SCIENTIFIC ABSTRACT LAVRUKHINA, A.K. - LAVRUKHINA, A.K.

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SCIENTIFIC ABSTRACT
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i . I ...JE XM- - M-7 -~~--4;- w ffl - /1279 t7'. DIVII51-- cif (7hemical ScIcfjc~_-r_ _ Z; P -36- o the Azad- -we-L-hjbg m, I -nent of U, Tz'. ~~-S BI Wilk. one have revealed simflar Ttwr- h5iv liten observed the * Tk' A~j oi -W-Zth P'r,otwi~3iiabo-w'n y3cm 'az~ rw-.- is Mth one wide max!--qum 7~- fla-z-11 A 0:-~-- z;ucie; mth fast Frvm~ not pr~&.;t-e Ther. 1. "-1,- (Ines nv %sfizatic,. ot thc, separation of-iron on t inercury etc-c- i I Tl~ .1. col'Icn. '()n ILI~t Q o%w 4a V:-T. . Th r~ tv_* wi0i. in md-window GinKt:r- r-'.04, A -.r- .!v-zcr,- a of IrzCts -,f Ft. VY, /9 Y P% et h( SUBJECT Y ICS CARD 1 2 PA - 1604 US'SR PJA AUTHOR PAVLdkA SF.I., LAVRUCHINA,A.K. TITLE The loot pe Composition of Rare Earth Elements which were Created on the Occasion of the Fission of Uranium-, Thorium-1 and Bismuth Nuclei by 680 MeV Protons. PERIODICAL Atomnaja Energija, 1, fasc.5, 115-123 (1956) Issued: I / 1957 The present work deals with the results obtained on the occasion of the radio- chemical investigation of the isotope composition mentioned above which was carried out in 1954- Hereby particularly the influence exercised by the concen- tration of the complex-forming reagent and the pH-value of the solution upon the degree of efficiency of the separation of the rare earths was studied. On the occasion of the separation of the totality of rare earths from the products of the bombardment of uranium, thorium, and bismuth by 680 1eV protons, cerium served as a carrier. The authors allow themselves to be guided by the follow- ing considerations: The radioisotopes of the various rare earths behave on the occasion of the precipitation of cerium hydroxide, cerium oxalate and cerium fluoride like cerium. The main quantity of cerium can easily be separated from the other rare earths by the oxidation of cerium up to the quadrivalent state with following extraction by diethylether. For separation an ion-exchange Coll- with a diameter of 0,3 cm and a height of 55 cm was used. Conclusions: The influence exercised by the nature of the complex-forming reagents (ammonium -acetate, -citrate, -oxalate, and -lactate) of the pH-value of the 1tomnaja Energijapl, fase-5, 115-123 (1956) CARD 2 / 2 PA - 1804 washing-out solutions and of the rare earth elements upon their degree of separ- 'ation was investigated. The most effective separation is obtained by washing-out with a 3,6% ammonium lactate solution at pH - 3,4. The isotope parts and the yields of the P-active isotopes of the rare earths on the occasion of the fission mentioned in the heading is determined. The results of the chromatographic separation of these isotopes are shown in form of diagrams. Comparison of the re- sults obtained here with those of other authors permits the conclusion that the yield of the P-active isotopes of rare earth elements (which were created on the occasion of uranium fissioning) does not change when the proton energy is in- creased from 340 to 680 MeV. There is much to indicate the creation of a hitherto unknown samarium isotope Sm141 with T - 20 days. In order to obtain complete data on the fissioning processes, further investigations must be carried out. In this connectiong attention must be concentrated on the evaluation of the yield of the isotopes decaying by electron capture. INSTITUTION: Name: LAVRUKHINA, Avgusta Konstantinovna I----------- Dissertation: Radiochemical study of nuclear trans- formations produced by high-energy particles Degree: Doe Chem Sci Affiliation; CNot indicateg Defense Date, Place: 20 Dee 55, Council of Geochemistry and Analytic Chemistry imeni Vernadakiy, Acad Sci USSR Certification Date: 9 Mar 57 Source: BWO 13/57 IAVRUK93NA, A. K. and RODIN. S. S. "Investigated the co-precipitation of franpir vith different sediments by the short-lived radioactive isotope F 0" report presented at The Use of Radioactive Isotopes in Analytical Chemdutry,'Conference in Moscow, 2-4 Dee 1957 yestnik buk 55SR. 1958, No. 2. (author Rodin. S. S.) LAVAMaM. A. K. %Z. 'Some peculiarities of radiochemical analysis." report preBented at The Use of Radioactive Isotopes in Analytical Chemiatry, Conference in Moscow, 2-4 Dec 1957 Vestnik Ak INsiuk SSSR, 1958. No. 2. (author Rodin. S. S.) N-1 i JV "Miff Elan (M ofma tnes with Ard-1. Khfr.4. 17, 41-7(11W); C1. V-4, 50, 299.-V0 11, P.JA of 'l' B11!* d Cd 1 d C i h F L~ Th d d w rtyA es was an e t , en e, hy , Studieti a', partial and full pptr,. af the metal. The propor- -e- proportion of Wd. hy- drt,XI;;t ~rne dc~ir.!ijj~ this IrtTe ob~~Veii when q-,art t% -,f pp~n ni,tal -lc below appi~%- 20%. B--~ q; [ , ~ .:.. eXPIS it is conrluded that Llp,;Z aZLL~ Uf PSI'CJP'LL~nt LE QUanLitim N-low the one re-- quired for pptn . 1)~ th-n! mctrJ and tht isame form micelles hamg like adsorbed cnuon-,l. Further addn. of precipitant 4~, T: muses the ruicpllez to cof-le3ce Rad coa"te. Thus the ratIG ;og whtm the nummtor is the eandthedenomInatoristhesov of the metal byvt= soly . , of isotope bydroxidels indicative of the extent of mpptu. for the givezi tielnents when the meml is not completely pptd. U 06 1 atiu j.~ & Za--4G% -W ihe.meW will Am& Aovin 80% of KUTHOR: LAVRUCHIIIA,A.K., KRASAVIIIA,L.D. PA - 2193 TITLE: Fission--of -nuclei of heavy elements by means of high energy particles. (Russian) I PERIODICAL: Atomnaia Energiia, 1957, Vol 2, Nr 1, pp 27 - 35 Received: 3 / 1957 Reviewed: 4 / 1957 '415STRACT: The present paper deals with radio-chemical investigations of the fission of uranium- thorium-, and bismuth nuclei by means of 680 MeY protons. By means of the interpolation method a complete picture of the fission fragments was obtained. The interaction of the high energy particles (,100 - 700 !AeV) with compound nuclei takes place in two stages: a) The knocking out of fast particles during the collision of the impinging particles with the nucleus. b) The following emission of slow particles from the excited nucleus by evaporation. During these processes the initial Lclei lose a number of nucleons and new nuclei are created, the so-called fission products. They extend over a wide interval of atomic weights, beginning from neighbors of the irradiated elements up to very remote elements. Also during the second stage a fission process !-,.ay take place. fn order to obtain a complete picture of the fission products of U, Th, and Bi by 480 j""eV protons, the yields of the stable and non-identified radioactive isotopes were determined from the radio-chemical data obtained by VINOGRADOV et al. (Session Card 1/3 PA - 2193 Fission of nuclei of heavy elements by means of high energy particles. M of the Academy of Science on the peaceful uses of atomic energy, de- partment for chemical science, page 97 (1055)). 1 diagram illustrates for instance IT the isotopes created on the occasion of the creation of uranium. he data obtained here result in the following con- clusions: On the occasion of the fission of U, Th, and Bi by means of 460 MeV protons, isotopes with surplus neutrons are above all pro- duced. The share of isotopes with a lack of neutrons is insignificant in the-case of this proton energy. (The isotopes with a maximum yield are within the range of the isotopes with a neutron surplus and the heavy fission fragments are within the ran3e of nuclear stability) The total fission cross-sections of U and of Th are large, amounting to 55 and 60 % of the geometric crose-section of these nuclei. Ihe fission cross-section of bismuth is 5 % of the geometric cross-sec- tion. The probability of the geometric and.similar fissions is greatest with bismuth (45 % of the amoun't.,of the total fission cross- section). With U and Th this share J-8 somewhat smaller. Finally the distribution of the charge over the fission fragments is discussed. All data and considerations figuring in this tend to show that the fission of U and Th nuclei cannot possibly be explained by pure Card 2/3 emission mechanism. This fission is much more likely to be caused I PA - 2193 Fission of nuclei of heavy elements by means of high energy particles,. according to a mixed barrier- and emission mechanism. ASSOCIATION:Not given IIRESENTD BY% SUBMITTED: .'