SCIENTIFIC ABSTRACT BERLIN, A. A. - BERLIN, A. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000204930009-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 8, 2000
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

AOOZSSION XR: AP4035097 S/0191/64/000/005/0004/0007
AUTHORS: Birliu, A. A#; Prosvlrkina,~.V. F.
TIT'LE: In-v""'estigatious In the area of.!the mechano-chemistry of
Polymers
SOURCE: Plastiohaskiye maesy*,,no. ~j 1964t 4-7
TOi10 TAGS':" polyvinylahloride, mechanical chemical proper.ty, mole-
culair weight distribution# suspension polymer, emulsion polymerg
milling, plasticization, mechanical destruction, differential
mol~oular ijelght distribution, benzoyl peroxide Initiatort Iso-
butyroazodihitrile initiator, differential viscosity
ABSTIRAOT: the molec4lar'weight distribution of suspension and
emulsion polyvinyl chloride polymerized with different initiators,
and.~Ithe change In the molecular weight distribution upon milling
Vero invee~igated to determine the relationship between the mole-
cular weight distribution of PVC produced under differeut condi-
tions and ~te mechanical destruationiduring processing. From dif-
ferential i4oleoular weight distribution curves It was determined

A0048SION XR: AP4035097
Thai the M~st defined and highest molecular weight fraction was
obiiined by suspension polymerizatiou.with benzoyl peroxide
(brind PB)j suspension polymerizatio%i with the azodinitrile of
a lar
lso~utyric't old (brand PF polymer) Save somewhat broader moleou
'Wel6ht dialribution with a greater low molecular fraotlon~ PB-l
il 0 compool-
and:PF-1 gpades of polymer we;e mor ~,uniform in molecular
tioA and eqntained lose low molecular polymer than the PB..-4 and
PF-4 brandA. The emulsion polymer with hydrogen peroxide initiator.
(brand M) contained more low molecular material and had a less
defined maiimum than the suspension polymers. By comparing the
dlfferentl~.l viscosity of the polymers before and after mlllIng,
thejgreate6t change in molecular'wei-ght, i.e., the greatest meoh-
ani al destruction, was found in tho-PB polymer and the least In
the,H polyier, even though the'avorage molecular weight was close.
Thug polymerization conditions and nature of the initiator as well
as fractional composition determine the weak spots In tha!polymer
whloh are Vulnerable to mechanical action. The average molecular
weight wasAowered (due to predominant rupture of the longest
molocules),land the physical heterogeneity was reduced on milling.-
Theirelative viscosity changes increased-gradually on milling in
Cc~,r! 2/3

ACOESSION WR: AP4035097
going to.'the higher molecular w'eighttractlons.- No relationship
was.found between the changes in the,Khaggins constant for'the
initial and;the milled polymers; KI changed insignificantly on
milling and,its value was generally higher for the higher molecular'
weidht fractions. Orig. art. haste 4,;figures and 4 tables,!
ASSOOIATION: None
SUB14XTTED: .00 ENOL;t 00
SUB!PODBio ZC, KT NR REP SOVt 006 OTHER: 005
Ib

ACCESSION NR: Ar4037243 9/0062/64/000/005/0909/09121
'J'AUTHORi Dulov, go As; LioRonlkiyl, Be 1.1 Ragimov, As Vs;
Slinking As As; Borlinp As As
TITLE,t Electrical',and aagnotic properties of polyarylonequinouse
SOURCE: AN SSSR,- Isvo Seriya khimicheskayap no* 5# 1964v
909-912
TOPIC TAGSt organic semiconductor$ semiconducting polymer,
polyaryienequinons
ABSTRACTs A study has been made of the electrical and paramagnetL C,j
properties of polyarylenequinones (1) with the general formula
R
and x-ray diffraction p4tteras-bavebeen rsiordede Polymer*
[Card

71ACCESSION NRI AP4037243
were synthesized.from the quinone and the bisdiazotized diamineo.
Their structure was linear-or three-dimensional depending on the-
reactant ratio (1/1 or 1/3; or 1/1 and cross linked with
benzidine).;
The~temperature dependence of d-~-c electrical conductivity_for
pellet,
samplee of I was determined in the range 100-350C at 10 5 mm Hg.
A correlation was found between molecular structure, packinj
density,
and electrical properties. Reduction of the backbone quinone radi-
cals to the stable semiquinone fo'rm resulted in a sharp rise in
conductivity (the change in activation energy remained small).
This is believed to confirm the participation of unpaired electrons
-in the conduction process. This research war. conducted at the
Institute of Chomical'Physics, Academy of Sciences SSSR, and the
Institute of Organic Chemistry imeni No Do FelinakLy, Academy of
-Sciences SSSR,. Orig. arto has: I formula, 2 figures, and 1 table*
ASSOCIATION1 Institut kbimicheskoy Eiziki Akadamii nauk SSSR
(institute of Chemical Physicas Academy of Sciences SSSR); Institut
organichaskoy khimit is* No Do Zelinskogo Akademit nauk SSSR
(Institute of Organic Chents try Academy of Sciences 005R)
Ca,,d 2

j,ACCESSI`ON NRS' AP4041172 S/0062/64/000/006/1132/1132,
IAUTHORs Sherle, As Is; Asay;v, Yu. G.1 Frankovich, Yet Lol Berlin,
Kaostochkin, Vs I#
TITLE& Formation of.& tetracyanoethylene chelate polymer
SOURCEa AN SSSRe 1xv, Serlya khimichashaya, no.'6, 19640 1132
ITOPIC TAGSs tetracyanoethylene, organic semiconductor,
semiconducting.
polymerp chelate polymer. copper tetraacetylenide A
ABSTRACTs Copper tatraacetylouide.(I) has been prepared, identified#
and Its semiconducting properties studied, Salt I was obtained In
aceftonitrile aiid with lower yield in nitrobenzene. Identification
was
made by elemental analysis and UV and IR spectroscopy* At
bilov.100C.
electrical conductivity (6) in vacuum was described by
6.W 10-0*6 exp(-5670/RT), 6- 10-4.7 OhM-1 cm-1
300k's
At higher temperatures 6 drops Irreversibly and after heating
to~150CI,
becomes 6 10004 exp(11900/RT)p 6gook 10-70O.ohn-I co-'*
cord 112

ACCZ'SS'16N kki----AP-4041
If I in heated in the presence of totracyanoothylons a now compound
(11) Is formed which unlike I is Insoluble In acatouLtrile and
tetra
hydrofuron. Compound 11 Is highly soluble in H2SO4 and can be prt~
-1cipitated-froof it with water,' IR spectroscopy suggests that 11
is
c4elato polymer, The work was carried out at the Institute of
Physics of the Academy of Sciences USSR.
ASSOCIATIONS Institut khiuicheskoy fiziki Akademii nauk SSSR
(Instituts, of Chouical,,Physicat Academy. of Sciences SSSR)
-0
=--A,SUBMITTE* D a24Mar64 INCLs
;Q-
UB CODES OC Sg~ .-~NO REP SOV:'.~ 001 -OTHERt 001
Card 2/2

