SCIENTIFIC ABSTRACT ALEKSEYENKO, V. I. - ALEKSEEVSKI, N. E.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000100920004-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

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lotA doiipficm 1. gc.i1k;r Ilic pc~,.t-r 11tv ault. ,If 11 and
thu Pr3h.r x. Addii. of dibut 0 phituiLa, I,, I im?,.- d L
_. a.mh - 'III "j-1 -.(. of 11 " ;,I, ~ - "71-, . 1-1 1"', , I% It
s to. c.g . 0 1 kj4-/sq. mni. AkLI btlt3diltlt- ItI1111I I-
I"A tiler gruatly lowt-r"i P, o! 1. (nds. T~13T t.Il
I)IaSLk'iZI'r1 in ot h,r Ic,Lr pul in, r,

ALIKUUNKO, V. I.
The production of artificial
prom. 16 no.3:25-27 W '56.
(Leather,
leather used for shoo uppers. Log.
(XIJUL 9: 8)
Artificial)

A- t- S,;~ S ~- Y 'z-- 1v V- ') j 'J -~
AIMKSF,yRNKD, V.I., kand.tekhn.nauk
of hydrophobic and hydrophilic high molecular
Compatibility
substances. Legg,mo 16 no.10:26-31 o ;56. (MIn 10:12)
Plastic.) (Colloids

ll.pomm..4

USSR/Chemistry of High-Molecular Substances, F
Abst Journal: Referat Zhur - FILimiya, No 1, 1957) 1122
Author: Alekeeyenko, V. I., and Aishustinj. I. U.
Fj
Institution: None
Title.* On the Compatibility of Polvvinylchloride and Poly-vinylacetate with
Other High Polymers
Original
Periodical: Kolloid. zh., 1956, Vol 18, No 3, 257-261 (English summary)
Abstract; The possibility of combining divinylchlorovinylidene rubber (I) with
rigid polymers, e.g., polyvinylchloride (II) and polyvinylacetate, as
a plasticizer is established. The Ppendence of the yield strength
and the breaking elongation on the rubber content in the plasticized
polymers is given. It is shown that when sheets of 11 containing I
are heated, an Iiicrease in the strength of the mixed polymers is
noted; this increase is explained by the interaction between the polar
groups. The authors hold that the nature of the polar groups is not
particularly important fo:? compatibility.
Card 1/1

17
22

KL=YA. L-Te.; B.S.
The 86PRratiOn Of solutions Of high polymers Evith Inglish summa7
in Insert). Koll.shur.18 no#6:691-696 N-D '56. (NLRA 10 . Z)
1. TSentr&l.1rq7 nsuchno-iseledovatellskiy inatitut zamenitelay
koxhi, Moskva. '
(High molecular wGight compowids) (Solution (Chemistry))

nabbur =d ~11-1
vr)vsmsmt!ojV6prova4 the ynechanlw4 propwtuea
mbl~ Wiih

ALIKSIMKO V I#-, BUGOSLKVSUYA, L.A.; MISHUSTIN, I.U.
. =-~-j a -" ~ a ~~w ~w
Compatibility as a basic factor in adhesion of high molecular substances.
Much. i res. 16 no.8:10-15 Ag 157. (MIRA 10: 11)
1. Tffentralinyy nauchno-iseledovatel'skiy inetitut zameniteley koshi
t obuvnays. fabriks "Mcorokhad.l.
(Adhesion) (Maeromolecular compounds)

I
~: `T -11-,
I V~-.Y I ~
".--. I
W_
=---m
-i_ -
-r~

a I. Sx=O' V, I.
1 0 w
lbthibl tion of rubber plastics. and equipment used for their
processing, Log, prom. 17 no-5:54-56 MY 157. (wa& io: ()
(Parts-Exhibitionn) (Ibibber industry) (Plastics)

ALEKSMIIYO V I - BLAGUVEBTOV. B.K.; BWOSLAVSKAYt'i, L.A.; ZHUVIKINA, A.-I.;
F.I.; MISHUSTIN, I.U.; NISNEVICH, Ye.A.
Use of synthetic gutta-percha in the ahoe industry. Log. om. 17
no.6:18-20 Je 157. MRA 10:8)
(Shoe industry) (Gutta-percha)

ALBKSEYEIIZK
Artificial leather industry. Leg.prom. 17 no.11:62-66 N '57-
(MMA lo: 12)
l.Direktor TSentrallnogo nauchno-iseledovateltakogo instituta
zaaeniteley kozhi.
(Leather, Artificial)

