SCIENTIFIC ABSTRACT BENDERAKIY, V. A. - BENDILO, G. G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000200010004-4
• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 13, 2001
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

Regularities uad Ulculauiv, Uthodo . float.) SrN/4043
3. Appltcation of the third method of calculating other jAwsicochemical
properties (density, boiling point) 56
C4. IV. Comparinon of the Three Methods of Calculation 62
1. Ccopering the accuracy of the three methods 62
2. Initial data on the propertlea of a3kanes necessary for calcu-
lating the properties of high Llkanes for each of the three
method,s of calculation and the overall series of Alkanes vhose
properties it is poasible to calculate 66
3. Conclusion 68
Tables 13-25 69
Bibliography
XIA11APLE: Library of Congress
JA/rem/m
Card 5/5 8-22-60

A I IT) 10HA I ''t I(lo

T f T r,, F, i c,I I
C wO, r(' 1. ("l,".
PKRIODICALi

ABSTRAM
Th"

Ilo Op t, v,

E-term Ltiat on C,!. R.-t- 2"!
lho I

Ca r c: 1/1 (' )

Concernim-, Analv.,31.,i of a Kly,-,,t-,rc),,i
ALItomatic Frequt~ncy Control C.1-rcutt
Dlf-~ VIYOGI'01111 fl-f-Cluency Install.!1.11-1.1i -,-er
,where S Ic Is tile Slope Of tile freq,11-~"v!Y '.'~3 reflector
-01tRg A f t e. r m to t; i nAl ni~, 1. 1 .
e r"'Irve. at-, th~,
3011,1 t0l' WAP~ It ;I ral)le .; 0 1, t,-j j-, -t t,l
proport.-Ion,".1. t1c) tll~-, :11"d
to "'It-ji. At'll-er d(Aoc-
Card 2/16 tIon thlo voltaj-,(2 -1,,, a-ppllo-~(l rof](!ctor:

conc zl~-, A!""i J,-"- 1-1
,,-;herr! k
l, k k k -1 ri !-I JIM 13 1 0 k-~ C (-'I t 2 0 f
i I
the and RC-11litpr

p e q-t t 1., o
I
S "11);; t-, I 1! 1 f, I ,
and
re r 6 f , t I 10 kL:; I. C P(I I 1 -11, 1J. I ()I' I P I] I Of 1! 1-, 01!, at I c
,,0, ron derived :i,-,:

I krYif
The stabilization
k -
For ext-Itnt'lorl of
rn I I n a 111111tLpl- oll
~!l it, -0 I-lp "A
-trd C)
I
I 1 1) 1 f f,
A-~ !7,111-ft 19

Concerning ATITII:iDis of' a Kl:;:-,trc)n
Akitornatic Frequency Control Cii,cuill
Q O'.T
(m 11'.) e (I I)y t I le Rc - f I I h,: calmed 't):,-
4A,
th- con(IVj,-,n "I
or 211
The trarimiziolon ooef*Vlolont Vni, .~L filter
p
T
wherj T I a nd r,~- Ira-
L 'L
dIfferont'I'll it, o
I Tj

ol~
Automatic c,f Conl,rol
dtAl-ermirmtlon of" t '.c!il Vrt of excitat~iol, is
I ~ ta I I I e d I
Wr IK (9)
c it T, y a 11, ,
wl.~!re CL T 2il-rl > SD ~- "'r "~a 1~d 13 t1le c'Alc)PL~ of
dl 3criviinator cm,ve. The crit-I.I.cai oha:3--~ shift without
i'l L te r I a
MT I
(6 1" k A
Af-er some slviolifI(,atl-oni and subst,itut Ions the critical
de.!ay time is found:
Card 5/16

Concerning Anqlynlu of a Klyntron
Automatic Frequer.cy Control Cirn,AIA, c
021)
A comp-arlson nf' tho
-ell t,ol,:
c I'l t t ',1 1,1%
ONE - STAAC TWO- STAr C
fiLttFt
C'It
T
From (13) It aPr,ea,,.-; that Ua~;T,c propc-i-ty-
suppression oC combln,~,d hl-in7,.orlc~', cclsed 1~1-1,
C,a rd o f a no de c u r re I I t 1! -1 "t ", rt 1: f. o:-n .1 1'~ "I ont"ol

Vr
'.Tl D I

A: a 1~ j,
f ont Lro,n
a A-P
0
The
"Y"l-Oln fWay he
dl:
co nt
0 Af, r,,
0 f L I I(-,
a I i
Driz; Ila lilt, ip

. I..; , ic f ~ . ". :, , . , ''. ,i,, i, ,; , ,
, ~ ~ , 1~ I , 1-1 , . .
i . i , 1 :~ ; .. ~, ., , , I , , .

