SCIENTIFIC ABSTRACT BALANDIN, A. A. - BALANDIN, A. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103210012-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

00 -A-. f a Ji
O&OKqw Owl,
Oka*
A # i 6 i 41 4 A a i a A i a 4
p M h a
Ili. YMMIN. A. A. balsoldim. A. 1.
Iwbtdm. and 0. A. Mlowas Cbrus..
Acad. Sol. VASA.). AhO. feed. KC U.P.J.5 Osion
swi. CUM. 1015. &&-Wb Bng*d4 WO, d. e.A. 30.
4'.W'.-TU activity d ligh sels IA The YmW-pbam by-
Mu was iev"Upt4d. MI OW wattr wm
kow two astommicsily tesillated Ulaudis
=
burtts isto as tvapomtw. aid from tben into a rwwOm
lubw PkAVd NO M #kC. O"ll I"WiNtWO bN NOP. dil').
The t = by a thmoorollA golocod kW&
The oraztra - a" The tpm Velocity art The
bodon asettims dw 4kwtwo and the rate
VA. fatle 1101PIoLl. it it k am kmve
tbas 0.7-1. b kin mopofum. It was lbat Mh
0049 to we doadivow at abo" W (txAt&Vls
M orl). .W . ad d. l.tW oil at as #AM
oew IWO. opi
kM a tMp. NA 4W* (Genabo 9Mh gel). Tu
in the I MR of otatow'sth i .44,
4 12:17T ChILVA-1 AW
of ibe tbrumucal
at It space welink an Omm of
M" (Wbkb ho "it. 6wV)"b'r
bwo Lr the tmt.
of sk don so n6tablish lb1H arloaal utMty.
W1btA0k&tv!4kAwwwW&t48O'.~ actilityrowGimil
W tbe some lo"I for sway left. (Ashl of pbmW 7-4%)
anif 4AW am cbsop sher tho butmat, v*k Mr. Tlw
bolorwoombom of siowd with S-41% 114M. tow-
fie empletely
"b 114ru'lle 10-0. -------
dooruvates It for IW '-p.-Pum It
j#jjLk~j4 Lnmt%ol VV3. brat Wfibft (A 04 UNIF16616CO" t%"*Sp
of
"'by"b" sk. 0. L.
0" 1 low 00,11440
e w GNT M10448. 614811k &A 00 Ili
0 ones
I j We #A a a I w FA
0 0 0 0 0 0 0 0 0 41 0 9 0 0 41-0 0-0-0 0-0-0-1
too
do*
see
0 0
ol~
a to
If
It v 9
A -A- A A-- A
j; ".74
4
fft4fiOt -.0 "_W.04 -t.
W_:
7u kbefte at dm twwaies a rv0k*qt sat. 4 hl=," Iftlateswc,
a W"M T #r#. T&k it, CVMAiIM.1 10 .%hffVW 4,
**A ItIT, IA) atm. and 44
9-N _sp,"Offlff 3W&It(RqftLb AtIvwirmp.-oU'.jlwrs&jn -0 &. I
CA - $0. INTO.-A Theory b ds vv6W ee dw cut of WA It priftwo and takww coiltra., J& tin
00 c 9.0pahkof me& W-140 Mus. to " ma the 9 ~tn on peg.
*4 the wbwbe4 It. aW K % WOMOK only OW 40lutinsivOy oct OW by tsfame. the K' vitaim * H.
*02 b WT. MADImpicip. 91"li 9 OW X, O&wb hVetkaft. khib brawki to the evach"ift that it b ftok" all
IN I Mid the 6MOL lmaw4m . w "d ---------
904 ! ~ Wnvbw the P mw a twYarA wa. At bMw
widambufti d 111t 411611irp" 9 . b ISAW Than aw &W. the WmAms role au- 6 beftw=
wAmpgarst ~ba. Aininted rofm two HU erkh reivett, to It. ad comberd to tabim at x1g,
Ob" M w as atm ed lbe = 40,11to 200-136ats.
.4 In.
~him r Oft too Ib* WOO-cats.0 Thtrait, 14 IDWw" that the
pred"d. daww" of tbs apps"t ALtivatim ~00 at bm a"
SO rnaim4me samaticift for the cam of tieviiii. no 16 - E61 4. the heau 44
pa"Ist% a" awl In 6w ON r~;;s um V cm ton tor I I the It goo
ild. Aftww' "A t- tiod vAbotsum, "
the WN Ili" b" to the exact
of H pe nesiv. &W ad thit rato ;7-dowd-soft-tary hivici . to the M" of Itimew.
st"n of scolvatift CW.lw4Ar. T%b am also b* AvOumd hum evptL aia too
the ft" :=,-*a; st. taw k ,oaro w"M b& Wwal site byaconwom rate tit viw" tit mftum tmq i3o-
see
Ot &%"t tu Isfum ink" Trob the of 1101. the OrKow go, K:.Afts cov"W by U. Z-1t; -'0
SM A The Vemkin Oft c""'. 00M - I IN". istakd.
With dw Wd of : I
J: %. ft*. In twtkr auvtmmt with the t". as
,rr
isvook i" umbw fqftw W". fetc. of Ow rate "Kivilm with incM*4 prommv.
Par
40 X, at I NOMW am "M 011111cip 41 we omgqwbbr to Irran"Isit by the see
A- Ik. r".ol rus-11, theory. pruviiied the mrvctwv %A ONC it"do" is vitt dis. $00
Wild rapid. As 6% owwk. the Stst ordet *jib ljMpw % IIA
Ike -W IM.
= =ZZWOL hi: of the lipbViettabuft w tow dausimste " NI aid The U99
IW Z:.-Aj;jO ;4jj"4~pr-*Wj is Ma&k-d to pvowm W&Vmk-sm of the r6t.. in 1h, p d Co.
Z . "taw
11141 AMW qulk"ItutivelY. 1"W's uPd. date on the
y
m=tbe V;~01_4 Ir4ruvemiticit of ethylitwe c" 4.0 Ma be
IL
is jefew It"(011t,e woo
is to x aq-118 a no a 0
010,
Ole 00
A
so
so
00
*Oil
iv $- &,
0 Of A 0
-A- L~&-ik.j.4 Jt_j__L A Q
COO* ull" by h$16 ill lbll~
okm wripe. U. AW1,4m of dft aw. L Kb-
,G.. A. VrWkmn. imW A. 1,
NA.J*AwdM"
W.&VS Owbak AcW. 8d. US.S.R.).
#as. "a, It. rim-S., Chilt"ICC Chia. I"$. 476-M
(URgink IONNOW-01 d. wvae" ~-,& The vu-
wow
el mck Ot
b.. b. immil O.WW SW -A walve.
be"- A. w%"y of tbw ailk* otl calabul.. Tbxvllo
ellpti. ~*Wr of On .1. betume 40 avA OW
p"ma Ohio ft be khv~ - Tbr wm io Im.
%rob bk* wtj" fto~ cleahl"u, t"044 With HNO~
jmw cwdwly W"w Omw drild. 114 qwu a ftm n-
wum to" 16-0 own. bm. vw. 4 CSWAYA au at..
W%hm Ob V wifta wers. w* Om mo&*
=40WW
bed 06"W #Ad H(l as 4 roba"thd rkm W J141
tv"w WM 0 Par YICW d pbmw kAmin p
amp ed base r"mm; candawsum Q4 the via" of MCI
6law bw im the Pot kd to W"WOO
of rmw wm NO& With mat" wit
C3
"kip. *Avg a tow
=
iliewkinwomm vwv%g~wel HaO. kam HoU La-
A to $A. IMO" IV". the ORIA11,14
0
7.7
stiowt of air at Into fer &
IN the tuldPla tw SmiVily IS ~W,j jo tjW
a E N
A 4- A-
0" Irmy. Imp 460' &Vj*, at W', ib, ywW ja p6oiji
is 11AV'i. to nwwtd 014h the au~=~,40 witual "k.
A-"m mW?b&t* (5%) "v= the 6ct", of the
bA~
6d C*Wpt At 4501, *a
(6,M) U~
the eawt dwap.
Pms W 6W* mod almm. du so dambi, to voUtibalbm
at The Haa ra k4 to the pwmm of w
so pblw* vw
=I. ahw 3 bmi tbw *a
ba HU em 84% of tha thewir: the cab&m ousamma
=W "VO
T*h arttv 1,11POWSON 111 XO'
the totalm applan to be vatWj be". OM hWd
hrmoom of V ekbo"b it "WWM
Irish, lopp" 5 *,
U
(pbrw rw at *A * Sp I.T4 unw, %blot" w -fth
cammidemill Am "vv wbm Wr=:.mL%lk8wcft6
am 6r$,
glos). m m
ON or MCC6 W" d Ammid w4ft
it UNIP" vub "Ad!
=t oak. Tin OWjT of Pa. fttkVM60 by ad&.
Cl
W "It it Cutle; with a CVV* tbO rWH W pbmd Oki -
tWwd 7031V of the ti;mir
'j; tau" calwom
cmig. 2% La" NW 10% mgm vv a Fw d
771A%. The WKSV&Wd "Vity is eatin n to taw
wemw cd VIM"; the mme. of ul" f"E, Slight
1"0" cd the Spucwfty d the awaira.
tem&rod bm"m by hewc. oWU fts be left bw
:4~lff
WO-ft" With CIACI,. N. Thom
40
160
.00
.40
000
-40
.00
woo
do*
see
&* 0
1060
so*
40*
too
woo
woo
100
I lwpw
0
6 of .q a 0 64, 4 A I tov 11 u a m a 1% v a b6 & 6. 42 a 44 a it m u
to
4.1-is
oil,
On
son

Imm AmAniq 4041"03 Oll
r, pov uwwmm 4" ju mug 10 &x""44 WtL V"J*
)a "m
ot 0" to peams an N&RA W6

ez -
30 - ftL '14AMW $a 0 604,fl % A
I Ov" "Nos Oml vg
$"I P" slipw
== "

00
1
'I" am " 2"ISM134 la kg" Ou WINOF
"AV =
A .
III j*rAj saaa
IIAI&M aq p wAV 4&um to
la
ORI C41 ~"Aw "Wo p 9"W" w4A^* to oat
=
4
6
6
04
%$)I
row P-M I so pftvl~0-14
vllv PM0
w so

o. -Plot" V Havu so Won 3w- -qk-m 09 p
~ j

p 00
so

t a tll 25 '0 $1 vi 'r, I T--4 -A A - I -
ft it
41 N 4 9 it it Iff m a I& AA ft 14 t- -

ts
* Jose** 60 6 0 0
"
A
4BL a A 4 [
z
*
4 4 4 4 4 4 4 a a
X A..A.
0 ON
Is
31
00
s a a s t 9 9 0 a 0 W a v * 6 4 & 4 - - r
6~ 9 0 1 V It. I 1~4-ii OR CL-M
'putgOM to "ho" 1111 a 0" 67011#0 A k%
Shah awl A. A..Wls MOL a--4 s-9 I -M
(Ulm mi skis". 100. 464-0. -IUW4 m ". awl It.'- t
WIN Istal" A star raw of culavviir "Pik"M. ;V~l Im.
MISS . OMI ifl
ar goal ulthilwir i0SN"m lbAl th,
Admv too %.d AW4 m4 411"t iter, wohw no 11W brAl 44
low 1volist. Of tow tvl.%Ilv 41,18. 'Ohl,livalt
slilk trimp In alvivior"i mith Ats1"iihWtq%m1i.
P, A 'I
see
go*
NO
too
Ill L (LMOKA10646
I Div. **.$AV
bitill do 0" Iti
u a Do A 1 0 %1 0 1 li-i il 4 1 9
a a a a A a 4 0 1 64 10
9000 9 * *
Alf
f-4. I

M#&bbskft Of VOW-*US* C4WYtk-'ftbGft66ft by
aryl VOW Kl%
1
1
00 1". 4
- FIN 111MI'l. Id A F
A A
-4 1h,
1
l
1
~
bw Vv and o" I be %&I.* pham lip r4k
l
.
;

00 13 '
l 00

0t
k ,is*

to 0
we 0

itIP" 11-084"
OR 141 stun It 0
too
V V. 91 moo 1 0 40 6 a a 4- r @1 9 OR
lot I a s a
U&
0 41 a
u 0 4 16 0 MT 8 m It V U P in IN IF a SO a 61 a 0 a to
1116*1" ms" vow is W
= of mw so PI.Mg-, A-..--
00
PiUm". MW A. 1. lobrIOrn. lchm#-
Mw. I*M m. sil. c#. C.A. 30. 4M';
a MWARM, of tbw mmV 00
tpb. 6" SMI war data. to The ~9411
of
00 of *of Ed " CatwYm "Y flallwAll
wato &Per the activity of
adwils. ewe C,4 &M its I
t%, It% *I powaves d& ~iwL CrCI6 W R" *V 0
49 Ow I d to%" CmAkhrraw. tot 6- am -00
1
affivt Its mw 1"talem ft togewm1bow.
MA a ago. Pl. CrM am Cu" h- Ow
A stfud to 1 - stabb tb"MWIY. "d
adkity of gd.C*C6 b PwIs
is rt*dft fettmfttfd with sit at 480*. IN CA-4ds.. ISO*
66 0 be MY 6MM Or dill"41 ftm tbt 6 poilml %be
HN kwVremsile
M; ,
tokiwacy (d. D TWkb lo #0 ol., CA. bil.
mots. MI; & mm Cuch
ON With 6 1111"d C;l
Oj% at 000 tMM wm prutkaft so W& rwalittas AA
at am, d& , -M, , sowtormted to 16% Of the f"Icting
PhCl. With Ura The effectivesm of the mt&17%t d-- We 0
carm but An iolow tin the 049W *111911"" 16
mnwwbat - . Tlw IDCmw al Cm In the tot*"
1! bvyftd a cidah falm. dm IKR ndw the rilkis xy of the
efialer ASS )see
- ovac I"
Phi It rm Vwy *MlY SWA th
VdOw rf. PbF did no bydn*ym evre
wq tie
fit am'. 6
;to*
too
I V- If T
I j m A s a Nd a a v I IF 0 0 a s
U 0 49 Q IA INPOCIllost ~dt $[I "all It U ~a
Vl()n the ~;at,4 I v i c t lon. I. K I i,ivt ir I: rr. ti 7-, fnr on
over -,tckril -;hur. Ob7,Tich. XMm., 1,5, No. iA-1,4tic Con'....ct
Orgwic jiti-tcti-inn, 1w,t. Ort- nin ~;h~mimtry, Acvi. ~;,A.
u W so e 4 so S-
a I. 1k 4 a
Is
Camlytist bydk fliihm... in, itoolhist 4*101"Wel -
If =MO."U" *11" "
f. (we. (lifoll - Ill. cw) 5, .to at

