SCIENTIFIC ABSTRACT MEDVED, R. A. - MEDVED, T. YA.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033220012-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MEDVED', R.A.; SEREDININA, N.V.
Hygienic characteristics of working conditions in the case of
electrostatic spray painting. Gig. truda. i prof. zab. 4 no.6:
7-11 Je 160. (MLU 15:4)
1. Meditsinskiy institut, Gor'kiy.
(SPRAY PAINTING-HYGLENIC ASPECTS)

-"I;- @: , ;.@ 1--w7-', @-'- -,'*,~7,-,if-~117~ii~A~~-~zR'-,

1111q:1.11. Ilp
.'Ij. p.l..Id (I p
P.p.: ... ... .. jI.Au'.'!
-.1-A... . P"
d.... Ta
,-d X 0 9 A.,
T,
Iq - I I
.43 J. T..
'1411- ":qll 1.11u. :11.@
SIA
. ........ .
VJ' -tl-" At--U-42TH PUT,

0,-
.4 U:.
JO
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qj v.j.. Cq
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tq Iql ..d T
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.21
.941 ... 9 -(1 219
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ul _"I 06, J. .... U@41
uol%..o ..Oj. I-I%U@--i
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,:;z 1/. 6 y 0 ()
AUTHORS:
S/05YA%/02/58/061
B
Boo6 B014
Amaglobeli, ff. S.,Golovin,-B. M., Kazarinov, Yu. M.,
Medved'. S._jf., Polov,".
TITLE: Determination of the Coupling Constant of Pion - Nucleon

Determination of the Coupling Constant of S/05 6V/'098/02/58/061
Pion - Nucleon Interaction From the Cross Boo6YBO14
Section of Elastic Neutron Scattering by
Protons at an Energy of 630 Mev
values by the function x26np 0@), the authors used a series of experiment-
al functions, ranging from linear to parabolic functions of the fourth

E02286
Determination of the Coupling Constant of S/05Y6 38/02/'8/061
Pion - Nucleon Interaction From the Cross B006 B014
B
Section of Elastic Neutron Scattering by
Protons at an Energy of 630 Hev
with m >4 because these terms are small compared to the error of more
f2

S/120/62/000/005/017/036
E192/E382
AUTHORS: Zinov, V.G. and MedvedL,_ S.V,
TITLE: Smoothing of the time intervals between randomly
distributed pulses

Ir
S/120/62/000/005/017/036
Smoothing of the time intervals ... E192/E382
amplifier then generates a pulse whose duration is m---. This
pulse actuates the generator, whose natural period is also equal .
to 't-,: . The operation of the generator is only possible in the
presence of the pulse from the limiter. The number of output

'11@1-@ Z-,

ACC NR: AP7012413 SOURCE CODE: UR/0367/67/005iOOl/Ol46/0149
AUTHOR: Golovin, B. M.; Zullkarneyev, R. Ya.--Zulkameev, R. Ya.; Kiselew, V. S.;
Medved', S. V.-Itedved, S. V.; Nikandrov, V. 1. Pisarev, A. F.; Semashko, G. L.
ORG: Joint Institute for Nuclear Research (Obl'yedinanpyy Institut yademykh
issledovaniy)
TITLE: Spin correlation during elastic scattering of polarized 605 M
protons on protons

ACC N% - ' APM124U - - ' - - -
for examining the photoplates. Orig. art. has: I figure and 4 formulas.
C13ased on authors f Enge Abs 9-EaRst 40,39
9 -

