SCIENTIFIC ABSTRACT GELPERIN, N.I. - GELSHTEYN, A.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000514710010-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

PWAULMO X.S.; VOYfaMCHS S.A.; GELIPERIN, N.I.; OGOROD,'.'IKOVA, Ye.A.:
DUCHINSMA, Yu.1.
Sojarating C 'I - CI,7 tstr&chlorO&lkanes from tolomer mixture3.
Trudy VIIIISai no.3185-92 161. (14IRA 14:10)
(Polywris) (Paraffine)

FRU4KOA, N.S.; ZELENETSKIY, I .1.N.; VOYTUVIGJlp S.A.; GE.-.,'F"rRlNj N.I.
Separation of macrocyclic lactones by vacuum rectification,
Trudy VNIISNDV no.5:93-98 161. (MIRA 14:10)
(Lactonea) (Roctification)

KISEIZVA, Ye.N.; GELIFERINO N.I.; SIIESTAKOVA, V.A.; ZELONNTSKIY, N.H.
--------------
Una of extraction by pairs of solvents for the parification of
phanyl ethyl alcohol, VNIISNDV no.5:102-107 161. (MIRA 14:10)
(Phenethyl alcohol) (Extraction (Chemistry))

YUSHIIIKOVp V.V.; VOYMNICIlp S.A.; GELIFERIV, N.I.
Continuous method for manufacturing benzyl acetate. Trudy .
VNIISNDV no.5:107-110 161. (HIPA 141101
(Acetic acid)

OILIPERINO N.I.; ASSMUS, M.G,
Mass transfer in injector extraction columns. Kbim.prom. n0-5:348-350
MY 1621, (Extraction apparatus) (MIU 14t6)
(awo tMusfer)

GELOPERIN# Nal,; AYWHTLYN, V,G.
Analogy between a fluidized bad of granular material and a fluld.
particle system. Mim.prom. no.3-1:750-756 N 161. (HIRA 1513.)
(Pluidization)

GELIFMDIP N.I.; KVASHkr V.B.
Determining and securing a4 optimum temperature field in chemical
reactors. Xhim.i takh. topiel masel 6 no,209-45 F 161,
(MIFA 14: 1)
1. Moskovskiy iwtitut tonkoy kh'sicheskiy tekhnolog:ti la. N.V.
INomonosova's
(Chadcal reactiont Beat of)
(Chemical engineering-Squipment wA supplies)
b P

I
--G.ELIPERRI, N.I.; NIKIFOROV9 VeAs
Absorption of CO and 12S from compressed ganes by cooled methyl.
alcohol in a paciq~ columna Gas*prome 6 noe,4:39-45 161,
(MIRA 14:3)
(Gases-Purification)

GUIPERIN, N.I.; AYNSHTEYN) V.G.; RADIKOp A.I.
ControIled proportioning feeder delivering finely divided materials
to a fluidized bed. Zhur,VKHO 6 n0-53587-588 161. (MM W10)
1. Hoskovskiy institut tonkoy W-4cheakoy takhnoloGii imeni
MoVeLomonoam"
(Fluidization-Equipment and supplies)

GELIPERIN, N.I.; GRISHKO, V.Z.
Using injector adsorption apparatus for removing carbDn dioxide and
hydrogen sulfide from Cas niabures. Gaz. prom. 6 no.6:46-5Z '61.
(MIRA 14:9)
(Adsorption apparatus) (Gas)

GELIFERIN, N.I.; GRISHKO, VA.
Absorption of COS and W by water oolution-9 of monoetMno2amine.
Gaz. prom. 6 no.12:46-51 161. WMI 15:2)
(Absorption)
(Carbon dicocide)
(Hydrogen oulfude)

GELIFEMN, N.I.1 AYNSHTEYNp V.G.; KLYUYEVAp L.M.
Determination of the specific gravity of Ion excluLnge resina in a
hydrated state. Zav.lab. 27 no.nsl375-1376 161. (MIRA 3j,: 10)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni M.V.
Lomonosova.
(Ion exchange resins)

KISELEVA' re.N.jGELIPMNp N.I.g SHESTAKOVAq V.A.
9
Rowel of impurities frm phonylethyl alcohol extraction vith
,rapor solvents in an injection column. Zhur. prikl. khim. 34 no.lt
167-172 %Ta 161, (KMA 343 1)
(ftonothyl alcohol)

BAIAKHONTSEVAj, V.N.; GELIFEMN,. JI.I.
Separation of a mixture of polyatomic alcohols. Khim.prom.
no.2:86-88 F 162o (MIRA 15:2)
(Alcohols)

GELIFFMN, N.I.; FEBALK, V.L.; KUMEMOVA, M.I.
Rotary extraction column with alternating mixing packln&free
separation zones, Zhur.VKHO 7 no.1:114-3-15 162. (MM 15:3)
1. fbakovskiy inotitut tonkoy kbiralcheskoy tekhriologii imeni
Lomonosova.
(Extraction apparatus)

GELIPERIN. N.I,j YNSHTSIN, Me
Effect of the size and specific gravity of* solid particles
on their coefficient of heat transfer toward gas in a
gluidized bed. Khim. i tekh.topl.i masel 7 no.3:6-9 Yx 062".
(MIRA 15:2)
1. 14ockmakiy inatitut tonkoy khimicheakoy tekhnold1PKm-
M.V. Lomonosova.
($1uidization)
-M.'. does_ ranamissiop)

S/08 62/035/003/007/024
D258%302
AUTHORS: Gel'perint No I.f Aaamuot M. G.j and Korovin, S. S.
TIT"-': Recovery of gallium by the method of liquid extraction
in a continuoualy operated injector column
PERIODICAL: Zhurnal Prikladnoy khimii, v. 35, no. 3, 1962, 516-519
TEXT: The authoro investigated the continuoua, liquid-liquid ex-
traction of gallium from aqueous solutions of a copper-bearing re-
sidue obtained in the course of aluminum electro-refining. A Elolu-
tion containing Ga (0-48 g/l)p H so (7.2 14), Cl-(67.7 g11) and also
2 4
V9 A19 302, Fe, Mo, Cu and SiO2 was brought up to a Cl content of
96.6 9/1 and diluted until its H 2so4 concentration was 6 11. This
solution and butyl acetate were injected, counter-currently and
continuously, at the top and bottom, respectively, of a 900 mm co-
lumn designed by N ii)Gellperin and coworkers (Ref. 1: Xhim. nauka
,6 The gallium-bearing extract was continu-
i prom. 5, 5609 (1;9;
Card 1/2

