SCIENTIFIC ABSTRACT KALECHITS, I.V. - KALECINSKI, J.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000620020013-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: April 3, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

H I II iH 1
Hmp
11 w a
--n
J,
:7
-IL,
a
111 In, k I
2e -2' - C71-?NT !7A T, OFF C 2 Or, A R,n
V74 TXV T-EITTERATURS,* ~J '1'v

FIMR, L.B.; UISCOTS, I.V
Composition, separation, and utilization of pyridine tar bajeec.
Trudy Vast.-Sibofil.AN SSSR. no*3:72-78 155. (nu 9:4)
(Coal-tar products) (Pyridine) .

;_!i-, INJ i-
4;i
WA
FA t::il
N
KALECHITS, I.V.; STRAKROTA, K,A,; SKVORTSOV, Yu..K.
Composition of the products of destructive hydrogenation of benzene
in presence of high-temperature catalystp. Trw1y Voot.-Sib.fil.,AN
SSSRO n0-3'.88-93 155. mu 9 14)
(Benzene) (Hydrogenation)

IMORITS, I.T.; XONDTA, L.M.; BLINDY, V.N.
---------- "Mow"W,
Mechanism of the hydrogenation of benzene over a mickel catalyst.
Trudy Vast.-Sib.fil.AN SSSR n0-3394-98 155- (KERA,9:4)
(Bonsene) (Hydrogenation)

TA C ITS, I.Y.; XATWVA. L.M.
% Chemism of hydrocarbon degradation in destructive hydrogenation.
Trudy Tost.-Sibofil.AN SSSR. no-3:99-104 155. (wLRA 9:4)
(Hydrocarbons) (Hydrogenation)

TALICCHITS, I.Y.; POPOVA, V.I.
Use of chromatographic adsorption alway2le In the study of pri=Lry
tare and of the products of their hydrogenation, Trudy Kom.Anal.khim.
6:97-121 (MM 9:5)
1. Tostachno-14birskiy filial AN SM.

LL
il-li: It

pilli
Of a,..C-tmctlv
ml
..,f Li :j

iv

dvi

It

z -1.
I ltfl-17t~-.~, I
!
; , :~=zT~t
i

FMMIMmmm, mmirm"Ir'"t I M.
I I Mil
Till Jilt N -IC
L The ir
ChoraiOlli Tochno-109Y lincrals.
b".-%^ntana O-f So).Jd Fuel N

SOVI 65-.59-7-9/12
Irrvestig.ations of Chinese Scientists in the Field of Destructive
Hydrogenation of Fuels.
and 48 Chinese References*
ASSOCIATION-.Vostoohno-Sibirskly filial AN SSSR (The East Siberian
Branch of the Academy of Sciences of theUSSR), and
Otdeleniye tekhticheskikh nauk AN Kitaxa (The Department
for Technical Sciences of the Chinese cademy of Sciences).
1. Fuels--Hydro4enation 2. Fuels--Test results 3, Scientific
research--China I

ZATDMAN, II.M.; SHMINA, N.I.; PMVAWU, IT.G.; XALECHITS, I.Vo
Use of spectrophotometric methode for the analysig of lower
phenols of semicoke tars. Tr~d7 kom. anal* khim. 8:243-251
'58.
l.Vostochno-Sibiroki7 filial Almdemii na-uk SSS2.
.(Cresol-Spectra) (Phenol--Swtra)

KALECHITE, I.Ve; GRZIMN UILBIN Chong Lu-pin]; SYUT CIURII-DON [Esix Chleng-tung]
Hydivgepating, isomerizing and splitting activity of some catalysts
used in destructive hydrogenation. Isv. Sib. otd. AN SSSR no.10t
3-22 158. (MIRA 11;12)
l,Vost6chno-Sibirskiy filial AN SSSR, Institut nefti AN, Kitayakaya
Narodnaya Respublika.
(Hydrogenation) (Catalysts)

(0) CHIC01/31-58-15-6/13
and I, Ve Kalechitis
AUTHOR; Chi, Tsu-wei
TITLE: The Mechanism of Formation of Lower Phenols Under Destructive
Hydro.genation
MIODICAL: Klo HsVeh Tlung Pao, 1958,, Nr 15: pp 472-473
ABSTRACT: Figure Ishows the possible mechanism of destructive.hydrogenati-on
of three phenols; p-propyl phenol 5-hydro indenol, snd tetrahyxlro-
e)-TiAhphol, as discovered by analyses of the products by both
chemical and physical methods. Two rules were found by comparing
results of destruetiv4 hydrogenations of 5-hydro.-indonol and tetra-
hydro-j~-naphtholz (1) The weakeA bond is C~-O. (2) The para-position
bond is meaker than the meta-nosition., An Awnl ni,,,Q+.4 - hn 00A

ill F VII 1 -0,1, !,:1 U! 7 1 1 1, i 11!1 Wsi H! I i I ifill I RI III 0114M H II UIX I &M MrIlmlil I guAll, I I ~13;1[1 IF (I I IM, 11 X.J 11. ~v 1.- 4 1-1 1 :W.
C
ku)
Yeh
Tsu-heng bl)
AUrHORs and 'Is Vs Kaloohito
ftTLE: On the Transformation of Basic Nitrogeneous Compounds Under
Destructive Hydrogenation II* The Influence ol Structure of
Nitrogeneous Compounds to Their Transformation
PMIODICALs Klo Hsueh Tfung Pao, 195$., Mr 15j, pp 4.74-47~
AA~BSTRACTs- In his article, isplacemental
the bond distance, the electronic d
id the hindrance effects are used to explain the experimental
results shown.in the table on P 474. The f ollcming statements are
said to be proved% (1) The larger the electronic dens'ity of a
r
b
ond, the shorter the bond, and the more the unsaturation of the
bond. (2) Hindrance effects are obvious for 2-vethyl quinoline.