PaRM-1
~aa..
E -2M
5~

KAMYMV, V.V.-, PISARINKO, A.P.; IJYAMINNKO, V.
WS" and OMPA" semiautomatic pressea for VUICani24tiOn Of
rubber goods. Much. i rez. 17 no.12:17-20 D 158.
(mm 12:1)
I*-Vaesoyuznyy nauchno-issledovatellskiy inatitut iskusetvennoy
kozhi.
(Hydraulic Presses) (Vulcanization)

AuEamm . .,3UGOSL&VSnYA, Lt..; ZAMROHEM, P.J.; KARAnTW, N.G.;
- 0-0 HISHUSTINg I.U.
Glue mde from latoxIlko NT "nairite." Isg. prom. 18 no-1:23-25
in 158. (MIRA Ilt2)
(Glue)

ALRKSMNKO, V. I.; HTAM, B.V.
` -r;
Cbaracteriatice of Intermolecular bonds in combined systems. Log.
prom. 18 no.3:18-21 Mr 158. (MIRL 11:4)
(Polymers) (Molecular association)

ALEKSMNKO. V.I.; MISHUSTIN, I.U..
- I. I ~-- I--,
Plnsttcizlnt,, polyvinyl chloride, polyviTT1 acetate, and nitro-
celluInse with carboVl-containing polymers, Lng.prom. 18 no.6:
18-20 Je '58.' WhL 12:10)
(Leather, Artificial) (PlastiCl2ero)

ALussymm. v. I.
Make use of advances in chemistry in developing the artificial leather
production. log. prom. 18 no.7:1-4 -Tl '58. (MIRA 11:9)
l.Direktor Veasoyanogo nauchno-issledovatel'skogo in8tituta
iskusetvannoy koshi.
(Leather, Artificial)

S%4F Y~F "Y'e_
69-20-1-3/20
AUTHORSj Voyutskiyj U.S., Alekseyenkoj V.1.9 Kalinina, L.Ye.
TITLEi The Compatibility of Nitrocellulose and Butadiene Copolymers
(Sovmestimost' nitrotaellyulozy a butadiennitrillnymi sopo-
limerami). 4. Relaxation Properties of Binary Mixtures (4.
Relakeatsionnyye svoystva binarnykh amesey)
PERIODICAL: Kolloidnyy Zhurnals 1958, Vol. XX, # 1, pp 20-28 (USSR)
ABSTRACTs The deformation of high polymers leads to a complex re-
grouping of the elastic chain molecules. This regrouping is
connected with the surmounting of the forces of interaction
between the molecules and with the disturbance of their equi-
librium positions. Relaxation is the establishing of a new
equilibrium condition in a deformed body taking place under
the influence of a thermal movement and leading to a reduc-
tion of interior stress. In the article, relaxation of
stress is investigated in films made from mixtures of nitro-
cellulose and butadiene nitrile copolymers of different po-
larity, with the aim of explaining the mechanism of plastifi-
cation by high-molecular softening agents. The films used
Card 1/4 in the investigation contained different quantities of acryl-

69-20-1-3/20
The Compatibility of Nitrocellulose and Butadieno Copolymers- 4- Relaxa-
*tion Properties of Binary Mixtures
groups, whereas the reverse is trve at higher copolymer con-
tent. The limiting relaxation timei-r *, which is the time in-
terval between two elementary acts of molecular regrouping, is
independent of the degree of deformation only for nitrocellu-
lose-copolymer mixtures containing 28.6% or over-acrylonitrile
groupst i.e. for sufficiently homogeneous mixtures. For the
relaxation of pure butadiene nitrile copolymers,the energy of
activation amounts to 10,7 kcal/mole. This is caused by the
fact that in all copolymers the local bonds have the same
character. For mixtures of nitrocellulose with.copolymers/the
energy of activation is lower and varies betwoe'n 5.3-7.8 kcal/
mole. It is possible that the lower energy in the last case is
caused by purely steric conditions opposing the close approach-
of popular molecule groups of both polymers in the mixture.
There are 6 figures, 3 tables, and 12 references, 9 of
Card 3/4 which are Soviet, 2 English, and 1 Swiss.

