SCIENTIFIC ABSTRACT PAUSHKIN, YA. M. - PAUSHKIN, YA. M.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

'41

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/J 4
USSR/Yinetice Combustion. Exploeions. Topochamistry. Catalyeis. B-9
Abs Jour : Referat Zhur - 1(himiya, no 6, 1957, 1864c
Author : -Ya.M. Paushkin, A.G. Khil'zonrat.
Inet : hcftderor -ofSpiences of USSR.
Title : Formatioti of Eanzone Homologueo and Spocial Part of flurfa-
cc in Thermo-Catalytic Transformationo of Isobutylene in
Presence of Bcron Fluoride.
Orig Pub : Dokl- AN SSSR, 1956, 109, No 5, 958-961
Abstract : Stu~ied were the catalytic tranc~formation of isobutylene
in rrese:ice of boron fluoride aelsorbed on activated carbon
BA, I (I), on Alf, (II), on silicagel (III) or on an alu-
mosilicate (III n a flowing sytitem at 100 to 5000 and a
volumetric opeed of 60 to 65 hours-1. Mainly the polyme-
rization Of C4H8 together with the formation of 15 te 20%
saturated products in presence of II, III and IV was ob-
served at 100 to 20CP. The reaction did not proceed at
400o in presence of 1, but in presence of II the
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AUTHORt PAUSHY,111,YA.M., OSIPOVA,L.B~, KHERSHKOVETS,H. PA - 2764
-
'TITLEr 'TK`e7S-y
n_tE_es_1s_of Nitryls from Alcohcls and Ammonia on Oxide L"atalysts.
(Sintez nitrilov iz spirtov i &=iak;a ma okienvkh katalizatorakh,
Russian)
PERIODICALt Doklady Akademii Nauk SBSRg 195T, V,31113, Nr 4, pp 832 - 835
(U.S.S.R.)
Receivedt 6 / 1957 Reviewed, 7 / 1957
ABSTRLCTs In the course of recent years materials are pr6duced by the ton
which hitherto have been difficult to obtain. This is also the case
with nitryls. Thus, acrylonitryl and dinitryl ot adipin acid are
already being used for industrial purposes, and the same is the
case with seetoni-tryl and other nitryle of fatty acids. In addition
there are inexpensive raw materials such as gaeous hydrocarbons ob-
tained from mineral oil cracking as well as low-oolecular paraffins.
$everal patents coneern the aitryl prodtiction trom ammonia and
alcohols. The authors investigate the reaction of ethal- and isoamyl
alcohol in the presence of the alixmo-mclybdenum-oxide catalyzer,
1cetone nitryl was ldentified'by a series of qualitative reactions,
~y physical-chemical constants, and by the production of the condensa-
tion product with floroglucine. In the course of experiments carried
out with ethanol the influence exercised by temperature on the
acetone nitryl yield was studied. It begins to form at temperatures
Card 1/3 of more than 3500 and the yield increases with growing temperature

PA - 2764
The Synthesis of Nitryls from Aloohols and AiLmonis. on Oxide Catalysts.
(4 tables, 2 Slav citations from Slav publications)
ASSOCIATIONt Instituto for 11i#eral Oil of the Academy of Soisnee of tho U.S.S.R.
PRESMID BYs A.V.TOPCIIIYZV, Member of tbo Academy
SUBMITTEDs 12-10-1956
AVAILLBLEs Library of Congreev
Card 3/3

_ 7_ 1Z
62- 5'J
v e v A Prokhorc-ra, A. A. , Pa u sh' i r. Y,a
o p__c 1i i.
Xuras'nev, V.
"'I !T
Irv,,:sti,,-ation3 in t1he Field of Boron -Com pound s
v oblasti soyedinc-niy bora) 1. 2he Synthesis of '.'riillyl-
buron (_)oubs!~cheniye 1. Sintez triallilbora)
i1ERIODI CAL: Izvestiva Aicademi'. Nmik SSSR Otdeleniye Fhimicheskikh Nailk,
1'45t~- Nr 3, ;)1)- 3`0 - 371 (USSR)
A S2RA ~,T 3oron compounds arc- most detailed investigated. As reFards
the unsaturated compounds the description of their chemical-
and physical properties (as iiell as the methods for their
production) became known relatively late. With restect to
triallylborori there is only cne reference. In the 1resert
work the met-iods for the synthesis of triallylboror. or bo-
ron fluoride, matne3iumbromoL.Ilyl, and boron trich1firide
are described. In order to prevent the fDrJAion of reaction
side products the reaction of the synthesis of triallyl-
boron in preparim- the GrigllLrd reagent (allyllialide and
Card 1/2 magnesium) was carried out in o-ne stage; that is to say,

InvestiUation in the Field Df Bc,ron-Compounds
62- 58 - 3- 2 3/ 30,
without precedin,~ synthesis of' ally1magnesiumbromide.
There are 6 r-efercnces, 3 cf which are Soviet.
ASSOCIA'.'ION: Institut riefti Akademii nauk SSSR
( Petroleum Institute AS USSR)
SUBMI'27PED: October 16, 1957
Card 212

SOV/ '65-58-11-2/15
AUTHORS. Mazitava, F_ N_ and Paushkin, YA.
TITM-, - New Oxidation Inhibit 6rid-for-Fuels and Additives for
Inoreasing the Thermal Stability of Reactive Fuels
(Novyye ingibitcry okislenlya topliv I prisadki dlya
povysheniya termle.heskoy stabillnosti reaktivnykh topliv)
PLFRIODICAL: Rhimlya i TelLhnclogiya Topliv I Masel, 1958, Nr 11,
PP 10 - 12 (USSR)
ABSTRACT: Standa.-d additIvas suoh as0-naphtol, parahydroxy-
dephanylamire and lonol are riot entirely satisfactory.
Amincphenols are 4ery effective as anti-oxidants and
are practically Insoluble in the fuels. AmInoalkyl
phencls vicre dee:-rlbed in ;arious publications (Refs-2-4).
The aith,;rs des%,,ribe the synthesis cf aminualkyl phenols,
allcy! phan3..9 and their esters and tabulate the anti-oxi-
dant properties of these substances (see Table). Monoamino-
Alkyl PhenOIB, especially 2.6-diamino-4-tert-butyl phenol
were found to be Ynore satisfactory than the standard
9.ddlt!',,e~q. Tests on the Inhibition of tar formation In
kerosine, which contained craoking oomponents, were car-
Card 1/2 ried ot~t on the apparatus LSA~ The chemical stability

()V/C)5 -5 B-11 -2/ it
New Of,dation f,).,' Fuejs and Additi7eS fOr Inareasin.17 the
Thqrmal Stabllit7 cf Reac:,cive Pl-,qlaz
cf ora~-,,rg pot-rcisam was d1rfined a.--.ording to the in-
du(,tl,-.--. Xlau~i-loi3OLL-71phencls wore m:~!,e effective
Zia 6t'fp-(,t of the:3e additives on the
f~rzmatlt~r of der.--st,.4 In tY-3 standard fael T-1 was also
1YNS3t1.,ZF,.t161 (aee Fjfru.-,s). Th6 addi,clcin of o-,amino-p-
t,~-.7-1 , ~-.111-31 pi; E.-, 0.'&' redUC 3 3 the f ormati -.m of deposits to
T.Nire are - Figui-e.. 1. Table and 5 References:
Scviet and 2 Eng)-is.'n.
ASSOCIATION: 1r, Lit, I tut AN .536-H ~!:,-.;~tltut-e of PetroleurrijAs MSR)
Card 2//'-p

PAUSHKIN, Ta.M.; OSIPOVA. L.V.
Production of acetonitrile by the reaction of paraffin h7drocarbona
with am~ionia in the presence of oxide catalysts. Trudy Inet.nefti
12:304-320 '58. (MIR& 12:3)
(Acetonit:~ilol' (Paraffins) (Ammonia)
W,

ZHOIVV. A.K.. PAUSITYIN, Ya.,14.
Catalytic pasiflentinn nt' petroleum residue I:n ensen contair,
Ing olpfines. Izv.vys.uc-hn1).znv.; neft' I gav 1 no.11:
1 85-90 158. (HIRk 12:5)
1. moskovokly Institut nAftekhimichr-skoy I puznvoy promyshlenno-
ott In. almd. I.M. GubkIna.
(Petrolnum Influstry-My-producta)

S S A
!'i ctr IE?Lr L;S, 11
orl.:

11 (4) . 5(3)
AUTHORS: Paushkin, Ya.-M, , Maz i t o v a, F IN. SOV/*52-59-3--4/2-,
Kurashev, M. ~_
TITLE: The Principlcs and Some Resui,-,s in 1he Field of the
Davelopment cf Antioxidant Additionzi to Fuels (Osnovr.,yyP_
napravleniya i nekotoryye rezulltaty v oblasti razrat,-tk-.
antiokialitelinykh prisadok k toplivam)
PERIODICALi Iqvestiya vysshikh uchebnykh zavedeniy. Neft' i gaz,
N-- 3, pp 67-73 (USSR\
kBSTRAM The increasing utilization of the p:?oducts of thermal crack~Jng
as fuels and the raised demands as to stability require the
investigation and production of new oxidation inhibitors
Especially impcr~ant is the thermal stability in flying Lit
supersonic spetd, From foreign publications and patents thp
additions of alkylated phencln in tae amino group of alk~-IELted
phencls and phenylene diaminefi are Nell-known. The aut~-,_rs
examined the efficiency of a
Card 1/3

The Principles and Some Resuits in the Field of the SUP 52- 59- 3-' 4/2 5
Development of Antioxidant Ldditions to Fuels
period of stability in min
4-propyl-2-ami.nophenol (not given)
4-tertiary butyl-2-aminophenol 270
4-tertiary am~,1-2-aminophenol 240
4-tertiary butyl-2,6-aminophenDl 540
dimethylphenyl-m-amino-n-oxyph.gnyI methanD 240
dimethyl tertiary butylphenol 120
An addition of 0.04% of the in:-iibit.or to ethylated gasoline
B-95/130
at 110OCon the basis of a begi=inf; turbidity, i. e. the
begini.ing of the formation of decoripoaftion- and oxidation
products of tetraethyl lead. T..,ie monoamines of the alkyl IDhenG.'s
secure the preservation of gasoline for at least 1 112 years,
Diaminobutyl phenol shows the `iighest stabilizing efft~ct. The
effect with respect to resinification and formation of
precipitation was also investi,?ated. Amincalkyl phencls 9~.cwed
a good stabilizing effect the ')est, however, exhibited
2-amino-4-tertiary amyl phenol. A prolongation of the alkyl
Card 2/3 chain increases the efficiency. Synthetically produced
was investigated. The per' 'od of stability was determined

The Principles and come Restilts in the Field of the SOV/152-59-3-14/25
Development of Antioxidant Ldditions to Fuela
aminoalkyl phencls have a high ant:Loxidant effect on
ethylated gascline, cracking gasol:.ne and jet fuels.
B. L. Kozik, Ye. N. Kornilova, Z. 1- Sablina and Ye. G. Chudinava
assisted in the investigation cf the synthetically produced
compounds. There are I figure, 6 tE~bles, and 11 references,
2 of which are Soviet.
ASSOCIATIONt Moskovskiy institut neftekhimicheakoy i gazovoy promyshlen., 'osti
im. ELkad. I. M. Gubkina (Moscow Institute of Petroleum Chemical
and Gas Industry imen' akad* M. Gubkin)
SUBMITTEDt September 29, 1958
Card 3/3

