SCIENTIFIC ABSTRACT BUSLAYEV, Y.A. - BUSLER, I.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000307720010-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 12, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

BUSIAYEV., Yu.A.; GORBUNOVAq Yu.Ye.; GUSTYAKOVA, M.P.
Zirconium and hafnium oxo-fluorides. Izv. AN SSSR Otdkhim.nauk
no.2:195-201 F 162. (MIM 15:2)
1. Institut obshchey i.neorganicheskoy kbimii im. N.S.Kurnakova
AN SSSR.
(Zirconium fluoride)
(Hafnium fluoride)

BUSLATEV.*Yu.A.. kand.khimicheakikh nauk
"Chemistry and technology of uranium fluorides" by N.P.Galkin
and others. Reviewed by IU.A.Buslaev. Khim.prom. no.3%226-227
W 162. 1 (KERA 15:4)
(Uranium fluorides) (Mayorov, A.A.) (Varyatin, U.D.)
(Sudarikov, B.N.) (Nikolayev, N.S.) (Shisbko*v, -fiII.D.)
(Krutikov, A.B.)

35588
s/o6 62/00()/003/003/014
B110YB101
AUTHORS: Buslayev,-Yu. A., Bochkareva, V. A., and Nikolayev, N. S.
TITLE: Reaction of titanium dioxide with hydrofluoric acid
PERIODICAL: Akademiya nairk SSSR. Izvestiya. Otdeleniye khin-,cheskikh
nauk, no. 3, 1962, 388-392
TEXT: The solubility of titanium dioxide in hydrofluoric acid, and the
composition of the compounds formed in the solid phase and in solution were
determined. The Ti02 (-0-5 ~o impurities) dissolved in HF, was stirred,
together with the solid phase, for 24 hrs at 25 OC. In order to control the
equilibrium obtained, saturated solutions of TiO2 in HF were kept fQr tnree
months in the exsiccator over KOH. When removing HP and H 0 from the
2
solution, a solid phase was separated which was stirred in the thermostat
together with the solution, and analyzed for Ti- and EF content. Ti was
reduced by means of Zn-Hg, brought into ferric sulfate solution'and
titrated by means of KMnO 4' HF in the presence of Ti was determined
Card Oil

5/062/62/000/003/003/014
Reaction of titanium dioxide with... B110/B101
'potentiometrically. To reduce the solubility of X 2 TiF 6, 4-0 ml C2H5 OH
were added besides KF. The solubility of TiO increases almost linearly
2
with the HF concentration. In saturated solutions, the molar ratio of
fluorine varies between 4-01 and 4-33, as [TiOF 4]2- was formed in the
solution. The first solid phase is about TiO 2* At 25-95-39.60 04 of HF,
TiOF 2.H20 is formed. In a solution with the ratio P: Ti = 4, a change of
the particle number from 1.45 to 1.22 was determined cryoscopically.
Concentration dependence and dissociation point towards
TiF + 2H 0 T-- (TiF *2H L'T (OH)H 01. The degree of
4 2 4 201 'z~ "+ + 'F4 2
dissociation of hydrated TiF 4 agrees with the electric conductivity of
titanium solutions of the ratio F/Ti = 4.2. The steep rise of the molar
conductivity with the ratio F:Ti is explained by the following equilibrium
H [T i F H
H[TiF4(OH)H 20] + HF 5 2 01 ]1+ + LTiF5H 201
H[Tir H 112LT'F~J -- 2A+ + 'T,F~j2-. Two solutions with the
5 A + 'IF L
Card 2/3