0. M271. Math. Matkas ate dt-
r
WrItIll"I Mf The or"ItiorM forlaren the plor-ows sooA
ipt.*10.1 Iwm. 4 OW M*1'1141 1.0 Ill, hPlIttv"tal(A (11,
11. awl the 1,11011"t 111) 110.6m t".
Wis I- *%wuu,i Its take ItIms-v 1% fell Vs I aml &I -
Witleol It %ilk 11W Ikal"altsm W avo G-lo,solorst WWI -hyth"
IW4 tw%mtwt kull. U1 IMIS voilk 4d"141*4 11 in
fe il
Wxv4d Ot to lom adwobimi It , Tbc chmp is
00 towilso A IA min. ~1,M (Ar~ Carl tor t% "b,
d-Ov"t vism-Avol- GI 11 f,11 I
r fe~,M
00 J': 1. volocts, It Is file IvIrmools, Jug I's 1% the le"osolo,
42j"$) Nis 1A oi.f - X)~ - Nixiorrov" 41or #two" dim.
000 rrsoc4im C4 X moss. .4 If
a
0011

ew
a NWOOR al X, W
. .1 Is Ilse Initial Swrtmrr.4 it.
twatis let the hytht4srualilm ul Coils ov" Cm. mrA4 CjI,
Sell I'lame tow q INI. ft" IV rislorr.W41 QIqW'.% I'v 16-
Mlkiokflekj~ 11WW ll~*l tO 1.11111kill
l1ki lbofolly
W"W
""0". five Me hydrognall'on 44 $*Gas anst 44 Coll.
"V*. IV. Kodke"Um of The byil" seefstit
sool"til" by*"*"" of ftuftm~ INd. -481-tv
(Rits)(sh asummary),- The effect 4 -Amnlros In The dim" -
akate tof Obt, It owderv -m floor "sotims Wrorlsudy sir-
11vtAhlovulborwetimikoots, lativArA totle semsorli" at else,
to-it Wartbotewl.
"Wisisla avveverat with kwv*n (Wis. 1114alsolpm.-
41111AMM&L 1,1111140101 f11,1111111111 Ma Oc IV lbe mvir4es Ok" ad 11W ki"lk
eurlm lbat Isa" tin 1vtoled'. w4hol
vidi old otilm Ii
9
well
see
410#
see
Of C
soll
000
600
Me*
weal

CE
o
*

tA w "
k
l

pW"Z 1-0A mas "Wyo.

go
1"k
j w:=
= "so
UNA 1
4m4 of Ni row.
9
a Nat % MW w4bomm mW
1V
"i
t
O
fil
mi
U
Ars=

Go a s
.
AS
ms
2
w
"
n"
8 11W thmit 64PI&O"S Aftfawd how #bow tv"Nmkol,
The q"01 rtkoms obmv"i 601 %r4nwU&1km td
OV" a I c%WY14 to " %1A canirt. 11.

90 ca%17%lfv h. rvi~ Ovor tl,W and platioufts Kyo 46*
99 drogemati n by of. 4irluu. Ibil. 61947o- In* theory 00
06 proposed la jart I Is applied to *Kplaratlon of v%ristion of 00
offeat with pressure, wA the 6hants of resetion
*MO to eatslyst polefting by 601 the order of roaction
to UO liquid ban* differ* fron that In the gasocus phase*
C
Hydregonat,lon
y 0 to disomsood. Tho applioa tiom of the
now ooov-pt dopes" partly on the ohose proo*ss tuvol"4
end on adoorptioal diffusion drfoots have so Importam"s
NOW

L to" "NOW
ai

r, 4 f, 4 4 4 a 4
L. to s, a b No a a a a a a a 0
I J 'A A
lit A,!!
do d i""FAMN (T M.
Mwwkvm (Ion, off C" Aad &i. UA.&K.). ago
go p"p. tow. "a. ZilL V.RAS wk 4wao"s),
TU mmamit of kb~ftft m Ow is
0e me, 41 O'Smkv,* 1.4m k tk pmm 5 i~~ (I too
got COJ by @=At""= I A I Fw
I'ars I at Ou Id. d NvAd 1 000
I's
so IRV L Ota" bf.) (cf - fthwAW. d al.. C.A. 36. do*
I V I r-A
411.), A%ft 7w (U), & law,
d.;9 1i n t AmayA of 6d&.
limp"id.povive
IL
L
R. L. May "gas
fto
gel,
oo 0:
"o
fto
Cor. MW., N SSS~ kloo
too
8 f chtm., sss~ too
0
low* 61411111 10 0
] wo
qvial'i bit 1141 iff
; ,-rTY-7
go
6
oo*o~*oooooooooo*oooooooloeo*oooo***Ooo*60
-00000000000*006
oooooioeo**oooo 0 9 0 o--q-j
I I

a r Ii I I I I Tit T --I _AA u Is I A p 4

d 60 SiArww'm as "*b' Mb 1w
b
A. A. halalmlas and j T I ulA%
,
'
O
-4W
0MV11"
s
1
S
I'
I
)._ -
6 Ian
R
S.
.,
'd
food
that be comm"vaum of tho vakitcy angle is a blich1v
4
s
th
ti
f
u
b
d
d
see
. u
a
mme o
e a
a hw
ag m
w
emp
m
ca Va ififtnueftte ushipid maplex. in evwy Way
11119MR 'o" am p hir boubtlity to the difectm of the
Motile llivii, iatqnww d6dawes 44 thm, catalyst go*
must be t4atmd W tbodiumdams of tb# a4wortmi ni-A, in tw,lrr that
m"Sistbammaps""Weapkit optimum6awf.
,r
k'
-m
Vir 4
the
w
lk
b
4
b
a
e ca
.
t
may
y &M
1
q
t
Wq%%U" of JJW V&k4WY "#W The 46"fal lutivilmv of Ow
1
d
k
h
d
rogerAtme 0
*
(110) "d (111) of KI in cato
yw" t
y
et"
O"It .16 a cakulatim of thf Optftuln Iniff.
cAffia" coallta
nwkw difutict bawd om sk ebm tbowy. It. R C,

&M C.
Or

C#v-
An
SSS~
too

---
1
W

u 0 a
an a 1 0 -W 0
.
anitit it a a it it to
SPA
0
00090 0 90 0 0 0 0 0 9 * 0 0 0 ovill 41 0 6 0 * 0 0 1& Al 0 0 6 0 0 1
0 * 0 0 000 0990 9 004 go 0-0 o 0 0 0 0 0 o 0 0 o 0 A
6 46 4 a 8 w 0 6 to V
a.- 0 owl - - - - to * * a 0 & 0 0 *
It, n D A j3 W -- F. to 0 a V, W v,
1JL1-J-.L#A
-11 M
011~# tf-tt -,to
T
Never" of W11 %dia" "4 WAkIps "Ollu
A Olly bftod halogen by, wafw valow. L. Kb, "11111.
A, A, IWAlklin, & V loin*ts, antl 0.
a , A. PildmAn
44#4. NOW. N18111 100. QW hN
go 40 - -A net* dirrvikou %if tbr tcatihom of ArX with &train
ofas foundi thbo mulls In Oisaboatliou of the bakqwn
WPUtcWtot fly 11) Awl it cattlynd by CuCle depcislied
4 cables of T1 or So. Only PbOll is FormW
what ilia gas tolwe"I to"Wit'l lio. IV. co., a. 0.
11 we aburnt, It is taliewd that ibir Initial rmtkin is
as unlilatiow., PhO 4- 6160 - IICI + WO + IQ[*; ILtv
it Oben vitili" toy Iloo to VA), *bile It trartto whb MO
awl givTO IICI owl 4:4116 Cl is ribul"ted "Hirt trathly
0: %ban Ik. %bile dichlivrobirmsews give a aftiowive nwHo-ro -.00
y*klk4 Coils awl MI. Posmat of 16.6 g. I1hC`I ar.-.1
'3 i 1 !
IJ.X-IX g, ligo over T911, c%mtg. 8% CuCIj at 1WRI" otih 490
00.3 a &r" vorlowit 44 134 941 v PM)II owl
46 _M 04 Sach U-7- too
go. 1.0"; 14KIII awl 114-33110 11 LF"hith. fth. VZ. ur
4 if; La a3tow, we goom ly wtivor. The ylebb al benseve rsoV CW.JI4 and Iloo ti~%w THlo-CuiLlf at Jka~* wilhz: 11146m
lit about 66% at At W. with notifrvaW drop at wow temps vvk-k-ity 3117-M7 save &.!'~ IICI. awl the Prod is
using. The c"vithimation covallysts (no detailed ykkis 4 tallied IM anti Cito in a 41A ratio. Paw4av W
C411 given). The 4-atalyst a6wly Ituotto its w0vity ol 23.8 g. PhCI Atu] 3-5 1. 11 to 113 mits. I- r v6x-ity iqo*
awl= 1. reztwWv%J by &i& 14.veiap at 6110'and *&1%. 242) over the TPO,-CuCho-41-1"' -100' ~899
will, CuCl.. The "chinimitica" red"lon bell" at about I-A.sav to I'bcl nilk"I sth I J imfl. IIA I Save awly Wol I
4M' on the t-v Motif citalpts. A TO-Co" catal t Ila; this qx0fiflift-41 florthowyollb, i go*
uwd at &U-NO with PbW and 1 -"Ira pvt anic showing that 11 litto-rat"t by cat,tlv~t. 14 eatable of flow.
ago
rowits: very little kOll foram. walk PhIlt readjo Sonve jgkdtllkg~ the U-UAl Atli hAll-ir -4141yok- livk-olyo4n. I
~)~j than IohCI under mnivarable conditions; I- Obviously. retifir.ti tuitable bor thi- -clit"inmuort" TV.
llit!- 10 0
Olt. Los!
M cim about 40- snulirt yielils than we obtakard Ocq~vo are q1thl. abir Im flu- apyl hAlk"
At SL A attALLU&SKAL L11146~406 ct'StOK'S"
a -ti ;4r Joe
U 0 49 go 'itW 0 n it
41110 0 * 010 0 0 0 0 0 0 0 0 0 0 6 0 0 0 o
6 Is
000.00 0 0 00 0 --- 0 *,1"-* 0 0 0 0 0 0 0 0 0 0 0 0 0
xmm~_T
Ine a of the dehydrogerial of on a
rival ftl
Off 0, 1110 911.1; ti. L.A. 4v, uf ki txjas..
2~7-re made with the note ty .. . 41
PC Cat. I No
tr~led fvr vrWWA. ar-tivit by ( rate of bylirwhatimi
of Imityli.1w (1) to Iml.131kim (11) at Comt. -LJ%IC'C w1mity
nmd tr"Ift, - astil rrs"wral"I in gin air oirmni betivecis mitit,
Ce"mmk4it twillfitm-4 for kitictic "tidy ;m- 6101,41V
and llixh %pace velocity, I I'Uw) I'A. cafillyo Mir.; lit thk
;C%tip, mvip'. Under OX"'I Mill. (rillat pm%mitchatill.
PCIP at not Ir." than W'~ drIlyhozvo %tim to 11. lighcr
trilip, Im"s -A& fractimm '11M allit. 0 11 lmllwfl i'4
bOul,ethimt of thiz krigills of thr ritil (11, 9. aml 1". mill ).
At a tinse of cf(art p - nA wc., the appin tit avillfitioit
,rill-tv of I - 11, 4- It i, -L"N.4 krat./mOt: tit N.M-
OW Alid .14-34 It 74 , . . .
'It of balaort.
Ifir 4 mill., v ,m. vill. -,I vrifalv,t u, tit,, jb 14) ulhl.
I IN: at 5 1111 1 If, k "r41 1. 6 1 L. F.:.' W11cf-I v4 11. rAl 1, oll, 'M.
a I ill I ti k ft. 1. 11 :1 2. 11 yd"ICAt t-Ml. 4).
wl't of 11 5.11 fti"k. : it r." it 1.92. IM CS 14. 05.1
it ft, :(!I, wi) '--39% LI.Q. Ul 0 (7.9. 0.0. 11.3
4 3 %1-%' 12 -, v vol. of catalyst
1-1) - A. I 't
ill)-, p 11,J) 111111 11g: ;it . 1.1-o. ;1.8,1 (6.M. 91.4, (1.4
7.,',, J1.11) 7.1; at 3.62, 4 It, (14 8 82 7, 0 4 15 4
1,U) 10) A; fit OW ( IA 111111.) KIP. !11~ bn.i3, Rill 0:4
'*.'-'. 1.2~ VIA. (2) Viii-,iijon M p Imill 1.1m0 3110 mill
111vt ru-i-I ill(- vit 1,1 otily (mm A-5 in CA snole % (at MP
r iii't-A. Thk wufirm~, oil the whole., Compict,
Cowrage C4 tht vnlal)~t %liffmcr, the det-latim Iltivil
ril"I ("
0 1C .1t."t (if (I(-Mlllllll. of 11. (3) In MIXI,l
of I + It, awr ill,, ~alne catalyl, Jw)lh the fichytIrrigena
tion I -- It mid 11tcotillfri. (#1 11 mvitr. The decompri
bictraict %%ith lin! mid with the initial cmtent cl
11 ill file Illikt., tit r.17 alld 6P)" file talu (if (If'Compa. 0
11 rx,ptA4 th,il -4 it,f Immatim mhcn the cmicut of ft I
.7~,'_ I'vampiv. tit Imlavive-. vol. tif valal)st 2 nil. 4
14 fill. ctli'lltil f P 1,19) mill. tic, 2 1
tribit. p.,i%vd In 11 it it - at 17 '. I In bittial mixt. IOD
97.8. 70.1, atid 51)A mOv ';, It nbf~jjm,d INI. 27A. A74
~O:v D~___>
r r

;MRSt
t
R. I
low.
misiftA by "ll-*
'
by a PW be,o. 11: saw mm,=~.7
be VA Is VA on tmm wo
b
ut
n t4
4l"w*40A-
A- -1 It"' Th VP, SM
Ilaw Wome
Wwd
to CO&O
n. prowl oft
Al Is oft
.100811, 1" "Obw
%
i~~
E5
a two of taw -do. .1
be cm
M
i
e
k i
Ma
T
.
t '"aft
irt vd. I
..t 1, .su
z

w IFSPIP-10*
Th
00 ma I I a 00
goo
10
solo
No*
;o 00,
600
1#00
pit, e o i,
"to
a,# A Im a L
A JL-
"tit;
km~-Jw

#OA

Oqp C

7 to the

"
poq"A.Mada 1 664 of
40"
wb
"
r
1
dais 10
y.
T.
.4
, r
f
?