.IAILABLE: Library of Congress Card 3/3 AUTHOR LAVRUMINA.A.K., ERASAVINA, L.D., FAVLOTSKAYA., F.I.j. PA - 2722 -bW-HISHCHEVA., IOU.) TITLE The Spallation of Copper by 68o-MeV Protons. (Raaahchepleniya iaedi piotonami B enirgiyey 68o MeV - Russian) PERIODICAL Atomnaia Energiia,, 1957., Vol 2, Nr 4j, pp 345-351, (U.S.S.R.) - Received 5/1957 Revimed 6/1957 AMTRACT The investigations described in this paper were carried out in 1954 and they aimed at obtaining a complete picture of the products ob- tained at the spallation mentioned in the title, Furthermore, the in- fluence of the energy and of the nature of the bombarding particles uponthe character of the spallation process was to be daterminedg Bew. dause it is not possible by means of the radiochwdeal investigation of the producti to identify the stable as well aa long-lived and short- lived isotopes., their~ields were estimated with the aid of the interpo- lation method. The investigations were carried out in metallic copper withvery small admixturea.'For one hour the copper plates were exposed toradiation of the innerfbundle (protons of 68oMeV) of the synchrocy- clotron of the Institute for Nuclear Problems, Academy of Sciences of the U,S.S.R. Then the plates were dissolved in nitric acid, and from th*olution the radioactive istopes of the different elements were separated on isoto .pe carriers. (The following elements were used. Na, Ps Sp Gl$ Ks Ca, Sc. Ti, V, Cr, Mn, Fe, Co, Ni, and Cu). Some conclusions. The total spallation cross section of copper amounts Card 1/2 to 0.6.10--2.4 cm4, i.e.65/o of the geometrical cross section. The The Spallation of Gopper by 68o-Mev Protons. PA, - 2722 main share in the entire production cfoss section of the spallation products of cobpar is yielded'by the isotope; of Co, Ni and Cu (6o0/0). If the stability is increased, the y~eld'of the isotopes also increases. At the spallation of the copper nuclei, protons and neutrons are emitted in almost equal ratio X./Sp - 1.3 The flying-off of an a-particle is more probable than the successive emission of four nucleons. At spallati- ons of copper by particles of high energy ro influence upon the nuclear structurew&B noticed. If we compare the characteristic particularities of spallation by protok3 of 68o MeV with the spallation of copper by different particles of energies ranging from 19oMeV to 2.2 BeV, we also obtain some conclusions about the influence of the nature and increase irienerdof the bombarding particles upon the charater of the spallatiop of copper. ASSOCIATION PRESENnM BY SUBMITTED lo. lo.1956 AVAILABLE Card 2/2 1AMUCHITIM., A.K. (lavrul&ina, A.K. ),-, KOPECKA, L. Itranslator) Use of radioactive isotopes in quantitative anal7sie. Jaderna energis 3 noe9.-272-277 S 157. 1. Ustav geochemie a analyticke chemie V.I. Vernadgkeho., Akadenie ved S,S,S,R, AUTHORS Lavrukhina A. K.,11o8kaleva L.P., Krasavina L.D., 89-lo-1/36 -Yr-echiehohava I.M. 24 32 TITLE The Forming of Wa and P when High-Energy Protons Enter into Interaction with omple5,?uclei. (Obr&zovaniyeNa 4 1 P pri vzaimodeystvii protonov vysokoy en- ergii so slozhnymi yadrami - Russian) PERIODICAL Atomnaya Energika,1957, Vol 3, Nr lo, pp 285-29o (U.S.S.R.) ABSTRACT The forming cross section for Na 24 and P 32 was determined by means -of radiochemical methods if Cu, La,Au,Th'are bombarded with protons of from 12o to 66o MeV. The following cross sections were measuredt Energy of protons in Effective cross section in 1o-29 am2 MeV Cu La- Au Th Na24 P32 Na24 p32 Na24 p32 Na24 p32 120 O,o9 O,o7 O,o99 22o 0,22 0922 0,3 SPU- 0,59 SPU- ren ren 34o 1,3 1,8 0,5 Ot73 OP13 003 48o 5,6 24 2 1,4 3,7 10 18 3 66o 25 31 21 - 8,1 2,2 - SUBMITTED may 31P 195 AVAILABLE Library of Zongress Card 1/1 ~,- 7, -,,,- --. -, - -1 p - -,7 -, `~,- ~~ I-* .-I z--. - . - .-1 2. -.-.---: - . , . ~ ~- .~:7~ 9 wsr~v 4 j ra lo: Me, SADMI j" pro= In tbla- whicb. v0 ca 1 1954, spa--W ral-antiou Uw &en to me_'%~F ut j!jt,~qa eiemant3. 'rbu .afiumca a' v&r1ia factora cc Me uf ral-navian wu isuicbcd tv find the optimura con- were tle n&Uxe of complexing tE *zta t~,u-~um ecoLatf, camte, xLlua. and lac to), mom zlp pfl c;j tkv cjL~ut Lnd the c. - tmtioz of ram earths. n. drca3 bury. meLhod ~_UowVl rLD to d*Wot radiciaotopes of 4moat aH tho rarc cartbo snd to datarzina v1swl -of Some of t~~m The form4iwn of now taotojv mt Bra wltb Wl life' 7~ - hu-thl lpprwdt~ly 2!~!!Kp 0 FO niflion Diva kh LON ~Ieblvvnlwolkl alialize- U mikbina. 701-c"'I'vitia LaLmilcolti, v. 21,3, May. IU77. I-Zlq Iq SPITSY11, V.I.; MYRUMM, A.Ke doktor khimicbeekikh mauk. Utilization of atomic euerff In Czacboslovakia. Vest. AN SSSR 81 .1s 157. (MM 10:7) 27 no.6:76. 1. Oblen-korrespondent Akademli nauk SSSR (for Spitsyn). Ozechoslorakia--Atomic energ7) LAYRUKRINA, A.K. Nudlear reactions in nature. Priroda 46 no.3:24-30 Mr lo Institut geokhimii i analiticheskoy khiril im. V.I. Akademii nauk SSSR (Moskva)* (Nuclar reactions) (Radioisotopes) 157. (MIRA 10:3) Vernadskogo "e "Y / ltl,~9 AUTHORS: Sekerskiy, S., Lavrukhina, A. K., 20-1w-15/42 TITLEt Radiochemical Investigation of the Reaction si3o(p,n+)si3l (Radiokhimicheakoye issledovaniye reaktaii si3o(p,r,+)si3l PERIODICAL: Doklady AN 855R, 19571 Vol- 117, Nr 1, pp. 61-64 (USSR) ABSTRACT: Iniatially it is reported on previous papers on the subject. The present paper thries to ascertain the reaction si3o(p,n+)si31 by radiochemical method. The isotope Si3l (T=2,65 hours) can even be amoertained, if its production croau-section is insignificant. In order to demonstrate the existence of the above reaotion, the dependence of the crooo-section of the production of si3l on the energy of the bombarding electrons in the interval between 12o and 66o MeV was investigated. A 6o to 8o mg weighing target from spectroscopically pure powdery silicon was wrapped into two layers of aluminum foil and irradiated by protons of differently high energy in the interior bundle of the synchrocyclotrone of the laboratory for nuclear problems of the United Institute for Nuclear Research (Oblyedinennyy institut yadernykh issledovaniy) The methodology of the investigations is discussed; The hata here obtained on the value of asi3l at different proton energies are here compared in a table. According to these data cfSi3l in the Card 1/3 area of the proton-energies 12o-22o MeV*is hardly changed at all Radiochemical Investigation of the Reaction si3o(p,n+)si31. 20-1-15/42 ASSOCIATION: Card 2/3 but it is highly increase at an increase of this energy to 22o to 68o MeV. In order to explain this behaviour of aSi3l, the authors investigate all sorts of reactions of the production of si3l on the occasion of irradiation of silicon by protons. The yield of s13l in the fission of admixtures in the silicon can- not provide an essential contribution to dsi3l. But the reaction s13o(d,p)5-31 ~oubtlessly takes an important part in the pro- duction of S13 .,At hilh energies of the bombarding particles the reaction s13o(p~n+)sj3 joins in the process, in which reaction energy-rich positiveigiong fly off. The cross-zection of the reaction si3o(p,n+)s I can provide an estimation of the yield of pions with the highest energy at the intraction of protons with'silicon nuclei. The experiment toa2certain the reaction (p,n+) by the radiochemical method in lage heavy nuclei. (e.g. germanium and biamuth) had no success. There are 2 figures, 1 table, and 14 references, 7 of which are Slavic. Institute for Geochemistry and Analytical Chemistry imeni V.I. Vernadaki.y of the AN USSR(Institut geokhimii i analiticheskoy khimii im.V.I.Vernadskogo Akadeiaii nauk SSSR) Institute for Nuclear Researche of the Polish AS (Institut yadernykh isuledovaniy Pollwkoy Akademii nauk) Radiochemical Investigation of the Reaction Si3o(p,n+)si3l. 20-1-15/42 PRESENTED: JulY 6, 1957f by A. P. Vinogradov, Academician SUBMITTED; March 5, 1957 AVAILABLE: Library of Congreus Card 3/3 PRASR I BOOK EXPWITATION SOV/1762 Lavrukhina, Avgusta Konstant-inovna, and Yuriy Alexsandrovich Zolotov Transuranovyye elementy jTranburanium Elements) Moscow, Izd-vo AW SSSR, 1958 125 (Series: Akademiya nauk SSSR. Nauchno- populyarnaya ;eriya)pio,000 copies printed. Sponsoring-Agency: Akademiya nauk SSSR. Redkollegiyanauchno- populyarnoy literatury. Resp. Ed.: P.N. Paley; Ed. of Publishing House: D.N. Trifonov; Tech. Ed.:. A. P. Guseva , PURPOSE: The booklet is intended for the layman interested in nuclear physics and also for physics students at the high school level. COVERAGE: The booklet describes the transuranium elements, mainly the two most Important ones -.plutonium and neptunium, and how they were added to the Periodic System. In qVmmerized form the author* relates'the story of their separation and~'defines their properties, 1ne2ndIng-b6me data on their electronic configur4tion. Various Card 1/4 Transuranium Elements SOV/1762 methods of.-isolation are presented ,; among them Is the method on separating the elements from impure solutions, as well as radio- chemical and radlometrical methods. Nuclear reactions serving as synthetic sources for the production of transuranium elements are evaluated in general terms, No detailed description of the chemistry of such reactions is given. Chapter 6 outline-- the principles of the chain series and suggests possibilities of predicting new elements. There are 41 references of which 33 are Soviet, 5 English, 2 French, and I Qerman. TABIS OF CONTENTS: Introduction 3 Ch..I. History of the Discovery of Transuranlibn Elements 5 Significant scientific achievements at the end of the 19th and the beginning of the 20th century 5 Are there elements heavier than ur4nium? 8 Formation of neptunium and plutonl~m 11 The chain'of discoveries 14 Card 2/ 4 TrIansuranium Elements sov/%762 Ch,~Jj, Preparation of Transuranium Elements 20 NUclear,reactions 20 n6ilwti. ons. slow neutrons 24. Reactiond with:eharged particles 28 Nablear reactions vdth,nulticharge ions 31 Difficulties with producing super-heavy transuranium elements 33 Naturally-occurring transuranium elements 36 Cho III,,. Methods of Separation and Identification of Tran=)Mnlum- Elements 4o Radlochewdoal ~ m6thods 40 CarrIO-Tr6cipitation .42 Ion-exehange chromatography 45 Extraction methods 51 R16ctr6lysls 55 '~-Mtra-microohemistry 56. Hadiometi-I methods a Protection from radiation F2 card 3/4 J- 5(2); 21(5) PHASE I BOOK EXPLOITATION SOV/1,000 Akademiya nauk SSSR. Komissiya po analiticheskoy khimii Primeneniye radioaktivnykh izotopov v analiticheskoy khimii (use of Radioact-1ve Isotopes in Analytical Chemistry) Moscow Izd-vo An SSSR, 1958- 366 p. [Series: Its: Trudy, t. 9 (12)] Errata slip inse-r-C'ed. 3,000 copies prin-t-eff. Resp. Ed.: I.P. A-limarin, Corresponding Member, USSR Academy of Sciences; Ed. of PublishIng House; A.N. Yermakov; Tech. Ed.: T.V. Polyakova. PURPOSE: The book is intended for chemists and chemical engineers concernad with work in analytical chemistry. COVERA6E: The book is a collection of the principal papers presented in Moscow at the Second Conference on the Use of Padioaeti-ve Isotopas. The