pmWTIM 1 11. lie..
V
organophosphorus compotinds, XT VY. S th i
2yn ests o anit-
AT"IM-111MIC
=qu
IT111. @-- , WeL hil.
Natok 1050. 615 in; cr. C.A. 43@ 57411e; 44, 7257f. -1 Ftrit fit '
Wf 0),P wh If CfItf, 11 -7 firs .with cotit jution-.1 relnov;1I or rIK
lit a Stream of (try ait, gave .31"01/10 IcIm'(:o .1
XORI)-., ll@
119 20*' Lfm. This (1.115 g.) kcill 8
11.3ys at mom tetrip. with 10 nil- 250 NU4011' lhu[$ mliell
9
If/ Tvirtin, gave all oil and a solid wreh all (. (it. Wi0i'M10
I -K
gave lift mistnted anit. (if unrenctcd ester, ho It 1 121; ille
Mt0411SOL (-rYstnI9,,nj. IM4 (fron, kh'q. t@[fjl I.CqI I&), w t
L- . I . --- .. - .I- V
tinlt5 with
widely differcill. tilm
2ml f S@qicn. collsts. are
llet)r I,,. A
I)bcllnl Pill Im It-ill and with alizarin red
'@iljjj)ler fitepti. Ls also give- I)ry par-aform (,41191411- zll
9.) Ill a 2-Lautnelar w-u; tre-atc-114-tv %vill'
g. 1,Cl,, t1jell lipated 5 firs. in
CILto' nave rogf-ii4f) g.
W;ls slowly 11(f,jed a( 2' 1,) IW
):I', nj,* 1.4983; thi, (50 9-)
fitoll, let stand overflight null -Ii'-I -d., Ot!1'"'119
A';
(72%) 0C11f1'(:(Wrj)"
---' .. .. - .1-, "", .. ,

MVM I T : Ya.
. . -USSR/Chendstry - Organophosphorous Jan/Feb 51
Compounds
"Brief Co=unications: Toward the Synthesis of
Aminomethylphosphonic Acid," M. I. Kabachnik, T.
PA 174TI3

OADWIation of Amil2c
11669d') M. I. Kabac
Bei. iYSSR
"It Ak Nauk SSSR, Ot
Fouid -that N-alkylat
Tabophotaic - acid (I-)
MejO04 Alm - alk, soln-r
P,unalogue of betsim
vi2q% reacts vith i
Pro4udts of incomple
:=Wds. Couditio
betaine-And Il -ar
be@ug caused bY d
gvoup and difficu

@ T L
IZIDUD, T. Yd.
Chemical Abst.
.. . 1.1 t- ^
/ The readton of qp A, ; ,,
"H"

-'_1 . . . . . . . . . .

J.),

V'y Inc and T.
11 It S
rg. soe4d' 41 5bernik
SIO )VOZ Cl. L-A.
49, 944b; 46, 421c; Chj@anc, C.A@ 43, 124b.-Ffeating
50 g. CICII,P(O) (OEt)2 and 240 mi. 2.5% N114011 in scaled
tub" I [it. at 150' (the: tutics are best heated in an autoclave
or bomb with suitable countcrprcv@mre of about 25-30
atm. to ptevent rupture) and evalin. of the contemts on a
steam bath gave a sirup@ This, in small vol. of H&O wai
shaken with 36 g. fre.,h moist A&,O and'filtered. The
filtrute wivi firecd (if Ag with HA filtered and the filtrate
alid wash 11,0 combined and evapd. to constain vol. The
yellowish residue wim Inkrn up in Amall vol. of 96% HtOlf
and treated with HtOH -Iti, -f M g. PhNHI (2 molcs per
mole of original c%ter). After prolonged strinrli- - --- -

tgo/chemistry
fte Reaction of PI
UniiLturated Ketonei
Ust of Org Chem, j
"Ti A Naukj Otdel
adds to cYcli(
cyclic 9-1
qY0110 P-'ketophbSpI
a.re:, obtained by ad(
I"tLtd ketones v:
this, ester which is
pboapbonic acids a:
iA6nes refutes Cv
at:Aie addn reactl

T. Yao
77777@=,
Organo-Phosphorai. :3.1 4ii7'52
-"A New Method of Synthesizing alpha-Aminophosphonic

"A Wev Method of S
Acids - 'Reaction o
phites and Ammonia
ftbachnik, Inst of
CV4 "Dok Ak Nauk SSSR
01%
In a previous pape
No 5, 1952, a new
phonic acids from
kylphosphiten was
is found to work e
It can be used to
free acids. The r