3/08 62/035/003/007/024
Recovery of gallium ... D258%302
ously withdrawn near the top. Recovery of gallium varied slightly
with the volum(,, ratio of butyl acetate to aqueoun solution, namely,
from 960' at a ratio of 0.23 to 99-50p at 0.92. The increase in phazue
ratio was accompanied by a decrease in the Ga concentration in the
extract - from 2.062% at the lowest mentioned ratio to 0.619% at
the highest one; at the same time, Ga in the aqueous phase decreaoW
from 0-014% to 0-005~o. The withdrawal of samples at different
points of the column showed an almost linear relalAonship of sol-
-vent concentration with column height. The same column was used
for the re-extraction of Ga from butyl acetate by meano of water;
,a complete recovery was achieved with a water/acetate ratio of
0.20. Adaptation to industrial plant scale was dikicuesed. There
are 3 figurea, 2 tables and 3 Soviet-bloc referencoo.
ASSOCIATION: Mookovskiy inatitut tonkoy khimicheukoy teklinologii.
M. V. Lomonosova (The Moscow Institute of Fine Che-
mical Technology im. M. V. Lomonosov)
SUBMITTED: July 11, 1960
Card 2/"2

BMWER, Yarojlevv, inzh.; SOKOL, DraUorir Sokol, Drahom-ir], inzb.;
AYNS"MI, V.G., kand. tokhn. naulcy Itranslator]; G&LIFERDI,
e 0 11.
N.I.,j-doktor tekhn. nauk, prof.,7 red.; TITSr-AYA, B. 'T
--TOLO-SIIIA, A.S.,, tokbn. rod.
[ToOmiques of fluidization]Tekhnika psevdoozhi,-,hcpIia. Pod Md.
N.I.Ciel1j;erina. Hoi3kvap Goot.optekbizdat, 11)62. 1!9 P- Irapslated
from the Czerb, (MIRA 15:12)
(Fluidization)

GELIFE doktor tekhn.nauk; FIMALK, V.L., kand.te?hn.nauk;
SHASHKOVA, M.N.
Horizontal multistage tube-stil.1 extractors KhLaoprom,
no.6s427-433 Je 162. MM 15:11)
1, Hoskovskiy institut tonkoy khimicheekoy tekhnologii im. M.V.
Lomonosova.
(Extraction apparatus)

GELIFERIN N I doktor tekhn.nauk; TYIIFT111, Ye.P.j. kand.tekhn.nauk
Methc-I for calculating the concentrations of d13solvable
substances in a multistage countercurrent washing of
precipitates. KhIm.prom. no.9:601-603 Ag 16,2. (MIRA 15:9)
(Chemista-Y, Technical)
(Leaching)

GELIFERIN, L.;.j_PODGAYFTSKAYAp 0.1.1 DUBININ, M.K.
Dryer with a fluidised bad for oebacia acid. Xtdm.prom, no*9t
689-690 S 162. (MRA 15ill)
(Nizhnyi Tagil-Sobscio acid)

AYNSHTE
,G&LiPE~IN YN, V.G.
Thermal detign of a pmeumatic conveying tube. Khiju.prom.
,no.10:753-757 0 062, (MI;A 15:12)
(Fluidization-Equipment and auppliois)
- . . ,

AYNSHTSYNO V,G,j RCHANOVAp N.I.
Hydraulics and heat transfer In a fluidized bed with an upr1ght
tube bundle. Xhim.prom, noUMI-788 N 162. (MM 16:2)
(Fluidizaticn-Equipment and supplies)
(Heat-Tr-n-losion)
~ I - ~; - 1. 1 ~Z.i:,--t, --f
.. . ~ - I - k ~ -:~: ... 1. . - - .

OIZHOV, Ye.B.; BLYUXWM,, Z,A,; GKLIFMN, N.I.
Purification of acetic acid and the resoval of formic acid from it.
Neftekhimila 2 no.5071-775 S-0 162. (MRA 14s1)
1. Institut Makicheskoy fisiki AN SSM.
(Acetic acid) (For3do acid)
f7

prof.; ZELIKSON, GAj RAPOPORr. L.L.j YANTOVSKIY,
S-AVjP iia-; KOGAN, V.V., tekhn. red.
(Manual on the low-temperature aeparation of gas mixtures]
Spravoohnik po razdelentiu gazovykh Bmesal metodom glubokago
okhlazhdonlia. Izd.2. parer. Pod obahchei red. N.I.Gollperina.
Moskva, Goakhimisdat, 1963. $12 p. (MIRA 16:7)
(Gases--Separation)

GELIMIN, N.I.; PEBAIA, VA.; ROZOV, V.N.;ASMS,, M.G.; MIIDVAIOOVA,, I.B.
Extractive purification of nickel solutions from iron and
copper impurities. TSvet.met. 36 no.207-42 F 163. (KMA 16:2)
(Nickel-Electrometallurgy) (ElectrolAes)
(Extraction (Chmistry))

OKLIFEM N.I. FMATETSMAp 0.1.; DUBININp M-K-
Process of curing of pentaerythritolp polyvinylbutyral, and suasion
polystyrene in suspension* PJAst.wasy no.4:31-34 163. (MIM 164)
(Polymers--Dz7ing) (sumpensiorw (Chemistry))

GELIVERIMP N.I., doktor takhn,nauk; KRUGLIKOV, V.ra.0 kand.tekhn.nauk;
AMYTEIN) V.G', kand.tokMnauk -
Effect of the geometrical characteristics of a fluldIsed bed
mid of a surface of heat transmission on heat transfer between
the bed and the surface placed into the bed, Nauch
Ukrnliproekta no.8123-33 062. iXSaMPA" 16d)
(nuidliation) (Heat-Transmission)

GELIPERIN N It doktor tekhn,neuk; KRUGLIKOVp V.ra,, kand,takhn.naukl
V,G,, kand,tekhnonauk
Heat tranofer between the fluidized bed and a eingle tube
placad into the bed, Mauch. zap. Ukmiiproekta no.80447 062.
(KIRA 16s1)
(Fluidization) (Heat-Tranaminsion)

OSLO PIMIN j IDILISONO Ye.M.; LIVSHITS, A.K.; BORISENRO, A.T.;
'79t,"Blact V,I,
Improved method for the production of xanthaites., %port no.4:
Preparing xanthates by the continuous method from Isobutylv
butyl SK, and iBopropyl alcohol. Sbor. nauch. trud. Gintevet-
meta no.19:255-262 162. (MIRA 16t7)
(ranthic acid)

GELIPERINV N.I.; PEBALK, V.L.; CHICHERINA, T.G.
Packed pulse coluums for extraction* Khim. prom. no.2:111-3.15
IP 163. (MM 16:7)
(Packed tomrs) (Extraction(Chanistry))
(Vase transfer)
7-777 777777777

ZAK# I.I.S., inzh.; IMZEROVICH, C.Y&., kwid.tekhn.nauk;,GELIFIM, N.I.,
doktor tekhnonauk# prof*
Study of a cold model of a double-chamber reactor fo- roasting
in a fluidized bad. Khim.mashinostr. no-3:8-12 1-~,-je '63.
(NIRL 16: 11)

doktor tekhn.nauk, prof.; AYNSHTEYN, V.G., kand.takhn.nauk;
KVASHA,, V.B., kand.takhn.nauk; KOGAN, A.S., inzh.; VILINITS, S.A., kand.
tokhn.nauk"
Apparatus for clasnifying fr'soo-flowing materials in a fluidized bed.
Khim.mashinoatt. no.61ll-16 N-D 163. (MIRA 170)

KASHNIKOV, V.V.-, 0,N.
rharacteristie of the process of aaponifIcAtion :,' benzyl
chloride. Trudy VNIISNDV no.6il5G-156 163. OEPA 17W