Al (11
j r Olo.
(it +

c( -I i I n f:,- A!! -I Iy
A It, c"n I LIC Fr':q I;:
17, Ar
A~ A~
wile r(?
i t

Con,-, ---rnl nir Analysl.o of' mylit,ror,
Atttom,atlc Freqw-ncy Control Cir,(-ol.t
Y
From .(23) tilt-,
d!wlng t,.,htch tlit!
Sch(:,Itlltj.(" of C~?Iculatlcm-- &nd III~, Experl;%~~n*,,il Veri-
f Ic at ion. The follo,ainc,' seq-,~eicf- oil raI-.daIIors is
LIL I I ird T
),k~,OAC-dl (1) Prom (11.) -Wd U5) T
c I'l
functions of stabilizati.oll r"
actol ,
t-1 Ic CO 4.14A
(2) the slopf- of 'I,,o
Ca rd 12 of'

Concernino Analy.31u of a Klvjtro~-,
Automatic Frequrl-i-ic,
y Conti
f rom SD =10s 1c, (3) K S' thQ :30Ui~ht-fOr
coefficient of the a, ~4) For a
better otability re.~ierve, a t- 1)and or thdi
a)~Iipllfler iu In acc
-2
The table below gives parameter3' of an automatic fre-
que icy control oystem .~jith initial parameters lo3
Q = 5
R = 1 mv/ 4 w ; P = 5 SJ~ ~ 1.5 mc/v; and
asymmetry parameter CL equals 2.5. Pov verification of
the proposed method a oystem ivia5 built as shoan on
Fig. 1. The system ts desije-ied for a 13tabiliZation
coefficient of 200, mod~Aatl,)n frequency is 1100 Ice, and
A three-stage
amplifler transmission band 1~: 15 ke.
ampli.fier with type 6 Y,~ p-,n*.c)d-' --o -,%as uscd. The
stabilization factor 1:3 181~. Th- 11~31P of V. G. Veselago
Card 13/16 and A. G. Semenov is acknoviledged. There 'is I table;

Concernin-Q Analysis of a Kly.Aron
Automatic Frequency Control Circuit -5 -19126
Table 1. Parameters of automatic fre(',Uenc,,,' control
9tem.
sy,
t 11, Ic Ik)*, sec .49, vlme A,, ILI 4 All, kc
.33 3
3 4.8
1N) 2,0 6 1:5 2,1 67 #3 7 9,6
:
, 50 2,0 6 t. ~) 1,4 too
' 10,0 t4,3
l
2m 2, 7 8 2, 0 1,4 1.1
, 13A I t,.
2W 4,() 12 3,0 ij 167 161-1 11.8
Card 14/16

Concerning Analysi,3 of ~j
Automatic Frequency Control t -C, i I
T, T, T.
r
71-
/M To kL'YSTOO-4
D PfFLECrOR
qt
IMPVT
F to m r Fri' PA
- 6E--,
Cai-d 1-5/16

concrl-rrljrl~; AtIrIly."'is of "1 11,1-
Autum,,O,tc
SUBMITTEDt
Caption to FJ.g.
of a jrj,,,r,,jt,j-Orjj
N I 11) p 0 r t - v 0 11,,, 1
1. L:,tyout, of
(T,
tit -I~iki
a;III)l IXI-v; (T,')
T Ft rnp L t f I
9) reoonarwe
control
7'
I f1gul'u; and 3 Solliet
JuLy 8, 1959
Card 16/16

BLYUKHMID, L.A. -, HIMU!% IY, T.A.
Magnetic snd dielectric properties of highly-orgmtized
macromoleoular structures. Dokl-AN SSSR 133 no.6:
1451-1434 Ag '6o. OURA 13 S 8)
1. Inistitut khtnichaskoy fisiki kkadenii asuk SSSR&
Predstavlano akad. 11,1.8amenovym.
(Polymers-AWnstio properties)
(Polymers--Slectric properties)

BLYUYl6NFr,Llb, L.A.; BLUDEHSKIY, V.A.; KAUWZON, A.E.
PossibElity of various interpretations of anwaloun magnetic
propertios of macromolecular compounds. Bioftzika 6 no 6:631-
637 161. ~MIIU 15:1)
1. Inst tut khimicheskoZ fiziki AN SSSli,,,Moakva.
tl4ACR(WLECUlAh CONFOUNDS-MAGNE C FROPERTE:;S)