5 --(0) OHTCOM/31-58~15-9/33
AUTHORI Chang, Yen-c
111ing 11 and 1. v. K,,aaauts
-TITLE: The Conversion of Some Six-Membered Naphthenea.Under,Platforming
Conditions
MIODICALt K ueh
to Hs" T'ung Pao$ 1958, Nr 15, pp 475-476
Uyer 430-470 C, 20 atm., space velocity 2oO-15#0/hrj.weight ratik)
hydrogen to oil 6:1, and in the presence of a platinum catalyst,
..he conversion products of methyloyclohexane and cyclohexane are.
analyzed with results Bhosm in Tabloo I and 2. The JmXluonce of.
reacting conditions on reforming are then investigated and briefly
Von, By graphical differentiationp the rate equations for aroma_
91
H 'Yn+.4 nn htMIMnt, "n ,. jr4 n ft striti +.n+_"j tevnjrn"n4,n ^P

-5 (0) CKICOI~/31-58-15-10/13
Chang, Yen-chling and lo V, Kaleahits
AUTHORt f,
TITLEt The Conversion of Some Five-Membered Naphthenes Under a Platf orming'
CataJyA
PERIODICAL: Klo Hsu//eh Tiung.Pao,.1958., Nr 15, PP.476-477
ABSTRACTs The analyses of the products from paosing.a 450-470 C,: 20 atm. 4:1
mixture, hydrogen and methyl cyclopentane or dimetHylcyclopentan6j,
with space velocity of 1.0-6.0/hr over, platinum refoming catalysts,
are shovm in Table 1 and 2. The influence of reactijig conditions
on reforming are then investigated and brieflystateds by graphical.
differentiation, the rate equations for aromatization.. hydrocracking,,-

AUJHOR. Chang., Yen-chling I, Vo Kalechits
TITLE: Some Problems of Reaction Mechanism and Active Center of PlaUorming
catalyst
JERIOMCAL: Klo Hs4eh Tfung Pao, 1938) Nr 13, PP 477-478
ABSTRACTt Using Pt-A C able 1:
~03 UP-A12P3,, or Pt-tW-Al,,% as a atalyst., T
shows resul a of platfdrming of methylc~clopentane and its various
possible intermediates to aromatic hydrocarbons conducted-under'
430 C., 20 atm,, space velocity 3.0 and molecular ratio of hydrogen
to oil equal to 6:1, It can.be seen that dehydrogenation is cata-
lyzed by Pt Al 0 ismerization is catalyzed by HF4120~,, while th,
catalyst HF:PMt0j can catalyze both dehydrogenation and isomerife.

TSMUT BIN-WX [Chiang Ping-nan); M SHI-PIN[Vol Shib-pOingle- LIN LI-U
[Ling Li-vul -, CHZHOU NTIF-r-311; E~.MHITS, I.V.
m.
Hydroconation of shale tare on fixed-bad catalyRts. Izv.Bib.otd.
AN SSSR no.2:81-;-96 159.. (ARA 12:7)
1. Institut nefti, AN Kitaya.
(Tar) (Hydrogenation) (Catalysis)

KALECHITSIL I. - ; SIDOROV, R.I.
Materials balance sheets of the liquid-phase hydrogenation of
the tar of Cberemlchovo coal. Trudy Toat.-Sib.fllAN SSSR no.18:
42-48 '59. (14IRA 12: 10)
(Coal-tar products)

KALECHITS, I.V.- OKUDNIKOVA, Z.A.
Chemistry of the conversion of the high-molecular weight part,
of semicoke tar under conditions of destructive hydrogenation.
Trudy Vost.~Sib.fil.AN SSSR no.18:4.9-63 '59. (141RA 12.:10)
(Ooal-tar Products)

KALECHITS LV. - PAVLOVA, X.A. ; SA14DYWV, S.M.
0
Zffact of the recrjvs tall Izat Ion of the W82 catalyst on its hydro-
genating and isomerising activities. Truoy Vost.-Sib.fil.AH
SSSR no,18:81-86 159- (14IRA 12:10)
(Tungsten sulfide)

SALIMGAREMA, F.G.; DAVIWVICH,B.V.; IVAROVA, M.P. k1i'AUCHITS, I.Y.
Hydrogenation of narrow fractions of phonolo from tars of
Cherer.khovo coals.over an iron catalyst. Trudy Vout.-Sib.fil,
AN SSSR no.18:87,94 159. (MIRA 12:10)
(Phanole)

TSZYAN Bin~Nanl [Chiang Ping-nan]; LIN U-U [Ling Li-wu]; CIIZEIOU M-LEPT;
KALEGRITS, I.T.
One-step destructive hydrogenation of crude Nowming shale tar
over a stationary catalyst. Trudy Vost.-Sib.fil.AN SSSR no-18:
107-129 '59- (MIW. 12:10)
(Tar) (Catalysts)

85428
S/081/60/000/016/002/012
Aoo6/Awl
k~67//10
P. 72, 1.64645
Translation from: Referativnyy zhurnal, Xhimiya, 1960 No. 16, p
AUTHORS: Kal2chits un-Yun-zhuey, Go Chu, Van Ke-in
[AnnotatTo-n---7C-orre76+ Sirng Yung-SFu-i. Kru-o--dh1u-7N-an-g-T1e-Ying]
TITLE: On the Physical and Catalytical Properties of' Molybdenum--A1.1,xmos1li.-
cate Catalysts, Information 1. On the Effect of Preparation
Methods on the Hydrogenating Activity of Molybdenum-Alumosilicate
Catalysts, Information 2. The Dependence of Physico-Ch-emical
^-P nn +.'Hf- AliimeurAl-qllie~nvt-l Pat-i.-i in +.'HFA~Car-

85428
S/()81/60/000/016/002//012
Aoo6/Aoo1
On the Physical and Catalytical Properties of Molybdenum-Alumosilloate Catalysts.
Information 1. On the Effect of Preparation Methods on the Hydrogen&ting Activity
of Molybdenum-Alumosilicate Catalysts. Information 2. The Dependence of Physico..
Chemical Properties of Catalysts on the Alumogel-Silicagel Ratio in the Carrier.
Information 3. On the Effect of the Alumogel-Silicagel Ratio on the Hydrogenating
Activity of Molybdenum-Alumosilicate Catalyste. Information 4. On the Effect of'
the Carrier Composition on the Isomerizing Activity of Mclybdenum-Alumosilleate
Catalysts.

