SCIENTIFIC ABSTRACT ROGACHEV, YE. N. - ROGACHEVA, I. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001445030004-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 65
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

IZ(JGA(.:Iii-.V, V.V.; A.A.
Microvoltmeter for use in electric Drospecting. Geofiz. prib.
no. 12.11-18 162. (M-TR-k 17: ::,')
I
I
1. 'SentralInyy nauchno-issledovatuellskiy gornorazvedochnyy
institut tsvetrlykh,. redkikl. i b-Lagorodnyl-,h metallov (for
Rogachev). 2. Oschoye konstruktorskoye byuro Min-isterstva
geologii i okhrany nedr SSSR (for Flaksman).

VORONIN, V.A.;
KHISHCRUK, A.A.; BUCHINSKIY, Yu.L.; ROGAM
KILOCHITSKIY, N.G.; LISKONOG, N.G.; 'PHEVKOV, L.V., red.
izd-va; OVSEYENKO, V.G., tekhn. red.
[Practice of constructing headframes] Opyt stroitel'stva II
b&shennykh koprov. Moskva, Gosgortekhizdat, 1963. 82 p. .
(MIRA 16:4)
(Mine buildings)

ROGACHEV, Ye.Ya., kand.tekhn.nauk
Operation of the c6oler of TEYdiesel lowamotives under winter con-
ditions; some practicai advice incited by ihe experiencle gained
din-ing the winter of 1962-1963. Elek. i tepl.tiaga 7 no.1100-32 N
163. NIRA 17:2)

ROCACIEV, Ye.Ya.2 kand.tikhn.nauk
Results of the tests of coolers with agitators on TE3 diesel
locomotives. Vest. TSNII IeS 23 no.1:31-35 64. (MIRA 17:4)

ROGACHEV, Yo.yft., kand.tekhn.nauk
How to improve the operation of coolers on TF6-3 C-Lieuol
locomotives in winter. Slelc.i tepl.tiaga 3 no.11:20-23
N '59. (MIRI, 13:3)
(Diesel locomotives -Cooling)

ROGACHEV. Ye.Ya., kand.tekhu.nauk; MAKSIMOV, V.P., inzh.
Measures for improving the vinter operating of the cooling system
of a TE3 diesel locomotive. Zlek. i lepl. tiaga 4 no.11:9-11 N
16o. (MIRA 13:12)
(Diesel locomotives--Cooling)

ROGACHEV, Yaja., kand.tekhn.nauIr
Performance of T93 diesel locomotive radiators under winter
conditions. Vest.TSNII MPS 18 no.6:19-22 S '59.
(14IRI, 13 - 2)
(Diesel locomotives--Cold weatber oDeration)

I I .. ; I - I I I . t ~ I ~;.,%,,, ; 7 .,- ~11;...,
'-:", -f ~j I
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1:', - . ~Z~ ~ I - 0 - - n. a -- . . - -1 0 (MTRA 18:3)

BOGOYAVLE:NSKIY, K.N.; GRIGORIYEV, A.K.; BORISOV, V.G.; ROGACHEV, Yu.D.
Cross stretching of strip in the manufactiwe of large cold-bent
shapes. Trudy LPI no.238t64-67 164. (MI1RA 17.11)

ARSENIN, N.D.; BUDKOVSKIY, N.G.; BOLOTIN, A.A.; BONARTSEVA, N.N.;
BOGDANOVA, M.V.; GOWVENKO, I.P.; ILIBITENK0, K.I.;
KIRPONOS, Ye.M.; KARAFETYAN, K.G.; KIRSANOVA, I.A.;
KUZNETSOV, A.L.; KORESHNIKOVA, N.F.; KOiZM- MESKAYA, T.I.;
NEMIROV,N.G.;_NIKONOVA, T.K.; NAZARCV, V.N.; PISAMA, I.A.;
POPOV, S.A.; PRONINA., N.A.; PAKHMAN, M.Ye.; REYPOISKIY, S.N.;
ROGACHEV, Yu.14.; SOSNINA, V.D.; STARSHINOV, B.M.; KHUDYAKOV,
V.I.; PARKOV., V.P.., podpolkovniky red.;
MupkiTrYEVP A.I., polkovnik, red.; CIIAPAMTA, R.I., tekhn. red.
(Relics of military glory]Relikvii boevoi slavy. Moskva,
Voenizdat,,1962. 166 p. (MIRA 15:8)
1. Nauchnyye sotrudniki TSentrallnogo muzeya Sovetskoy Armii
(for all except Muraviyev, Chapayeva).
(Military museums)

