SCIENTIFIC ABSTRACT KOCHERZHINSKIY, YU.A. - KOCHELOVA, G.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001401410012-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

JISSR
GINZBURG, 1. P., KOCHERYZHENKOV, G. V., MATVEYRT, S. K., Teplo.i
Massoperenos. T. I., Minsk, 1972 pp 65-74.
where X 0.10 is an empirical constant. The distribution of friction
stress over the cross section of the boundary layer on an impermeable
plate is found to be little sensitive to Reynolds number.
As analysis of numerical solutions shows, when there is a moderate
longitudinal pressure gradient or injection, when the Iasi expression is
used for displacement path length, the de-o.endence of ulv,.- on yv,/v near
the wall remains near universal. Nevertheless, the prQssure gradient is
found to have a strong influence on the dependence of c +/2 on R** = ue6**l
/v, which is related to the influence of pressure gradient or injection on
the velocity profile and on the friction stress profile in the external
portion of the boundary layer. To provide a single-paraneter representa-
tion of the friction stress profile in the boundary layer when t-here is
a pressure gradient and injection, it is suggested that the nek, pareumeter
i1p. h tic, ~'6
-r, dx v, Wv ki
be used, which provides a universal representation for T/TW T/Tw
with various condition of friction in the botindary layer. 16 Biblio. Rci's,
2/2
q

USSR7 UDC 621-336.8
JAHKIJ, IIjjj_A_ and PETIKOV V, V.- Institute of Physics
&WIMINH I I SRI'Kiev
751 Metias ox -VA~F-AnWcfemy of Sciences of the UkrS
"High-Temperature Attachment to the X_.Ray Diffractometer"
Moscow, Pribory i Tekhnika Eksperimentav No lt Jan-Feb 72t
PP 191-194
in sorption D ing a 10-~_
pump provid 11-forr vacuum and the possibility
of free rotation of the attachment on the goniometer axis is de-
scribed. The speoial features of the attachment, inoluding the
bui2t in pump, the hermetIc all-welded beryllium opening for pre-
heating the body by pumping out thelfacility for fixing, heating,
and temperature measuring of specimens up 'to 2000 00, azid the in-
sertion of a vacuum-metering lamp in immediate proximity to the
specimen, are discussed by reference to the schematic drawing and
the circuit of the attachment. The temperature measuring accuracy
is �1%, the accuracy in maintening the.temperature is �100, the
Abstract: The attachment to the ray diffraotometer with a built
1/2

USSR
KOCIMHIIISKIY, YU. A. o and M'KOV, V. V. PrIbory i Teikjuilka Eksperimenta,
No 1. Jan-Feb 72, pp 01-194
interval of diffraction angles is 0--ao deg. , and the power input
is up to 3 kw. The attachment weighs 7.5 kgv it can be used for
the investigation of metallic and non-metallic materials. Frag,-
ments. of diffraotion patterns of Fe, Hf, and HfOg obtained Yrith
the help of the described attachment are shovm.' 1hree illustr.9
six biblio. refs.
2/2

Instrumentation and Equipment
USSR UDC 621.386.1
KOCHERZRINSKIY and PEVROV, V. V.
"X-ray Cameras for High-Temperature (above 1000*C) Studies"
Kiev, Metallofizika, No 32, 1970, pp 130-142
Translation: A survey is made of the designs of Debye X-ray camieras and
attachment cameras for X-ray diffractometers; for invest#ations at high
temperatures (1000-3000*C). Their-advantages and disadvantages of these
cameras in investigations of phase equi-libria in*metal systems are dis-
cussed and prospects for further improvement are reviewed.
Bibliography: 38 entries. Illustrations: 17

USSR UDC: 621.)94.4
KOCHESUOV, B. I., STAI-OBLiSKIY, A. 0.
"A Device for Improving the %eliability of Transmitted Informattion"
arnL -e
Moscow, Otkrytiya, Izobreteni~ya, Fromvshlanilyye ObrazTsy, Tov. rj Znaki, o 21,
1970, Author's Certificate No 274153, filed 24 Rar 1969, P 39
Abstract: This author's certificate introduces a deviae for .he I-01-i-
ability of transmitted information in a system for data tran;3ziissior, w-f-.1h Al~to-
matic error interrogation. The device contains a transmitter witi-_ (,~yal Ic C.,-Id.-,
decoder and a receiver with cyclic code decoder, As a fuature Of
the patent, the message handling capacity of the channal for
is improved without impairing trIe reliability of the roceivei by con-
necting a rectifie.- at the receiver input. An "error or intorrogavion" signal
is sent to the con-wrolli-nc? in-put of th-s rectifier, whilu a control =~.Uula is con-
nected to the transmitter decoder and to the receiver deca,44er. Zac4 of t~.ez;e
control modules contains a controlling section made in the fo~na of a blstaole
mmemory elenern.. An A , cix-cuit is connected ;to the outpL-. c)-- t, e
Me"Mory element. T"ha Other input of the AND circuit is conna'.-te-di to an "cmo:-~Eoncy"
signal zource. One of the inpuLa of t4o bistablo olorent is to Lli,) dal
codar outk.T~ut, while ti o utaor Jinj~ut j:3 cornactrid tt) th J t
a
in the rocoivar tho othor input of 'Uha oiatablo oliniont is aloo aclwio~ctol to t6ho
ilerror" s-i-rial sour-.-e.

