
ng
, (c
I.
,

00 1141tritay.C.A.11,11XII). Ito the nutatl--n of Mollialk
cowixfi. with NrO, In the pre-race of 5n% of
00 coast4ned N is convened into HNO, which is not tt.~l 0
in the reaction. A compkie use of Nit), I, Ix-4ble in
00 thii 1&h. teats by the adda. .1 K.V). to the tea,two taixt. 00
V alter (he "Multiveloill oil file Ixf gfear a( (Ill. Irin-lian: 111119
RH 4. Me I 111A)s - 14NO* I IUSNO. 1 110);
09 "If + IIANO. I K"NO, - ItNO. I il.41. I "Al. I so
00 KJL4. flence, the without addial. so
IIkLh or S". C.11.(N(h)t was obtained In 97,64% yield
00 fly valifing dtopwise. with slitting, 10.1 a. Nit). its V) a.
-7'
45% fumin
11
RX t
122
PhNiLt
I E
Afi 09
00 o
P
a.
.
rt
J
, &
g

00 -14rallng lot I hr.. the Irl"p. DI the rr;".14xtl tnill. **.
Fill" to IM, 0 hr.), Own "U" 1.0 411' and 4111il. Willi
00 1 100 tv. 1111A). fly this nimil uxi. MirCJI.Nih save 9011,~

00 I-ANWIIII&IT anti M
M
61 1
C 2.4.0. MN)tCol I Me. And
1
11
N(
V
C
)
i
:'1
.
i-m lit
aildi
.
N
,(
, 640
so ittle ivactitm ortup, 4"40 ) n howctl nortlcvt at the riatiar
00
00 And the y1clits of the Oration I'lool 111A K.
,
"
1141. 111 t. NtL% anti L
I a. of 34% funiong 11"), at ;l 041
ormillef 0.6 a. of a alito ptoduci, solidifying at 46 4W.
7
-
'
3
i
X
00
I)
Treat
.
7 a. (thl ittol.) p-
IeCjIjN(h as
vialt
ng 1
0M
l
i
4
f M
0
N
12
fi
4.
.
P. jO-
mo
.)
n
it.
a. o
niang IIN),
%
111441C o(:R) min
luld then at file Mine frili
'Ailb 1:1 A
.,
0.
p.
jUJIS inul
and stittin
for an ad
l
Ii
.ull
) K
~Q
t
I
of .
.
i
.
u
t., m
"
.
s
lit 1". 11*6 2.4-iO#N),CJ1&%Ir. Fw4hlifying Imunt
Os cll.~. Man,
'U. 00
V
00
00
so
00
a Ms-

"Moo
W# ANO 0200091,11 -0#0
00
68
0e A
00 L 19OW0819es
41 ZO
A. I.- Own. R=I, - I9W- to"-
it I - W mixt"MO(clipmN
, r-- JqLA
0 sad JkOIL UW YW&%S
Pdina
=v9 vmvrww~
W aw4wsuc
sea Saw* temp.
obt9od Wkb PM&
d mutim
Wd
W~Vd%
R. T.
dhosinviL I
JUL 4
As"LA alt"LUt"AL UINNATtOt CLAUWKATWM
too. 119,421va -
141461 -&b cow ant
u " AV Q Ali; 10 D to to a of
a 1 4 ; In
00000,00000000
::.::logo 00:00 00 0 0 0 0
-0 #1- ~9910.i
I Z-
.104. Q.Ow
-4141i1 -4tt
, Wo as I IN
tt a
00 1 0 000000006*0000
0000
-00
00
loo
.00
'-See
j 200
Ile*
.-too
,too
1100
No 0
tie 0
::0

----------
7

-
Ktiff R R U.N-1111 Joe
f

04
,
S 0 0 * 0

I f - k. It it " I, "
I it a a
L U L r 6 it 4 L a k
r 6 1
V A 14 h "a ff art 4-11 VI) 1.11 t,"
,
I
, ~. L AA 0 a W it,

