SCIENTIFIC ABSTRACT POLYAKOVA, A. - POLYAKOVA, A.L.

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SCIENTIFIC ABSTRACT
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POLYAKOVA, A. Fifteenth anniversar7 of People's Albania. Vnesh. torg. 29 no.12:28-29 '59. (MIRA,12:12) (Albania--Economic conditions) --- ~ . - , , ..I-,- - .- I V AUTHORA Tilicheyev, M. D. . Ddee-aned,,-ar4 65-1-8/14 'v A.A__ .ZolyAk TITLE: Trie Aje 8 Mru~ Hydrogenation of n-He'ptane and n-Hexa- decane in the P'resence of a,Nickel Catalyst. (Destruk- tivnaya gidrogenizatsiya n-geptana j n-geksadekana v prisutstvii nikelevogo katalizatora). PERIODICAL: Khimiya i Tekhnologiya Topliv i Mase191958,Nr.1-pp-40-47. (USSR). ABSTRACT: Card 1/3 The destructive hydrogenation of n-alkanes (n-heptane and'n-hexad6cane) wa-9 investigated to ascertain the structure of the formed products. The properties of the'initial hydrocarbons are tabulated (Table 1). The destructive hydrogenation was carried out in an auto- clave at high pressures. Temperatures were measured with a chromel-alumel thermocouple. Fig.1 gives a dia- gram of the experimental apparatus used for the destruc- tive hydrogenation of n-alkanes and Fig.2 shows a scheme of the investigations. It was found that when n-heptane was heated to 400 - 42500 under pressure in the presence of a Raney Nickel catalyst a hydrogenol7sis reaction takes place; no isomerisation, cyclisation or polymeri- sation processes occur. The hydrogenolysis of n-heptane occurs at a thirty times greater rate than thermo-cracking 65-1-8/14 The Destructive Hydro enation of n-Heptane and n-Hexadecane In the .Presence of a Nickel gatalyst. Card 2/3 reactions at the same temperature. In the initial stages of hydrogenolysis n-heptane undergoes the following reactions:- 80% OH4 + 06H14 a7H 16 17% C2 H6-i-- C5Hl2 3% C3H8 -'F C4 H10 During Ithe 40% conversion of n-heptane (in the presence of a catalyst) the yield of n-hexane constituted 56.3% and that of n-pentane 18 .7%,(Tables 2 and 3). The des- tructive hydrogenation of n-hexadecanev in the presence of a Raney Nickel catalyst at 4000C to 42500 in the liquid phase proceeds at a six times slower rate than the thermo cracking at the same temperature. During the destructive hydrogenation of n-hexadecane, under the e)Terimental conditions described above, n-alkanes of low molecular-weight are formed; no isomerisation, cyclisation and polymerisation reactions could be ob- Ll son al P61 ftg* Q-.Uu am. fti. %ftQ4 or Ge "pft ago pulmout SOV/20-127-2-42/70 AUTHORS: Polyakova, A. A., Ziminaj K. 1.9 Petrovv A.Aso i:rr--R-: At TITLEt Mass Spectra and Structure of Vinyl Acetylene Hydrocarbons PERIODICAL: Doklady Akademii nauk SSSR, 1959P Vol 127, Ur 20 PP 386-388 (USSR) ABSTRACT. Investigations of relations existing between physical properties influencing structure and reactivity supply data for infrared.spectra (Ref 2), Raman spectra (Ref 3), and dipole moments (Re,f 4)o Results obtained from'investigations with the KS-1 mass spectrograph are reported here. The mass spectra of vinyl acetyl and of its three monomethyl derivatives were taken. Results are specified in table 1. Maximum intensity is exhibited by the molecular ion. The most intense split ions are produced by the rupture of the C-H bond. Split ions produced by the rupture of the C-C bond are not typical of these compounds. Unlike piperylene and isopreno, the introduc-tvion of a methyl radical decreases but little the stability of the molecular iono The normal chain isomers differ from isopropyl acetylene by a /2 greater intensity of the peak 63 (C H + Ion) Card 1 5 3- ,.Yass Spectra and Structure of Vinyl Acetylene Hydrocarbons SOV/20-127-2-42/70 A striking fact is that the greatest stability is exhibited by those split ions,which have conjugate bonds. It would be interesting to compare these properties with data concerning the kinetics of the ion reactions of vinyl acetylenes. Unfortunately, there are no such data available in publications. There are I table and 6 referencesp 5 of which are Soviet. ASSOCIATIONt Vsesoyuznyy nauchno-isaledovateltakiy institut po pererabotke nefti i gaza i polucheniyu. iskusstvennogo zhidkogo topliva (All-Union Scientific Research Institute for Petroleum and Gas Refining and Production of.Synthetic Liquid Fuels) PRESENTED: March 26, 19599 by B. A* Arbuzovq Academician SUBMITTED% March 21# 1959 Card 2/2 TARASOV, Aleksey Issarionovich. Prinizaali uchastiye: KtZIMINA, A.V.; ZIMIMA, K.I:; POLYAKQVA,,-A,;A.; IOGANSSH, A.T.; IOROLOVSKIY, P.A.; LULOVA, U.1 j--WITOOG, L.A., vedushchiy red.; MUKHM, I.A., teihn.red. (Gases obtained in petroleum refining and methods of their analysis] Gazy neftepererabotki i matody ikh analiza. Koskva, Goe.nauchno-takhn.izd-vo neft. i gorno-toplivnoi lit-ry, 1960. 