problems discussed at the Conference ineluded cc~precipitation, aging, and solubility Tmitnation of the instability constants of preciptates, dete- Card 1/10 Use of Radioactive Iaotopes (Cont.) SOV/1900 of complex compotuids, separation of rare earth metals, and ion-exchange cbronatography. No pe-roonalities are mentioned. There are 351 referanre4 175 of which are Soviet, 33 German, 19 French, 8 Swedis-'a, 2 HurZarian, and 2 Czech. TABLE OF CONTENTS: Foreword 3 A.K.. So, e Characteristics of Radio- -14vrukhina,- Art --c-li6iffe-a-1 Analysis 5 Shvedov, V.P., and L.M. Ivanov. Separation of Some Short-lived isotopes from Complex Yjix- tures and Purification of the Isotopes 20 Rudenko, N.P., and 1. Stary. Determination of the Complex Formation CQnstants of Indium Acetyl Acetonate by the Extraction Method 28 Card 2/1D LAVRUKMiA, A. K. AIM PAVLOTSKAYA, F. I. (Inst of Geochemistry and Analytical Chemistry im V. I. Vernadskiy AS UMR) "The Chromatographic Method of Separating Promethium From the Fission Products of Uranium" Isotopes and Padiation in Memistry, Collection of papers of 24d All-Union Sci. Teeb. Conf. On Use of Re4ioactive and Stable Isotopes and Radiation in National BaouozW and Seience, Moscov, Izd-vo M SSW, 1958, 38G7p. Mis VOIMM V-Ub11sbvd the reports of the CbAmistry Section, of the 2nd AU Sci Tech Conf on Use of Podloactive and Stable IsotA)pes and Radiation in Sc.iezee and the National Economy, spoarored by Aead Sai USSR and Haiu Admin for Utinzation of Atomic Energy under Couneil of Kinisters IESR maeow 4-:L2 Apr 1957. /~/A-A-,, A, ff AUTHORS! Lavrukhina, A. K., Pavlotskaya, F. I.,Pozdnyakov,A.A . 78-1-15/43 Grechisbcheva, I. M, TITLE*. The Chromatographic Separation of the Radioisotopes of the Elements of Rare Earthelby Means-of Ion Exchange (Ionoobmennoye khromatogra- fiches-koye razdeleniye radioizotopov redkozemeltnykn elementov). PERIODICAL: Zhurnal Neorganicheskoy Khimiij 1958, Vol. 3. Kr 1, pp. 82_87 (USSR) ABSTRACTO. Some'problems of,the aforesaid separation of the isotopes which _4're formed with nuclear transformation under the influence of par- 1.ileles.with-high energy are dealt with in the preseA report. Spe- Pial Attention was paid to the Ankluence of the quantityof the elament&on their degree of separation, as well as to the position of the maximum of the chromatographical curve. Metho-dics. It was found (reference 1) that the best separation of urani=, thorium, and bismuth was achieved by-protors with an energy of 68o MeV by washing out with a 3,60/o solution of a=onium laata- te with Pli-3,4'.-The separation was carried out on cationite "dau---ks -5o". Figure-l'shows that the separation was quite effective. Figure. Card 1/4 2 shows the same for hafniam. If laraer quantities of other elements a The Chromatographic Separation of the Radioisotopes of the 78-,1-15/43 Elements;of Rare Earths 1)y 'Yeans of Ion ExchanZe.. Are present the separation is- not always achieved. The influence of the ouantity-of elements on the'deLyree of their on, 'xPe dependence. o jjV5.LLUUU, 01 FnU- MaXIMUM 01. Tne CnrOMawgram on Tne quanrjiTy oi rae orementa Those proMems were Investigated WHE yttrium (rererenFe 6). it resui as f'rom:figure'3, which shows the washing out curves. without carrier and in the presence of lo mg yttrium, that the maximum corres= ponding.to variousquantitiesof yttrium are rather far from each other, Consequently, the quantityr of the element can influence the p0- 3 t ition of itfr maximum on the curve,# With low concentrations the maxi- mum is displaced in direction to a more rapid washing out of the re= spective element. The shape of the maximum- is Influenced in so far as it is sharper with ultra-low concentrations, The same was proved with the washing out of tetravalent cerium (also in references. 3,4,7.99). The data by Ser_iyavira and Tikhonova (reference 8) Which obtained wide apexes of curve strontium are incomprehensible in this context. The assertion. by the authors on the,width of the apex of the curve ia not contradictory to the current conception of the theory of exchange- chromatography. . The inflnence of the quantity of elements~on their degree of separa- Card 2/4 tion. The Chromatographic Separation of the Radioisotopes of the Elements 78-1-15A3 of Rare Earths: by.-Means of Ion Exchange. The afore~,mentioned displacement of the apexes of the curve with. the change of concentration can lead to a coincidence of two or more apexes-.of neighbouring elements' 0 This will reduce the degree of separation in the case of a great difference of their concen- trations. This is proved by the-example of tullium and ytterbium, whiob cannot be separated at a ratio of 1.115o (figure 6, curve e'q'ua'l c6hcentrations they-can be separated satisfacto- ri (figure 6, curve I).-Further examples are given. From the abovwexamples it can be concluded that the coincidence of the apezea of the curve must be taken into consideration with the de- termination of the optimum conditione,of separation of the elements. This-is'of great importance with the investigation of the natural radioactivity,.(6. of promethium, samarium and otherm) in the' rresence.of gr6at quantitie,-w of neighbouring elements, a3, well as, with the-analysis of irradiated material. There are 5 figure3, and 9 references, 6 of which are Slavic, ATION: Institute for Geochemistry and Analytical Chemistry-imeni V. 1. ASSOCT Card 3/4 I The Chromatograptiie Separation of the Radioisotopes of the 78-1-15/43 Elements of.Rare Earths.by Means of Ion Exchange. Vernadskiy AN USSR (Inititut geokhimii i analiticheskoy khimii imeni V.... I.- Vernadskogo, AN SSSR). SUMITTED: June 18; 1957w AVAILABLE: Library of Congress. Card 4/4 LA VR14 t~- 11 AUTHOR: Lavrukhina, A. K. 78-1-24/43 - - TITLE: -- ---------------------------------- The Search for Promethium in Nature (K voprosu. o poiskakh prometiYa v prirode). PERIODICAL: zhurnalliiarkanioheskoy Khimii, 1958, vol. 3P Nr 1, pp. 129-135 (USSR) ABSTRACT: In the beginning the author gives a survey of the respective works performed in the,years between 1917 and 1949 (ref. 1-5). Principles of the search for radioactive isotopes in nature. The opinion about the lacking of Pm. should not be regarded to be definite. The radio-isotopes ft145, Pm147 and Pm'5o can be searched in natural objects. Thus, already in 1934 (ref. 6) a soft P-activity was observed in carefully purified Nd-samples, which were attributed to a'neodymium isotope of T - 1,46.1012 years. Later on (ref- 7) it was predicted that the isotope Nd15o was supposedly contained with a quantity of 5)6% in the natural mixture.The secondary product Pm150 of T - 2,7 hours is in equilibrium and therefore can be discovered in natural neodymium. The failure of the search for prometheum isotopes (ref. 5,900) can most probably be Card 1/5 explained by long lasting separation methods, so that Pm150 The Search f#r Promethium in Natm*. 78-1-24/43 decomposes completely in the mean time. A basis for the search of a-active Pm was only created when about 15 a-active isotopes of rare earths, natural as well as such produced by nuclear reaction with particles of high energy, were determined. There is the possibility to raise the question of the search for Pm147 (of T w 2,7 years) in uranium minerals and -ores within which it will form because of a spontaneous decomposition of U238. From the known mass spectrum of these decay products (ref. 15) the Pm'47 quantity can be calculated, which is in equilibrium with U238. Table I contains data on the radiation character of Pm isotopes which can be found in natute as well as on their quantity per 100 g of natural neodymium (for pm150) and per 100 g of natural uranium (for Pm146). The method of investigation: The following methodical problems should be solved in connection with the Pm-search: 1.- The selection of radiometric methods of measurement of P- and a-activity of weak intensity; 2.- A powerful separation method of Pm from other rare earths$ 3-- A method of separation of these elements from others existing in minerals and ores; ad 1.- the intensity of activity as well as the Card 2/5 radiation type of Pm isotopes determines the method. The The Search for Promethium in Nstju-e 78-1-24/43 determination of Pm150 is easily possible with an end- counter (tortsovyy schetchik). Pm150 can very quicklv be identified by the determination of T and E po For PmI47 this is, however, very difficult and demands the construction of a special counter for weak activities. From the counters described the author selected the 4n-oounter which operates in the methane flow under the pressure of I atmospheres of absolute pressure. Pm145 can be determined by means of ph6tographic plates (ref. 13). Ad 2.- For this the method of ionexchanging chromatography was selected (ref. 16). Weighable Pm quantities were separated from the sum of rare earths, which develop by the U255-separation by means of thermal neutrons through a 3,6 % ammonium-lactate solution at PH - 3,4. The same method was used for the isolation of not-weighable promethium quantities of relatively great quantities of neighbouring elements (oxide mixtures of Er, Tb, Eu, Pr, Nd, Sm and Y, 0,5 mg each irradiated with slow neutrons in a nuclear reactor). Promethium develops as Pm149. Ad 3-- On the one hand we must consider the presence of great quantities of Ca, Mg, Al, Fe and U, and on the Card 3/5 other hand the presence of radioactive decomposition The Search for Promethium in Natm 78-1-24/43 235 238 232 products of U , U and Th Table 2 shows the values of the actiiLties of the P-active products of decomposition of the above mentioned elements per 1 kg of uranium ore (content: 10% U, 1% Th). Table 3 gives the activities of a-active isotopes in minerals containing rare earths (U and Th contents, as above, lid = 10, Sm 0,5 %). Before the solution of the problem of separation of rare earths from other elements the reaction of Pm147 was studied (table 4). The author worked out a method for the isolation of purely radioactive. rare earths (ref. 16) from the products of a bombardment of 1-2 g of natural uranium by protois of high energy. In this all chemical elements were contained (from Na to NP) (ref. 17). After this a method of separation of rare earths from isotopes of other elements (with the exception of actinium) were described. A method is also given for the actinium separation. Card 4/5 The Search for Promethium in Natmre. 