A Hydraly I of the amlno 910UPS in the nitro" and nitro
4orivativeo -of 2.6-diandnopyiidins and 2-amalno-fli-hy-
V call lye otitaim-A fil "Al IRP ", Vivid fly immisK Ill and IV
droxmilidine. A. 1. Titair. J. Grm. CAWm, (U - S. S. R.) Willi C.A.1 N ( M I'll 3 11,1V -I * at 1) 1 "II"I K,0 1. and
1"
14KI-JAIiin Fairtilb. cf. Zridr asid', 1-ili"it V oxi'lli'll Willi :10
, Ho, m Ill N!1~011 .4
1.
t', A. 30. 11739'.- Alitmir addid. clipt
Titov N44COT siv- 3--a- ~*.,-1,hJ--PY,14lq, M), I ~ml
,

l
11
1
1
silictl .4, the gtitit,111ir alul rurtsy -lationallilit AMM 11 ."1 lilt ,, I a. .4 64".
-00

1
:
d The Fraclim n( llydrEdyaq. I he IlCl 1411, A 1.,
j
" IIN(h t- I x. R".. dl-~(
o m
l
1
81111
11
i Nil) and
N a, at

.
(IICI Aw MOM fitact will, oil.
it, jorl dr,irypyridim; (Vill), tr,4 41141 midalp"I

N -490
.

d
,
giv, U1.4it Ilit",
wvf~ ol'idilml frmts I
"
JIT'hiticts. hkmieal pt'
!
!
a 31. ill 1
mill IV fly midali'm Willi 110, In '111 '%1[.( M. I 1.,

-
stud IV si%r tkl`~
W Id
l
110 i .4 11 gav.. a 11-fly it It'd$ '10A .4 file .11 A,
A Vill
fla-l't --I
N-,,
0
, .
n
%MW
I'l 2. "lilt titl- il .
lt i
1104111 At lb, fill IL days- lly'litAybi4 at virvacrit trittim lilt' Pf.1010'111 -1011' "1 Vill, 11. L411V 11"
' -Olill
'
procced, very vapidly but give$ Misitirl"I'le i ill it" _ht I.,
111 VII Alld Vill tilk" jlL1VV Willi lit
04 V call IK. jilcutly uk,taitted In INK10 field from
I.Xillvis 1.111iliff. 110ifilIg %Hll 11,SA)j IM A fill, X4- trlke~i
.
I
*nil It fly Ittating 2 a. amine in -ill UIL liso t-Jutg, it lilt-
r of Nil, aud fill, pt,xim-1 0 Will, Ki ill

ia j s. at t)- will& 4m.od lilt. cif 041 X NuN( h and lit'ilms Ga 2 Ili,. tile 'll-A, derm, .I Vil aml Vill 400
-d alh,wing the kra.lion mitil. I-, malld All, lra,ilv ImillAirt'd ill 11tyl, VI Ch~i.. lllmw
04111 far lu't.vs. V. a twatly _A~ltr~ -b.twav. jlVt73r,,1w~d .1111110
00 ludlis if I'll, Nil,, 134, No. K and kh', the int~r;-OY -1 -10 1111
file .14.w lmn"~ %, it It tile irmater t-ictt y of th~ makirm
00 .09