222 p. (KIU 13:2) (Petroleum--Refiniug) (Gases--Analysis) 315 5 S/ 61/000/022/001/076 OBPB 6 2,0 t2z-o B102 B108 AUTHORS: Zimina, K. I., Obolentsev, R. D.9,Polyakova, A. A.7 Khmellnitskiyf R. A. TITLE: Mass spectra of some homologs of thiophane PERIODICAL: Referativnyy zhurnal. Khimiya, no. 22, 1961, 12-13P abstract 22B72 (Sb. "Khimiya sera-i azotorgan,. soyedineniy, soderzhaahchikheya v neftyakh i nefteproduktakh", Ufa, v- 3, ig6o, 81-92 TEXT: The mass spectra of a-alkyl thiophanes with radicals of normal structure 'from C1 to C6 were studied by means of an MC-11 (MS-1) mass spectrometer. Total ionization caused by 70-ev electrons was studied as dependent on the molecular weight of the substance investigated: It is shown that the total quantity of molecules and fragmentary ions increases linearly with increasing molecular weight. The total ionization value measured for thiophenes makes it possible to carry out an analysis of the structural,groups of heterocyclic compounds. The ionization potentials of thiophanes were determined approximately. They were found to decrease Card 1/2 31516 S/08Y61/000/022/001/076 Mass spectra of some homologs B102 BIOB (from 9-5 ev for C1, to 8 ev for C6) with increasing length of the chain of the alkyl radical. The mass spectra of the alkyl thiophanes were all characterized by the presence of an intense peak at the mass 87 which permits identifying these compounds. [Abstracter0a note: Complete translation-] Card 2/2 -J J00 AUTHORS: Polyakova., iminn, K. A. Petrov, A. A., IMr, III Cill. H. A. TITLE: Mass Spectra of Vinylalkylacetylenes PERIODICAL: Zhurnal obshchey lrlhimii, 1960, Vol 30,.Nr 3, pp 912-918 (USSR) ABSTRACT: The mass spectra 1~ tile following vinylalkylacetylerie- studied: pent-l-en---l-ne, hex-l-en-3-yne, and dec-l-en--.1-yne The results of this work are given in Table A. The ztabilitly of the ion molecule decreases and that of ion fragnient-i-. increases with the increase of alkyl radical. Amonr., ion fragments formed with the rupture of C - C bond the + following types of ions predominate: C H C H + + I-I 2n-3 1-1 2 n - 5 C H and C H A rupture of bond to a con,uZated n 2n-7 11 2n-4 system is characteristic for higher vinylalkylacetylenes. Carbon-carbon bond (to conjugated system) is less stable Card 1/11 to electron bombardment. The ions of the type C 1-1 11 2n-4+ Maol~ Spectra of' Virlyl, _t I J~y I ac'ety lenf~- 78281 SOV/79-30-3 -0/09 can originate as a result of rearrangement processes related to hydrogen migration. FoilC5H6 it will be- C113-C' 12-(" 12-CI12-C-_C~CII=CI 12 -id 5 references, 3 Soviet, 1 German, I There is 1table; at U.S. The U.S. refe-;,ence is: American Petroleum Institute Research, Project 44, Mass--Spectral data, N. Y. SUBMITTED: March 28, 1959 o --- - ------- LON INTEI-451-T'~ tIA55 AN r, CoHoo-sil'. ()i- I of 14-C lr~ ~Zll~ -C=r- -0i ~Cllz if I- C11 Cl(Z z --- fy- 2 zfi~ 1-5 0.9 13 C) 1. 1.3 -- 1 1.2 - - if) cif 0 4 i 2.0 15.3 9.3 25 C, I ij; 3.8 7.8 127 C, 2m 83 521.6 78.2 28 C, 1111 M. - L7 :17 ('~3 1141 4.4.5 4 2.2 7.0 9.1 9.7 0.1 Iff).0 48.5 08 L5 41 0.6 23.7 12.2 41 CIIIJI - 1.8 115.0 67.3 63.8 I" -% 1 3.0 9.4 .1- c:, I I "I - - 4A 33.3 48.8 c, 2.8 - 13.0 .0 7.0 20J; 12. -5 ~d Ctil" 17.0 2 7.7 112 27m It .3 Ili.4 4.4 3.7 c, 2.3.1 c, 11i 3.3 .57 C, I I,-'1 0.7 A c o n t d 18 2 8 2 -Cit- C C OA --- CO 1 12.0 3.(i I - 6 4 t 2 W V'.() 8.7 . ;3 C51t;+ I. I I 18-11 21.4 614 C's I I i , -- M, 65 C'11' 38.0 4 48 35.9 C '51164 11%).() 0 ~ "8.7 1-7 CsI 1?' 0.6 15.7 75 C 11 + 6 '1 , ' 5.4 8:1 2 3 40 77 1 i ' ' 68.1 . . 1 l 7s C l 18.5 1 13. 79 C, I I Ify1o Ro S12 'sl C'11" 4.fi S.4 PI Cl 6-1.7 5.8 11.7 0 4 . 4:1 9 1117 C. I I ' ' 2 . I 1 los C A cl,11 Cal,d 4/4 POLYAKOVA, A.A.; ZIMINA, K.I.; FEMOV, A.A.; KBIRLINITSKIY, R.A. Mass spectra and structure of some allene hydrocarbons. Zhur. ob. khim. 30 no.9:2977-2983 3 160. (MIRA 13:9) 1. Veseoyuznyy nauchno-16aledovatellokiv institut po pererabotke nefti i gaza i Leningradikiy tekhnologichookiy institut imoni ilensoveta. (Allene--Spectra) (Hydrocarbons-Spectra) 84688 2Z 12 q 0 IZI I aj, s/o?-o/6o/134/004/013/023 B016/Bo6o AUTHORS: POLY A~ A.s Zimina, K. I., Petrov, A.