TOPCHITXV. A.V.; PAUSHKIE, U.N.; RAYRY, 1.7.; KURASHIV, N.V.; SHULESHOV. 0.1.
Present status of the e7nthesis of benzene hooologe and their chemical
processing. Trud7 MINMGr no.24:269-285 '59.
(MIRA 13:3)
k Boris ene )

PAUSHKIN, Ya.14.; ORWV, Kh.Ta.; KATSOBASI[VILI, Ta,.R.
Isomorization of h-paraffinic hydrocarbone (C,,-CJ8). Izv.
vya.ucheb.gav.; neft' i ga2 ? no.9:57-62 '59.
(141RA 11:2)
1. Honknvakiy inntitut naftskhlmi.,.heakoy i gazovoy promyahlonnostl
imont akademika I.M.(hibkina, Institut neftekhtnichaskogo ointeza
AN SSSR.
(Isonarizution) (Hydrocurbone)

5)(3)
AUTHOPS: Laushkin, Ya. M., Osi '%ova, L V. , 5 OV/ /74 - 2-2
(-117--
.ofj c ()w7-
TITLE: Properties, Production ar,d Use )f Acetonitrile (Svojstva,
polucheniye i primeneniyE atsetonitrila)
PERIODICAL: Uspekhi khimii, 195), Vol 28, Nr 5, pp 257-264 (USSiC,
ABSTRACT: Gases of thermal and catalytic -racking, as well as paraffin-
hydrocarbons with a low octane number are increasingly usud
as chemical raw materialE. The industrial production of
acetonitrilt! is only delayed because there are at present no
cheap and simple methods available for its production. In the
present paper only those proper".ies of acetonitrile are listec
which are in some relaticn with its practical use. Also its
physical properties are cf inte---est: it is a colorl~--ss
0
with a melting point of -45.72 , boilin6 point So 060, 6.
20
0.7857 (Ref 1) 0.7828 (Rt-f 2) and n D 1 3441 (,I,-f 5). It %as
a high dipole moment, 3.44D (Ref 3) and a high dielectric con-
stant: 35.13 (Refs 4,5). The la- ter mi-'rht be the caus, of its
considerable dissolvin,~ el
'fect. Acetonitrile is frEquently
Card 1/4 used as solvent , as cci..pcnent in azeotroi~ic distillations and

Properties, Productior and U2e of Acetonitrile SGV/7"'-26-"-2/6
as chemical rais material. Presently mainly tne intcraction
of oxygen-containing com,~oands , pr~-,fernhly acetic ficid and
ammonia, is used for its proaaction in industry. Instead of
acetic acid ethyl ether may be also used. On the interactinn
of aldehydes and ketones with ammonia in the pregence of
fluorine-containin6 catalysts alkyl pyridin-s are obtained
(Ref 176). Primary alconols with ammonia in the presence of
zinc sulfide (Yef 183), alumomclybdenum (Refs 18.1, 185) and
some other catalysts yield the corresponding nitriles. At
temperature increase the yield in the corresponding nitril,,s
is reduced and the yield in acetonitrile increases to
the cracking of highest nitriles. Promisin.7 is t~,e syntn-sis
of acetonitrile from olefin-hycrocarbons and ammonia (Taole 1)
Until quite recently the couimunications on the reaction of
paraffi.i-riydrocarbons with ammonia were confined to some
patents (Table 2). As can be seen from thein, on t%e inter-
action of alky1naphthene hydrocarbons with ammonia ioth ;icetc-
nitrile and aromatic nitriles E.re formed. The aut?-.ors
thoroughly investigatt--d tht re~LCtion of n-butane, n-1,entane,
i-pentane, n-hexans, n-heptane and n-octane with am;i,onia in
Card 2/4 the prei3ence of oxide ca-talyst& in a system with continuous

Pro pert it-s Prod act ion a j.d Us of A c--ur. it ri I c CV// 7
flo-A at atmos,.ht:ric :)ressarv 1.,iefs 165,2'~9) . It was 'car,,,'
that the yield ii~ acetc)ni trile depends on t ei-3 t ar, , volame
rate of the supple- of' initial hyurocarbon and the molecular
ratio of the rea -ents . !!ost promisine for industria: ~,ur-
postjs is the alulic-l!:C1~6dcnum ^,atalyst by means of higi~
yields in acetunitrile wt-re obtained at lowest tcuip--ratures
(Table 3) - It is I, os ~i ib 1 -, to 9y nth es i ze succ f~ s:,, f a I I j a c f I(, -
nit r i I e.,j from an, Yxr. i i antl A (,I i t~ a p raw mat c r in 1 .1 uct. liu 'jW -
molecilar par-.~ff in-hjur,--)(-,?iLrbL)n9 . kt present , the
regardinE t~-E reAct ion , char ism of oluf in- ar,d ,~a!-af 1-ir.-
hydrocarbons wi*,'-. nia are r-ith--,r at variar,cE . A z Cr I,
to the aut- ors I )j-ini,)n t 1) ? a6dit ion of ammonia tc, t '-
olefin bonc takes ..~'-ace in ~~onse juence of a chair, reactioi
under participation of Cree radica'.s (in contradiction witc.
the formula by Llarkovnikov' . The .-.nvesti,-it ion 1,1' th-
tion of isciamyl n1cohol viti ammonia also sug-usts ar,
of ammonia to the doubli- bo.-id in cc-ntradiction. ~%it: tn~ ~,rma~El
by Idarkovnikov. Corre.91jond ing
, hi,,i ust r,itrile.,i aro~ I ormuc
thert whicK are tht principitl products of' refict.ion at low
temperaturus. At high temp,?ratures they decomi,ose ano fori:,.
Card 5/4 acetonitrile (Hef 266), In the reaction of acetic acid an,~

~: C) V
Properties, Productiun aric Unt-, J Acl--tonitrlle 1,
hydrocar!)on~: v-it~i am;:iunla acc-tonitrile ie I-nt
foru. of an azeetroic :7,.ixtarc e;it~l ivattr. T'n t wa r- ~a-. I.
eliminatud from acet-oritrile in :iLvt-ral ways: by ::t-ans Cf
combined d,-qtill~tticn.-, I,..- r,frip'(ratlor. ar~(! ;1, ;,M'ltlo!.
liquid layt~r (ReC '00), by ,4aturati(~n of' t~~e azecIrrq-
carbon.c anhydri-le and armonia. and Eubt4ej.Aent separa,i~ri
the u;~~,er layer (Ref, IsLi), z).y ::~(-ans of I)assa,-,v off tht. a-Le.--
tro,dc t..jxture ov~--r th, ac tiva-ted ala!i.iiilm oxide at
pressure (Hef ~o,), or i's a-stillatior, at luw jr,slurl L?
I f cheap ane s; I - niL t h:- .!s Ife r th c Pro cac '. i i, nat cri Lr ! I e
are found, it wiLl iRv a Ir--tding part in or.,anic, ~;Jnt,,., siL3
due to its manif, -.u` i,o!~,s ~.Ihi [it i,s of' trinsf,-)rmat ion. T!. .. r
are 3 tables ar.,,; 2 7F) rt f reicefi , 2t, )f which arf- Sf v
Card 4/4

50)
AUTHORS: Mazitova, F, N., ~aush~in, Ya. M. 30V/2~)-125-~1-221,,'
TITLE: The Influen(.,e of the Structu.r-e of Nitro-compounds
of the Aromatic Series on the Rate of Catalytic Reduction
(Vliyaniye 3troyeniya nitros-Dyedineniy aromaticheskoFo
ryada na skorost' katalitich-askogo vosEitanovleni-ya.)
PERIODICAL; Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 5,
PP 1033-1036 (USSR)
ABSTRACTs The reaction mentioned in the title haz been known since
1872 (Ref 1). Other research workers (kt-,fs '), ;) showed
that the existence of such slibstituentE as 011, Cl, C11
and
3
COOH at the nucleus do not influence the rate of hydrogenatior,
of the compounds mentioned i,a the title at room temperi~ture
and atmospheric pressure. There are, however, no punlications
available on the nitroalkyl--)henols under the conditions
mentioned. The authors synthosized several nitro-compounds
with alkyl groups at the nucleus (Table 1) in order to
investigate the problem mentioned in the title. Furthurmore,
purified o-nitrophenol (melt-ing Point 47 0) and r.itrubenzerie
Card 1/3 (boiling jo:.nt 209o) were reluced. FrCVioU31Y purified

The Influence of the Structure cf Nitro-com-pounds
of the Aromatic Series on the Rate of Catalytic deduction
hydrogen waa blowr through the alcoholic: soluticn of t~-e
compound to be reduced, which contained a certain quantity
of platinum catalyst., The experiment lanted until tht~
hydrogen absorption ceased. The hydrogen rjonsumption agreed
in all experiments with the theoretically calculated
quantity. The reaction products - correfipunding arom&tic
amines - wore iaolnted from the filtrate under vacuum after
the solvent had been distilled off. They did 11L)t CO!Itaill
by-products (Table 2). Figure 1 shows the rates of hydruCen
absorption :.n the:,eduction of the individual nitro-products.
This rate iii c-,n6tant for each compound until the reducti(,zi
of the main mass of the substance curicer-ned has taken ~Iact:
(85 - 90 ~4), Table 3 shows the values ol the averaCe rateD
in each ind:.vidual case. They characterize indirectly tho
rates of reduction. This indicates that these rates are
practically equal for nitruberizene and r,itrophenol (k'ie
Curves 1 and 2) (corresponds to Ref 4). However, the rate
is reduced by approximately 42 ~o during the transition frcLi
nitrobenzeno to nitrobutyl-benzene. In the case of
C ard 2/3 nitrophenol and its alkyl derivatives t~.e alkyl group acts

The Influence of the Structure of Nitro-compounds
of the kromatic Series on the Rate of Catalytic Reduction
in a similar manner upon the rate of reduction. The rate
mentioned iij still more reduoed by introducing another
alkyl group into the nucleus. This is still more increased
by replacing one of the hydrogen atoms of the nitroalkyl-
-phenol nuclous by a phenyl group. Thus, the rate of reducticri
in the series of nitro-alkyl-phenole decreases with the
increase and complication of the structu::,e of the alkyl-
substituting group. The authors try to explain this phenomenon
by the resulting steric inhibitions. There are 1 fiPure,
5 tables, and 4 references, .5 of which are Soviet,
ASSOCIATIONs Institut neftekhimicheskogo ijinteza Akademii nauk SSSR
(Institute of Petroleum-chemical Synthesis of the Academy
of Sciences,USSR)
PRESENTED: November 3, 1958, by A. V. Tc,pchiyev, AcE.demician
SUBMITTED: November 5, 1958
Card 3/3

