SCIENTIFIC RESEARCH

• Document Type: CREST
• Collection: General CIA Records
• Document Number (FOIA) /ESDN (CREST): CIA-RDP80-00809A000600200223-3
• Release Decision: RIPPUB
• Original Classification: R
• Document Page Count: 2
• Document Creation Date: December 22, 2016
• Document Release Date: June 29, 2011
• Sequence Number: 223
• Publication Date: August 10, 1948
• Content Type: REPORT

Sanitized Copy Approved for Release 2011/0x6/29: CIA-RDP80-00809A000600200223-3
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ON 1947
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JAN 31 1955 Iffi
FOR OFFIC
DATE DISTR. 10 August 1948
NO. OF PAGES
NO. OF ENCLS.
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SUPPLEMENT TO
REPORT NO.
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SOURCE Documentary as indicated. (Information specifically
requested,)
HECENPLY W3LI. Hr p RESEARCH OF THE IVAMOVO
INSTITUTE OF CIf1.`ICAL TECENOLOGY USSR (II)
P. F. forodkin,and S. I. BurrAstrov (Ivanovo
".hur Obahoh Shim" Vol 17, .19472 pp 63-6
Nitroaminee were reacted with 2-naphthol as follokes:
2-naphthol and the nitroaminu in a 1:2.5 molsoular
ratio were heated to 160.400 and treated with o_s
til HC1 evolution ceased. Cooled mesa was exhaustfgely
-+-d
th aw_w_ ...- - .. - --
e&_
-
w
rrava, then 1( Na; evaporation of the Et20 gave the
product. Only nitroemines having a meta configura-
tiorr of the NO2 and NH2 groups give satisfactory
yields of the secondary an-4nos. Increase of the molec-
ular ratio of nitroamine to the naphthol favors the
yield of thesecgndary amino, with beat results at
S. V. Aogdanov and N. N. Karandasheva (2varovo Cheri Tech
"Zhur Obehch Shim" Vol 17, 1947, pp 0-7-94
and NgNn sulfite. Synthesis-procedures with ,acre
described.
STAT
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LSanitized Copy Approved for Release 2011/06/29: CIA-RDP80-00809A000600200223-3
 Sanitized Copy Approved for Release 2011/06/29: CIA-RDP80-00809A000600200223-3
I
?Bens2 2- and 4-nethaogr-l-napetlg-1 Betonan and Pherg1
2- and 4-methoaW-L-n9phtbyl flikaetoncs,s S. T. Bnrmistrov
and E. A. Shilav (Ivanoro Chem Tech last)
"Zhur Obshah IShim" Vol 17, 1947, pp 1684-1
P B CO2H was heated on a steam bath with PC13, the cooled
mixture treated with CS2, atr/i the solution gradually
added with icsroooling to A1C13 suspended in CS con-
taining 1-46egC; mixture then decomposed uitN ice and
organic layer tilled aith steam. Residue wen heated
with soda solution and the insoluble matter, on crys-
tallisation Prom EtOH, gave benwl 4-methoxy-1-naphthwl
ketone and its piorete. This heated with Se in Ao?O
gave Ph 4- thOW-l-napht1V1 dike3tone; this ggives a
quinosa1ine on beating with crtho-C (Ffl )2, while md-
dation with H2O in aqueous pyridine gave BeOH and 4-
methwy-l-naphthoio sold. Letter acid treated with
m the a
SOCI.. then
~
heated.
ooacentrated k41,
g an
~
1-f-(/`-~nsth
of
1)-
qu n-line. Reaction of PWCH2CCC1 with MOCIO
aimi-
ltrly give. bens'l 2-othcog' 1-naphtk l ketone.
Ketone
on dation with SeO2 gave phergrl 2.eiethwrr-l-napht1y1
dihetons, which gives a red calor with No in EtOH so-
lution, the color vanishing on ebeking, then reappearing;
oxidation gave 2-metbcayy-1-naphthoic sold.
"The ZJsohanism of k dro]ysis of Chlorine," E. A. Shi.lov
and S. N. Solsdushenkov (Ivanovo Chem Tech Inst)
"Z ;ur Pis Shim" Vol 21, 1947, pp 1159-61
Contrary to t?orris thelydr4ysis of a^1 in water cannot
be dug to reaction with OH ions because reaction cen-
stoat increases during an experiment although th OH
concentration decreases.
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STAT
Sanitized Copy Approved for Release 2011/06/29: CIA-RDP80-00809A000600200223-3