-A., and Mova I Khmel A. TITLE: Mass SpectrPand Structure of Silicon-containing Vinyl Acetvlenep PERIODICAL:~'Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 4, pp. 833 - 835 TEXT: The authors have-,#edoU*-jproved (Ref 1) by studying mass spectra of acetylenelana its analogs, the interdependence between the intensities of the molecular ion and some split-off ions, on the o -ne hand, pLnd the structure of the hydrocarbons, onthe other. The present work was conducted to examine the mass spectra of four enin-silicon hydrocarbons: 1-trimethyl- ,o-silyl-buten-3-ine-l (1), 1-trimethyl-silil-3-methyl-buten-3-ine-1 (II), ~l-trimethyl-silyl-penten-3-ine-1 (III),.and .1-triethyl-silyl-buten-3-ine-1 :(IV). In contrast with vinyl acetylene hydrocarbons, the process of dis- sociative ionization of their silicon-containing derivativer. is exclu5lvely selective (Table 1). Under the action of an eleict~ronic impact, the molecule Card 1/3 HAss Spectra.and Structure of Silicon- s/o2o/6o/134/oo4/oi3/023 .0 Bo16/Bo6o ntaining, Vinyl Acet of (I).mainly undergoes the dissociation of a single methyl radical..While the molecular ion with mass .124 has the highest intensity, 48% of the total ion current falls to -the ion with mass 109. The further.dissociation gives rise to silicon-containing ions with -masses 0, 83, 81~ ?9, 69, 55, and intensities from 3 to 15%. This dissociation takes place by the successive ilplitting.off of, CH-', CH?-, or CH groups. There can be no doubt about the 3 .:presence of silicon in these ions. The dissociation of the two closest- ,,.-related homologs of (I), namely,(II) and (III), proceeds along a similar 'pattern. In'both-these homologs, the most resistant ions were found to be those with mass 1.23 which result from the splitting of the methyl radical from the molecular ion. In the case of (II) and (III), the further dis- sociation is even less distinctly marked than in the case of (1). 68 - 71% of the total intensity of ions falls to ions with mass 123- (CH ) Si4 ions 3 3 ,.;with milse 73 are the most intensive in the spectrum of the saturated analog Of-(I)O viz., trime'thyl butyl silane. The splitting-off of methyl groups takes place to a,much lower extent. The ions representing this direction of dissopiation in the spectrum are (CH Si+H ions with mass 59. The remain- 3 2 ions in,the spectrum of trimethyl butyl silane-have a very low C ard 213 POLYAYOVA, A.A.; KHlCL'NITS'KIY, A.A.; iTTROV, A~A. Mass spectra and structure o.;" organic ewripaunds. Part 9: Masa spoctea and structm-a of C(.11,, hydrocarbon!) (1,3- tund 2,4-hexadien-3-yne). Zhur. 0L,., )~ illit~ 31, no. 5:1484-148'l1 Itr 164. NILRA 17.7) 1. Vsesoy-uznyy natichno-issledovatellskiy institut po perer.botke nefti i gaza i Leningradskly tekhnologicheskiy institut imeni, Lenina. A ULANOVA, M.F.- RAPOPORTy I.B.; MLYAKOVA A. ITSIKSON, T.M. Composition of esters obtained in the synthesis from Co and H2 on an iron-copper catalyst. Neftekhimiia I no.5:653--660 S-0 161. ~(MIRA l5s2) 1. Vsesoyuznyy nauchno-issledovatellskiy institut po pererabotke nefti i gaza i iskusstvennogo zhidkogo topliva. (Esters)(Carbon monoxide)(Hydrogen) POLYAKOVA, A.A.; ZIMINA, K.I.; PETROV, A.A.; KHMELINITSKIY, R.A. ------------- Mass-spectra and structure of organic compounds. Part 5: Mass-spectra of enyne hydrocarbons Vith a tertiary butyl radical at multiple bonds. Izv. vYS. ucheb. zav.; khim. i khim. tekh. 4 no. 2:321-324 161. (MIRA 14:5) 1. vaesoyuznyy nauchno-issledovatellskiy institut po, pereabotke nefti i gaza i Leningradskly teldmologicheskiy institut im. Lensoveta. Kafedra organiq#eskoy khi3hii. (Hydro~arbons-wSpectra) POLYAKOVA, A.A.; PETROV, A.A. characteristics of the mass spectra of.enyne hydrocarbons containing a tert-butyl radical. Zhur.ob..khii. 30 no.10:3499-3500 0 161. (HERA 14:4) is Vsesoyuznyy nauchno-issledovatellakiy inatitut po pererabotke. nefti i gaza i Leningradskiy tekhnologicheskiy inBtitut imeni Lansoveta, (Unsaturated oom-pounds--Speotra) POLYAKOVA, A.A-, PETROV, A.A. Mass spectra and structure of organic compounds. Part 6-. Hass spectra of alkanylvinylacetylenes. Zhur. ob. khim. 31 no. U :3515~- 3521 N 161. (MIRA 14:11) 1. Voesoyuznyy nauchno-iseledovatellskiy institut po pererabotke nefti i gaza i LeningradBkiy tekhnologicheskiy in-stitut imeni Lensoveta. (Acetylene--Spectra) POI.TAKOVAj A.A.;, KHRLINITSKIYS R.A. Certain regularities in mass spectra of monoolefins. Zhur.ob. khIne 31 no,12:4059-41%0 D. 161 (KMA 15:2) Owing) mage Spectrometry): i POLYAKGVA,-AJ-, MELINITSKIY., R.A. Mass spectrometry method for determining paraffinic hydrocarbons of normal and branched structure. Khim.i tekh.topl.i masel 7 no.8:70-3 of cover Ag 162. 