77~-- .... ...
77-1-7-771
'77
USSR UDC 541.572.5+541-572.8
RO.1,Zf, I. P., SADTKOVA, E. 11., GUR'YANOVA, Ye. N.,.K.QLLI, 1. D. , and KOCHESK OV
K.' A., Academician, Physical Chemistry Institute imeni 'Karp6v-, 7698'W"
and Moscow State University imeni M. V. Lomonos.ov, Moscow
p v-Conjugation in Triphenylphosphine"
Moscow, Doklady Akademii Nauk SSSR, Vol 195, No 2, 1970, pp 372-375
Abstract: The p 7,-conjugation (interaction of the undivided electron pair
at P with the ii-electrons of the aromatic system) of Ph, 11 was studied on the
3
basis of the dipole noments (d. a.) of complexes R P (R - Bu, boxyl,
3 * '3
octyl, Ph) of phosphines, which are active n-donors, with a nunber of ac-
K~3 BC13) and of the heats of formation of R '-1Xj
CcPtOrs M - AlBr GaCli, 3F"
(MX3 = AlBr.-3, GaC13~: Thelthemal effects involved in the substituLion of
R3P with dimethylcyclohaxylardne in R3P-BF3 (R - Bu, hexyl, Pb) and of Ph3F
with Bu3p in Ph-P.BC13 were also considered, The d. ri. of complexes Alky'3-
P.AlBr3 were close to each other, Lut the heat of formation o~ the second
was much lower than that of the first because of energy lossei associated
with breaking of the p -n-conjugation in R P during c Drip lax- f ormati on. On
the basis of this difference and similar Efferences for complexes with other
1/2

.USSR
q.1, Doklady Akademii Nauk SSSR, Vol 195t No 2, 1970, pp 372-
ROMK, I. P., Et
375
acceptors (those for complexes with BF3 and BC1 were calculated from the
thermal effects in the substitution reactions), 3the p w-conjugation energy
EC in Ph3P was estimated at 11.7 + 2 kcallmole as an average of values
based on data for complexes with The four acceptors IfX3- E for Ph P was
c 3
lower than that 14.9 kcal/mole) and much
for N-methyldiphenylamiae,(E.
lower than that for Ph N.
3
2/2
55 6

OrganomerTlic Ob nds
j 5 S 47'. UDC 547.13 + 661.781.6
FO11,ffiXA, N. V., SREEVERDINA, N. 0., and Acadeadcian,
Physico-Chemical Institute imeni L. Ya. Ka ov, Moscow
rp
~_v
"Synthesis of Germaniumt-Organic Compounds of the Type Ar2GeX2
Moscow, Doklady Akademii Nauk SSSR, Vol 201, No 5, 1971, pp 1128-1129
Abstract: Previous methods of preparing germanium--organic compounds led to
mixtures which were difficult to purify. A method proposed earlier for the
arylation or alkylation of germanium salts in the presence of Cu powder was
extended to cover the introduction of a second aryl group starting with
ArGeX3 at much higher temperatures. All reactions were nin in an argon
atmosphere. Starting with tribromoplienylgermanium at 250' for 10 hours
with Cu and iodobenzene, dibromodiphenylgermanium was obtained. Yield was
dependent on the ratio of the startLng materials. Diiodadiphenyl-germanium
and dibromophenyltoluylgermanium were obtainied in the same fashion.

-112 021 UNCLASSIFtEb* P[~OCESSING DATE--IBSEP70
....TITLE--SYNTHESIS OF UNSYMMETRICAL ORGANOTtN COMPOUMOS -U-
~.AUTHQP--(03)-,MELNICHENKOv L.S.v ZEMYLANSKIYP N.N,i, KQCVIESliKOVo K.A.
~,~.COUNTRY OF INFO--USSR
"~SOURCE-DOXL. AKAD. NAUK SSSR 19709 190(3), 597-9
'--.-.DATE PUBL ISHED ------- 70
,-,:SUBJECT AREAS--CHEMISTRY
;jOPIC TAGS--ORGANOTIN COMPOUNOt ORGANOLITHIUM COMPOIUNDe CHEMICAL
~_--SYNTHESISv UV LIGHTi THERMAL OECO14POSITION
7.CONTROL MARKING--NO RESTRICTIONS
-.00CUMENT CLASS--UNCLASSIFIED
~PROXY REEL/FRAN'E--1984/1563 STEP NO--UR/0020/*10/190/1)1)3/05')110599
CIRC ACCESSION NO--AT0100181
UNCL ASS IF IF-1)