1.111N.TURF (1.111P.CAtiCk

%u A,
0 0 0 0 0 4 0 0 0 a

00
00
C
66
to o
00
00
00
13
00
00
0 .4
00
so
so
10000000000000 0
, M.L. if Of IVA _Ii 4 4
U
LU
Tog
00
The CA#MW Profwd" W scst'llitit- T%* "I"bWO ol
Wd in &&qtj6 " in the fe-0941, Of filld(StOd. -0411
lljo-v.~' J. G". CA", (U, S. & It.) 9, 0.3"(1m) - k
-studin an the effect of U acetate. Na Almlato -00
mid K acetate ork tbo mulY. of w1fardlic acid In AcOlf fe- .00
virmled that the say. was Inemwd couiddirtably.
CkTtrudo &.rvend
-L
111111TALLUAGIC&I. LITRI&IM CLAIVOKAIM
7- --:7
11119111#0 -- a; "
Ilk vi I oill , - - ow d"I ilk
1-7410 U AT 00 V 1,1A 14
I I ff a
L g I OW a N
0 0 0 0 0 0 o o o 0 010 0 0 * 0 # 0 0 ~ 0 0 0 0 0 0 0 0 0'
0 0 0 0 9 0 0 0 0 0 0 . 0 0 o o 0 o o 0 o 0 0 & 9 * 0 0 * o
.00
A 0
too
A 0
000
AO
U00
wo~
0

9 0 0 0
f, 16 0, 0 0
051?07101 f?119.90 loot. 1021, A. "1 11 is IT ZVY a loll U13 Ull 3611 xxv 41 043 hlan*
no
PIS
s
V 0 It T Z AA
F- F- C N 1 9 L . u - . A - -L A -e
PIC-COSIt A.0 PROER110
The inechanim of the Konovaloy reaction (nitration of
Titov.
saturated h!4Ttigbons). . 11. A. 1. J. Ceq.
C1WM. (U . 10. IS78'SI(I!Wi; c[. C. A. 31,
85161-NO, acts an McPh at 10)* to give chiedy I'll-
a Cff,NO, (1) and. by oxidation, litif and WOII. Sam,
PhCI1(NO,)j (H) and nitfritolucurs are also fortned, but
Wh has a very slight nitrating action oil the tiog, Con
versely, HNO, acLs only to nitrate the ting when it i-
pure, but if it contains some NO, NO, is jortned anti the
side chain is also nitrated. rhu., it ureA is added to
JINO, to remove all NO before nitrating, 2,6-dinitio-p- see
=00
96 cresol is the chief product, anti the %ide chain is neithrr
nitrated nor oxidirM, although the latter reartions prr-
00 Zee
NO.
dominate when NO is left in the acid. Ncillicr If.
nor NO, converts I into It. It ii prolluced when the
MCII, radical, fornieJ bv rmetwo 4 PhMe and NO..
reacts with NO to form i1tCIIINO which i,;ouierixc% m
Q;0 0
PhCff NOH and then reacts with N(h to form 11.
00
It. M. 1xic"ter
1000
We 0
i'troo
PTEMITURE CLAS111"CATION
Ito 0
.11 CIl "1 0
Aii -
0 U AT PO It K ts rt It 09 n 1 14 An I 1 4 ftd 0 1 lc 14 1 it 4 3 1 #10
0 00 000
49 46 0 0 0i0 0 6 0 0 a 0 0 0 0 0 0 * 0 0 0 0 a 010 0 0 0 * 0 0 0 0 0 a 0 0 0 0 0
61'e- 0 a as Gig a 0 o 0 a & 0 0 a 0 0 0 0 0 * 0 4111-0 a * 0 * 0 0

IM R
021 . . 0 0 0 0 0 # 0 0 0 0 0 00 06 6
31 33 13
10 1 0 1, 00 0 11 .01 '0'. 44 01,0
000
00
00
# 0
00
19
0o "
00
W
00
L C-4 I a _j -&-t- J~
T7-60