BENDEMKIY, V.A.; NIKITRI, N.S. (deceased); TATEVESKIY, V.M.
Regularities in the physiocochemical properties of alkylcyclohexanes.
Zhur. fiz. khIm. 36 no.1:63-71 Ja '62. (WRA 16:8)
1. Moskovskiy gonudarstvennyy universitet Im. M.V. LomoncLlova.
(Cyclohexane)

S/020/62,'144/004/017/024
B100138
AUTHOR": Benderskiy, V. A., arid 131yumenfe-11d, L. A.
Ti~i'7: States invoIvin(,, charge transfer in organic systems
S I 7~
Akade.,,riiya nalik SS.;R. Doklady, v. '44, r.,,. 4, 1962,
T77'X"': Ii hypoth~.-;i:~ iE3 (leveloped ref;ardint, the mao.-nutir and electrical
propertics of organ-.c polymers with conju~-,ate bonds, crystals of low-
molecular compounds which have such bondo, and donor-arceptor crystals
made up of two components. The local states which determine there
properties involve charge transfer eitfler between moleculeg or botweer.
ronjuj;ate suctions of a molecule. Following L. E. Lyonu (J. Chem. Soc.,
1957, 5001) it is assumed that carriers are formed by dis~:cciation of
charGe transfer complexes (CTC). The determination of the dlisso,,,iation
energy E d of the local state involving charge transfer and the f:)rmation
of a central ion at the defect and of a free carrier can be reduced to
determininG the polarization energy E of the cryGtal with the aid of
quantum-field theory. The motion of the electron waQ found to,be
accompanied by an adiabatic wave of electronic polarization which
Card 1/5

S/C,,2C/~2/14 ~/!r_- 7/,-,24
States involving charge tranqfer ... D101P-.11 Aq
diminishcq the ,-.elf-o?nergy of the conduction clrctrt)rl. T 1. e
onert_-,,i of* Ihe crystal is representild by:
where D a numerical coefficient dependinE,, on the nhae of tne cryntal,
v - volume of* a moleculo in the crystal, K irte~;rAl ofC I I om 1,
0 nn
interaction between two clectronn in the uppermost occiqied molecular
orbit, fi .oicillator stren6ths, and n e r o f * t k. eni t e da ', t? s
W(R where W~..
of the polar -, tate,3 io riven by Ed [1 - f2D,'v,))> (f.
d 0 0
enr-.-6y of Coulc,mb interaction in the polar stat-,. Calculpt i of
Lnd z- Q1.r 1.08 and
for aro-naliic hydrocarl~on3 Jave ru,-,;rectively ~ir,
1 -47 for naplitha: (,,n(,,;1 and 1 .06 for anthracene; I . 7 11 ~ I C' - 78 fo r
naphthacene; 1 . 1) 5 and 0.4 8 f or pentacene. On the cl, thi--,
of 'local centers with charCe tranaff,r, an additional of
carriers is f)c:ss:.'h1e if CTC are dissociated by excitcr.:1 2). r1he
carri;ar concentratiun is given by p - 11 exp(-E /2kT) - n cxp(-E,/-,,~-r1
0 u I , -)
4: 1 + )]exp(- 1~r /2kT), where 11 concentration rf the pairo;
+ , L,;,/ . 2 0 0
Card 2/3

jjlc;eo/62/144/~~A/01 71C24
S t a t i vo 1 vi r,;-, c u) rCe t. i-;LT;.-3 re r
'J1 /Pli 1~
arid V4 p r o ~ a ~i I i t o f d e ri c t i va t I o n 1i n (I d e 0 f f', x (- i t r en p C C t 1 v e -
0 in I c, t - ~ i n t; I v t t r:i n:i f - r F-, n e r i~-,y . Tl~-re irc? 2 figures.
i rvi f i t it ~ k It; rii r lie n koy f i z i k i Al, wl 1, m 4 i n:v,
( I nf; f, I tu t o o f Chom I cal P hy!; i f t !,e I e,~iy i) r
joierices USSR)
r 2 3 T B Jan u:. ry 0 , 19 6 2 , by V . It . K ond ra t N e v A cei I em'.,-, it n
3 U -BY. I T T F D . DeCe:Tller 30, 1961
Fie,. 2. Diagram showing model of
an organic semiconductor.
1) = conduction band; n - local
level callsed by CT(;; 3 - exciton
sin6let hand.
C a r d 3