'et, On of I
V.V. lllrivjsldi-f-i~tion H'ot"
Fe'dorov 'bu of tlv~; labol"Aory, r I
f4 C: Ite ;~lectlrical ~nl-dnaeri Laabor,-~Lory (Ts
1940 C~,:Iltral -L I a
!,i-'LnL;tr- of Po-.:c-x Station--.
SC; 14 se-At. lc~53

ger con'-=npl,
-'f f ec tof 2,4-d-initrop'k-,enol on zhe W.L tln,~
E
Plants- Fizlol. rast. 1-1 z,,o.4:' ''.-606,6 T
-,0 Ti-Aryazeva U'; SSSR, Moskva.
Ty t * 1c).-ii rasterdy n ,
IS '.L Ull, 17- c,- -

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it
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Tho Ingots" of fat so *a dermarooksame of bacteria
0ai! Is tbe olorgissuft W canned W odierwise
vu K
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4.
The rcsistaum to beat of nouspoteforming bacteria is not .00
increased when the beating Is done in fats oc oil. Faisand
00 see
oils turt a Protective &CtWQ 00 the SPDMS Of the $864U$
0'5 mejejolericus grmp but only in thow cases in which the (at; =00
0 or oils we completely wthyd. In the ordinary methods of
sterilization of fotxb coutg. animal fats and ads, therefore, 0
00 many becterial spom may renutin alive so that rigid sterili- zoo
LAtiOn COGIN iOUS are neCtSIBUY for the PrCgtfV&tiOU Of
fuu,6 of this type- 51. G. NItiore zoo
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Al-SLA attALLUOGICAL CITERAT01 CLAISIFICATION
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USSR/Medicine - BEcteria. Spores Mar 1947
Medicine - GeoErkT)hy
'Thermostability of Bacteria! Spores of Clinatic
Zones," A. I. Rogacheva, All Union. Scientific
Reeeerch Institute of the Canning Industry, 4 DD
"Mikrobiologiya" Vol XVI, No
Study giving the various periods of exposure to
various temperatures necessary to kill spores of
cultures from different geographical locetions.
16T2o

0 0 04 0 0 0 0 0 0 0 0 0 0 0 0 0 0
I F, -f i7, ol~ vi~I-o'loicoul;-'I ac,~ u, s

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TT
QT IT 4 T:
I" M7~ IIT w41 9! - t:.-, i tnr o

ROGACHNVA, AL.I., kandidat tekhnicheskikh nauk.
(Microbiological control in the canning industry] Mikrobiologicheskii kon-
0
troll konservnogo proizvodstva. Moskva, Pishepromizdat. 1953. 93 P.
(MLRA 6:8) ~
(Food--Bacteriology) (Canning and preserving)

ROGACHEVA, A.I., kandidat tekhnicheskikh nauk.
Thermostatic aging of canned foods. Ref.nauch.rab.VNIIKP no.2:
13-16 '54. (MlaA 9:4)
I
(Canning tuid proser4ing)

,AQWA,-A,j_t,_kandidat tekhnicheskikh nauk; MATROZOVA, R.G., kandidat
_AW
tokhnichookikh neuk; MCKHOTINOVA, T.I., kandidat takhnichookikh
nauk; STCHZVA, M.Te., starehly nauchzkyy sotrudnik.
Schedule for the sterilization of canned foods. Trudy VNIIIP no.3:
32-47 '54. (KEBA 9: 8)
(Canning and preserving) (Steriliz&tion)

ROGACHEVA, A.I.
Phy-toncidal properties of the plant raw material in the canning
industry. Pr1roda 44 no.12:95-98 D 155. (MLRA 9:1)
l.Vaesoyusnyy nauchno-isolodavatellskiyy institut konverrnoy
proqrshlennosti.
(Phytoncides)