Thari a
l of Ia. favestiption of the
d
I
Z
l /0 !-Go
. . 2
l
,.
h dine and 3,6- droxy-
y
Y
"Mahy
~
a
~'00
dine. A. 1. Tit
ov
nh. B. Levin.
Chrm.
-
mr. S. S. continuation of previout 00
1
ock (C. A. 30, (17MV) tin vomptis. rontif all attliflovinyl 00
grouping. the vote of hydrolysio of
if) was studied. On the banis of resonant situcint" the 0
relative case of hydrolysis of thin compd. to 2,6-,unino. -00
h* yridine is explained, as well as the comparative
1
"I tit further hydrolysis to the 2.6-dihydioxyt,vri.
rhr tote of hydnily-it, hy 4111, lt,~k 1. wo- oudio,d
n't front, 11o'c data obtained ok-t of In
rative Conditoinq
/ 041
.00
fqW 11 will deld, as follows; lip g. I And 0" K. IIA"', 1 It-4 1,
T
are heated at 155' for 4.6 ht%., difd. with Mire. Hot), let
Itand at 7-10" and the anhyd. sulfate of It is filterrd off
in 4.6-g. yield. On diln. (it the mother liquor A further *0
~1.6 g. Ito obtained, giving a total yield tit W%. Toobtain ~06
he free Ww. the sulfate UN g.) in '.'tp tv. tioilins wain it
;1roted slowly with NuOAe or NOIS(h unill twitteal top
Congo red, boiled for several mIns.. filletcd and cooled. 00
The ppid. product is the hydrate of It (50.5% yield), m.
`
.~W.5-204
. By treatment with Acj0 it iscuriverted into
theOll-dia"fate no (39"(froonlitO). Prolonged hydroly.
is,Wl in `70% UpRi. at 175" yiehli more Nil, than the 00

hrowellcol dint. fitim hydrolyWoo of the Nflo group,o. in-
t
06
tilt-at Ing hydrolysis of the pyridine ring. Astuall(InAntily 1`00
of an acid was isolated frout this hydrolysis tuixt., but
could not be identified positively. G. ht. K. =41110111111
Ald-SLA ARTALLURGiCAL 1.111101JR9 CLASSWKAMW
MA.&SICNI *pilot a" a... all
to to I IA KWI 1 -0
is AV No ISIS,, I $A I I V PM 0 M 0 1 it k 9 A a I
U to Cr to 00 69 K 4 It N it cc if it
00 0 0

io
06
00
04
0*
00
004
00 -
09 -r
004
00
,, it
00
of
"-w-W-W-4v4v-4v,w v W- IV w W-W-W -W
0
x wl m u a 10 a 41 a a a
t A-li-i 4 '1 4 0.. " 0
a
00
13 C- '00
SL A OCIALLUROKAL UIRRATLO11 CLASUPICATIC*
t-It, , -
u a AV go Ls
;o
*00*0000000000:0:0:001
.T.'s 1 000
:0*!0o00o0,oGo:*Q****.c
I la-I **-In.
in
a I #A L S I
000000000000000000000
o0 1700 0:
000000*000000000**Ooo
100
so
0
GOO
200
%0
Coo
o
Wo 0
VO 0
%0
goo
104
bo 0
too
goo