5 (3)
AUTHORS:
TITLE:
PMODICAL:
ABSTRACT:
Card 1/#
Topchiyev, A. V., Academicia;2, Orlov, SOV/20-127-6-25/51
Kh. Ya., Paushkin, Ya. M.
Isomerization of' Normal Paraffin Hydroew-bons of the Composition
C15-Cl. on Sulphide Catalysts
Doklady Akademii nauk SS',)R, 19599 Vol 12'1', Nr 6, pp 1235-1238
(US311)
The authors have been concermed for yearti with the isomerization
of the bigher paraffins of the petroleum- and diesel-oil
fractions. This is of considerable interost 4noe the isoparaffins
have a law melting point (-40-600) (Refs 1-3). The investi-fration
of this isomerization is complicated by an iqtenne cracking and
other secondary reactions. The authors found, however, catalyots
and conditions which make possible an isomer#ation p:racticilly
without cracking and with satisfactory y1elds. The icorna-riza'4-ion
proceeded at 20 atm. The mixture of the n-paraffins 7ith !,,-dr,_)gen
was heated up to 160-1800. Industrial catalyjts were used:
WS 21 VIS 2-NiS-Al203, WS + alumosilicate. 91/~ benzene was added to
inhibit the cracking. The principal results are shown in tables 1
and 2. The optirmim reaction conditions ware found for TS,:

Isomerization of Normal Paraffin Rydrocarbonei of the 3OV/20-127-6-2ri/11
Composition C 15-C18 on Sulphide Catalysts
380-4000. Volume velocity of the ram material: 1.5 1/1-h. 1A
molar ratio of 1:7-5 between hydrogen and poxaffina, the
catalyzate containedt about 3(~o isoparaffiao, 26% untransformed
n-paraffins, and 44% cracking products (the fraction boiling out
up to 2400)- with an increase in the molar ratio beWeen hydro-
gen and paraffins up to 15.6, the content of ieoparaffins in the
catalyzate rose to 35%, whereas the crackiag products fell to
30%. A further increase in tho said molar ratio inhibited both
the cracking and the inomerization (Tables 1, 2; Figure 1). The
isomerization on WS -NiS-Al 0. is accompanied by much less
2 2
cracking. This makes possible an isomarization at higher
temperatures with satisfactory (nearly double the) yielde
(Fig 2) of isoparaf fine. Table 3 shows that the isomerizat
BUlphide catalysts brings about the formation of mono- and
dimethyl-substitutod isomers. Mainly the former are produced if
the reaction is inhibited by high molar ratios (Experiment NT 4).-
There are 2 figures, 3 tables, and 7 references, 3 of which are
Soviet.
Card 2

5 (3)
AUTHORS: Topchiyev, A. V., Academician, 30V120--128. ' 29/'!3
Paushkin. Ya. M., Prokhorova, A. A., Kura3hov. M V.
TITLE: Investigations of Boron Compounds. Reactivity of Triallyl Boron
PERIODICAL.- Doklady Akademii nauk SSSR, 1959, Vol 128, Nr I,
, pp 110-112 (USSR)
ABSTRACT: The present paper investigates the reactivity of trial)yl boron,
Its preparation methods were previously described (Ref 3),
Triallyl bcion was subjected to the action of oaxboxylic acide,
alcohols, and aldehydes. At zoom temperat2-re.. triallyl boron
vigorously reacts with the a:oove compounds, thus causing that the
reaction mixture is strongly heated. By interactiou between
triallyi. boron and glacial a.:etic acid, diallyl boron acetate and
propylene are formed. Triall7l boron forms diethyl esters of the
allyl boron acid and diallyl eater of the allyl boron acid,
respecti-rely, together with .9thyl- or allyl alcohol. By interactip-n
with acetallehydG, ethyl ester of diallyl boron acid is obtained.
Triallyl boron reacts readilf with bromins. HoweveT, the
addition of bromine at room temperature takes plaos only
graduall.y. AT, present, only few references are made in publicatiozLe
to unsaturated complex compoitnds of boron with amines. The
cathors obtained the triallyl boro4 pyridine complex.
Propertieo of eynthesized boro.-organio compounds are given in
table 1. There are 1 table and 3 referenoes, 2 of which are
Soviet.

PHASE I BOOK UPIDITATION SOV/3734
Pzusbkin., 7aroslav Mikheylovicl~ and Tamara Retrovnk Vishnirakova
Frol2vodstvo olefinsoderzhiBahchikh I goryuchikh gazov 12 neftyanogo syrlya.
(Producing 0-lefinic and kuel Gases Prom Crude Oil) Noncaw, lzd-vo
AN MR., 1960. 233 p. Errata slip inserted. 1.,8W ecTies pluted.
Spmsorlng Agency: Akedemiya nauk SSSR. Institut neftektdxdcheskogo sinteza
Ropy. Ed.: A.V. TqpchJyevj, Acadendeian; Ed, of F03.1shIjag Routs: A.L.
,Bankvitser; Tech. Ed.: I.F. Iftzimin.
POMMU: 7his book is intended for technicians Intereatod In the gasification and
conversion of oil stock.
COMAGE: This book deals vith the gasifimtIon of heavy oil stock (fuel oil.
cracking residues, and bottoms) and the conversion of ratural gasoline and
condensing gases into gases vith propylene, etbylene,, sAd bydrqMn obAtent.
16DUrn'units and processes for the gasification of liquId. fuels are describ-
ed, The authors point out Soviet interest in propylene, and ethylene as raw
Card 1/
23

P ?
S106216S~8 A/o6/ii/oii
B020/BO61
AUTHORS- TopGhiyev, A. V.,.Paushkin, Ya, -, Kurashev, M. V.,
Polak, L. S., Tverskaya, L. S.
_Z_1 -
TITLEt Polymerization of Cyclo-olefina
PERIODICALs Izvestiya Akademii nauk SSSR. Otdeleniye kh1micheskikh nauk,
1960, No. 6, p. 1140
TEM In a short report, the polymerization reactions examined by the
authors (cyclohexene,loyclohexadiene-1,3, cyclohexadier*-1,4, 1-methyl-
cyclohexadiene-1,4, 1,2-dimi!thyleyclohexadiene-1,4, 1,4-dimethylcyclo-
hexadiene-1,4, and 1,5-dimethylcyclohexadiene-1,4) are characterized, and
their properties and the posaibilily of the use of the synthetized polymers
in various special fields are given. The polymerization of the above
hydrocarbons was carried out, in different solvents, at various temperatures,
contact times, with the use of different catalysts, and under the action
Of anf y-radiatio 3The polymers obtained with organo-metallic
T!Cl , and BF , as well as with and I-radiation are listed,
and Weir movt i~po~tent J;o~;rtlee., together with analytical ri5sults sra gi V4.
9=*=*
Inst. of Petroleum-chemlcal Synthesie of the Acad. SCI. ITM
Sulordtted.. ftvh 196o

S406~460/000100810111012
B 04 054
AUTHORS: Frankin, E. I., ~rokhorova, k. A.0 Paushkin, Ya. M., and
Topcbiyqv# A, V,
TITLE: Production of Dibromo-phenyl Boron1by Direct Synthesis
PERIODICAL: Izves%iya Akedenii nauk SSSR. Oideleniye kh:Lzioheskikh nauk,
1960, No. 8, pp. 1507-1508
TEXT: The authors conducted the synthesis according to the following equa-
tion:
Out of a Balandin burette, benzene and bromine in a purified nitrogen cur-
rent were led into a quartz -tube (length 600 mm, diameter 22 mm) which was
filled with 75% of powdered toron and 25% of nickel on kiese1guhr. The
reaction temperature was 500 - 5200C. The reaction products nere collected
in vessels cooled with dry ice. The yield in dibromo-phenyl horon was
21%. Due to side reactions, also BBr,t C6H 5Br, C6H4 Pr 2' and traoes of
broso-diphonyl boron were found. Dibroco-phenrl boron is a cclorless liquid
NJ
C6H6 + B + 1t11r,,, '30 C6H5BBr2+ Dr.
Card 112

S /' (
, ) ,
B024/'BO76
AUTHORS: Zhcmov A K V'shnyak-)va T P.
ani Pajrhk,r, Ya M
TITLE: Kinetdcs c~f High-Terrperat.;re Pyrnly.~3 -f
to Gas With a Figh Olefin Content
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy- Neft, i ga7,
1960, No. 9, pp. 103 - 107
TEXT: The aathcrs consider the possibility of appying
G.M, Panclipnkcvls theory on the kinetics of thermal cracking rf
petroleum hydrD,~arbons to the desr-ription cf the pyrolysis of cr,.ide
oil t1residues in the p-esenc,;, of steam In c3eperaticn with
v S, Tret'yakova (Ref 3) G M Pancherikov obtained an equation
from which the velocity constants of the first and second stago7; -,f
a ~~cntinuois first-order rea--tion in the -rackLng pro-ess !an 1,i~
determined:
Card 1

KlInetics of High-Temperaturt! Pjrolysis S//' 52 /60/000/00~ /003,/004','XX
of Crude Oil to Gas W-~th a High Olefin B024/BO76
Content
k. x)
n dx
di V x vr: x
2
v k k
where x df-notes the degree of' --onve-sion; I the distance from the
beginning ~f the reaction zone; v. v 2' v5 v5are thp 3toichiometr'~
coefficients; n_ is the number of gram-akoles -~f the initial crq"k-rg
residue; k, k are the reac-ion ?onstants B~ ivan.5 of a grap~i,.c
.I
solution of this tran5formed j~quat,.on the a-,ithors ascertained that
the equation obtainel, for thermal rra!!king Ij ILII) applicable -,.o
high-temperature pyrnlysis There, a.-P 4 figure,, and 5 r-(-ferqnceE
ez
Card 2' A-7. A-
0-

8h8';7
S/062/ ~0/000/0 10/0 10/0 18
BO 15 ID )64
//,/.2/0
AUTHORS: Topchiyev, A, V, , ?aushkin, Ya. Lt. , Neprya-china, A V.
Ananlyev, 1). G., and Dmitrevskiy, 1-1. N.
TITLE; Reactions of Hydrocarbons in Metallic Melt3. Information 1,
Acceleration and Inhibition of the Crackin,~,; of n-Heptane,
in Idolten Aluminum and Sodium I
PERIODICAL. Izvestiya Akademii nauk SSSR. Otdeleniye k.-iimicheskikh nauk,
1960, No. 10, pp. 1838-1843
TEXTi Conversions of n-heptane in molter t3odium and aluminum Wol,,1
investigated by means of a .ont inuout3ly ope rating apparatiis (Fig. " ) ~ The
metal was introduced into the reaction veavel. after which it was molter.,
and n-heptane vapor was continuously let through, The experimental resu:ts
obtained (Table 1) show that the widest possible conversion of n-heptane
takes place in aluminum, and that the conversion rises with temperature
and contact time; at 7000C, for example, it is 65.3%, and at aOOOC it
approaches 100%. Sodium has an inhibitory effect upon n--beptane
Card 1/3

84857
Reactions of Hydrocarbons in Metallic Melts. S/062/60/000/0-0/010/'018
Information 1. Acceleration and Inhibition B015/BO64
of the Cracking of n-Heptane ir. Uolten
Aluminum and Sodium
pyrolys'-s. The composition of the gases (Tables 2,3) also indicates the
different character of the effects of sodium and aluminum. While -.he
composition of the pyrolysis gas obtained by the contact with aluninun
does riot greatly differ from that of the gas produced by thermal pyrolysis
(40-44% olefins, 12.2216 hydrogen), the gas obtained af':er the contact
with thc sodium melt does nGt contain any unsaturated hydrocarbons, and
consists chiefly of hydrogen (75-65%). Cracking is inh",.bited in tY-e
pyrolysis of n-heptane in tho j):-e,,,,unoo of sodium; this iu Qxplained by
the fact that first (300-8000C) organo-sodium compounds are formed while
hydrogen is separated. The latter reacts Lmmediately witb the olefins,
thus inhibiting cracking (which is a chain reaction acceleratod by
olefina). No liquid reactior. prod~i--.ts aro formud in thc
n-hoptane in molten sodium, rind the n-heplane emerging from the rea, -,oti
vessel remains unchanged (Table 4). Liquic; reaction prcducts are
obtained by the contact with the aluminum melt. Af 700011 these prDducts
consist of unsaturated aromatic -omp~unds. which, at 600c~('. are repla-k-d
Card 2/3