ACCESSION NR: AT4020715 S/0000/63/000/000/0253/0259
AUTHOR: -Benderskly, Vo A.; Kogan, 0. Ya.; Gachkovskly, V. F.; Shlyapnikova, 1. A.,
TITLE: Electr4cal and magnetic properties of polymers with conjuga4ed bonds.
1. Polyphenylacetylenes.
SOURCE: Karbot:sopny*ya vy*sokcmolskulyarny*ye soyadlnenlya (Carbon-chain macro-
molecular compounds); sbornlk statey. Moscow, lzd-vo AN SSSR, 1963, 253-259
TOPIC TAGS: polymer, conjugated polymer, polymer electrical property, polymer
magnetic property, polyphenylacetylene, paramagnetic resonance, phenylacetylene
polymerization
ABSTRACT: This work Initiates a study of the nature of paramagentic centers, the
mechanisms of conductivity and the relationship between the two characteristics in
conjugated polymers. The electron paramagentic resonance spectra, the electrical
conductivity and the optical centers were Investigated In fractions of the product
of thermal polymerization of phenylacety)ene (atomic weight 670). The benzene-
and toluene-soluble fractions, with atomic w?ights ranging from 340 to 1870, were
obtained by successive sedimentation. In th~ tests conducted In nitrogen at 90
370 K and, In part, In a VIO-5 mm vacuum, a 975 kcps lKhF-2 paramagnetic reson;nce
.5peFtrometer was, used. The paramagnetic center concentration and the saturation
Cdrd . 1/2

ACCESSION NR: AT%020715
f
factor determined from the electron paramagnetic resonance spectra, were found to'
Increase as the molecular weight Increases. The duration T, of spin-lattice re-
laxation and Its dependence on temperature were determined. The signal intensity
In unsaturated electron paramagnetic resonance absorption strictly follows the
Curie law, the line center having the Lorentz form and the line wings 'icing describ-
ed by the Gaussian curve. A form analysis showed that a paramagnetic center con-
tains at most 11 equivalent protons. It Is concluded that the paramagnetism of
the polymers stems from small local centers rather than from molecules of the basic
substance.. the activation energy of dark conductivity Is Independent of rr~olecular
weight. and the carriers' birth results from the thermal Ionization of luminescent
centers. "in conclusion, we would like to thank Lo A. Blyumenfelld for discussion
of our work." OrIgo art. has: 4 graphs and 14 formulas.
ASSOCIATION: INSTITUT KHIMICHESKOY FIZIKI AN SSSR (institute of Chemical Physics,
AN SSSR)
SUBMTTEO: l8jul62 DATE ACQ$ 20Mar64 ENCL: 00
No REF SOV%. 012 OTHERS o04-
SUB CODE: 00
Card 2/2
7~1: 1057.11101

BLrUMENFELID, L.A.I-NNMRSKIY, V.A.
States with chairge transfer in
strukt.khim. 4 no.3s4O5-414
organic systems. Part 1. Zhur.-
Yq-Je 163. (KIRA 16:6)
1. Institut khimicheakoy fiziki AN SSSR.
(Aromatic compounds) (Electrons) (Cryatala-Electromagtic properties)

EENDERSKIY, V.A.
States vith charge transfer in organic systems. Part 2: Transfer
excitont and conduction electrons in molecular crystals. Zhurj-
atrukt.khim. 4 no.3t4.15-423 YfY-Je 163. (MIRA 16-6)
1. Instdtut khimicheakoy fisiki AN SSSR.
(Crystals) (Electrons) (organic compounds)

ACCESSION NR: AP40,110958 S/0031/64/016/003/0467/0474
AUTHOR: Bende kiy,,V.A.; Shevehenko, I. D. ; Dlyumenfel Id t L.A,
TITLE: Electric and magnetic pro;ertics of donor-acceptor crystals. 1. Complexes
formed by strong donors and acceptors
SOURCE: Optika i sptktroakopiya, v.10, no.3, 1064, 467-474
TOPIC TAGS: SPR apectrum, absorption spoctru-mi, dark conductivity, donor acceptor
crystal, donor acceptor comrlex, complex crystal, chloranil, tetra-chloroquinone,
para-phanylonediamir,e, benzidine, Iodine, charge exchange, polar crystal model
ABSTRACT: The electric and magnetic properties of complexes with charge transfer
in the solid phase have attracted the nttontion of many investigators. (A review of
rtecent research in the field has been published by L.A.Blyumenfelld and V.A.Dander-
My, Strukturnaya Wiimiya,4,405,1963.) The present work was devoted luo investiga-
U
.on of the EPR spectra, the absorption spectra in the visible and Infrared regions,
TA the dark conductivity, as well as the tempernture dependences of these parame-
rs, of complexes of chloranil (tetrachloro(~uinone) with para-phenylenediamine (1)
benzidine with iodine (2). The EPR spectra were recorded by means of a standard
1/3

