SCIENTIFIC ABSTRACT DOMBROVSKIY, A.V. - DOMBROVSKIY, K.F.
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CIA-RDP86-00513R000410910014-1
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December 31, 1967
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SCIENTIFIC ABSTRACT
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D014BROVSKIY, A.V.
Maerwein teaction (haloarylation and arylation of unsaturated
compounds with aromatic diazo compounds). Reakt.org.soed U:
285-373 162. (MIRA 1516j'
(Unsaturated compounds) (Diazo compounds)
DONBROVSKIYP A.V.; ZOLOTUKHINA, K.G,,; (,'ANUSHCHLK,, N,I.
Complex compoundo of coWt aul copper thiocyanates and antimony
and bismuth iodides vith 4,-I;~-liLperidino-2-metbyl-l-phonyl-2-
butene. Ukr.khimozhuro 28 zi).4459-461 162. (KIRA 15:8)
1. Chernovitakiy gosuda.,rotvennyy universitet,
(Complex cosWunds) (?btals--Ana3.yeis)
DOMBROVSKIY, A.V.; @ALIONP Ya.G.1 TASHGHUX, X.G.
Haloarylation of unsatw@ated compoluWa by aromtic diazo
compounds. Faft 3,4: Synthesis of e),-l -mothylatilbenes.
Zhur.ob.khim. 32 no.2:&)3-607 F 162. (MIRA 15:2)
1. Chernovitakiy gosucbLrstv9nnyy universitet.
(Stilbene)
DWROVSKIY, A.V.; GANUSHCHAK, N.I.
Halogenation-of unsatw-ated compowds with aromatic diazo compotmda.
Part 16z Synthesis of L-e-vl-193-penitadienes by arylation of piperylene.
Zhur.ob.khim. 32 no.6t:LS8840P Je @62. (MIRA 3-5:6)
1, Ohernovitskly gonudaretvemyy',wAversitet.
(Piperylene) (Diazo compounds) (Pentadiene)
DOMWMKIY@ A.l[.,&--SHEVCHUl.v M.Iq KRAVEM., V,?,
Preparation of c(-Iwowethyl aryl ketones by bromination. of etbyl
aryl ketonea with dioxane dibroudde. Zbur.ob.khim. 32 no.7s2278-
2281 JI 162. (MM 15:7)
1. Chernovitakiy gooudarotvennyy universitet.
(Ketone) (Bromination)
DCHBROVSMp A. V, L T
jama, K. o.
HaloM,lation. 6f-unsatumte,d compounds vith aromatic diazo
compowids. Pt:r-.t 17: Arylation of o(-chlorostymne and pro-
duction. of tdlans. Zhur. ob. kbim. 33 no.1:165-170 163.
(MIRA 16:;l)
1. Chemovitakil poudarat-rennyy univeraitat.
(S"ne) (Diazo compounds) (Acitylens)
SHBWHUK,, M.I.; DC,MROVSM A.Y.
Freparation ofVA_-mowbrozomethyl aryl ketones by brominatiou of
methyl arrl keto-fies in dioxans. Zhur.ob.khim. 33 no.4:U35-1136
Ap 163. (HIM 1645)
universitat.
(Bromination)
ZOLOTUKHIIIA.. K.G.; GANUSHCHAK, R.I.; YUKHOMKO, ILK.; !2T!jW
@M @A-
Tertiary aminea and quaternary isalto based or, 4-chloro-l-aryl-Z-butenes
of secondary and tertiary 'heterocyclic n1trogm bases. Zhur.ob.khime
33 no-4.-:1222-1227 Ap 163. (KRA 16:5)
1. Chwrnovitskiy psiudarstvennyy universitat.
(Amines.) (Heterocyclic compounds)
DOMROIISKI &.V-J, SHEVCHMs 14-L
Synthesis of aroy.~nOthylonstriphsaylphoopboranes. Zhur.P@Ahim- 33
no-4:1263.a269 Ap 163a (MIRA 16:5)
1. Gharnovitskiy gosudaretvannyy univeraftet.
(Phosphorane)
YUKH)MENKO., M.N.; GANUSKIUK, N.I.; DOMBROVSKIY, A.V.
Synthesis of 1-trylhiten~Zbtldl,ethylmaloiiie esters and 1-arylbuten-
2-ylacetic acids fron ch orbaryl butenes and sodium malonic aster.
Zhur. ob, khim. 33 ni).8:2528-2532-Ag 163. (KIRA 160.1)
1. Chernovitakiy gosudarstvennyy universitet.
GA.NUSHCILIK, N.I.; DOMI]ROVSKIY, A.V.; VISIDBITSKAYA, O.A.