04M 15:8) 1. Vsesoyuznyy nauchno-issledovatellskiy institut po pererabotke nefti i gazov i polucheniyu.iakusstv6nnogo zhidkogo topliva. (Paraffins) (14tas spectrometry) POLYAKOVAP A.A.; PETROV, A.A. Mass spectra and structure of organic compounds. Part 7- Mass spectra of 1-tert,-1,3-alkylbutadienes. Zhur.ob.khim. 32 no,5tI415-1418 W 162.. (KRA 15:5) 1. Vaesoyuznyy nauehno-isaledovateltakiy institut po pererabotke nefti gaza i Laningradskiy tekhnologialieskiy institut imni Lonsoveta. (~utadiens--Spectra) POLYAKOVA., A.A.; KBI-ELINITSKIY, R.A.; PETROV, A.A. ........... Mass spectra and structure of organic compounds. Part 10: Mass spectra of nonconjugated 1,5-diyne hydrocarbons. Zhur. ob. khim. 34 no-10:3296-3300 0 164. (MIRA 17:11) 1. Vsesoyuzny-.y nauchno-issledavatellskiy institut po pererabotke nefti i gaza i Leningradskiy tekhnologicheskiy institut imeni Lensoveta. ~._-.TAGS: hydio'CiA ss*-'ipdctrdm, hydrocarbon structure, molecular rearrange- m t i izing,electron, unsaturated hydrocarbon el~ 4 on The ~.Work` isr devoted 10-2 study of earratgements occurring in the mass r during the interaction between ionizing-electrons and hydrocarbon molecules of various types undergoing dissociative ionization. The investigated hydrecarbonswere unsaturated and ranged from Cn~2n-2 to CnH2n-6 with an open chain and different numbers of multiple bonds in the molecule. As the degree of unsaturation increased, a tendency toward stabilization of the large ionic frag- an [tin ti: resul g-fr~6m the-electron bombardment was observed. Analysis of the mass 6tra:of the hydrio-carbon's A d that the intensity of the ions formed by re- spa owe MATVEYEV, Ye.L.; POLYAKOVA A.A., KHMELINITSKJY, R.A.; MEDVFDEV, R.A. Modification of the recording unit of an IlChl"03 mass spectrometer. PrIb. i tekh.eksp. 10 no.5:172-174 S-0 165. (MTRA 19:1) 1. Vaesoywnyy nauchn o-3- s sled ovate I I skly Anstitut nefteperora- ba-by-vayushchey prorVshl.ennosti, Moskva. (00/T VIE 01 SOURCE CODE: UR/0065/65/000/ /C)008/0012 AUTHOR M-khaylov, I. A.; Polyakova~- A.-A.; Khmellnitskiy,,R. A j, Loktionova, Ye. L. M6dV6de V, -'VNII,: 0 RG: ocarbon com"o a p-sition.of dearomatized liquid par ffins SOURCE Khimiya A teklmologiya topliv.i madel ~no. 8i.1965, 8w-12 TOPIC 1AGS., hydrom rbA aromatic,hydrocarbon, 'petroleum r fining petrochemistry ABSTRACT: 1he hydrocarbon composition '6f highly dearomatized liquid para- i ffina of different fractional 6ompopitions was investigated, It was shown that they consist of paraffin h _ydrocarbons of normaland branched structuro., i;monocyclic naphthenes and aromatic hydrocarbons. In marketed. samples of paraffins of the Moscow Pbtroleum Ref inmy '~~the content of normal paraffin hydrocarbons 'vas 9 5% paraffin:. hydrocarbo4'9,.of branched:, struct e 34% ur -~naphthene hydrocarbons up to 1%,~and aromatic-hyd carbons n M ot~morethan -iere, repr sented by compounds with from .0-5%- Normalparaffin hydrocarbon's i e o 22 carbon atoms per, molecule, isopa 14 t raffin hydrocarbons - from 17 to e 7-7. from 14 24) and naphthen to 16 carbon atom --_ Marketed paraffins of the GrozRvy Petroleumw4U Pl~ant: are'eharacterized- by~ a reduced content of normi al- -structure paraffin bydrocarbons (90% and lower)~and a high~'content of isopara-1 Lffin hydrocarbons- (frm'8.to 17%). ~ Di6tAbution of nonral-Anicturo jararfin -of number,of carbon 'Zhe same as hydrocarbons in terms atoms in the molecule was s from sulfur-cont in,paraffin aining peAroleum~stocks.',l,but in a different quantitative ratio. Origo- art., .3.figures, and, 3 .,tables. LJMJ SUB CQDI,;,. 11 07 SM DATE, n ne :~UDG; 665 411553.98 L L 01306-67 Zt ~Nk~-270]29-- I SOURCE CODE: UR/0120/65/000/005/01 Wd!74- AUMOR: Matveyev, Ye. L.; _Polyakova, A. A.; Khmellnitskiy, R. A.; Modvedev, F. A. 014 ORG: VNII of the Petroleum Processing Industry, Mose (VNII neftepererabatyvayua-, shchey promyshlennosti) TITLE: Modification of the recording device of thAK-h1303,mass-spectrometerlo SOURCE: Pribory i tekhnika eksperimenta, no. 5, 1965, 172-174 TOPIC TAGS: mass spectrometer, oacillograph Al-700 04,(;-izk ABSTRACT: I "to reduce the time of recordingp the~regular EPP-09 recorder of n ord! the MKhl303 mass spectrometer was replaced by the N-70046scilloizraph,\Owhich permits the recording of signals by 14 galvanometers of various sensitivities. The voltago range of measurements is from 0.005 to 50 v. An overcurrent protection was provided for each galvanometer circuit. A circuit arrangement of six M0011A galvanometers is. schematically illustrated. The galvanometers operate within the 0-40 cps range wish a maximum permissible current of 0.3 ma. The current sensitivity is about 1400 mm/ii ma.m. By using this method, it took only 18 min to obtain the mass spectra for mold"r 'cularnumbers of 50 to 400 under optimum operating conditions of the device. Orig. art. has: 3 figures. ~SUB COM OVY/SUBH DATZ:- 3SAug64/ Ord 1/1 (.2j..5jjj 1JP(c) W/JYD/q1 TJI.