'. MKOMET400 -W
(M/bO81/65/0OC;/0O6/SO38/h0
SOURCE: Ref. zh. Ehici7ap Abs- 66255
AMMOR: Derlit-, A.A.; Samrin, Ye.P!.,- Saninj J.G.; Kozimj T_S_
TIN12: Investigation In the field of pol~mmrizable ollemeres.
Synthesis an some
properties of steracrylotes ly,,ntaerythrite - base
17-
CMM SOME: I Tr. po khImdI i khim. tekhnol. Gor*_ y, vyp. 10),
19611, 3-05-3-07
TOPIC TAGS: chemical -reaction, pol7merization, m~alpia
TRMIATION., The condensation telowrization of pentaerythrite and
the foll in~
dicarbo),ylic acids: sebacic aw ,
adipic nzid phtalic with an addition of nc-tlincrylic ncid
in n ratio of pentacrythrite to the acia3 1:2:6.6 In the presence
of r~~ of dil. (1:10)i
H,,GOjj a8 catalyst; or using n-tolueenesulfonic acid in a
toluene, or benzene m2dium
under continuous azeotrople distilL-ition of the reaction water
wos carricil out.
Polyeateracrylates are a mixture of oligoraeres with a degree of
pol.,conJcnnation.
n_-2. At n-1 the ester nwiber and the broridde number were
determined. The ML
1;) was
found. The polyesteracrylate vw polywrized with O-51p' of benZo I
at 700 at
.1200 Zor 5 brs. The a sue as hardnesz
(Brinell), static bending strength and the weiSht loss at 12! 7n
e_ atmosjphere were
determined. fi. Vikolaenko L
SUB CODE: 07
cmd ii-, '-Ili

BERLIN. A.A.; VONSYATSKIY, V.A.; LYUBCHENKO, L.S.
Electron paramagnetic resonance spectra (EPR) of some
polynualear
aromatic hydrocarbons. Izv. AN SSSH Ser. kh3z.,
no-7tll84-1168
JI 164. (MIRA 17:8)
1. Institut khimicheskoy fiziki AN SSSR.

-77-
KOROLEV, G.V.; SMMOV, B.R.; BASHKMVA, S.G.; BERM, A.A.
Polymerization in highly viscous media and three-dimensional
polymerization. Part 8& Determination of the rate constants
of initiation of radical polymerization by means of some
peroxide and azo Initiators in an incompletely set
dimethaerylate
butylene glycol. Vysokom. soed. 6 no.7al256-1260 Jl 164
(MIRA 18e2)
1. Instlitut khWebeekoy fiziki AN SSSR*

43 -Mvi
9 11 &A 17 7 1) 72 1
1: C-
ABSTRACT! On the basis. of data oUltaineJ ?~ruvlo~,i ~Irll -
researchers on the catqlvtlc pronertf-s of

L 17BL9-65 ENIT (ra) AEFF (c )/F71AM )/T PC,-hlpr-t
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yra,
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ir-Q
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L 178h9-65
,,LccEss-ro,,,q mR: AP4-o47410
16 'CC lik T. Tnstlt--if-p
R~
C 2

TIM E,
R 20,
ni~ io 1 1 f;4
:5: Jene glycoi, butylene glyooi, phdhahc acid, :~eol-.cic a(-ic~',
rigidity, polvacrylic ester, acrylate
A B S -ITA C TI: The hardened prnduchs of f~ie follvwi7l.~-
2
t"Ie 4 F'Im in di~tmetur; the spcellic pressurc- -ov-:z-~
U--~7eer' 0! T,
merization was plotted. Samples with a degreo of conversion close to
100~A- wef P th-
~'I -j 1/2

w(,Tfc. in a clenser struebim such as MDF, greaWr bads are needed to
m.oduce desa-
yu. M. -Sivergin for Rupplvingf 4,Y~r,
A
VR~ 3z
'n~

T. 7~n i !T Pf-
r A
A I 7'1'l ~f 1~.* A c s- xro vq R 70- Sivitifl-, ~,i:i
Tz
P, if, T)! 1 1 V
R With

L 224
ACCR~1811 NR- AP5000483
rr.-,,t i "n.
1, -OFU

B~T -A.A.; MIKEVICH, Ye.L,; CHERYASHNA, L.G.
-YARDII, V.P.; FP
Meal activation effect during the reaction betweon
tetracyano-
benzene and some aromatic hydrocarbons. Izv. IN SSSR Ser.
kh-_m
no.llt2108-2110 N f64 (MIRA 18%1i
1. Institut khimicheskoy fiziki AN SSSR.

pri zm A.,
~VRPR/FuPfj) T Fc-l_- rr--ii:
Ya Fi r
Tf--. DT(- -F A n ot d vf-z ts' r Iv n'! ;I t' u
y
C.,d 11/2
iN

- - - - - - - - - -
increase in crossliu~,hig, wlAle the iower strengm aL a coemciem u.,
EWE

ACCESSION NP, AP5000027
AM-
A-!' ryva i 5E. ,X
As
-B*~ It. Novoaelova. I A
Heat s tabilizer-~ for P!~.ly(ethvl~~ne terepb tilainte, ~e
TITLE:
SOURCE Bvtjl. izobr. i tovar, znakov, no. 21, 1~i64, 4'
TOP I C A C. '-,v e n e t e r e jra 1t e e r77 aF
ABSTRACI: An Author Certificate has been if:r-ue,4 F,,
duc t, 'If the neit treatment of olvnuclear ar"?-At! k
z e r 5 p 0 1Y k ei'l ve n et! r e:,i
SUBMITTED.- 16Jul63
NO REF SOV: 000
ENCLt 00 S) U 8 C 0 1? E-
nT~!ER: 000 ATD PPFcc:- 1 r

'ACCESSM.' NR: ;P4009148' S/0190/64/006/001/0058/0063
ATITHORS: Berlin, A. A.; Zherebtsova, L. V.;'Razvodovskiy, U, F.
TITLE: Polymors v.1th conjugated systan. 37. Synthesis of lymers
with charged
hetero3toms in the rincroriolocular cbvin (onium "Inorizationr
SOURCE: Vy*3o',cowl,)Tiilyxtrny*yo soyedineniva, v. 6, no. 1, 1964,
58-63
TOPIC TAGS., polymer, polywrization, conjugated system)
4-chloropyridino, 4-
bror,opyridine, copolymerization, 1,4-dilbormobutzina, onium
polymerization, charged
heterstomp polymerizntion kinetics, stopwiso mechant.sm, ionic state
ABSTRACT,.' In the so-called "onium" type of polymerimtion the
growth of the chain
is snid to proceed via the incorporation of hoteroatoms as ions of
abnormal valoncy.
In the present paper, 4-chloropyri dine ond 4-bromopyridine wore
subjected to thorral
polymerization In sopled evacuated glass sqmiles i-a a temperature
rpnFe of 0-220C,
for a 1-5 hour period. The rolymAriz.".tJor of 4- chloropyri dine
was also cenducted in
y7ridine solution at 100C for 6 hours. Gotolymerization of
genw,sremnal-diprIdyl
with 1,4-dibronobutane was also schievud. The polvmers obtained were
subjoctad to
chemical analysis, and thoir rtalocu;rjr reizht, olocyrival
conductivity, infrared
spectra.,and electron parampatic resonance data studied , In the
opinion of the
Cara l/J