2/2 021 UNCLASSI F [ED PROCESSING DATE--18SEP70
ACCESSION '40-AT0100181
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. REACTION OF PHLI WITH RSNCL SU133
IN ET SUB2 0 AT 4114US 20DEGREES GAVE ETPH SUB3 SN AND BUPH SUB3 SN.
KEEPING 2 MOLES ETSNCL SUB3 AND I -MOLE ETPH SUB3 S14 IN UV LIGHT 2.75 HR
AT SMALLER THAN 35DEGREES GAVE 90,9PERCENT ETPHSNCL SU6'2v M. 66DEGREES,
ALSO FORMED FROM THIS MIXT. 1 1.5 HR AT 140DEGREES. SIMILARLY BUSNCL
SU83 AND BUPH SU83 SN GAVE 90.3PERCENT BUPHSNCL SU82, Mt 50DEGREES- AT
ROOM TEMPot T14E REACTION IS SLOW AND REQUIRES 5 DAYS FOR 65PERCENT
ICONVERSI.ON. ETPHSNCL SU82 AND AQ. KF GAVE 95PERCENT ETPHSNF SU82-1
DECOMPO, LARGER THAN 300; BUPHSNF.SU82t DECOMPD. LAR 'GER.THAN 250DEGREESI
WAS PREPOo S,IMILARLY* BUPHSNF SU82 AND PHLI IN EVS
I U82 0 AT MINUS
-250EGREES GAVE- 92.7PERCENT DUPH SUB3 SNt.M4 610EGRE-E-S.
UNCLASSIFIED

Abstracting 8ervi e. Ref. Code
Acc. Nr.
ST.
CHEKICAJ, AB
Air 045325
f' 90897m Sykhesis of canjuga ed ilymerle orga~anuorine
compounds. Panov E. M.. RVOO Va- F-4kKht'- kw-&-&
' ' ... 7- T-A El-cr.'
(Fiz.-Khim. Inst. im. a=c W. 14
Nauh SSSR 19", 1900),1122-4 (Ch9m i K )J! A'rhi, .of Y-
1),~vas obtaini4jin 85-90%
[a
an - eQuiv.~ amt. or
d Ar or N. The I mi it.
>Wand hail av. inol.
r C~
wt. 844 W.P. -71. 1 (n 6) was obtained in 30-5% ~-ii!ld by dis.
solving mixed I in toluene and cooling. Addm. of IE6,-O to the
mother IiQ. yielded, -40% 1 (n -:z 14) (1a). The ),-no6er liq4or
from this step was then poured into; h[eOH to ppt. (n -
3) (1b), m. 175'. The absence of Cl ahd:Br (end gro and the
Oame elementary cnmpn. for all I out "te(l a cglic otirllcl ure, ~ Jb
added 3 moles Br after 3 M4, to 9 VO WA qj?"Clotris -
(1.2-difluoro - 1,2-dit)rornooth)ilene)~~~yienel- C~cli ~P -
(1,2-difluora-1.2-dibromoeth~-l~ni~)~h~~yletieI (6217c) wa4 similwris-
obtained at higher temp. after 3 hrfrorn la. I W ef eQ i&ed, t o
Ir
terephthalic acid by Cr2Oj in 40% HOAC.
X
REELMAME

......... .. ---- ------- ____ - __ -
USSR UDC 621-357-5-035t621.70.027(088-8)
ABAYDULTH, G. U. UR=X1Y R. A. , and KQrjffiPjK0VA L 1. IL,
"APparatus for the Electrochemdeal Treatment of Metals",
Author's Certificate No 338342, filed 21 Oct 70, published t5 Jun 72 (from
Referativnyy Zhurnal - Xhimiya, No 8(11)l, 1973, Abstract lio &288p)
Translationi A device is patented for the electrochemical treatment of metals
which is in the shape of a drum having a regulator for the flow of the process
solution, electric driving gear. a power supply, a pipe for the delivery of
the process solution, a bath, and a pump. It is improvad in that in order
to increase the efficiency and the technological possibIlities 'Of the
instrument, along the axis of revolution of the baxrel M9 located in a mobile
chamber baying throttled openings directed towards the mone of the treat-
nent of the piece.
20