8%28
1;/1081/60/000/016/'00 2/012
Aoo6/Af)o i
On the Physical and Catalytical Properties of Molybdenix-n-Alimosilicate Catalysts.
Information 1. On the Effeot of Preparation Methods on the~ffydrogenatlng Activity
of Molybdenum-Alumosilicate Catalysts. Information 2. The Dependence of Phyalco-
Chemical Properties of Catalysta on the Alamogel-Silicaggl Ratio:ln the Car.-ler.
Information 3. On the Effect of the Alumogel-Silicagel.Ratio on.the Hydrogenating
Activity of Molybdenum-Alumosilicate Catalysts. Information 4. On the Effett of
the Carrier Composition on the Isomerizing Activity of Molybdenum-Aiumosilicatte
Catalyst5.

85428
3/08 1/60/000/0 16/002/012
A006/AOOi
On the Frysical and Catalytical Properties of Catalystit.
Information 1. On the Effect of Preparation Methods on the Hydr!~Jgenat-:-ng Activ.1-tv
of Molybdenum.-Alumos ilia ate Catalysts. Information 2. The Dependence -of Fhiysleao-
Chemical Properties of Catalysts on the Alumogel-Silloagel Rv,-,io in the Carrier,
Information 3. On the Effect of the Aiuwsgel-Sillcagel Hatio on Ue HydrogAnating
Activity of Molybdenum-Alumosilicate Catalyst'~5. lnformatt-or. 4. On the Effect, -2f
the Carrier ComprzlTion on the Isomerizing Activity of
Catalyztls.

85428
S/08 1,160100010161'00214012
Aoo6/Aoo i
On the Physical and Catalyttim! Properties of Molytdenum-Alutroall-le ate Cataiysts.
Infc,-rma-,Ion 1. On the Effect of Prepara-tion Methods on theeflydrogenating ActlvtAty
of Moly;bdenum-Alumosilicate Catalysts. information 2. -1he Dopendenoe of Physi,,:r-,-
Chemical Properties of Catalysts on the Alumcgel-Silica;-,el. Ratio in the carr.'~tr.
Infcmation 3. On the Effect c,.,' Qhe Alumogel-Silicagel Ratl- on f-he Hydrogenating
Activity of MIclybdenum-AlumosilLeate Catalyst!!. Information 4. On the Effect of
the Carrier Compvzition m the Isomerizing A:~t�vity of Molybdemum.Alumosilicate
Cataiyats.

85428
S/081/60/000/016/00 2/10 12
A006/AOOI
On the Physical wid Catalytioal Properties of Molybdeniam-Alti,ire,~sil,icate catalys*,q,
information 1. On the Effect of Preparation Metnnda -ni thE Hydrogenating A,,t i v i "IT
of Molybdenum-Alumosilicate Catalysts, Information 2. Thf! Dependence of Physizo..
Chemieal Froperties of Catalysts on the Alumogel-Silicagel RAtio in the Carrier.
Information 3. On the Effec~t of the Alumogel-Silicagel Ratio on 'the HydrogenatInF,
Activity of Molybdenim-Alumosilicatte CatrAysts. Information 4, On the Effect of
the Carri-er Composition on the Isomerizing k-tivity of Mc lybeftenum-Alumos-I lie a'T~e
Catalysts.

_S1 TSZU-VEY, [Hot Tsu-Wel); ULIMQ&RMWA,
Transformations
.of some individual phenols under conditions
of destrdetive hydrogenations Trudy Yost. -SM, fI.AN SM
no.26:45-62 159' ~Phenols) (Wdrogenation) (MIRA 13:6)

~-MLMITS,j I.V.v IW YUAIP-GW (Tin Yuan-)mnl
Activity versus selectivity of hydrof Ining Catalrilts.
Trudy Tosto-Sib.flAN SSM no.26:106-120 159. (K3:Rk 13:6)
(Catalysts) (1~6ogenatlon)

UMHITS i.y., rw mr-aw [Yin Tuan-ken]
Iffects of additives In the reaction Wyture and In the
hydrofining catalysts on th~ activity and welectIvity of .he
latter. Trudy Toot.-Sib.fl. AN SSSR no.26:121-127 159.
(XIU 13:6)
(Catalysts) Rrdromiation)

)TS
5N
Rl
H-41
r .:I
-9 -15 IF
0 x k. AS-

o P4
d $i
I f
H of.~l
g
all :J's
oil]
Iggig (AMInit
p v .1. ilit!
A v 9- a mill
I I v
if
Id .0

KAUCHITS, I.V.
Selection of high temperature sulfide catalysts fccr various casi s~of
destructive hydrogonation. Proble kin..i kat, 10:12.1-127 160.
(mm 34% 5)
1. Voutochno-Sibirskiy filial AN WSR.
(Hydrogenation) (Catalysts)
(Sulfides)

C/ 081/ 60/005/ 001/001/004
F0311FOO4
AUTHOR: Kalec4its. Sung, Yung-jui (1345/3057/3843); Kuo,Chlu
(6753/4342); and Wang, Klo-ying (,3769/0344/3841)
-SiO catalysts.
TITLE: Physical and -catalytic properties of MoS2, Z'A'203
1. Preparation of MoS2-SiOz-Al'O catalysts and effects of the
2 3
catalysts on hydrogenation activity
'nU-'DTnnjCAL: Jan Liao HsUeh Pao, v. 5, no. 1, 19 60, 1- 6