ROGACHEVA. -Aleksandra Ivanonf~; TOKIN, B.P., professor, retsenzent,-
KASLOYA, Yed., redaktor; YAROV. N.M., tekhnicheskiy redaktor
[Plortoncides and their use in the canning industry] Fitontsidy
i ikh isoollzovanie v konservnoi promyshlennosti. Moskva,
Pishchepromizdat, 1956. 88 p. (KLRA 10:2)
(Canning and preserving) (Phytoncides)

,6AWAGU I"Alrandidat tekhnicheskikh nauk; KOSTROVA, E.I., mladshiy
nauchnyy so trudnik.
Microbiology of tomato products. Trudy VITIIKOP no.6:96-110- 156'~--:-
(NLRA 165)
(Tomatoes) (Food-Ifteteri6logy)

q C
ussR/Microbiology - sanitation Microbiology F-4
Abs Jour : Ref Zhur - Biol., No 3, 1958, 9890
Author : Rogacheva, A.!., Kostrova, E.I.
Inst
Title Microbiology of Tomato Products.
Orig Pub Tr. Vses. n.-i. konserv. i o-roshchesushil'n. prom-sti,
1956, No 6, 96-11o
Abstract Ca=nings containing tomato sauce are sterilized for a
shorter period of time than other cannings. It was con-
sidered that this is due to the bactericidal action of
acids contained in tomatoes. Investigations showed that
it was also due to the presence in tomatoes of phytoci-
des, active in regard to Bacillus mesentericus, Saccharo-
myces cerevisiae, and mold of the Penicillium type.
Bactericidal properties of different kinds of tomato jui-
ces vary in degree.
Card 1/1

RO
Production of canned sauerkraut. Ions. I ov. prom. 12 no.3:44 & 157.
(KERA 10:5)
1. famoyuznyy nauchno-Issledovatellskly Institut konservnoy I
oveshcheaushillnoy promWehlemosti.
(Sauerkraut)
E

ROGAGIBIVA A. 1
4, !- - W
Cleandine.-B-s-as an-important factor is quality improvement of caused
foods. Kons. i ov. prom. 12'no.4:39-40 AP '57. (KLRA lo.6)
(Canning and preserving)

,',-.RMAGHNVA, AJ..
Microbiological control injish-canneries. Xon9A ov,]prom. 12
(YJARA 10:8)
(Fishery products--Bacteriology)

ROGACHEVA, A.I.
Mier,-%biological control in the canning industry. Kons. i ov.
prom. 12 no-7:23-25 Jl '57. (MMA 12:4)
1. Veesoyuznvy nauchno-isaledovatellskiy institut konservnoy i
ovoshcheaushillnoy promyshlonnosti.
(Food, Canned)

APT., F.S.; KOSTROVA, Ye.I.; MATROZOVA, R.G.;HEKHOTRIOVA, T.I.;--&0GA-G~,,
NOSKOVA, G.L., kand. biol. nauk,, retsenzent; SY-CBEVA, M.Ye.,
mikrobiolog, retsenzent; NAMESnUKOV, A.F... kaiid. tekhn. naukv
spets. red.; MURASHEVA, 0.1., red.; SOKOLOVA, L.A.., tekhn. red.
[Microbiological control in the canned food, concentrated food and
dried vegetables industry] Mikrobiologicheskii kontrol2 konservnogo,
pishchekontsentratnogo i ovouhchasushill.nogo proizvodstva. Mosk7a,
-PO WRA 140-1)
Pishchepromizdat, 1961. 114
(FOOD-MICROBIOLOGY)

tF~ r3"

SIMONOVICH, N.M. Q.Gorlki7); ROCYACHNVA, E.p. (g.Gorskir)
Detection of ionizing radiations. Fiz. v shkole 16 no.2:75-76
Mr-AP 156. (NM 9:6)
I.Meditsiaskiy institut.
(RADMACTIVITY)

ZFIOLKEIVI'~:!!, V.1N. ; KHOLLER, `V". A.: ROGACHEVA, A.Y a.
Correlat.-Lon between .-espira-11ion and '-eat, loss in Fro-win'-, leaves. DGki.
(MTR ~
91 SSSR 158 no-1:121.3-1216 0 164. ~ _, 17: 10)
1. Institut fiz-iologii rasteniy lm. K.A.Tiriryazeva All SSSR i Moskovs'f-liy
gosudarstvennyy universitet im. M.V.Loiponosova. Predstavleno akademikom
A.L.Kursanovym.