~.901-66 'WTA AC C N K: 1~601 fi/5LWf(A)/TSOUi1CE CODE, UR/0413/66/000/009/0072/0072 INVENTOR: Lh&renvuk. I. P.; Blokh G. A.; Polyakova, A. A. ORG: none TITLE: Method of curing chloroprene rubber. Class 39, No. 181273 si�tCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 9, 1966, 72 TOIC TAGS: chloroprene, chloroprene rubber, curing, rubber curing AB9TRACT: An Author lCertificate has been issued for a method of curing chloro- prene rubber with max.Pcompounds. To improve the technological properties of the- mixes and the properties of the rubber, monoepoxy compounds are the epoxy com- pouAds used. [Translation] [NT] -~B CODE: 11 SUBM DATE: 11 Jan6 5 1 1 UDC: 6-78-.7.-6-3. 2. 028. 294 MIKHAYLOV, I.A.;_POLYAKOVA, A~A.; KINELINITSKIY, R.A.; LOKTIONOVA, Ye.L.; MEDVEDEV, F.A. Hydrocarbon composition of dearomatized liquid paraffins. Khim. i tekh. topl. i masel 10 no.8:8-12 Ag 165. (MIRA 18:9) 1. Vsesoyuznyy nauchno-isaledovatellskiy institut po pererabotke nefti i gazov i polucheniyu iskusstvennogo zhidkogo topliva. FOPOVA, T.I.; POLYAKOVA, A.A.; ZIMINA, K.I. Mass spectrorztric analysis of complex aicohG! eixtures. KL,-",- i tekh. topl. i musel 20 no.220,52 F 165. ~qr4 '.II ., ~: -, -, " ~-, ;, ~-"- 1 , - - 1. ~ - ~ 11 ~ ~, ~,- V /03W 3/ k:~15 3 31 ~PoPova .1,14 ftvk~ -13.'- Mai x~ -POMP 822 XAM 19A.. 74:--. 7, ."A2.0 75 -42 32 2.0'.-~ 79" : U 7 j 7L- 2.0 45.-1 `2 .4 L*,~--0.6.~., 10 A.6 - 16' - 501 28.5 i'r"27.0' ~- lt.U.' 10.0. .3' IS --8l 65.0;~- fOD 0 7.4 82 05 43.9., .7.8, 83 -3.8 US 6 4.9 -,921 V ' 53. , IA .9 -0.2, '10' , 96 JU2 . 0 7 too, so POLYAKOVA A..A.,;,_KIZELINITSKIY, R.A.; MEDVEEDEV, F.A. Mass-spectrometric method for analyzing petroleum paraffins using unitized characteristics. Neftekhimiia 5 no-1:153-159 Ja-F 165. (MIRA 18:5) 1. VaeBoyuznyy nauchno-issledovatellskiy institut po pere- rabotke nefti. INIVIII "I 111 11117 ELAM KHMFLINITSKIY, R.A.; -E,'L-Y-Ar~ dDVEDF-V, F.A.; PETROV, A.A.; r STADNICHUK, M. Mass spectra and structure of organic compounds. Part 1-1: Mass spectra of 1,3-enyne germanilLn hydrocarbons. Zhur. ob. khim. 35 no.5:773-776 My 165. (YJRA 18:6) 1. Vsesoyuznyy nauchno-issledovatellskiy institut po pererabotke nefti i gaza i Lenlngradskly tekbnologicheskiy institut Imeni Lensoveta. POLYAKOVA, A.A.; KHNELINITSKIY, R.A.; PETROV, A.A. Mass spectra and structure of organidr,*' ounds. Part 8: Yass spectra ofiisome allene,hydrocarbon-,,,, timptert-butyl radicals. Zhur. ob. khim..33.no.8:2518-2525 Ag-i' 163. (KMA 16:11) 1. Vsesoyuznyy nauchno-issledovatellskiy institut po pererabotke nefti i gaza i Leningradskiy tekhnologicheskiy institut imeni Lensoveta. IMICLINITSKIY, R.A,; POLYAKOVA, A.A.; P11'.TROV, A.A. Mass spectrometric analysis of silicon-containing vinylacetylenes. Trudy Kom.anal.1diim. 13:4%~,490 163. OURA 160) 19 Vaesoyuznyy nauchno-issledovatelgakiy institut po pererabotke nefit i gaza i polucheniyu iskusstvBnnogo abidkogo topliva. (Silicon organic compounds) Put~myne) (Mass spectrometry) POPOVA, T. I.;.POLYAKOVA,-A.A.; Zil-MIA, K.I. Mass spectroscopic analysis of alcohols. Trudy Kon.anal.kh4m. 13:490-495 163. (IIM-,A 16*,5) 1. Voesoyuznyy nauchno-issledovatellskiy institut po parerabotke nefti i gaq& i polucheniyu iskusstvannogo zhidkogo topliva. (Alcohols) (Mass spectrometry) TALIROZE V.L.; ZIMINA, K.I.; POLYAKOVA, A.A.;, TANTSYREV) G.D. Y Ikas spectrum analysis of mixWes of organic oubstances. Trudy Rom.anal.khim. 13:456-414 163. (1111RA 16*5) 1. Vaesoyuznyy nauchno-iseledovatellskiy inatitut po pererabotke nefti i gaza i polucheniyu iskusetvennogo zhidkogo topliva. (organic compounds) (Mass spectrometry) FOLYLKOVA, A.A.; ZIMINA, K.I.; KHMELINITSKIY., R.A. ,!~-~MaBs spectrometric analysis of complex miitures o*f hydrocarbons. Trudy Kom.atal.khDa. 13!495-502 163. 04I~ 16- 5) 1. Vaesoyuznyy nauchno-issledovatellskiy institut po pererabotke nefti i gaza i polucheniyu iskusstvennogo zhidkogo topliva. (Hydrocarbons) (Mass spectrometry) POLYAKOVA, A.A. Case of.pulsonalT abscess In postabortion enterococcic septi- copysmia, cured by pleural puncture and Intraabscass Injections of penicillin. Akush gin. No.1:49 Jan-Yeb 51. (CIML 20:5) 1, Of the Division of Puerperal Diseases of the Institute of Ob- ststrics, and Oynecology (Acting Director - Profk.P.likolayev, Corresponding Member of the Academy of Medical Sciences USSR). of the Academy of Medical Sciences USSR. - ----- - - - - - I - POLUMV.11, A.A. Conservation of hod-,.,-~ of wator. Olkhr. ln-ir. i --.1--cv. dc,14) v ss~7 ------ -- iW,16~T61561 W061-10.1-3210- ACC NR: AP-6031,-)5.3 siyo~,cE CODE: C6 AUMOR: Polyakova, A. D. ORG: Acoustics Institute Akusticheskiy institut) TITLE: Nonlinear effects in