ACCW4ION NR;. AP4M58
EPR spectrometer with provision for maintaining the sample at temperatures from 90
to 3800K. The dark conductivity was investigated by the potentiometric mothod.1,10st
of the measurements 'were made on compneted powder pellets, but some were rade using
single ci7stals (complex I only). The absorption spectra -were measured usinu SF-4
and LKS-14 spectrophotometers with the -3pccimens in the fom of gublimatcd layers.
The E!?R spectrum of complex I was also obtained in methyl alcohol solution. The re-
:3ults are presented in the form of curves. Singlo crystals of coniplex 1 exhibit a
singlo narrow EPR peak (0.4 Oe) with a comp-ex exponential temperature dependence.
Me activation energy for exchange intoraction ngreas with the enorgy for excita-
tion of the host to Ute magnatic statc. The activation energy is not connect'2d *;:-.-'I,
Singlet-triplat splitting. In the caaa of complex 2 the anisotropy of the EPR SiGwl
depends on temperatur3. The peaks in the absorption spectra agree with the values cc
the activation energy for dark conduction: 1.17 and 0.48 6V for complexes 1 and 2,
respectively. The.inf:rared absorption spnctra of the complexes differ markedly from;
the spqctra of the constituent components. The rosults are discussed from the stand-
point of the crystal i3odel with low-lying polar states. Orig.art.has: 5 figures
and 2 -ables.
Ccird 21A %

~ A,; SfIFVf,'fD,Jm, i ~!t,
- " 1 14 - T 11" 1 , i A.
Elol~trlr and mai~nntic prcpprties (-.f donor - RCC')P* 'I-.,- Cry3tals.
Part 1. Opt. I sr,-Itr. 16 r-.3:467-4'4 Mr '64. (IJIRA 17:4)

ACCLSSION ITR; AP4034942
S/0181/,54/006/0034=A544
AUTHORS: Benderskly,, V. A.; Bly=enretlld, L. A.; Shevchonko, '.:. B.;
AlItshulor, T. S.
TrrLE; Electrical and magnotio properties of donor acceptor crystals
SOURCE: Pizika tvordogo tela, v. 6, no. 5, 1964, 1542-1544
TOPIC TAGS: electric property, mgnotic property, donor acceptor crystal,
organic somiconductor, aromatic amino, aromatic hydrocarbon, rhloranil, bromanil
ABSTRACT: So many -.heories have boon proposed for the generation of carriers
in organic somiconditetors that the authors sought to weigh the evidence and
uncovor the proper theory. They compared the activation energies of conduction
with the position of the band of carrier displacement in weak donor-acceptor
systems- in both soli:' and liquid phases. They examined complexes of chloranil
and bromanil with aromatic amines (o-aminophonol, n-bramanalid, and diphonyla-A 0)
and aromatic hydrocza-ba.,s (pyrono and atilbone). In all these conplexes the
absorption bands of the films proved to be identical to the spectra of the
solutions. Change in the aggregate state did not load to expansion of the band,
and the shift in the tend did not exceed 0.07 ev. For the hydrocarbons the bwW
Card 1/2

ACCESSION hR: AP4G.'141942
shifted toward the red and of the apoctr=, for the aromatic amines toward.tho
short-wavo end. All, these facts indicate that the processes of optical excitation
are identical in both liquid and solid phases. Measurements show that the activa-
tion energies and t':.e -maxima In the carrior-tr'anhfar band are identical. It
thus appears that c.).rriorn.are generated in thaso complexes in the same way an
in one-componont mo'.1ocular crystAls.- Orig. art. has: 1 table and 2 forzulAs.
ASSOCIATION: Inatil;ut khimicheakoy fiziki AN USSR, Moscow (I"'titute of
Chemical Physics AN .3SSR)
SUMITTED: ISNov63
SUB CODE: SS,OC
DATE ACQ: 20May64
110 REF SOV3 006
ENCL: 00
OTHERs 006
Card 2/2

1 1
ACC-7SSION NR: A1,4040490 S/0190/64/006/006/110411110
0 "enderGkiy, V. A.; Stunzhas, P. A.
'-T 1:1ectrical md magnetic properties oi polyners with conjugated
Fluore~;ceoco of polyphanylacetylenes
2 0 1: 7~ C 7 Vy,~sokor-,zl~t--',