"
lkilb T
It
It
k
ime,
. N.
I'SMAIII K
Oct
OOW

wk I"
P 0
I lit 1,61,66i me
AN I I
see
r. too
69*
see
Sol
"000,60 00"
esooefooooooooooooo:oosooooooooooooo0000900
1100000 01009
*"New
6 0 r 4 d a % 0 N-A ~m ~ , .-A-S-L .1-AL- t--& -- -
M alt $#too A'A 496 #4#464
a -jt:
0
004
000
60a
0o
o0: 400
*03 .001
08 f too
3 000
008
Poo
3.00
p1m 4RI p $"WNW"" 841 WMAW4 Almm ".4
000 "-VIP 0 40-10 li
0*0
too
p UPU OU '-41-0ajpAq p
0-000-0 %M p r"s IRl'irw wm* fee
M wVqA"""J$pftp- w4l
P, HOMILOW 1"0"1 v -$%an .(w 00
00. v ~v
roo
00-
.00
'J",-,f woo
D! 1 6 14 1 # , I
,I ; -'j , it.
non tim Theory of the Selection of Catnlys!'s 11 by A, A Balandin (p. FOO
f0: Jovrnal of Gene al ChemIrt (Zhurr;al Obchehei Kh'mil) 1~-Oj Volume 16p No. (
!::" F~v ZO
4 4
of A 11
]
09 a -60
00
git
Ito - "I'mv rdymnetimni, mlymne: hence. the room 1019b tt4wirk I
5.
rm- Oven. .82-111t to 61"111194111)(14 MITI evolvetied all",- tat COt b.f. waseld. U.S. Ot
04. Co 40.6 is
);`ild. CA calwyk. its . 11, nk it., ;;-ti Clis. Coll %ji ) A
rtpb dild. with CCA, (1:2 do 0.) at arme (T"b Cstalyst "" I At 3. after ST ton. A it. cr L lot
the amt.. r. of reg"Welillilm I it k falling to 31 after 21 bil.; on 2md rv.
MC":Clli 9""ah"ce'l Oft t' Of the Clawlenutir) rtnusloed gtat tim all" TI lom. I - No. 4. M Kra"Wralkat of a
rwwt kally Indelemirol tot I be role, ml f."Insig cutalvot faillm from s AI A IoW tat 41s)") in add sk 941""'
4. &%-1 %AkJ W jiny. 1. I-staIrst, %I N751, at OWO few 3 tws. rrviorril its fall %vivow 011vily; &too
increasing /. e I .. W" f im at" and 3m). villect W64 alwood with an ak~tcam "It. (1: 1 kat
n-P. 42) At WO", withimut dilo,. XMI N.A. for 21"11-z 23
'ill**" than In Kilih.lim. a.jfs fWh,bmI*wjyO only to # 44; It is rmornfrorrul"I Ito rrertottate every 2tJo- 1;e 0
W"k 1w- 1401 P hg I - 7311. Mo. 1W. 2OU 31OU h". (7) urkim a pr"wre reAw'"I In 3M Nam. 11it, A
a - 33.4. 31 V. 31 k 30 7. 22.4, to op.; btwv I he iw~ *&a 41 as against 'WI Ulvlff I at on. &Mt 48 ill 1: 9 121411 - d11111 I ; 0 0
dortivily, P - W. fr%lwrvdns I' in kif.llir.~ij ,in t, Voith m (at folo'); conic'"e"lly, -111", 1"th COR W Mwe
bt!W at 4 1111111"'J". f 9f.. 1111". 1:2,f to 430. P - oil j., eflocti" than mfwvf pm%urt. (8) Activiallow of tior
j 3.4 000
(3)1o'swrimimm fresisly proppl. relmlyl. at Ato)% its It. r"wtd im 8 4
I hit koor it of I he c4istrin of eat afrat from W con. (buhung as against o X 1 for M; ton activation in If to WvvwAwy "411411
4 34 sall. ratalro) to 11 I-M. 42.s Md.) load so elect C" 0 at oftevrwilrov"etiton. iv) Sim"riourntsa: Iran% of lia lassil-
60"OS" WO f X11) W. (4) Fiample of a b*kOft u( a valt the Cu-Cr eatals-st. 110) AMn of IIX(Ai rot-ts the ~00
i b4w. M! total Imm I.M.W4 4J% C.. *I am", 1 4-,V. dan. O""T but this effect cannot IV restated on fternatmoo".
ITIMCCIA so 1!2 Imsdood 41.A cmdeaftle. $411411
(11) r$ 41091. PAC11101, in the Cloovivassir. 0.1-41.2 1. is
V*14 401.7" , hdAwA ton Et to Mi. ell( M. I be" I W 21) rid. at 0. 1 X Ito in .411110
I" the COlk"111le. Ph%j, 11.26 C.. PhFj Ph Passed.
IVAI it.. too ArOlf added until a light -yellow lint it lotstaimord; aftet IS 41
ovoids. standing its thedark, in rid, tif It)", KI is btlilell anti
^z the Ism" kxlifw Mral"I aith NOACk. imrwwv 0.73,
ties
is*
Ito 0
Ot's, fit to I, to, 0 14 a d it R a As to It KAQ M I In
0 0 0 :J* q 0 So 0 0 0 so 6 0 0 0 0 0 So 0 11111 0 SO 0
1*411 1-11110411,111141114111 _*_0 0 * So 4 So 6 so
0 0 q J" 2 lk a It,*
0
Ji
taxi"#$ 6w P,
00, nUI342. Thee pin *at &Wis.
I-allil It
I Amid of PKII.C11 Xe Vol
4 list
Ah. U. Malmakruse, will A. A T10140pre am NO., of fall-"* IN d* I with Name and mor.
Ion's (C.A. 21 4M) mIttumptim of 0* I-*wwikm of
Afflaal L'brow, iIJ-1411-14.) 19. ONVOWINAIN Roo- C114 awt WIS In the am Imm thew mml%ts,-. Tath"
"Wrtle at Ph& tow AT. T1 of
Coll GrA C#114 WT lorvied by way of byinsommicirsis .4
a cono.. Asomat Iwit. mmical .11 rb I(I i Ad r%CII; ell&; WA It "All1k. VMIL 11,1444khl-
MOIXII, In Ilat t"wArminift r1ov with Ik- frativ. up to Ivivat. this hf*UVSWYM# WAY bt dW 10 If Will. 11 0%
4 @"1-- Ibm 14111061 0440101INt tWw W MISVI 0 - Xl-N
-will be a two reaction. T%u comM vm be itirr"iy
WC.. at NO. rh OIL% 661$1 676*1 5 - 0.7, 114, 1104, FrOWA-4mot viefther *a- It dnfnnw4- 000
. b
%bdv"4 a cilacnicill crilition wlkwllyzm "w"
%ilk coo (1:8 low) at I - 114 Ovarremolowme to knuathn of 1PbCII:CIjj. Tu dw-
bed i milk OWN to ;~~. PLICO, 8 - 0.5t, 6.2. 304. maps. Of PlicilXHILO(lihm. "ilk I:1c1w)-w1y:-t 411011111
-*1145 foms.). 31.4ri. %'kill$ we ommq!m fly Iveroo Iran &W to Ms. tow cc tow kmw r. At t 30 we, q
WIF tbrtw4imt %has fill Cm CI~CGIAJ!Y" "m Is but is all time kow 2% Vo It- between SW will W; at OW'. 9,
fewsthow toommilit. atom'. 71w
8,
I* nowswriall nwthm WAS dremosmattif by mempon. 1111W.Withello.
It" tapts. a quarls. ponvialls, mewl, &w km Cll!;e Abe. Ueda am CMbtkm. the lict-campa. of Ph.
lubm DrA wub= P4 " cu=m parmstip; mdbu elf . III is da a than Its formation Irvan Poll
I. AMR.
she kilo aft the uslur of the w4 have an tam -d VbNII% kwwa to "bit potraverisation. lowtv 9. 1 logo
7w. aw"is that km WWI 04 kvit carbon black i~~n to *IA% with 62 wt. !-w
am dn,%&A obs"willy Set 4 it* on - flat don a" I%Nll., Will to 20#1 arfill 3X-q - at simallew r. tow effect Ire 0
-rvw cit Cie or on omamsel PC. V- s4amommict; is *Savant owy -- A of Ph. 1160
V, b oln how with SI Will fit. O&fx.;Wh
towl a# dilm. with 4 of 6% lumvis. 11 Mine I I to,
v... %be wom allow ins" M bm I !A,. At U*, A at a 31% &ad h-mm 26;9 to 16. 1 at 9 7 1 . soudkv avats. St do*
room. terap. GDO Itailthemalmot 4 v results Is a steep iv- 11*011 Q%) WT allective only at the lcom w. Om goo
ji. 311% wAtb 1:2 CW at f a sec.. bwd% aillia. of IsbOll has a bnw&cW ellact ca 5 an tat
follosmil by slow - arkis further iocreft*4 T; p= of nat, at 6w*. r 71, 5 rome fromm 33 to 40%
0 1 flat has' to do am r-AW - All".. Soce, am al 14111% rholf *will$ to a alwarlato dws of tow woo
5 can Allow ~~a Values with catalysts; it metray, divomova, wbkfA wmW awrially tia dgadmi at work
wberiamoo ", wy tm - rate d dematim. d lemmer. ralyriorrimation of Phcll: Collis fttjdystd by C. 111,00
I%Cn: Cole lia a blifter IN-,44 ill"Nsfur-d-l-laww's aide" it Mfg. 77,01; rkcll:cl(,. PLIOA arvem 6*9
SPOI191110glik LIM Ifft "TaW C of M mal-II.Amr. at 4.10' was mv"IC4 into " -",w
mmv VOKWA 16"A mall. only 311 ~r" MCI[: Cit... Woe
mt�kMlomm 14. TINJ
04 A a a a is 31 0 v
11 1*0 lei
0 0 0 0 0 0 0 0 0 0 0 0
4 Z -i - 0 0 i I It A S
a 0 # 0 0 0 0 0 9 0
A
A A
k

D,
lot
1
E.
alptr
bodW
comV4
dW
W
4dol
k art
W
ams

a * 4 a, 4
0 0 0 6 0
9 * : 0 :
sm J!M61
%4-. WCV.S.A.R.). 1. A W Chrot
2TY-ft 190)(11 RAW4W ' i"PU"PA
at 11tweaptins to orp. pbut If;;; %be cift.-
is spiewic ftWkm by diets.. it Is am",
404*0powtual it
I:Clit Without plow @rpm.,. so wjy
I Ims" JU "Now but I
Immm VON
ft. C4 a va , mid 4(X6
hw SIPM, MI"t 14 f to d*W
Pe WUMetcontent In the lakimA Ohl. In-

at the OPMW of MR, The I
=
dwreapolibelatter
34. AM IM tha PWM,. 6;
('
*0 A
d
l
d
tW
0
V
ft
w
Mm
w
y%
.
)
comkonw, mw brw* the Mmiw
lot. ww I Im. fmp.. I'd, wtvavr I
w*
d1h iX