3/062/62/000/003/004/014.
B110/B101
tl
AUTHORS: Kharitonov, Yu. Ya., and Buslayev,.Yu. A.
TITLE: Infrared absorption spectra of oxofluorides of some metals
of the fourth and fifth group of the periodic system
PERIODICAL; Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheakikh
nauk, no. 3, 1962, 393-401
TEXT: The character of the metal-oxygen bonds in solid oxo-fluorides of
titanium, zirconium, hafnium and vanadium was investigated on the
following compounds: TiOF 'H 0, VOF -H 0, KNbOF 'H 0, Zro
2 2 2 2 5 2 21
Zr 4F10 (0H)6-3H 20' Zr4 F10 (OH )6 -H 20' Zr4F10 03' ZrF 4' 3H20, ZrF 4' H20,
Zr'F 0, ZrOF , KZrOF '2H20 , Hf4F 0 HfF 4' H 0, Hf 4F 0 HfF 4'H0,
4 14 2 2 12 2' 2 12 21 2
HfF 14 0, Ff0F 2*K2 NbOF5 was obtained by dissolving Nb metal in the aqueous
mixture of HF and H 0 and precipitation by KF addition. The infrared
2 2
absorption spectra were obtained between 0"50-2000 cm- The wide band at
Card c,/5-)

S10621621000100310041014
Infrared absorption spectra of... B110/B101
,-750-950 cm-1 of TiOP 2' H20 was characteristic of the bond Ti-O-Ti-O-U-,
and was also present in ROSO 4'H20. As a wide band is maintained for
anhydrous TiOF between - 750-950 cm- the following structure can be
2
assumed.
- 0 Ti 0 Ti - 0
F F F F
- 0 Ti 0 Ti - 0
Since the frequency of the stretching vibrations is < 950 cm the Ti-O
V
-ond is a double one. A TiO bond is also proved by the small TiO distance
(1-78 ~) in the crystal lattice of ~TiCl2 (C2H5 2 0, which corresponds to
the TO distance (1.80 R) in the crystal lattice of TiGSO 4*H20. For
VOF 2. 2H20, two effects, corresponding to the loss of the two water
Card 2/5

S/062/62/030/003/004/'014
Infrared absorption spectra of... B110/3101
molecules, exist in the thermograph. An intensive narrow band (1001 cm-
proves the stretching vibrations of the V-0 bond. As the force constant
of the VO band is 7.2 mdyne/i, a multiple bond exists. The frequencies at
459 and 517 cm- 1correspond to VP bonds, those of tJ 3163, 3331 and
3500 cm-1 to the stretching vibrations in the water molecules. The
NbOF 2- ion contained in the crystal lattice of K NbOF*H 0 is presumably
5 2 5 2
of octahedral structure, with the 14b atom in the center. An intonsive
narrow absorption band at 928 cm -1 corresponds to the NbO-bond, the
intensive band at 1630 cm-1 to the b(H20). A multiple (:~-2) bond in the NbO
is also proved by the force constant of 6.9 mdyne/~. Since in the
monoclinic zirconium dioxide each Zr-atom is surrounded by seven O-atoms
and the length or the ZrO bond is 2.04-2.26.~, no double bond exists, but
0 0
0 - Z'r - 0 - ZIr - 0. During thermal dehydration, Zr F (OH),-3H 0 (1)
1 1 4 10 0 2
U U
Card 3/5

S/O 62 16 2/000/00 3/004 /014
Infrared absorption spectra of... B110/B101
loses two H20 molecules S-Zr4FIO(OH)6'H20 (11), which again loses
wat er ~, Zr4F1003(111). Tetramers are presumed, and no ZrO double
bonds in 1. In 11 (-'875-975 cm-') ojid III (,v 877 cm-'), Zr-O double bona'
presumably exists. The force constants of Zr=O in III are 6.2 mdyneA.
When heating ZrF 4' 3H2 0 (IV), water is separated and ZrF 4*H20 (V) and then
Zr F 0 (VI) are formed. In air ZrF 0 hydrolyzes to Zr OF (VII).
4 14 14 4 2
Dehydration of HZrF 4H 0 produces HZrF -4H 0 --t (V) (VI) -'(Vii).
F 2 5 2
0 F Zr ZrP 0 exists in the crystal lattice of IV. No ZrO double bond
3 3 N 3 3
exists, only for VII (864 cm-') there exists the zirconyl group. The force
constant of the ZrO bond is here 6.0 mdyne/~. KZrOF 3' 2H20 has the ZrO
double bond (absorption band at 833 cm-1), force constant 5.6 mdyne/9
The
thermal decomposition of ~Hf4F12(OH)4*3H201-2H 20 goes over to Rf4F1202 due
Card 4/5