GELIPERIN, N.I.; IIEBUK, V.L.
Calmdation of the processes of rectification of b1nary Mixtures
in the y - x diagram. Dim. prom. no,6t440-41#5 Je 163.
(WRA 16 s 8)
(Distil-lation, Fractional)
(Plate towers)

GEL I PERIN, N.I. - DUB! U "N. M-K.; ~"(! -,,-7' ',-- ", i`
I . 1. 1 .
. ~ ;~c nt,7 ' , 3 1--, 4,j fjjl,.,jjze3
ContInlious dT-jlng of free-f",~,vr,g .L.Y
bed and in suapension. Ilim. prom. 'C-?71, 0 16).
(M,RA

GELIPERIN, N.I.; AYNSHTEYN, V.G.j ROIWOVA, N.A.
Hydraulics and heat exchange in a fluidized bed with bundles of
vertical pipes. Khim.prom. no.11:823-830 163. (KMA 17:4)

GELIPEMN, N.I,; PEBALK, V.L*
Problem of the average driving force of count4jrcurrent Mae
trander procsisseis.,Zhur, VKHO 8 no-5:595-596 163.
(MM 17;1)
1. MoBkovakiy inatitut tonkoy khimicheakoy tokhnologi:L
imed Umonosova.

GELIPERINP M-1 - PEBALK, V.L.; BARANOVA, Z.P.
Study of mass transfer in rotating disk extracWroo Min i
tekh. topl. i matiel 8 no.6:46-52 Je 163. 04IRA 16-6~
1. InBtitut tonkoy khimicheekoy tekhnolo Li im M.V. l4wonosova.
Extraction ap ratual
Mas transferr

GZLIPERIWI,,,~J.; AYNSHTZYN,, V.Gs; ROHANOVAp N.A.
lbthod of determining the bydraulic resistwice of a
f2uidized bad. Din. i tekh. topl. i mavel 11 no.9$1640
S 163. (MIRA 16t 11)
1. Moakovskiy institut tonkoy khisicheskoy takhnologli im.
M,V. Iomonosova,

MILOSERDCVp P.N., Inzh.; NAUMENKO, P.V., inzh.; GELIPERIN, II.I. doktor
tekhn.nauk
Distillation and rectification of synthetic fatty acids. Masl.-
zhir.prom. 29 no.lltl6-22 N 163. (MIRA 16:12)
1. Volgodonskoy filial Veasoyusnogo nauchno-is.31,.,dovatel'skly i
proyektnyy institut sinteticheskikh zhiro--amen.Lteley (for Hilo-
serdov). 2. Gosudarstvonnyy komitet po pishcha-my prmyshlennosti
pri Gooplane SSSR (for Naumanko). 3, Moskovski;r insti ,tut tonkoy
khimicheakoy tekhnologii, imeni M.V.Lomonosova (for Gellperin)e

GELIPERIN, N.I.; ZELENETSKIY, N.H.
Regularities of the process of mass transfor during va=n
rectification in packed columns. Zhur. prikl. khIm. 36
no.llt2445-2456 N 163. (MM 3-7: 1)

N. L "' PEBMX V. L. ; YURCHEINKO, 11. "USSN7_13, 1-1. G.
SHPV51OCOVA`,'__M. -n.; CHICKERINA, T. G.; 7AMSHLYMEN, V. G.; (-HEX:TC)WV, Y". K.;
KUMETSOVA, M. 1.
"Investigations In the field of the technique of liquid extraction."
report submitted for 2nd All-Union Conf on Heat & Maor, Transfer, IMinsk, 4-12
may 1964.
Moccow Inst of LIght Chcmieal Technology.

RA',IMNO, lasy "folseyevich; GFLIFIERVIIA I za-11. uo~atcll naulci
i tekhniki doktdf_tekhn. nauk, FJ1.0t., ret.,,,or.2nnt;
TlTO"KAYAj B.F.# ved. red.
(Fluidization and pneumatic convoying of free-flowing
materials] P9uvdoozhIzhenio I pnevzniatlchus~li tranoport
sypuchikh uviturinlov. Mochao Khiniiaj 1964. 159 P.
17:9)

GELIPFAINP N.L, doktor tekhn, nauk, prof.1 AYNSHTFTN, II.G., kande tekhn,
--.Kiuyf 'COYMMAN, LD., inzh.
Investigating the fluidization of granular saterials in a field
of centrifugal forces* AkIm. i neft. mashinO3tl*. no.1:13-16
J1 16A. (MIRA M12)

GELTERINY N.I.; AY2'IITFYN, V.G.; PI)RAIRWA, N.A.
Effect of the height of the heat exchftnger surface or, the
coefficient of heat transfer in the fluid!zed Ix-d. *him.
prom. no.2tl0l-104 F 164. (FIR-k 171g)

GE
i t V.! X 1,V
xy

GELIPERIN, N.I.; ATNSff7EYII, V.G.
Two-phase theory of fluidlzation. Zhur. VKHO 9 no. 3056 164.
(MIRA 370)
1. Moskovskiy'inatitut tonkoy knimicho-tikoy tekbnologit Jmenl
Lamonosova.

MILOSEMVI P.N., inzh.; GELO?IRINp N.I.p doktor tekhn.nauk
Development of optimm conditions for the rectifld4tj , of synthetic
fatty,acids. Report No.L' Maol.-zhir.pron. 30 , A0%,742 F 164.
(MRA 170)
1. Volgodonskoy filla Vaesoyuznogo nauchno~-iasladoy*.Wlakogo I
proyaktnogo institute, sinteticheq" zhirozaaerdt-bivy (for
Miloserdov). 2. Institut tonkoy'%Uimicheskoy t4hnologii Imeni
M.V.Lononosova (for Cleltperin). -

fil
reftt Pxc'mnt-f c1 anal Ll.e I
rllll(~-,izel hed. nuft. no. I.: j

IV Ei~
A: 7~
ACCESSION NRj- AP5017239---- UR/()l70/64/(P)0,'0(q/0015/0Olq
F, -!.-A -Un- -OR -t
T
ITLE., Raqe of existence of a uldized bed
SOURCE: Iraheric.,,no-fizicheakiy thilmal, no- 7, 1964, 113-19,
20PIC TAGS: Akid nechnigg-1
ABSMCT-. 7ho ticle considers i, arange of existence of fluidized beds on the
Wr
basis of the ivmge of the fluidizel state as a function of.particle nize and the
litniting-polyclispersion ksumber functiod-of the velocity of the-."luidizing
agent. The rocults are given as rettios of dimensionless qva-ititiee. A compariaon
made-be tween - the-- highest - allowkble fuidization numbern end-poly-difopersion
Umbers fcurA in earlier
r paperis anl those obtained in Vie precent study. Orig,
Associmm rnstitut tonkoy khisichesko~y tekhnologii is. M# V. Lou)nosova, Moscow
(Institute of Precision Chemical SWneering)
19