Nr: Abstracting Service: Ref.,Code:
Acc.
ATO-101484 CHUMICAL AB 10 - ?h
-7 4FA
121652J Reactions of a Series; of organotin contpounds vith
dlethylaznlne.~ Kadhe"khima Domra0lev. G.- 'A.;
Razuvaev. G.'A. CUSSR).~ Zk.' Obshch. Xhim. J070.- 40(2).
377::D(Russ). Heating R&%- with nt4-VH 6 hr at 400* gav~e~ the
following % yields of RH, olefin', Rt,.Ht, C1116, MeQN, and tar,
resp. (from the: indicated value of R): Et,3.3.0,0.$,4.0.l3k1G.38I
0.21, 73.6; Fr. 2.7, 0.721, 0.53, 0.18, 6S.1; U, 2.0.
1.54, trace, 0.37, 0.52), 0.12, 71.5; and isr>-CaH,4 1.89, 1-81'
_09-041, 0.55,-0-.07, 73.5%. Th6,.main--reavtiun--dkection -is the
cleavage of H from the ~miue to form RH and with incrtasin&
chain length of R the propbrti6n! of -the dispropbrfionatipn re~
action of the resulting radicals increases, while theidecompn. of
the radicals in the preseilce of Et"NTH is inhibited. The change
in the product proportion in the~pmence of MIMI daring' such
pyTolysis of R,Stl is ascribed toc64dirlatioirbf the amine on a Sit
atom, which reduces the polar effict of Bn on the 0-clitnitiation
reaction. M.'Kosolapoff J
REEL/FWIE
13651390
PIMAIIII MEW 11 IMP, =43111 =1:1.401111MUTE"M _0771"JIMM"

A
Acc. Nr *0101483- Abstracting Service: jo~:
AT -- CHDIICAL ABST. C,
Ref. Code:
121653k Reactions of tetracyclobexyltin. Razuvi~ev. U.-A.
r
Donlracliev, G. A. Koelietikhina,.-k- G - GoncJiarov. V.
5-~- ; - Pyro
h .2 f s).
Ysis of (C41-111),411 at 2W* gave inly cycloliexane,and cyclo-
hexene, metallic Sn, and Ur in 12 coavorsim; at 3N)* tracts of
methylcyclopentene and dicycloh~eiyl were also formed and some
tar formation was obsd., while at 350* more cycloltex;4ne and le:is
cyclohexene were fornitd, the other product yields th-inI4 compa-
rabic to those above. Reaction in the presence of, Lt., N11 gave
more cvelohexane an(] less cyclobe4ene than were obt~ained Ivith-
out th~ added amine at 250*, but at 350' the yieUL of cyclo-
hexane was lower and t1w of cyclohexene was higherj titan is-ere
obtained without the andne. Other product yields W~re con1pa-
rabic to those above. In the presence of (C1601-01 Ille Yield of
cyclohexane was raised, that of cyclobexene lowered considerably,
and other product yields were comparable to those above, while
some (SnOICCIfIO-1. viras also formed: Thus, the Idispropor-
tionation of the free radig:11 intermediates increases vith the
temp. rise, while the O-elfraination reaction is inhibited by the
higher temp. The effect of the added amine is uscr!W to co-
ordination of it with the J-H atom (Xvith respect to the Sn atoin)
of the cyclohexyl. group. Thus, donor rtagents in reaction with
this R4Sii exhibit their nucleophilic nature in the Ist t;tep, then
react as acids or as bases. G. Al. KosolapojT
REEL/FWIE
0(1
19851389

USSR mn 62i.382.3.o2g.6
PETROV, B. K., KOCHETKOV, A. I.,, SYNOROV, iVe F.
-liCalculating tl~e _Stationary Temperature Fields.in Overlay Superhigh Frequency
Transistors"
Moscow, Radiotekhnika i elektronika, Vol 17, No 10, 1972, pp 2176-2181
Abstract: The stationary temperature distribution in th e semiconductoz crystal
of transistors with band emitters was first calculated in the two-dimensional
approximation [W. R. Wilcox, IEEE.Uans, Electron Deyjcp_~4 ED-10, 5, 308, 1963j,
and later a simple.formula was obtained IV. F. Synorov, 4-.t al., Radiotekhnika
i elektronika, VoI16, No 6, 1090, 19711 for the thermal resistance of rhe crystal
in superni-ii frequency overlay transistorsi In the two-dimensional approxima-
tion the heat fluxes from the edge emitters in the direction of the Oy axis
were neglected, and the emitter bands were~considered infinitely long. Now the
equation of thermal conductivity has been solved to obtain the stationary
temperature distribution RT and the formula for the thermal rouistance of the
semiconductor crystal of a superhigh frequency overlay transistor for the more
geoeral case of a three-dimensional heat flux. A numerical example of calcula-
ting the thermal resistance of a crystal for a standard powerful superhigh 11're-
quency silicon transistor is presented to compare the tvo-dimeasional and three-
dimensional theories. In real instruments the temperatura dror. within the
emitter area is highly significant (=50%).