00 (kW" am
g
dw to tod. wrars. pwtku IMY at
AAJ I&NI no to a prommatimil efort of
Cj4Uvs mine.. the calairm va eal
1
rv PbRi bit c&v=.g!pmmI
Am
,
,. ak sft~ftmw at
smau.. his% ywb of P%011:01#
Dilm. twitit M Is beds
thest, I N. We
mma of the b-pa..
dw..P:m
&t L W110-
fthkv. cam be fecow"
111
with DD-~ FWJ At 40
"fA In the coaft"to mp
Wo. by fivm;a"~ 5
owt an "Vemant of the CAM-
Won with the &W of X&A,
Sid comopowats. 6 vc
for the IMS001. of "WARINN
devj___
rizatics. R. T.
let
of
40
400
lot
411114
IGO
if
4111116
111110
41111o
40*
see
too
111 6 49 00 01; a ve v a I IF 111 9 a a S 0 1 d6.
VA
T ZZ
"l, If I, f P! m
AL
MU
*0 oil bbtlill-Wiff
reactlus ma "014,41
the neawim of dm vaf~t*w ja~ftijm b
li" 44 b?*620 tat L. Kh. FreMs. A. A. V*
Lebr4ava. WW 0. A. Frkl~ (Aced. M.
00 .3rliftu
00 Moacw). Ads Plip"him, V.R.S.S. 21.
WMIOW-T" Priuml Wat an %be vew-*vc
00 rmtkm Rl wyl baw" WRk 1W is the imp. raw of
Is MMWW wM r" warI4 pu*%iwly I% tht
60 0 of &X% Ed %e
00 a malrat Kv UO of ha"m bl,
llwull Is pbtw Mt. as wa on 1&" 1101 emy La ww its
Ole Itaitt the &"in W U. ww"" otbw met% &an"
0 * It. = of %I* vorl" TWMA go the twuma." .4
00 lot N duatt eke" 6 PrOPM4 which vaplaw the
00 keb INA IMB SIS The otbw obmtrvW pb-X-M
With tu vepw-pbmr by"YWO of I to phend.
0* P. 1. I-Mqg
f lee
too
love ""saw lee
ONO 11:111411"
aiv 1111,61 Ta 10 all
90 *A Rd 9 a I I IN 0 0
at
Mb db A 0
-F"-f IF
I
irk a
4 M -AL C-L J-6 f-A
Is Aq 1.0 yo-'#*
too *00
*of "00
ot 0011
#Fro~ilpn of A A. liala"din Old
Ak-
Ads. P, 111-1314.
of Orrouip ckemajolrat, Arod-my
MV.S.M. I v, 616
Vor tho stady two ardro of r1pelin-to were "vadO, Go*
one Involsing dilution with carbon dioxide And the 0 S
00. oWr withael dilution. In both OffiPs Ow 1P1"Pcr4-
lure now vrwily *"a estalyst jehromium "Ildol too
we" kvpt efmt&nL Results ovolmd. 000
w*o
go*
000
vo*
goo
wee
1, 4 a go ii, low.1 -1 10 4k - Ofliii, O-W Str 1 00
0 -Aoi _i,-- In 0 1010
to I, p m, .1 a A 11 I's of H of 0 1 24 a 4 3 0 9
0 0 0 0 0 * 0 0 0 0 6 0 0 9 0 * 0 0 0 * 0 * 0 0 0 0 0 0 0 0 0 4
0 0 0 0 111, # 0 0 0 0 0 0-0 top 0 0 0 0 0 e 0 0 0 * 0 111 0 0 106
t 4 a 4 4 , I;I. # 9 0 4 9 0 0 0 a #
IF A 9 1
411 0 0 MD 0
IN
A-A. ". ffmA
00 A
t
00
So A TW AWbubs W lut"I fififets

"woksm
All*
S
S
V
M
OWS
M
n
21
1
-
.
.
.
.
.
06
)
y
.
I
)I ll~ C.A. ft. 01"', all 64041, -Iftqw,,4-vj
""I. lop~r, was vv*;4wttfr almst.-I I'v
rmitalytt c-4, I?.
00 Ow"am- "m "wimin w&% 1.41~1 at ri- t,id-
fly -we Ci P40ON a- DOW frIIIIIS let" iokkfWft-
go
00 Amr* bnewly; it rrnw"" cunt. 14) aluoli

goo 0.8 ft. PIT I., sbM UNA thir cold. talk. TIw activd.
0- mo n *I n-* cowrim of the murfav to 18,m) cid,
M Md.. "4 is RAW ift the bQri&mt&I
Tbr ". -
"n&
HO diff
ff f
M
f
W
i
roo
GM o
,
11chn (C.A. S. at Sow
,
fel
4
1
l
w saw
l. 71M 1 Its We lotgfprrltd to

00 that lbe "kat Wive ralalr4l palribm we ski l1w
i0l-f*" 14 OW tWM SOMS. TIW QA-lfTV VVUj"*
1 A X hP, jwf
ftum Ow &d*
46
t
t
1
4 3~
.
NM
.
.- .
_
i
CW#-*f,&r ul thr -11IMPat 4-1-wpli-wl "vvI "ol Iw thr n..l
A. VU-twl%-f
&
w w w V
0 * 41
0
0
I*$
MJ
I HIM SOMPIV
I Tri
`109
F V* 0
So 0
Ot
see
90.0
SO*
woo
0
9 a 4 3 a 0
----- -- ----- --
us VChemistry - ep/cat 46
cbemistry - AUO*I, C011(dial
*A PkrelcoahemIcal SUdy or M11ca-Gel Catalptap" Te Wei, A. SmUndln,, Inat Ora C-4mp
Aead Sai usmt wmwo 16 pr
"AcU PIW&IeDdWdoa MWO VbI M# 3b 5
Gives diffvtAI&I beating mr"s for ollics-01 catalyats. Plots cur"s of rate of
9mU' n of vat.or, at . temporaturep tv astalysto. %mr 1"linjagry bouLtreatmant
for ev"rel days at toMaraturts 46% 545s 70D# 7909 end 103D'OC., &Ape off those ourm
IrAI&Aea that the therval lrrevvrO.ble lmaotlvatl n of catalystp whI& starls 4M-
55CPC# Is not due to any Imer struutural dharWe but probabI7 to, ellaination of
definIts amomt, of &*x1eally bound vator, Received# 12 OA 1945.
FA 54T40
Wt. Otj um't. Chon., AN
"zip rm,-Jr-g
a D 4~ it
A,
A A L A- A -1 A
-a
11,
it * 0 7-40
#-*"TqTqv vw 1 1
1.00
4 30T at o1 tha sows 4j 60 astiod" le"I We 64 64 "Utrity -
dwm "Wift. A. 1-111doeseillew and N. A. Vali - -00
(M,V.IMmOWWVftm*vojv M4*xow). C*mjw. me*
ad. age. U.R.S.S. U. ta...06m)(18 U866A), --
= cmrd (6twons vialewolm chrriatlice t~M~ WW KAI- lee
bwm Mtratim astervica (v4;Tjthj-6bwr a% ah -l,411-
bole tnw) q I I - *vaw4 wkb It NUet to nown *11
I" with W."VOSIbe elipmaylvaime led her NU-
fles. A4Mivw 14 c*1191111410 -M
R 6 t a t be nwq hod ci zemook WI'-PWy vmt
a .
a hutted W 40', 090
I"I. it. p. 1471 wina tww"M
Tbp talc a dchrinve"tift to Cyckhr"m to bria" w
she* vlarywilik 6J*%44* wl" owd an nwv*w fiV The cuts- 4*0
lysie W4. lw.1 to be tWkv tb&t With AMPIMI-4V S'btv4" '" 1a011111
4:111"kie. ma thee merlierstiles "all is CW./Ov* Was 13AN
fat the erberyartfle4yP C�Uhn and 14,= 1w the SMI-bi- E
b,k Inw. Tin ~im (anewrot the kiwJc I elm coo
F-- It? awsbUshod by 5 C.A. 30. 4") . =.-
krgTpW of th, Iwo es y1ts obwwd that the Pt
c"ard tow it , mobaAam, but saresat-I am
1111maebtfibre, aW*dos. The wMdy diftematst activi-
ti. Relay -be due to the 4 6eforMim of clelor-
to
ank ww to
M-V,LOvvw&OSGv SWX viv Moir-$ 145COIC Mv~ AN Iss
lee
View
444#9 10" 00.6.0 lee
It ~*, "; - =
of a i -09 a
$06 000 0 00 *go 0-a-G-16-6*6 a a *Leo 009
0 At 9 S 41 0 ;jb
A
D4r*spm&Ii"- -oil i6m etrw
R. Lufl4cr and 0. 70u"ety402,
34ate vaiv.. mmqvv~. roympf,
fted. 060d. ki. SS, 12' 411)(10641tili Pnlli%h);
94. C.A. 40. -00
00 c
with Okomw4tryt tyruatter lot the jort-wittv si AKU
This It" pawd ovtr a #"Iwv4 Co rlyromife misIrl
s,
16mr4im to Adkins mA Conetv 111). m &-%Naql as
111) (C.A. 44,417") is a qows to juvrivWx tabr.
diki. with 9 nW-, LIXimd. 1. at a spim wrimiiv rg Xly~-
00 ul. kqvidA. mulystflw. wW at Ttw
:00 eon4emte W" W*btd. dtkd with KMN. WW ibe
99 umatyl.shy"wbanx JIV) dirld. by By. Tlyty nvets,
orl wm cv&vttd -nt brim and artalyervI [tit 014,
0. CO. AM It. At as' M gavv 93% (4 vumsmwe
0 OP
0
6341", IV, - 1weryke It. gavv #IV; of eft"keVele
.:SS: 80.0l.v IV. III could bo revervated and It evuld
am. Chastity In spect, volmty W little retvi. The
nuLlo "O"itylk way I br ydropuatkin ty! 1 to 114C: City.
CA) was formcl by pwtW mimilmi W ('(h Ipy 0-A ut the If -
pmldmd, Some stilbrar way imbird but Its byromikort
was twlkvwql to Imr due I he My it a Sal A"11, 4d
met
timof I Jsdkv*sNI from thr point ut view id HA mothil-ki
Atthur A. IkAWKIL
11-C-4 M. SOWN
too. W.644
isto" 440 ~:ij
0 Air 10 it
4 My A I a
It- 0 * a W 0
00 8 4 : 0
0 0 0 0 0
-D NDI ,31-As A*- .. Vo
A. KMt!1Y'L--Z'- V"
"Isotopic Exchange in the t4~drogsnation of Benzene with Deuterium ovor Platinum
and Chromic Oxide Catalyataj" Z, Ve KNu-ina, Ro V. Teys
IODmpt Rend Acad Sci, Ursa" Vol 53, 1901, pp,715-18
During the hydrogenation of benzene over a Pt-on-asbestos catalyst and over
Cr 0 j, it was observed that exchange with D occurrede Under the conditions
of2de experiment, Leo, at 1000 with tho Pt catalyst and with a If-benzene mole
ratio 8f 14p corVlote Yqdrogenation was achieved, but with the Cr 0 catalyst
at 160 and with the other conditions the same, the degree of hyidgenation
was about 8-12%j whereas thle degree of Isotopic exchange amountad to as much
an We
SO: W-336,, 31 Mar. 48.
---- --- 0
"The. of till! -9"t-iir Pit,:zu 'jubntitutlon. of ~-,.vdroxyl i'or Aryl ii'llOr-eng
Dok A'~55, NO. 1, 1946- Ac.td. of Scj., Inct. of Orf7t-,"c Chen. Hr):lcow-
v a P a
LIE M's At % 0
A F COWYIW *"bar
womalk orso. tiv 10, sow,
~VA a5~A Ubn1tva. ond G. A.
U
10171 "00
4714111. 40. 611SM-71m etialytic &CjjvjjyA bdwa get
The gm-Nma Cam"I'lioll of MI lato JON011 by 1100 Vapor
Isp= la"ftwilbO.N.
al *&* PI Olk
ON (41%) to vow"Vienlate its I-mm A C" llw~%ilh
"'islibmaliam. "kith Is velictabk itbe" ~kkk* and amikc.1
Atmove,110-W. Wilbam"albeCu silkled, the adivity W
lbt ftialylit Is four plemerved up to AW' but falls oil ago
above that lemp... pute sit" Sri Mee
worn blizowbe1=1vatium In a t the Mine trimp.
lanp (400-W). In tubes W W20 mm. th4m.. w,d. W
C4141M 60 Mi.. With 18.0 #. MO Alki 111111101 10 15
H&O pawed In each ran at 430% W% UPU*. an4 tkk)
40-60 vAlm
~mbe yklb ;I PbOll *am aptorm. twice those
Corugvlele
tvpqwat is achieved by brati*4 In an all stmam 6 hri.
M rdw. virms tit Moll Attained a v- owl 3111, 44 lh~'
MCI pa-rd. Calslyts t-4-woftivy hlacl~ .. NO*
OVIS Von tile ahmout m"l4r(Tly Infilled by tt"J"Ta"Almal
but " is vitbutil clin't on thontally disai-
"Ill Col.)
.1. yvis. Thus. ttratn"t with Cu all. can I... see
m"41 to di%linjUlth betwern lev"vible awl illew".414e tie.
w1wstlem. Artivallon with Cthl*% Is "Psally to" litt. we
lines " catairse the eschmat*. N. Mal
I k A 04 lltktwocht~ L"llatot CA.AlwCATIN t-r' -%I~- boo
Iwo*
-=le-t# to"" .69 4my set
VX41
Al MISA& tar"#
Too- e-0-0 0- 0-

0

0 o0
--I
De
00 A -

Do

DOI A rmm he mW-mm'"'d ma s."s, is Games C-.
Imam
=1.1 ms, MA migbar 01
by. Apmu"ea
" *11- A=vrftWmRu9,I
Cy"
jet...,
hki

on. A. A. 8
U ,
N
41 a and M
t
9
M
n.
ar
J
see
elf
1
0
SHM
A
3 .
1
ry
D.t 47
, P.
The w,*tW at Deopla and M cCartY was OT&Iu-
j was fmn4 that butadi
. I ons, and also, butYI-
goo

1
0
a art aboorbilid b, AMAWW
W
terminnums of bmmM
d
C
yaside
WAI RItke "t
IS this P

oo
,
3
0 : e
nee
bu low givo incormt relults.
tadiene and butYll

DOW Wyed due to the
Aboarppon of butadient to bell
I
03L
formatlion of a aduble C40P
Sol