ORLIPERIN,,, N.~.; PEBALK, V.L.; ROZOV, V.N.; ZAMYSHLYAYF.%', V.G.; MLOVANOVA,
Extractive refining of a nickel electrolyte from iron and copper.
TSvet. met. 37 no.9tl9-22 S 164. (MIRA 180)

GELIFERIN, N.I., prof.; GRISHKO, V.Z., kand.tekhn.nauk
Absorption from gaseous mixtures. Zhur.VYHO 10 no.ls26-33 165.
(MIRA 1813)

I - .. . - . . fl; V
l..
~IITIAI I III I.. i1i u . I . ; i), ,
p '15ALK , V. ,, . .. 2
(.01U,':IYlar MlAing at-A vottilng ,iltf; ribratory yerfora"d
plates. Khlm. prom. 41 no.1:37-41 Ja ',-,5. 0AIPA 18:3)

GELIPFRIN, N.171 prcf.; PODrATP.'rSKAYA, 0.1., kArj.t6k'w:. rim uk; MOB, MA.1,
latest in the tpohnology of di7ing if polprori-, materials.
Zhur. VMO 10 no.2tI95-202 165. (MIRA 1.401

FF-BATY, V.L j_rT-LIFFRIN,N.1.j VATIKOVA, M.N.; KIIZNETSOVI,, M.T. i
Calculation of the processes of liquid extraction ftom ultieomponent
solutions. Khim. prom, 41 no.3s212-217 Mr 165. (MIRA 18:7) 111
.. i
1. Moskovskly In3titnt tonkoy khimichoskoy tekhriolcgii imani,
Lomonosova.

~-, , r I , - - I *, I . ; - . ,: ... I i , . 7, . ; ' , . .1. 7 -. - - - . . - - . .
. :. L . "", . I I , - . , 0 , - . I . ~ - I I I - . . ~ L. . , , .- . - I . 0 . . .1 . " , . , .
Fp---,4 and rpass in tji~ f; j - -i -, toe --, ci:5perslon
systeu::j . KlArrt. pron.. 41 nr-.,'~ , ,,*'L)-. -17 Jii 1,~ 4
I 'a
(MIRA 18:8)

"4A
distribullicn i,71A.

GELIPERIN N I dc'kicr tekhn.rL&uk) PEBAI?., V.L., ka-nd.tekhn.nauk,- CHICHERINA,
-T,G.J. kwrid.teklin.nauk) SHASHKOVA, M.N., inzh.
Horizontal multietage atomizing extractor. Fbim. t neft. maahinostr.
n,1-9~1-3 S 165. (MIRA 18:10)

KCHISSAROVA, LoNo; YURCHENKO, L.D.; MIROIE14KO,, A.P.;
K(CeIvIllp. S'S,
Extraction of zirconitim and hafnium from hydrochloric acid
solutions by acetophenone. Izv. vys. ucheb. zav.; khim, i
khIm. tekho 8 no,3:402-406 165- (MIRA 18t10)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni
Lomonosova, kafedra khimii i tekhnologii radkikh I. rasseyan-
nft.h elementov.

GEVPERIN, N.I.; PEBALK, V.L.; ZAMYSHLYAYEV, V-G.; CHIGHERINA, T.G.
Cylindrical mixer-sedimentation extractor. Zhur.VPUIO 10
no-41462-463 165. (KRA 18ill)
1. Moskovskly instItut tonkoy kbimichaBkoy tekhnologii ineni
M.V.Lomonooava.

GEOPTRIN, N.I.; AYNSHTEYN, V.G.
Calcul-ition. of the expannion of a layer In homogeneous
fluidization. Zhur.VKHO 20 no.4r475-471 165.
1. Moskovokiy Institut tankoy khimichasicoy tokhnologil
iwn� M.V.Lomonooova.

GELIPERINO N,I.j PEBALK, V.L.; ROZOV, V.N.; ZAMYSHLYAYEV, V.G.; SOKOLOVA,
T.O.; KLOVANOVA, I.B.; YEPISHEVA, H.S.
Fraotional reextraction of metals from complex wtal soaps.
TSvet.met. 38 no.10,41-49 0 165.
(MIRA 18:12)

OL963 t.Wim)/AT(j) RH
ACC NRs -- JAoo6724 100010011()0391006)-'
AUTHORs lachansklyl L, N,j G*l9L*rinp_N. L 17
--MMOMM-M^-~ /C5
none
TITLEI StudY Of the continuous fDA-"votroj)ic method of polyesterification In the
synthesis of alkyd resins
SOURCES lakokrasochnM matorialy I Ikh primenaniye.. no. t,, t966,, 39-63
TOPIC TAGS$ polyester pla6tiog alkyd re3inp esterification, varnishl, azootroplo rLix-
A33TJLICTS The process of synthesis of gj"tal resin 110. 188 (TU 1W 1819-M) and
pontaphthalio varnish No. 170 A (TU MP 41-23--5-37-was i-n-vostiedea. A RoTu-mn apparA--.
tua was used for the polyostarification. The latter was carried out in an inert sol-
volit (xylone) which formed a hoteroazeotrople mixture with water; tho combination of
conditions under which a liquid film was formed with azootropic distillation of the
water produced the most favorable conditions for the polyesterification "action.
The change In the acid number and viscosity of "sin No. 188 was studied An a function
of the food rate and temperature, It in Bhown that in the synthgais of allwa res-Ins
in a column apparatus by the fUtp-aze,otropic mothodp the decrease in the acid numbers
oftho esterification product occurs in a few minutes instead of the many hours ro-
quired in an ordinary Wocesay and that resin No. 188 can be produced in a rotor
Card 1/2 UDC8 667-661-1

1 ACC NRt AMoo6n4--
type column unit at 2,%-2350C. It in concluded that the possibility of considerably'
raising the temperature of the polyesterification reaction is one of the most Iqxr-
tant characteristics of the continuous process of synthesis In a column.unit. Drig.
art.. has 8 4 fig,;res wid 2 tables.
Of -
Sull CODES 11/ SUEN DATZI none/ ORIG REF1 004/ OTH REF8 004
Card

GF-.,&F~IN, 11. L.
Hydraulic presses In the chemical industr7 Moskva, Gos. nauch.--tskhn. Jzd-vo
mashinostroit. lit-ry, 1949. 190 p. (50-15552)
M.46o.o4
L

(ZL'FERIN.1 N. V.
"Production of Crank Shafte for Tractor and Harvestor Engines."
All-Union Conference of Foundry Workers, end of 1,057. Moscow.
Hashinoetroitell, 15r,-8. No. 5, p. 48.
-~ f / I f/ , - /
I- %e%e- e- C,~ --,~ 11 -A, /9~ .
I III-w /,'// 4 )

GILIP31RIN, N.Y.; ZVOLIASKAYA, T.T.; PARFINOV, V.S.; SHIRMAN, A.D.
Crankshaft founding procedure at the Vladimir Tractor Plant for
N-)O entines. Lit. prolsv. no.10:15-16 -0 160. (HIM 13:10)
(VIadimir-Founding) (Grakke and crankshafts)