MEDMI# To Yao
KMVMI, T.U.; KABACEIRM, M.I.
New synthesis of aninophoq2hlnic acids. Report no.2. Reaction of
ketones with dialkylphosphites and ammonia. IsY.AY SSSR. Otd.khln.nank
no.2:314-322 Kr-Ap 154. (MLRA 7:6)
1. Inatitut organichaskoy khimii in. N.D.Zeliuskogo Akademli nauk
SSSR.
(Ketones) (Phosphites) (Ammonia) (Phosphinic acid)

MT. 46d the N, V:"

t , W,
-"A h-- I li'@o,eyan-ate-A@
or
M-:thiovhdi3i)hiiA,~,.i6i(i"6iit--a -

Pro
ld r?
an IS6 a c
R
@
ad L@@Ml

@mth@ worL with Katsnachwlk 64 z
26
.6its

1M
tile unqjd@lqcxtij@
@itzictl
the resldpAl mltzLtt@`
t.@c .151traic ev4pd.-,
ovap4..-
aled'
led after, stand lqg'2 4
ttaine lim 4n acidi
in Wcorib@,tltrate
!ailai,i,
4H;PO4.; kleatin
aealcd tmbt
ive, aii -oodistillahl
with Akio@ flIttrad
@d.@ and the resid
Cjj@@:abS. rI"Cj5'4-j T
.r3t. e,.tir (1.05
@h @@ith 'r)% Nam'

A!7:
ai r rl-ent -@ri t 1-.r
ya-@-@n !-I- Del 51@

. .
I IN f!j" ...........

0 w-as @,.dd-,4 Il
To 19 C011112 ki. 40 ull. -11,4111 a,.-
M @N
IMS 6ymiglut a@
rrA-,Ili te y dbig, a ppt

P 0,
@
I
j
le
t
-
W
artrud bi@ 3z-- -
-15aa all ww;Uv,@ -.4
M jr-:c0qw.

A -IjUgil
vi@l @li -M-Of4OW

`f
7

MEDMI -T I.. ..: - KARACMilK, K. 1.
Acylation of aminoalkylphosphinic and azatnoaliqlthiophosphinic
acids by chlorocarbonic asters. Izv.AN 3=.Otd.khim.nauk no.3:
327-331 Mr 156. (KLRA 9:8)
1. Institut alementoorganicheakikh soyedineniy Akademil nauk S;&M.
(Phosphinic acid) (Formic acid) (Acylation)

@ MEDVED'. TJ&.;-,KMCHNIK, M.L.
Derivatives of t4-aminealk7lphoisphinic acids. Raters of rw--ise-
eyanatoalk5rlphosphinic acids and their conversions. Izv.Aff SSSR.
otd.khim.xauk ne.6:684-691 Je 056. (muu 9:9)
I.Institut elamentoorganicheakikh soyedineniy Akademii nauk SSSR.
(Phosphinic acid)

,,fZDVEDt) T. Ya. (Inst. Elementary Organic Compounds As UsSR)
"Synthesis and Study of the Properties of Aminoalkylphosphinic Acidan (Sintez i
issledorvaniye svoystv aminealkil-foofinavykh kislot)
,d Uses of OrF-anoPhosPhorous Ccn'poundf;
r,v,,-rii -qtr-v a - --nnieheskikh s)YcdncnJ-Y

M @ 4 u 2,1 J , -i&t
AUTHORS: iledved', T. Ya.,.Kabachnik, bl. 1. 62-11-9/29
TITLE: Sjnthesis Of Aminoa lky lphos phonic Acids (Sintez -In afkcmykh
kislot) Reaction of Some Heterocvc.Lic iietones with Dialkylphos-
phites and Ammonia (Reaktsiya nekatorykh geterotsiklicheskikh
ketonov 9 dialkilfoefitami i ammiakom)
PERIODICAL: Izvestiya AN SSSR, Otdelenie Kllimicheskikh Nauk, 1957,
Nr 11, pp. 1357-1362 (USSR)