*$A
00
4
0
9
00 13
00 43
*OV
Inductive, Mea6mlifle. And little Ofticts In Unuttirlited
sad aromatic scids. A. 1. Tiloy.(Lilo, Orl. chem., K. H.
vorashilov Milit. Acall., *161micow). . . Gels. Chem.
(V.S.S,R.) 10, Iffil-MI94d)(in Rus.-lan).-The fact that
a,$-unsaid. acids are weaker th;tri the cormsponifing
0,-l-unWd. widis (e.g.. Cif,C11,01:01CM11, loex -
1,11: CII,CII:lCIfCII.COOII. VIX - 3.41) 1- iotermted
fly the sullcrIKKillms of a tx)G. lvt~wiorric (-# At) rffcvt on,
the ties. Induclivt (-I) effect. rVitilling ill all Increo-W
of the tit charte an the earboxyl And a Irsstning of the
entirticy to ;onistation. The -#-.V effeel v.%plains also the;
increased It: -ijj.c-ptopcrjk~ of IlliNth a4 minpuriA with.
!IM-SLA 49TALLMICAL LfftNATURN CLAUWKATON
b U AV
0 0 0 0 0 0 04,0120 0 me
I wait
Oz/
hlv.Nii,. whrle.44 Ito- det-Fritse of the I%LOC prol.flits in
PIINII. U, cooil..Lml *tilt MeXII, i~ lur to the -M
effret. The %troog bicteww of acidity from CII&CII:
ClIC0011 to CII,C!CC(X)II I IOK - 250 as arunit
2-1) is und,r~iari(Liblv from lite fact thAt lite two r-booth
of C: C Itc tit tti&mtit pLutt., only tow of which .u% he the
scat ,(,in Af~&vt, Ijrtr;&, ill 11tv other in.joetivv alliav.
gioll of "I'virotil t"n.on, oliv-411no,tted. I'lic loArge4l
ck-cl I uph 111,111 Ill Ow e.kiltolivI C. ilue it) the At anti thel
0-trotorTic rAvvis, del.. l1w much lo%%vr r,ilmo( qno~vifi-l
cation of acidb in comparison with tW
corr"potuling !640. avioN, whereas the somewlLit greatcri
rate in #.-f-uo"td.avid, 6vilplAinedbythe e 0,vurrence
of the I-effect. Ina,inuch as full realizat"ion of the M-1
effect of r-bonds dvpvtjds on location of the cormpouding
atou" in one plitne, sub~titucuts that disrupt the plarve
structure an bteric Uoundi will hinder resonance and re-1
suit In higher a61 di,-4vu.; [cr atefic reAsm%. the cis,
fornis of Cl[sClf:CIICoOll and of I,hCll:CIICOOII art.1
littongtr acid, than lite tr4m forms; the lauic stcric fmior!
also umictlics the ffirtt-wse of iixiAlity from PhCOOH to o-
NICCJJ,COOII to ~.1,1141eCJIXOOIJ wi contmited with
the "ity-decreaillit +1-cffert of introduction of Me
Xfoupa ill P" anti P IN)%itioni. Thecotntsinrdxrtionoftbt~
teric and the +I cilt-vt I, drid. for the stAbditr tit the
I 2.11111-Africil 11CO I Varbunittill ion in U411. In
&Vrx= 2--
134. VOWAng
--Ijiisl GK GOT Its
i i a im o a v -i ir v 9 a a
.00
goo
86 ~41111111111
coo
Ire 0
t600
we*
goo
1100~
Ze
see
see
age
it**
WOO
0

0 0 0 0 -0 0 0 0 0 4 46 0 00 goo 0 o'W
f
10 11 4 U M " M V 1 0 us :16sr alto A11 go 40411~0
I L A,
41- c
0
004 iiOry Of nitration Of saturated bydrocittlions and their
d#riVs!jVQ'
1
G
J
l
d
00
-
,
CuNrA
Conc
-
usions on the primary
'
Wertion of th
i !
00 In e react
on. A.'I
llov JIAIJ. L)r1j.
%j -so

got (wxow). J.
J6
, 144-lig)(10916)(iii Riji.
004 -The incftectivellm, of purc I I.N(3, lot the "it'ati." .00
(Al 114r4fli-, lkiraffink- Adc ch.diii. and c)cIoWjffjnj, Was
d
ell"WrIliti Ill AWAY r%Pt4 at f': lit t - It elfin,
* "
"
2
T"F
7-Ahoethyloctati
l
l
l
o
7
.
o
r, cyc
le'
i,
d
]
h
.
"
it IINO'
l
(I. 1.40-1,.L
; risults werc al- Sitg. with Cillo
and cyclo.
'
h
e"'lle '&' IfX)
, 1() lit", Nitration Proceeds not job
see JA.No, Wt with So, which focill-i to mile xtent above

04 301% 5
- if) "d. cyviahriiane nitratetl with HNO. (d. 1.4) tit
'
;1*
%
V 40
-
r4vc only 0-H of. proiluct while the same amt. re. -
god acting with 12 9. N'(h gave 7.5 g. nitrated products. goo
Furtfirr proof is dirrived front expose. an the nitration of