ACCESSIM WR;- AP4000,1448
authors the polywrization process presumably. proceeded along steps
outlined in Fig*
2 of the Enclosure, In a stepwise pattern, through the stage of an
ionized complex
involving a tr;msfer of charge as well as of the - intermedipte
corplex. -It -,WAS found
thst polymerization in an aluminum cell rroceeded without any
inducti. on. pari ocl an(I
elt "n aceolerated luce as corpared with a sill cone-coated cell.
The addition of
0.5-1.0% 'KI cat-alyzed the polymerization of 4- chloropyA dine. A
maximum roleculpr
'wejoht of 4360 for -,,he 4-chloropyridine polymer was obtained et
165C, while the
Z-bromDpyridino polymer had -a rmleculnr waight of 1920 at 150C. All
polymers were
soluble in water and hydrochloric acid, wIdle only the onbs obtained
8t 0-50C were
soluble in methanol And ethnnol. The polymers po3sesred increa-;~&
electro-.
-Conductivity. Spontaneous polymerization in 4-bronopyridine
monorers on storage was
observad, the polymer being of. crystalline structure. Thanks are
given to Ye. I.
'Inl*barov fox, determination of electrical properties o:t the
polymers. Orig. art.
has: I Tormla, 2 tables, a~d 2 charts.,
CCI ATI CNI "rnstitut. kh4-michaskoy fizikij, JN SSSR (Institute of
Cbamical Physics,
A? SSSR)
311MIT7SED; 27jul62 DAUS ACQz 2OFeb64 01
SM 005 OTHERt
SUB CODE: CH NO RIF 005
Card

DUBINSKAYA, A.M.; BUTYAGIN~ P.
Some low-temperature reactions of macro radicals in
the solid
phase. Dckl, AN SSSR 159 no.3:595-598 N 164 (MMA
1821)
1, Institut khimicheskoy fiziki AN SSSR*
Predstavleno akademikm
V.N. Kondratlyevym,.

ACCESSION NRi
AP4037280 S/0190/64/00'6/005/0832/08371'
iAUT11OR: Berlin,_A,-A.- Cherkashina, L, 0,; Frankevicho Yes L,J
Balabanov, Y_eeko; Aae;avg Yus Ot
TITLEt Polymers with a conjugated systsmo 1, Synthesis and
investigation of the elactrophysLeal properties of polymaric
phthalocyaaLnes
SOURCE: Vy*sokomolekulyaehy*y,s soyedinentya, v. 6, no. 5, 1964,
032-837
TOPIC TAGS: organic semiconductors semiconductor polymers
phthalo--"
cyanine polymer
ABSTRACTs The effect of oxygen-containing groups and the effect
of branching on the aleetrical.properties of phtholocyanine
polymers
have been studied* This was considered of interest because
previously
prepared phthalocyaniaeo based on aromatic tatracarboxylLe acids
Card
3

ACCESSION NRI AP4037280
showed semiconducting and catalytic properties. The polymers in
this study were synthesized by reacting lv2#'4,5-tetr&cyanobenzene
(TCB) or TCB and phthalonitrile'i(PN) with copper powder or Cu Cl.
in the presence of urea at 300CO* PN was added to control both
the degree of branching and the content.of nitrile end groupsl
which.:were subsequently converted to oxygen-containing groups by
1hydrolysi with H SO The electrical conductivity at 300K for
11 2 4j
the TCB polymers was 0-5to 10-2 ohm-1 cm-1 and the activation i
energy was 6-2 kcal/mol.. These figures for phthaloc'Yanine
polymers
prepared earlier from pyrome7itic acid were 10-4 Ohm-1 cm-1 and
.1-4,2 kcal/mol, For the polymers from TCB and PN which contain
oxygen
groups, the conductivity was 10-S ohm-1 cm-1 and 10-2.6 ohm-1 c=-1
for reprecipitated and rconreprecipLtated samples, respectively*
The thermal stability of the phthalocyanine polymers with oxygen-
I
containing groups was higher than that of the
nitrile-group-containin1el',
analogs (300-350C versus 250C)a This research was done at the
Institute of Chemical Phyaics;Academy of Sciences SSSR* Origo
arts..
1hast 3 figures$ 2 tables$ and 2 formula**
Card

i Ir I
.Mrd - 3 /3 - 1
I

TOPIC TAGS: polymerization, organic azo compound, polyester piaSt4C.
--icrv7i-c
plastic, organic oxide
deDend on the decreee of convert-ion or, the Do'Lvoatpr

se~ po,yester acrylate g,as5e6 WkL:, z e6
e n C.-re
initiation were approxi=zeu 1,3 T.LM65 luWur Taull u [to
rlf decomposition. 7he efficiency 0 f initiation by pe ro% -J e
ASSOCIATION: Institut khimicte'akoy~flziki Aiq SSSR 'Unstitute of Chzmicall
AN SSSR)

ACCESSION NR: AP4045435
8/0190/64/006/009/1684/1687
AUTHOR: Berlin, A.A., Ganina, V.I.,.Kargin, V.A., Kromnan, A..G.,
Yanovskiy, D. W.
TITLE: Formation of salt groups by the -reaction of
polytvinylohloridel with nitrile ad
methylvinylpyridine rubbers
SOURCE: Vy*eokomolekulyarny*yoi;oyedinenlya, v. 6, no. 9, 1964,
1684-1687
TOPIC TAGS: poly[vinylch~oride], nitrile rubber, methylvinylpyridine
rubber, plasticiza-
Lion, polymer infrared spectrum polymer, impact strength, pyridine
salt, volume
resistivity, grafted copolymer t
A73STRACT: The proposed mechanism ~f formation of grafted copolymers,
their infrared'i
spectra, volume resistivity and some physico-me'chantcal properties
of the products of
coplasticization of polylvinylehloridel (PVC) with nitrile and
methylvinylpyridine synthetic
rubbers were investigated on 0. 08 mm thick films made from a 1:1
mixture of PVC and
rubber. Models for the grafted copolymers of PVC with
methylvinylpyridine rubbers (MVP)
were low-molecular pyridine salts. The absorption spectra of PVC, MVP
and their co-
plasUcization products showed that the absorption bands of PVC and
rubber appear in the
spectrum of the coplasticliation product either unohanged or with a
slight displacement.
1/3