C/081/ 60/005/ 00110011004
Physical and catalytic properties F03l/F004
10 hrs, add 2. 3 N NH4 OH and agitate for ll,hcs,, then filter and dry, and calcine for
activeness. 2. Preparation of Si-Al carrier by the coprecipitation method, Add
800 m! alurninum sulphate (15 gm A1203/1) to 1.3 1 waterglass (100 gm SiOZ/1), ma-
cerate at 50-600 ir arnmonium chloride four times and in altiminum sulphate four
times, then filter and dry, and calcine. 3.L Preparation ol: Si-Al C;Lrrier by the -.om-
pos ite me thod. Add wate r glas s (165 gm SiO? / 1) to 1. 5 N H!;03 solution at 150 for
-ivture for 20 hrs, macerate four times i:. NO
q 5170 ku'4 3, and in water

C/ 0 81/ 60/ 005/ 001/ 001/ 004
Physical and catalytic properties F031/FO04
catalysts and the physical structure of catalysts and carriers. The mean radius of
pores was calculated by formula r -Lv- X 104 where r is the avenge diameter of
S
pore, v volume of pore, s the surface area. 6. The hydrogenation activity of cata-
lysts: The experiment was under conditions of 4200 temperature, 200 atm pressure,
31hr fluid speed, 8: 1 hydrogen-benzene ratio and t0.0003 refraction rate of samples.
Chromatographic methodwas used for the determination of benzene content and the

I
C/081/ 60/005/ 00110011004
Physical and catalytic properties . 4 * F031/FO04
Colloid Science, Z, 399 (1947). Linstead, R. P. , Thomas, S. L. S, J. Chem, Sot.
1127, (1940). Anderson, R. B., McCartney, J. T. Hall, W. K. 8-- Hofer, L. J. E. ,
Ind. Eng. Chem. 39, 1618 (1947)
ASSOCIATION: Chung Kuo Wo Hstleh YUan Shih Yu Yen Chiu So (Petroleum Insti-
tute, Chinese Academy of Sciences)

S/lDBi/60/000/024/003/016
A005/AO01
Translation from: Referativnyy zhurnal, Xhimiya, 1960, No, 24, P. 76; 95733
AUTHORS: Kalechit~-, I.V., Sung Yung-jui, Go Chu, Van.Ke-irl
TI M On the Physical and Catalytioal Properties of Molybdenum-Alumino-
silicate Catalysts. 2-nd Report. The Dependence of the Physioo.
chemical Properties of Catalysts on the Alumogel- Silica Gel~-
Ratio in the Carrier
PFRTnT)TCAT.- i an -3miahan- Anta fnnal-ta sinlea- lc)60- Vol xr~ I nn

8/21/~?/000/024/003/016
A005/AO01
On the Physical and Catalytical Properties of Molybdenum-Aluminosilicate Catalysts.
2-nd Report. The Dependence of the Physicochemical Propbrties of Catalysts on the
Alumogel - Silica Gel - Ratio in the Carrier
the surface acidity chanf;e, which, however, does not conform to the splitting ao-
tivity change. The interaction causes also the appearance of new big pores in
the carrier and the change of its phase composition, i.e., the formation of a new
phase similar to CO -5i02. On the basis of the changes in the physicochemical
properties in consequence of the application of MoS2 to alumosilicates, oae call
t'n"e'lliAt. +1n%%+ +-V%" ^.p M^A- W4+v% +hA

88256
S/076/60/034/012/005/027
BO2O/BO67
AUTHORS: Kalechitat I. V. and Int Yuan'-gen' (Irkutsk)
TITLE: Kinetics of Olefin Hydrogenation Over a Cobalt
Alumomolybdenate Catalyst
PERIODICAL: Zhurnal fizicheskoy khimii, -1960, Vol. 340 No. 12p
pp. 2687-2693
TEXT: The cobalt alumomolybdate catalyst used contftined 0.8% Cot
- -,w - --- ce c24e-% Ml- An-vina -Fm-r in-rpaaii~m 'h-~A11--rrann+A^vi ^^"nic+&R ^'P

F--
88256
Kinetics of Olefin Hydrogenation Over a S/076/60/034/012/005/627
Cobalt - Alumozolybdenate Catalyst B0.20/B0617
chromatographically from raw material 11. The refractive,index of the
hydrolyzate was experimentally determined withan accurao yof 0.00001.
The experiments were made with a catalyst having a Orain;size of
29-35 mesh. The results are given in Table 1. The data Otained wero used
to determine the kinetic differential equation. The,authors give an
example for calculating the equation from the data aiven in Table 1.at
2500, which has the following form: v - k apo
P ? p band PH are
u PU a H u G~
.the partial pressures of theolefins, paraffins, and of hydrogen, k1s
the constant of the reaction r .ate. and a. a

KALECHIT-5, 1. V. , Dr. Chem. Sol. (dies) "Tnvest- cr tion In Field
of Chemism of Destructive Hydrogenation of Ftials." Irktutsk" i o; rv- i ,
49 pp. (1-foacow Instit. of Teolhnolo gy In, M. V.

UM'~011ITSv I.V.; SALr.GAI=bVAI F.G.; IVANOVAj M.P.; TIZZ11ITSIMUCAP P.Vj
Cheir-istry of the transformation of enters in liquid p'--ase 17drogem-
tion, Izv*Sib.otd. MI SSSR no.lt44-51 161o OUrA 3j,,-2)
1. Vostochno-Sibirskly filial Sibirsko o otdeleniya All! SSS-`4
(Hydrogonation) &ters)

SALIMGAREYEVA, F.G.-, IVANOVA, M.F%; TRZHTSTIISKAYA,-B.V.; KALECHITS, I.Y.
Transformations of carbonyl compounds in destructive hydrogenation.
Izv.Sib.otd.AN SSSR no.5iI15-117 161. (KML 14..6)
1. Irkutskiy Institut organicheskoy khimJi Sibirskogo otdeleniya
AN SSSR.
(Carbonyl compounds) (Hydrogenation)

KALECHITSs ~.j!i.PAVLGVA, K..A.
of producto of toluene destructive hydrogenation
in the presence' of, high, temperature catalyets. Tiudy V6st,-Sib.
fil*AN SSSR no.38:15-18 161. (NMI 15:10
(Toiusne) (Hydrogenation) (CatalyiU)

