SCIENTIFIC ABSTRACT NOVIKOVA, L. V. - NOVIKOVA, N. G.
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CIA-RDP86-00513R001237510012-9
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RIF
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S
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100
Document Creation Date:
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Document Release Date:
August 23, 2000
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12
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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AUTHOR: Novikova, L. V. 78-3-26/35
TITLE: Study of the Solubility of the System GaB04 - M9304
H20 at 3500 by a Traeer-Atom Method. (Izuehenive
rastvorimosti sistemy GaS04 - M9304 - H20 pri 350
metodom mechenykh atomov.)
PERIODICAL: Zhurnal Neorganicheakoy Xhimii, 1957, Vol.II, Nr.3,
pp. 662-668. (USSR)
ABSTRACT: Independent studies of the system CaB04 - M9304 - H20
were made using for the determination of calcium the
alcohol method and the tracer (Ca45) method. Measure-
ments were also made of the viscosity and specific
gravity of various solutions of the system. With the
aid of the traner method it was shown that the true
solubility of calcium sulphate in the system is less
than the solubility found by using the alcohol method,
which is probably due to coprecipitation of magnesium
with the calcium in the latter. With either method,
Card 1/2 the solubility curve at 356G. showed a minimum and a
NOVIKOl/4L'#L'."V.q(;nnd Chem "Sci-((Uss) "Study of salt cquilibr-An in the
!f2SO,I-l!tE;()4-CvSO4-'120 sy""m rtt 35",nnd 44o obttining of AWW prirv.~%ry
polyhalitc." h~oo, 195-5. 13 pp (Acad Sci USSR. In--t of 6czic;r,,.l aiad In-
organio Chemistry im. N.S.Num-Yov), 1130 copies (;-::Lt47-53vl3O)
LUTHORS: Lepeshkov, I. IT., Novikova, L. V. 70-3-5-35/39
TITLE: On the Formation of Primary Polyballte (X voprazu ob
obrazovanii pervichnogo polifalita)
PERIODICALt Zhurnal Neorganicheskoy Khimii, 1958, Vol 3, Nr 5,
pp 1261-1264 (USSR)
ABSTRACT: Experiments for the explanation of the process of
formation of primary polybalite . viere carried out at
350C by the evaporation of ujnthetic solutions by ad=
ding acqueous calcium sulfate solutions.
The chemical analysis of the obtained deposit showed
that more than 95% of the deposit consistsof purest
polyhalite - K SO LISSO 2 CaSO FT,O
2 4 4 4
The microscopical investigations confirm this result.
It results from the thermographic curve that a complete
dehydration of polyhalite occurs at 32ooC and that
melting begins at 88o0C.
The formation of primary po4hallte -ias confirmed by
the chemical, crystallo-optical and thermographical
Card 1/2 analysis.
On the Formation of Primary Polyhalite 78-3-5-5-35/39
There are 4 figures, 3 tables and 9 references, 5 of
which are Soviet.
ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. 11. S.
Kurnakova Akademii nauk SSSR (Institute 'of General and
Inorganic Chemistry imeni N. S. Kurnakovlks USSR)