Syntheses baved on diene condensation. Part lt 1-Methyl-4-
arylanthraqW-nones. Zbur. ob. khim. )@ no.8s2532-2534 Ag 163.
(MIRA 16:11)
1. Chernovititkiy gosudarstvennyv universitoti
YUKH3WIrIM, M.M., GAWSIMIAK, N.I,-, DOWROVSKIY, AN.
Synthesis .)f 1--arvlbuten-2-ylacetyljicetc,tios. Ukr. khim. zhur.
30 no.6v616-618 164. (MIRA 180)
1. Chernovitskiy goqudarstvennyy univeraltet.
DDNBROVSKIY, A.V.; SMCJIUK, M.I.
Preparatiop of vinyl aryl. ketonns by Wittig reaction from aroyl,
methylar4triphanylphosphorane and paraldehyde. Zhur.ob.khim. 34
no.ltl92-196 Ja 164. 09RA 170)
1. Chernovitskiy gosuclaretvenrqy universitet.
SIONCHUK, M.I.; DOMBROVSKIY A.V.
- :-.1
Preparation of 2-vinyl furyl- and 2,-vinyl thienyl ketones.
Zhur. ob. khim. 34 no. 3:916--919 Mr 164. (MIRA 17:6)
1. Cherziovitskiy gosudarstvemyy universitet.
NAIDAN, I.M.; DOMBil)VIKIY, A.V.
........ aw, ..... 61,11"low"W
Nea method for prelparatior :)f aryl tic ac-lcs.
ob. 'him. 34 no. 511469--@473 iAv @64. @ lqFA i . :
1 C ierncv-!tskiy gosudarour-nn,//
I
"'V.
I @ r, @@ @ - . , @
Preparation of i9or-ropcr 1 aryl kv@-)nes t@y tr& - lt-,;
71111r. ob. khIm. )4 no. 5$14'73-1417 '.y 16,@. (i-"@ :1 @
1. Chernovitakiy gogadustven.-W ur.,-;nrsJIt;,t.
GANUSEHAK, N.I.; YUKHCKWKOp M.M.; STAMIICHUK# M.D.; 2TBFn!.S!.IY A-V-
Haloarylatico of unsaturated compounds with aromatic diazo
compounds. Part l8sCbloroarylation of diisopropenyl. Zbur. ob.
khim. 34 no.7t2238420, Jl 164 (MM 17t8)
1. Chernovitskiy goemdarstvannyy universitat i LeningradislAy
tekbnologicheakiy institut imeni Imsoveta,
1,
PA.-ITUSHAK, N.O.,-_@OMOVSKrr, A.V.; ROGOVIN, L.I.
Haloarylation of misaturated compounde with aromatio diazo
ampounds. Part 19:tChloron7lation of dL -ohloroaorylon it rile,
Zhurt ob. khime 34 no.7t2243-2246 Jl 161+ (MIRA 170)
1. Chernovitskiy g-)ffudaretvecnyy universitat,
SIIEVCHUX, M.I.; GANUSHCHAK, N.I.; A.V.
Syntheses based an diene condensation. Part 2tCondensation
of vinylaryl ketones with some conjugated diene hydroamrbonse
Zhur. ob. khim. 34- no.7t224?-2250 JI @64 (KM 17 W)
1. Chernovitakiy gosudarstvennn universitet.
SHEVCHUK, M.I.; DOMBROVSKIY., A-.V.
- wwfGmmwwk4j%wmjmh'-"
Ultraviolet speatra of aroylalkylenetriphenylptiosphorane. Zhur.
ob. khim. 34 ito.8.-2717-2718 Ag 164. (14IRA 17:9)
1. Chernovitsl:iy gosularstvemyy universitat.
GAIWSKJi@i
,.N.I.; YUKHOMEYKI), M-M-; ROVIAGA, R.I.; DOMB.MSKlY A.V.
Part 3: 2-Methyl-ldryl-
5yAtheses based on diene condensation.
and 2,,3-dimethyl--,-rylanthraquinones. Mite ob. thim. 34 no.8:
V18@-2721 Ag 164. (MIRA 17:9)
.1. Chernovitakiy gosudurstvennyy universitet.
4
PASTUS"K) N.O.; DOMBROViAlY, A.V.
Haloarylation of unsaturated compounda by aromatic diazo compounds.
Part 20: Cbloroarylation of ("V,-methylacrylanitrile. Zhur. ob. khim.
34 no.9:311.0-3115 S 164. (HIRA 17: 11)
1. Chernovitskiy gosudarstvennyy universitet.
NAYELkN, V.M.; DOMBROVSKIY A. V
to
vmw__, i@o
Haloarylation of unsaturated compounds by liazo compounds. Part 21:
1,1-dichlorc)-2-(p-nitrophanyl)athane and p-nitrophenylacetaldehyde.