Some bands characteristic of PVC coalesce with the corresponding MVP
bands. There,
the width and intensity of the separate ban4s change. The appearance
of new bands, for
the reaction product at 1628 and 1470 cm-4 can be explained by the
absorption of the
pyridine Ion, for which two characteristic bandi lie In the regions
of 1630-1640 and
1485-1490 ciel. The low-molecular pyridine salt shows a very sharp
pe4k at 1636 cm-
anc a wide Iniensive peak with a maximum in the region of 1470-1480
cm It has been
confirmed by the spectra that during the coplasticization of PVC and
MVP, by the
interaction of'theiir functional groups, grafted copolymers having
the structure of high-
molecular pyridine salts are produced. The volume resistivity data
for PVC-MVP afid
PVC-nitrile grafted copolymers as well as for the coplasticization of
PVC with butadiene
and butadiene-styrene (SEE-30) rubbers,' are tabulated. The volume
resistivity decreases,
considerably U the amount of rubber, containing functional groups
which Interact with the
chlorine atoms of PVC, is Increased.. This Increase in electrical
conductivity for PVC,
compositions 'with rubber may be due to the fori~atlon of an Ionic
structure in the grafted
copolymers or to the accumulation of hydrogen chloride In the system,
as a result Of
the dehydrochlorInation of PVC during plasticizAtiollo V Analysis of
aqueous-acetone
extracts showed the absenee of chlorine and hydrogen Aoms'In the
composition. The_
2/3
:Card

AUTHOR: Berlin, A.A., Kronman, A.G.# Yanovskly, D.M., Kargin, V.A.
TITLE: Mechanism of the processes occurring In the coplaaticization
of polytvinylehl
oridej
nitrogenous rubber,: mothylvinylpyridine;. isoprene, graft polymer,
polymer Impact
strength, hydroquinone
SOURCE: Vy*aokomolektdyarny*ye soyedinentya, v. 6, no. 9j 1964,
1688-1692
TOPIC TAGS: co~lastlcizat:ion, copolymer, polyMnylchloridel,
4itrogenous rubber,
raethylvinylpyridine, Isoprene, graft polyiner, polymer impact
Rtrength, hydroquinone
-ABSTRACT: no properties of grafted copolymers synthesized by the
joint plasticization-
of poly[vinylchloridel (PVC) with nitrile (SKN) and
methylvinylpvridine (MVP) rubbers
were investigated in order to clarify the molecular and radical
mechanisms occurring
during the formation of these copolymers. Films 0.4-0.6 mm thick
obtained fro*ma
0. 5% solution of polymer In cycloboxandne at a PVC: rubber ratio of
9:1 were tested
for strength. and viscosity. It was found that the nia3dmum tensile
strength for films of
frafted copolymers Is much lower than for films obtained from the
correyonding mechan-
Cal mixtures. This is due to the loosening of the polymer structure
rem tting ftom the
g process, which lwds to the formation of systems characterized by
lower density

ACCESSION NR: AP4046436
and air-filled micropores. Viscosimetric Investigations showed that
the InWnslo vis-
cosity of mechanical mixtures of PVC with MVP-15,* SKN-18, SKN-26 and
SKN-40 Is
IntermedlaW between the viscosities of the Initial polymers, but that
the viscosity of the
corresponditig coplasticization product is lower, than the viscosity
of either initial
polymer. However, the viscosity of the coplasticization product of
PVC with Isoprene
rubber (SKI)Iind that of their mechanical mixture are almost
Identical and arq inter-
mqdiate between the viscosities of the Initial polymers. This Is due
to the absence of
ne rubber able to react with PVC, which results In a mechan.--~
functional groups In isopre
ical mixture during their coplasticization. The' specific
viscosity-concentration curves
for a PVC composition containing 10% MVP-15, plasticizedfor 2.5, 5,
10 and 20 min#
show that the viscosity decreases with decreasing reaction time while
the Huggens con-
stant increases. During the plasticization of PVC. with IQ% Isoprene
rubber, the
viscosity remains unchanged with time, but the
concentration-viscosity curves for
2.5, 5 and 20 min. almost agree. This confirms the theoretical
difference in the pro-
ceases of plasticization of. PVC with rubbers with or without
functional groupswhich can
react.with It, Ile effect of the addition of hydroqdn6ne to the
mixture on the pivpGrues

ACCESSION NR: AP4045436
of the coplasticization product of PVC with rubbers wag also studied.
PILN.Bticization with
1% hydroquinone, used as an acceptor of free radicals, showed that
hydroquinone does. not
affect the Impact strength of the samples and decreases the reduced.
viscosity of the
plasticization products only slightly. Thermal dynamic curves show
that hydro.quinone by-
hindering the recombination of radicals and cross-linking, improves
the flow properties of
the composition slightly, The decrease In temperature promotes the
destruption of the
macromolecules during mechanical processing. On the basis of the
experimental-data, itwas'
established that the role of Ta&cal vrocesses in the formation of
grafted polymers 11~

RASSP S.I.; BERLIN -A.A,
Particular features of the effect of local activation in the
inhiUtlon of oxidation pronesses by compounds with a conjugation
system. Izv. AN SSSR. Ser. khim. no.10g1913 0 164.
(MIRA 17-12)
1. InstItut khimieheskoy fizAi AN SSSR JL lnstitut tonkoy
khimlcheskoy tekhnoloe-i im. M.V. Lomonosova.

-.----Tix ~17
I le,'
7f:-
A C C E S S; 1 Cp AP4047200
'i-l, A, Mi rlk :t R
III Ine Prcsence

ACCESSION NR: AP4047200
watalmd no rotleeablv ar r 17-" t 7,
f tp
Nc. I the r
i aTmn.-, -,,nc, ri c oxygen up to 300-400C.
c or (b rem i n n t or.
ii!i v t! r 1 n.
r P, a

TTTL.-~ tdin-~
Certaln problems of 4-chlrtroov- e r) n v
~,A
T OP ! C T A(, Z. ;z a r, ic oamiconductor, sp-rnii conduct ing
loropyridine, pcl,pmerization k i n, t i c 2 n n vTmp
tton T- 2 c h a n i z Tt
AbSTRACTt A study haa been made of the ktnpt(eg P--I
E! 2
c c7 r -,n q r i r, Ti rn ja r I i ~4 n g r-

C.
C!
Ternary amines and w2ter inhibited the reaction
i t e r i e a! -',i
j3 u-, C a C a a C L V fi v i I v u
e 9 e d.
a r h as 1 5 figures., 2 tables nn,~

:-m-l -~ ,
. ,, " Q , , -
: , -~ .4*.-_- -,-
7 -
=,5~~ , --L
: :.I, ~-~ -:-

A C('F S S r ON N P AP404q 14 7
D e r I I o , A A D b i n 9 k a v a A I I-i 1~
b u i Q I Z) n
SOURCE- Vv *A oknmo 1 ekil I v a rn v1 ve s f-, v e ci it, 1 1 y
F(- (4
t~ s c m. Icoriduc ori r ~i c r v1or.
p r c t p e
was conducted t n 1,L i n
a c r vOn i r i r-. r v I o r a m
r o j c L 7
7 i 7
m e e Cr- m
formamide T- i r e I e r n i s n r,,E
Card 1
WE
LE i

L 1517j-65

ACCESSION NR:
AP4049147

v t s c os
me.,!; urc-men t-, ~,howed thi t n
~~I t s

u L Y 'i c r vo T1t

c r tr--

u- r Tn .11 T -1- 11

of the original polyacrylonitrile. Orig. art. bast 8 figures.
--ASUCZATIGNI, none
SUBMITTVD: 0 0 ENCL: 00 S U b'~t'
140 REY ~ov 0 3 0-H 1: F OCIR

BFM,IN,, A.A.j A-SEYEVA, H.M.; SUMBA, Z.S.;
KASATOCHKIN, I.I.I.
KinetIcs of therml degradaticn of
chlorine-:ttintaining ~.,arW-
chf,On yo3ymers. Tzv. All SSSR Ser. klAm. 11 164
(1-111RA IS.-l)
1. Institut kli-imicheskoy fj.ziki AN SSSR.