a hypersonic wave SOURCE: Zhurnal eksperimentallnoy i teoreticheskoy fiziki. Pis'PPL. v redaktsiyu. Prilozheniye, v. 4, no. 4) 1966, 132-134 TOPIC TAGS: hypersonic wave, shock wave, low temperature effect, laser application, shear stress ABSTRACT: The author discusses e hypersonic wave-#at bujlds up when ajight wave produced by a giant laser pulse s focused ins 1'kuart;~~single crystalV' with special attention to the role p ayed in its propagation nonlinear phenomena, which can lead to a distortion of the wave form, to the appearance of higher harmonics, and in the case of sufficiently large intensities to the formation of a'periodic shock wave. Conditions under which this nonlinear-distortion process is counteracted by energy dissipation are determined from analytic estimates of the degree of nonlinear distortion in the sound wave in terms of a parameter (R) that depends on the absorp, tion coefficient, the specific heat, the Gruneisen constant, the relaxation time, and the temperature. It is shown that the nonlinear effects play essentially different roles at different temperatures, the parameter R increasing rapidly with decreasing, temperature, so that at 25K and below the'sound wave is a periodic shock wave with ACC NR: AP6031583 front width approximately equal to the lattice constant. It is also noted that the-'-, large forces that arise in the front of the shock waves can cause local damage to the crystal at low temperatures, such as observed by S. V. Krivokhizha et al. (Pis1ma ZhETF v. 3, 378, 19066). In addition, att. large values of R a purely longitudinal vave cannot exist and shear stresses arise, which under certain conditions can reach large values. These stresses can also cause crystal damage. The author thanks 1. IEVbe~ linskiy, G. A. Askar'yan and K.A. Naugol'nykh for useful discussions. Orig. art. , has.--._I figure, [02) SUB CODE: 20/ suBm DATE: 31maY66/ ORIG REP: 002/ OTH REP: 002 ATD WSS: 503 Card 2/2 POLTAKOVA, A.G. Success for officienc7 promoters at the Kherson Conblus. Tokst.prom. 18 no.12:56 D '58. (MRA 11:12) 1. Prodsedatell Khersonskogo oblastnogq orgbyuro Vsepoyinnogo obsbcbe- stva isobrotatelay i rateloiallsaitorov. (Kberson Provi*'nce--t.o't'ton'm'*anufacture) LICBEDIRSKAYA, Te.I.; PbLYAKOVA, A.G. Some age-dependent changes in the intera'etion betveen the first azA second signal systems In two-to seven-year-old children. Vop.paikholo 3 no.1:53-60 Ja-F '57 WaA 10:3) 1. Kafedra, fisiologii vyishey nervnoy deyatelinosti Moskovskogo universiteta i Otdal razvitiya i vospitaniya Instituta pediatrii Akademii meditainakikh nauk SSSR. (Child study) (Conditioned response) A\Q 1.4 M.. t~k r 'o d 41 of dWiiyl phospho~~n:s' licift"'i~ll' 'e-TIL-TUD36YMITT -75 X-llk3l)phosphdni~ a66' . Y' S Aminiov,.Y flochkova. nnrln.'D Pwlyak;) (S. a. t,-zrijv umm.-l noT... TMT 44- ---tROCH -mat "IdelsivOes and of 6dilytic atnt~'~ONNICO-~ N~`- I k;aIrl. 140ivc~~Cr' the -v~~nicd ~estcrs:of (lzydroxvalkyl)--~" UUM 'a'it, I 'Vit jstn..'~ (volv ~lhe tvreac q, 6a"4attenlowc Um (1, d7 cokaet:witWadiori;~~ts much a~ A1.0s; or~ nctivawd Cill Meoll"o itlus. , Tlw'mF~_- Gflcleivmg~! %if tbe; ro: (1-fild bo'lid, bt:W.;cQii:ihk 1.10 jWoUP~tjjjdLjkQ iii6btloh. " Th F h tion vrat faro~vtd b J, . I. e.cours~ 0 -1 e reac 'piarlson orAhe plv~!t: mnsts-bUthe i6hLtl rtaactloa~mixt.* (widlatiI a Steaj 'il bathI tioll with -AIOm was nin Is-, ili6atingl-2 hrs..,Dti' IC - the solvent invarlia.-'T. ' he~ products: Obwill;i Me' d P(Olcla VIV d &nd dio ~jteoclrCHION -(OIT) .1 'Pr. Ire, W.O.:-1 ~+In L,-. LIGS!" 1j) cOullcj-.l-O)iP(O)CR(t)jjj 9ft(OH)Ph. f3q.7. 1M'041- 6-TIOC.ThCU(011)P(O)(O.Clr.,C4flOlfe'h,.~ 0*), 1.4345, f.1,573 (widistcl.' oduct; r -CH--V C~ 1-1)( CW,)~; 1.46M -1, (F -3,; :1'.4430;L;: .136 4, -lOCJlgClrjO P O)c T(OlF).Ma,- 67. 1.4476~lf 1.100; Q3lOClrjCFl:o)'p Q)Cll(OH)Pl..'q' 667.r";'~ 1.4=111 1. 183; a-HO C'.11, Cj.T(O�(P)(OClr2CHxOD)T. M7,, (rjOClTelClltO)sP(O) CA e,,OH. 34 (bil 144~-V),'1.4410 LOW;_ (FJ()Clficirio)~F(O)C(OH)(C)TI)di~: .1.4='~ (O)C(0-7)(Clrs),.~'74.0.'~ 1.4.1 LIM; (DOCll-.CMO)tP welitco, ArePrCO, -Acph"pb2cO.'(phcTlApQ-l find Bz% stinwed cviclenmofrc~ctiori b6fthe'desirccl prC4.1 Could not be isoluted,' G.W. lrosialasieff, POLYAKOVA A.