8057
Reactions of Hydrocarbons in Metallic Melts.
Information 1. Anceleration and Inhibition
of the Cracking of n-Heptane in McIten
Aluminum and Sodium
S/062/60/000/010/010/018
B015/BC,64
by highly aromatized compounds. There are 5 figures. 4 tables, and 12
references; 7 Soviet, 5 US, 1 British, ano I German,
ASSOCIATIOV. Institut neftekhimicheskogo sinteza AkadE,Mii nauk SSSR
(Institute of Petrochemical Synthesis of t e Academy r'f
L2
Sciences USSR)
SUBYITTED: May 23, 1959
Card 5/3

o o
B I 17/B1
AUTHOftS. Topciiiyev, A. V., Pau shki-n,_Ya, M., Nepryaktina, A, V.,
Ananlyev, P, G , Dmitriyevskiy, 11, 14,
TITLE: Acceleration and retardation of n-heptane cracting in
molten aluminum and 3odiiim tit 500 - 800 0C
PERI,jDICAL: Referativnyy zhurnal, Khiniya, no, 1'1, 1961, 46~,, abstract
17M153 (Tr, ln-ta nefti, All SJSR. v 14, 1q60,
TEXT; The pyrogenic conversion of n-heptane (1) in molten Al Lind Na was
found to lake place selectively, depending on the metal tised Al promotes
the crack:.ng of 1: The degree of conversicn amounts to 91; *' as compared
. , 701
to 57 /a in pyrolysis. The thermal decomposition of I is strongly retarded
by Na: Al. 600 - SOOOC, the degree of conversion reaches 5- 6 ;') only. Tile
gas obtained by pyrolysis of I in Al contains 40 - 44 '740 of olef ins and
12 - 22 ,b' of d Conversion of Na yields gas containing 75 - 85 /a of H-,
2' 11
which contains virtually no olefins, A diagram of the device ie en('Iosed.
lAbstracter's note: Complete translation,
Card 1/1

3 869()
8/510/60/(314/000/005/(jo6
D244/D307
A', C S, Topchiyev, A.V., Prokhorova, A.A.,jaushkin, Ya.l~., and
Kurashev' 1'. V.
T'LTL'--': inves'ti,,,ations in the field of unsaturat-i?d organoboron
compounds
'A' 1 ~-. -; nefti. Truly, v. 14,
3 C UR C E: ka ~i e .. 1ya nauk SSSR. Institu 1960,
Khimiya nefti, 85 - 89
T'~-- aut,.ors developed a method of synthetizing trial'iylboron
in 90 ~~ yield and studied its chemical properties and those of its
Poly
,,meric derivatives. The reaction for the preparation was as fol-
10,ws: 3CH? = CH - CH MgBr + BF --> (CH,, = CH - CH ) B + 3?,,gBr P. It
2 3 e 2 3
was found that triallylboron reacts readily with acetic acid, ethyl
and allyl alcohols, acetaldehyde and bromine. Some physical proper-
ties of the following derivatives were obtained for the first tine:
diallylboroacetate, diethylester of allylboric acid, ethyl eater of
diallylboric acid, tri-(1,2-dibromopropyl) boron and a complex of
pyridine with triallylboron. It was established thc-Lt the polymeriza-
Card 1/2

S/510/60/01 4/000/001/006
Investigations in the field of ... D244/D3C.7
tion, of ~riallylboron occurs in the presence of oxygen. Triailylbo-
ron via& found to be an active catalyst for the polymerization oil
met,'-,.acrylate and an inhibitor in the polymerizationlof vinylacetate
and acrylonitrile.
Card 212

ZHCMOV, A.K.; VISIMAKMA, T.P.,- PAUSHUN, Ya.M. ---
Kinetics of thei high temperature pyrolysis of crude petrolown
to a gas of high olefin content. Izv. vys. ucheb. zav.,- neft'
i eaz 3 no.9:103-107 '60. (MIRA 14:4)
1. Moskovskiy Institut naftekhimicheskoy i gazovo, promyshli3nnosti
7
imeni akademika I.M.Gubkina.
(Pyrolysis) (Olefins) (Potro-leum)

46 6791L
57 j Y190
+4) 3/020/60/ 150/03/021/06'-
Boll 1/BO1 6
AUTHORS: Topchiyev, A. V, Academician, IL, Kurashev, M. V.
'
q
TITLE: the I eac t ion of Phono
AlKylation by
Investigation of
f
on the Ba:3is of Boron Fluoride
by Means of Catalysti
PERIODICAL: Doklady Akademii nauk ~,S6H, 196o, Vol 130, Nr 5, Pt 559-561
(USSR)
ABSTRACT: In the present paper, the autho:7s used the same methods as in
reference 1, but liquid amylene~3 were directly introduced by
miiture of phenol and
means of a glass capillary tube into a
0
catalyst, which had been heated to 100 . The mothod of amylene
preparation is then described. The first a.lkylution experiments
were made separately with 3-methyl-butene-1 and 2-methyl-
butene-2. In both cases alkylates of equal composition were
found to result. At n molar rat:Lo of' phenol : amylene . 1 - 1
p- tert-amyl -phenol ia formed an the main product. 1to forma-
tion from 3-methyl-butene-1 is possible only in cont;equence of
the iclomerization of the latter to 2-methyl-butene-2 during- the
reaction. An analoj~ouu phonomenon is known to occur in the
Card 1/3 alkylation of benzene by 3-meth.,tl-butene-1. Table 1 igives

4
Investigation of the Reaction of 1,henol Alkylation
by Amylenes by bleanu of Catalysts on the Basis of
Boron Fluoride
67914
3/020/60/150/ 0 3/ 021106 5
:jO11/BO16
general data on the alkylation of phenol with ~imylenes in the
presence of various catalysts. Herefrom it may be seer, th~~t the
highest yield:3 of p-tert-amyl-phenol are obtained in the pre-
sence of boron fluoride and catalysts containing boron
fluoride (experiments Nr 1, 2, 3, yields of 95, 90, and 89i4o of
theory). Less effective is 75.1"' H2 so4(811/t), and the least ef-
fective is aluminum chloride (64%). Table 2 ahows the influence
exercised by the quantity of the catalyst (boron fluoride)
upon yield and composition of the reaction products. This
influence is Mall at 100 0 and with a catalynt content of
between 1.8% and 26%. The process mentioned in the title devel-
ops better under the same conditions than phenol alkylation with
isobutylene (Ref 1); it gives higher yields and less by-products
with the lowei3t catalyot amounts applied (0.9%). An increase of
the catalyat quantity to 1.7~-' incroaacei the yield of p-tert-
amyl-phenol up to 95% and decreases thc quantity of by-pi-oducts
to 3%. The optimum catalyst juantity wk,s 1.7%. Furthermore, the
Card 21~ composition o:." the crude alkylate at a molar ratio of phenol ;

6791 L14
Investigation of the Reaction of khenol Alkylatior.
by Amylenes by Means of Catalyst.9 on the Basis of
Boron Fluoride
SUBMITTEI-:
~iIO201 SO/ 1 50/(,5/ C2 I /-)
zso 1 1/.80 16
amylene - 1 -. I and 1 , 2 as wf~ll as the constants of the end ,-
products are given. There are 2* tables and I ',"oviet reference.
July 13, 1959
Card 3/3

,5"; 91 C' J 9 DO
-12

AUTHORS: Paushkin -Ya.-Id.- Topchiyev, A.V., 3/020/60/130/05/022/061
cian, Kurashev, M. V. BC,11/B005

TITLE: I
Alkylationof :Phenol by Isobutylene With Homogeneous and
Heterogeneous ,at;-,Ystsll
PERIODICAL- Doklady Akademii nauk 333il, 1960, Vol 130, Nr 5, PP 1053-1036
(USSR)
ABSTRAM The purpose of this paper is a comparison of the efficiency
of acidic catalysts and of several granulated heterogeneous
oxide catalysts in the alkylation mentioned in the title at
a molar ratio of phenol; iaobutylene - 1:1 and at 1000. The
homogeneous catalysts were either soluble in phenol or
powdery. The alkylate obtained formed an oily crystalline
mass from which the liquid part was filtered off. Table 1
ahows the results. The solid part of the alkylate consists
of pure p-tert.-butyl phenol. Di-tert.-butyl Dhenol (up to
75_85%) with an admixture of o-tert.-butyl phenol and other
products prevail in the liquid products (Table 4). The liquid
Card 1/3 products obtained by alkylation with H 3P0 4- BF 31 BF31 H3 FO 41

66012
Alkylation of Phenol by Isobutylene With 3/020/60/1
Homogeneous and Heterogeneous Catalysts 8011/B005
AM 3 and Al 2(D 3*4SiO2* nH20 con.3ist of alkyl phenols only
(see Diagram). From table 1, the authors draw the following
conclusions: Catalysts containing BF,. are moot efficient for
phenol alkylation. The yields obtained show that the BF
complex with orthophosphoric a(;id and particularly BF3 itself
are most efficient for the formation of p-tert.-butyl phenol.
The industrial aluminosilicate catalyst also yielded good
results. Its use will also cheapen arLd simpliCy the process.
At a ratio of phenoltisobutylette - 10, phenol is fully
converted. The resultant di-tert.-butyl phenol is no waste
product but ie used in various ways. The catalyst offers
further advantages. For these reasons, the authors also tried
to determine the optimum temperature. The amount of catalyst
was 69.3 g,and was used in 8 successive experiments. Table 2
shows the results. The amount of catalyst was chosen in suci,
a way that a satisfactory absorption rate of isobutylene is
Card 2/3 ensured. Table 2 shows 1300 to be the optimum temperature at

68612
Alkylation of Phenol by Isobutylene With
Homogeneous and Heterogeneous Catalysts
SUBMITTED:
3102 60/1~0/05/022/061
B011YB005
atmospheric pressure. In this ease, the yield in p-tert.-batyl
phenol is 56,10 of the theoretical one representing a maximum
while the liquid products are formed in a minimum quantity
In further experiments, the catalyst was periodically re-
generated for 3 h between working c cles of 90 h (at 5000,
then blown through with air for 3 h~. Table 3 shows the
activity of the catalyst under these zonditiona. It changed
relatively slightly. There are 4 tabli3s.
July 13, 1959
Card 3/3

~t72 1P13 1
-6 -. 3 rc)
S/ 0 2 ~ 6'0711~1 / 0 1 / 0 2 9/ 0 6 0
Topchi-yev, A. V., Academician,, B011 ~'006
Prokhorova, A. A., Paushkint 11,ra. 14#, Kurashev, I.!. V.
"ITLE:
Investigations in the Field of Boron Compounds. Oxidative
Polymerizationlof Triallylboron I
PER10DICAL: Doklady Akademii nauk SSSR, 1~)60, Vol 131, Nr 1, PP 105-108
(USSR)
ABSTRACT: The authors investigated the polymers formed on the basis of
triallylboron (Rey 5) and tested the catalytic activity of
triallylboron in t1i Polyt.-ierization of unsaturated hydro-
carbons. If trin"~"JAQrOn is P3'epared in a nitrogen current
insufficiently purWee from oxygen, solid yellowish polymers
are formed. As can be seen from table 1, the latter contain
boron and oxygen. The authors systematically tested the poly-
merization of triallylboron bY atmos-pheric oxygen at room
temperature, as well as in isopropyl;enzene and in tert-butyl-
ben2ene at 1300 by N 2+0 2* The polymer was also obtained by
addition of benzoyl peroxide or H 202, The oxidation by N 2+02
Card 1/3 was intended to explain the polymerization mechanism of tri