ZHOLKEVICH, V.N.; ROGAGHEVA, A.Ya.
Effect of water deficiency on changes in the acid-soluble organo-
phosphorus compounds in plant tissues. Dokl. AN SSSR 151 no.2:
456-459 J! 163. (MA 16.-7)
1. Institut fiziologii rasterdy im. K.A.Timiryazeva AN SSSR.
Predstavleno akademikom A.L.Kursanovym.
(Phosphorus organic compounds)
(Plantsp Effect of aridity on)

BELYUSTINI) A~V,; ROGACHEIIA, E.D~
,. - - ~~%j
... 1.
Formation of crystallization conteru in the preoerice of the
seed crystal. Rost krist. 4:5-9 '64. (MIRA 17.,8)

X-Ra, investigation of the structure of alloys in the system
CL;',-sSe2-Ga_0Se3-L. S. Palatnik, Yu. F. ';,cmnik, Ye. K. Belova.
Eiecrrical and optical properties of alloys in the system CuGaSe2-Ga2Se 3'
Koshkin, L. G. Manyukova, Yu. F. Ka-nnik, L. S. Palatnik.
X-Ray investigation of the system CuInSc2-In2Se3. L. S. Palatnlic,
Yu. F. Kamnik, E. 1. Rogacheva, L. V. Atroshchenko.
'Electrical propertie's -of alloys in the system CuInSe2-In2Se3.
L. S. Palatnik, V. ti. Koshkin, Yu. F. Komnik, L. N. GaPchinetskiy,
L. G. Manyukova.
'ence on Semconductor Corpo~unds,
~Ieport presented a'. the 3rd National Confe:
KisUnev, 16-21 Sept !963

SYROYMMOVSKY, Ye.1 - RG"GHAVA, E.V.
Recent data on th distribution of some birds in the taiga of
the Yenisey Valley. Probl.Sev. no.2:20-3-211 '58.
(MIRA 12:4)
1. Institut geograft-, Iq SSSH.
fend ey Valle~--Birds)

SYROYECIIKOVSKIY, Ye.Yo.; ROCkkCHEVA. S.V.
Recent data on the distribution of birds in the taiga of the
Yenisey Valley. Report Mo.2. Probl.Sev. n0-3:91-97 '59.
(MIR& 13:4)
1. Inatitut geografil AN SSSR.
(Tenissy Valley--Birds)

SYROYECHEOVSKIY, Ye.ye.; ROGACIIEVA,,__~~,.,V.
Birds and mammals of the Yenisey forest tundra and the effect of'
economic activities of man on them. Pxroibl. Sev. no.4:95-107
161. (MIRA 15:1
(Yenisey Vall-ey--Zoology)

ROUCHEEU, E~V~
Conference on the problems of the organization and methods for
taking,the census of animal resources. Izv. AV SSSR. Ser. geog.
iLo.6:162-163 N-D 161. (MIIU 14:12)
(Animal population)

S)WrECHYxOVSKIYj, Ye.Ye., kand.geograf.nauk- ROGACICEVAj E.V. (Moskva)
0 -j-
Sables and wild ungulates of the Yenisey area of Siberia.
Priroda 50 no. 3:102-101+ Mr 161. (MM 14:2)
(Yenisey Valleym--Zoology)

ROGACHEVA E V.
Abundance and distributiorr-of birds in the lower Yeloguy I
Valley (Yenisey Valley taiga). Ornitologiia no.5sllg-134 162.
--. - (KM 16s2)
(Yeloguy Valley--Birds)