04 fill, J-11", Meic, Phcll,. Phricif, Phic.
M-NIc viiih NA with czct%% of citht-r NO of 0~. in he
-00

ow 38 kcal.) suit
firm raw flu to 1, Ell 2.0, 3.0, 4.0. 3.5, 4.7, 3.1. 15, 26.
r 'u wril disnell., X'06 - NO, + NO.
dro-
ondin
h
f th
C
rr
ti
it
ti
i
l
f
E
too
1 on o
o
ues
or
1e n
ra
e
esp
1e
va
f
y
g
very Mix I.; in the presence of 0. due to the -

1
00 carbons, Rif. 11tat nitration 13Y Not is of the rAdwal
olil,Lition of NO to NO,. nitration I!, significant. only as*

rm-tioll type is furthri, corrot.,galel by uch (Ac-U aii its
he "n"'?rMer X()~ is effective, NO, Is not. The '-Y
Pful 0
t.
locolzation in the hydrocarbon Oa-, abcnce Of An I
rrac too isamumed tobe Rif + No,- R + HNO~Igiviflg ti
-di
f
i
t
h
i
t. PreselKle
e un
on: ant
o
t
ty ti
ri- to free radicals R; by Its eltictrophilk nature, Nos .fluence of the liolar
C i
T
"
d
T
CL h h
At
Id
.
c -u
w
s
s
no strong
,
-,I,wus to at. h4loprill, being enrrgvtk-4Uy C1010t 10 Ac
e"
:
-
1l
i'While atwn. valu" of tile ene"" 0( stabilizatioci inechankin. Rif + NO, - R + JUNO!. is furtV" %up.
hat 14 ra,lical, R arx- drrivrd flout the ditTerellcot of ki. 1"Itil by can4defutioris of energetic anti ii "ic imptub-
ncti, cncrsjr4 of activation E d hydrOL-4i'llotis Rif and bility of other niechanisuis, such as )tit + NO, RNO,
o( CIN. 4"uming the difference to be aptWo EA; for -+IlcwC--Crupturc.
l
*
tile tytw RXOOII 6 improbabic oil ottic riound~ will on
the nitrali"ll of elf
H
43
to a is
-
.,
all ht
n
ties of
66-1 (or a no. of rn,lk-aj% R (for ce of Cifi-trAUS ConWiNitkil UIMII'f 0W.W111011 Of Nos.
A
-.1 at'c I"#.'
R Ft, f1r,
1300
-
k
SLA ACTALL411141KAL UTIRATU19 CLAIMPICATION
ASO-
I 11041
3*4W IlWas " - views 60,01MV
-
-
-
-
-
-
MO
- =4
S
4
4
9
I 183060 Nip OftV cat Call"C"Cl 1311111 Out 0-T ill
U 0 AV 10 At I . , , . I M I I a w 0 8 1 Is so $10
; it & a W 1, is 41 Or it i A T Us
:
2

1 * 0 0 0 0 0 0 0 0 9 0 * 0 0 * 0 9 0 *
0 *
00 0
0 0 * 0000 0 0 0 0 0 6 0 *--W
g'-* 0-0 * 0- 0 0 go 0000 *
V

W
O
s a I I I I 1 10 Is 12 13 u is 16 if Is AD v u III k a M jY Al 0 6 41 a it a d to
-,A F J_ 11- 11. A Is IK _11~ 11_11_1 t'
lit"11, -
A
*00 The 114itilkance of ateric fact
orlt In 61kyuboa Aqu. Q!1.1 'zUJ,.Lf 06

&C
I
tilans A ~ 1, Titity'i K 1, jo. th- 2 r,-Ivms

'
/0 -00
.
VI)r,Atii',,v Mda. Ara.l.. J. r,,--
,
CUM _ jt4Ijm t,y I .:..I ~.lkvwiitu by 11, pr,~I with Apw-

6, ;h1l 1 -IM(II1111)(ill Hu
i4n); c(
C
A
41 S Amin is -0
thesunryaA-ity. rhel-tccicv. oi-acrst, the
,
.
.
,
'
.1 fe.ielions Ythba type are detd. 1-
*0 , : Undoubtedly greater in the nitrate that in the nitrite. but
04

ii
not Ossify by the Poe. ekc. charge im the correspoudin
I I
9 ter %jesic acceviibility the latter N exhibit'
owing to Sm
~
so a
electrophilic centers but also
to a large extent
b
the its elccuophilic nAture m4we readily, forruing the intermr-