S/1 2Y60/000/010/008/016/XX
A033 A133
AUTHORSt GellperLn~LH. L.; Zvolinskaya, V. V.1 Parfenov, V. S., and
Ige-rman, L. D.
TITLEi Technological process of casting crankshafts for the AB-30
(DV-30) engine at the Vladimorovskiy traktoTny,,r zavod (Vladi-
mi.-ov Tractor Plant)
PERIODICALt Liteynoye prdzvodetvop no. 10,-1960, 16 - 17
TEXT: Based on the experience of the Khartkov "Serp i molot" Plant,
the Vladimirov Tractor Plant started the casting of crankshafts for the
DV-50 engine. The authors enumerate the deficiencies occurring during the
casting of the crankshaft for the CMA-7 (SMD-7) engine at the "Serp i molot"
Plant and point out that the elimination of black spots by increasing the
machining tolerances Je not expedient; therefore, it is necessary to pre-
vent the originatJon of black spots which can be attained by the desulfuri-
zation of the cast. Iron, bringing the S-oontent down to 0.008 - 0.001, .
1%
This is possible if the cast iron is smelted in a basic electric furnace.
Attempts were made to oliminate the technical difficulties connected with the
CaH 1/3

5112 6010001010100610161XX
Technological process of casting crankshafts... A033YA133
production of magnesium-modified cast Iron by using other m)d1fiers, like
cerium, tellurium, calcium, strontium, lithium, etc. Tests proved cerium
and foundry alloys on the 'base of cerium to be the moot suitable modifiers.
In comparison with makmeslum, cerium offers the following alvantagest no
metal ejection during modificationj the assimilability of cerium amounts to
not less than 30%; lower oensitivIty of the cast iron to demodifieral In-
significant cast iron temperature drop during the modification process (be-
tween 20 and 4000); uniform distribution of sulfur over the casting and ab-
sence of black spots on its surface. In order to maintain a constant chem-
ical cast iron composition during the investigations basic cast iron of the
following chemical composition (in ~O) was smelted in a 3-ton acid electric
furnace' 3.5 - 3-8 0; 2.0 - 2.2 SJ; 0.8 - 1.0 Mn; not vore than 0.04 S.
Then this cast iron was remelted in a 50-k9 capacity acid induction furnace.
The metal was heated to 1,460 - 1,4500C, the modifiers (conposition: 5 - N
Mg, lWa' Fe, 40 - 5010' Ce, the rest rare earths) amounting to 0.4 - 0-3% of
tho liquid metal welght was put on the ladle bottom. T3 riamove cementite
formations and increase the mechanical properties, the 3ast iron waa subaer;v
ed to additional modifiostion by 0.3 - 0.44, Cm (Si) 75 fer-rosilicium. kfter
two minutes holding In the ladle the metal was poured into the crankshaft
Card 2/3

S/1 28/60/000/010/008/01 6/XX
Technological process of casting crankshafts... A033/JL133
shell molds. Besides, speoimens were cast to determine the macro- and
microstructirre and the mechanical properties. Table 1 shows the results
obtained. The sand-resin mixture was prepared in a mixer of' HIILITILASh de-
sign, model 821, the shell mold was made on a model 830 nachine of NIILITMM
design. The cast crankshaft structure contained ledeburite cementite. The
crankshafts were annealed as to the following conditions; holding at 9500C
for 2 - 5 hours, cooling in the furnace to 6300C, holding at 6300C for I
hour, cc-oling in the furnace to 4500C, further cooling in the air. In com-
par2.son to die-forged crankshafts 22 kg metal were saved wi-,h each cast
crankshaft. The econcmio effect amounts to 1%'j of the crankshaft cost
price. There are 4 figures, 2 tables and 4 Soviet-bloc reforences.
Card 3/,,

dcktcr tekbn. naiA; P.YN.SIITV.YN, V.G., !Land. lekhr. vil"'A;
GOYKIIMA),, I.P., Inz%.
Speed of' the beginning of fluidization and the vrpansion of it
fluiolze-cl bed in the f.i,A of cantrInigal forees. Khlwo i
neft. ma.sh!nostr. no.vlt!,8-U N 164 OURA 18W

IM i AP50W'S7
URA)03 2/05 M31/006,1075 8/0759
AWA. VOES i Rub H.; Gel*perin, Ye. Bel msk V. A.; Shtedi
ihteyvi.L V
_polymerlo -mater'.1als--
TITLE., Spring-loaded i namometor for t9sting of
SOIR',IE: Zavodaka 1965 758-759
Ya -Iatqmtori~ I, o* 6,
TAGSx --a4asurlhg aj-~paratus tooting,-devico rix~t EPV 2 IIA
plastic mate
potem,tiometer' EPV2,03 p6tentiometa;r
ABSTWICT. The trAmi)zator described here has been desIgned for r4pid testirqp, of
Plastic materitils fol, elongation and breakfmg limit at temperatures between 4,0
and 2C,0C. Lengths of' tho'l-tested speeimen varied with different material and
could ~veach 160 Mm. A dotailed deacilption and a drawing of tho iiustruwnt.aro----j:
g~ven.'~', In-teating, a sp-ticimon is placed in an 0.5-kw electric ovem, heattA f Ior
f ive m-Inutes.' and eubjoctel--to -tenaion: At:-the-- rate of 3 cm per ninute, Lengyt%
readij4-..-S bare taten vilift an accuracy of 0*5 in. Change in length of the spring:
a =xImm force of 4 1~3 was 31 Mm., Each 0.155-i= division of tbi round Ocala
corrospondod to 20 Irrems of force. Overall dimensions of the dylutm)meter are
880 x 2,W x 144 tmv and its weight is 10 k4,,, Orig, art, hast I f JA-,uro.
Card
IA~

5/iq1/62/000/010/C07/010
BIOI/B166
AUThORjt Jhcherbakov, V. 1.4, Mazur, S. V., Solomon, Kh.,V. G.Wperina,
ITITLE: ~)trength of glaus.reinforced plawtics. Humidity, atmospheriq,
qnd hiph temyeraturea effe9ts on the physicomechanical
1)ro;)crti(-.,s of glass-'reinforced plaitics
i(l 01 CA Plautic.'ieskiyt. masny, no. 10, 19629,37 - 43
,;';,,'AT -. Tito? authorn examined r
jaw;-reinforced plastics of G~-2 (BF-2) plicnol
resin, opoxy renin or cL)ld-setting or thermo-netiingUH-1 (PN-1) polyester
reain vAth T1(TO Plass fabric, satin cvlass fabric no. 6/3, or glass mats
ivith the r-iLio warp i filling - Is 1-5 as a filler, pro~-uccd by vacuft,
preau, or contnot techniques, YIfh thicknesses of or 10 mm. Up to
1210 daya titic tint,q)1ea vere kept in water so a!- to test its effect on them,
then their bending utrangth vina studied according torocr4640-56 (CwT
Requital After 00 days, the drop in bending modulus of polyes-
ter -,tnd phenol renin wis 50 W/s, that of epoxy resin -15 - 19;.. The
Card 1/3