78-1-24/43 There are 3 figures, 4 tables, and 21 references, 10 of which are Slavic. ASSOCIATION: Institute for Geochemistry and Analytical Chemistry imeni V. I. Vernadskiy AN USSR (Institut geokhimii i analiticheskoy khimii im. V. I. Vernadakogo Akademii nauk SSSR). SUBMITTED: June 19, 1957 AVAILABLE: Library of Congress Card 5/5 AUTHORS: Yerz-h-;bek., V. SOV/78-3-7-40/4, TITLE: The! Extraction of Sciva RaL,.n Earths by TrKoutyl Pho.;sp~- (E1cLvtmkt.,0,ya P.-.kotorvkh -,-.edkoz =.elr~ykh elmeniov tz4butil-Msfatom) PERIODICALi Zhj=al WWI, 1958, Vo~ 3, Nr 7, p,,j 1' 3--!708 (USSR) .ABSTRACT: lr!reatigatiorw wara carT~vid out for the saparation oll z)--rs ear-%hs trm largar qatrxld-Mt~3 of iaanium, Iron, allmium, magae--itm, ani ml,rA-lxn 17j e.0,r%oilion by meatA of tri:butyl pbosphate, In the ent paper the opt-4=m conditlons for the separation of small qijau- titleA of rap.~ earths by extraotion ara worked out. A mora rap~-3 merthod for +.he aepamtion of small quantities of pxct-4t~J*amby otbgr oonta:Wed '&.,a urardum ores ia described. 1t was formid thal" iap, prasa-al:~i Pf -azenium in the Folu-~icyn i--reatiga".e~-.1. reducc,s the of the distribution of rar-a earths ba`~-~..en tha ftlb;~~tylphoaaplmt- p',1xa,5e and the aqueous pteve wayide-rably. R wi r fcp,.nd V~rat 'to aeparailiv umni~xm 1--y ether ftom. the -,uxT ~mTthn- aril than to exirao-,; the raxe eaLx-",-b-.j Card 1/2 by mean-.i of teiLt"'a-V,1phoephate. The extraction of ytteum by The Extraotion iuf Scm-a Rarv- Bartim by Trllbutyl Phosphatea 3()*lr/7P,-3--7--40/44 .1.0 was al:so The r, ct p-m- matlid'r=, and othtw eazths frm aock-apan,-Ing elvvents by =bans ot tr,%leutyl phoaphaic~~, ahovm that -tb,,g lmarerjscm of. irilice-0 acrid cop.- rimtm~-leir. lknom?a~t-" -tA-txaotjon of j-uri otsaihi; b7 tlkb-atyl phlm,pha-~,~. TbRx,3 arg figurea, 3 teblsi aru5 3 rafnermizir, I of whi,,~b 1A Scr-.'-14.e*. ASSOCIATION: &-lc~klldmil t analiticheskoy kh-imii im. V.I.Vernadekago nauk SSSR, Inbtitwk yaaampy fiz,,tk*.',- Chekhos3--vatskoy Akwdn.mil mw& of Gtio&imi-si,-~,- and Analytl-ca-l Ch--mistx7 lme47--A V.I. AS USSR, Im~-Altulhi of Nu-:J--~&r Pbyx~aB P 13 of SUBMITTED-. jzzv~ 1.50 i957 1. Rare earths-Separation 2. Butyl phosphates-ApplicatiGns cam 212 AUTHOR: TITLEt PERIODICAL: ABSTRACT: Card 1/3 Lavrukhj.Z2a, A. X. (]Aoi3cow) 74-27 r/;,--/6 The Present State of Nuclear Chemistry (Sovremennoye aostoyaniye yadernoy khimii) Uspekhi Khimii, 1958, Vol. 27, Nr 5, PP. 517-550 (USSR) In the introduction the author gives a short survey of the investigation of rules governing the nuclear trans- formation of different chemical elements. This transfor- mation was for the first time in an artificial way per- formed by Rutherford (Rezerford) in 1919 and the investi- gation of the rules governing nuclear transformations to- day belongs to the fundamental problems of the investiga- tion of the structure of matter. In the first section of the present report the author discusses the methods of nuclear chemistry. In the second section the author deals with nuclear reactions occurring under the influence of 81OW particles: a) nuclear reactions under the influ- ence of neutrons, b) nuclear reactions under the in.- fluence of charged particles. In the third section the nuclear fission of heavy elements by slow neutrons is The Present State of Nuclear Chemistry 74-27-5-1/6 discussed. In this connection the authors of many works are cited. The great number of investigations of the nuclear fission products of heavy elements under the influence of slow neutrons permitted the determination of a number of characteristic features of this fission which are given in the present article. In the fourth section the author discusses the nuclear transformations taking place under the action of high-energy particle8t 1) Yriclear reactions under the influence of fast protons, deuterons, a-particles and neutronss a) The characteris- tic features of nuclear fissiong reactionsq b) the cha- racteristic features of nuclear fission by high,,energy particles. c) the emission of light nuolei~ d) the secondary nuclear reactions~ In the second summary of the same section the author discusses the nuclear reactions under the influence of multiple-charged ions., in the third summaryt The nuclear reactions under the influence of f -quanta~ in the fourth summarys The nuclear reao- tions under the influence of n-mesonB and in the fifth Card 2/3 summaryt The production of new particles. The fifth see- The Present State of Nuclear Chemistry 74-27-5--1/6 tion deals with nuclear reactions in nature. At the end the author states-that the examples given in the last section indicate that radioactive and nuclear transfor.- mations no doubt play an important part in nature. There are 13 figures and 376 references, 166 of which are Soviet., 1. Nuclear reactions--Theory Card 313 AUTHOR: Lavrukhina, A. K. (Moscow) SOV/74-27-10-3/4 TITLE: On the Properties of Francium (0 svoystvakh frantsiya) PERIODICAL: Uspekhi khimii, 1958,.'Vol 27, Nr 10, pp 1209-1220 (USSR) ABSTRACT: Early in this paper the author briefly mentions the efforts made to discover the assumed element 87- With the discovery of the short-lived radioactive isotope in the radioactive decay products of uranium by M. Perey francium was given the symbol Fr. From thattime scientists started to look for this new element in natural objects. The first chapter of this paper is exclusively de~cted ~o these efforts. It is said among others that already Dobroserdov (Ref 4) had discovered this element and given it the name "russium". A great number of scientists searched for this element 87 in cesium concentrates using the x-ray method Refs 6-9). The author discusses the work of various scientists efs 10-22). The numerous investigations.of the decay products R of the radioactive elements showed that some radioactive isotopes of francium are either intermediate members of the actinium (Fr 223), the neptuniuzr, (Fr 221) or the thorium (pr224) series of Card 1/1-0 decay. In the second section the author discusses the properties ,On the Properties of Franci"um SOV/74-27-10-3/4 of the radioactive isotopes of francium In the course of diverse nuclear reactions until now (except Fr2~3) 8 radioacti--re is~otopes of francium were obtained (Refs 23-30)- In section 3 the author discusses the methods for the separation of francium (Refs 15, 40,41). In section 4,the chemical properties of francium are described (Refs 3y49,41)- Section 5 deals with the problem of the separation of francium from the alkali metals. io to now two methods are known for this separation: the correct 00- precipitator (detection) for francium, which could act neither on rubidium nor on cesium; the chromatographic method. This latter method is regarded up to nor as the most efficient method in the distributicn of the elements with similar chemical properties. In section 6 the ranges for the practical application of francium are discussed (determination of actinium oz de- termination of sarcomae) (Ref 58)- In conclusion the author mentions the biological properties of francium (Refs 60-61). The investigation of the practical application of francium is continued. There are 4 figures, 3 tables, and 61 references, 12 of which are Soviet. Card 010 AUTHORS: Pavlotskaya, F. I., Lavrukhina, A. X SOV/56-34-5-2/61 TITLE: Uranium Fission Products Obtained by 660 UeV Protons in the Range of the Rare Earth Elements (Produkty deleniya, urana protonami s energiyey 660 meV v oblasti redkozemellnykh elementov) PERIODICAL: Zhurnal eksperimentallrioy i teoreticheskoy fiziki, 1958, Vol. 34, Nr 5, PP- 1058 - 1069 (ITSSR) ABSTRACT: A. target of spectroscopically pure metallic uranium with a weight of 0,5 - 1 g was dissolved in a few milliliters of concentrated hydrochloric acid (which contained from. 10 to 20 mg of berium and of hydrol,~en peroxide) after having been irradiated in a beam of 660 MeV protons from the synchrotron of the Laboratoriya yadernykh problem Ob"yedinennogo instituta yadernykh issledovaniy (Labora- tory for Nuclear Problems at the United Institute of Nuclear Research). The further treat-ment of this solution is discussed. A diagram illustrates the curves of the washing-out of radioactive isotopes of the rare earth elements, which form in the uranium fission caused by 660 MeV protons. The yields in P4, - and P -ac- Card 1/3 tive isotopes were determined by a method dessc,ribed before (Ref 3). Uranium Fission Products Obtained by 660 MeV Protons SOV/56-34-5-2/61 in the Range of the Rare Earth Elements Every peak of the chromatograms was identified by means of the half-life separately for each type of radiation and separately for the different energies of the P- and y-radiations. The necessary corrections are pointed out briefly. The obtained yields in radioactive isotopes of the rare earth ale;-Ients are compiled in a table. Based upon the measured and interpolated data the curves of the