!ACCESSION NRz AP4039616 S/0076/64/038/005/1118/1125
AUTHOR: BoguslavakLy, Lo 1. (Moscow); Sherle, A. 1. (Moscow);
Derlinp
A. A.._(Moscow)
TITLE: Study of the electrophyaLcal properties of films of
polymeric.
complexes of,metal tatracyanoe.thylons
SOURCE: Zhurnal fizLcheskoy khLmLLO v. 38, no. 5, 1964, 1118-1125
TOPIC TAGS: tetracyanoethylene, metal tetracyanoethylene, tetra-
cyanoethylene polymer, organic semiconductor, semiconducting
polymer
ABSTRACT: A study has been made of the electrical properties of
films of chelate polymers of tetracyanoethylene with various
metals.
Films 10-4-10-S m thick were prepared by treating strips of Cu, H
Fe, NL, Ag, Pto Al, or glass with tetracyanoethylene vapors at
150-450C- and 10-4-10-5 MM Hg. Electrical measurements were
carried--
out in the frequency range 20 cycles/see-200 keyelealsee with
simul--
taneous application of d-c voltage* Electrical resistivity and
its
temperature dependence, activation energy.for conduction,, and
dLelec-
tric constant were determined, From changes in these parameters
Card i/2

-[ACCESSIO_N'~'N_-R:-
processes taking place in the formation and heat treatment of the
films were observed. The dependence of resistivity and dielectric
I - on frequency' and d-c. -voltage are interpreted
constant of the filmr
in terms of the heterogeneous structure model. It is assumed that
iresistivity and activation energy are essentially due to ac
'tivation
jumps over barriers between macromolecules. The work was idarried
out at the Institute of Electrochemistry and the Institute of Chemi-
cal Physics of the Academy of Sciences USSR. Orig. art. has% 8 fig-,
ures, I table, and I formula.
ASSOCIATION: Institut elektrokhimii Akademii nauk SSSR Mwtitute of
Electro-vi
chemistry, Acaden7 of Saiinces, SSSR); Institut khimicheakoy firsiki
Akademii nauk
1SSSR (Institute of Chemioal,!~4ysicsq Maderpyof.Sciouceag SM)
SUBHITTED: l8Mar63
DATE ACQ8 19Jun64 tENCLt 00
SUB*CDDB: NO RBF SOV: 006 OTHER:
002

tOP T'~A (11 r r
L: TH J.:t: r
Kiseieva, Ye. D. RaLlimov A V nG *,,y~ .
Kliventc,vpskay-a, M. M. , Bryushkova, T A.
TFI f,F- Effect of an ionizin- radiation ci,rrp-t -f
SIT Zhurnal fizicheskoy.khirnii, v. 38, no. i), 11~64,
FOPIC TAG S- polvsulfophenylenequinone cationite. inm~(-
PS-3, radiation stabilitv, accelerated electron radlgtlnr
radiation, EP11, spectrum, doible bord
BtabPaitv-df-pdl~~uUooh~nvleiienuinone c-ationites subiected to
accelerated e3ectron current i adiation in water and in a cirv
qtmnrnhort~ ir-

-,-ACCESSIOYNR~-A-P4046OB-6---.-
j4 4
stilbenedisulfonic acid-2. 2(TII) (1-T'11=1:3 for ionite PS- 3)
v-I!P(,trrAn pnprff,,!=4 NI F rurre- ~,trp,t,40, !r'
-<
-a]3iy inereasea.- a,ne- incTe-aSed-IOn-eXchange- Capacity of-the irradipapd
3~_R_ qP_~4_
tionite w2, explained due to the formation )f cnrboxvl
ASSOCIATTON- Akademiya np-lik SSSR Institut
Cc.,d 2/3

ACCESSION NR- AP4046086
Sciences SSSR Institute of Physical Chemistry)
SUBMITTED, 24Apr64 ENCL: 00
SUB CODE- GC, EM, GP NO REF SOV: 002
C.,-d3 / 3

ACCESSION NR: AP4013331 S/0020/64/154/003/0627/0630
AUTHORS: Berlin AIIA.; Voneyatskiy, V.A.
TITLE: Induced reactivity of several compounds with conjugated
systems on reacting with 1#1-diphenyl-2-picry1hydrazyl
SOURCE: AN SSSR. Doklady*, v. 1540 no. 3. 1964, 627-630
TOPIC TAGS: conjugated polymer,, paramagnetic polymer, Induced re-
activity, hydrogen transfer, pi complex, polymer chemistryo poly-
phenylene, electron paramagnetic resonance, paramagnetic activa-
tion., 1,1-diphenyl-2-picry1hydrazyl, paramagnetic induction of
reactivity
ABSTRACT: The reaction of 1,1-diphenyl-2-pierylhydrazyl,(DFPH) with
solutions of paramagnetic polymers containing conjugated bond sys-
~~tems (polyphenylene (PF), polyazophenylene, polymethyl ridylacetyl-
ene, polyphenylacetytlene, and heat-treated anthracenely-and with
anthraeene monomer, was studied spectrophotometrically and by the
EPR. DFPH is not destroyed in solution with anthracene, whIch in
Card 1/3

ACCESSION NR: AP4013331
not paramagnetic, but is destroyed on addition of FP3 its destrue-
tion increases with temperature and is dependent on the presence of
oxygen. The destruction is associated with the transfer of H from
m (not from the solvent) to form 1,1-diphenyl-
the conjugated syste
2-plerylhydrazine, but not a DPFH-PF compound. The folloW4ng re-
action mechanism proposed: DFPH dissolves to form solvated com-
plexes, which on addition of PF form a DFPH(PF)solvent pi-complex.
Paramagnetic centers of the PF activate the S-T transition of the
diamagnetic PF macromolecule, making possible the transfer of the H
to the acceptor DFPH. 7he acyl;ive PF radical thus formed breaks off
an H (or other atom,.eg. halogen),from the solvent 0olecule in the
complex, and -the renAinir4 --savent: radical reacts witt'l, a
-second ---
f io" (0i.;
molecule o expralne-- thi 1* 1
a CnitW _ZIM ilia
ift", `Vfth~dchj tOd-bond
I U
Met 0000"e", Genterm I . 7mrs Ma
AVzWthods Irk organic -and polywr ohemls-
Card 2/3