5/06YD'2/000/003/004/014
Infrared absorption spectra of... B110 B101
to the gradual loss in water. A narrow band at 889 cm -1 correspor(~s to the
stretching vibrations of the HfO group, the force constant is
06.8 mdyne/~. IffF*3H 0 (VIII) decomposes according to:
4 2
VIII - HfF 4'H20 (IX) -~ Hf4F14 0 (X) HfOF 2 (X,)' X and X! h-'-.ve
absorption maxima at 896 and 894 cm- 1. As the force constants are
6.9 mdyne/1, the Hfb group is maintained during the X~ XI transition.
The stability of the 1140 bonds in oxofluorides increases;
Ti(4+)oo the density of the superimposition flow remains con..
stant and the densities k i of partial flows tend uniformly to zerc-,
then 2) at n--~>00 and if at any large t the probability of nc-t, cb,..
taining a call from this partial flow tends to unity, then the d-"-c-
tribution of superimposition flow P(k,t) tends to the Poisson di,F--
tribution since knowledge of the asymptotic bebavior of superimp-
sition flows in an applied problem solution --is insuffic:ler-t. The
author considers the distribution laws of superimposi.ta-on of 2 an,,.i
Card 2/ 4

50
S/56 61 000/009/003/012
Superimposition of stationary ... D'201YD302
n independent flows. For 2 independent flows the required density
function fk(z) is derived as
1
00 00
i~(Z) = f(l f(2) (x)dx +f(2)(Z) f(l)(x)dx
1 1 )(Z) 1 1
z
and for n independent flowe a similar reasoning leads to
00
n n
f(V)(,) fW (x)d-x fe3)
fl,(Z) = ;~ 1 . F1
v=1 i=1
i/V
Card 3/4

33503
S/562/61/000/009/003/01?-
Superimposition of stationary ... D201/D302
These equations are then used to solve certain examples, from wh'-I-h
formulas are obtained which are stated to be useful for solv--,ng
mass-service problems by statistical methods. There is 1 Soviet-
bloc reference.
Card 4/4

BUSLENKOI N.P., doktor tekhnicheskikh nauk, inzhener-polkovnik
. - -.,- ---- - -- -------
Grandiose prospects for the development of science and technologf.
!!est.protivo-%rozd.obor. nfi.10:20-2/+ 0 161. OMA 15:2)
(Science)

PHASE I BOOK EXPLOITATION SOV/6185
Busldnko N P D. I. Golenko, I. M. Soboll, V. G. Sragovich,
--aflu luo R. 0hreyder
Metod statisticheakikh ispytaniy; metod Monte-Karlo (Method of
Statistical Testing; the Monte Carlo Method) Moscow, Fizmatgiz,
1962. 331 P. (Series: Spravochnaya matematicheakaya biblio-
teka) 22,000 copies printed.
Ed. (Title-page): Yu. A. Shreyder; Eds. of Series: L. A.
Lyusternik and A. R. Yanpollskiy; Ed.: V. D. Rozenknop; Tech.
Ed..: V. N. Kryuchkova.
PURPOSE: This book is intended for mathematicians, physicists,
and engineers engaged in the solution of problems in applied
mathematics. It can also be used by students and aspirants
studying the Monte Carlo method. Knowledge of the basic con-
cepts of the theory of,probability is required for reading
this book. Some knowledge of random events and quantities
and their probability characteristics is desirable. Acquaint-
ance with the normal law of distribution, Lyapunov's theorem,
Card 1/0 0-