"
.
o
y
'k-o)"finafive isimitn." 4A thinse centers, expressing the diAte cunsiplex O=N -OCII,Ph. Likewisse, phrooli react
d of their steric acemsibility and their capacity of
'
= ut'N 4(
f
a consixts. with jk higher c~v&dis%Atiosa no. without
o
so substantially altering the elec. niturr of the rest of the readily with nittiles (in netstr;al or 'li4htly alk. inedi
sur"
,
th
RCIIO
t
i
NO
FAXI
h
C
: forming nitrow coinpils.. hist are inert to alkyl nit
'
mis
u
n
%,
.;
, itsidSistoms
,,
s. t
e N.
,
o
t
i :
6
di
li
l
td
l
d
f
di
i
(3) Further examp1m 0( t1w effect -)f sirric unsatri. me the ; to
: are ca
r
na
w
y un%s
. an
teat
y to
orm
nterme
ate
c
m
o0 .3 1
o
te
itho
b
t
t
tW
i
i
Th alkyLatint action of alkyl indfAtri and the,wylating activn
xe
w
c
u
2u
%
;4ti
sixt
vat
mp
on.
ts-
e nucle
I
1 11' atoru A (charge -e) in the mol
sc
M-A-N will re
ct ol most carboxylic acid riters. The enhancement bi the S
.
a
.
00 a 1 J:
F
er With either the elewtiophitic ectiter % or with that
alkyLifing Ability of sulfurtim acid esters by addris. 0(-

00 a i at tit (charg" +es anti +4, steric resistances, R, and NO) trong inorg. acith may he due to the form ition of interme-
=0 0
it, the mol. (0)(T)(X) Bi-Ill (Y)(7).d
00 c ding on the
r if
0
sign of the difreterwe tit the driving forces
of the two fe-
e* Sctions, itppcox. equal to the diffetence oll the two rate diatecompleiLm it _0 _S O-R]
I 000
consts. ~: Ak ,, f, - ft -, Pe(ej - ei) - (RI - R,) where
oo z
J) a* o
P 6 ~1 (unetion. of the I16tatim (3) These cimWitcrations
are applied tit the reictious of MINH with the nitrite Ily w.sy of acylati-in of Priln-Y IliPhAtic al,7011011 H
Pheu,N(h (t) and with the tiltmte PhCllsNO, (It):.

V
I
i
i
h duc to a Iargr "tent to the greater steric acc"iihifity-
see
rcactun
t
A X.
w
0) g. MINH under cooling. giving,
'
Olf 300
after 2 da"
standing and twice tepeater! distu., 94 20
' to
f th
II
C HIC-all" rif with
o
a
ultrosuditnethyWnine. Ut.N.N0. Is. 17"
, anti BN% o
m
I
e
a M c
r
mp 0
PhCllrOff; nil alkylA-tion took plam. On the other

hand. 6.8 S. 11 maeted with 10 g. Rt'VIl with to 0

atom temp. ti%c to 65% solu. in 30 nil. HCI (L:2), the reaction proctrding over the In-

oo
with edier, WItAlinization. exits. with estber, and distia. of
the ext. gave Nu% (PhCfl,dEtsX. b. 209-13% identical tI* a
k Yw,-, with the product synthesized by bolling an a water hath -

oo
40
-3 bra. 12.5 g. PlICIGO, 25 jc'co.' Cato. - 1
t its" "it I a '
*)&III ant ai.
~ Lis a
~

U 11 4' '0 "'i A 19 St K a tt It at K
;
W ft An I t v 1W a 0 0 1 N as 5 a a 3 1 1,
dara~

0 0 0 0 0 0 0 0 0 0
T10
a * so 0 0 * 0 0
0 S'o 0 9 0 * : 0 o
0 0 0

0 * I
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