PAVLOVA, KA.; KOMHITSI I.V.
Composition of products of o- and mt-xylene dwtructive bydroganation
in the presence of tungsten sulfide, Trudy ~ Vast.~-Sib,fil.AW M
no.38:19-24 161.
OCYISW) (wroganation) (Tungstan sulUdes)

NALIBERDO,, L,M.; KALECHITS .1,V,
Chemical mechanism of hydrocarbon cracking in dostructive
hydrogenation. Report No,3.* Trudy Vost,-SibfI2,AJI MR
no,38:23-30 '-61. .15 44).
(Hydrocarbons) (Hydrogenation)

AUTHORS:
TITLE.
PERIODICAL:
33602
S/678/61/000/038/001/009
A057/A126
Pavlova, K.A. Kaliberdo,'L.M., Skvortsova,
G.G., Bogdanova, T.A., Sidorov, R-I , Trot~enko, Z.P.
On the chemism of transformations of bi-cycliebydrocarbons
under conditions of destructive hydrogenation
Akademiya nauk SSSR. Vostochno-Sibirskiy filial. Trudy. Serj-ya~
khimicheskaya,-ho. 38, Moscow, 1961. Prevrashoheniya aromatiches-
kikh uglevodo rodov v protsesse deatruktivnoy gidrogenizatsii

33602
s/6713/6i/000/038/001/009
Or. the chemism of ....... A057,/A126
cry, and schemes for transformations of bi-cyclia hydrocarbons: In vapor- and
liquid-phase processes presented. In the present paper a discuesion is pre-
sented of the problem oftransformations of polycyclio hydrocarbons with a re-
view of appropriate literature data. Among the problems::t,o be solved is the
question, whether a direct splitting of the ring is possible inhydrocarbons
of the tetralin, tetrahydroanthracene,~eto. type, or whether isomerlzati94
occurs before and which bonds and bj what reasons are most easily split. Thie
and related problems were Investigated before. Experlme),pts voere carried'out
-4. )117/%Cfl 11CA -1.- -.5 V. '_ _A 1 Ad4.-1 _-i-

137 0 C 0 0
AUTHORS:
TITLE.
33604
3/678/61/000/038/003/009
A057/'A126
Pavlova, K.A., Kalechits, IN.
Destructive hydrogenation of methyl naphthalenes in the
presence of a W32 catalyst
PERIODICAL: Akademiya nauk SSSR. Vostoohno-Sibirskiy filial.. Trudy.,
Seriya khimicheskaya, no. 38, Moscow, 1961. Prevrashobeniya
aromaticheskikh uglevodorodov v prot'sesse destruktivnoy
61 - 67

33604
3/678,/61/000/038/oo3/009
Destructive hydrogenation ....... A057AU26
were carried out with each hydrocarbon and only a low conten-, of high b-vdro-
carbons observed in the products. Prevalent in the methane-naphteni', fraotion
are isomerized hydrocarbons of the series of bioyclo-0,131--t-octane, and bi-
CY010-0,3,4)-nonane. By an exhaustive dehydrogenation of T;he.aroma+.ic trac-
'IV-ion of the methyl, naphthalene hydrogenation product the present authors de-
termined that hydrogen addition occurs quicker in -the non-substitut.ed ring.
Hence the same regularities were observed as with other catalys- *~.i. Thus the
obtained results demonstrate that the introduction of a methyl But-s-tAtute a--cell-
__ - 4- __ I . . . A- - - - - -4-4-- -C _____4 - - 4. 4 __ --A --1 j 4. 4. .8 - -- - - -

3-11604
8/678/61/000/038/003/0()9
Destructive hydrogenation ........ A057/Al'_)6
bond between tertiary and secondary atoms, but with a strong favorable forma-
tion of a secondary ion. There are 5 tables and I figure.

331609
S/67'8/61/000/038/000/009
A057/AI26
AUTHORS: Kalechits, IN., Okladnikova, Z.A., Nikolayeva, D.M.
TITLE: On the problem of relative hydrogenation rates of PolYcYclic
aromatic hydrocarbons
PERIODICALs Akademiya nauk SSSR. Vostoohno-Sibirokly filial. Trudy. beriya
khimioheskaya, no. 38, Moscow, 1961. Ptevra3hchenlya aroinati-
cheskikh uglevodorodov. v protsesse destruktivnoy gidrogenizat.-
,,14-- lip - IP4

~CHIZ~V
Consecutive reactions in gasoline recovery pr;aceos. Trudy Yost.-
Sib.fil.,AR SSSR w.384152-154 161. (MMA 15 24)
(Gy0i (Hydrogenation)

33493
S/195/61/002/005/018/027
E03o/z485
AUTHORS: Kalechits I.V. *Lipovich, V.G., Vy1chovanets, V.V.,
Petrova,
TITLE: Isotopic investigation on the mechanism of berizoll,
cyclohexane and methyleyclopentane conversions in
destructive hydrogenation
PERIODICAL: Kinetika i kataliz, v.2, no.5, 1961, 748-753
TEXT: Destructive hydrogenation has been studied at 4200C and
350 atm on a WS2 industrial high-temperature catalyst in order to
elucidatp the RPmjPnr_P and T.,q I A+ i n"mbin he%+ WAAn. i canme.-ri 7.ffifin-n, A" A

33493
S/195/61/oo2/005/018/027
Isotopic investigation on EO3O/E485
the conversions required. After cooling, the hydrogenate was
separated from the benzol by chromatography and then distilled oua a
60-plate column. Both the yields and activities of catalysate .were
measured. In all experiments, there was a good linear relation
between the activity of the fragmentation products and the methyl-
cyclopentane yield; this indicates that hydrogenation proceeds
faster than either isomerization or fragmentation. To show which
of the two latter processes were more important, six experjments
were carried out with no methylcyclopentane in the feedstock.