CHOUNSI, D.Garris (Chauncey, D.Harris); FRENCH, R.A.; ROGACHEVA, E.V.
(translator]; STANOVA, T.A. [translator]
Foreign scientistalstatements on Soviet geography. '.1ay. AN SSSR.
. Ser. geog. no.4:106-109 Jl- 162. (KMA 16:5)
~Geography)
m

GEFTER, Ye. L.; ~ ~ACHE~VAI.~
Interaction of aryldichlokoPhosPhinea vitb cyclic oxides.
Part 5: Reaction of chlorophavy1dichlor*pboaphine vith
.i D 162.
ethylene oxide. Zhur. obo khiz. 32 noo22-.3962-396,
(MIRIL 16:1)
1. Nauchno-issledovatellskiY inatitut plasticheiMdkb mama.
(Phomobine) (Ethylene oxide)

OSEFTER, Ye.L.; ROGACHEVA, 1.
Interacticn of ax- dichlorophosphines 144tl% CyCliC ox-l-des. Fart F;:
J 1
Interaction of toly1jichlorophosphine with ettylene
khim. 34 no.1:88-91 Ja ~64.
w-, -i'l F-L~ . Dart
~Iyj g: acid.
"V-94 (MIRA 17:3)

1 00891-66 WrW/EPF(c)/3-JrP(j) RM
ACCESSION UR: APS020085 UR/0079/65/035/008/1463/1467
547.261118 547.361
Rogache
~AUTHOR: Gefter, Ye. L: va, 1. A.
'TITLE, Interaction of. 1-,;qfith cyclic oxides. X. Contributioni
Ito the* problem o the 116 eriza onto ~chloroethyl esters of
-arylphospho- I
4
inous acids
Zhurnal obshchey khimii,.v. 35, no. 8, 1965, 1463-1467
r
ITOPIC TAGS. chlorinated aromatic compound, isomerization, cyclic. group, aromatic..
-1hydrocarbon
ABSTRACT: Several B-chlaroethyl esters oflaryl-B-chloroethyl asphonic acids of,a
~ph
X 0
Igeneral foinula
CH >P0 CHLCH,op < > POCH'C"'Op < + CICH,CH,CL
0 0 0
CHCH&CI [WA-50; CBE No. 121
SU15 CODEt- 07/ SUBM DATE: 20Dec65/ ORIG REF: 003/
Card 1/1 UDC: 547.26,118

J~ 34022-66 Ew (m)/EwTp T.jp(c) am
ACC NR 'I P6025533 SOMC3 CODE: UR1007916'61 061-1007WrOgi
AUTHOR: Geftor, Ye. L.; Rograchova, I. A.
ORG: -Scientific Research Institute of Plastics (Nauchno-issledovatellskiy institut
plastia~lesi rmass~~~-
TITLE: Reaction of ary1dichlorophosephines with cyclic oxidese XI. Syntheses of
eaters of Dhosphorus acid and ethylene glycollby thermal selfcondensationl
SOMCE: Zhurnal obshchey khirdi, ve 36, nos 1. 1966. 79-81
TOPIC TAGS: ester, phosphorus compound, otjiyleno glycol, condensation reaction&
chemical syntJiosis, UV irradiations chemical bonding
ABSURACT: A simple method was developed for'synthosizing esters 6f phosphorus
acids and OthYlOnG C1Yc0l by thermal 3elf-condensation of mono-bet-2-
ehl0r08thYl esters of the corresponding acids at 200-2400. The structures
'of some of those compounds ware confirmed by converting them to the corres-
Pending acid chlOPid0s (with PM ". as-well as by countersyntheses. The
invarianco of the rate of the QrEcondensation reaction in the presence of
Initiators and inhibitors of radical c"Gost as well as under the
Influence of Atggwiclet Irradiation, makes a free radical mechwdsm of
this process improbable. The authors ocasider a heterclytie oomrse of the
thermal welf-condensation (in the polar nedia of the esters thomwIves)
Card