96
1041
160462 OL"WICA's"
iL
4111 lap
4d I
ILI I t- I
t--r 11 oil 8 0,,
u .0 0 Is P o o o oo o
DO 0
MWIN11 A. A.
of Me cotalytic fornatloo and dewmpWil"
gj~,% R Anil lit
Gm. Ckirpt. 17, 2 IFU-ir.4 194-0 tin
cf. C.A. 41 5117i.-to order to. det. quit"ItItatlIrTly the
i
YIEMS of MC11:01, froin I'M as, a function of triolo.,
iqricc N-OfIcity. And tit"c 4 teintairl. 30-rmin. runt urric
ou'le under rigmpusly ct*itrplkd coodilion'.'AIIII visital)"1%
of rnedicus" activity, rerxitirrated tit ficirturot Intetivit1% for
fw,t the little nrcrs~iry ( IS-25 Into.) to k-rep Vic urtivity 9
unchanerti; t1hilt wA% checked by statilliliAl rtov;. Weire atut
after each eipt.. iteith 273 tnl. hiltrid Plirstil.
PhUCCCh - 1:2 tools., nt the even It-MD. With Ire-
clurnit Olessirt trgoicraticini, ',oir r-cwtion riF the cmalpt krIll -
41 const. activity ditrinK 78-W gunA. vw "itelit, x -if
1111C11:01, lit the C-1kn"Iti, Ax.rv C~qircclcql lit Vach raw
for thr.61ght ili.,T~rvncc lwtwi:tn thcarittal artivity of the
catalyst in the rottin irtim and Out Minwn In the 2 irtintirrit
tit fit, altri Trier cri"'cquirntly to ill(* -.title aclivily. Its it
t-i-Tial 7-11r. C!kPt. at ON)". It wi%IL "istx-riallicil thil tile
miwicn"te crintain.% only PbCII:CIIj iod untencted
PhEt. At N'W Anil A75% with ~Y) rnt.. 7 rim. of riltalililt
dilli, Phrt:C(N - 1.2 t"crMi-C of tht- , Ice vi: nc
ity r"Ilt?xI In rapid of S; e.g.. tit N*411' I ) mill,
UXI mt, A.1hr., x - 70 Anil 30~-~ tat (WO) it It
it
31.61-~- rc-.p , (he 2 titimil CV0 'Anil AM')' ln(tt%,rct mt
athytt 15C) irdA./hr., a 4114.V~. M (V4*. x A"t lit. It
cireati" with Inti-r-axint pfinee yriadty. tugities 1111imto a
Virly fl~wt otiv. (x at".tt 40-r. at M"it 3M) trit.11.1hr.. tbenv
%knVIV fictleaticq. to JV',at 22VI 111I.A.Air.,
IIIJIYI* pIrAtiol x apiti,t [tic their otcrint.ict
%her t .. rtt!litliot (tic tul'o.', I m It
IM410 H11,10 + a) ( V12731 (While fill. Of
PhFt, of -,p. rr. 4, Vj~xctl lit I rrAii.. ff nulls -At., t;
vctmity al tbQ WF. Ira, WOO ill r - sl~
holp ,), 11 1'.10' olill 575" show tillifolln illkrva~c 'Ai0l
111CM-4119'r. fa%lt r lit UANt r It. at AN), x first fises steeply
"lift i'l," ls,i~g ~, I-) RIV"It 411'~ or I - :I.n Svc., thvil ill,-
crr.t~- I'lls- ob%icilit iii1tvilirtation that the fAl
III` x, al A.st) '. I( vcry Iniv vi-toullici, I-, ditv to tic
irmllit, (,f tile IlliCilX111 forin(d. %rxi ronfirrocid dliott;
fly li-mr, it trivur ilic vitrit, rataly,l, dild. with COI
(1:2 tor-lv,), it lIPI ;twl sit ~173 tril. ml thr,
forlifir plcr :0 (Vat'. up to Y)"~ of tile 1*hCII_._
CII, psj-(il 1, tftcntfsj~l. Th, of Ic(viivipn, lit-
C-rea,,r,, will Ifie. (villp. atid niih r. Th.it (fie tmax. I,( x.
(%li*tfvvd sictu.111y'a FtNtill ot 11M"111111. nf Ph-
CIf;CIII I% sh'.11VII by C%tt.llw Imillp (he cotitV (4 x .1K,1111,411
r, lwynii,l thi: this rxtrar,toi,,o ilrmihi give. tit r
7.1 -ec., it as miziiti,t I c swill it 45" t, - th,,- drill, It
27'-'r, rqual, vttv r1o'cly the ft.-riti- vf Occollip". ff"Iful
diellOlY lit their Will' 310 T- TlW viluscity (,( cataIrtir
decoini'li. of I'llk, I I ~C lit is cot"hicraMy hither than thator
(host,al 025", pj,TnI)-.I% lift 041%
1,11CII101, ollcll~llixol, Isillitc,is Ill vala ).0c gIrvointim.. lit
I-A
-BALANDINI-A.-A.--
"Soviet Obamistry on Zvo of Thirtieth Anniversary of
October Revolutimp" A. A., Balandin, B.. M.,Berkongam,
A. N. Newayanov, Moooov, 20 Py
.."UspeNhl Xhimll" Vol XVI, No
General historical article brIefly recounts morela-
'portent vorks of Soviet scientists, such as lowonomovp
Gesso Bab# Vernadsklyp Fersuan, oto. Pictures of tho
more Important of these scientists.
TA40T8
#0 goo,46 # 00 0 0 0 Olt, g, 0 0 S s 4
8 it tf
At 1. : f -A-- -
ve-stj -
06 t .11"" d MA d Admd aftsum L TM afthamma .40
wd Dnmftn Rubuhll& EL -Kkww
a 00 NW101L PbONWA. 04 Qb"W. tIL - 48W40" Kydf4b. 00
"Oulm 'k A01"(ft rbpwwitift. rxm~q, MI. It Ill. 161 1114~
60 %Ot Asit (1~ VIRWIA1. 0. 1 .00
6OmAvwww4. M. I IU Lim.,ti.A of evri itwk.4,141 Milt". ar"I .00
414TM Oft IMU-J (nmi lbP IlWat 444ii;w of IN- nrw fhm" fl%ilnw~mtwn.
Thp lbrqwy men" silk I goo,
Vwuelml. hra."'Mmolf4by
"w0 Ill"Wom Ill . -) 1'%r 1we O..rY ia !N,;-/ .00
00
00,3
0OW
001
goo
so*
It m4TSk1.VftlE4L L11164 IIW11 CtOlOICA144
%1t 6167.
61491101
V11 fw a 0 a I a Im I a a
goo 0 0 0 0
"r4b 44
06 00*1000000
goo**
'Of a as a#
A' A' AW lat
memo of 61kylatematte hyAmuw" to
d P64swiftwo. itad the laws
l1bak matIlOoft. L~,srsf 0. M.'
it ~ I
:~i Mm took *#Ad.
a h 121*19411(lis Hadbak)z cf. C.A. 40.
41, S111711--lU &hYdIeer"HoN of P-41WO-P14-
(1). Ill, WF-4% dj* 0,111M, NOV 1.4001. av" Co-Ct at
4113' and Ambidat aftte o( 423 OW. 0"W 1/1.
=VV%(q pow
awl 1.2.3,4-tolm.
Z;itbak". The reaks from "Ovium-
=...amlrd with thew. ;0 crimets) (1) Obe rest cl
dm &W file Yield jwv greater, the kma" the see
7kX.-b%t a lenter chain Im A broken; it)
the tatiO of It Mha A&A the J4114 bwmw 6
arbra t1he It *ft me We m4w*~L* a v 0 1, by goo
it sms tic saboahowls- (3) for brummoom wkb em alkyl see
imbathunt costS. go 41; this 2 c - tin rate of dt-
bydrodirmatift Is like tow as that of I I "Itswk.
embofitmints: (4) for d6& IM*mrm of Am show-
ammikoied 'Irpe The Mfg of dtIrk,".o.. 4 it, oem
Bit,. an time Motive padtion of thitI embstiltmOits.
it. 8- Maman
too
661,11,10 'west C'Lutwoull" we
0000 111"llsive too
%olded "a. 0.0 off Aii-111 Voi on sit
-T--I" -
oil
0 lip 0 r!$ !11 !1 0 0 0 0 000*000*0
O
*
o LLM.M.

3

0
00 M
L, t
- t
led, A~
chtis At"'.Ww- - .
(loom. or".
148C 14 fill we" GlITT"4ttly POL"Od StIl a Cgl'bh*k
fttalirst. uwih4 Ow "me am.. -Wt*. frou"O" MM
tacibiall of AfwVwe A. wrt"ely. The k#wh go catqrst
lay- was I I rin. i diow. W MO. M aw, leap,, Mb I i
OrVVVk%l
A. Tbt N bm Vapon "t "L 0 11 "wk.) *jib
CCN- O"r a fmbly 1111" tea calstrM the M%Q of &.
*a* Mobw for (M.1%) tb" for, U
(41.0%)t but thr
uAll (PWtv"4 of
1. the waramtko
om" OW 2 4w
Am p".ejj%#j
wadwi of It nv
4
loved, ?A
mant.
1"W"CO CW
AW 1110 to
j"k Poo I
ale.
1k
.11. rT
wzii;-10 all 0 a 0
Is to a 'V it
(049 10 -
10
0 0 0 9 0 : S` 9
-0-0. 0
V V
* . . .
-A
In ft
tiond
low
W40
I ral" bo"
dftlVhtkn to ftfAr Votes ON APW*S.
th. a Attampt waa to Istarpm I"Al.
COMWratkV of The CTY"all stlectwe ad The
NA"Ins With Ow abspe "Widw of H. tho
a fav4vetetW lbllk* of Cu wkbr" IN.
I 11M for lbe JU "WdrostwAbe
a A. lordek
rat wk% t1to
a iii ~d
If 0 o 0 e a 000000000
~ 0 *go* o
see
ago
466
too
400
40040
too
to
A
:'6 '3
64W
U
v 0 woo a we 0 v
04
, 4-ft.- "I'a's *' M 1, -
'to 11 11 a
0111wilots Ole 080fist-41 wilt,
blisaim A. A. Saknilia stool
Ck. lot
In twirt)I-TIM" Po&tumt" am 91%" in lift elphilt-
li,,oo liter subaiifultel ov-pr"IAIWO
snel a-two.40" to ys4l
40. kW by way (it it 441,vot
V1.11 4.011441cet. Wit" tvLtw Oll"UhAIM14114T. OQf' ID
I" Owli InIvel" Am-% *WA br%%oves a A n"Itort"t
Went cowkp4. Iis =101 Ike &-vic"MAWMI 1#04 6% tween
ft Ind Into a boullild, Wins in ME Is
a WAY tb^t the " sIZZ t'bt " chain calm into Ihe
str0beving C-C bmd of the 11-mrosbmd ring. anel 43)
thh fol"Iss of MO at* C Micro pl*r Wto Slower IN"e,110 94
stop This Ivil Mv fvilft~l fi,*% the 114 "IV
tiowl %'100 A'aw"trivol fin##,% o"O 11'"41 11w oko'.411
firdfulwix"o, 11M. hom 2.2,1
sy1rur is 11-WIM-11. whrrftl hewn J'I disawthvi, Y. Idow sow
'outiq nor in qvia-ts, Ave. to all with lbral-W Iwal"1411'. in
I C*Ws. with lot I tAlw twins
hi MAJ.
iF
. A,
-7
Zoo
gee
1041110 0
goo
see
ve 0
gift 11111114v*
view
IX 4 1=6 014 of 4R 4146A74wi awq%* is,
it -6 , t I 1 -4-11- - I - --I" 111-11119-4-c-,
01 4 j I. v a In I a
00 0 0 : 0
0 000 010 0 0 0 4111 0 111 111 40 0 0 411 1111411141 0 111 0 0 0 0 0 0 0 0 0 0 $ 0 0 goo ieL~;
of mostoiiiii,
C.A. i.-TU It Walytic- jar
=Inb: W m4 1. 1h,
=1640"na evA mqab,. owd VA14 awme sal.vii
ek-Immism. =,prepbs. witoo
as- 1140 *Wb locos" V%bkf~m (vi amph.
3!t~tdf-;W~" air. ryclolerms"al) sibi
Fk~_IFM600T-711
T
dipf" 0 oftimlywo them lbr r awt.11mr.
Vb mul TIL The tutablk of ThA was *bum I A
hiss So" of -- on activity With VA ebmvd that
Cut%. -*Wb=
:1011111"1 ON I!= " a Malym Ow drby**-
Is" V=
eftolairsed Oft
We Obw I I Is
h theory Id. C.A, 4j.
k the estalreft IC-C - LU A..
C-0 !!!%VA., smil kv-H lJDI A.) opproahm"o obe
ask to" (V - I^ Cot 1.0. OW-Ta - 1.411A.~.
b 0" "ted to ftlesaiias and do.
I-.. W- M.-dinjoy.
Rx,m-W-A iff .k qnMb-b,g but gaint rotritlymS
M1611M. M. 0. Maw,
c4
0- 9,f* *-* * 0 * 4-S 4 A 4 0 , . . . - - - - -
1 16
, .- I it, 0 4
so

I
talenolin *not M M Polawookism low4, A W
A A.
00 Vail Xxxx" foim~ Abo". Aebb lots, CNI V, 0
so
so j'.A~ 41. 7^41. -In putumme W site 1wryift" Or.110,
Kernel, C.A. 41. MWI) that Pblrl and P-CAUls No 46
0o I of #INF amnif rare. end MAI. in the .1, lee

00 kird"IMOM vol tow laffer. The only mwhxl is jo-Voll.
141c
ell VIt
11
i
k
di
'00
00 s
e bit"Itte
%i3i%vI(.s. bevel I
dl
f
,
#
1
ft"Itpoativot wilb relety"t, 4 9
T
1#0
09 WOVIIY of - ft"ied Ow at as'. wmk I.IA-CAP
I-
.
t! MO-40
r
i
/I A
t l
t
W PbR
;~
il
; .60
00 .
in
i
c
ca
es I
s a
W-Wh
t
w
'I'loor "V v0swity Xte tho VIM of unsaid. Im"t %I%
1
i
v
M
%) rom
k M% aml .
n .
.only my hillf. let, rrep. f
00 falre. leov. 4(w). W. ni"I sit). the norlonsto 04 un"I'l 00
00 mromiNk. in I#* "Nookfami" (volt'd . Irv. #-'r 3. J, AM 1 00

90 1--uhle I-mmil Imeow jocacti0ally r4tial. W & gAh. An-'
f
t.. Cimseolmatly, flow elkyt ortalow bm vmvm . to
V1 2 0*
00 And till wital"t twoopews dtt &( IN
r .90
1o, and too (A )Wltwd in "vowleollml *hot. in fIN
%&"w
00 -W and Woolokofolitufftl %lowiva. all %of-oitoovol- atoodplov,ho .00
so,"IM 04MUH40"Oudy. too% Itir INISIG 14 tworove ife"If.
me can ermatneorq. loop to omit. Or rAmItIrart Inowlet I,
The &WAlLso Wwwoe LIN 5-C It hr and the orataiv,
;W ;Z;=*?
t
d it
i
4
urvis, &a
"
ve cmt
a
tv. TVA act
w
tnv4, hr. flat m %be towlsort. whk I CSISIVII einm 1%-mpv
i"I like ve"Iff of Ow floll. mail 3 P410014 wAyst m,'"I
'4140
ili$#kW%l 41114 OR the I OAW 14 tdCh Vt gnXIII, U Ith
;
"W" 1111411YOf 61000 WAeff"I 10 t#W KAIIS. W IJA too 1`14111-~ 1. 1
%be I-altortu wrl an vortattettral toystat facV. the wtupkt,
woodd iftiv"Ift It, slams, In a fritaw triangle d 4 atom%-
too
SkIfts fteb I r. a Seltet P66 one tmf More Ill 4 aumo,
N. I Nut
.300

'U a 0' it 1, a
41 a or -t a It a a 11 A, 'too
.,I
016 0:
t
a fee** a 90 0 e 0 0 0, 0 000 0 0
o 0000 0 so 6 of)* e 0 0 0 a

1 41 8 a 9 goal NQ
.