33493
S/195/6i/002/005/oi8/027
Isotopic investigation on E03o/E485
acidic) but only one, and the,molecules move over several sites.
The reactions of hydrogenation and'the reverse reactions are
therefore best described, not in terms of rupture of.-the benzol
nucleus but in terms of a complex formation, involving proton-
transfer from the Tr-complex of the ring. There are 1 figure,
2 tables and 10 references: 8 Soviet-bloc and 2 non-Soviet-blo;~.
The references to English language publications read'as follows:
Ref.9: F.G.Ciapetta, R.M.Dobres, R.W.Baker. Catalysis,
ed. P.H.Emmett, v.6, 1958, 495; Ref.10% F.E.Condon, Catalysig-
-A- 10 W V---++ .1 r -far-A 11A

---TSYAN-BI]f-J1AN' (Chiang Ping-nanb VEI SRI-PIIq (Wei Shill-Pting); GUN GHZIM,-
KAIECHITS Ij
.Hydrofining of crude shale tar on fixed-bed catalysts at reduced
pressures. XhimA tekh. topl.i maeel b no.2s2I.Q4 F I&.
Onk 14ti)
!a Institut nefti AN Kitayokoy Narodnoy Reapublw I Inatitat lrbimii
Vottoohno-Sibirskogo Mials, Sibirskogo otdelemiya AN SSSR.
(Chiw--CU shale) (Chi=-4oal-tar products)

8/076 ~61 /0 3 5/003/002/0223
31211 203
AUTHORS: Kalechits,--I. V. and In' Yuan#-Sent
TITLE: Kinetics of simultaneous olefin hydrog6ii.ation and hydro-
genating ring cleavage of thiophene on a oobalt-aluminum-
molybdenum cataiyst
PERIODICAL: Zhurnal fizicheskoy khimiij v- 35, no, 3., 1961t 501-508:
TEXT: The authors studied the kinetics of simultaneous,hydrogenation of
heptane-heptene mixtures and thiophene hydrogenolysis ows. 001U00 -A.1 0 cata-
4 2 3,
-A-C+4^-. nil- - - - - - -

S/076/61/035/003/002/023
Kinetics of ... B121/B203
bIpO,87
1,42 - 10-IP11".
I / (250*); (6)
1,05. to-SP;-UP? (7)
OGPO MP6.311P.i
9,67 - 10-54. L (37~*); (8)
z,,T 2,3 - 1 0-2P.0;84PIO?v PO~33 (3750).
for the olefin hydrogenation rate vot and for the thiophene~hydrogenol~siw
rate vTs rvapootivoly# TOMPOr4turoo &to given iW 001 p, duAlotoo the O;&riLIkI
pressure of the resulting saturated hydrocarbon. Theae equ&tions chow that
thiophene influences olefin hydrogenation, and that ol6fine affect thiophehe
hydror,-onolvais. The effect of temperature on olefin hydroittnation and

Kinetics of ...
S/076/61/035/003/002/023
B121/B203
of thiophenef it is more probable that-olefins react with molecular hydrogen
than with chemiaorbed hydrogen. The activation energy of hydrogenation in
tho temperature range of 200-4750C is 14.5 koal/mole, that of hydrogenolysis
ie 17-5 kcal/mole. There are 1 figure, 4 tables, and 10 references: 2 Sovi-
at-bloc and 8 non-Soviet-bloc. The four most recent references to English-
language publications read as follows: W. A. 'Wilson, W. P. V.oreck, R. N.
Malo, Industr. and Engng. Chem., 49, 657, 1957; F. W. Kirsch, H. HeInemanp
D. H. Stevenson, Industr. and Engng. Chem., 49, 646, 1957; S. Wellee, J. Amer.
Inst. Chem. Engrs., 2, 59, 1956; T. Kwan, J. Phys. Chem.y 60f 1033, 1956.

K&LECH -CLEADNIKOVA, Z.A.; NIKOIAXLYA., D.Kh.
.Relative bydrogenation rates,of poll-cyclio aromatilo krdrocarbono.
Trudy Voot.-Sibofilo,AM SSSR no,38s=-124 961. (Km 1524)
(Hydrocarbons) 00drogenation)

YLA,ic~" I.V.;,XJPGVICH, ~.G.I'MHOVANNIS, V.V.
Mechanism of the destructive bydrogaiiation of:tenzeno studied
b SSSR no.38:5-14~
means of tagged atoms, Trudy Vooto-Sib,fil.AN
(MM 1534)
Nanane) (Hydrogenation) (Carbon-lootopeo.)

ACCESSION NR% ATWo6il
AtITHORt Nekhmanovich, A. S.; Kalechits, 1. V.
TITLE: Hydrogenation of polycyclic hydrocarbons and heterocyclic compounds Oyer
a platinum catalysts In the liquid phase
SOURCE: Kataliticheskiye reaktsl I v zhidkoy faze. Trudy* Vsesoyuznoy konferentsfi.'
Alma-Ata, 1963, 166-170
TOPIC TAGS: hydrogenation, catalytic hydrogenation, polycyclic hydrocarbon h~dro-
---- I!-- h-el%ftwelir rina hvdracenation. Adams olatinum- catalvtic hvdrocenatton

19
ACCESSION NR: AT4010611
hydrogenation in gl~acfal acetic acid and decal in was compared and the latter was
found to be strongly inhibitory, 'especially for the hydrogenation of naphthalene,
ant6racene and biphenyl. This Is due to the fact that the decal in takes op a tignt-
f Icont proportion of the aqlve surface of the catalyst. Orlq. art. has: 1~ ~ 2 tables,
ASSOCIATION: In*tItut nefter i ag_1ekhImIcheskogo sInteza,~SIbTrskoqo otdaleniya
AN SiSR (institute of Petroleum and q0_nIc. Chemical Synthesis, Siberian Section
AN SSSR)
SUBMITTED; 00 DATE ACQ: 25 an(4 ENCL: 00

FAMCHITSy I.VD; NAKEWOVICH, A.S.; KAZANTSEVAp V.Mo
Influence of the bond zaltip-licity on -the hydrogenation
kinetics of polycyclic bydrocarbons. Kin. i kat. 4 00-3:
395-403 My-Js 163. (KMA 1627)
1. Institut nefte- i uglekhimicheskogo sinteza Sibirokogo
Weleniya AN SSSRo
(Yqdrocarborks) (Wroganation)
(Chemical bonds)

KALECHITS, I.V.; NAKHMANOVICH, A.S.
Hydrogenation kinetics of polycyclic hydrocarbons. :Dokl,Aff
SSSR 148 no.l+:835-838 F 163. (MM 164)
1. Institut nefte- i uglekhimicheskogo sinteziL Sibdrskogo
otdeleniya AN SSSR. Predstavleno.akiLdemikom A.A.BaUndinym.
Oydrocarbons) (Hydrogenation)

7RZHTSINSKAYA, B.V.; IAL
WIM"I.V
Chemical mechanism of alkyl pher7l ether conversiono under high pres-
sures and at high tesperatures. Kin, i kat. 6 no.2:346-350 W-.Ap 165.
(MIRA l8j7)
1. Institut ugle- i neftekhimicheakogo sinteza, gorod Angarsk.