.-320/"u 2,,"144/ 005," 001/ 017
S
/ v
B125/B104
Simulation of nroduction nrocesses with electronic
di~-,itLil comnuterz
1962,
nauk SSSIR. DoIclady, v. 144, no, 5,
1 oc 6
of algorithms to allow of simiulating assembly-line
r; ~I ir",
c -c f* on )_--oc c~ ~i t helectronic digital computers was studied.
of a nrodaction process makes it possible to
C C- 1-.-: iC tC, 11U.Joer of workpieces, semi-prodacts, rejects,
nt c!rr ut i o n zof 'Une ~)raduction process, and idle time of -machines, etc.
instant of time, e properties of a semi-product can be described
y A
by a ce.-tain nu;.~ber of ~)arar.-.eters and indices. The production process
i., rep:,--sen~c] ito of a finite number of the follo-,,in,. o-.)e.,,ations in
suce,,3.,ion: (1) orocessink7. of semi-proiucts; (2) L3.30mbly of workpleces;
cin:rol processes. 'Ihe follozin8 process is simulated for illustra-
t ion I'_)n an assembly line the machine parts are a3sembled from
lar"
- . 1

3/020/062/144/005/001/017
Sii.iulation of produci;ion -)rocesser, B125/B104
-)L.rts. `,'he -Individual -jarts nos. 2, 3, ..., I are then
4 ,
u;,jn workp-Jece no. 1. The assembly line displaces workpiece
no. I L-. such manner that 'the i-th assembling operation of the i-th
U
workr,iece begins'at the instant tj - ti,:, where k - j+(j-1)l+i-1. The
inst-L-it.,, t -are detormineCi by the nature of the prod,-ction -orocess and
ij
used to simmlate that mentioned above can be rour~lhly
-.(,(PI; A,; Nt'; A,; R; 'Ps""; ](6; A!"; Poi,2,; K,i; Kr'6; 01K~,-, A-'6.
a s t 1-1 e
is the of t,' and A, is their stor. .2; i.
co,,.-. ~arison t T (T = duration of the production process;); A is 'U--e
1j 4
-,rocossinr, and output o--:~ the results of simulation; 11 is the comparison
5
K and derote the additions j+1 and i+1, respectively; the
6 K66
7-j or a 1 o ~, P re-ola6es the simulatin- sub-algorithm. of the i-th assemblin
6 o i
operz,.tion; K I's t' e coun'ingr ooerator of the -,,orkniece3 that have
Card

`102n,162 4 /005 /Oc" 1
i --.n ia i; -~ on of j,.-o, I uc t i on. i,.r3conL'es ... B125/B104
i-th aLr;emblin- on crat ion ; and K, i
Is the countinr
o., e r: tior .1~ i lit i~rvkl") u-cfferod by the i-th 'operat i 01-1. 'Ihe
o-.)erator can be re-,)re:3ented, for example, by
Ae, A99- 15- 21 Pio,~ -, P11 K11" 01.4" P14;10" K1,16; 110";
"; 10 pt22- A10- L86A - X20
A17: P18,2j; (Pig -23A2o; A21; led, 241 22, :3.
"he aii-,orithmu for other production processes require cor.-
i . I ~ I plex
;iodels -iji'h n
ore complex aleorithms. The procedure
consi6oz-ed here can be used for calculating the parameters of machines
:7n.3 prohaction processes.
R i D
SU'37'TTT-'--,D
June 5, 19619 by A. 1. BerE, 11cademician
Ma
?: y 11 , 1961
Card 3,1",

BUSLENKO', N.P. (Moskva)
Contribution to the theory of complex systems. Izv. AN =R.
Tekh. kib. no.50-18 S-0 163- (MIRA 16:12)

BUSLEENKOY N.P. (Moskva)
Modeling of IndustrIal processes using electronl,- dl.gltal cmputers.
Probl. k1b. no.91189-22.0 163. NIRA 17,-'LO)