Synthesis of AminoFtlkjl;,,Iioep-ionic Acids. Reaction of Some Heterocyclic 62-11-9/29
Ketones vith DialIqlphosphites and Ammoula.
was apviied:
influence of dialecjlphoaphites or, '4--tones undfr I@r-,.13F-%Ce Of J@,-
diara-alco',iolate. There ure Ii Slavic references.
ASSC)CIATION: lx@utitute for @;le"aunt-urga!"ia Cumpot'Ids of the Ali j@Sq 'I,--
3titut ule,-,,eritoorganioheokikh sojedinenij jlk-ide!;@,il :1-11k "Z31)

AUTHORS: Kabachnik, M. I., Mpdvt-d' T. Ya.,
-Senyavin
Kozlova, G. K., Maid-
Tikhonova, L. I.
TITLE: Synthesis and%stivgof the Complex-Forming Prop,@-rties
of Several Or,@anophosphorus Compounds (Sintez i ispyta.-.iya
kompleksoobrazuyushchey sposobnosti nekotorykh fosforor,@a-

Synthesis andTestingof the Complex-Forming Properties SOV/.
of Several Organophosphorus Compounds
ethylenediamine and dialkyl phosphites and aldehydes
(or ketones), esters of ethylenediaminodialkylphosp-i_,-.:'.c
acids form. By saponifying these @sters the free acids
can be obtained. The complexing properties of the

AUTHORS: Medved' , T. Ya., Kabachnik, M. I. sov/62-58-10-9/'25
- TITLE: @-Ethyl Mercapto Ethyl Phosphites and Some of Their
Properties ( fl-etilmerkaptoetilfosfity i nekotoryye ikh
avoystva)
PERIODICAL: Izvestiya kkademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1958, Nr 10, pp 1212-1218 (USSR)

@ -Ethyl Mercapto Ethyl Phosphites and Some of SOV/62-58-10-9/25
Their Properties
PC13+ 3C2H 5SC2H4OH + 206H5 N( CH3)2---+ 2C6E5N(CH 3)2-HC1 +
+ C2H5SC2H4C' + (C2H5SC2H40)2 POH
Similar to this synthesis of di-R -ethyl mercapto ethyl
phosphite the ethyl-P -ethyl mercapto ethyl phosphite could
be produced. Some properties of the synthesized 8 -ethyl

,q -Ethyl Mercapto Ethyl Phosphites and Some of SOV/62-58-10-9//25
Their Properties
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk
SSSR
(Institute of Elementary Organic Cappounds, Acad=W of
Sciences, USSR)

1 .3630
.UTHORS: Kabachnik, M. I., Medved', T. Ya.
77070 2 - 1,4 //4. -.?
sov/62-59--- I
'ITIE: Vinylphosphonic Acid and Some of Its Derivatives
IERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
---- -- I- -,I,- -,I,- 1--l

inylphosphonic Acid and Some of Its Derivatives 77070
SOV/62-59-12-14/4--?
(1 x 10-4mm); n 20 1.5571. The acid dichloride and
D
trimethylene glycol, in the presence of triethylamine,
form the cyclic trimethylene ester, In 53% yield; bp
129-13CO (2 mm); n20 1.4775. Diethyl vinylphosphonate
T)

I
.Vinylphosphonic Acid and Some of Its DerivatiFes 77070
sov/62-59-12-14,/43
1 U.S., 1 U.K. The U.S. and U.K. references are: G *
M. Kosolapoff, J. Am. Chem. Soc., 70, 1971 (1948); A.
Kinner, E. Perren, J. Otlem. Soc., 34'J7 (1952).
ASSOCIATION: Institute of Elementoorganic Compounds, Academy of
Sciences, USSR (Institut elementoorgqnicheskikh

3/020/60/135/004/022/037
B016/B062
AUTHORS: Kabachnik, M. I., Academician, Medved', T. Ya., and
Polikarpov, Yu. M.
TITLE: Phosphine Oxides Containing the Vinyl Group at the Phos-
phorus Atom