ACCESSION NR: AP4013331
try. "...ebullioscopia measurements were carried out with V.V.
Tartarintsev." Orig. art. has: 4 figures and 4 equations.
ASSOCIATION: Institut khimicheskoy fitikip Akademli nauk SSSR
(Institute of Chemical Physics, Academy of Sciences SSSR)
SUBMITTED: 07Aug63 DATE AoQ:, e6Feb64 ENCL: 00
SUB CODS; CH NO ]REP 11ROV: 008 OTIM 003
Card 3/3

N NR. AP4012978 5 .,,1 no
-uzu ~m
i~-Ya- ns-vaWdv V
IR, T. R e r L, A, A
ATIST RA C-1 7~1, e a r ,n awn e t i
T-I

-irf-g." ar, . -h-j-s 1 ~tjwjp-
khirnlchealk~.;y fAlLik, Ak

BERLIN A.A.; GRIGOROVSKAYA, V.A.; PARINI, V.P.; GAFUROV,
Kh.
Local activation effect in the low temperature pyrolysis
of anthracene and bianthryl. Dokl. AN SSSR 156
no.6:1371-1374
is 164. (MIRA 17t8)
1. Institut khimicheskoy fiziki AN SSSR. Predstavleno
akademikom
V.N. Kondratlyevym.

.7
/r7,~Jp4 4t7%j
5W
-TA
I OF I C T A IS
eiectron paramagretic resonance
iction with znql,)trone a t rach iDro I, enzlj'~Q ui' non F-.) op
e c as e o t 'fly -benzenp c,~
P-

man
F MR.
and
Ll;e mec"llp" -,I
v i a i- i en c es assR)
F$E~
'1777,;
212

A~ q'P P N c,
M.
t
stability b1 ymer
ABSTi.ACT: This Author's-Certificate introduces a inethc*.d for
therm.'al staIiiliza-tion
'of- three-dimensional p6lym ah& -,613-mm of ursatmated esters
ers cq?.
-Ov oligdmer.-. P ducts of pyr,~Ivr-lm -r'
7 hermall, -sta)~Ilizers to. -tAm mommer ro
acetylenes ar-p- used, yielding a DIroauct which is stabie -a-,
-ON -
-ASSOCUTI
rl ME, VMS g 6 M, 9 W w W 1=9 9 PP----

'~ACC_NJh:--AP6O039k --SOURCE CODE: UR/0374/6510001005/0145/0148
AUTHOR: Perlin, A. A. (Llvov); Shuter, L. M. (Lvov)
ORG: none
TITLE: Determination of the flow tenperature of olyEersil
SOURCE: Mekbanika polimerov, no. 5,,1965, 145-148
TOPIC TAGS: polymer, polyethylene plastic, polyamide, temperature
sensitive element,
temperature dependence, transition flow
ABSTRACT: A evice or the direct determination of polymer flow
temperature has been
developed. It excludes the,necessity of observation of the
transition moment of the
polymer to the flowing state. The method offlow point determination
by the device
described. above provides reproducible data ever a wide range of
film thickness
and pressure stresses, and ensures also good conformity of results
obtained with the
,literature data.. The possibility'of determining.the nature of the
value of the trans-
ition temperature of the polymer to the flowing state by means of
temperature depen-
dent curves of the transition time is shava. Orig. art. has:. 3
figures and 2 tables
[Based o1a authorls abst7act)
SUB CODE:, 11. SUBW-DATE'et. .26465JI ORIG REF: 007/ (YM REP: 003/
UDC. 676.01.53
L51rd ill
141

BERLIN, A.A.; BELOVA, G.V.; SELISKAYA, O.G.
Studying the thermal oxidative degradation of
Dol~mers with a
conjugated system of bonds. Plast. massy no.8:3-5
165.
(MIRA 18:9)

ACCFZS'aO?,NR: AP5002818
AUTHOR:
Borliq~-A.A.A)m
M
-TI-TLE! 'Pranaration and some trap r-formatiopq of the ~1-1
TOP!C "7A(,S- dehydro-Wortnation. chl'oromr-affln

none
:,.:I -! -,
Submiiar~Lj: Vv
i
NO REF SOV: 008 OTHER: 014
13'. 1
e-c!,;
I

ity ar, e on the phvz
icall ard C49tuical prqpe-'.-ti~-s
-ET-CNI --!z-eierate and change the chemism c., ir-.-'.
~7
~_'; mor; mm

2/2

U C t S 0 f Rn t h I-A Cl 11 t! MI fl W t h -1 ~4 j
Ar or The T,
CiCfio -"-~TOAUCt
MIANCITil, -Nz

, 6, Ir
L 2 9 q -.Cl
!, : - 1, !
1;1-~ ,I .
- 0, . ,
I~i mm i 7,1."i~n - I

RIML IN, A ~ A. j.- P.,'US V 15. 1 0
Effect of local magnetic fields created by paramagnetic
particles on
chemical reactiona. Teoret. i eksper. khIm. 1
no.2-.151-159 mr-Ap f65.
(MRA 18:7)
1. Institut khimicheskoy fi.24ki. AN SSSR, Moskva i
Moskovskiy. institut
tonkoy khimicheskoy tekbnologH imeni M.V.Lomonosova.

77- -7.7771~-~-,--
01~ zi

ACCLSSION NR: AP5004309
I cstv:,Lngtb, butb -iong.-Itudinal and crosEql,,;--
31~- el
in APeclfil: -~!-Pctrllzal -esIstance and P. !~Ilight

BERL71*4, A.A.; DIYAKONOVA, V.?.; TIVIOMIMA, Yo.l.
- 7'~- I . - - II
-` -
Polp-Ster enryllito emiuls!ons as bindnrs for c,-Ilulose fiber
materiAls.
Plast. massy no.405-57 165. (YURA 1.8t6)

rr-/ J- /H-

T F,, p F
A
4 1 L"r -zthod for obtaining oligm, -lass 3 91
,era capable of polyzeriz-ation. W
No. 152821,
An an altorna.
hiph
elsotriml UOUVIty; h -aff are treated a HO tor-narat,--iDa, ,iui
haterocy-clio cczr>o=dq auch 8g W
quinolinat dipyridyl, etc.
ASSOCIATIONt n~ms
Card 1/2