- G. Spatial characteristics of induced potentials in the caralral cortex of nowborn animals. L-udy Inst. norm. i put. fiziol. MIN SSSR 6 t11-13 162 (MIRA 17-.1) 1, Laboratoriya obshchey fiziologii tsentrallnoy nerv-noy sistemy (zav. - deystveitellnyy chlen AMN SSSR prof. P.K. Anokhin) Instituta normallnoy i Patologicheskoy fiziologii AM? SSSR' USSA,/ Human and Animal Physiology. Growth Physiology. T Abs Jour: Ref~ Zhur-Biol.,- No 9.1 i~58, 46901'.., Author : Lebedinskaya,.,Ye.,I.;~Pblyakbvai,_ A. G. Inst : Not Given. Title : Changes in the Interaction of the First and Second Signal Systems in Children 2-7 Years Old, Orig Pub: Vopr. psikhologii, 1957, No 1, 53-6o. Abstract: The nature of the answers by children concerning their activity (playing ball) depended to a great -extent upon the form of the question posed by the adult. When adults denied the action carried out by the child, children in the 2-4 age range often gave an incorrect answer, by disclaiming the ac- Card 1/2 -11(5) SOV/92-59-1-30/36 ;AUTHOR: Polyakova, A.G. TITIE-. Theawt"5638ff'df Inventors and Efficiency Experts At Work (Sovet izobretateley i ratsionalizatorov za rabotoy) PERIODICAL: fleftyanik, 1959, 14r 1, P 33 (USSR) ABSTRACT: The personnel of the Kherson refinery has pledged to complete the 1958 production plan by December 5thg and to raise labor productivity at their refinery 7.5 percent. Thanks to the contribution of inventors and efficiency experts this obligation is being promptly discharged. The author cites some names of outstanding experts, among vbom is W.P. Gromov, operator of a cracking unit, G.I. Alekeendrovskiy and others. The youth of the refinery also takes an active part in the campaign of practical suggestions and proposals. A group of efficiency experts, supported by some engineers, made a good suggestion to remodel the electric desalting unit. Some suggestions vere also zmade to prevent corrosion of the refinery equipment. Thanks to practical proposals, vhich vere accepted, the refinery succeeded in saving a considerable amount of money. Moreover, Card .1/2 The Council of Inventors (Cont.) SOV192-59-1-30136 a substantial amount of steam, waterand materialwas saved as well. The group of refinery efficiency experts guided by the refinery council now makes efforts to attain the goal of having every fourth worker act as an efficiency expert. Card 2/2 DURIHYAN, R.A,; POIZAKOVA, A:.G~ ElectrophysIological mnaIyois of a short latent period poTential induced in the ascouiative cerebral cortex cf a cat, Dok-'. AN SSSR 165 no.4-055-956 D ~65. (MIRA 18:12) 1. Institut norimllnoy i patologicheskoy fiziologii AMN SSSR. Submitted Januanr 15, 11965~ POLYAROVA, A. G. Spreading ways of afferent signals to the associative cortex. Dokl. AN SSSR 165 no.5:1208-1210 D 165. (~g RA 19: 1) 1. Institut normallnoy i patologiche3l(Oy fiziologii AM' SSSR. Suhnitted Januai-i 15, 1965. - -M KUDRENKOV, B.I.; MUDROV, G.G.; PQLYAKOVA, A.I. New requirements of atone materials. Avt.dor. 27 no.1:27-29 Ja 164. 09RA 17:4) lltulzRT--R-~:;_-ljxl-W.. -t AW mom KUGENEV, Petr Venediktovich.9 doktor sellkhoz. nauk; POLYAKOVfi, A.L., red. [Primary processing of milk on farms] Pervichnaia obra- botka moloka na fermakh. Moskva, Rossellkhozizdat, 1964. 157 p. (MIRA 18--4) KU MTKOV, B. L ; -POIATAKOVA, A. I. Conference on the Increased use of local rock materials In road construction. Avt.dor. 23- no.2:30-31 F 160- MR& 13:5) (Road materials) TIMM I - ---- - --- - -- - - - --- - - -- -- -1 .- ---- --- VOLIFSON.* I.S.; POLYPKOVA, A.I.- ALIPIDOVSKAYA, V.G.~ FAY-ffIC,',,.'D'R?OVA, L.T. Present status of the Production o1" )q-dr!7!;7r-z-1x-in 3tocAr in gasoline plants of thA middle Volga Vallvy CounciI. cX National Economy-. Gaz. delo 1. Tatarskly nefty~moy 1xistitut. I POLYAKOVAPI.A.T.; FAKHRUTDINOVA, L.I.; MINEYEVA, S.I.; ALIpTDOVSKAYA, V.G. Operation of a up-it for the dryinp of reduced gas in the Minnibayevo gasoline plan,". Nefteper. i i;-tft,--khim. no-5:14-17 164. (MIRA 17: 8) 1. Tatarskiy neftyanoy nauchno-issledovatellslkiy institut, g. Bugullma. I IMR a IBM IS I KMFhIKGV,, Boris Ivanovich;_POIYAKGVA Antoning pyna; FILATOV., Anatoliy Petrovich; RUDENKO, red.; GANYUSHIN, A.I., red.izd-va; DOTISKAYA., G.D., tekhn.red, [Beneficiation of stone material for road nonsb~uctionl Obapebabazie kammogo materiala d2ft damsbaop NWOI- tel'stva. 14oskva, Avtotransizdat, 1962. 59 p. (RoIad construction) (Stone, Crushed) (MIRA 15:4) STPRTSEV, D.I., prof.; FOIYAKOVA, A.I., red. [Selectrion work in breeding 3tations] S~alekt.~Acjr:- naia rabota v p:Lemennykh zavodakh. Illoslcva, Rosnellkhoz- izdat, 1965. 245 P. (IIIIIA 19:1) ~~-UXR vim" Rl~ 1-4-ft, ,3,.)