ALIYEV, G.A. (Moskva); IBUSLTNK~~_, N.P. (Moskva); KLIMOV, C.P. (Moskva); NAZARENKO,
A.I. (Moskva); POLYAKOVA, N.A.; DATSKEVICH, R.T.;
GAYDABUKA, L.A.
a'
Modelina of the operation of an automated furnace m~--chine for weld*
pipes. Probl. kib. no.9:211-240 163. (MIRA 17-i)0
1. Elektrostal'skiy zavod tyazhelogo inashinostroyeniya (for Polyakova,
Datskevich, Gaydabuka).

pt! or r
t t a-' Computer, -1--,C r
7 tal r -j:r, -

A c (7 EC;S T ril !jp
'V E171.
Forsword
Intruduction
Ch. to the
jCh, III. Modeling algorithms and their reallzition in djcjt%2
7; R,,mpr',
r

7 - 7~,
C'h, ITIN. Modeli:ig production operntions
furnAce-weld&J pipes ~2u
V,
-Card

ACCESSION NR: AP40Z8971 S/OZ80/641000/00Z/000310011
AUTHOR: Buslenko, N. P. (Moscow),*, Yurkevich,.0. M. (Moscow)
TITLE Operations with aggregates in complex eye terns
:SOURCE, AN SSSR. Izvestlyal. Tekhnich~skaya kibernetika, no. Z, 1964,. 3-11
r
TOPIC TAGS: cybernetics, Information transmission system, information I
transmission A system
ABSTRACT: A class of complex systems was defined earlier by the author
(AN SSSR. Izvestiya. Tokhaicheakaya kibernetika. no. 5, 1963) and named
"A-systems. 11 The primary elements of the A-systems - the aggregates - are
connected, from the information-trans min sion viewpoint, by the relationsof
succession or subordination. Algorithms of various aggregate constructions are
determined by developing a system of algebraic operations with the aggregates
regarded as elements of a met., Concepts of equLlity and equivalence of the
Cord

ACCESSION NR: AP4028971
aggregates are formulated. Multiphass and multichannel A-systems are J'.
regarded as aggregate constructions; product- or convolution-of -aggregates
operation is considered, and Its characteristics are investigated. This operation',
permits finding an equivalent aggregate with input and output poles and internal
functions of the A-system in question. For multichannel systems a summation:
or uniting-of -aggregates operation in developed. Orig. art. has; 60 f6rmulas..
ASSOCIATION: none
SUBMITTED: l3;an64 DATE ACQ: 30Apr64 ENCL: 00
SUB.CODE: DP,,~ IS NO REF SOVI 004 OTHERt 000
Card, 2/2 Fe

FITIUVA, L.N.; BUSLENKO, P.S. (',-faskva)
Char,,c-t,eristica eird diat7loatic dgnific,,-rcr~ -)f' c-as',A-c-
in mitral sterlo.-As with rcgulr-r rhytlza ,~f mtrdl - c
Klimmed. no.7:96-:1.02 161.
1. Iz labomtorii furlitsionallroy diajt,,v-,stih!-
nai* G.G. Gellshteyn) Instituta gTriidn(,,,,r khivirf-ji -N-ll 553R
i: C C'. .
Wir. - prof. S.A. Koleanilcov, n-..uchnyy inukovc,61tel!
A.N. PrIculev) i klipiki fakiilltotskoy lchinLrgi-I (sav.
A.A. Dusalov) pediatriche.9kogo f,-Jailltatr- II
meditsinskogo institute.
(MITRAL VALVE-DISEASES)

BONDARIV, I.M.; BUSLICR, I.V.-. ZHIGALINA, L.I.
Method of rapid preparation of electrophoregrams [with su-nAry in
Snglishl. Biul.ekap.biol.med. 44 no.8:114-118 Ag '57. (MIRA 10:11)
1. Iz kafedry patologicheskoy fiziologii (zav. - prof. A.H.Gordivenko)
Rostovskogo meditainskogo instituta. Prqdstavlena deyetvitelinym
chlenom ANN SBSR N.A.Rozhanakim.
(ELICTROPHORESIS.
rapid prop. of eleetrophoregram (RUO)