yield distributions of the various elements versus the mass numbers viere constructed. These curves also per- mitted to extrapolate the yields in the _remainin& isotopes of the rare earth elements (dysprosium and terbium). The experimental and interpolated data toJether give a comprehensive conception of the fission protiucts of uranium nuclei by 660 MleV protons in the ranee of the rare carta ele-:;ents. The estimation of the chare in stable iootopc.: -.s woll as in inotopes with neutron excess and neutron deficlit. is also briefly discussed. These 3 types of isotones form i4i about the same yield; pertinent details are giver. In a short para=aph a report is given on the influence of the shell structure of the nucleus. The evidence obtained from the fission of heavy-ele..lent-nuclei by high-energy particles Card 2/3 hardly seems to have influc~nced the presently valid rules govern- Uranium Fission Products Obtained by 660 MeV Protons SOV/56-34-5-2/61 in the Ran,-,e o he Rare Earth Elements ing tho distribution of the rare earth elements. The authors express their gratitude to A.A.Sorokin and L.S,14ovikov for the identification by means of the y-radiation and for the computation of the yields of some of the isotopes which decay after the electron capture. There are 8 figures, 3 tables, and 31 refer- ences, 15 of which are Soviet. ASSOCIATION: Institut geokhimii i analiticheskoy khimii Akademii nauk SSSR (Institute of Geocheniztry and Analytical Chemistry AS USSR) SUBMITTED: October 31, 1957 1.Uranium-Fission 2.7ission fragments-Analyais- 3-*Rare earth element isotopes(Radicactive)--Determination 4.Chromatographic amalysis-4kppl.tcations Card 3/3 AUTHORt Lavrukhina, A.K., Doctor of Chemical Sciences 26-58-6-3/56 TITLE: Achievements of Nuclear Chemistry 'Uspekhi yadernoy khimii'. PERIODICAL: Priroda, 19586gr 6, p 9-18 (USSR) ABSTRACT: The discovery of radioactivity opened the way to a new science nuclear chemistry. Radiochemical research is one of its main characteristics. It determines exactly what kind and quantity of radio isotopes originate from a given nuclear reaction. An important step in the development of nuclear chemistry was the fission of uranium-235 nuclei by thermal neutrons. The studies on the nature of fission products by Soviet scientist V.G. Khlopin and his assistants are a valuable contribution in this field. The past ten years have beer, -characterized by the de- velopment of nuclear reactions of fast moving particles, pi- mesons, gamma quanta and multicharged ions. Great steps have been recently made in the study of new isotopes of rare earth- elements. Radiochemical methods also facilitated the study of the spectra of tantalum, holmium and lanthanum fission pro- ducts. As to new transuranic elements, neptunium, americium and.fermium were synthesized in-reactions with slow neutrons and several other new elements were discovered. Card 1/2 There are 7 diagrams, 'and 14 references, 10 of which are Achievements of Nuclear Chemistry Soviet and 4 English. 26-56-6-3/56 ASSOCIATION: Institut geokhimii i analiticheskoy khimii imeni V.I. Vernads- kogo Akademii nauk SSSR (Moskva) (Institute of Geochemistry and Analytical Chemistry imeni V.I. Vernadskiy of the U-13SR Academy of Sciences) (Moscow) Card 2/2 1. Chemistry-USSR 2. Nualear.chemifitry-Development , 3. Radiochemistry-Research- AUTHORS: Lavrukhina, A. K., Krasavina, L. D., 2o-119-1-14/52 db Fozdnyakov, A. A. TITLE: Radiochemical Investigation of the Products Resulting From the Fission of Lanthanum by 66o MeV Protons (Ra= diokhimicheskoye issledovaniye produktov deleniya lan= tans. protonami s energiyey 66o MeV) PERIODICALs Doklady Akademii Nauk SSSR, 1958, Vol- 119, Nr 1, PP- 56-58 (USSR) ABSTRACT: The sho:rt introduction reports on previous works dealing with the same subject. This work gives some results of the radiochemical investigation mentioned in the title. The main difficulty of this investigation was the pro= duction of the fission products of lanthanum. in pure ra= dioactive form. The investigation was performed at the synchrocyclotron of the Laboratory for Nuclear Problems (Laboratoriya yadernykh problem) of the United Institute for Nuclear Research (Ob"yedinennyy institut yadernykh issledovaniy). The target, which tas to be bombarded, Card 1/3 consisted of lanthanum oxide powder with a weight of up Radiochemical Investigation of the Products 2o-119-1-14/52 Res-iiitinglrom the Fission of Lanthanum by '66o MeWL'.Protons to 1g; it was wrapped into an aluminium foil. These tar= gets were irradiated by 66o MeVrprotons for from 1-2 hours. 'Then.the powder was dissolved in hydrochloric acid and subsequently,the radioactive isotopes were separated. For the separation of the fission produ 'ots of lanthanum a method for the rapid chromatographic separation of.Un, Fe, Co, Ni, Cu,and Zn was worked out before. The essence of this method -is shortly described'here. The here obtained experimental -data and the computed cross sections are compiled in a table and indicate-the following: In the fission of lanthanum isotopes with a neutron surplus are essentially generated. Theisotopes are in the wide interval of the atomic numbers from Z - 15 to Z~ - 40. A diagram illustrates the distribu- tion of the yields of the fission products of lanthanum, on the atomic number This distribution has the character of ja flat curve, whi;h speaks for the high probability of the symmetrical and also of the unsymmetrical fission. This conclusion agrees with the theory, after which fo5 nuclei with .average atomic weight (A 16o), for which (z /A)/ Card 2/3 (Z2/A)before) 0.6 holds, the barrier in asymmetrical 21M PHASE I BOOK EXPLOITATION SOV/2039 Lavrukhina, Avgusta Konstantinovna Uspekhi yadernoy khimii (Advances in Nuc ar Chemistry) Moscow, Izd-vo AN SSSR, 1959. 143 1p. (Series: Akademiya nauk SSSR. Nauchno-populyarnaya seriya) Errata slip inserted. 20,000 copies'printed. Resp. Ed.: I.P. Alimarin; Ed. of Publishing House: D. N. Trifonov; Tech. Ed.: Yu. V. Rylina. Sponsoring Agency: Akademiya nauk SSSR. Redkollegiya naucho- populyarnoy literatury. PURPOSE: This book is for chemists, physicistspand more especially, teachers and students of courses in nuclear chemistry. COVERAGE: The book offers a historical sketch of the development of nuclear chemistry and the fundamental concepts of nuclear reactions as they apply to the transformation of chemical elements.' The Card 1/6 Advances in Nuclear Chemistry SOV12039 general cg~racteristics of rcLdioactive disintegrations and nuclear reactiuns are described/and basic models of atomic nuclei and theories on nuclear forces are reviewed. Consideration is also given to descriptions of radiochemical methods of studying nuclear transformations, which methods include beta-, alpha- and gamma- spectroscopy, scintillation counting, use of photog;4phic emulsions, etc. The role of slow particles in nuclear reactions and the Influence of these particles on fission processes in heavy elements are discussedlas well as nuclear transformations caused by high- energy particles. Reaction prod 'ucts are also considered. Nuclear reactions on the sun, stars, and in space are described and attention Is given to the role of radioactive transforZations in changes in the composition of isotopic elements of the earth's crust. The practical application of the principal advances in nuclear chemistry is reviewed with special emphasis on nuclear reactions which yield isotopes of transuranicelements and atomic power. Finally the problem of systematically Classifying the nunlei of radioactive isotopes is considered. There are 28 figures, 4 tables and 26 references, all Soviet. No persor.alities are mentioned. TABLE OF CONTENTS: Card 2/6 Advances in Nuclear Chemistry Introduction Ch. I. Short Review of the Historical Development of SOV/2039 3 Nuclear Chemistry 6 1. From alchemy to the realization of the first nuclear reaction 6 2. Discovery of the neutron, artificial radioactivity, and the fission of uranium nuclei 11 3. Creation of charged-particle accelerators 15 Ch. II. General Characteristicis of Nuclear Processes 18 1. Radioactive disintegration of atomic nuclei 22 2. Nuclear reactions .28 3. Classification of nuclear reactions 30 Ch. III. Methods of Nuclear Chemistry 32 1. Principles of the radiochemical method 33 A. Use of carriers 34 Card 316 Advances in Nuclear Chemistry SOV/2039 B. Methods of separating elements in the radioactively- pure state 36 C. Radiometric methods 46 D. Scintillation counters 49 E. Mass-$pectrometers 53 F. Determination of effective crosf section 54 2. Method of thick photographic plates 55 3. Other methods 56 Ch. IV. Nuclear Reactions Which Take Place Under the InTluence of Slow Particles 58 1. Nuclear reactions under the action of neutrons ~9 2. Nuclear reactions under the action of charged particles 1 3. Reactions with gamma-rays 64 4. Fission of the nuclei of heavy elements 66 A, Fission of nuclei by slow neutrons 67 B. Pc,~omplishing a fission chain reaction of uranium-235 70 %J. -~"Lssion of nuclei by charged particles and gamma- quanta 72 Card 4/6 Advancesin Nuclear Chemistry SOV/2039 Ch. V. Nuclear Reactions Which Take Place Under the Influence of High-energy Particles 75 1. Characteristics of the interaction of fast particles with complex nuclei 75 2. Splitting of nuclei 79 3. Fission of nuclei 82 4. Emission of nuclei of light elements 85 5. Secondary nuclear reactions 87 6. Production of new particles 88 Ch. VI. Nuclear Reactions in Nature 91 1. Nuclear reactions of the sun and stars 91 2. Nuclear reactions of cosmic rays 96 A. Nuclear processes in primary cosmic rays 97 B. Nuclear processes in secondary cosmic rays 99 