Physiology
USSR urc 616-127-071:358-k
KOMEAKOV, V. M., Candidate of 1,16dical Sciences, Lieutenant Colonel,
Medical Corps, and KOCBETOV, A. K., Candidate of Medical Sciences, Ueutenant
Colonel, Medical Corffl-
"Phase Analysis of the Contractile Function of the 14yocardiosclerotic Heart
in Hypoxia!r
Moscow., Voyenno-Meditsinskiy Zhurnal, NO 4., 1973~ pp 65-66
Abstract: Polycardiographic studies were conducted On 3 groups of fasting
subjects, or 3-3-5 hrs after a meal; the studies were repeated during the
18-20th minute of breathing a gas mixture containing 9. 0 . Group I con-
4 2
sisted Of 30 control subjects with a mean age of 37 yr. Group 11 consisted of
37 patients with focal Dostinflamuatory cardiasclerosis, with a nean age of
34 yr. Group III consisted of 47 patientsvith limited atherosclerotic
cardiosclerosis. All of the subjects were without coirrplaints and had Loxval
blood pressure. Analysis of the results showed that duzation of the cardiac
cycle differed little between the 3 groups- However, the averaGe phase of
asynchronous contraction in Group III was prolongedin cc.-parison with Group I,
which apparently was due to left veritricular hypertrophy, as well as
dystrophic and sclerotic changes in the myocardim. Again, in corq)arison with

Group I, mechanical systole in Group III was prolong-ed. The itit-rasystolic
index, rate of increase in intraventricular pressure, anzc~ the mchanical
coefficient in Group III were si[,mificantly decreased in comTarison with
Groups 1 and II (P4 0.001), while the cardiac tension inclex vas iiacreas-ed in
Group III in relation to the other 2 groups (P -,-' 0.001). In the li~Toxic test
the heart rate increased by 5-7 beats/min in all 3 groups of subjects. in
Groups I and II the phase of isorrietric contraction decremsed and the rate of
rise in the intraventricular pressure increased. In Group III in most of the
subjects there was a tendency for the phase of isometric contraction to
decrease; the rate of increasa in the intraventricular pressum, was decreased,
as vel.1 as the intrasystolic index. Theselchan~ges in the Group III subjects
were indicative of stage I hypodynwUra corOis.
2 /21

USSR
UDC: 539.171.017
AZIMOV, S. A., DAUDOV, Z. Kh.,,IIOCILETKOV, G. A.9 MTEN`KOj Yu. P., LEV-
KOVICH, S. G., Tashkent State 1. Lenin
"Fluctuations of the Number of Particles, and Transition Effects in
Electron-Photon Showers in Lead at Energies Greater Than 20 Gel"'
Moscow, Izvestiya Akademii Nauk SSSR: Ser, Fizicheskaya, Vol 37, No 7, Jul
T3, PP 1354-1355
Abstract: Fxperimental data are presented on fluctuations of the number
of particles at depths of 1.5, 4, 11, 15, 19,and 23 radietion units in
electromagnetic cascades at energies greater tl~an ^20 GeV for four energy
intervals. The lead-brass transition curve is given for.five brass layers
located at a depth of 9.9 radiation units.

USSR uDc 621-791.053.o1:669-017-3:669-71+621.762
OV P. G. Candidate of Engineering Sciences, and IUKIFORUV, G. D.,
P' * A
DbqocEFE~oneering Sciences, Moscow Aviation Technology Institute
"Effect of Structure and Gases Contained in Sintered Aluminum Powder on Weld
Bath Forming"
Moscow, Svarochnoye Proizvodstvo, No 3, Mai 73, Pp 27-28
Abstract: A study was made of the effect of structure and gases In sintered
aluminum powder (SAP) on weld seam formation. A complex composition of mix-
tures exist in SAP of different gas sources from complex hydroxide films on
the particles, bubbles, moisture, and aluminum stearine and stearates which
amount to 200-250 c--2/1009 in the initial.material. It- vas established that
satisfactory weldability of SAP can be achieved by two means: use of increased
pressures during welding or complete degassirg~ of the mterial. 7he first one
is the most complex. It has been associated vith the use of npecialized
equipment and does not ensure stable weld joint properties because the causes
of porosity are not elirnin ted., the liberation of gases being only suppressed
during the welding process. The second method, associated vith-total degassing
of the material, can be promoted by the use of a specified technology of SAP
1/2

USSR
KOMTKOVJ P. G., and NIMOROV, G. D., Svarochnoye Proizvodstvo, No 3, Mar 73,
pp 27-28
treatment. In this case the problem of selecting tile most practical tenmer-
ature-time mode of briquette annealing should be solved emd measures under-
.taken to control gas content at the different stages of se-mi-finished
producted manufacture. 5 figures, 2 tables, 3 bibliographic mferences.
2/2
- 72

USSR UDC 542.91.547.455:547.11118
SHIBAYEV, V. N., KUSOV, Yu. Yu., TROITSKIY, M. F., and LKOCHETKOV, N. K.,
of Organic Chemistry imeni N. &. Zelinskiy, A.--adem, ~iences
Institute of SL
USSR
"Chemistry of Glycosyl Phosphates and Their Derivatives. Communication 4.
Phosphorylation of Benzoylated Glycosylacetates of the Phosphoric Acid and
Synthesis of a- and a-Anomers of 4-0-Methylsulfonyl-D-galactopyranosyI
Phosphate"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 8, Aug 73,
pp 1862-1867
Abstract: The synthesis of a- and 5-anomers of 4-0-methylsulfonyl-D-
galactopyranosyl phosphate was carried out by fusion of 1-0-acettyl-2,3,6-
tri-O-benzoyl-4-0-methylsulfonyl-B-D-galactopyranose with anhydrous 113PO4.
During phosphorylation of glycosylacetates containing a benzayl group at
C-2, the reaction products may be predominantly 6-anomers of glycosyl
phosphates. It was shown to be possible to use Ion exchange chromatography
for the separation of a.mixture of anomers of the shielded gl-ycosyl phos-
phates.
30
. .... ... .....