SOV/120-59-1-26/50
AUTHORS:Blokhin, M. A., Busler 7 1. V. 7- Kramarov, 0. P., Chernyavskaya,
TITILE: The Use of a Monitor in X-Ray SDectral Analysis (Primenen-iye
monitora pri rento-eno-spektral:nom analize)
C>
PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 1, PP 106-111
(USSR)
ABSTRACT: In the continuous recording of intensities in X-ray spectra
by means of ionisation or scintillation counters, a hi-h stab-
ility source of the radiation is necessary. At the same time
it is difficult to ensure a high stability in the anode volt-
age at the relatively hi,-,h power used by the tube. This prob-
lem is particularly complex when the anode current has to be
varied within wide limits, for example, in the measurement of
the intensity ratio of a very weak a-ad a very bright line. For
this and other reasons the present authors have developed ineth-
ods for measuring line intensity ratios either when the inten-
sity is directly stabilized or when the source of the radiat-
ion is not stabilized at all. Ionisation chambers or -eiger
counters are used for this purpose as monitors. The device i2
shown diagrammatically in Fig 1. In this figure 1 is the
anode of the X-ray tube. Primary X-rays leaving the anode are
0
Card 1/3 incident on the specimen under investigation 2 and an addit-

SOV/120-59-1-26/50
The Use of a Monitor in X-Ray Spectral Analysis
ional specimen 3 Fluorescence radiation leaving
, 2 is
analyzed in a spectrometer which uses a geiger counter as the
detector. The radiation from the additional specimen 7) enz-
ters the monitor 7 through a collimator 4- . The monitor
is in the form of a geiger ,counter. The additional sDecimen
is made from a Dure element (or its oxide). The stabillizat-
ion is ensured by using the output signal of the monitor tr_-
stabilize the cathode supply of the X-ray tube. The system
is completely automatic, the control --ircuit being shcrrn in
Fi- 2. It is shown that the use of a monitor in conjunction
with good collimation of the direct fluorescence radiation
from the additional specimen enables one to carry out accur-
ate measurements of X-ray intensities without any st-abilizat.-
ion of the supplies. Fig 4 shows a typical spectrum obtain~~d
with this instrument. Fig 3 shows the root mean squo-ae erroi
in the intensity of the K (x line as a function of the atomir- n1im-
ber Z of the specimen under investigation, the aaditional
specimen being Ni It follows from this figure that if -3,
Card 2/3

SOV/120-59-1-26/50
The Use of a Monitor in X-Ray Spectral Analysis
relative error of 3% is sufficient (the nujifDer of counts taken
being sufficiently high, i.e. the statistical error being, low)
then the atomic number of the specimen under investigation may
differ from the corresponding number of the additional specimen
by 4 . Hence altogether nine neighbouring elements may be
investigated whose atomic numbers are symmetrically placed on
either side of the atomic number of the additional specimen,
If the relative statistical counting error does not exceed
491o,then for the above 3% the final relative error would be
less than 5%. Thus almost the entire spectral region normally
used in analysis by long wave spectrometers may be covered.,
using a single additional specimen, for exam-c)le, a chromium
specimen. Typical results are shown in Fig 4. There are 4
figures, 2 tables a-ad 12 references, of w1iich 8 are English,
1 is Japanese in English and the rest are Soviet.
ASSOCIATION: Rostovskiy-na-Donu trosudarstveiinyy universitet (Rostov-
na-Donu State University
SUBMITTED: January 18, 1958.
Card 3/3

SEMENOVO A.D. _
Stable amplifier for measuring the pH value of solutions with a glass
electrodt. Gidrokhim.mat. 34:157-163 161. (MLRA 15:2)
(Amplifiers (Electronics)) (Hydrogen-ion concan'.ration)
(Electric measurements)

STRADOMSKIY, V.B.; BUSLER, I.V.
- - -----
Small-base apparatus for measuring weak3,v active -radiation.
Gidrokhim. mat. 35:177-182 163. (MM 16:7)
1. Gidrokhimichaskiy institut, Novocherkassk.
(Water--Radioactive properties)