I* Or-
'k
kb "d
V
*v
m
M.
CRATSIkARM417119AWAAA4 "K(A w)RD
(Progroes In Chem.

y. vat 10411, P. u8 2N.
'Jul
M
dgeolopWal (%f eb"* 11100A06 AM dart
0
ftmM
hi
,
s O
Ago 1. otatm# of t
basis of We afta his own experl"Wo. the
then Is a Is d1v#rvW#
170M
t3
.
on.
Wiesen tM two typos of rou
1 1*00 0 It Sol
W.
.679
see
. . . . . . . .. . . . . . .
I L
a 0a 0 4 age
t. It L*r A a "I it A A. 01,
--i.vo-'.
coewrm &br4mftaO" of &at"$ now Ift himetodes. 190M) bdaS alt&hKd cma a IN CaWnt at WA SPOT
I Dole at 1-4106""AhW4 - d AM =LA/bf - TV; dirloyelm"IbDom. wkb
A. N. A. VILAYURAM. Deaf. JOU&I 1 rtk-a aboorst W It= on a Id cats" at .0110
O"Ol."m tooll-9-A., = G. . UtIN'll foet.-mot
KNom. (I. (Us. Climerim.) III, 308-W(IW).-Tb11m feet. &~) oebe be kwomord by time " rewim MINCH,
Om was lavrellpted we a retpremetstail" of a can -m 9cmilklexi-lo - 1114NII + Clio: ClIC11,031t.
00 1 as ,bee In C-.'4.C bnw Into >CooX- as o 1"oh W of
tj all am Its SaW. The seats reactlems Nil*. (1) OR a lot estalm Joe clery"Aite, oeshmes) 0 1 .00
climeMil - III + MINCHICIV ljj%~U-K' (14 na) 1.4 MW 0.3 sou/sel.- (w%kvb 9111ormoor motated).
, ,
0
0: 1 civ" a lortlatime; pom" " rete"W". mookboll
00 0, W lie "m 29A. V A. 413 48.11. W4. 30.1 Md - of I W.
big at Mo. art (R - Mr. R' - XtoNC1lI#M I Maim I& of Ot, 16 0. 143.12 k 14 t 18A
eoz~ fl- ' W raw auk a OWTO cafalra i;ich am: 1* 0
all It $'4 ' Otte vortivitics &W larg" auto of Mile. Foam
may pvt
C: NK + lisk ~~ 800
thermoset I ji
low./Od. (3) Vtltb polcootall"tootiot ybtl& wm on". I 1 000
R elk" I"Wilias em,"lot. Ibesalvation tow lask-rd-1
+ 141 IN Ow. Afl& 1011 of NO Law(.
at to a" 03 see
cat&" *0 d 30 to 10 M11oth. He (61
a" Oj L klandat-ohliydrow
Win
#1>C: Nil R T11 300 ad, 67
JaS activity rermalm" sacbmapol. (3) On a CIS catalyst.
"AAJU
we*
RICII:>Cf%k ~, IIX
of boortle 91CIA
at -.I=i
0 It 0
R A
J0940"".6mbpbrilit .
.6 PW40
:,"=,v 1, the Mm M_4_ -is i
Im bmmdmw Own of the lot a" ftd Had. and tk ftte.
C WOO= .7
V. slev *a wooddem U W. Is ibe pnWwu of
a miao do at 0 4k ON Was 6R an 1101111801111W
tbl nit 1W
mi
I 10~' &) M(" -
ow. (-Alto
am ;
all Vis IMM-flo-1, -all
un . 0 . .
a ed 6 a I I v
see
04 6-6 4 . . . . ..

M the
VSWV".
tNwl 1, tg. so

GY".. A..
Von
h
"
Owe Owe
4h, The saw
I
00
00

00 s hwolliam of tba 100-
w The oil w -.bp 1
2 *9
00
0
abi~w Tbm
Wilk emiL
00
*0
00 00
00 00
go 00
00 00

00 06

00

06:66041064009MOMMO
00000
0000.0
L~ 2 1 Omhl I
",klA-IDT:-$ A. A.
drol-onatt,4
'roll
Its" 411111114, taktodw Clkt-
OnspowtZIP:20
Airtw a
FirMlive, A A flaltirlm, ar"I N. 9 X"Aforra. hwo(
.1"d' Klim Nook 1%0. 1114-201.
if. CA, 43, ATNA4. In unervelAlysird mor-temp. PVTO!""
t4 Mt INI, ci.t I`bI Wt I its Ow temp. taftee oil W -?tl7*
AIIII 444 41.10 . If-4, I. in CIA- IU"RA- litt 111"'"Aly 4frP-
1-ho IN.. 1%4 oil # R , 0 he so R: is an Alk I loirtor re'loral.
C.1 1,. p I* belle-ve rd by 14; + I'M It I ~ 14C#l IA)I I - And AA -
vird I'l A olf "A. 1kin tit Ilor frArlsopitwot tylor.,
I I, I, " IntL-litfill, the l4fiff giving* m fullhef giv-
mnjen.. Itill nd 0 1. thy Ins% ~ Violets cil joholl. ficien
I m OMr not Me IFI. aft AL7 Awl (Id.2. . A 64"' Anti At
1.11 "Bib 1011wr tiint Imp. These
YU ~J. Call 1% Uj_IAjjJUIIV JnjVjOVTd cenly it Itif fl-WOMI
Wave 11111ps. in the jlfltlefht~ O(Ctt&IY%t%
No PhIIII 1kt4l3,Cm,iIIcA get
#if 11147 A-"At With Initiw. PhOW 4 11,1)
lhvvil
Ivisveds
Sid.% IVIWs, an-I 2r, As MV; tit Imith tows. 11,0 only
orwitAtro thr I*yt,Av-t-. but 41terenol
I
she Alm-tKV Of 1*01tKi'k tit byliftilyus JMCOII), In "W.
Ifj%t Ito gtA%% An.1 In ulwa SO. mlive sibmtes catalyst tbe~
ItyTIAT.S. v&-ormly. With IW&fe Wilimt HIM at a
,pact vri,ortly, -.;Irkl c A. catalyst/hr.. In 40-ruln. run-,
At 2P&J. 314. 4 tit. 4 4:1. Aoki 4.WJ 1. the yi*14S of Mill were
17.4). M.7. 751 imalkl. MA. and 53.V7e. t)ecwnpn.
Ijecias gelpiest 21.1, %,$.if Ibean in The unicawyet'll nwtkm.
Awl I% in&%, at 401% evie"A. veit"( tattly" tbffe u so
trac-tiany"at,443'. In DOEA%
is evtolred at 443'. Anti Only ") Mi. gas Is "Vlvvd ficame
it.64 S. loboMt at 493' (Cl I.. LO. &~W I It, so unmatel.).
The Mit uW.- O'but"011181foad
to nCitooll; cex%wq%mrntty. ibe IssatmerlsAtion tu"b=
Who h IA. 1 1, to. see Um ej.j*~j
.1.4
1,11: V,.I.or vWt
4.1 at 3101 .1 PSI( - pit I Alit At " twill
j!",. AIM. A Ill% 11,I) 11111).%j, . 111J 1. I-hf,lf
M' ; The. ewe, rfi.~ I ,1 11,41 1, ""1"1 1.1 ur""Prig
~ Need aroll. 41'. at-wil'i .4 1 hV414411b, IrAi
Ito" forivertet I'M M, Athl IfA) t1w activity tof the I si~
AVO CAtI1 IW 19111V IIV Ift.1110o"I 101111 Alt At &*It
I In. Yield .,I I'ht III it.." 1-hi'vi 0. ".) ;e~ , .1
.3131f;
h- Ittin W but of ~-Itjlh. mmi-
C'U. (k( V, it ml h. '10 41.,1% 1 tie .
I'MIll 4'st Ws. 1'l. -.1 I'Miff
ofv-t-f,AmAm1Im pt-- A 1144 N Ito.,
9 # 0 # * 4 # a 4 S 0 9 9 & w * to 0 # 4 -,0- a -0 2 -0 R 9 * & ~ I S 4 ~ 1 . . - , - I - . . .
0 WV-" -V 4P A 9 0 0 0
4r
c"000
oat 6o, stbor *6 6 A"If ibm d 0".
ratwe Or do "Mob m= 6" BAN tht fkW of PhOll in Wis *Ai lort; tbq ut.
IMMU...A. A. re was rte of C,11. and "multoctl Co. Cll., :totf It .4 41
n.01.8cam latbe feed It f)-aIrAlia) At.V1117'41-gare
44
viekli Ed JIMM of bysbrf vfwv vvl'w*tbm
wd N. W N&llavu". 1004, AW. N4111b S.SJA,
OAM. Kilool. N**bh Im, No, 1. It With 1111L)KI i- lk%119"1111 A U-01i 44111-4 Alut AP4*ft-"W* fT w
00 a tqps". t4 MOM* OW IWKI WOC0946 PdWAf#Y alkyl 4401 Owl 11101w; kbelw4 I 1 -00
smalmdon at PbOll. with Probablit kvinadmom of Im Tlwol -gsav-nwtw
shmjw
wawy tb* Sthm "dor" a 'Vimemowd blat 10% ICJ14 (the 111A il 0% sly" bovv); the educal
HOW= amtsine
karm the lot re"llaw load Wb farmatime al alkylilbamilt,
00 it wottr vapoltau"PA &her Owpoaft-tsaftbe to ~' but C4114. bad Sartiected MOM; so 11bUo vc 11611 was fmand. ago
Ifec"LaW4 the Iftcom ftle. V*pco ed MR wm G. U. k.A.P.8
VWV*4
*04 OVA bult4to 49J Nor m tog
00 IS rowl Wes em. in the edk*nt 16 , I wuim*, Wbik tht
othm prailmovu "to hakod by trwtb"Um. MUG
Vi" 14`4 M011 at 321' at -vdocky -212 is an
r t 1. - 40
I" the pm-gd
the abovo ' I . us I bit".
of6w)
45. 1 ti. SN *. 2MV7 7W'
The of * to i Porem 4ASS'
o A
w
Mull. vrit the pboll I the nomalm"
k4dW
lit Mt om diats. V Collu 1% PbOUt.
o"'
too
16 Lb"Ic Welk alwa (talvo 11" fm*o
XA
41 90
~vq ro Moo, *1 Ohl 116"li ima 0%w All,
u Is 1.0 Ac! rA a 1, 1
is 6, it t9 0 a 44 a a I a it of a IT 1:14 a 't w a 9 a T -1 1 v
VM/Chadstry Jan
Dehydrogenation
Chemistry --,Naphthalene, Deeahydro
"The Orientation of Decalin and Cyclohexane
Molecules on Oxide and Metallic Catelyzors Dur-
Ing DehydrogenatIon Acad A. A. Balandin,
0. V. laagulyeate, pp
"Dok A Hauk 880" Vol LXTT, No 2
ftp;r1mentally confims that cyclohexane must
dehydrogenate faster then decalin wben theIr
molecules are emoothIj oriented on catalyzerle
surface, vhleh mlgbt be expected an baste of
maltiplet theory. Submitted 2o Nov 48.
904
400
isd 6
Tbo
ww"m
rim!
I a s % s 84' I-it t-"- la a Lft, I ft' 1011- C-L- &-I W, a-&-1 oft
qvo~ $M-F,J1110
'b Im 0,11 10 Ali j j j j j j j j i t
0 0 0 0 0 *
* 0 0 0 0 O'o 0 0 0 0 0 0 0 0 0 0
n

P N a Is a 6 a
1 a a a r. a m 0
:
I 1, a a a - -0
a
4.0

-
"
1
ck
O
71 1 Z, .
modicum
1
of
V
~
~
x(vo.