3. Changes of the isotopic composition of elements in the atmosphere and in meteorites 99 4. Nuclear processes in the earth's crust 101 Card 516 Advancesin Nuclear Chemistry SOV/2039 Ch. VII. Practical Application of Advances in Nuclear Chemistry io6 1. -artificial preparation of new chemical elements 106 2. Preparation and application of artificial radioactive isotopes 115 3. Nuclear Power 118 A. Utilizing the energy of fission chain reactions of uranium 119 B. Studies on controlled thermonuclear reactions 121 Ch. VIII. The Problem of Classifying Radioactive and Stable Isotopes 125 1. Regularities in the properties of atomic nuclei 126 2. Regularities in the properties of alpha-radioactive isotopes 130 3. Proof of the special stability of nuclei containing 2, 8, 20, 50, and 82 protons or neutronsand 126 mutrcm 132 4. Predicting the properties of ye t undiscovered isotopes 137 Conclusion 140 Bibliography 142 AVAILABLE: Library of' Congress Card 616 TM/dfh 7-22-'59 IkkVRUKHIKA, A.K. - EDURZHI14, V.; FILkTOVA. L.T. Determination of actinium in natnral objecto from the daughter product Fr 223. Radlokbimiia I no.2:204-207 159. (MA 12;8) (Actinium-Analysis) (FranciUM--ISOtOpeI3) JAYRUMU, A.K.; CHZRU PIT-TSZI [Chu Vei-chil Dependence of the distribution coefficient (organic phase - aqueous phe-se) on the concentration of the distributed elements. Radiokhimiia 1 no.5:530-537 159, (MRA 13:2) (Attraction) LAVRUKHI tor khimicheskilch nauk Radioisotopes in the earth's crust. Khim.nauka i prom. 4 no.4: 472-478 159. (MnU 13:8) (Hadloisotopas) (Geochemistry) 21M AUTHORS: -vrukhina, A. K., Grechishcheva, I. M., SOV/89-6-2-6/28 it~ - TITLE: Radiochemical Investigation of Nuclear Reactions Producing Pions (Radiokhimicheskoye izucheniye yadernykh reaktsiy, pri- vodyashchikh k obrazovaniyu n-mezonov) PERIODICAL: Atomnaya energiya, 1959, Vol 6, Nr 2v PP 145 - 151 (USSli) ABSTRACT: The experimental part of the work was carried out with protons of an energy of iiO - 660 key, which had been accelerated in the synchrocyclotron of the OIYaI (Joint Research Institute of Nuclear Physics). The targets were irradiated with different proton flux radii for 1.5-2 hours. The proton ray intensity was determined by means of an aluminum monitor, wherein the Al"(P,3pn)Na" cross section was assumed to be 10 mb. The identification of radioisotopes and the cross section determina- tion were carried out according to the method escribed in i reference 3. The copper target was 25-7.0.5 mm high, the La2 03-target weighed 50 - 200 mg and the copper target 400-800 mg. Card 1/4 All elements were spectrally pure. After proton irradiation Radiochemical Investigation of Nuclear Reactions Producing SOV/89-6-2-6/28 Pions the samples were dissolved in a 50% solution of HNO 21THI10 31 3 and aqua regia, respectively. The radioisotopes were separated from the solutiot)s, i.e. nickel from copper, barium from lanthanum and platinum from gold. The cross sections measured mav be seen from the followinz tables: a in 10-30cm2 Ep = 480 Lev EP = 660 11ev Si 30(p,n+)Si3' 2.2 4.0 Cu 65(p,n- )Ga 66 0.34 - CU 65(p'Pn,)N,65 2.0 3.4 La 139(p,pn+)Bal39 Not observed Au197(p'pn+)ptl97 Not observed 65(p, R+)11,66 Cu. 2 Not observed Card 2/4 Ra.diochemical Investigation of Nuclear Reactions Pro,lucing SOV/89-6-2-6/28 Fiona EP (110v ~B 2 cr (in 10 -am - Ga 66 Cu 61(p, -njGa 66 130 1.30 + 0.15 190 2.0 + 0.2 M 250 3.1 + 0.2 1.8 3,50 4.40 + 0.25 3.1 480 3.5 + 0.2 2.2 The experiments permit the following conclusions to be drawn: 1) The cross section of the reaction (p,n+) in heavy nuclei is in the order of 10-30cm 2, the production of the n +-meson being more probable than that of the n- meson. The ratio is: Card 3/4 Radiochemical Investigation of Nuclear Reactions Producing SOV/89-6-2-6/26 Pions 41 -1p, + - R A = 6. 5 d(p'n-) 2) The reaction (p,pn+) is more probAle than the reaction (p,n-). That agrees well with the data hitherto available on the nature of nuclear reactions caused by highly energetic particles. The high cross section (Ref 2) of the rcaction (p,n+) in silicon can be explained only by the occurrence of the reaction (d,p) in addition to the reaction mentioned. 3)In the proton energy increase from 480 to 660 Hev a slow cross section increase of the reactions (P,Dn+) and (P,n+) was observed. S. Sekerskiy separated the Ni66-nucleus from the irradiated copper target. There are 5 figuxes, 3 tables, and 16 references, 12 of which are Soviet. SUBMITTED: July 14, 1957 Card 4/4 1,0) OW it 0- 21 (0). 5 (a) 02MAR T. 31pasLuu an Ratlo4bsa.18-7 (TSOOM%XVY $10pollua jox = 1 23M=XCAS-s At-, a suarglya, 1959, Tot 7. Ir 2, pp 175-176 (USSR) AMILLM t I., L eMagian Was hold In Lamingral froal 3 %o 5 KAX0.4 1959. Marv than 200 jortric' 1pents fr- different institutto in Moscow, UALW-4, XIz-, lr*vooLbLr*k# TbLIUI and Gcr$kiy attended it~ Tweat7eigbt papers a" real. The tollc*Lg are coationel, 1. To. Starik. On the problen of the siolvtasr state or alcroause. at _ radia"tive alsoonte in volutional Z. To. StuLk, T. Z. Ampolocavs. M.V", L. D. 5h,YdLn, s 01 aLosenve -~ZAC T of Xn' IMA (Zr, Am. ft, ?0).W. ta,lova, j. r Application of the A1.1-ole- xauxtion at uranium carriers LA natural loodism of To. T. lot fom*tL= of the sultLw4*ot ~ - 9~ K. 3 T. Y. PmLn, Dosexxion UM and the snot"ilit7 17 Ion at of the CorLux, OSAa&t@ = core 1/3 L Coples: torsation of PlAtoIna am ^Mricium iib6~liiio d4-4, 'titr:~ -Atto said (=TL) McL oulia ad pto.phuj, "La. now Othad for the dvtimination of Lan charres, of radioactive slonan to in saIntions by application of Lan oxchWiv, ro.ina or different swelling capsnltiwo.-X~ 3. A_jj-.TrnUa=, I of amplex votne-Lun and ZDTA V application of the Lon excluIc* and the potentimetrLo "thods. 1,11-TdAzAtko et~ 5 1 Determination of the conditions of conpourAs ; , in the argavla phase, (kydr.tlan or uxw4l ULtr.t. with ' T T. -&1S' *star). T. 11. 424ZXDU Degree of bzdr.%Lou of - lbut7l OS altric W the diotIqlan. SIZvol. X.-X, of solvation, of the ftAtrlc, said In the dibtjpl other of the dith,71421 417001 L D.t~rnlnatlaa of the apa4vacy at the .between the arCuotla and the astery phases LA order to d.torntno the condition or the s~bataaaa LA the solution and ,a h. tone-tration maj,- at which co.pl.z to-Atiam #tarts ~ I P-R-Z"W-I-ctumd - *rtr=ttm of hosavalent tungtan with saill- fre. hydrochloric a.U.. ...Card 2h jjVUAujM on substittion of k7dragon in tonsol U1 the recall atone p3# VBT6 and SbV24. a. 0. vxmt4w #Qt~owd an t!m "call *tons froct the "ca-Laus of U 6(r.x)T, 1(14(g,p)CI4 in & ..di- of cyclic h2drocarboul. an the Influence of the 1103 &M 9- loas, on the reduction velocity of boxavalout plutoulux u~~ tjzo b1fluonoo of itc own wrodiatian. In the course at tharouCh discuagiona it was established that the conprohoo,oLog or the condition of radjoactiv~ almants, in solution, Are of eninont loportance for the whole range of radio cboalstr7. Vare tudiva h4r* to be cado Lt. tU, field as were made tefore. A better coordination of all the institutwo which am tacupled with this problem will yl*14 good ro-ul to La the ratm. ~% AUTHORS: Lavrukhina, A, K., Pozdnyakov, A.A. SOV/89-7-4-15/28 TITLE: The Spallation of Hafnium by Protons With Energies of 660 Mev PERIODICAL: 13SR) Atomnaya energiya, 1959, Vol 7, Nr 4, PP 382-384 (U. -ABSTRACT: It is the aim of the.present paper to determine the yields of spallation. products and to investigate some details of the interaction between 660 Nev-protons and hafnium nuclei. The chromatographical separation of the spallation products, calculation of /19 and /9_~-yieldB, and of the K-capture isotDpes was carried out according to methods which have already beer,.described in publications. On the basis of experimental and interpolated data for all identified elements..the curves for the dependence oZ isotopes on their mass numbers were then constructed. In the spallation of hafnium by 660 Mev-protons the isotope-distribution functions are cupola-shaped like in the distribution of the spallation products of copper. In the case of hafnium the cupolas are considerably shifted in the direction of the nuclei with neutron-aeficit. In the spallation of hafnium nuclei with neutron-deficit are essentially produced. Card 1/3 They comprise 67% of the total spallation cross section. The Spallation of Hafnium by Pro-bons With Energies of 660 Mev Card 2/3 SOV/89-7-4-15/28 23 and 10% respectively correspond to the portion of stable nuclei and to nuclei with a neutron surplus. The cupola-shaped curve with Z= 64 is shifted towards smaller masses and lower yields (compared to the adjoining elements)* This may be explained according to the statistical theory by the influence of the closed oubshell with Z= 64. From the cupola-shaped curves the summated isotope-production cross sections are then determined. The total cross section for the processes of hafnium nual eua spallation is , li5-10"24 cm 2. This amounts to 85% of the geometric cross section o.t the hafnium nuclei. In the fraction of lutetium there is an activity with the half-life of 4 hoursq which may be attributed 168 to the new isotope W . The second diagram shows the dependence of the cumulative yield of the isobars on the number N of the departed nucleons. This yield remains constant a-IV, N 20 according to the exponential law 1n(5 _- PA+const. Here P = 0.11 holds. For the isotope with A N >20 the production cross section of a given product-nucleus may be calculated according to the formula by S. Rudstam(lzef 6).' The Spallation of Hafnium by Protons With SoV/89-7-4-15/28 Energies of 660 Yev d (A 1?7.1) exp[PA-Q-R(Z i SAi) 2] Here P ='.0.11; Q 12.8; R - 1.2; S 0-433 holds for the parameters. A table contains the numbers of