Phosphine Oxides Containing the Vinyl Group S/020/60/135/004/022/037
at the Phosphorus Atom B016/B062
dity of this reaction for compounds of the type PC1 39 RPC1 21 and R2PC1.
They proved that the P-ohloro-ethyl ester of diethyl phosphinous acid is,
when heated, converted into compounds of pentavalent phosphorus. The
authors succeeded in isolating the two products of the regrouping of
(nnf avn1ainAd In the text) at the same times a) B-chloro-ethyl

Phosphine Oxides Containing the Vinyl Group S/020/60/135/004/022/037
at the Phosphorus Atom B016./Bo62
oxide. Mention is made of a paper by M. 1. Kabaohnik, Chzhan Zhun-yuy,
and Ye. N. Tsvetkov (Ref. 9). Table 1 contains the formulas of the syn-
thetized compounds I - IX with constants and yields. There are I table
and 11 references: 10 Soviet and 1 US.

899UN8
5- ;@W 2?Cq I i2S7 ji53
AUTHORS:
TITLE:
S/062/6 1 Irr,.-,1'5C;2 /-,', 2
B1 1 5/B207
1, T. Ya. and Kabachnik, M. I.
Organophosphorus monomers. Report no. 2. cL-Chloro-
and a-bromo vinyl phosphonic acids and their derivatives

89908
S/062/61/000/002/004/012
Organophosphorus monomers. Report ... B115/B207
The aniline salt of this acid melts at 194-1950C. While the authors
tried to obtain an anil-ide of this acid, a dehydrobromination occurred,
and a dianilide of a-bromo vinyl phosphonic acid was separated. In

8", @-;
s I o62 '06 1 /000/010-2,; '- D4,; C; * e-
Organophosphorus monomers. Report ... B11NB207
apart from the addition of chlorine to the double bond, and the formation
of avO-dichloro ethyl phosphonic acid dichloride, a separation of
hydrogen chloride and simultaneous formation of cL-chloro vinyl
phosphonic acid dichloride. The two acid chlorides were obtained in

89908
3/062/61/000/002/004/012
Organophosphorus monomers, Report ... B115/B207
vinyl phosphonic acid were obtained from the reaction of a-chloro vinyl
phosphonic acid dichloride with alcohols. By interaction of the ethyl
ester with aniline, the dianilide of this acid was obtained. In

S I I 9C)// i !003/007/021 1021
15, Soso B-0-,/B230
AUTHORS: Tsetlin. B. L- Medved'. T Ya . Ch:kishev. Yu G , Poli-
karpov, Yu M ., Rafikov, S R , Kabachn:k. M T
TITLEt Radiation polymerization of tert,,ury mon-,:.v,.ny.phosph-. tie 6xi-
d es

Radiat@'cn pclymeriza*,icr. of
th,@s type of in' I iatcr .3, !. ther nc@ t pc 1 yiner al a.- r thtl i r p(. I y -
merization prcceeded ,,, an ex*,ieuiply 'rjw iu-c- e , y puo- y;e:i "He'.
2, see below) A uthors: ted expeT ,mer, I. s ' "a*, e Ymer @ 7. a', 1-on
of die thylvi ny' phosph,,ne ox:dt- (1) Eind ~l,,phL-ry'vriy'pt,.)sphir-li@ cy-de (II)
by radiation. Aa gourct, :Rdia!-,or, an X-ra.-,, apparLt-@s was

0
2111@277 S/190/61/003/007/021/021
Radiation polymerization of.... B101/B230
reprecipitated polymer (II) is about 1800C (determined by thermomechanical
method, Ref. 3: B. L. Tsetlin, V I- Gavrilov, N. A. Velikovskaya, V. V.
Kochkin, Zavodsk. lab., 22, 352, 1956)@ It has been proved hereby that
the radiation polymerization is an efficient method to obtain polymers
on the basis of oxides of monovinylphosphines. Mechanism of the process
i - I --- - - ---Ai _j - - - - - - - - - rA I., - 4----4.-- 1 - --*- . 0- - -I -*@ +- .I @ +j - I