PAVLOVA, K.A.) PAIITMMRTAp~ B.D.j DMAQUi .3.9.1
Effect of nonotoichiowqt~io oulfur an tho activilly of auuido,
(mm 1813-0)
1, batitut nefte- i uglokhimiohookogo ointesa, k4arsk,

MHOVANETS', V.V.; CHENETS.. V.V.-,,; KMOV, V,-.I.;,,KALECH1TSp I.V.
Methods of the determination of the mark position in six-
membered rings. Izv. vys. ucheb. zav.; khim. i khiia, tekh.
8 no.3:432-434 165. (MIRA 18:10)
1. Irkutskiy goaudarstvenW universitet imeld Zhdanova,
kafedra organioheskoy khizii.

VYKHOVANETS, V.V.; LIPOVICH, V.G*; KNUTOV, V.I.; CHENETS1 V.V.; DIMP 0.1.;
KALECHITS. I.V.
Synthems of mtbyloyclohexanes labeled with carbm-04 in
positions, 1,20)4) am&-7#- Zhur#VXRO 10 no.W65-466 165.
(]#RA 180.1)
le, Institut nefte- i ugiekhimicbeokogo sintema,

SAKOVIGH, F.I., kand.tekhn.nauk; KALECHITS, N,,P.
Utilization of drained lands in White Russia. Zemledelis 25
no.5sll-16 My 163. (MIRA 160)
1. Belorusskiy nauchno-issledovatellskiy institut, melioratsil i
F,0
vadnogo "ozyaystva (for Sakovich).- 2. Direktor M:Lns)O_'
eksperimentallnogo khozyaystya Belorussko'go nauchno-issladova-
tel Iskogo instituta melioratsii i vodnogo Ichozyaystva .(for
Kalechits).
(Minsk Province-Peat bogs) (Minsk Province-Drainage)

for de~urn--lirin- -qui-,
in ~,jr
i: ri i~; r
rlo.i: 54-57 Jra 165.
UM

------ KAMHITS. S.
Training in a work brigade, Prof s-tekh,,obr. 17 no.6,.10-11 Js '600
(KMA 13:7)
1. Zamestitell direktom po uchebuo-proisvodstvannoy chasti
strbitellnogo uchilishoba No.25, Kinsko
(ftilding trades-'Otudy and toaahing)
(31dacation, Cooperative)

KAIECH 'S Mikola7evich; MINg V,A,* nawbayy reid,j KIKMICHUK9
S ikola:7~evic
J~~
[Methods manual for instruatoro in speoial training at-building
and trade schools for plasterers) . *Wicheoko-e posotis pro-
podavateliam Opetsial.1nol tekbnologii pri podgo.tovb) v stroitsV.
r7kh i remeslenzWkh uobi]Aohohakb shtWcaturove MosIcvap Vseo, ,
uchobno-pedagogaftd-vo Proftekbizdatq 1960. 116 p. (MIRA 106
(Pl"tering-Stu4y and teajhing)

nd
KARTINMICH, F.S. im geograf.nauk; SOWN, Te.T4,, kand.geograt.nauk;,
BCLIB&KOT;. V .*9 kand.akonom.nauk; LANTA, D.D.t,kand.ekonon.
nauk; QLA IT, Jog kand.geograf.nw*. starshiy prepodavatell -,
i
ANICHRMO, G.V., kand.geograf.nauk; KOTT, G.Z.; 7MILKO, N.P.,
kand.ekonom.nauk; KOROLMO, I.K.9 Jaind.skonim.nxak; (Ra-M& To.Gol,
kand.geograf.nauk; CHI 0. V.A.; GHBOM, L.P.. Prinimall
uchantiye: XOZLOVA, A.I., KOVALEVSKIT, P.V.; MUNRO, R.V.;
KMYSHA, TS.I.; MMOVA, V.S.; SEMINSKIY, I.I.; KMINA. Z.A.;-
rAT.7CHg6"_- 11MANOVSKIT, N.T... red.; KOS7-EVICH, X.R., red.;
TUMMICH, L., red,&zd-va; SIMMO, N., te)dw.red.
Distril6tion '_ of the industry of'White Russia for the processing
of agricultural raw materials] Fammeshchania procqnhleunosti BSSR
-nn -nj%rarabntka sell skakhaziaintvannarn avr1in- Minnk. 1959. 193 m

KUWHITS', V.V... [Uliechvtol. V-V.1. inzh.
Broad prospeotee lauka i zhyttia, 8 j;oo8:9-:L3 Ag 1589
(Y.IU 12t 1)
1. Gl&vny7 spetsialiot Otdola khimicheskoy prom~mhlennostl
G69plana Soveta, Ministrov t=. i
Onthetip products)

PHASE I BOOK EXPLOITATION SOV/4870
Arnolldov., Ye. M.., T.T., Hontaj, VA. Kalec-- 0.1. KikJmeWw p Ia. M. Neytin,
O.M. Murzin, D.M. Savych, V A.M. Shyans I kyy
Khimichna promyslovist' Ukrayiny (Chemical Industry of the Ukraine) [Kyyivj
Derzh. vyd-vo tekhn. lit-ry MWI 1960. 128 P. 2p000 copies printed..
(Series: Do dekady ukrayins,koyi literatury ta, mystetstva v Xoskwi)
Ed.: A,I, R~ikavyshnykov; Ed. (Inside Bw)k): L~*,Raytburd; Tech. No L. lorkavenko.
PURPOSE: This book is intended for the general reader i4terested in the development
of the chemical industry of the Ukraine.