ACC Nks AM25533.
accomplished as a sequential or simultanet"as cleavage of the and C-Cl
bonds, to be the most probable mechanism. nve prwicudy wkwwn eaters
of phos;A" &cIds and ethylene glywl Were eyntheid.sed..and Characterized.
Origo &A* has: 1 table- V-PRS: 35.9"J
SUB CoDr.-: 07, 17 Soil DATE: 22Feb65 ORIG REF: 007 OTH REFs 002
Card 2/2 P"

GaT-R, Ye.L.;, ROGACIDIN.A I.A-
Interaction of aryl dichlorophosphines with cyclic oMPOOd. P* Ov
Arbuzov rearrangement of di-~'IN chlorethyl eaters of phe4l- and
chlorophenylphosphinic acids.2k;.ob.khim. 33 no.4:1177-1180 Ap 163.
(KMA 16:5)
1. Nauchno-issledovateltskiy institut plasticheskikh mamas
(Phosphinic acid) (Esters) (Rearrqngements (Chemistry))

S/079/62/032/012/003/008
D424fD307
Ceftcr Yc-..L. and
Rogacheva, 1,.A.
T IIL ~.teaction of arylphosphonous dichlorides with cyclic
oxides. V. Reaction of chlorophenylpliosphonous
dichloridc with ethylene oxide
1) 10 DCAL Zhurnal obshchey*hhimii, v. 32, no. 12, 1962,
3962-3965
The rcaction with a chlorophenylphosphonous dichlor-
ide consisting mainly of the ;)-isomer wit'n a small amount of m-isoI- 1,/
mer proceeds readily to give di-.0 -chloroethyl chlorophenylpl~os-plniin-
ate (11). Thi-- ester could not be distilled evc-ti at i-2 nim 1-19 with----
out isomerization with evolution oll" heat to givc 0- -chlorocthyl.
chlorophonyl-P -chloroethyl-phos,,hinate (III). (III) was obtained
in pure form from the crude iGomerization product by converting it
with PC15 into the c6rres-pondingr acid chloride, purifying this by
distillation, and treating it with ethylene oxide. Even pure (III)
decomposed on heating with the evolution of dichloroethane (this re-
Card 1/2

S/p79/62/032/012/003/008
action wiLL be cxcuiincd ilija subsequent coi,,imi,.-aication). TreatmcuL
oi tl-ie cl-ilorojAienyl- '21 -cl-iloroethylphospl~inic. ~bliloride obtaincd trom
(III) i-rith-triethylamine gave chlorolilienylvinylphos-,2hinic. chloride.
The adclition of sulfur to- (11) gave di- P -chloroethyl chlorophe" I
phosphonothioate. 1 t1v--c-,-cothermic reactions described libe:
less heat than the corresponding, reactions of the unsubstituted
phenyl compounds describc4 previously.
AS'SO G IAT I ON -11-auclino-issledovatellsl,-.iy institut p1ast'L-,hc--kihh
mass (Scientific Research Institute of Plastics)
SUBMIT'rED: December 27, 1961
Card 2/2

GEFTER., Ye.L.;-RQq_A~HEVA, I.A.
Interaction of aryldichlorophosphines vith cyclic oxides. Part 4:
DeriVatives of phenylphosphinic acid. Zhur.ob.khim. 32 no-3:
964-967 Mr 162. (MIRA 15:3)
1. Nauchno-isaledovatel'skiv institut plasticheskikh mass,
(Phoaphinic acid)

GEFTERY Ye. L; ROGAGREVA, I.A. _
Reactions of aryldichlorophosphines with cyclic o#des. F
Derivatives of j:Gienylvinylphosphinic acid. Zhur. ob. khi,
no.3:955-958 Mr 161. (MI,
1. Nauchno-issledovatell Aiy institut ~lasticheskikh ma
(Phosphinic acid