SUBMITTED: December 28, 1957
AVAILABLE: Library of Con3ress
1. Polyhalit-e-Preparation 2.
3. Folyhalite-Dehydration 4. calcivia Sulfate -Applications
Card 2/2
AUTHORS: Lepeahkov, 1. N., Novikova, L.V. SOVf78-3-10-27/35
TITLE: Physicochemical Investigation of the K 2s0 4-ugso 4-CaSO 4-
H20 System at 350(Fiziko-khimichoskoye izucheniye sistemy
K so _MgS0 -CaSO -H 0 pri 350)
2 4~ 4 4 2
PERIODICAL: Zhurnal neorganicheskoy khimii, 1958, Vol 3, Nr 10,
pp 2395-207 (USSR)
ABSTRACT: An investigation was carried out at 35 0C of the solubility
of the salts, the viscosity and specific weight of solutions
of the system K2 so 4-ugso 4-CASO 4-H2O,as well as of the
ternary systems K 2so 4_MgSO 4-H20 'K2 SO 4_CsSO 4-H20 and
Caso 4_Mg30 4H 20 belonging to this system. In the investiga-
tion of the four-component system the following salts were
ascertaineds polygallite -(K. so 4* MgSO 4* 2CaSO 4* 2H 20)-'
singenite -(K2so 4' Caso 4_H2O)_' gvpsum-(CaS04' 2H 20)-'
K2 so 4* 5CaSO 4*H20, schenite- (K2so 4' mgSO 4* 6H 20 )-, epsomite -
Card 1/3 ugso 4' 7H2 0 ) and arcanite( K 2'304), Polygallite is formed
PhysicochIemical Investigation of the K2so 4_*SO 4- SOV/78-3-10-27/3115
;Ca So -H OjSystem at 350
4 2 1
in the system analyzed at 35 00 only in the range of higher
concentration of magnesium sulfate. The crystallization
range of pollygallite is extended considerably when
temperature is increased. In the solid phase of the system
polygallite is at 35 0C in paragenesis with gypsum,singenite,
schenite and epsomite. In the potassium deposits of the
Volga-Emb and the Carpathians , polygallite is in paragenesis
with the following sulfates: anhydrite -,(Caso )-, gypsum,
kieserite-(MgsoV H 20)-, langbeinite -(K 2 SO4. 4 2MgSO 4)_
and glaserite -( 3 K 2soV Na 2s04). The results of the
solubility of the ternary systems correspond to those
obtained from the investigations of viscosity and specific
weight of the systems. The results of the physicochamical
analysis of the four-component system K 30 4-MgSO -CaSO -
H 0 are of i portance for the explanation of thi formition
of natural pomlygallite. The formation of polygallite in
nature,which is caused by evaporition of sea water, takes
Card 2/3 place probably at relatively low temperatures ( 1o-35 0G -
physicochemical Investigation of the K 2S0 4-3(gso4 507/78-3-10-27/35
0 CaSY20 System at 350
There are 16 figures, 4 tables, and 27 referencest
14 of which are Soviet.
ASSOCIATION: Institut obahchey i neorganicheskoy khimii im.N.S.Kurnakova
Akademii nauk SSSR ( Institute of General and Inorganic
Chemistry imeni N.S.Kurnakov of the Academy of Sciences-,USfSR)
SUBMITTED: September 6, 1957
Card 3/3
W)IEW(j)/T Pr.-4 FM
L
T-CC ON 1qR: APS002808 S/0078/95/010/001/0294/0296
AUTHOR: 1UgdjM&. L. V.; BelyUey- L N. 4
TITLE: Investigation of the solubility of potassium sodium, barium and lead ti-
tanyloxalates
SOURCE: Zhurnal neorganicheakoy khtmii, v. 10, no. 1, 1965, 294- 296
TOPIC TAGS: solubility, potassium titanyloxalate, sodium titanyloxalate, bari-
um titanyloxalate, lead titanyloxalate
ABSTRACT: The polythermal solubility of K, Na, Ba andgb.LUaL1dqA&L-A"tEk8
deter-nined. K2TiO(C204)2. 2H20. was the most eoluble,- its solubility increased
, ____ I IZZA f- AA '41 wt. 96 from 10 t3 60 C. The other compounds were fairly in-
L 34507-65
ACCMSICN NR: "5002808
SUBMITTED- l5Apr#4 ENCL: 01
NR REP SOV., 004 OTHER: 000
SUB CODE: GC,
.... .. ..
34507-a
ACCESSION NR- APS002808
FNCLX)SLTRE: 01
E
48 X 0 79 A? N t T
Fig. I
Solubility polytherms of sodium, barium and leact titanyloxalates
0
1-- 3odium titanyloxalate Na2TIOf C2 4)2- 2H20 barium. titanyloxalate
Card '3 13
NOVIKOVA, L.V.; KHIDIRBEYLI, Kh.A.
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