68815
Investiga,;ions in the Field of Boron Compounds. S/020/60/131/01/029/060
Oxidative Polymerization of Triallylboron B011/B006
allylboron (see scheme). A similar scheme was suggested by
S. N. Danilov and 0. P. Koz'mina (Ref 6). The aut~iorsl scheme
fully confirmed the conclusions of these ic
known that the threedimeneional polymers fori,-.ed are inuoluble,
non-swellinE anC infusible producte. The proportice of the
polymers preyared)by the authors were of this type. The poly-
mer can be sep.,~-ated into a soluble and an insoluble componeht
by treatment with 1OFil) KOH. This can also be effected by heating
with CCI 4 or with totrahydrofuran. The analyoeo of the polymer
fractions ore Civen in table 2. The authors found that tri-
allylbokon ia an active catalyst for the polymerization of
riethyl 7-iothacrylate. The ret--ct-ion proceedc under intense
liberation of heat, yieldinG a solid trPnoparent block after
only 1 - 1.5 h. Polymer yield is b6"". Since, boron was not do-
tected in the analysis (Table 3), oc: evidontly
not give copolymers. Fi(,,ure 1 -hows the depondonce of poly-
mothylmethacrylatelviccosity on the concentraLl'on. Vrif-tITY77-
boron has no noti"ceable effect. on tho polymerization of
otyrone, except that it*nomewhat inhibito the r)rocon,,.,. The
3

68815
Invct:ti,-,Aion,; in t~c Field of `IorQjI Compoundus
C,.:id-tive llclyriori7,ation of Tri-10 Oil
;-.S'5GCIATI0I.':
3/020/63/131/01/029/060
B011'Doo6
polystyrene yields obt.,--ined on adding various amounts of catalyst
are shown in figure 2. The viscooity of' the polystyrene pro-
pared in this manner decreases considexably (Fig 3). Triallyl-
boron is (5 mol%) inactive in the polymerization of acrylo-
nitrile and vinyl acetate (Table 3). The authors mention
G. S. IColesnikov, L. S. Fedorova (Ref 4). There are 3 fieures,
3 tables, and 6 references, 3 of which are Soviet.
Institut neftel-chimicheskogo sinteza Akademii nauk SSSR
(Institute of ?eti-oleum-chemics.1 Synthesi's of the Acadezy of~___
Sciences, USSR)
'UBI,,I'2TEI):
October 1P 1959
Card 3/3

TOFCHIYI,'V, A.V.. akademim;-4UMIN NIERYAKE.M. A.V.;
, -Ta. M. ;
AIMITEV, P.G.; IIK17MSKIY, N-Jh--
Inhibition of hydrocarbon cracPd-ng in funed sodium and in
potassium hydroxide. Dokl.AN SSSR 133 no-1:134-137
i'l 160. (MMA 1317)
(Cracking process) (Hydrocarbons)

TCPCHIYEV*. A.V.. akademik; PAUSHKIN, Ta.M.; FROKHOROVA, A.A.; FRENKIN,
]:.I.; XURASHEY. M.'7.- --
Studies in the field of boron compounds. New 6,erivatives of
triallylborane. Dokl-AN SSSR 134 no.2:364-367 3 160.
(HIRA 11-9)
1. Institut neftekhimicheakogo sinteza Akademii nauk SSSR.
(Boron compounds)

1,7106 2Zoll kjj!. Ijlt> I 1~
it, I ~ ~-o
AUTHORS: Prokhorova, A.
TITLE: Investigations
and Properties
PERIODICAL; Doklady Akademii
84666
0/020/60/135/001/019/0 30
~016/BO67
A. and Paushkin, Ya. IA.
kk
in the Field of Boron Compounds. Synthesis
of the Cyclopoitadienyl Boron Compounds I
nauk SSSR, 1~160, Vol. '135, No. 1, pp-84-86
TEXT: No data exist in literature on cyclop(intadienyl boron compounds.
Tricyclopentadienyl boron (a) could be easily produced by reacting cyclo-
pentadienyl magnesium bromide with boron fluoride etherate. The yield in
(a) was 72.5%. At a molar ratio of C 5115MgBr : BF 3 '1 : 1, cyclopenta-
dienyl boron difluoride (b) was obtained (yield 69.8%). The reactions sere
made in an tither medium in a current of purified nitrogen. Both compounds
(a) and (b) are oxidized on air, (b) turning black and being dissolveJ,
(a) changing into a white powder. With pyridine, compound (a) forms a
white crystalline complex 1:1. The elementary analysis for boron was made
by the method of B. M. Mikhaylov and T. A. Shchegoleva (Ref. 2). (a) is
difficultly soluble in organic solvents. From heptane, tetrahydrofurane.
chloroform, and isooctane, it is precipitated as light-yellow flakes.
Card 1/3

8h666
Investigations in the Field of Boron Compounds. S/020/60/135/001/019/350
Synthesis and Properties of the Cyclopenta- BO16/BO67
dienyl Boron Compounds
N. L. Galanina took a spectrum of (a) in the -altraviolet (Fig. 1). This
spectrum confirmed the presence of cyclopentadienyl rings in this compound
Fig. 2 shows the picture of a tricyclopentadi,3nyl boron crystal. In the
ether solutions of (a) and (b), a heavier layor was precipitated under t~e
action of air, which gradually became harder forming a polymer On re-
moval of the ether in vacuopboth compounds readily polymerized. The ultra-
violet spectrum of the polymer of (a) in chloroform (Fig. 1) showed that
polymerization1takes place as a result of the rupture of one of the double
bonds. The-Fl-gh' oxygen content in the polymer indicates that oxygen takes
part in the polymerization. This confirms the mechanism of the oxidative
polymerization of unsaturated organobaron compounds described in an earlier
paper (Ref. 10. The authors further studied the effectof(a)on the poly-
merization of styrene. An addition of I mole% of (a) widely influenced
the polymerization, i.e., it had an inhibiting effect. The polymer yield
and the viscosity of the polystyrene obtained were reduced (Fig. 4). By
this method, also tris-(dicyclopentadienyl)-boron was obtained from di-
cyclopentaiienyl magnesium bromide and from boron trifluaride etherate
Tnere are 4 figures and 3 references: 2 Soviet and 1 British.
Card 2/3

84666
Investigations in the Field of Boron Compounds. S/020/60/151)/001/019/050
Synthesis and Properties of the Cyclopenta- B016/BO67
dienyl Boron Compounds
ASSOCIATION Inatitut nef tekhimicheskogo sinteza AkadDmii nauk SS5R
Unatitu%e of Petrochemical 3ynthesis of the Academy of
Sciences, USSR)
PRESENTED: June 8, 1960, by A. V. Topchiyev, Academ:ician
SUBMITTED: June 8, 1960
Card 3/3

9/1 r 6 1 /ooo/1,c 213c 21r- -a
P'24~YB203
AUTHORS; Paushkin, Ya. M., Yuzvyak, A, G.
TITLE. Cyclopolymerization of butadiene with production of vLnyl
cy-lohexene
PERIODICU~ Izvestiya vysshi.kh uchebnykh ~tavedeniy, Neft' i gaz, no, 2,
1961. 69-74
TEXT: The authors studied the cyclopolymeri,,,,ation of butadiE!ne and the
further chenical conversion of the dimer. In the thermal polymerization a,t
400-500'3C. *;he reaction may proceed to the dimer or trimer. The dimer yiela
attained by 3, V. Lebedev was 65-66% at 150oC after 5 days~ A dimer yield
of about 8Tj; was attained in an experiment irt an enameled bomb at 1500C aft-
er 120 hr (S V. Lebedev and S. R. Sergeyenkc~ (Ref. 4)) Viny" cyclohexane
Is produced in the hydrogenation of vinyl cyclohexene, and vinyl decalin in
the hydrogenation of vinyl decalene, whereas styrene and vinyl naphthalene
are produced in the dehydrogenation of the compounds mentioned The cyclo-
polymerization was conducted in a flow reactor made of q;uartz glass with a
central canal for the thermo-2c-iple (Fig. 1), The reactor tube was filled
Card 11~

8~152~61/000/002/002/CO'5
Cyclopolymarizatio:i of B 24/ 205
with the caarge to be investigated or with the catalys-,, The liquid poly-
mer was collected in a receptacle, and the gas in a gasometer The polymer
wasdistilled in a laboratory column, the frE,ction obta:,ned at 128-1330C.
and its ph.ysicochemical constants were determined. The following catalysts
were used; phosphoric acid on kieselguhr, &.nd chromium oxide on aluminum
oxide Ex'Deriments without a catalyst were also made, first with glass
packing. then with activated carbon- The effect of temperature on yield
and proper%ies of polydivinyl at constant vclume velocity was studied, At
constant volume velocity, the liquid-polymer yield as %ell as the specific
gravity and the refractive index increase. The amount of unsaturated com-
pounds in the liquid polymer drops with rising temperature , whereas in the
presence of the fraction 128-1330C, which -.lso contains the vinyl cycla-
hexene , -~ t. rises wi th temperature , and drops af ter reaching a certain maxi-
mum (Fig. 3). The polymer yield increases both with respect to the i.n!tlal
butadieni:- end to the polymer with the volume velocity of the supply c-f raw
material at constant temperature (4000C) (Fi~,-s- 4, 5); a supplying re,te of
the raw material of 12 h-I is optimum, The iimerizatio~n was conducted un-
der equal ccnditions (temperature, volume veLocity) on activated carbon
Card 2 3

P
'9/1 r, 61 /000/00 21OC21C
Cyclopolyme.-izat,..-. BI 24~YB203
and glass packing; the yield of the fraction 128-1330C was ligher witn acti..,
ated carb~,n; the same applie3 to the polymer yield (Fig. 6). Butadit_ne pcly-_
merized in the presence of H 3PO4 on kieAel~7uhr only at 4300C, the polymer
y.4 eld af t :?r one passa~!e beint.- 39 -40,"a of the ini tial bu tad i ene , and the di mer
yield 4. of the liquid polymer. At 45000 , the polymer y ; eld was 31 .6c%.
The formation of all three xrlenes can be assumed on the basis of the specif-
ic gravit.1, the refractive index at 200C, and the aniline point. In the
presence of a Ni-Cr catalyst, the degree of conversion was 13.2% at 400C0,
and 17,.7% at 4900C. The product mainly consisted of aromatic hydrocarbons
(xylenes) The fraction 128-1350C distilled in a laborator.1 column dE!IiVered
almost pure vinyl cyclohexene (up to 95~fo yield). The resulting cyclol.exene
was selec-.ively hydrogenated (Ref. 6) on a catalyst (100% Pt Dn activate
carbon); here, a product was obtained whose constants corresponded perf____W
to these of vinyl cyclohexane. There are 6 f:.gures, 2 table13, and 6 refer-
ences: 4 Soviet-bloc and 2 non-Soviet-bloc.
ASSOCIATION: Moskovskiy institut neftekhimicheskoy i gaz:)voir promyshlennost-,
i4m. akad. I- M. Gubkina (Moscow Institute of the PetrochemacEi:
and Gas InduEtry imeni Academician I. M. Gulkin)
Card 313