J4848-65 EP s 211E WTnP Fc )/E WG (v /EP R/EP A (w 2/EVIP PC-4,/Pab-10/pe-5/~~4/
-2 ~~F of) C-,/60061 006 -1
oval I..
at
TITLE: Amethod for producing i 9- P Z~s I Cs Class 33, No. 169246
-to - rhykh znakov, no. 6,
1965, 61
'SOURCE: Byullet6n' lrobreteniy1 va
r, F; T- Dolvmer, ncm~,-Ia-
ASSOCIATION: none
WMITTFS: 3lMar,61
C,
ENF'!,: 00
SUB COM MT,GC
Carri I/ I

BITAINKIN, Dmitriy Aleksandrovich;.,ALFKSMYKO, V.I., kand.tekhn.nauk,
nauchn.yy red.; GOLUBKOVA, V*.A0-'-j~j&.-;'-MM)VR=A. R.A., tekhn.red.
(Artificial leather] Iskusetvannaia kozha. Moskva, Izd-vo
"Soveteksia Rosalia," 1959. 8 p. (MIRA 13:7)
(Leather, Artificial)

NkRINSKAYA. A.R.; PISAREIMD, A.P.; A4~~E~~V
Improving the properties of polyamides used as finishing
coatings. YLozh.'-obuv.pron. no.2:17-20 F '590 (MIR& 12:6)
(Resins, Synthetic) (Leather, Artificial)

15(9)
AUTHOR: Alekseyenko, V. I. SOV/64-59-2-10/23
TITLE: On the Compatibility of Polymers (0 sovmestimosti polimerov)
PERIODICAL: Khimicheskaya promyshlennost', 1959, Vr 2, pp 139-144 (USSR)
ABSTRACT: In this paper problems &rising in connection with the properties of
finished products obtained by mixing various polymers are discussed
as well as methods of determining the compatibility of polymers.
V. A. Kargin, G. L. Slonimskiy, P. P. Kobeko et a34found in their
investigations that many linear polymers have the struoture of a
liquid phase, i.e. they belong to the class of amorphous polymers.
The relation between the polar and apolar part of the molecule and
their interaction play an important part in the reciprocal solubility
of polymers. In polar low molecular substancei the oriented (dipole)
effect and in the apolar substances the dispersion effect (Table 1)
predominates. Plastifiers for polar plastics (polyvinylehloride etc)
should have a polar and an apolar part of molecule, with polarity
being neither too we4k nor too strong. The re&atioii between
plastifying properties and molecular structure (table 2 according to
reference 8) as wall as a diagram of their effect in FVC (Ref 8 ~! are
Card 1/3 Phown in a iaile (Fig 1). In the papers(4089411.lheauthors pointed

On the Compatibility of Polymers
SOV/64-59-2-10/23
to the Influence exercised by the polarity of the molecules on the
odmpatibility of polymers, as may be seen also from diagrams on the
function of tensile strength of nitrocellulose films of a content
of weakly polar butadiene-styrene-copolymers or highly polar
butadiene-nitryl-oopolymers (Figs 1, 2 and Table 3)- Investigations
described in other papers (Refs 11, 12) on the plastification of
PVC with butadiene vinylidene chloride-(DVKhB-70), carboxyl-
containing and aorylonitryl-rubber types (SKN-26) ledto similar
observations. Rubber types with a polar and an apolar part of the
molecule (butadiene styrene SKS-30, M-50, butadiene methyl
styrene SKHS-30, SKMS-50) and types with only an apolar part
(butadiene SKB) have no plaitifying eXfoot on PVC (Table 4). It
may be assumed:that a polar polymer may be mixed with another
polar polymer. In this connection the nature of the polar groaps
is not important, only polarity must be sufficiently similar. On
thelother hand, also-spolar polymers may be mixed. The polymers
are mixed if the miKing process is exothermal with the exception
of SO 30 + polystyrene and SKS 30 4. SKB, which the author considers
to be anomalous. In irwestigating mixed polymers in the infrared
spectrum no changes could be observed in mixing apolar sodium
Card 2/3 butadiene rubber with polar nitryl rubber and polar nitrocellulose

On -the Compatibility of Polymers SOV164-59-2-10123
in the infrared absorption spectrum (Fig 4). Further, it was
found that the spectra are summed up. By mixing nitryl rubber
with nitrocellulose the absorption band of the OH-group shifts
(Fig 5). The additional energy o-A' intermolecular interaction in
this mixing may be approximately computed according to an
equation (Ref 19). The problem of the incompatibility of
polymers of similar poletrity - polychloroprene f PVC, PVC f
nitrocellulose - remains still to be solved. There are 5 figures,
4 tables, and 20 references, 17 of which are Soviet.
Card 3/3