USSR UDC 542.9l.-547-455-547-11118
SHIBAYEV, V. IT-, KUSOV, YU. YU., KUCHAR, S11.0 and ICOCIIETKOIT, IT. 11"
Institute of Organic Chemistry imeni N. D. Zelinskiy cade.
Sciences USSR
"The Chemistry of Glycosyl Phosphates and Their Derivatives. Com-
munication 2. The Synthesis of Deoxyglycosyl,Phosphate Deriva-
tives of 6-, 4-, and 3-Deoxy-D-Glucosell
Moscow, Izvestiya Akademii Wauk SSSIR, Seriya Khimicheskaya, No 2,
1973, PP 430-434
Abstract: Synthesis of deoxyglycosyl phosphate derivatives of 6-,
4-, and 3-deoxy-D-glucose was achieved through fusion 0 tile
acetates of deoxysugars with anhydvous 11 PO Acetylation ot-
3 40
deoxysugars was attained with Ac 20 in the preschce of AcOlla (100 0
2 h)., and subsequent phosphorylatioh of the resultant/3-tetra-
acetates was performed with an 8-fold excess of H PO der vacuum
3 411 n
at 500. Deacetylation of the products with I N LiOH resulted in
practically complete removal of inorganic phospbate as the lithium
113

,USSR
SHIBAYEV, V. N., et al., Izvestiya Alcademii Nlauk- SSSR, Seriya
Khimicheskaya, No 2, 1973, PP 430-434
salt. The resultanto(- andg-anomers of the deoxyglycosylphos-
phates were resolved by chromatography an a Dowex-ix8 (HCO-)
3
column, by elution with a linear gradient of triethyLarimonium bi-
carbonate (1311 7-5). In this manner, the respective triethyl-
ammonium salts of 3-deoxy-O(-D-ribohexop),ranos),l phosphate (1)~,
3-deoxy-,8-D-ribol-iexopyranosyl phosphate (II), 4-deoxy-O(-D-
xyloilexopyranosyl phosphate (III), 4-deoxy-/3-1)-xylohexopyrinosyI
phosphate (IV), 6-deoxy-O(-D-glucopyranosyl phosphate (V), 6-deoxy-
S-D-glucopyranosyl phospbate (V:1)jD(-D-g1ucojj3,ranosy1 phosphate
(VIVJI~ andB-D-glucopyranosyl Phosphate (VIII) were synthesized
from the correspon ding j6-tetra acetates (I and,11 from 15234p6-
tetra-0-acetyl-3-deoxy-/3-D-riboltexopyranoseI III and IV from
ls2,336-tetra-0-acetYl-4-deoxy-/-3-*D-xylohexopyranose, V and V-1.
from 1,2,3,4-tetra-0-acetyl--6-deoxy- D-,glucopyrartose), and VTT
and VIII from 1,2)3,4,6-penta-0-acetfl-/3-D-.--Iucopyvitiose. The
average yield of the deoxyglycosyl phosphates ranged from 3S-40%,
and formation of the~X-anomer predoraInated under these conditions
2~3 phosphorylation. In the case of the D-glucopyranosyl
47

USSR
SHIBAYEV) V. N., et al., Izvestiya Alcademii Yaulc SSSPZ, Scriya
Khimicheskaya, No 2, 1973, pp, 430-434
phosphates the ratios of 0(- and fl-anomer were reversed, apparently
due to the shorter phosphorylation times. Optical rotatory dis-
persion data and [00 values were used to evaluate the config-ura-
-D
tions about C-1. Mobilities on paper electrophoresis were identi-
cal for the deoxyglycosyl phosphates and the Q-:D-.-lucopyranosyl
phosphate (paper M, Lenin,-,rad Factory 'No. 21 20-25 V/cm, I hr, 0-05
1 C former
triethylaw-monium bicarbonate buffer) P11 7-5)., ~Ivhilt! th
M
showed greater mobilities on paper chromatography in two solvent
systems.
3/3