Zhur. ob. khim. 34 r.o.10:3351-3352 0 164.
(MIRA 17:11)
1. Chernovitskiy gotiudarstvennyy universitet.
DOMMOVSKIY A.V.; TASHCHUK, K.G.
Haloarylation of unstiturated compounds by aromatic diazo compounds.
Part 22.- Mechanism oj-.' arylation. Zhur. ob. khim. 34 no.10:3353-3354
0 164. (HIPA 17:11)
1. Chernovitskiy gosudarstvennyy universitet.
N
.L 38289
BOW/.
7
A=SMN:ICRI
AP50110
Drovski, Al A-
TITLE: I -To".Pht hajorj.@HA_Me th r].*n* 1WjPjjen7jVhoWP7aoranCe on the baals cif P-
-diethylbonzene@
SOUR= h4her W.6il 41 -y 3@9@ndeli 1964, 3741-3743
Zhurnal. 41be :j
TOPIC TA(S: benzen;@, adiati "tia @@pnjc compound,
phosphort is co@j)ot@ad
,bstract The7'raaction'of- at 41 in sahid usacetic acid:wL
A L _y io th
bromine ; 1roduced a1ups, which reacted
trjphen -1phojT�int'ko J'orm a d Lq uaternary sal bia-;1pha,a1?ha'-tr0har_Y1-
Iphosphop.u= P-:aLdcetT1 bromide; the Litter reacted readtly with sodian sthylate@
undergoLig dehydrobominatLon sttt &Lvirg p-terephtha I oyl -bi &-me thy I ene tr ipbenyl -
phosphori,ne. The latter, inter,icting with 'benza I dehyde, gave p-bta-ainiawyl-
Ierqzene. which was &Igo produced by condeneatton of p-di.acetylb,anzena wLth
benza I del iyde. The diketorm @ ha3.,a ater of the product i4aa corif i rw-4 b y t to forz2,
hae '7 7arm
tion of -his-phenyt -or ---2,74-tirtLtropht;nythydrtrortes.' Orig tLrt - U2^3
Card
3
;. 1. - - . @; )I : - ., *-@' ."I i. 4 1. i -, 1 ,., ': @
PASTUSHA1, N.O.; POM@ @J.
Production of sors unsabirated aliphatic-aromatic aldehydes by
the reduction off-arylaarrlic nitrileB. Zhur.org.kh1m. I no.2s
323-325 F 165. (MIRA l8i4)
1. Chernovitakiy gosudarvtrennyy Univeraitet.
SENYAVINA, L.B.1 SHEYNKER, YU.N.; MELTOVA, V.N.; DOMBROVSKlY A.V.
smv-olfmv M.I.
Infrared spectra of aroylmi.h;rlenetriphanylphosphoranes and
their salts. Izv. AN SSSR. khIm. no.5s895-898 165. (HIRA 180)
1. Iiiatitut khimii prirodnykh soyedineniy AN SSSR.
KABACIINTK9 M.I.:: MASTRYUKOVA, T.A.; WIRWYEVAt T.A.;_WT@qYSKUP -A.V.1
,%T.VGHUKO M.I.
Conjugation in the systems with a tetrahedral phosphorus atom.
Part It Substituted ben soyltriphe ro,lphosphinome thyle ne a. Teoret.
i eksper. khim. 1 no.2t265-269 Nr--Ap 165. (WRA 18:7)
1. InstitiA elementoorganichoskikh soyedineniy AN SSSR, Moakva@
i Chenovitskiy gosudaretvennyy universitet.
11ASTUSHAKs N.O.; D(*IBROVSKIY, A.V,; MUMOVA, A.N.
Haloarylation of unsaturated ewpounds by aromatic diazo com-
pounds. Part 23: Wn,-oarylatior. - c4h-chloromethylacz7late and
the rcduction of Of--,nsaturated acl"Is and esters. zhur org.khim.
p -(o5- ( IRA 18W
1 no.31572-575 M,
1. Chernoviti3kiy gosuc'Wrstvennlry universiWt.
TOLOCHKOP A.F.; TOMBROVSKlY, A.V,
@-p -unsat.iratpd r;(@Ida r,7 the
Synthenla of et@l esten3 of
PO-olefination methrul. Ukr.khl@a.irthtir. ';I i),-,,.2t,.2(.'-.223 165.
(MIRA 18:4)
I., ChernavitEikLy gosudara LventV7 up-!,. ri,
GRIGCIREIIKO, A.A.; .3HEVLIIUX, M-L; DOMBROVSHY, A.V.