neutrons and protons (determined by estimation), which were emitted in the spallation of hafnium. The results obtained indicate a considerable increase of the number of evaporated neutrons with increasing atomic number of the irradiated nuclei. The number of cascade neutrons remains nearly constant. The average excitation energy of the hafnium nuclei is 150 Mev. There are 2 figures, 1 table. and 7 references, 4 of which are Soviet. SUBMITTED: February 13, 1959 Card 3/3- LORUKRIla, A.K., doktor kbim.nauk (Moskva) Transuranium elements. Hauka i zbyttia 9 11 159. (Trausuranium elements) no-7:21-23 (14IRA 12:11) AUTHOR; TITLEs PERIODICAL: Lavrakhina, A. K. 6691Q SOV/74-28-11-2/5 The Role of Nuclear Processes n the Formation of Chemical Elements Uspekhi khimii,- 1959, Vol 28p.Nr 11p PP 1310-1342 (USSR) ABSTRACT: In the present paper, an attempt is made to investigate soM,1 points.of the theory of the synthesis of elements on starelon the basis of experimental data concerning the course of various nuclear reactions. To solve the problem of formation of elements, data on the distribution of chemical elements and their isotopes on various celestial bodies are of high importance. In 1889, Clarke (Ref 1) first tried to find a relation between the relative distribution of elements in the earth's crust and their.atomic numbers. After him, numerous research workers tried to obtain more exact data on the distribiition of elements (Aefs 2-19). So far, only a small number of cosmic bodies, mainly-atmospheres of some stars of, our'Galaxy, have been investigated. Nevertheless, it appears -possible to draw some conclusions regarding the fundamental laws of distribution of chemical elements in the cosmos. Card 1/5 Figures 1 and 2 give the curves of distribution of atomic 66911 The Role of Nuclear Processes in the Formation of SOV/74-28-11-2/5 Chemical Elements nuclei according to atomic numbers and mass numbers, correspondirg to data in reference 10. According to the author's opinion, the cases of deviation from the average distribution of the elements are also-important for the solution of the problem of their formation. The most significant cases are given (Refs 10, 15-17, 20-51). The theories of formation of chemical elements may be divided into 2 groups (Refs 52-57). The former includes the theories of formation of atomic nilelei at thermodynamic equilibrium of the initial system (Refs 2U, 54, 58-74). The main deficiency of these theories is that the reason of "freezing" of the thermodynamic equilibrium of the system, in which the nuclear processes take place, is not yet clarified. Besides, the problem concerning the cosmic bodies, in which the stabilization of equilibrium must take place, remains unsolved. The second group includes theories of the synthesis of atomic nudlei in non-equilibrium systems (Refs 41, 52, 55, 75-87). According to data of modern astrophysics, there is no cosmic body with such a high temperature and density of .Card 2,/5 particles as is demanded by non-equilibrium theories. Recently, 66911 The Role of Nuclear Processes in the Formation of SOV/74-28-11-2/5 chemical Elements research workers have tried to find non-eqilibrium synthesis reaoti-ons of atomic nuclei which proceed at temperatures lower than in the systems-witH th(armodynamio.equilibrium (Refs 52, 75-80). These theoriesp however, can only explain a few rules of cosmic distribution of elements but not the formation of all chemical elements.. Better prospects are offered by the theory recently developed by th e American physicists Fowler, Salpeter and..Greenstein as.well as by the English astrophysicist's E. M. Burbidge, G. R. Burbidge and Hoyle.(Refs 41, .55t 81-86). According to this theory, thii synthesis of elements takes place at any stage of development of the cosmos in close relation with nuclear processes which explain the energy and illuminating power of cosmic bodies, their-evolution, and the change in their chemical compoiition. In this theory, the cosmic distribution need not~be explained by the assumption of any preastral stage of the cosmos. The formation process of chemical elements taken place during the whole period of existence of the metagalaxy, being a regular.process combined with the evolution of stars which still continues, Furtherp the Card 3/5 principal features of nuclear processes axe discussed which 66911 The-Role of Nuclear Processes in the Formation of SOV/74-28--11-2/5 Chemical Mements give rise to the formation of elements in the starst and which are postulated in the theory of star synthesis. Besides, some proofs.-are offered which were obtained in the investidation of, nuclear reactions in accelerators (Refe.88-162). The available-data on the synthesis of chemical elements which takes place in the course of some stages of development of stars in nuclear processes, and on the subsequent variation of their isot9pe composition during the straying of cosmic radiationt,!in the-interstellar space indicates that there 3*.s,/no ,doubt some connection between astroDhysicall adioastronomic,'-,/ and i;~clear physics data. The whole t of the nii6lear processes in*estigatea offers a qualitativel~-good explanation both for-'the-average cosmic-distributibn of,elements and for the few considerable deviations in-.the.content of some elements in various cosmic b6diesi In order to obtain a general idea of the processes which give rise.to the foxmation of.chemical elements, new data on the chemical composition of a number as large as-possible of cosmio'bodies will be of decisive importance. The following Soviet scientists are mentioned in 'Card 4/5 the present paper: G. I. Pokrovskiy., V. V. Cherdyntsev, The Role of Nuclear Processes in the Formation of Chemical Elements ASSOCILTION: 66911 SOV/74-28-11-2/5 L.-E. Gurevich,-A. P. Zhdanov. There.are-16 figures, 11 tables,.and 162 references, 58,-of which are-Soviet. In-t geokhimii i analiticheskoy khimii im. V. I. Vernadskogo AN SSSR (Institute of Geochemistrv and Analvtical Chemistrv Card 5/5 21 (8) AUTHORS: Lavrukhina, A. K., Revina, L. D., .90V/20-125-3-18/63 Rakovskly, 2-.-Ye--. TITLE: The Ftmetions of'the Ebccitation of Pragments of the Fission of Lanthanum (Funktsii vozbuzhdeniya oskolkov deleniya lantana) PERIDDIGAL: Doklad y Akademii nauk SSSR, 1959, Viol 125, Nr 3, PP 532-534 (USSR) ABSTRACT: In the present paper the authors try to investigate the excitation functions of the fission fragments 32 66 73 f l th th P N d S i e o an anum n e energy range i , an i40 660 Mev of the bombarding protons. The investigations were carriecl out by means.of the synchrocyclotron of the Oblyedinenny,y in.stitut yadernykh is8ledovaniy (United Institute of Puclear Research). Powders of lanthanum oxide (covered by an aluminum foil) were irradiated for 0.9 - 1 hour. Af ter the irradiation, the lanthanum oxide was dissolved in concentrated hydrochloric, fvitl, an-J the radioactive isotopes of nickel, selenium, and phosphorus wore Card 1/4 removed on isotope carriers. The removal of Se, Ili, und I is The Functions of the 1,;bccitation of Fragments of ths SOV/20-1 25- Pission of Lanthanum, discussed in detail. The results of these exDeriments are shown in two diagrams which show the excitation functions 73 666 ' 32 of the fragments Se , Ni , and P of the fission of lanthanum in the energy range 1110 - "'PSO 7-Tev of the incident protons. Those results arn, % P-Ve-arc values of P parallel experiments. For so 3at E'p 140 Hev and for P32 at E = 220 Mev only a very low activity, (~5 pulses/min) p was observed, which permits the determination of the "' 100 -'ev production thresholds of these nuclei (E thresh for Se73 and Ethresh - 200 11ev for P3 The nuclei investigated by the authors are interesting since 2 of then, have a neutron excess (P32 and Ni 66 ) and the nucleus Se73 has a neutron deficit, The characteristic sharp ascent of the curve s f ( TO ) for p3 2 and , P ,e73 beyond the threshold of their production (if the en3rgy of the protons increase's) Card 2/,r Tl,a Functions of the Excitation of Firagmento of SOVI/20-125 - 3 -16/6 5 tho Fission of Lanthanulm is indicative of :-. significant increase of the probability of the asymmetric fia!;Aon of li.,,ntlvinum- nuclei in the investigated 66 energy range. The excitation function of Ni has a somewhat different char-i.cter. The cross section.of th., nroduction of 66 111i variestylOtimes if E p rises from 140 to 660 Mlev. The probability of the symmetric Tission of lant-hanum nuclei in a lower degree depends on the energy of the incident protons. This fact explains also the constancy of the cross section P 300 - 6`0 ":ev. of the fission of silver in-'he interval E IV C. .. The rrrethod of the'thick-layer photo--Plates applied in the present.~aper does not permit the recording of 'he pzoLiucts of a strongly asymmetric fission. -'~ further invust_i,;~-t.L~n of the excitation functions of the fission of thG nuclei of the middle part of the periodical system is veryimpoz-tant for the explanation.of the fission mt-chanism. The authors thank L. P. ~Ioskaleva and M'. I. Blckhina fnr their help in t*--- carrying out of 'he present investigation. The-ra are ? f1glires ,_,r.rd VA and 14 references, 5 of which are Soviet. Punctions of the Dccitation of Fragments of TM, SOv/,-O-I-,-:---m/"~ Fic.ion of Lanthanum 5 Z I "~ T 10 N :Institut geokhimii i nnalitiches-kor khimil im. V. 1. Vernadskogo Akademii wiuk SSSR (Instuitnto of and Analytical Cliemistry imeri V. T. Verna~ukiy oi.' tv;it~ Academy of Sciences USSR) -RSSE'~TED: December 10, 1958, by A. P. Vinogradov, Acade-nicifin December 5, 1958 Card 4/1~ 19 2+_t7t AUTHOR-. 