V,
1 14 2-IC) 9
22515
5/062/61/000/004/004/006
B118/B208
AUTHORS. Kabachnik, M. 1. and Medved', T. Ya.
TITLEs Organophosphorus monomers. 3. Vinyl thiophosphinic acid and
some of its derivatives

2253,5
S/062/61/000/004/004/008
Organophosphorus monomers. ... B118/B208
thiophosphinic acid (III) obtained by hydrolysis of the acid dichloride is
sirupy. Its aniline salt melts at 105-1060 with decomposition. The acid
A4^h1nride (II) gives with aniline the dianilide of the acid
- - - -@4 -1 +V, a di P@11 A@i Ao (TT I wi +h

22515
S/062/61/000/004/004/008
Organophosphorus monomers. ... B118/B206
CH2-CHPO(OC 2H5)(SC2H4SC2H5) (XII); compound (IX) (as well as its isomer-
ization product (XII)) add an alcohol molecule, when heated with alcohol
in the presence of sodium methylate, and form the corresponding ester of
- - -- . .1

5 -2, (,::, 3 0
29521
3/062/61/000/01,//008,/0'2
B103/Bl47
;@UTHORS: Kabachnik, M 1, , Medved'-, T. Ya. , Polikarpov, Yu M@ , and
Yudina, K, S.
TITLE: Synthesis of diphenyl-vinyl phosphine oxide

29521
Synthesis of diphenyl-vinyl ph03phine..
to diphenyl-chloro phosphine was effected
of the former in the presence of AM and
PC13 formed, The yield in diphenyl-cLoro
I @' - 4 --1 . - -1 - @a - a . Q i I v rpn rn du n i h I P re
3/062/6 1 - @ I ui-@, -.' .@ *
B'07/B147
by catalytic dispropov',Ioli:11.@
constant distilliiig, (-f'r - '
phosphine was 70/o N, - @-@ :n: ,
qu I t s ,Di t o 1 v I - c h] o ro - oF, p r

29521
3/062/61/000,,'01 1/008,1/012
Synthesis of diphenyl-vinyl phos.phint,... B103/B147
Polikarpov, Dokl. AN SSSR, 135, s4q (la6o)). Isomerization of the
.1 , j
G-chloroethyl ester of diphenyl-phospnirious acid yields no" only the
products mentioned but also (a) ovinc to spontaneous dehydrochlorination.

10WIT
-1 @-Y A -.
PHASE I 1300K EXPLOITATION SOV16014
Konferentsiya po khimli i primeneniyu fosfororganicheskikh soyedinerliy. 2d,
Kazan'. 1959.
Khimiya i primeneniye fosfororganicheskikh soyedinerdy; trudy (Chemistry
and Use of Organophosphorus Compounds; Conference Transactions) Moscow,

Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
Organophosphorus Compounds held at Kazan' from 2 Nov through 1 Dec 1959. .
The material is divided into three sections: Chemistry, containing 67 arti-
cles; Physiological Activity of Organophoaphorus Compounds, containing 26
- DI- P,@tprtion. containinv 12 articles. The renorta reflect

7
Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
Andreyeva, M. A. , 1. A. Gribova, M. 1. Kabachnik, G. _ S. Kolegnikov,
, T. Y I
JV,-- E@grs a. Med (f, Yu. M. Polikarpov, Ye. F. Rodf6rova,
and L- S. Fecloro-Va-7nistitute of Organoelemental Compounds]. Some
Methods of Synthesis of New Organophosphorus Monomers and Polymers 263
This study attempts to develop new methods of synthesis of organa-