S/081/60/000/01~/008/009
A006/AOO1
Translation from. Referativnyy zhurnal Khimiya, 1960, No. 14, p.-620, # 59669
ga*). fikL. -,-aA
AUTHORS: Alekseyen)~q,.V.I., Kalinina, L.Ye.
TITLE: Studies Into the Compatibility of Acetyl Cellulo.-elWith Rubber
PERIODICAL: Kozhevenno-obuvn. prom-st', 1959, No. 11, pp. 29-3,3
TEXT: - An amount of 20-50% cellulose ester (acel) with 42% aoetyl groups
and 4.2 dielectric constant at 60-700C wV added to the following r".1bber,
masticated on rollerr: CK H -18 (SKN-18);rCKH-26 (SKN-26), CKC -30 (SKS-30)
with dielectric constant --;iT
and polychloroprene rubber s of 6.4, 10.3., 2.9 d~.2
respectively. Plates of 1.5 mm thickness were removed from the rollers and
subjected to heat treatment in a press for 10 min at 1200C; extenzlon diagrains
were taken 6n a Polani dynamometer. The modification of acel properties is
possible by combining it with SKN-18 and SKS-30 to obtain highly elasticfilm
materials. The correlation of the polarity of components is a determining
factor in the combination of cellulose esters with rubber, independent of the
chemical nature of the polar groups; , the introduction of a vuicaLnizing
Card 1/2

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and polar (P) by adding a third strongly
Card are 4 figures, 2 tables, and 14 ref-
12 of which are Soviet.

SOV/76-33-4-2/32
Investigation of the Compatibility of Three-component Polymer Mixtures
rolling (140-1500C) and pressing (10 min, 150-1600C) of the
~P)-mixturss.-The experimental results which are tabulated
Table 1) and represented in a triangular diagram (Fig 1) show
that the combination SKN-26 or DVKhB-70 with "nairite" NT
proves to be a better plastifier for PVC than dibutyl phthalate
(or SKN-26 or a single DVKhB-70) and that mixtures with good
properties are obtained (if the PVC-content is not higher
than rXr/.). 2) The system polyvln~l acetate (PVA) + "nairitf; NT +
polar rubber (as mentioned above w investioated (after
1 0 as
rolling at 50-60 C). The results (Table 2) show that in analogy
to the above mentioned observations a combination of nairite
NT and DVKhB-70 with PVA yields mixtures with high physico-
mechanical properties. Theoretical investigations of the mechan-
ism of formation of ternary mixtures led to the observation
that the compatibility of three components of different polari-
ty depends on the dipole interaction and thus substances with
the same or similar dielectric constants are compatible and
that on the other hand$ a compatibility may be attained in the
case of weakly polar and polar (P) by adding a third strongly
f4
polar component. There are 4 gures, 2 tables, and 14 ref-
Card 2/3 erences, 12 of which are Soviet.

BOV/76-33-4-2/32
Investigation of the Compatibility of Three-component Polymer Mixtures
ASSOCIATION: Veesoyuznyy nauchno-i8sledovatel'skiy institut plenochnykh
materialov i iskusetvannoy kozhi
(All-union Research Institute Of. Filia Materials and Arti-
ficial Leather)
SUBMITTED: July 4, 1957
Card 3/3

AUTHORS:
TITLEt
PERIODICALt
88316
S/191/60/000/002/002/012
B027/BO58
Alekseyenko, V. I., Mishustin, I. U.
Combination of Polyethylene With Other Polymers
Plasticheskiye massy, 1960, No. 2, pp. 8-13
TEXT: The authors deal with the improvement of the plastic and elastic
properties of polyethylene. The thermal resistivity of pure polyethylene
is insufficient, and thus it is necessary to admix other polymers in
order to increase the tensile strength of polyethylene without reducing
or increasing its durability. Ye. Ye. Rylov and V. L. Karpov (Ref. 6)
proved on the basis of electronographic and roentgenographic studies of
polyethylene-polyisobutylene mixtures that these polymers yield macro-
homogeneous but not miorohomogeneous mixtures. N. V Mikha lov, Z.,V.
Ukhanova, V. S. Klimenkovt and Ye. A. Kurillchikov iRef. 7~ Point Out
that when using polymers as two-, three- or multi-component mixtures for
the manufacture of synthetic fibers, the properties of the latter im-
prove. G. L. Slonimskiy and G. V. Struminskiy (Ref. 8) proved that heat
is seDarated when mixing rubber CKE3 (SKB) and C.Yc -30 (SKS-30) with
Card 1/2

88316
Combination of Polyethylene With
Other Polymers
8/191/60/000/002/002/012
B027/BO58
polystyrene which indicates the miscibility of these products. A. A.
Tager and V. A. Kargin studied the heat of solution of polystyrene in
ethyl benzene and proved that the heat separation during solution is due
to a previous stratification of the chain molecules from CI