ST
Ik -9",A
;
L

"y
;
on

-jr
T,

k i

polyner, halogenated
0

aeric

t
i

riyc
roqu
none, car, -;s
-

e n - a i ri j n ahigb-mo1ecu1ar-w-ejp-h,,+

,NO REF sov!
000 OTHER: 000

ss-
PRE

1/1
C

ord

6
.L 16509-66 EWTW/WPW/T/~TG(P)~ :-,WW11LM-
___: - /-AN
ACC M t AP6061492 Soma cots i uR/bigiAMCOO/012/0008/0010
AUTHORS A. A.; -Korolev, - G# -V* 11akhonina L, I* ISellskaya, 0. G.'I.
ORG: none
Effect of conjugated polymers upon Rpljmerization(N~,of
oligoesteracrylates
and.thermal. stability of the produced polymers
SOURCE: -Flasticbeakiye maosy, no, 12p 1965t 8-10
TOPIC TAGS: oligqmart-thermal dacox~ositiofi_atsbiliwr additive..
conjugated
polymer- polyester plastic polymerization Metics / ATV-2 thermal
scales, 1.495W
-T
t W-2 1yeateracrylatet MBF-1 polyesteracrylate
I ABSTRACT: Thermal stabilit.040f thre"imensional polyesteracrylate M
was
studied by using conjugated-ther=stabilizers.6 polyphenylene (II),
polyazo-
phenylene (ni)t poin%enylacstylene (IV),, poly-tolane (V)., anthracene
(VI), and
thermally treated (IV) and (VI). Kinetic study of polymerization, of I
was per-
formed according to the method described by G, V, Korolev (Plaot.;
naasyt No* 3p
51, 1963). Kinetic owres of the thermal-oxidative dee sitionlof cured
I were
card I/ UDGi 678.01035

It was established that addition of 5% Of either of the tested
thermal stabiliZ-
ers completely retarded destruction of I. In lower concentratior's
(up to 1%)p
d thernal3,7 treated IV was most effectives It Is concluded that
deactivating abil-
ity of this type of thermal stabilizors increases with temperature,
which is in
contrast to the bahavior of other known stabilizerso Orig,, art*
bast 4 figiures'---
SUB CODE: 07/ SUBM DM: none/ ORIG -W t MQ/ OTH RUt
Card 3/3-

NRILIXOV, '!,F.; GAFI"R(jV, Kh.M.; Gilv"HKOV'All,
FLYUME, NEIL, I D, L.A.: BERLIN A-k
'-.-x---
Influence of paramagnetic e-?nters rin some
ph~(.,,ieal proDertieg of : ;,"
anthracene. Izv. AN 5.1SR. Ser. khim. no.5i932-933
'65, (X1RA 18:5)
InotAtut khimichenkoy fl-dki A-N

"7,
S T LON ';-71:,' UT R 0 0 6
AP
_- 2,
ATT- T I Be r n A A n i t K i a
CBA
TOPIC TAGS- I I i 1 1
All S T PLA CIT i -,v I o r I. d e PVC c h n t ,-I ~l p ri
MR!
t N t~

-I on
Cal Phynica, AcnARrav of S

-'-t 01003-66. W/f tM .
--- ------ UR/OiO/65/0 0/008/0003/0005
AtCESSION NR: AID50195 2 0
678-766.2,01:536.495:543.8.72
Bel aj 0. Sellskayao 0. G
AUTHOR: Berlin, A. A ov
TITLE: Study of the tbermal-oxidative degradation of poLvmers with
aconjugation
system
SOURCE: Plasticheskiye massy, no* 8, 1965, 3-5
1A
TOPIC TAGS: heat resistant polymer, zrgan4c semiconductorl
semiconducting polymer,:
polyphenylene, *po:Lypheny3:vinylene,' 'thermos S~_ Y~
ABSTRACT: A thermogravimetric study has shoun the high
thermal-oxidative stability
of certain conjugated polymers of the polyphenylenej,~nd
polypheffivinylen e.
For example, the weight loss in polyphenylene held r 9.5 hr at 400C
did exceed
5%,. It is postulated that on heating these polymers, in addition to
degradation
processes, 'processes are also possible which involve cross-linking
and the formation;
of segments with condensed riugs. This increases the stability range
of such poly-,
zero. The-authors express their appreciation to V. A. Vonsyanski-v
and V. P. Parini,~,.,
for making the polyphenylenes. avaiiable. Orig. art. has: 4
figuYd?r-and I table. Y,6~-
ESMY
Card

L 2556-M--. EW(m)" WP I WrIAM
AWERFW/k (j)j_
ACCESSION WR: AP5024106, UR/0138/65/000/009/0023/0026
J-5 67~.- 7:539.612
AUTHOR: Shmurak. I. ?~*~Uzina, R. V 1LE' r1in, A. A
TITLE: Certain factors determining the chemical bond formation on the
adhesive-
substrate boundary
SOURCE: Kauchuk i rezina, no.'g, 196.5, 23-26
TOPIC TAGS: adhe sion, adhesive, substrate$ interpolymerization
ABSTRACT: 1 Examination of factors determining chemical bond
formation on the adheslvem-
substrate boundary, with a view toward increasing the adhesion
strength of polymer
systems resulted in the following conclusiog A high adhesion strength
can bt
attained as a result of interpolynerizatio 'a the functional groups
of the adhesive*
and substrate.
"Onium!' interpolymerization, which proceeds with a low aativation~
energy~ and forms no by-products, is of particular intereste This
conclusion was
confii-ned experimentally for cord-adhesive-rubber systemalin which,
e.g., the
adhesrv-e contained but adiene-acrylonitril e copolymers with varying
component ratiop
and the rubber contained chlorosulfonated polyethylene. Thed9se
contact between:;.
the adhesive and substrete macromolecules$ required-for
interpolymerization* can be
acb-leved by making adhesive macromolecular chains sufficiently
flexible. This, in:~
Gard 2/2

-W - -w -"AVW~U J~V.LJS=A, LWU =Jk%wLIO"e$C; AVMLLAO
seniconducting polymer, electron ex ange resin
ABSMCT: An Author Certificate has been issue(I for a preparative
mthod for beat"
resistant polymers, from diazy an r
jeoupounds. To o~ksin a polymer vith redox d Io
excbange prvperties$ b1suizolized benzidinesulfonic acIDB ntieted
with-quinones~
e.g., bbnzcquinone. The-polywr can be used as an esteritleation
catalyA Uhich
simultaneoUbly inhibits resinification and prepolymerization.
ASSOCAMION: none
StMMTND: 22Feb62 ENCLI~ 00
Stk- OODR. OC'k~
no MF SOV.. .606 DMIR ATD PEWS:
car