21087
5/07 61/031/00A,/011/013
B 1 IN3207
.1
AUTHORS: Gefter, Ye. L.-44, and Rogaoheva, I. A.
TITLE; Rea,~tion of aryl dichloro phosphines with cyclic oxides.
III. Derivatives of phenyl-vinyl phosphinic acid
PERIODICALz Zhurnal. obshchey khimii, v. 31, no. 3, 1961, 955-95a
TEXT% Taking account of the papers by M. I. Kabachnik on the eynthesis and
applicability of vinyl phosphinates (Ref. 21 Izv. AN SSSR~ OKhN, 1947# 233),
as well as by G. Kamay and V. S. Ts~junin on the synthesis of ethyl-vinyl
phosphinates (Ref. 3: DAN SSSR, 128' 5,1-4, (1959)), the authors synthesized
some hitherto unknown phenyl-vinyl phosphinatee, proceeding from the provi-
ously described (Refs. 4. 5: ZhOKb 1'. 949 (1961); 7,bOKh ~1, 952 (jq6Q) .
phenyl-,A-chloro ethyl. phosphinates (IT'and the phenyl-viny] phosphinic acid
chloride. When treated with alcoholic alkal-i lye or triethyl amine in
equimolecular ratio, the esters (I) split off HC! and were converted into
the respective phenyl-vinyl phosphinates (II), the constants of which are
giver, in
tabls,f,-chloro ethyl ester no. 3 could only be obtained from
a
triethyl &mine, in the reaction of PCI 5 with pheny'.'.-vinyl phosphinates, the
Card 1/4

21087
S/079/6!/O3!/0O31/O';1/O13
Reaction of aryl B 1180 /B207
eater bond was eaaily split under the formation of phenyl.-viny) phosphinic'
acid chloride (Ifi)f
C6H 51, 0
P + PC1 5 -4 C 6H5 0
POCI RC1.
CH - CH OR
2 f,
CH ~C4 III) C1
2
Compound (III) was also obtained by reaction of phenyl=A'--chloro ethyl phos-
phinic acid chloride (V) with triethyl amine. Chlorine is more mobile in
compound (III) than in the acid chloride (V)y and hyrolyzes rather quickly
in the air. The hydTolysis of compound (III) yieldB.phenyl-vinyl phosphinic
acid (IV)andg when it is treated with alcohol, the ester of this acid is
obtained. Thus it was shown that the esters (II) may be obtained in two
wayst from the esters of pheilyl-f,--chloro ethyl phosphinic acid and from
the phenyl-vinyl phosphinic acid chloride. The reactions are i2lustrated
by the following scheme:
Card 2/4

S/079/61/031/003/011/013
Roaction of a ry I ... Bl-18/B207
0 C it, 0 C It 0
~~pe 5>p//
CIC11"Cil \C, Cll-,-C1l-/ \C1 C112=Cli \oil.
(V) (IV)
110111tKI,
OA C,11 0
C6115,\ /0 Koll si,.,fil N(Clf,).
P/ 5 p OR
a) or). There are 1 table and 7 Soviet-bloc re&rences.
ASSOCIATION: Nauchno-issledova'vel'skiy institut plasticheskikh mass, Moskva
(moscow Scientific Research Institute of Plastics).
SUBMITTED: April.26, 196o
Card 3/4

21087
S/07 61/031/003/011/013
Y
Reaction of aryl B118 B20 7

%P

n. 11.
d," Dwo

Al
Shl"O.-

E, ACHO JIP 0
/T,

i MOTIMOMIrt . . . . . . 93-950 1-9336 IASSO 56 16.8 17.01
2 DTimomift . . . . . t 16-118 1.5249 1.1150 82 15.6 15.79-
3 3-X:10P:)TIT.IODLIrI * . : J23-125 1.5395 4.2392 61 13.2 J 3.43
4 .
. . . . . . . . IIS-120 1.5170 1.1120 86 14.6 14.74
5 ii.-OvTmionuri ** . . . . . . 120-122 1.5119 A.0899 73 J 3.65 13SI
6 Azalmonfirt . .. . . . . . . . tIS-120 1.5278 U295 70.5 14.69 14.89

7
(De
,mmomart . . . . . . . . . -133
130
1.5391
U025
69
12.59
12.6&
Legend to T able: a) no.; b) ester; c) b oilin g point (1 mm pressure); d)
yield; e) f ound; f) calculated; 1) methyl-;' 2) ethyl-; 3) 11-chloro ethyl-;
4) propyl-; 5) n-butyl-; 6) allyl-; 7) pheny l,
Card 4/4

E
I -,-N
ww~~