BOGOLYUBOV , Vasiliy Ivanovich(Boholiubovp V. I ); U",,C JITS)
V: V.
At!~~iy Vs.aillyevillb fKaliechYtO, 1.
BALR.lSifTtil,-V.Y-O-.[-baumi3htein-p V.IF,.],, red-
[Mint that makes gold; chemistry in our life] MonetDyi
dvir, shcho loiiue zoloto; khimiia v nashomu, z)V-I,ti. Kyiv,
Politvydav Ukraivy., 1964. 109 p. (MIRA 17:9)
1. Glawyy spetsialist otdela plamro-vaniya khLnicheskoy pro-
myshlennosti Gosudarstvennogo planovogo komi-tota Ulcr..SSR (for
Kalochits),

H ITS e I t. -Ivevich; LNVITSKIY,Ye.F., redAkktor;
, e-1 of 0 icheekiy redaktor
(Principlee of organizing production enterprises in continuous
road constraction) Printeipy organizateii proinvodntvewwkh
predprilatil pri potochnom stroltellobve dorog. Xookva, Nauebw-
tekhn, izd-vo avtotranspe lit-ry, 1955o 91 P- : (mlRA 9:2).
(Roads)

K3KRABOV, Vladimir konstantinovich; I ik ~e
Nit eM
ALMMY# A*Pep red.; ore
[The bu'ildirg of 'utomobile roads3 81:roitellnivo avtomobilinykh dorog.
Hoakva, Ilauchno-t:khnoizd-vo avtotranep, lit-ry, 1957, 486 p,
(Road construction) (Hru 11:2)

KOYLYARSKIY, Boris Isaskovich; PIYARSKIY. Tikhon lv,snovichL KALICHITSimilwe&
redektor; MALIKOVA, N.Y.0 tekhaiaheskiy redaktor
[Organization of work of road machinery units] Organizateita rabot
mashinodoroshnogo otriada. Xoekva, Sauohno-tekhn. lzd-vo avtotransp.
lit-ry, 1957, ni p, (MLRA 10:9)
,(Road construction)

KALICCHITS. Te.V., inzh.
Re-examine the system of compiling estimates. Avt.dor. 20
no.11(181):26-28 N 157, (MIU 10: 12)
-t( Monads-Istimates and costs)

NAISCHITSy Tevgeniy Vitallyevich; BOCHIN, V.A., red.; ISDRER, A.S. p red.;
-1- - -e-RW
DWSKA At G,D. t t red;
(Basic econwic, aspects of earthwork operations during continuous
construction of roadol Oonovy ekonomiki proizvodstva zemliapykh
rabot pri potoobnm stroitellet" dorog* Pod red, V*A.Boobina,
Moskva, Nauchuo-tekbn.izd-vo Ywya avtomobillnogo transp. i shasoel-
mykh dorog RSM 1961. 191 p, (HIU 14M
(ZaAhworki (Road construction)

THESKINSKIY., Bergey Anatollyevich; KALECHITS, Te.V., red.;
KOVRIZHNTKH, L.P., VA, A.-:'.. tekhn.red.
(Roads on moving soilal Dorogi v podvizhuykA grimtakh
Moskva, Avtotransisdat, 1963. ]L43 P. (14IRA 1~:10)
(Road construction) (Soil stabilizat,',on)

KALECIIITS,,Yo.V.; ROMXIYCIIFVy Ye.D.; IVANOVp N.N., prof.y red.;
OLEYNIK, L.K., red.
(New developents in road building; variant design of the
plans for the general organization of automobile road
construction] Novosti dorozhnogo stroitellstva; variantnoe;
proektirovanie skhem, obshchei organ:lzatsii atroitsllstva
avtomobilInykh dorog. (n.p.] Rosvuz:Lzdat, 1963. 50 P.
(KIRA 17:9)
1. Otdeleniye usovershenstvovaniya rukovodyashchlkb i in-
zhenerno-tekhnicheskikh rabotnikov (for Kalechits)
Romanychev).

4p
5/001/63/000-1001/03/001
44/DI o6
AUT FORS - Jeiowska-Trzebiatowskas B.,- Kttleoifiiki,~~' J.
TITLE. Radikition chemistrj of Oxy-.anio'ns oJ* tronsition alewnta.
Pv rt I. Reduction of poteasium perm4ngdnate,.in aqUeoue
3olutions by CoOO I-rays
1. -iyFA,'no-.
PERIODICAL: Hri fe ra. t i v nyy vshu na.1 .h tInti1 963 j:
IB613 (Bull. Acad. polon,' sci Se-r,. aci'!-:-chem.'-q vo*.gp
summary. Russ,
no. 12 , 1961 , 791-797 F8 ' " - ''. -1 )

113/06 1/6 31000,1001102 3/0( l
of Ill 44/Bi (36 -
1.7"'. The bi,,,ii vetfuction yielcl-.-. nre explained bv chain vv-iactlona.
b-; L o.tc I. et- nv Lt~ Voi~iplete Lrauislaiinn.1

-4- .
I . TRZ&BIATOWSM-MOWSU9 B.; -KALEGINSKI.- J
-%A-
Radiation chemistry in Alkelin solutions. NWdoonika 9 noqV8,z
1625--635 164
1, Institute of Structural Research,, Polish Academy of Sciences,
Wroclaw.

TOPIC TArS: rpdiolysis , alkal!ne solution, marig:viemd! , c:hromfL,,jv,
oxyaixlc3n

L 34699-0'5
kCCESSI~~N MR: AP4045669
(I-) tons were used. The radical and molecular yields were
ed on the basis of the mechanLsm of manganate r4diatitan reduationi: ta
tha rLqd,ucti oil Of!