so
IN r(NOJ
3
r
031kh us
em 16).
of tu ce

4m,

04 swowd of
aft Www to n*cti.A
Wftkb (1) of the "m
6#0
Mos of Iffid"tes that
wvw vwkuuu of f &W '00
so 116.4A. fm (61. aft
0" lot
W
00
a
7. J. T. lt=! I
1
woo
no*
14 off
too
IIa-1-1 1 a 60 6 a a I w i I -A4
I * : 0 * : 0 * 0 0 4 0 4 6 0
a * 0 0 0 0 0 0 * 0 0 0 0 0 0 0
p Is a a a Or
m'mtim ok looWoR
m 0 m Of
R-!TqW v W
, i !
_qj-- oil a* 1'* 0900 0
0-9 0
-.00
4,A), oil
*&has (I -A
con." mol Vo
4.6swA 61 or
also WA
we Alor"..
*0 A. A. ING 1.4100 it
jl~ i~. ! ~ '="~ A 0,01 A. he- to- vse#- wit A V '11'#
,' T., 46
Abal *10
'Neit -t- s'" 141
J1 M.,
0 fit Vtolif mts I'Y'Slarin to) 111, old, /Htw .9 0
Is ".I ~ 1 w411. j7 dill, 11"
to I 1 1,
notO $A CAI& tv
4& ad 6% irb 1 7";.1 witbomit 0-1
.8 saimm do= , j4qvW "not tjx' qvittly 0
NOjun J~ij 0 Is V)M
CIS 41, 3.14 4,
Wilk No
tu 0- &"' to '2 5 1 see
cre(OW"' by MI R14, 6talyst 14 1 17.1. 211A.
Ire*
joi N*011 IMM wt o.
V1 by N1#M 1*1 Kj
toy P.- . v 81 a VA- IWJO. Ila
v t"Wd *Ilk 11 6 bri. oil 43-~= 131 .10. IV 00 b
a too-41, ti..
it "to "I.e.
j410A JU1420 I low
;j I ~& & jumtkol J-.nW, I, the goooc"
a MA b. spW to, ""two OWSWO (in %W. is Wh ""Ouste of 1o, tm 411OW-1
13 "No lot Im"t do*
i"Weims oil jWjj Woristwom,
vu Oka W
W.6setwo So 8.0 &4 64
164A Ike 10 for a A" 3uW -
v to b.2 6 4.7A.9-4.1 10 - A ppkAj.14AtWM
A "' WeVas"ti.. W tolot as"O'
00
Jim tbo,~Ak ter*. ;,ifahO
a J.'" too ~ 6mWWW-'I ;;W? i0mallor 11111A too goo
00
Tkq~- Vby tiocataystodws' kjjgo*. -,4. Tb- I
few- '7d 'W by&ste 1W to to -toy," c"0.. Via. to see
of Was 41 adogebe oiartm, "Cous"Kq ,owls wat
%not
Ill Ws. ol was. 2t for at V,
Wk t=-
at IS), for catairvit.
at It Me "r
of j AM
I Cook ON I ,*
TOC
lbo ca 11of IW". wulk
to it S." -z
"gWo."s,
$6.6
r1fl, mi-T I I
a a fm 0 0 0 0 0 0 0 0 0
0 0
Ask
;4
*ft4
A
4so,
00
111619
=77 taI-'-W-~~:v7x7t-t 'W17 T,7t") ':(-t
4 IN I h A tim ) sit & S.W h votalm to oakwelft (al"is
VKh by ul.). at a &m 160 44 0.0m
dw Pat** of deb -
(1) (how". ;UW, Ill. of OVA of
= ut. wv*wvvI by "OF t. (97 ; Fare)
wift.. MA #I
tW d
=,by =Ath
VON" Ip in to min.. an at tm so
Afff~erbmaAma Now
f=~nM ON only (wb"
A"It,'klion "leffift) hut -brAmo n*Ki& In ow
bvwv W
he wall I tvtoly1h in. OW
MIllowl AM. 11OW Is no.
MS.
164"'1 witil ~; highmA on
The .= a X Cloth mtalv~d WMIA141 Now. ibe
mo-titi l1w kbph~'.! tin f4 U bWft do.
IL14j"ib"o 104 Ili) Mal. f2f fly the sow lowlF.

4' M ".- "A
.-

A I I

02

t. 0. #W. "I IAI- 1.1 'Ithl"If"
'
11
`l
.WWNl.llIIh. I OtTvIors
.1 U.
1. lh
4
I'll awma of t1w Catal
lbr if
44
st; two
m
r.
.
.
y
da"Imart vtrm *11IN iWITS"ne "o. -1 raw"
-
i
rl
b
f tk
C
i
l b
W
4
mmi
rma
am
g
. o
w a
ox
otaws oil
yt
y 0
p
Thk Wo to an esid. role
A
C
M
OW)
,-
"
.
.
.
,
..a IMI OW 1. *Md LAWN ftWK4WAiM f"RAID4 VAM
I a =
ke a amb"amemew colalys, aw-W. 11 C%n
bwwd in dek
to
tifte"Wom "
an a Ni mtAi
l
.
r
y
P
the f0mrstrofamwailcm crolit. m.
1 h
k
1
it
goo
4-
it* Arr%miu% lk"r-
w
e
ail' lj A Lvol nutIrl
Intl
OW
(4cjjv*jhvj twig
ow w

.
W
y
Itto th4t 44 e *
U. 000

1:6 -if
OWN l"Ill"
so" .0 1 Nbomo 086 Wv go ail 4wi
0 AV ID v I Or
0090099*0
10 0 low
41 000o00 00 0 *-o : : 0 0 0 0
wee
wee
off
Noll
M
SAIANDIN A&-.L-p L-a-Kh-t-FreydUn-and-S-4A. IA-haniva
j__ _a
Interaction of Acid AnWrldes with Formates. 11. Effect of the Mature of the
AnWride,, page 350
Sbomik statey pa obahchey khiaii (Collection of Papers on General Chwd~tr7,%
Vol I, Moscow-Leningrad 1953, pages 762-766
Inst of Organic Chwdetr7, Acad, Soi USSR
. ~, I". . I
I ~- , , , - k , , ,
FUTDLIN.LM~MWNX~X.G.; BALANDIN. A.A., akademik.
Investigati6n of the nature of activity of a skeleton Iran catalyst. Dokl.
AN MR 91 no.5t1171-1174 Ag 133. (XLU 6:8)
1. Akademiy& nauk MR (for Balandin). 2. Institut organichaskey khimil
Akademii wmk MR (for Preydlin and Radnem). (catalysts)
~DUS, A.A., akademik.
Roduction of the metal-hydrogen composition of the active surface of a skele-
ton nickel catalyst. DokLAN SSSR 91 no.6:1349-1352 Ag 153. (HLBA 6%8)
1. Akademiya nauk SSSR (for Balandin). 2. Institut organicheekoy khtcli
Akademii ninik WSR (for TreydI in, Ridnwm).
(Reduction, Gliemical) (Catalysts)
!W~p A. -- --- - -- ---- -- - - -- --
"The ft*e lboorgy of Adsorptim on Dobjdrogenation for a bettroSeneous surface.'
Doki. - Aked. Nauk WO, 93,, " -58p M.
7M adsorption of abbstanoon on a botorogemom dehydrogenation catalpt is
alsouseed wA eqvatloms an SlTen for the fr" worgy of adeorptlon on avob a surfaco.
BAIMM. - -A. A,
"Ibe Nature of activity centers of Dehydrogenation catal:sts." Dokl. Aka4.
Wauk SM, 93, 475-8, 1953 (of. ibid. 273)
A tentative pbys. explanation is offered for the 2 lave of dehydrogenation catalysis,
namelyt (1) that the changes of environment of the active center of quasi-Vniform
centers act alike on the attraction of vario a mole., as a result of vh1oh their
adsorption coeffs. remain unchanged,- and (2) that the catalytic overvoltage (11)
is proportional to the adsorption overvoltage (A') vith a neg. sign, or 31 = W
ISAGULTAIM, G.V.; GOLOVIKA. 0.A.; BALLRDIN, A.A., akademik.
%."- 0
Synthesis of acetaldehyde and ethyl alcohol tagged with radiocarbon 014
Dokl.AN SSSR 93 no.4:659-661 D 153. (KLRA 6:1b
1. Akademlya nauk SSSR (for Balandin).
(Acetaldebyde) (Iltbyl alcohol) (Carbon--Isotopes)
_U&qR/ChemIstry --Fuels
Card 1/1 Pub. 129-8/23
Author : Slovokhotova~ T. A.1 Bovaloval L. I.; Kazarskiy, B. A.; Balandin, A. A.
FAWO"Waff"M
Title : Catalytic conversion of isomeric, octanes with water over a uIckel and
kieselguhr catalyst
Periodical : Vest. Mosk. un., Ser. fizikomat. i Yost. Dauko 9, No TO 65-72P Oct 1954
Abstract : Saturated hydrocarbons rout with water over a nickel and kieselguhr
catalyst forming products of gradual demethylation of the original
hydrocarbon. The degree of conversion depends on the structure of the
hydrocarbon. 2., 2,, 4-Trimethylpentane reacts slower than the 2, 2P 3
isomer. Eight curves. Ten references (five USSR).
Institution : Chair of Organic Chemistry
Submitted : February 1,, 1954
jj. "I. -, i -,-
At A.
"Cataly-tie Hydrorenationt 1, Kinetic Equation of HydroF-enation and Leloydrorenation
over Hickel Catalyst; 11, Catalytic Hydroirenation over Nickel and Platinum. Hy-
dropenation by Deuterium; 1110 Further revelopment of the Theory. Hydrorination over
Copper and Pallaftim; TV, Yodification of the Hydroren ~'urface. Selective Hyclro-
renation of MJ;xtures," A.A. nalanding Acad !7cl; Mf!R, Voscow
"J Oen Chem QT1,1',SR)ff Vol. 15, 1951it PP 6M-169 619-271 770-PO, 7PI-,X)
A new theory of catalytic activity is pronosed, accordinr to which hydroFenatiou requires
different areas of Ni. catalyst for activation of the bydrorenatinr substance and for
activation of H. The absorption on the active points of either type occurs according
to the LanMuir Isotherm. The kin6tic equations deduced from these considerations
explain the quantitative relations observed In hydrorenation of toluene over a N1
catalyst on the Al ?()3 carrier, This theorty is arlied In the explanation of vArlation
of tenperature effect with pressurf-, and the chanre of rraction order In catalyrt
Poisoninr by (10; the oHer of reaction An the 11(juld nhase differs from that in the
raseous phase. Hydrorenation by D Is dierssed. The annlication of the new concept
denends purely on the cheirical rrocess involved and on adsorotions diffusion effects
have no ir-por-tince. Vathematical rvlations arv Oeveloped for the equilibria betwoen
the raneoun and adsorbed forms for the material to be hydroF,-enated.
SO: 7-3361 31 Yarch 19118
Us s
7`4
USO/Chemistry
cam 1 1/1
Authwis I Balandin, A. A., Academician
title t Multiple theory and -principle of minute equilibrium. The machaniwe of
hydro- and dehydrogenation
Ppriodical Dokl. AN SM11, 97, Ed. 3., 049 - 452, July 21, 1954
Ostmet i The multiple theory and principle of minute equilibritra, w'Ach in hundreds
of cases Indicate the sequence of reactions of complex molecules and make
it Dosqlble to deternine the energy of bonfis 1-etween the roolecules and the
catalyst, are explained. The results, derived from the a-plication of the
hanic nr4rc~vip If Vic multiple theory - cju,-4rinposition c~r molrc,iles on
the lattice iurface of the catalyst, are Joscribed. The rnachanll,,%-n .-f hy-
dro- arid den ~;,-vpritepn -fer,~neoi: 1 '~-UFat
.N,Tiro~77-7nation is Plucidatf-d,
and 2-USA. 'Graph, drawings.
Institution i Acad. of Sc. U,,ZR, the N. D. Zelin3kiv In9t. of Org. Chem. and the M. 7.
Lo-nonosoy State University, Moscow
Submtted May 22, 1954
USSR/Chemistry - Catalysts
Card 1/1 1 Pub. 22 - 25/46
Autbors I Wandint A. A., Academician
TItle I Catalytic layers and their effect on the activation energy
Periodical i Dok. AN SSSR 97/4, 667-670p Aug 1, 1954
Abstract I Tha effect of catalytic layers (five basic layers In Intermediate
state), on the activation energy of a heterogeneous catalysin, in
elucidated. The affect of catalyst atoms, which are not included
in the active center of layer I, on the atoms of layer 11 is
identical to the effect of surface micro-roughness or nature of
sometimes separated atoms (carriers and admixtures)q. Muntions
are presented which in4icate the elements constituting tha acti-
vation ener f nded catalysis react-tons, Fifteen USSR
gt~sax enyj
references (1930-1954). Drawing.
Institution Acad. of Sc. 033R, The N. D. Zelinskly Inst. of Org. Chem. and
the M. V. Lomonosov State Universityp 24o9cow
Submitted Juhe 1, 1954
Card 1/1 Pub. 22 - 23A7
Auth,)rs i rialandin, A. A.~ Academician, and Klabunovskiy, E. 1.
Title I Kinetics of butanol-2 deh)drogenation over nickel
Perio4ical : Dok. AN SSSR 98/5, 783-786, oot ii, 1954
Abstract t The kinetics of butanol-2 dellkydrojFenation over nickel was inve3tigated in a
vaporous phase of a flowing system. The rate constants were determined from
the general kinetic equation of the catalytic mono-molecular r9actions occur-
rinj in the flow. Equationo determining the relative adsorption coefficient,
change In free energy and entropy during the adsorption on catalytically ac-
tive centers are included. The heats of adsorption displacement were found
to be ver- hyd g nation
y hialh and exceed the activation enerry. The actual ro e A
-ennnted in a table. Eleven reforenceei
-2 is pi
activation nergy for butanol
A-USSR -, I -Eng 1i sh; I-Fronch and I-tlnlgian ( l)25 Tables; graphs.
Ir-ititution Acad. of Sc. U33H, The N. D. Zel-inskiy Institute of Organic Chemistry
Submitted July 29., 1954
L1101597 TREASURE ISLAND BOOK REVIEW AID 817- 3
BALANDIN.-A 'A. (Institute of Organic Chemistry, Academy of Sciences,
U33kf.__'DISKUSSIYA (Discussion). In Problemy kinetiki I kataliza
(Problems of Kinetics and Catalysi-sT, vo. 8. Izdatellstvo
Akademii Nauk SSSR, 1955. Section II: General Problems of the
theory of catalysis. P. 155-156.
Discussion of the classification of catalytic reactions given by
S. Z. Roginskiy namely: 1) oxidation-- reduction reactions and
2) proton reactions. The author considers this classification
incomplete, since surface reactions may be of ionic or atomic
nature. He proposes the following classification:
1. Non-ionic (atomic) reactions
II. Ionic reactions
1. oxidation - reduction reactions
2. acid-base(proton) reactions
To non-Ionic reactions belong: catalytic dehydrogenation and
hydrogenation of hydrocarbons on metals and on some oxides;
dehydrogenation of alcohols and amines; hydrogenation of alcohols,
ketones, aldimines and ketimines; nitriles, etc. To ionic reactions
belong: catalytic oxidation (With 02) of hydrogen sulfide, ammonia,
hydrocarbons. To acid-base (proton) reactions belong: hydrolysiso
1/2
BAiANDIN, A. A., Diskussiya AID 817 - 3
. hydration and dehydration with acidB,, iaomerization, cracking, and
numerous condensation and polymerization reactions. Although there
are specific catalysts for each type of reactiono some of the
catalysts may be used In several reactions.
2/2
HATA INA,V.A. (translator]; BOGDAYOVA,O.K.Ctranalater]; VASSERA V.I. ,
[translator]; KIPUKAN.S.L.,(trauslaterl; SALUMIN,A.A., &Womik,
rodaktor; RUB1NSffUW,A.M*, professor, reduVWPTR7WVA,M.V.,
rodaktor; OGANDZHANOVA,N.A., redaktor; IOVLZVA,N.A., takhnichookiy
redaktor
[Catalysis, catalyst* for,organic reactions; translated from the
ftlishl latalis, katalizatory organicheBkikh reaktoli. Perewod
s anglilskogo Balandinoi i dr. Moskva, Isd-vo inostrannoi lit-ry,
1955. 336 p. (KLRA 9:2)
(Catalysts)
AM1597 TREASURE ISIAND BOOK RETEW AID 834 - S
OBALODINP A. A- (InStitUte of Organie Cbemistryt ACeleny of 5clenceal USSR)
bl=S= (Discussion Ig Problevq kinotikl. I kataliza, (Problems of
Kinetics and Catalyais~y vol. 8. Zzdatel'stvi,Akademii Nauk SSSR, 1955.
Sectiot IV. Nature of the active surface. p~ 233-234.
With referenoe to the paper by 0, M. Zhabrove. Balandin points out that
on many catalysts both dehydration and deby&ogenation belong to non-ionic
reactions, i.e., they occur without formatica of free ions. The dehydration
of alcohols may be conducted &a an Ionic re-totion under the action of acids
(6.g., addition. of phosphoric acid to acti-rated carbon.) In experiments
with isopropyl alcohol, Balandin found that on addition of chloroform to
aleshol (25% chloroform+ 75% isopropyl aj;ohol) at temperatures exceeding
300 G (in the presence of chromic oxide); the dehydration of alcohol is
markedly increased. HOI shows a still gveater effect. One reference
(Russian) (1954)
I T-7 I r 7r 7
ZST,!NSKff. Nikolay D-vitriyevich, 1861-1953 (deceased] XAZARSKIT, B.A..
Wcadealk; B&MIN. A.A akadenik: KOCHXSMY, K.A.; SHUMN'. N.1.;
KAYMNITA, Te.119 lat twitcheskikh nauk; LXVIX&. R.Ta.. doktor
khtmicbeekikh nauk.- PLATI, A.F., doktorkhtmicheskikh nauk;
RMINSHTWN, A.M., doktor khtnichaskikh nank; YURITXT, Yu.K., doktor
khtnichaskikh nank; IISKJVA, A.A., tekhalcheskly rodaktor.
[Collected works) Sobrante trudov, Moskva. Isd-vo Akadmil nauk SSSR.
Vol. 2. 1955. 74) p. (KLRA 8:11)
1. Chlen4mrreqmndent AN SSSR(for Kocheshkov and Shvqktn)
(ftdroearbous) (Ntrolem)
The -notbinim and alze,ic, at &-ttle tsa V%t