41')1/62/000/010/007/010
Jtr(~n., t h of' [I; Is U voi I) 1701TOd D101/B186
effect ot' vatrsr j.-. cAplAned by itn penetration into inicrocracks, copccial-'
ly 1,1-iblv lo form in recina %Ath poor adhesion to rlaau. The grcateot
drop it; boriding modultiv, o-curs -,Athin the first 30 days. By k0opir1r, the
arkinpleo, iri -tir f,,r 14 J;I.Ya, thoir bending modulus re3forea by,.22 - 561,,.
16 Jeterliflation 1,4:1 ell.;C11suel, qnd the method by It. E. Chambers find 1"'. 1.
cGorry 'A.J'j3; Jull., no. ;"B, 56 (1)59), ibid., no. ~33, 4(Y (1?50)) is
recon,%x 1dr 1. Pretro-Aw(unt of T glass fabric with orralooilicon CWspoullds
.such j.,; H uil or 174o;LOU3 7idylltrichloro' ailane, polyvinyl siloxane rezin,
Viuy! tr'1(-A,;Yl Oilune, cotim,arcial. PBC-9 (M-9) or 9-1prepnrations improves
its resi;3tiiity to -.-.atcr. Vinyl triethoxy ail3ne may be added to polyester
renin (i lircotly. tmoaphoric influences were examined by keeping
BF-2 an-A T _amplea 20 months on the ground in the open air, but the ofibcte
were not cl'i!;:jifled under indivIdual factors auch as UV light, humidity,
tetnpprat~.ire, ete. Tho tensile strength and Impact strength remained un-
chani-ed ;hvreaa the bonijinr, modulus shoved a reduction of 11.5 - 23.4'to.
Jhort-i)c..-~oJ heatin(- at 350 - 100 OC for 1 - 2 min did not affect the
strunr,th, sind in soine snmples the bending modulus was thereby even incr=od.
fience allitiontil ther.,ial treatment is recont:,ended for such J;lasu rein-
forced I.-.z;tics ua Gro to be used at hisrh temperatures. Special techniquEu
Card 2/~

J 3/191/62/000./010/007/010
jtrenCt-i of (Jasu reinforced B101/bIB6
for teutinr V.1uns reinforced plastics at high temperatutes, miaking allow-
-ince for tt,u raize of' upecimen, heating rate, and other conditions,* are
doemed nenon-nry. There nre 4 figures and 5 tables.
Cori 3/3

CHERUYSIIEIV~ Ye.A.3 VANGNITS, Ye.V.; GELIPERINA V.M.; FETROV, A.D.
Synthesis of bis(organochlorosilyl) derivatives of aromatic
hydrocarbcna and tris (trichlorosilyl) benzene. *-'zv. AN SSSR.
Ser. khlmo no,lN1807-1814 0 164. (mr-RA 17sl2)
1. Institut organiiheakoy khimil Im. N.D. Zelinskogo AN SSSR.

2, 7887-6 , EWT(m)/EPF(o)/LWP(J)/T/EWP(t)/EWP(b) IJP('.-) RMIUD
ACC NR: J.P3025042 I SOURCE VE; UR/0286/65/0W/016/0085/0085
AUTHORSs Pakhomov, V. I.; Andrianov, !--LOIG~llmina, V.
ORG: none:
TITIZ: Method for obtaining allicon-organic compounds containing the chain
'41icon-divalent organic radical-silicon. Class 39, No, 173954
~ISOURCE: Byullateal Izobreteniy't '-tioiv~rzWkh znakov, no. 16, :L965,
WPIG TAGS,: *j~AUZ,- compounds polymerization, poly=!r., wwn4w-f--
ABSTRACT: This Author Certificate presents a method for obtAtining silicon-
organic compounds containing the chain silicon-divalent organic radical-ailicon,
ty treatirg silicon-arguni m0 Mors. To simplify the procetis and to increase the
Yield of ;olymer silphen 1mon:mers containing an alkyl group and more than one
alkoxy groUp at each silicon atom are used an starting reagents. The dispropor-
tionation of the monomers is carried oat at or above 200C in the presence of
alkali catalysts.
VUB COEE: CY71 SUBM DATEs 13Jun64
Card UM 1 678,84
:,f 0- eI:w

L 00265-66 'FXF(0/EWPW/&1TW/T lat
ACCESSION M AP5013444 UR/0020/65/162/001/0079/0081
44
AUTHOR: Andrianovt Ko A. (Academician); Pakhomvs V- I.; Gel'perinal
--a new wathod of sjnjhesis'~f sillcoorpanic pol
TITLE: Disproportion reaction y
mers. Synthesis of polyphenylenesilanes
SOURCE: AN SSSR. Doklady, v. 162, no. 19 1965, 79-81
TOPIC TAM disproportion reaction, allicoorganto polymer, syntbesis. rolyphenyl-
enesilane
AMSTRACT.- Base catalyzed disproportionation of several bis- (dime toyle boxys I I y1)
benzenes in studied In an attempt to find new routes to the synthesis of poly-
plienylenestlanes. Tho lonic.machanism of this reaction Is-
CoM 1/4

1, 00265-66
kcassXON NRI AP5013:444
CH'I Clio Clio
tto 11
cut CBS Clio
Roll
jut Jill
Clio
etc.
The reaction Is catalyzed by XONj alkali metal alcoholates, anines. eta. Dls-
proportionation of 1,4-him-01"Othy
lethoxyal lyl) -benzene g1vev a dimer (360 molec-
ular weight) in a 48% lield. Dispropoirtionation of (CH3)2(OC2li$)S'qlkS'(OC2N)3
gave a polyner t(CH3)S.1C6"4J0.2t(C2H5O)2SIC6 30,, inla 98.7% yield. Tht kinetics
of the disproportionation reaction are ahown"in g. of the Enclosure, OrIg.
ari.. has: 3. flgur*.
COM 2/4.

L oo265-66
ACCESSION Mgt APS013444
ASSOCIATION: Hauchno-looledovatell skiy Inatituit plasticheakikh mass (Scientific
Research-In3titute of Plastics)
SUBMITTED! 14Jul64 ENCbl 01 SUB CODE: GC# OC
110 REF GOV iOW OTHERI 003
Card 3/4

L Oo265-66
ACCESSION NR: APS013444
Fig- 1- J-(Cl13)2(()(';?ll5)SlC6114
Sl(Cl13)2(lC,?llS at 2110"c' and with
1% KOH; [f'-C?1150Wil07.Sll'G114Sl
(CH3)20(:2115 at 2301r and with 1%
KOH; III-- (C2H5O)2CllJ!;lC6ll4GiCH3
(OC2H5)2 at 2300C and with 1.5%
(OC2H5)3 at 2400C and with 1% KOH
Xv
C'Ord 04-