'USSR UDC 542-91:547-455:547.1'11,S
KW;H&TXO-K,-V. K.,, SHIBAYEV, V. N.., KUSOV, YU. YU.) and TROITSIM,
Mv Fe. Institute of Organic Chemistry imeni X. D. Zelinskiy,
Academy of Sciences USSR
gThe Chemistry of Glycosyl Phosphates and Their Derivatives. Coni-
comication I. The Synthesis of 4-Thio-Q(-D-Glucopyranosyl
Phosphate"
Izv. Alcad. Nauk SSR, Ser. 10iiinicheslcaYa,
Moscow No 2, 1973,
PP 425-430
Abstract: This is the first reported synthesis of 4-thio-O~--D-
glucopyratiosyl phosphate (1). The reaction sequences leadin(F to
the synthesis of I were as follows: 5.6 - 20,6-tri-0-benzoyl-4-0-
'X-inethyl-D-glucopyranoside and 4.8 9 C
methylsulfonyl-L 6i[ 5COSK were
dissolved in 50 ml DMF and I-teated to 140 the mixture was cooled,
sediment removed, and the filtrate concentratedi.ny
fArun. The
resultant residue from the filtrate was dissolved in CHU 3' fil-
tered through a column of activated charcoal, concentrated by
wicuum evaporation,, and recrystallized from abBalute ethanol.
1/3
45

USSR
c I icsicaya,
KOCHETKOVI N. K., et al., Izv. Akad. Nauk SSR, Ser. Khimi
No 21 1973, pp 425-430
Three and eight tenths g (64%) of 2,3,6-tri-O-benzo3,l-4-tilio-4-S-
benzoyl-a-methyl-D--lueopyranoside (II) ivere obtnined. The struc-
ture of II was confirmed by IRI spectra. Subsequently, I r, II was
treated with ST~'- 11Br in glacial AcOH (20 nil); the suspension was
stirred for 24 h at 200, poured into 20 nil of glacial AcOll, and
extracted three times with 50 nil CHCI 3' The oxtracL was washed
with Na11CO 3' ice water, dried over ITgSO,,) corii',,entrated 1)),, vvarwra-
tion., And yielded 0.9r) I" of 2,3,6-tri-O-benzovl-4-'Clii.0-4-S-beiizoyl-
0(-D-glucopyranosyl bromide (III). Five tenths -a of the chromat-o-
graphically homogenous III was dissolved in 10 ml CJ1Cl (alcohol
3
free), and 0. 5 - AgOAc added. The suspension was stirred 24 11,
filtered throu.-h celite, concentrated by evaporation, and the
residue recrystallized from abs. ethanol to yield 0.32 Ir (64..S';)
1--O-acetyl-2~,3,6-tri-O-benzo3ll-4- 4-S-benzoyl-p. -D-gltlco-
pyranose (IV) Lm-P- 129-1320., LOOD + 56.Sol. lWand AFIMR spectra
confirmed IV. 0.2 - IV were then phosphorylatad with 0.21 g
crystalline H 3P04 in vacuum for 3 h at 500~ the mi.xoxro cooleld)
213

USSR
KOCHE-TKOV, N. K., et al., Izv. Alcad. Hauk SSR, Ser. Khimicheskaya,
No 2, 1973, pp 425-430
g crushed ice added, and extracted with CIJCI .1 containing 0.8
ml trioctylamine. The CHCI extract was conc~eAtrated by evapora-
3
tion, applied to a Dower-lX4 (FICO-) column, and eluted with a lin-
3
ear gradient (0-1-0-5 M) of a water-methanol solution of triethyl-
anmionium bicarbonate. Fractions containing or,ganic phosphorus were
pooled, concentrated by evaporation, and yielded 7.9 g (3-l',j) of
2,3,6-tri-O-benzoYl.-4-tilio-4-S-benzoyl-O(-D-g-l.ucopyranosyI phos-
phate as the triethylammonium salt (V). Finally, 2.29 of V was
debenzoylated with 3 ml CH 3ONa in argon saturated methanol for 48
+
hr.' at 0 The mixture was filtered through a Oowex-50 x0l"'In' (H
the cluate neutralized with S% N.1 011, evaporated, dissolved in cold
water, washed with ether, and rapidly evaporaW to dryness. I
was obtained in a yield of 1.83 9 (79/'0); [OQ + 60 So.
D
3/3
-46

U S-S R
ZHIBAY-p")"I v
vT
of the USSR lica' yj T L
of Scju~cj~'
Zelinskiy 11-Stitilte
USSR AcadQ-v of
-Ciences *7
--ascow
IrA P~-ew SYn. he,
Of
o"'rala's'
ri
Do!, Lad-v
c,-, VcA 20-, -7,
al' the
of , _-~
h
I ykla -I
Phasp!r"~t;:!"~
1: t;
E~vvth-asis of
tatjr)'% or
of
Z
tho-e ~'Itl
Oil"; djfj'ir-'Ilt"jr r)(Ji.
ur: the
t; rt t ru)
n4'.- s., 4 !~; R!
-radjo_'jCtj-,re 4
rl t I t
lit, c
'a f U J.*'-
1, ' t h
;ii I`
to J P, I'l..