10878-66, EV1T(m)/F.WP(J)/t ~RPL RM
'ACC NR: AP5028254 SOURCE
4, CODE: UR/0379/65/001/0041(
AUTHOR: Liogon'kiy, B. I.; Regimov, A. V.; Berlin
~.ORG: Institute of Chemical Physicg, AN SSSR, Moscow (Institut
khimitheskoy-fiziki
'AN SSSR)
iTITLE: Preparation and study of stable polyradicalslof semiquinone
type
SOURCE: Teoreticheskaya i eksperimental'naya khimiya, v. 1, no. 4,
1965, 511-518
j
'TOPIC TAGS: quinone free radicals electron paramagnetic resonance
ABSTRACT: The treatment of polygrylenequinoneal(PAQ) with alcoholic
alkali forms
;polyradicals of semiquinane type (MQ), which were identified with EPR
and IR
spectra. It was found that in alcoholic alkali there occurs not only
an oxidation
!of.the hydroquinone form, but also a reduction of the quinone form
of-PAQ-to-semi-:,~_
,quinone polyradicals,.this being due to-the electroh-donor properties
of the
.-hydroxyl-ion.- -The-rate of formation of Mq and their stability in
alcoholic alkalis
ware studied, ard the semiquinone conversions of mono-, di-, tri-, and
tetra-
.phenylquinones were inivestigated for comparison. PSQ isolated in the
solid form,
'washed, and dried under vacuum at room temperature retained a s
'trong EPR signal in
fair for many weeks. They also proved stable an beating in air and in
a vacuum at
.Card 1/2 Y

idy 'of thc'.-
o4vir
to t 6:
otm 0471~.Vlf -.140hilral c oatl- i
0A

.,

bi In electrital.: ibhduct~vity,
'
y

Age
4e and 1-4146
ffgt4

#tM.ICWE-. -'---07 1
'00

Ll~THNSETM, G.T.1 STMOD, Yu,Ms; BERLINp AsAa
1~plioatlon of the adiabatic method for the
determinatlcn of
kinetic and theniodpamlo parameters of processes*
Tooret,
i eksper. khime 1 no, 5t690-04 S--O 065 (MIRA
19c1)
L Institut khimicheakoy fissiki AN SSSR, Moskva,
SlubmittecT
VAreb 81, 1965.

ASUEVA, R.M.; ASErEV, Yu.G.j BMLIN. AiAol KASATOCHKIN, V.I.
Spectral study of the products of oxidation of high-molecular
conjugate polyenes, Zhur. strukt, Wm, 6 no.lt47-52 Ja-F 165.
(W-P,k l8tl2)
1. Thatitut kbimiahaskoy fiz.iki AN SSBR. Submitted November
190 1963.

!_L 1137-M. EWVM)/~T~(c)/WPQ)/I~ W/RM
ACCESSION NR; AP5021600 UR/0192/65/006/004/0649/ig6,1
541. 67
AUTHOR: Gafurov, Kh. M.; Mulikov, V. F. Gachkovskiy, V. F. Parini, .
V. P.
enfelld, L. A. qi.G
iIFLE: Effect of local par-onvagnetic cei*rs on the optical and
photoelectric pro-
perties of anthMea_
SOURCE: Zhurnal strukturnoy khimti, v. 6, no. 4, 1965, 649-651
TOPIC TAGS: anthracene, paramagnetism, pyrolysis, optic property,
photo-
electric property
ABSTRACT: Soluble products of the pyrolysis of anthracene at 450C
were sub-
jected to thin layer chromatography on aluminum oxide and the
fraction with a
mean molecular weight of approximately 1000 was separated out. The
intensity o
the signal in the temperature interval from -15C to 25C obeyed
Curie's law. The
width of the syMirsoetrical electron paramagnetic resonance line was
about 6
oersteds. The elemental composition of the polymer fraction was: C =
92. 98%;
H-5.06%. The anthracene was purified by zone melting and was blended
with the
polymer fraction by mixing benzene solutions of both components.
After holding
Card 1!2

me c
the photocurrent indicate that both of -these quantities are
extremely sensitive to
very small amounts of paramagnetic centers. The symbatic change of
the yields
of -fluorescence and photocurrent with a change- in -the
concentration of paramag-
netic centers permits the assumption that these centers affect these
character-
istics by the same mechanism. Prig. art. has: 3 figures
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR (Institute of
Chemical
Physics AN SSSR) /7
SUBMITTED: 15Feb65 ENCL:'00 SUB CODE: -OGI,=
NR REF SOV: 020 OTHER: 001

13P r In, A, A. Sherle, A. 1. Be' a v a `3
AUT110r,i
SOURCE Vvsokomolekulvnrnyye saved ineu i vav
INK njugatt-d-
NS
N
Sys tem" rei3or t9 the preparation j f cc;,per , i ron and fnq Fnf~v
te t ra-
c A r, nh vP n fiTC F coordina tic n -,cl -,P
u ri r A i i
r a k n c3 w a e r s,I n 8 0 1 u 1) 1 e L :1C
b u ts c, I ub 1 ein concdRS 0 The copper-containing -,).D vmc-.~ uan
s1~ a
2
bu t tho magnegium-cuntcining polymer I o
h SO
~l I VIEVE W-127-l"t

a n j k.

e-1 - n, r.1' n r, ,j -in
rL

I I 1~1 U , m
. - i I'll x "-

A7JTHCjRS-. Berlin A., Asl* P92pva Z. V.; Yano D. M.
v r
ro-.-,ction
t-ha us:
~-,-ABSTRADT-
RRY,
W! ardl-, poly -i~
eno, Z t~a
I eta __Oni6 0-i --47-WT-Giai~ "Was mea-surelalat 'iffie In,itning-of
,illc~n, the of the 1~-, tht lu s-8 itat
Ccfd

- LIOGONIKIYP B.I.; RAGIMOV, A.V.; ASEYEV, Yu.G.;
BERLIN, A.A.
Spectral study of polymeric arylene quinones rnd some
products
of their transformation. Vysokom. Boed. 7 no~4:661-669
Ap 165.
(MIRA 18:6)
1. Institut khimicheskoy fiziki AN SSSR.

CHE"RKASHINA, L.G.; FRANKEVIC112 Ye*L~; YFIMINA, I.V.;
BALABANOV, Ye.1,;
BERLIN, A.A.
Symtheals and alactrQphysical properties of polymerio
phthalocyanines,
Vyzokom6soed. 7 no.7%:L264--1269 J'-L 165.
(MIRA 18:8)
1, Institut khimichesk.:;y fiziki AN SSSR.

1. -i'61647-65 9WT(m)ATJ?(c)1W(J)1T- Pc-4#r-4 HK
f12
XUTIS~WR. AP5015597 UR/0062/65/000/005/0932/0933
541.67+547.672
I Wuroy. 0,11.1 0jcbkovoMY& tartus, Vo P.1
AVMRi tulikov, L 0 - - - J
Blyumonfai'd. 16. A.1 Berlin. A"6
TITLEt Effect of "ramaguatic conpars on: gone of the
pbysical properties of
anthracene
-933
SOURCM AN SSSR. laventiya. Beriya khimicbeakayl, no. 5,
1963, 932
TOPIC TAGSs anthiace a. paramagnetic resonance.'slactron
spin resonance. fluores-1
cone*, pbotoconductivity
ABSTRACT: It has been sbo;m earlier that the.prosence of
local atic center
affects the cbenical babavior of compounds witb c0 j ~ 1
'7.
kbeir reactivity (effect of local activation). The =
Mound that the pre-
ionce of magnetic centers also has a considerable offset
on Vw pbysical proper-
etes of sueb compounds. The soluble paramagnetic
fraction (NW-1000, ISR signal
intensity 2.6 x 1010 spin/&) separated frm the
tbormlysiq products of antbra--
purified by zone molting. Samples of anthra-
can* was introduced into antbracens
cane dopod in this samor contalwA paramagnetic centers
in concentratioss. of
Card _1/2'.