Bromo derAvatives of aroylmethyle,nittriphenylphosphoraneis. Zhur.
ob. khim.'35 nct.7sl227-1231 Jl 165. (MIRA IM)
1. Chernovitakly gosudarstvenW wtiversitat.
NAYDAM, V.M.; DZUMEI,ZEY,, N.V.; DOMBROVSKIY, A..V.
Haloarylation of unsaturated compolunds by aromatic dIazo mramir.
Part 251 Chloroarylation of vinyl chloride,
arylethants, 0-chlorostyranes, and 2-ax7lasthy.Ldioxalanea.
Zhur. org. khim. 1 no.8tl377-1383 Ag 165. (MIRA 18s.U)
1. Cherno-vitakiy gonudarstwennyy -an-1veraitat.
NAYDAY, V.M.j-MMajOvSKrT,_A.V.
Haloarylation. of unsaturated compounds wlth aromatic diazo
coarpounds, Part 281 Chloroarylat.,Lon of trichloroothylf..ne,
lpltls2-letrachloro-2-arylethanstip~Xt,4 p-trichlorostyrones,,
and A A -dichlorostyrones, Zhwe org. khim, I no.llil998-
2002 N 165, WHA M12)
I* Chernevitakiy gosudarstvannyy universitet. Submitted
Deoember 19, 1964.
TASHCHUX9 K.G.-, DOKBROVSKIY, A.V.
Haloarylation of unsaturated covp)undo vltb aromtic diazo
eompounda, Part 271 Cb1oroarylation of styrene, Preparation
of atilb3nax. Zhur. org. khim. 1 no.Utl995-1998 N 165*
1 (MIRA 18sl2)
1, Chern.)vitskiy gosudarstvenrWy universitet. Submitted
December 19, 19649
R
1. 3070-7-66
UR/0062/65/000/005/0693/069
F;@CC NR- AP6012080 ;CURCE CODE:
0
AUTHOR. Senyavina- L. B.; Sheynker, Yu. N.; Zheltova V. N., D A* Vo 0-
mbrovskizi
1`.@Tj e -entf-;eva, T-
Shevchak, W.--T-.-,--Kk-achnik, ff.- I.; Mastryukova, -R-1
ORG: Institute of the Chemistry of Natural Compounds. AN SSSli (Inutitut khimii
prirodnykh soyedineiLty AN 6,95R)
TITLE : infrared spactra of arovli~iethylenetr:Lp~errLlphot3.phoran(--s- and their salts
SOURCE: AN S,SSRo Izvestiya. Seriya khimiclieskaya, no- 5. 1965P 895-898
TOPIC TAGS: IR spectrum, organic salt, organic phosphorous compound, electron doncrp
cyclic: group
ABSTRACT: The integral intensities of the carbonyl abBorption in the infrared
spectra of aroylmotltylenctriplionylpho.,jphorant!o (in which the carbonyl group is
bonded to a phenyl ring) and their salts wera measured. The data were considered
.from I;ho otandpoint of elec'tron donor and electron acceptor properties of the
phosphorus atom and the aromatic rings of tho aroyl group, its well as the influence
of substituents in @%e aromatic ring on the absorption intensity. The addition of
an aromatic group to the carbonyl in phouphoranea led to a decrease in the frequency
and intensity of tha valence vibration of thii carbonyl group in comparison 4i-th the
corre3ponding aliphitic derivatives, evidently no a result of the functioning of
.the aromatic ring a3 an electron acceptor, competing with the carbonyl group for
.,electrons from the atrong electron-donor pho3])horua atom. The frequency and in-
rnrd 1/2 UDC: 543.422
L 307-97-66
ACC NRs AP6012080
jensity of the C=O vibration are also detemined by the configuration of the mole-
-Cule, detemined in turn by the size of the nubstituent at tho carbonyl, group, In
phosphorane salts, the tatracovalent positive phosphorus plays tho role of an
j.elec-*&on acceptorp resulting in a sharp dro:? in the intensity of the C=O band in
:compirison with ph,)aphoranes. The absorption bands in the region of 1317-1390 cm
,foriirylmethylonot-riphonylpliouphoranes and IM-412 cmrl for aroylmothyltriphanyl-
I
!phosphoranea were tentatively assigned to tmt vibration of the P=C band. Orig. art.
Nis: 2 tables. 'J PRS I
SUB CODE: 07 SUBM DATE: 20Ju164 ORIG REF: 005 / OTH REN 004
CnrA
SHEVCHUK, M.I.; GRrGORENKO, A.A.;-@!g-jB40V
A.V.
syrLheol.q of G