TOPCHIYIV,, A.V.; KURASHEV, M.V.; PAUSHKIN, Ya.M.
EffeetiVeneae Of IF arioua datalystp Jm the alkylation of phenol. by
ispbutylene. Izv. AN SSSR. Otd. khlm. nauk no.23307-311 F 061.
(MIRA 14:2)
1. Institut neftekhimicheskogo sinteza All SWR.
(Phenol) (Catalysts) (Propene)

I-PAUSRUN, Ya.m.; OIUOV, Kh.YBL.
Isomerization of hIgher n-paraffina,, C15-C18- Izv.All SSSR Otd.khIm.
nauk no-4:657-663 Ap 161. 041RA 14:4)
1. Institut neftekliimicheakogo sintem AN SSSR.
(Paraffins) (Isomerization)

IL
23486
S/152/61/000/005/001/002
7 B126/B219
AUTHORS: Paushkin, Ya. M., Vishnyakova, T. P., and Chernukhina, V. G.
TITLEt Catalytic reforming of naltithenic hydrocarbons to aromatic
hydrocarbons from benzine iractions using a catalyst with
0.1 - 0.3% nickel
PERIODICALt Izvestiya vysshikh uchebnykh ,,.avedeniy. Neft' i geiz, no. 5,
1961, 69 - 73
TEXTs Fo r petrochemical synthesis the problem of aromatic hydrocarbons
obtaining from crude oil is of current importance. The dehydrating
effect of nickel catalysts has already been carefully examined by
A. D. Zelinskiy and his school. Ciapetta (Ref. 2, Ciapetta F., Hanter 1.9
Ind. Eng. Chem., ZL~, 147, 1953) showed that isomerization of normal
pentane, hexane, heptane, and octane to isciparaffins is poasible with
a catalys': containing 5~~ of nickel on aluminum silicate ani at 4070C,
25 atm pressure; (yield 55 - 65%). Kh. M. Minayev, N. 1. Shuykin,
L. M. Feofanovs and Yu. P. Yegorov isomerized normal decane and hendecane
with a ca--.alyst containing E~o of nickel on aluminum oxide. The authors
Card 1/6

23486
S/152/61/000/005/0()1/002 J
Catalytic reforming of ... B126/B219
of the prosent paper experimented with nickel catalyoto containing 0.1 -
0.3~6 of' n:,ckel on aluminum oxide. The cate,lyst was preFared from the
active form of aluminum oxide, obtained by calcining ord-inary aluminum
oxide at '1000C, whereupbn the T-form A120 is achieved. The aluminum
oxide obtained was soaked with a nickel nitrate solution of Ni(NO 3)2.6H20
in such quantities as to obtain the necessary concentration of' metallic
nickel on A120 3 after evaporation. The best experimentE,l results were
obtained with catalysts containing 0.1 to 0.3~~ of nicke-... They are given
in Tables 3 and 4. A catalyst with 0.1 - 0.3% of Ni on Al 20 works with-
out any noticeable decreaee in activity fo:r 10 - 12 hr at a 4olume rate
of 0.2 hf', then the activity drops as a result of coking. Regeneration
was effected by burning the coke at 400 - 5000C. In Table 5, a comparison
between reforming by nickel and reforming 'Dy platinum is given. The exper-
iments thus proved that a catalyst on a ni-akel basis on.'.y differs slightly
in its ac-:ivity from a catalyst on Pt-basiO, but it is much cheaper.
There Eire 5 tables and 3 referencess 2 So-viet-bloc and I non-Sovie t- bloc.
The referEince to the EnClish-language publxcation reads as follows:
Ciapetta P., Hanter I., Ind. Eng. Chem., C~, 147, 1953.
Card 2,/6

21-1486
5/152/61/000/005/001/002
Catalytic reforming of... B126/B219
ASSOCIATIONs Moskovskiy institut neftekhimJ.c heekoy i gazovoy
promyshlennosti im. akad. I. H.- Gubkina (Moticow institute of
Petrochemical and Gas Industry imeni Acad. .1. M. Gubkin)
SUBMITTED: February 26, 1961
TeminpaTyps onuTs. ' C
3 0
v
1 % \i
nOK232Te.vn - .
Ha
A 1%03
~
450 500 5w pil
IIAOTHOCTI. 11*4" 0.7360 0.7.51 0.768 0.782
MOACKY'lapillan Dec 110,5 118 128 139
r.11OU1108 411CAO 5,5 13 10.2
1"pyllnO0011 COCT211, Dec:
opousTimecunt yrA6OAOpOJj1j 61 13.3 21.5 31.1
1101PTVionue - 36,7 30 20.2
40) 11spaoll"Osme 42;j 38 39,8
.j)nenpeAe.3bmkae 3.9 8.9
Como ran (% o6vemai.)
41~OAOPOA 58 73 GG17 70-80
Card 3/6 -jf)joenpeaexwiue 3,3 7.5 8.8

S/06 61/00(;/012/005/012
B 11 8Y1314 7
AUTHORSs Paushkin_,_,Ka. M., Topchiyev, A. V., Nepryakhins, 1. V.,
Ananlyev, P. G., and Dmitrevskiy, N. N.
TITLEs Acceleration and slowing dovin of hydrocarbon cracking in
various media
PERIODICALt Akademiya nauk SSSR. Izvestija. Otdeleniye khimicheskikh
nauk, no. 12, 1961, 2204 - 2209
TEM The authors studied the effect of various metallic media on the
thermal cracking of hydrocarbons. These media were intended to inhibit
the thermal instability. The conversion of n-heptane in the presence of
Na, KOH, Al, and Sn at atmospheric pressure was studied and, for compari-
sort, the results of n-heptane cracking wi*:,hout metals anti on activated
KM (KAD) and 60 (BAu) charcoal are listed. At a given temperature and
rate, n-I.Ileptane vapors were continuously passed through molten metal or
coal saturated with KOH. Results are presented.in Figs. 1, 2. The
mechanism of action of inhibiting additions may be explained as followss
Chain rupture is apparently due to a conwersion of alkali metals with
Card '11,41

!i/06 6 1/0UO,/O 1210051012
Acceleration and slowing ... B 11 BY13147
ASSOCIATION: Institut neftekhimicheakogo sinteza Akademii nauk SSSR
(Institute of Petrochemical Synthesia of the Aoademy of
Sciences USSR)
SUB1-,'JTTL'U' May 9, 1961
Fig. 1. Dependence of n-heptane conversion on temperature and medium:
~1~ Na, ~2~ KOH on KAD activnted charoonl; (5) KADI (4) without metall
5 Al; 6 Snj (a) convt-rsionp by weight.
Fig. 2. Dependence of n-heptane conversion at 7000C on tim.:! of contact
with: (1) BAU; (2) BAU + KCH; (3) KAD + YOH; (4) tin, (a) :1onversion,
lj~) by weight.
Card 3/#

z/oli/62/019/001/009/017
E073/E136
thin, J, K. , and Yuzbyak, A.G.
AUTHORS~ FR!L
TITLE: Production of vinylcyclohexane and styrene from
butadiene
PERIODICAL; Chemie a chernicka' technologie. P;ehled tochnick~- a
hojqpod~r'sk~ literatury, v.19, no.1, 1962, 32,
abstract Ch 62-450. (Neftekhimiya, v.1, no.1, 1961,
6o--64)
TEXT: The authors studied the influence of various factors
on the yields of butadiene polymerizationt, the composition of
catalysts, the volume, speeds and temperatures. The optimum
temperature of formation of vinylcyclohexane is 4oo ')C.
Selective hydrogenation of vinylcyclohexene to vinylcyclohexane
on platinum catalysts is at atmospheric temperature. The
possibility of conversion of vinylcyclol.-iexene to styrene was
proved by means of the mechanism described.
2 figures, 6 tables, 10 references.
[Abstractor's note3 Complete translation.]
Card 1/1

Al
s/o65/61/000/0111/003/005
E075/E'35
AUTHORSi Vishnyakova, 7'. P. , Pau-shkin, Ya,~J, , Bondixi-enko , L V,
and Smirnov, A, P.
TITLED Influence of the chemical composition of hydrocarbon
feedstock and aqueous vapours on the dynamics of
formation of olefines during high temperature pyrolysin
PERIODICAL~. Khimiya I tekhnologiya topliv i masel,~_no.12, 1961,
11-14
TEXT; The aim of this work was to study dynamics of
gasification of n-cetane, a-aiethyldecalin and a middle kerosene
fractions (b.Pt-200-300 'C) leading to the formation of ethylene
and propylene. The gasification process was carriec out in a
laboratory apparatus, a di;.igram of which is shown in Fig. 1, where:
1 .. rea:tori 2 - electric furnace; 3 - flow meterE, 4 - receiver
for condvn~;ate, 5 - water pump; 6 - feedstock pump, 7 - burettes.
8 rece,_ver for condensate; 9 - condenseri 10 - water washe-,
11 oil washer; 12 - gais meter-, 13 - beater for feedstock,
14 heater for steam; 15 - sprayer. The feedstock was preheated
to 300 OC, sprayed into the reactor with. steam preh(?ated to
Card 1/~ _-)

Influence of the chemical s,/o65/6i/ooo/o12/003/005
EQ 7 5 /E 13 5
450-500 OC (feedstock-steam ratio 1:1). The mixture was healed
in the reactor to 800 OCI the temperature being controlled
electrically. The total material balance and the balance for ea h
section of the reactor are obtained as a function of the place
gas take--of'f. The time cl' contact of feedstock in the reaction
zone was deAermined to obtain the speed of gasificatiDn of the
different lypes of hydrocarbons along the length of the reactor,
For tbe n-cetane fraction the formation of olefines passes
through a raaximum and reaches about 4ooo of the total gas for tht-
rea~tion times of 0.5 to o.6 sec, Subsequently the concentrali,)n
ef olefines begins to fall rapidly and for 1.5 - 9-0 sec reacli-,zi
limes it i!5 as low as 5-79r, The extent of gasification after
'~ sec reaches 90~0 of the feedstock but at the time of maximum
clefine yield, only 5Mv of the feedstock is gasified.
Gasification of ct-methyldecalin fractiork gives less olefirles and
a maximum yield of 24% is reached for the reaction -time of' 0.6
The kerosene fraction, which consisted mainly of naphthenes ariA
paraffins, gave a maximum yield of 27~0' after 0.3-0.5 sec. The
composition of gases formed during the pyrolysis is clifferent for
eash hydrocarbon fraction investigated,
Card 2/,k'9

Influence of the chemical .... !;/o65/6i/ooo,/ol2/003/005I
1'075/E135
There art) 11 figures and I table.
ASSOCIATIONt MINKh apd GP imeni I.M. Gubkin
Card 3M ~',