vri's Awarl"Wa al 60 AZU1,P su!'.
Y,r-
4 A, .k
lot

h-t, ~,,l Th, ....... A-1

rm p4l, 'm
."d o tv ds~j 'n., ~' -j.
be 441.cI*J T t,
-_ 4 refers to Th.
Z 1. 1h.t P."" 11-1 rxistrlu~ 4 -W!"" ."I 1h,
-difi,_, 1. h" fl- -.1r,14" IN---
~i-ULW ~q..l A 1, -, !,,, 4 -11., - k
f'40 rerrvilrrsy Ti ji~ i7i tht

Ttl~,
of

BALANDIN. A.A.
...... ~, ,
Prose*% state of catalysis and theoretical priwiples of catalyst
research. Isv.AN SSSR. Otd.khim.nauk se.4t624-638 JI-Ag 155.
(KLRA 9: 1)
I.Institut srganichoskoy khtail imeal B.D.Zolonskoge Akadeuil nauk
SSSR. (catalysis)
. . .. ---- .: . II - : . - -- - - I
F; ", , ~ :,; ~7- ~ -- --, ~ I 1~; . --. T--
- I . . I , : ~ ". ~: I ~ .... 1, ~ " ~* , I ~ ". ~ ,, .~ f, ~ ; i. ; .1-1 . '17
. - - -- - . Vi,
VWGbomistry - Catalitic chOmiOtr7
Card JA Pub. 124 - 3/32
Authm 1 Balanding A. A.0 Academician
Title 1 Pmblems and perspectives in the develoMent of oatklytic ebwdstry
hriodicalIVest. AN SSSR 25/6, 19-23, June 1955
Abstraot ITho advantages mid great importance of cataysia and cata-I.Yets in
inoderr, -rgFr,c &nd 'Y\orgFm~:
6~ g the
role VhIch -Ptlky-tto Chemistry VIII lav- 'r '~n re 'iling
-n na-
t,qs,,c nrxlor
'r,,rc water, &.1r, "-"rc~-gaaps le ex-
""ecti r &11(~
cesses are ana_!,yzed.
IX3titUti(M 3
Subaittadi
At- t
Ifli
.. ........ ..
41pil." '1' 4 1.0 1 Pd
120. -th-'f -d th.
-1 4, vl~l 1" 11, A, . %- 4~4' 1,. -1.1,411
-V Nil, /1' /1, H If,, 1, 1 i'l-
I'd A 4 IS' Nil,.
.1.ll , ga" pm'-I-t 'n'I -.rll tA.,
P,i ..1 140
:15 01~i, 11 llnA I N' I I , All?' th,
Y W I I .;. , 4 4.V it!) It, S IA 1, 3s t'V
11 "h 18.21~' Nil, tk'6UIICi: I'( Mitl 0 [lilt
It, cltalyni;' abo gavc i4'rnf pl~fni ip, I-.r 11,14 't the
I ,I lriam"I'lf lf , . f,:, . 11, --!- - ,
kehmmes ('f C 4 21) P%r'. Ni i, -I 'j-6
cawylic t1=0c"s, Ifims af cyrit'helane h dro"' Ltwns on
Tr--r-
fshimimsilkste t4itilyst A
nZ~W~-~ .. I thul-kau-
110 kfxr7)T,.T)
"lumpl-41watv o
)kIIIA .11 lift"lucts (r"111 IIAAj&;bt-j r,
~.~M 14 1IR11i'l g--"
T"', 11h"
VOW A cAr, pst4,m hytif"Cart-n" 1"Juttl
viiiatiR.n t:,t,l c.li.. NiOil, ~,N ......
highcr arvmtk-9): cyclArvine R2, 17l, 29, 13, 4. 4 1,
12.3. 1 4 2.7, 2.5, 8 "irthyteyelohminc 60 r~. '.Irk 3,
24.9. V2. 7.6, 15.5, SI, 24. 6~).
64 0, 1", 2 4, 21 0, 9 ii, 7 1. 16 1, . . 1.4 2, 2
.N~thylrycl.hrzariv 64 N. 3 11. 1 6. '-N 1 ~ 11 1. 4 2, P,
-, 2. 11, 3.0- 74 1 3,F) 1.1.
19.3, 9 5. - I i 4. hvi-s " I ~ 1. !, 1-1 1 A.11
trimrthvic ycl,,himim :04 1. OPI, 4 A, 3A I ', ~ % 'I I I
. 1.1, 4, 5.4, q, % 1, - I. h. -- t~; 1 2711. 4 1 Li 11,
16.3. 14 3 J 13 1 ~,~ I-p, J
c.,nuwt. the prater Ih, prol-Iti'm 'd g-s--
tmr1IrIIl:~,;N, C )I,, th, 0."., .4 t ,f "j-, W-1 I
~vl~ity o 2,.4 1,/I-/hT Fl-atwn ,f t-np Ir, m t~W t,
,%8* raiws tive total tn.vtr*mn, tht vivid .,I g,,ws. a-I
amt of MePh formM The apparent "As, 11"n tn"j)
was faund frotn ga, rvoluti,m lo 1. V '00 -,4,
mpthvlc)t-lo4it-xnnr I- I., ~~ . .
;I M )~.~,+pcl
lj~ \, i
.4
1
MYDLIN, L.Xhl UU"11, A.A., akademik; XAZAROVA' N.M.; TBGMT, Tu.P,
Alkylatisn of propane and At-pentans with propylons at high temperatures,
under high pressures, wA In pressnoo of aluximim oxide, Dokl. AN 888R
105 no*6tlZ~0-1273 D 155. (NLRA 9t4)
1.1natitut organicheskey khivii imeni NoD.Zelinakegs Akademli nauk SSSR.
(Alkylation) (Hydrocarbons)
COTTRELL, T.L.; DTATXW, X-Tes [translator]; RLIA'11- We akade-mik-,-
redaktor: OGANDZHAMOVA. N.A.. rsdaktor: TALOTO V.I., takhnichs-
skiy redaktor
[The strength of chemleal.boods. Translated from the Anglish)
Prochnost' khtalohookikh sviasslo Pereyod s anglilskogo M.N.
Diatkinol. Pod red. A.A.Balandina. Moskva, lad-yo inostratmot
lit-ry, 1956. 281 V. (KIRA 9:8)
(Chemistry, ftsical and theoretical)
(Valence (Theoretical chemistry)
NLM-DIN, A ~,
USSR/ Chmistry - Orpnic cherAstry
card 1/1 Pub. 40 - 23/25
Authors 3 Freydlin, L. Kb.; Balandin, A. A.; and Borunova, V. V.
Title $ Effectivenoss of catilystq preparod Pror nickelous oxide tretted in water
vapors under pressure
PbriOdical I Izv. AN SSSR. Otd. kh1m. nauk 1, 128-130, Jan 1956
Abntract i It was establitshad experizent,:-Ily that by employing different aging conditions
for NIO on the carrier by treating with water YaDors it beccces possiblo to
control the nctivity or nickel raLAlysta. It wan found tnat nickel catalysts
I r6at fw r t j(-'- st mrv)er ',c -,%t, '~N, 1. 1,Y nyl -nj7vr,.Rt lrijw ILI'le &r(XM LIC twnc
Y"
Institution 3 Acad. of Se., U&9R, Inst. of Organ. Chem. in, N. D. Zolinakly
Submitted i Ju1Y 20, 1955
USSR/Kinetics Combustion. Explosions. Topochemistry. Catalysis. B-9
Abe Jour : Referat Zhur - Khimiya, No 6, 1957, 18625
Author : L.Kh. Freydlin,. ~.A. ~N.V. Borunova, A.Ye.
Abronomov.
Inst : Academy of Sciences of USSR.
Title ; Mechanism of Deactivation of Nickel Catalysts by Steam
Under Pressure.
OrIB Pub : Izv. AN SM, Otd. khim. n., 1956, No 8, 913-922
Abstract : Unreduced catalysts of the composition 35% of NiO and 65%
of A1203' as vell as Ni-catalysts prepared from them
after reduction vere treated at 3500 vith amixture of H2
(700 atm) and steam (100 atm) 5 hours in a special high
pressure reactor. It was found that their activity in
the reaction C6H6 -+-3H2 and In the reverse reaction de-
creased strongly after tha treatment, especially if the
samples had been treated thus before the reduction. In
this case, the magnitude of the specific surface of
Card 1/2
2- e- I I rJ 6 ki I I'v5j. 258 OVIC Chet-,4, 'q fV OSS/;C.
(9-V I '?
USSR/Kinetics - Combustion. Explosions. Topochemistry. Catalysis. B-9
Abs Jour Referat Zhur - Kbimiya, No 6, 1957, 18625
samples decreaces (from 170 and 80 to 10 and 30 sl-m/g
respectively)# vhicb the authors explain by recrystal-
lization of nickel lower oxide, as well as of the carrier.
The authors think that the bibliographically recorded
deactivation of reduced Ni-catalysts (mid, as it seems,
also of Fe-catalysts) by steam during the process of
work is explained by the appearance of a surface film or
a phase of NiO, vhJch recrystallizes rapidly and the re-
duction process of which is hampered and results in the
formation of little dispersed Ni.
Card 2/2 259 -
RAIANDIW~ A.A,; TOLSTOPUTOVA, A.A.
linstic determination of bond energies as an approach to the
theory of the selection of catalysts. Part 2 Co"rison of re-
sults with chromia [with Znglish summary In insert]. Shur.'fis.
khin. 30 no.7tl636-1646 J1 156. NLRA 9t11)
1. kkademiya nauk WMj Institut organichookoy Wall imeni N.D.
Zolinskogo, Mookovskly gosudaretyennyy universitst, iment K.T.
Lononosova, Kooky&.
(Chromium oxides) (Catalysts)