D!,-LYA., KABACHNIK, M.I., MOSHMI, P.A.$ VA.9SHAVSKTY, S.L.
KOFMAN, L.?., OMER., YE.L., TKACHENW, G.V., DANILEE-VICH, A.A.
Industrial method of synthesis of di-B,B chlor-ethyl of vinyl-
phosphinic acid from ethylene oxide and ohosphorus trichloride.
Report submitted for the 12th Conference on high molecular weight compounds
A-+-A +^ Pmlm- 'A-7 Any-4149

Bl 17YBle6
AUTHORS: Andreyevav M. A., Gribova, 1. A., Kabachnik, M. I.,
Kolesnikovt G, S,, Korshak, V. V., Medved', T. Ya.,
Polikarpov, Yu. M., Rodionova, Ye.-r., Pedorova, L. S.
3/08 621000102311191120
TITLE i Some methods of synthesizing new o -rganophosphorus monomers

4!85L
// , ..If I s/2o4/62/OG2/oo4/olq/01q
6-..- ?6 ", 9075/E436
AUTHORS: Kabachnik, M.I., Gefter, Ye.L., Moshkin, P.A.,
Medved'. T.Ya.
TITLE: Phosphororganic monomers. Review paper
PERIODICAL: Neftekhimiya, v.2, no.4, 1962,.639-651

'Oe
S/204/62/002/004/019/019
Phosphororganic monomers E075/E436
of M. Treatment of (II) with PCI 5gives CIC H2FH2 P CI2
11
0
-which can be used for the synthesis of amides and esters of
P-chloroethylphosphorous acids. Removal of water from (II) with
alcoholic alkalis. or heatinz over BaClq. 7jvpa ru-@ - - -- -

S/204/62/002/004/019/019
Phosphororganic monomers E075/9436
until recently the only available method for their preparation.
The phosphines polymerize easily by ionic or radical mechanism.
At the present time the polymerization of vinyldiethyl and
vinyldiphenylphosphines is being investigated under the action of
X-ray and chemical initiators. In general.- the

NOLESNIKOV, G.S.; RODIONOVA, Ye.F.; FEDCROVA, L.S.; MEDVED', T.Ya.;
KAWMaK, H. I. I------
Carbochain polymers and copolymers. Part 41: Synthesis,
polymerization, and copolymerization of vinylphosphinic
.deaO Vysokom.soed. 4 no.9:1385-1389 S 162. (KM 15:11)
1. Inatitut elementoorganichook-ikh soyedineniy AN SSSR.
(Phosphinic amide)

KABACHNIK, H.I.; MEDVED', T.Ya.; POLIKARPOV, Yu.M.; YUDINA, K.S.
--------
Reactions of vinyldiphemylophosphine oxide. Izv.AN SSSR.Otd.khi--
nauk no.9:1584,-1589 S 162. (MIRA 15:10)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Phosphine oxide)

KAMCBNIK# M.I.; MHDVEDI,, T.Ya.
Synthesis of methylenediphosphine caride. Izv. AN SSSR. Otd.kblm.
nauk no*3.lt2lO3-2104 N 162. OfM 15:12)
le rnatitut slementoorgenicheakikh qo7edlneui7a AN SM,
(Dipboophine)

S/079/62/032/010/004/008
D204/D307
AUTHORS: Popov, Ye.M., Tsvetkov, Ye.N., Changg.Jung-Ytt, and
Medved', T.Ya.
TITLE: Raman and ultraviolet spectra of some unsaturated
---in nnmnnunds of Dhosphorub

S/07 62/032/010/004/008
Raman and ultraviolet spectra of ... D204YD307
nal = CH2 group, and the UV spectra of CH2 = CH - C4H9 and CH2 =
= CH - CH 2 - (O)P(OC4H9)2 were practically the same, indicating that@ /
in these compounds there is practically no interaction between the . ,

- -j a'@a
ACCESSION NR: AT4033994 8/0000/63/000/000/0117/0122
AUTHOR: Korshak, V.V.; Gribova, I.A.; Andreyeva, M.A.; Kabachnik, U.I.;
Medved', T. Ya.
TITLE: Polymers containing phosphorus. X=. Heterocyclic polyesters of vinly-
--,-I --A --@gx 1r1VCYA$1