30VI/20-129-6-,21/69 TITLE: The Problem of the (p,r;~) Reactions PERIODICAL: Doklady Akademii nauk SSSR, 1959, Voll2q, Nr 6, pp 1277-1278 (USSR) ABSTRACT-, It was Dossible to determinQ the reactions Si 30 (p'-"')Si31 and Cu65(P,i,_)G. 66 at proton energies of from 200 to 660 ~.Iev by meana of the radiochemical method. This fact is in eontradicti,,)n to the T-resent conceptions o! nucleon-nucleon interaction5 within ihe rani,~e of hir~h energieL;. The possibility of the 0 develoDment of reactions in which only one pion departs in each case follows from the data on the energy spectra of the charged mesons produced in a collinion bet-,%reen 670-',-.Iev Protons with carbon nuclei. The apectra of the positive and net~ative pions have a maxi.,:nam in the energy range of -110 ;1ev ano extend to 400 Mev. These spectra may possibly extend even farther, viz. to the maximvm energy value possibIE- (470 Ylev) corresponding to the reaction C 12 (p'-n')C 13. The development Card 1/3 of the (P,r~t) reactions may possibly be exDlained accordint; 68isa The Problem ofl~the (P,r..-+) Reactions SOV"20-129-6-21/69 to the theory of peripher,-;l collisions. The nost- interesting data for the purpose of explainin-- (p,v:L) reactions are those of Kh. F. Babayan, 117. L. Gri-vrorov, ct al. (Pef 6), according 11 12 to which 10 - 10 ev particles use up their entire energy for the pro,luction of mesons in their interaction with iron nuclei. In this case there in no successive interaction of the primary particle with the nucleons of the nucleus or -with their complexes, for the primary nucleon collides with the meson cloud, and therefore the prob-ibility of the departiare of neoons is great. At lower energies (up to I 13ev) the probability of such peripheral collisions is very small, and they can be +\ detected only by employing very sensitive methods. The (P'T~--) reactions observed by the author on complex nuclei hnve a very small cross section and may apparently be examples of peripheral collisions In this energi range, Therefore, reaction investigations carri.,-,d out on other complex nuclei, in pions fly off, an well aE3 furth~-r inve st igut ions of the anSular distribution and energy distribution of their products will render better understanding of the interacti-on tirocesses of -V"ard 2/3 hi-vh-energyy particles with cor;'-;I,~x nuclei. possible. f 8158 The Problem of the (Pllt�) Reactions There are 6 Soviet references. ASSOCIATION: Institut geokhimii i analitiches,:oy Akademii nauk SS8R (Institute of dski Cbenistr.y iniQni V. 1.-Vprny of the USSR) PRESENTED. STJ.V'-I ITTED: SUOV/20-129-6-211/6- khimii ir.. V.1,VernadsI,,o,-Io -leochemistry and Analytical of tbe kca6emy of Sciences August 19, 1959, by A~ F. Vinoj-,radov, eicademician August 11, 1959 Card 3/3 Lptv R L) K I PHASE i BOOK M2LOITATION SOV/5410 Tashkentskaya konferentaiya po mirnomu ispollzovanlyu atomnoy ener&ll, Tashkent, 1959- Trudy (Transactions of the Tashkent Conference on the Peaceful f I zes of Atarmic Energy) v. 2. Tashkent, Izd.:vo AII ITzSSR, 1960. 41.19 p. Errata slin inaerted. 1,500 copies printed. Sponsoring Agency: Akademiya nauk Uzbckskoy SSR. Reoponcible Ed,: S, V. Starodubtsev, Academician, Acada-my of Srience3 Uzbek SSR. Editorial Board: A. A. Abdullayov, Can- eidatc of Phl,rsic:. and Math2matI03; D. M.. Abdurarulov, Doctor cf I-Tedical Sciences; U. A. Arlfov, Acadetaician, Academy of Sciencea Uzbek SSR; A. A. Borodulina, Candidate of Biological Sciences; V.' 11. Ivashev; G. S. lkrcmova; It. Ye. Xi~; Ye. M. Lobanov, Candidate of Phynica and Nnthcm atlas; A. 1. Niholriyov, Candidate or ll-.)dlcal Sciences; D. Vit3hanov, Candirlati of Chc,:Ical S,:_Iencea; A. S. Sadykov, Correoponding Momber, Acadcmy of Sciences USSR, Academician, Academy of Sciences Uzbek SSR; Yu.*N. Talanin, Cav;__~ Tranvactions of the Tazhkent (Cont.) SO-VI5410 Candidate of PIrry2les and Mathematics; Ya. Mi. Turakulov, Doctor of Biological Sciences. Ed.: R. 1. Khamidov; Tech, Ed.: A. G. Babakbanova. FU7G OSE : 7he publi~-ation is intended for soientific wcricerB and enploy,~,d in enterpriaes uh'~re radicaet5ve ieotc-~cs ar.-I nuclear radiat'lon are wed for re-,--c-arch in chemical, Gco- IcSteal, and technological fleld3. OOVEMGE: Thi-= collection of 133 articles rcpre!~enti the second volume of the Clrant-,actiona of the Ta4shkent Conference on the F,~~a^efuj Uses of Atomic Energy. The individual artl,,%len deal with a wide range of proble-me in the field cf nuclear radiation, including: produattcn and cherLical analyz~is ef radioactive isotcpez; inwatigation of the kinet-4cs of chemical reactions by means'of izotopes; applIcation of spectral analysia for the manufacturing of radioactive preparations; radioactive methods for determining the content of ele-ments, In the rocka; and an analysis of methods for obtaining pure substances. Certain Card 2/20 -.Transactio no of the Ta3hIcont (Cont. SOV/5410 Inatrum--ants used, such as automatic reculatoro, flot.,meterz, level Saugeo, and high-sennitivity Cam-aa-ralays, are dooeribed. ITO personalities are mentionod. Reforencoo follow individual article5. TABLE OF CONTENTS: RADIOACTIVE ISOTOPES AND ITUCIZAR RADIATION IN E110111MING AND GEOLOGY Lobanov, Ye. M. [Institut yadernoy fizikl UzSSR - Institute or Nuclear Physics AS UzSSR]. Application of Radioactive Isotopes and Nuclear Radiation in Uzbekistan 7 Taksar, and V. A. Yanushlcovokiy (Institut fiziki JUT Latv SSR - Institute of Physics AS Latvian SSRI. Problems of the Typification of Automatic-Gontrol Apparatus Based on tfie Use of Radioactivq Isotopes 9 Card 3/20 Franchuk, L. V. Sulima, ~Brcd~4"Iy.~ A. r. Aragcrov, 1. F. 1. 1.. 1%khtenko, V. A. L-nnenok, A. 3. Foraanlco, and A. 14. Alek- 0 S--*iTdftn [Inntitut fizie.hczkoy Minii M SSM - Institut or _--hyAlral (7;hen,15try AS MR). InwotiaGion of the 112chanirm of. 07_%,,5t7~ing Reacticna by the Isotopic l'othod tut gcokhinii i analiticheskoy Ithimii A, K. g,:, A-TI SSSP - lnttitutG of Geocho-iniotry and _Ako 7hr-!z_t:r-y imeii V. 1. Vernad3kiy AS U33,111. -E--thods of '~' - Fadloatcmi5try and the Fields of Its Application A., K. '11, rhrautov. and F. P. 14azarov. Cinsti- I rf Physl~al Chcm-1.3try AS USb3R), Study of the Adsorption r~f A-~,,Icaline and Rare-Earth Elcmcnts on Black Earth by the 01racer Atom Me' cd A. 1. [Tadzhik7:kiy gosudarstvennyy univerritet im. D~niua-Tadzhik State University imeni V. 1. Lenin]. Co- -'reolpitation of Small Quantities of Various Cations and Anions A, With T~etal Hydroxide& Ampe~.Iogova, N. 1. [Radiyevyy institut im. V. G. Ehlopina Card 16120 327 34 3 341 349 MOSKALWA, L.P.; KA.LYSHU, V.A.; SATAROTA, L.M.; LLVRUKHIR, A.-K. - r- -xusij SU MWN-M su H=g Angular distribution of &~4 nuclei and fission fragments in the interaction of high energy protons with nuolel of gold and uranium. Zbur.ekep.i teor.fiz* n0-3:994-993 Mr 160. (KM 13:7) 1. Institut geokhimi.1 i analiticbeekoy kbimii Akademii =u SSSR, (Sodium-Isotopes) (Protons) (1hiclear reactions) 22460 B/186/60/002,/001/014/022 A057/A129 AUTHORSs Lavrukhina, A.K.; Rodin, S.S. --------------- TIM: Radiochemical Investigation of uranium fission products obtained by 000 Mev proton bombardment PERIODICALs Radlokhimiya, v. 2, no. 1, 1960, 83 - 93 TEXT: Fission and spallation products of uranium obtained by bombardment with 660 Nev protons were Investigated radiochemically. From experimental data and results obtained by interpolation a full chart of residual nuclide products is.prepared and basic regularities in their formation are determined. High-en- ergy fission was discovered in 1947 by G.T. Seaborg et all [Ref. 1% Phys. Rev. .72, 74o (,1947)). The present-authors started in 1955 detailed radiochemical in- vestigations of fission products (in the Interval Z = 78 - 93) obtained by 66o A Mev proton bombardment of uranium. Comparison with literature data on fission products of copper and bismuth can give information concerning the dependence of fission characteristics on the atomic number of the target-element (from Z = 29 up to Z.- 92).' A, Linder and R. Osborn's paper [Ref, 121 Phys. Rev., 103, 378 (1956)) on fission pr6duots obtained by 100 - 340 Mev proton bombardment of ura- Card 119 22460 s/186/6o/oo2/ooi/o14/022 Radiqchemical investigation of uranium fissionwr.. A057/A129 nium in connection with the present results may give come informations on the ef- feot of the bombardment energy in the range of 100 - 660 Mev on the yield of some fission and spallation products. In the present work metallic uranium foils (0-3 - 0-5 9) were bombarded In a circulating 660 Mev proton beam of the synchro-cy- clotron in the laboratoriya yadernykh problem Oblyedinennogo instituta yadernykh issledovanly (Laboratory for Nuclear Problems of the Joint Institute of Nuclear Investigations), varying the duration from 15 min to 2 h. After irradiation the uranium foils were dissolved In HN03 or HCl adding H202, the elements Pt, Au, Hg, Tl, Pb, Bl,. Po, At, Fr, Ra, Ac, Th, Pa, U and Np were separated by chemical proc- esses and Identified by their radioactive properties. Activity measurements were carried out with a standard end-window counter [of MCT-17 (MST-17) type] and scintillation counter with ZnS(Ag) crystal. In the obtained uranium fission and spallation products 42 nuelides in the interval of A = 188 - 237 with a half-life T from 20 min to 140 days were identified (see Table 1). Relatively high yield of neutron-excess nuclides was observed. Data were obtained by interpolation. From the experimental and interpolation results distribution curves according to the mass number were plotted (Fig. 4) and It was demonstrated that nuclides with maximum yield are distributed close to nuclear stability curve. Distribution curves for theelements Z-