CODE: UR/0190/66/008/00911618/id
AP603115 SOURCE 2
Pakhomov
AUTHOR- Andrianov,__K. V. I.; 'ifPvri~a V. M.;-'Mqkhina, D.
ORG: Scientific Research Institute for Plastics (Nauchno-insledovatellskiy inatitut
asticheskikh mass)
P
I -bis(dinicthvlhvdrt
TITLE: Catalytic ~0~ densationlof 1, 4 )xysilv1)2he th
Yco .Mylene
diphenyldillydroxysilane and octam ethylcyclotetrasiloxine
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 9, ICA6, 1618-1622
TOPIC TAGS: polycondensation, catalytic polyconde!isat ion, ceP013-Mer, linear
,chain copolymer
'TRACT; A study WaS made of the polycondensal ion reictio- )f 1, 4-bia(dimethyl-
roxysil-l)phcnylene with oct-.ttncthyleyelotetrasilc)xaiie wid diphenyldihydroxy-
4
ne in the presence of alkali catalysts. Tilese interactions were found to produce
following linear chain cqj)olymcr
S~-
cil, CIN
11 0--s i -.0 SI-0)"11
112 UDC: 541. 64+ G78. -11-1

I ACC NR' AP6031157
c1l) cilia C
110 Sl- -"i-0 -(Si-0 If
I
CIII Clip x fil, )1'
The destruction of n-bIs-(dImeth lhydroxysilyl)phenylene was found to proceed much
fa-ster above 400C. C(3polymers- f 1,,I-bif3(diiiietiiylhydrt)xy,3ilyl)piicnylene with
were found to form as a result of polycondensation as
well as polymerization with opening of octamethylcyclotetrasiloxane. The polycon-
densation of compounds was studied at various ratios. Orig. art. has: 2 tables and
5 figures. [Based on authors' abstract)
SUB CODE,
07, SUBM DATE: 21JulIII ORIG REF: 001/ OTH REF: 005/
Cmd. 2/2 1,40

GEL' i(UD,__Samujj_yarkQyjch- ZARUBINA, Alla Georgiyevna; FODbOILTUV,
Vasilly Vasillyevichl KUDMASHOV, it., otv. red.; SHATROVA, T.,
red. izd--ra; LEBEWi~ A.0 tekhn. red.
(Collection of problemo on the atate budget] Sbornik zadech po go-
sudaretvennowu biudzbetu. Hoskva,, Goafinizdat, 1961. 94 P.
(MIRA 14112)
(Budget)

2 0 2 CIO
I(). ,P"
5, 'i6'. "027/1)03/020/025
B 10 1, V'~
AUTHORS: 7. N, and
r1 T ti: e ti r r- ng' i L i ni :,i e 1, a 1 i if 11 time n t 3
~1!," 14 v !36i
334--335
in tior if avnila~.It, -,4n:i 1,11~vroticul data, the
-i~itlnl~:-.-' mak- osi'i;tap~li~ns the ti,it"co -.1,-E-neth of thin metallic
fJ Til thp 34r-np-h :*-,c ctal a w,. tb diame ters
f 0 - C 'I L 1 1) a vt li j I. I TI &;qerltments ihowei
.ht-~t the attrocg1th ~f 201A~ Wid more
141 fr~-M the altrength ~Af :,,ys-talo, frozi the values
known IM lni,i~!.-y 1 n 1. ~ i, m ~, t al 1 41 ~ f1 ir. "n t'Va ar,.~ letis). however
the SIL'~flgtll in.i u!ty FA~+an t,.v t ~~trength of zetai.N~
-11 *'ho T'll 4 a
-,it ?n-
t
.I 1~ orl -, lic ri- a -I (-;I :11-w., :It:, ngt hf ay only *n rE- -,ase of
4
d-n.-,;ty :4 dlala::zLt--,ans.
lhis 4, too' -!in n.) t. 'Le .i t (t a a --,-ery -ivoii dtstri-

causezi Of tllt~ g I zLrnng* a f S/032 /1/6 -1- 027,"003,"U20.,"025
B'O'l B 20 li
tutton of !-ni i h tO X. ~j In.I n ghtc-it iphor.0-
F,~nelty x-,auq~j~i all 'I t nC- X- -eY ' r.VC-3- !gat lons
c%hc)wc,d t - . w4d
-hat thin mcr~ than
; ri tt ~
that of mit-ivi, ~,t -%L- Gr,,O. f the
mletal 11 [,~ f 11 iii-in, Ti i i _i ii i -i %i m pn Ad o o - oxFe:-IL,,:ntal
a t a h,: rina vi fzv*,s,,,~,. :-j- ~h:-wel teat
n y "r, c , a 1, em e n a p r~ r y
I'
The nlimb or of -il zo~ c,-,E; in,- t I-. r. r rim-in, d i ELT.9 tf%:-
a n th i s c ao,: 1; i. -h h 1. c b m a
ly fiffn-~-t th,.- T I q e 1 t a r, that the
strer-4,;th of s thair bul-rasc.
n 1.y . -,!th th-~ tti~- ;a~,-n4th i-, or, ths, dismeter.
x pe r 1. r,;.e n t a I' F. h-. -3 ~i p Th r. 1 -.- nf s t re r.6 t h
on the surf a - i:- i;ji.' ri~, 'I- k','. 1: .lqpenden~~e :on .hE
diamet~.r and th,-, I
carliej- by t r. C 6 h . i4 ac t c, -. 9 wh' I. c h
are all~io ff)r tiv, -pr,-ai -A Crvv-113 orlith
Card 2/3

20200
Causes of the high strength of S/032161/027/003/020/025
B101/3203
diameters of 20 - 30/A and more should be excluded f--om the study of
superstrong metal because of their laminated struoture. It is further
stated that the size factor of thin metallic filamen-.9 is of quite dif- t
ferent nature from that of larger objects so that data cannot be compared
with each other. There is I figure.
ASSOCIATIONt . Institut metallurgii im. A. A. Baykova Akademii nauk SSSR
(Institute of Metallurgy imeni A. A. Baykov of the Academy
of Sciences USSR).
Legend to the figure: #X
o: 1 2 mm a: d 6-5.At-1
1) d, kg/D. IAV
% I r
JV-

Y'l ~w4zZ

A
"A

N
A

Vq-
I ta 11
TO,
Too jou ilis of
Ac 4 MaIni'll)"11 14"
Wits and Iligh arid
tab. Column ISW 111ru.
stuld-V11= the U%e Ds steel sphats I'S
hgrged~wjth Fit or
lam
lWA&.d ft()t&l aA ~~.`rr
OC in diam. to wlitch pitch II-OW11
Artifik.1;411Y 211plied.
1&A Were j~,.
I mm: to b 1111ts - In th"C IQ can) of air' 1101m it
d and vubble fity jr
are drop, (it K 0011tioltillred Witt, plactil At in-
1,otaqb werwuCrIlds he MIUXI-.11, voliuw: rati(A Of ;jj.'.t;jj
no Turn
I terv all ()f tip
(if tlic joulecl spliert) K111, ritv!V4
to total volOuld
1:5.46.
I Ur
Bp K 1.3 t11r, 1:4.h5
ja - " 'Ind U4
1.2. 13.
IS log Re wheic
thom 1:1. to
In the Imir I:)j Eu
lotted C(,Vef do unit 01'
OLT The t!Kctj, AVA
Py
v0.) Is PIK.'
atid log Re Va
III Which 1(% 1
frow tango (viii:
in
t
cV&jjI" 6 00 ara o.4 it) 2.0, trip-
lutictiuns of IPI%ctc
th - - ~ 7
I.-;e is, c And Y -1c. for tl,.c
'A iqUals cuK111
W111ta anil t~ fire 0.7. 4-3,
r6-is tim -1u
.c wIth a filin 0!
Aj~
to 011. 4 a 11 it 1.4; 3~O to 5
ano 0

A d
Z;-z
t
r t hio
it v
Eva
Eli; f,
f! mv
9 ;1tj it s
T T.