39703
S/- 52/62/000/0-D2/002/ ~04
Is7 J,?O 0 Bl,-6/Bl 36
AUTHO;~S: Paushiin, Ya IM, , Mir6aleyev, I I
T JTL;I~ Kinetics of bonzene alkyl~ition t:, j~ropylerie n,f effect,-,
of' soi,,ie physica- lactoro
r FR 101) 1 C,, LI z v e s t i ya vy s s hi k 1. a c n e b ny k h z a vd e n i y ~ N e f 1, t.ra z , r~ 0.
1962. -7-80
TEXT ~ Al ky . at i on of benzene w! t r, ~roj)y I ene it he I iquid phase was car., e J
out to accertain whether diffusion effects, sach as the jhyliica. .rccess
cf gas decomposition, ran retarj the reaction rate, The sp, cia'L
thermcstati, reactor used for the tests was aiapted for c:ampling dui,inb-
,ne reaciioi, Alum.'num cnloride was used as a catalyst. 1~. was found
tnat a feed ratio of' propylene f'r'o::. 0,21o to 1,1(. mole per nole of benzene
per hour ac,-elerated the react-on considerabi,. A ~ibiher r~Ltic ni~ 1 ):.f:t,r
has this effect as the -oncentration of dissolved propylene reacnes
equilibrLum. Acceleration of stirring from C to 1500 r. p. m al so
accelera'.es the reaction, but further increase of' the speed lessens i tie
effect. TI.e optimu.-,. quantity of cat~~lyst is 10,p, By de,~ern:ni,-,g t~,e
-ard 112

33703
~"I:',21b~100() 1'),.) 2 / )~) "I O~A
Kinet i cs -i' nenzene %ticn -&, t,,, ~11''6/,Bi 58
cii_-riges i % reac t i ci, rat u in d ej~e,tdence o;. tit p, m,at ure , ut i:~6 t ~,(, ,i:i in e
benzene concentration, at. activation energy 0:' 4 5 kcal/1--iol, I'ol a
3onversion degree of O.,-,~ molar parts, and ol ~.4 kcal/mole for 0,"' T:iolm-
poxts was determined. Thes e re D u i i, i; show the predominant inf'luence of
diffu,uion effects un the ulkyiation of benzont~ -Nit!i propylene. .f 0
Babin, I . M. Hodigin, :.nj V, C; . 111yusnin are nentioned . There are
fi.-ures, 2 tables. and ..~ references. 0 "oviet and 5 non-Lovi.?t -bloc,
AS~'OCIATION. Mcskovskiy in,_~~itut neftekhimicheskoy i gazovoy
p r o my s h I e nn o s im, akid 1 111, jubkina (111osc~it insti-ate
of ?etrocnemical and ~as lnduitr n
,y imeni ~c&dezici-tr,
~;ubklr,~,
STJBI,~l TT EL Octr-,ber I)C) I
Card Z'12

S/152/62/000/CO7/0G2/OG2
B126/B144
AUTHORS: Yusri-Zakhra, Paushkin, Ya. M.
TITLE: Use of cobalt on aluminum oxiee as catalyst 'or the
synthesis of petroleum-deriveci aromatic hydrocarbons
PERIODICAL: Izvestiya vyushikh uchebnykh zavedeniy. Neft' i gaz, no. 7,
1962, 57-63
TEXT: The article is a study of the cataly-tic reforming of gasoline
fractions with A120 3 catalysts containing 0-5 'to 1 -0.) of Co. The tests
were made with straight-run gasoline, boiling range 7.0 to 140 C, and the
best results Avere achieved at a temperature of 570 OC, volume velocity
0.2 hr-1, using 1.0-/. CO on A1203;'the products of this catalysis contained
59.1~6 by weight of aromatic hydrocarbons. Comparison tests were made
with 0.51i' Pt on A1.03as catalyst; at a volume velocity of I hr-1 the
results were better with platinum, whereas at 0.2 fir'_1 they were analogous
with cobalt and platinum, however cobalt should be used uhen the catalyst
Card 1/2

S/32C~/62/1 44,/,-C'/,-,2 7111~17
Bl 24/ zl 01
AUTHCHS; Paushkin Ya. p Yuzvy;~k G and -Rubiris.. teyr. , A - '2 -
Synt`es's of dimethyl cyclohexadiene and vir...yl
by dinerization of butal`,.ene
',ez;iya nau', SSSH. -ok'ad~-, v. 144, no.
1,~ D I .k a - - I I C,
conditions Ifor the Of ou'-Jleno tc, C~.CI;L
C-IMEZIS o__ vIrl-ou-I compositions were stu"Lied in a re&--ior
.-h ac-.:Lvated-carbon -;ac-in,~. "he polymer cbta'ned ;.us subjected t~,
1~ I J
I
-ractic,z.a.1 distillation, ~n_l cuts %-~th boiling-point :.n,~ervals f:-3:L 5 to
7". were ccilected and examined. yields of ld-~zeric fract-43nS verb
ob-tained a, 4~,0-42COO, wiln a feed~_nl- velocity of 11 ars-I , and .1 am
.pressure, corresprondinE to ICI/j I 3-dlr~.ath~,! cjclohexadiene aral 4f;`; vlnyl
cyclche;~erra. The yield of dimers c~acreuces %7-:t17 increas,_rq; react: .on te::il,~t~r_
ature, and incrouses -,vith increasing pro3zura.. in addition to -he
CYCIOhCY_ad._LeneS and vinyl cyclohvxvnc, lonS-ctain aromatic compound:j anu
bot1h cyclo,3ciadiene- and c.,rcl ode c ene -type hydrocarboas wer,~ Emown tu bu
present. '2he thermodynamios of the reactions:
Card 1 / 3

S/02(/62/144/CG7/023/G."O
.D
Synthesis of dimezhyl cyclohexadiene ... 3124jB101
divinyl K'O ' vinyl cyclohexerie (I); divinyl L~~vinyl cyclohexene (1);
-2 V_
dimeth5-1 cyclo'hexadiene (11) were calculated in the gas phase -from
/p 2 for reaction I, and both (2)
the equations2 ('1) Kp. Pvi div
X(i ) - 'D and (3) K~2) = P P 2 for reaction (II), where
P p dimethyl/ div
X , K 0 ) and ~2) are equilibrium constants of the two reactionsat con-
P P p
stant pressure, and p vin' Pdiv , and pdimethyl are the equilibrium partial
pressures of vinyl cyclohexene, divinyl, and dimethyl cyclohexadiene,
respectivol,r. If z-100 is the percentage of vinyl cyclohexa.diene in reac-
tion, I, x-00 that in reaction II, y*100 the percentage of dimethyl
cyclohexadiene in reaction II, and if PO is the Dressure rec.uired, we have
(1") Fp - (-1/2)z[l - (1/2)z] / (1-1z) 2.P0for reaction I,
(211) X(1) . .7 - (1/2)x - (11'2)y~ (I - x - y) 2. P and
P 0
K(2) . y[i - (1/2)x - (1/2)y (1 _ x _ Y)2_po for reE.ction 11. At
P
Card 2/3

ACC NR: AP7005630 SOURCE CODE: U11/0413/67/000002/006171/0087
'ychan, V. R. ; L.Unin, A. F.
INVENTOR: Paushkin, Ya. M.; Omarov, 0. Yu.; Mkr.
Yu. i. ; Golubovskaya, L. P.
Liakumovich, A. G. ul~
ORG: none
TITLE: Method of preparing polyoxyphenylenes. Class 39, Nc. 19056G
SOURCE: lzobreteniya, prornyshlennyye obraztSy, tovarnyye 2,naki, no. 2, 1967, 87
TOPIr, TAGS: phenol, diatomic phenol, polyoxyphenylene, inert gas
ABSTRACT: This Author Certificate introduces a method of obtaining polyoxypheny-
lenes. To simplify the process of synthesis, the diatomic phenol is heated at
200-300 C in the presence of zinc chloride in an inert-gas atmosphere. [Transla-
tion of abstract) INT)
SUB CODE: 1l/SUBM DATE: 21Jul65/
1 / 1 UDC: 678. 644'14

1 142o4-66 EwP(j)/z-WT(m)t1' RM
ACC NR3 JT6DO3429 SOURCE CODE: U.R/0190/66JO08/001/0181/018
AUTHOR: Visl!myakova, T. P.; Golubeva, 1. A.; Paushkin. Ya. M.
ORG:', Moscow Institute of the Petrochemical and Gas Ind,"try in. 1. M. Gubkin
(Hoskovskiy I tut neftekhlmicbeskoy i gazovoy pronyshlennosti)
TITLE: Synthesis of ferrocene-7and nitrogen-containing polymers with a conjugated
bond system
SOURCE: llysi)konolekulyarnyye soyedineniya, v. 8, no. 1, 1966, .181-185
70PIC-TAUS: organic semiconductor, semiconducting M123mry - o nitrile
ABSTRACT; Nev ferrocene- and nitrogen-containing polymers-poly ferrocenylni t ri lea-
have been prepared by polycondensationlof amides or ammDnium salts of ferrocenecar-
boxylic acids. The reaction was conducted in an autoclave in the absence of atmos-
pheric wwgeii and in the presenc of ZnC12 catalyst.' tolyferrocenylnitrilel was pre-
pared at 170--200C from.ferrocen:carboxamide, aumonium ferrocenecarboxylate, as well
as from farrocene.proper.-
a C*11&F4C4ThCONJ13+ZnC1
+ znC12
card 1/3 541.64+678-86

--L 242o4-66
ACC NRs AP6003429
0
In the case of ferrocenecarboxamide, P205 ani TIC14 catalysts were used in addition
to ZUC12. The simplest and most effective method was the second (yield, 87% on the
ferrocene). Polyferrecenyldinitrile was also prepated at 200C from 1, 11-ferrotene-
dicarboxamEde and from diammonium It l'-ferrocenedicarboxylates
zoo.
The best method, was the second (yield, 44.5T on the ferrocene). All the polymers
were black to brown powders; their physicai and electrical properties are shown in
Tible 1. Structuris'were confirmed by IR spectroscopy. The temperature dependence
Cwa 2/3

L I M2, T~
ACC N% jX60D3429
Prop rti
M.P., 0c
DMF* VH-F
ecdublf imold
Folyfer 350 >500
rocenyl- -.400
nitrile
Polyfer-
rocanyl-
i of ferrocenvInitriles
Mol. wt N, spinh ao~c AE, ev
-101! 10-11- 0.724-
1200 1017
-1600 10-8. 0.09
diuitdl- None >!' WO 1011) l0..12- 0.93-
0
*Dimetbylj!o de
of conduetivity of thA polymers was exponential in character* Origo arto has:
4 ta-FTe-9-anZ-I,EIigure. ISM)
SUB-COM, 071 SUBM DATE: lOMar65/ -ORIG REP: 0071 OTH REP., 032/ ATD PRESS:
Lgmd 3/3 Joi:

PANIDT, I.S.; PAUSHKIN', la.H.
Simple inathod of preparirg bis (dielhylemLno) 'Dorrin, ch.:orlde
and syntheves based an it. Dokl. AN Arm. MR 41 no. 4t226-2219
265 (MIRA 191l)
1. Moskovskiy Institut neftakhimicheskoy i gazovoy promysh-
lennosti imeni (kibkina.

PAUSHUN 0 YU.M. 1. VISTINYAKOVA , T.P.; SOKOLINSKAYA , T.A.; PATAIAKH, I. I.;
. HU.80-F.F.; KURASHEVA, I.D.
New iron-containing monomers and polymers form five-membered
naphthenes. Trudy MINK'HiGP no.44:15-26 163.
(MIRA 18:5)

PAUSIKIN, Ya.M.; NIZOVA, S.A.; GAYEVAYA, V.S.
Synthesizing macromolecular hydrocarbons Oth conjupte double
bonds by a dehydrohalopolymerization reacticn. Trudy MINKRiGP
no.44:43-47 163. (MIRA 18:5)

~s homo logs w t ),I. v
'I cil 'I,
of boron fli,c7id-.