-,dy of ao 43-54, 16 1 -3 -M M4, "t rw -,A r IWIVI -I- - I~At*a-RiMr--- r,_- .4 '1240) SOV/2o-122-1-13/44 AUTIIQR: Polyakoval A. L. TITLE: On the Absorption ol~'thc Sound of a Finite Amplitude in a Relaxating Medium (0 pogloshchenii zvulca konechnoy amplitudy v relaksiruyushchey srade) PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 122, Nr 1, PP 51-53 (USSR) ABSTRACT:. This paper investigateBtlie absorption of sound waves in a medium in which internal processes due to the transition of the energy of the progressive motion of the molecules to the internal degrees of freedom are possible. These processes cause a relaxation and, therefore, an additional absorption of the sound the frequency of which is similar to the re- laxation frequency. The Riemana(Rinan) solution cannot be applied where the wave has a saw-like shape and where dis- continuities occur. For the description of such a wave, the author uses a solution deduced in a paper by R. D. Pay (Pey) (Ref 2). An expression for the vibration velocity is given; it may give a Fourier (Furlye) expansion for a sari in a Card 1/3 viscous medium. It is found as an approximate solution SOV/2o-122-1-13/44 sOn the Absorption of the Sound'of a Finite Amplitude in a Relazating Medium of the exact equations of hydrodynamics in consideration of viocosity. According to the solution method described in the paper by R. D. Fay, the non-linear effects may be taken into account already in first approximation. If the expression for the vibration velocity is found in first approximation, the absorption of such a wave may be described by the re- laxation theory of the sound of inf-initely low frequencies. An expression is then deduced for the energy which is dis- sipated in an irreversible process caused by the deviations from the equilibrium. After some steps formulae for the average value of the dissipated energy and for the absorption coefficient are deduced. If the Reynolds (Reynollds) number R is increased approximately 10 times its amount, the ab- sorption in the maximum increases approximately 1,5 times- By an increase of R, moreover, the maximum of the absorption is displaced to frequencies that are lower than the relaxa- tion frequency. From a physical point of view, this result is well understandable: The non-linear alterations of the solution are equivalent to the presence of higherharmonics in the spectrum of the wave. Every higher harmonic absorbs Card 2/3 a part of the transferred energy. If the ground frequency ---------- SOV/2o-122-1-13/44 On the Lbsorption of the Sound of a Finite linplitude in a Relazating Medium of the sound is lower than the relaxation frequency, the higher harmonics are within the region of relaxation and this intensifies absorption. If R increases, K increases, too. The above-discussed effect has a noticeable intensity and may be observed experimentally. There are 2 figures and 4 references, 2 of which are Soviet. PRESENTED: April 20, 1958, by N. N. Andreyev, Academician SUB11ITTED: April 24, 1958 Card 3/3 IN 32 t2 All Ij 0 Pit I- Z. 1, [.Sal allp lip, 1, 11 im i 1 a d SOV/46-,9-1-14/24 AUTHOR. TITLE: Thermodyntunic Theory of Absorption of Finite-Amplitude Sound in Relaxing Media (Temodinamichaskays. teoriya, pogloshcheniya zvuim konechnoy amplitudy v relakairuyushchikh sredakh) PERIODICAL: Akusticheskiy Zhurnal, 1959, Vol S. Nr 1. pp 85-90 (USSR) ABSTRACT Propagation of sound of finite amplitude is considered using themodynaMics of irreversible processes. It is, assumed that two states are possible in the medium in vhich sound is propagated: transition between these two states occurs under the action of sound (relaxation). Such transitions are due to transfer of translational energy of molecules to internal processes (for example vibrational or rotational decrease of freedom, ctiamical reactions, etc.). An expression is obtained for energy dissipated in such processes. It is shown'thatfinite-amplitude sound Is absorbed morestrangly than sound Ca rd 1/2 SOV46-5-1-14/24 Thermodynamic Theory of Absorption of Finite-Amplitude Sound in Relaxing Media of infinitely small amplitude. The absorption maximum is found to be displaced towards frequencies lower than the relaxation frequency. The paper is entirely theoretical. AclcnowledgmentB are made to 11.11. Andreyev for his advice. There are 1 figure and 5 references, 3 of which are Soviet, 1 English and 1 translation. ASSOCIATION, Akusticheskiy institut AN SSSR, Moskva (Acoustics Institute, Academy of Sciences of the U.S.P'.RQ' Moscow) SUBMIXTED.- June 27, 19-58 S10461601006100310081012 B019/Bo63 AUTHOR: Polyakova, A. L. TITLE: Propagation of Waves With Finite Amplitude in Relaxing Media PERIODICAL: Akusticheakiy zhurnal, 1960, Vol. 6. No. 3,, pp. 356-359 TEXT: In the article under abstraction, the author studies the propaga- tion of sound waves with finiteamplitudes in relaxing media with the help of~ the second porturbation-theoretical.approximation. Proceeding from the hydrodynamic equations (1) and, (2) and the reaction equation (3) she V/