L 248-i7-65 L?WT(m)/ZPF(0AWP(J)/T
PcA/Pr-4 P.M
ACCESSION rIR: AP40417396 S/0062/64/000/010/180711814,)O
AUTHOR: Cherny*shoir, Ye. A.; Vangnits, Ye. V.; Gellperina, V. WL;
Petrov, A. D.
TITJI.,E: Synthesis of bieforganochlorooll3~l)derivativeI of ar'omatic hydrocarbons
and kris(trichlorostly0benzene
SOURCE: AN SSSR. 12-.vestiya. Seriya khimicheskaya, no. 10, 1964, 18017-1814
TOPIC TAGS: benzene, benzene derivative, synthesis, high temperature conden--
sation, disprqmrtionation reaction, exchange reaction
ABSTRACT, The high temperature condensation method described by Ye. A.
Cherny*shev, V. F. blinorov and A. D. Petrcrr (Izv. AN SSSR. Otd. khim. n.
1960, 2147). wherein the reactants were contacted for about 30 seconds al. about
580CI, was utilized in the synthesis of a iseries of p-bio(organoclilorostlyl)benzenes
..and of tris(trichlorosily0benzene. Disproportionation reactione. did not occur iA
theiie gaseous reactions between the organochlorosilyl benzenes and chlorosilanes;
only the silyl groups were exchanged. Hence pure bio(organodl,,.hloromily.'L)ben-
Card:1 / 3

L 24837-65
ACCESSION MR: AP4047396
zenes were synthesized:
P-C1130281WIXI + CIIIS11102 I?-CIhOrSiC4H4SiCWIIS + HCI;
P-C402SIC4HO + C4HsSIHCI,-
0-CJWtSIC414SChC&Hs + HCI
Gas phase condenaaflan theoretically would not result in the synthesis of pure
bis-s.dyl benzone derivatives having different methyldichloroallyl and trichloro-
silyl Igroups on one benzene ring. But compounds with different organochlorosilyl
groups were separated by their differences in boiling temperaViros, e. g. in the
following synthesis:
P-CAMSICACI + CHOW% -t- P-C4HsCIsSiCITI6SICIjCHs;
p4;HjCI3SjC6H4CI +~HSI(3s--t-p-C41tsClsSicSH48IC13
High temperalure condensation of a four-Fold excess of trichlorBildne with a mix-
ture t)f dichlorphenylt richlo roe ilane isomers gave a 13, 5% yield of tria(tric-hloro-
allyl)benzene Which was 'methlated to trie(trimethylsilyl)benzene. Thephyisical
propDrties of the investigated compounds are tabulated. Orig. art. has: I table,
.Ceird 213

L W17-65
ACCESSION NR: AP4047396
I figure and 10, equations
ASSOCIATION,. Institut 6rganlcheskoy khtimll Im. N. D. Zelinskogo Akadeniff
nauk FSSR (Institute of Organio Chemistg, Acaderny of Sciences SSSR)
SUBMITTED: 2IJan63 ENCL: 00
SUB CODE: G(40, 0C NO REV SCM. 003 OTHER: 002
Card 3/3
gn ti
bE?~

R
7.

D048/D002
AUTHOR: Gellslite-7n. A. (Leningrad)
TITLE: With Academician Kostenko
PERIODICAL: Nauka i zhizn', 1960, Nr 3, pp 4a - 43 (USSR)
ABSTRACT: The author reports on the professional career and
the work of the 70 year old prominent Soviet power-
engineer, Lenin prize laureate, Academician blikhail
stenko, who took par - -re Ve- To p _-
Poliyevktovich Ko t In the
men-z or all basic types of electric machines produced
in the Soviet Union. He worked out the theory of
the so-called synchronous twist and wrote many scien-
tific papers. About 25 years ago he published the
book "Kollektornyye mashiny" (Collector Machines).
The Stalin prize was twice awarded to him. For more
than 30 years Kostenko has headed the Department of
Electric Machines in the Politektinicheskiy institut
imeni M.I. Kalinina (Polytechnical Institute imeni
C&rd 113 M.I. Kalinin) in Leningrad where he trained more

S/025/60/000/03/016/045
D048/DO02
With Academician Kostenko
than 400 engineers. For many years he has led the all-
factory research office of the Zavod "Elektrosilall
("Elektrosilall Plant) and is a member of the plant's
technical council. Furthermore, he acts as Chief
electrician of the Kharlkovskiy elektromekhaniches-
kiy zavod (Khar1kov Electro-Mechanical Plant). Gao
Tszin'-De, lecturer for power-engineering in Shang-
hai is mentioned as one of Kostenko's pupils. The
author reports on a visit paid Academician Kostenko
at the Institut elektromekhaniki Akademii nauk SSSR
(Institute for Electromechanics of the AS USSR) of
which he is the head. At Kostenko's laboratory, a
miniature model of the Stalingradskaya GES (Stalin-
grad Hydro-electric Plant) is erected. In this con-
nection, the author mentions that the Stalingrad GES
will deliver a.c. to Moscow and d.c. to the Donbass.
Card 2/3 He refers to Professor Venikov of the Moskovskiy

S/025/60/000/03/016/045
D048/DO02
With Azademician Kostenko
energeticheskiy institut (Moscow Power Institute) who
together with Kostenko worked out the pattern method
which will be widely used in the electrifization of
the main lines of the RR of the country. A photo
shows M.P. Kostenko. There is 1 photograph. V/,"~
Card 313

AUTHORS: Gel,Xshteyn, A.I., Tomidn, M.I. 76-12-14/27
TITLX-. Kiwetics or the Cbmical Interaction of Ethylene and Prapyletw with
Sulfuric Acid (Kinstika khimicheskogo vzaimodeyetviya etilona i
propilona a s*rnoy kislotoy)
PERIODICAL: Zhuvnal Fisichookoy Khimii, 1957, Vol. 31, Nr 12, pp. 2697-2705 (USSR)
AbSTRACTs The kinetics of reaction with the absorption of ethylene and profflone
by sulfuric &oid in the diffusion range me investigated here. 'The ve-
looity or olefin absorption by the immovable liquid layer of great
thickness under the constant pressure of the absorbing gas ws~s measured.
The problem investigated here can be formulated an follows: a gas dis-
solves in an immovable liquid and enters into reaction with the samet
taking place at a velocity proportional to the concentration. The torm
which connects the observed speed of absorption with the constants of
velocity of the chemical reaction in looked for. It is assumed that the
absorption takes place with & great liquid excess. The reaction velooi-
ty between Sw and liquid can therefore be expresaed by an equation of
first order. Further, it is assumed that the equilibrium between the
gas phase and the liquid layer Immediately adjaoent to it sets suddenly
C,krd 1/3 and follows Henry's law. Provided that the thidmess of the liquid