-F_AVSj.jK3N,,Ya.M.; VISHNYAKOVA, T.P.; SMlRNOV, A.P.; ANANIYEV, P.G.;
... -
NEPRYAKHINA, A.V.
Recent developments in the cracking of hydrocarbons; cracking
with heat given off and cracking cut off at high temperatures.
Trudy MINKHiGP no.44;118-128 163. (MIRA 18:5)

I t R1
L h579-65 FW'T(m)/EPA (F )/E,'IP(J )/T ,-
ACC NRj APlj026987 Soma CODE: uR/oo2cj!65/.16h/005/1O65/1068
Faushkin, Ya. M.; P21ak, L. akh, I. I.
AU7710H: Lunin, A. F.; Patal 1., 41
ORG: Mosemy Institute of the Petrochemical and Gas Indust2 in. I. M. Gubkin (Mos-
kovskiy-institut neftekhimichesltoy i gazovoy prox~rshlennosti)-, InstitTie of Petro-
chemical OVithesis im A. V. Topchiyev, Academy of Sciences SSSR (Inst tut neftekhimi-
cheskogo teza. Mad r-n-a-uW OEM)
TITLE: Vew synthesis method for njjr2gen-con ~41.L
r!g th con ated bonds
_pqlyjp~ps,
and their electrical properties
SOURCE: IM SSSR. Doklady, v. 164, no. 5, 1965, i.o65_io68
16
TOPIC TAGS: Qrganic senie-nnductor, semiconducting polymer, polynitrile, polymeriza-
tion, electric property
ABSTRACT: A new preparative method has been developed for polyni.triles. The method
involves the beating of amides OT aMM0niUM salts of mono- and di-basic organic acids
with a debydrating agent (ZnC12
IR
ZnCl
HC00NH6- 2 OR-C~N----G=N-.i
2H,o
Card
5.41.64.67

It posalble to prepum pa2yoltriles without rwmft*bW to'such. *env* T
%me I we" pro-
7anle aild. ..Irm zay"trileaAmban is
IvAwlsU as bWdroL
IL
moo.
ago""
9.. ~tm-
to %W U -48,
wmwg &IN mw Dim
a mxm%
we baw Gal
IUD L&W 60
DO &AW &0
INA eal
L%W M

AUG PM AP,9;026PUT
pra-yaretive coDductors were daterodned. 7be pDlyners were dark-
Ibrom -Ao*10"* pooft"g, tarusible me Insolgbia jm~ the r pa'' solvents, =6 embibiting
hilo I tbmm*l'~ strIdUty. W&I&t losses at a= veke,T-10. n spectya wA elemental
we ibb"4CIbe J*ms Vm 16matical to tbuse of PoWtviles preWed'IW P~IY-
Uftiftgtiai Vt tbi bitMen 1, CWrimbIg the popmed rearticar weebmism and structures
X_Imw'j atim*tgra: anslyals limUcateG the bI& erystallimIty et the polpmrs. Table I
Win or the polymrs masured rm, pmased p&Ue!t. smawles.
aiiz~aw~liii vu 'N-m wtvam matIT"Im seem -for Md. ebad"I strpe-
~tws st.vftwr-,,i 9 I,umlt. We corzalatice Is interpreted-is, terms Or!prdbmbWty
far-14unwilas, of oaftaima. -,Iuft. site._bw A: figm 0012 tam". IBM]
~60.ftwr~ WJw am: I&bz(*/ Mg NW: W51 OM Wt ODRI ATO PMB:

rm*t wlbmr.*~a 4i-tb
bt e'-
par Id
ek!dy, arin y-y 0-- dineli-iya -va'l -9, 19654.
soye vp
WGO'.- d
pp,~ -tin .--pp yner,:- e, L3M
_,up
nc-v,-,p:
022&Y-me
--6 rtat
'.,.:ff(.w'-6m-J,Lttempt hi
Oiflof'122w-dil a
ma
6!9 en made- to substi,
nes.,140 bpen propone
:IiiA.6al~birk oxide:
Dmpoundt at
ate calci-um'-,~bide, for the oxide.

4'1- b, ejizeneil~'tC
~-av- -a - cro.

T~

77- ";7- 77:7 77. 17

T.Y.

~'A U -~ ~ .. N , y q . I*,. I V '- , - , . ., . . : , 7 7 1 : . . L ' - , . .1 . - .
I . .
Prf-,-~Irfit'.On cl . -.' t" ,
.' ~ ': , ~ -- "r- r * ! , - . . -, , ! ~- - , '. , - : - -
..hur. rJ,. O'M. -i- it .

BELOV, V.F.; VISMIYAKOVA, T.P.; GOLIDAINsm, v.i.; i4AKAROV, Ye.F.;
FAUSHKRI, Ya.M.; SGKOLMSKAYA, T.A.; STUKAIT, R.A.; TRUKHTANOV,
V.A .
Study of ferrocene copolymers by means of the Mabituer effest.
Dokl. AN SSSR 159 no.42831-834 D 164 M.IRA 18:1)
1. Institut khimicheskoy fiziki All SSSR i Moskovski:7 institut
neftekhimicheskoy i gazovoy promyshlennosti J . I.M. Oubkina.
2. Chlen-korrespondent P11 SSSR (for Golldansliy).

~_7
-T7777T-
-,-'51307-45, Pi~4 M ".R
N"a
I/F_P~/M
ACCESSIOM ~::0,50112 190 1
7 0713 071
54
Vi i J
P. t Al:A b L' A PEI
prroc
4
Ap V.,
61)koliolbk~~6 voyedin(i
7 965y
TOPIC, TkO'i oig =-io _qynthesis~,~ nitifle7- i,f
'grou]~' t=o_cenep 3 mi speetr=p
A--- i~- -"=AxiAivitVt temperalm're de~bendeftc
ee id
ABSMUTj3-,- Za6 aiiiole' discusijes:: the ~-.-syfitYesi~s~ ui I'd. and some
eM6
bf -Ahvproei~ -fi this conoAm dbt49 e& by- polycandensatl 6 ~hrbamylferro-.
'a aly
e- pare, senc-a of zino diloride and- phosph4rus pentoxide
6 ne. in he' t IS. It is a
powdilaii- rom8ing frorablack . to light- lirom, - dep6~lng~ on boAdit c 7: of_~ the reaction)
he
s,' Ix
and--.~ ii i~tialiy soluble it dime*1formawd de] None ofthe hwolui)le products
5000, -and--the ;4oluble'part decc~qp'oses.
In -the in'~ex val 1 from 420 to
Odd., ~61eoi~- weight of this'latter part Is about120O."i a j~o ti
rp on
tka, ho,", Air- ilisoiption buni ~it--82
1~i_l --thatkoferiatio- of N owi pad ~absorP_..
Jrr ie
000 cur charaoteristlo,of
+=O~~ 94t~!6~- at: I nd ~ I 100.! - fro6 - cycIi.ipeutajUerql rings of
ferrocenot ebpeMence of' ~ivity on temper4ture i.ias meanwed
)ledtrioal donduo
in: the lfti~ratmre ranp,20-3POC, Tempqrattwe at reaotiouprew~tiou iime ratio

i:il: ~04.,a,3yaiip sad d7 Of 3~Mer arial Ca 91
-ipo ifidi -t* lAii.~imjtalb; 66 athired
to --waues of
6
- 65 i The -- tolIMIXUL "a b gjex 2 figureE
-. origin arb
4' 6w
xh*
j~d "a- T"Anntbr)
miat
casi
Oct IT
W- sov
ia
W'~
5
-it
"yj
to

ACCESSION NR: AT4020712
S/0000/63/000/000/0227/0230
AtITHOR: Paushkin, Ye. M.; NIZcNa, S. A.; Gayeveys, V. S.
TITLE: PrepDration of-polyvinylene hydrocarbons by a dehydrogeniltion-dehalogena-
tion-polymerization reaction
SOURCE: Karbotsepny"e vy*sokomolekulyarny-Itye soyedlneniya (Carbon-chain macro-
molecular compounds); sbornik statey. Moscow, Izd-vo AN SSSR, 1963, 227-230
TOPIC TAGS: polymerization, polyvinylene, poiyvinylene hydrocarbon, polyphenyl-
acetylene, dehydrohaiogenation, acryl halide
ABSTRACT: A new method is proposed for the preparation of polyr-henyl acetylene
hydrocarbons in which, In the presenqe of metallic oxides or hydroxides, acryl
halides are dehydrogenated, dehalogenated and polymerized according to the reaction.
Aj- Ar
J13-ClISR-11601hi
X
__1 At
mcH,.i.2xHX+nC&O.I-:41-CH'-).+ACAXS-J.Rllso
where I and 11 denote the products of dehydrobalogenation and immediate polymeriza-
tion. respectively. The procedure 15 described In detail for the preparation, from
Card 1/2

ACCESSION NA: AT4008696 6/2982y'63/000/044/0027/0032
AUTHORi Paushkin, Ys. M.; Yunyak. A. G.
TITLE: Synthesis of new monomers from (1, 3) -butadmne
SOURCE: Monow. Institut neftektimicheskoy i gazovoy promy*shlemosti. Trudy*,
no. 44, 1963. Neftekbimiya, pererabotka nefti i gaza, 27-32
TOPIC TAGS: 1.3-butadiene, 1.3-butadiene polymerization, 1.3-butadiene dimerization,
cyclohexena. vinyl-, cyclohexane. vinyl-, 1. 3-butadiene thermal dimcrization, monomer
ABSTRACT: The authors first studied the thermal cycl(Aimerization of' 1.3-butadiene to
vinyleyclohexene and 1.3-Wmethyloyclohexadiene over activated charcoal at 350-500C and
2-3 atmosp~-icres. After dimerization, the liquid polymer was fractionated and the frac-
tions boiling at 124-128 and 128-132C were collected. It was found that the yiuld of total
polymer increases with the temperature, but that the yield of dimer decreases, so that
the optimal temperature to 400C. At this temperature, the yield Increoses with a decrease
in the rate Of 1710W Of the monomer. The authors then studied the selective catalytic hydro-
genation of viry1cyclohexene over I?t at room temperature, yielding viinirlcyclohexane, as
well as its chlorination with C12 iu CC14 at -60C. yieldW vinylehlorcycilohexane, and its
Card 1/2

ACCESSION NR: AT4008696
hydrochlorimition with HCI in the presence of anhydrous SnCI4 in CCI at -65C, yielding
vinylchlorcyclohexane, chlorethylcyclohexene and vinylcyclohexene dilydrochloride; the
latter reaction (lid not take place In any solvent in the absence of a catalyst and was not
catalyzed by Ti',-14, ZnC12 or FeC13- Orig. art. has: 3 figures, 5 tables and 2
structural formulae.
ASSOCIATION: Institut neftekhimichieskoy I gazovoy promy*ehlennoeti, Moscow (Institute
of Petroleum Chemistry and the Gas Industry)
SUDY=ED: (10 DATE ACQ: I6Jan64 ZNCL: 00
007
SUB CODE: GC,F? NO REF SOV. OTHER: 007
2/2
Card