ACCESSION NR: AT4033994
Yields ranged from 23.2% for VI to 88.6% for 11, indicaring that penta-cyclic -;! I r5 are
the most suitable. StrucLural modification of the synthesized polyesters was tlj- 1,
attempted by the use of radical polymerization catalysts (benzoyA pero-ade, Lart. -k?!@ I
peroxide, tert. -butyl hydroperoxide and metallic Na; 0. 5,to 3. 0% by weight, 55-90C.
10-51 hours). 'nie po!ymers obtained were solids or simpar to factice rubber with

ACCESSION NR: AT4033994 - 2XcUq asters of vipylphoM&Inio a4d ENCWSURE: 01
TABLE I MR
D C. % H, % P, %

hemical formula B*P.
IC/mm 20
n 20
d Cal-
cula- bal-c-u-
lated .0 Calcu-
lated
D 4
ted 0
44
bR

)DDLESNIKOVt G.S.; RODIONOVA, Ye.F.1 FEDOROVAO L.S.; PRVED!q,-,T.j(@,-L-
NABACHNINj M.I.
Carbochain polymers and copolymers. Part 43s Synthesis,
polymerization, and copolymerization of aromatic asters of
vinylphosphinic and 4:-ohlorovinylphosphinio acids. Vysokom.
aced. 5 no.102-38 Ja 163. (MIRA 16ji)
1. Institut elementoorganicheakikh soyedineniy AN SSSR.
(PhAqnhinin AMA) [PnIvm&im4-2n+4^v%I

XABACIIUK, M.I. [Kabachnik, M.1.1,- GIIEF7ZR,, E.L.; MOSKIN, P.A. (Moshkin)
P.A.]; 12DWED, T.I.
Organophosphoric monomers. Aruilele chimie, 18 no,.3;62-76 ii-s 163.

K.MVEDI, T.Ya.; FRUNZE, T.M.; KIIU CIIIN-MEY; KURASHEV, V.V.; KORSHAK, V.V.;
-@-MAMMK, M. I.
Organophosphoris po4vamides based on methyldi-(m-amlnophenyl)phos-
phine oxide. Vysokom.soed. 5 no.9:1309-1314 S 163. (MIRA 17:1)
1. Inatitut elementoorganicheskikh soyedineniy AN SSSR.

- @ sifid blai-;- -. TZ
on'
I to' volymais @ d. the tylid 'I

@3 UW484i
Lideo-:- The--polyar4ldw-0-0
b W f 0- r' the -89'- x
a floi

ARKHIPOVA, O.G.; KOCHETKOVA, T.A.; RUDOMINO, M.V.;.MEDVED', T.Ya.; KABACHNIK,
M. I.,, akademik
Effect of aminoalkylphosphinic acids on experimental beryllium intoxi-
cation. Dokl. AN SSSR 158 no.5:1235-1237 0 164.
(MIRA 17:10)
1. Institut gigiyeny truda i professionalInykh zabolevaniy AMN SSSR i
Institut elementoorganicheskikh soyedineniy AN SSSR.

KABACTINIK,' M.I.j BALUYEVA, G.A.; NEDVEDI., Y@.j TMTKOV, U.N.; CRZHAN WN-
YUY lobang.Jung-Jul @ j__ _
Xinatics and mechanism of bromination of vinylphosphinic acid derivatives.
Kin. i kat. 6 no.2s2l2-220 Mr-Ap 165. (MRA 18:7)
1. Institut alementoorganicheskikh soyedineniy AN SSSR.

Yi Oi
jwj
ti Pol- @nr

ppTe p
,Iazid@ th -infr@@i@@or-
wa

MEDVED'.-T.Ya.; POLIKARPOV; YOULA, K.S., KABACHNIK, M.I.
SynLhesis of 9-ketophosphine oxides. -Tzv. M4 SSS*R. Ser. khim.
no.9:1707-1708 165. (PERA 18.-9)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.