USSR UDC 541.15:547.455
N. K., KUTDRYASHOV, L. I., CHLENOV, M. A., and GRPNEVA, L. P.,
Institute of Organic Chemistry, Acadewl of Sciences USSR imani N. D.
Zelinskiy
"Radliolysis of Aqueous Solutions of Some Organic Monophosphates"
Leningrad, Zhurnal Obshchey Khimii, Sep 71, Vol 41, No 9, pp 2071-2076
Abstract: A study was conducted on the radiation-induced chemical conversion
of a number of organic moaophosphates. Cyclohexyl monophosphate and glucose
monophosphate containing the phosphate group in I and 6 positions tere selected
for the study. Determinations were made of the decomposition yields of the
dipotassium salt of a-D-glucose-1 phosphate (G-1-P) and disodium salt of
D-glucose-6 phosphate (G-6-P) as well as of the yields of inorganic phosphate
on radiolysis of these salts and cyclohexyl phosphate disodium salt. The
OH radical appears to play the dominant role In the process of radiation
dephosphorylation. The formation of inorganic phospiiorus is not followed
by the formation of glucase. The zvaluat~on of the total amount of neutral
sugars in the case of both sugar phosphates has shown thaL the yields cor-
relate well with those of inorganic. phosphate. 'The yield of reducing-type
sugars was reduced to one half and equaled 1.0 and 0.5 for dipotassium salt
1/2

USSR
KOCMKOV, N. K., at al., Zhurnal Obshcbey Khimii, Sep 71, Vol 41, No 9,
pp 2071-2076
of a-glucose-1 phosphate and disodium salt of D-glucose-6 phosphate, respec-
tively. The neutral salts included desoxy- and desoxirketo compounds. Further
studies of radiolysis products and related regularities will provide a clearer
pattern of radiative dephosphorylation in terms of biological activity.

--r-wT
id olz UNCLASSIFIED PROCES�rNG DATE--230CT70
TLTLE--THE CHEMICAL METHOD OF SPECIFIC DEGRADATION OF RNA WITH SELECTIVELY
REMOVED BASES* 3.FISSION OF PHOSPHOESTER'BOND IN RtBOSE12o AND
AUTHOR-(05)-TURCHINSKIYI M.F.o GUSKOVAs L.I., KHAZAlt IoKor BUDOVSKIY#
EtIal jpQJ~TKOyi N&K.
COUNTRY OF INFO-_Zlussk~
ilk
SOURCE-MOLEKULYARNAYA BIOLOGIYAr 19TOr*"
VOL 41 NR 3r PP 428-434
DATE PUBLISHED ------ 70
SUBJECT AREAS--BIOLOGICAL AND-MEOICAL SCIENCES# CHEMISTRY
TOPIC TAGS__RNAf CHEMICAL DECOMPOSITION9,AMINE DERIVATIVEr AMINE CATALYST
CONTROL MARKING--NO RESTRICTIONSi
DOCUMENT CLASS--UNCLASSIFIEO
PROXY REEL/FRAME--1998/0187
STEP NO--UR/0463/7010041003/042810434
CIRC ACCESSION NO--AP0120885

212 012 --AP0120885 UNCLAS SIFIE0 PROCESSING DATE--230CT70
CIRC ACCESSION NO
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. AMINE CATALYZED FISSION WAS
STUDIED OF THE PHOSPHOESTER BOND IN RHE RIBOSEr2(3), PHOSTATE, THE
COMPOUND MODELLING INTERNUCLEOTIOE LINKAGE IN RNA WITH REMVOEO BASEo !T
WAS SHOWN THAT RIBGSF,3,PHOSPHATE WITH PHOSPHOESTER BOND IN BETA
POSITION OT HE GLYCOSIDE CENTER WAS ONLY SPLIT IN THE PRESENCE OF THE
PRIMARY AMINES. THE ABILITY OF AMINES INVESTIGATED TO CATALYZE THE
CLEAVAGE OF THIS BOND DECRE~SES IN A SEQUENCE; PYANISIDINE IS GREATER
THAN OR EQUAL TO ANILINE APPROXIMATELY OtAMINOBENZUIC ACID GREATER THAN
BENZYLAMINE APPROXIMATELY EQUAL TO LYSINE.GREATER THAN ETHYLENEDIAMINE
GREATER THAN PrAMINO BENZOIC ACID APPROXIMATELY EQUAL TO SULPHANYLIC
ACID GREATER THAN BETA ALANINE APPROXIMATELY EQUAL TO METHYLAMINE. IN
THE PRESENCE OF PYANISIDINE UNDER MILD CONDITIONS IPH 5930DEGREESt 5
HRS) THE RAPID SPECIFIC FISSION OF THE PHOSPHOSTER BOND OCCURS BOTH IN
AND IN DEURIDYLIC RNA, PHENYLHYDRAZINE CAUSES RAPID
SPLITTING OF RIBOSE%2oPHOSPSHATE OUT NOT OF RIBUSE#39PHOSPHATE*
FACILITYS INSTITUTE OF CHEMISTRY OF NATURAL PRODUCTSP ACADEMY OF
SCIENCES# USSRt MOSCOW*
"N't AS
U14UL Li

USSR UDC'547.455
KUDRYASHOV, L- I.o LIVERTOVSKAYA, T. TA-t VDZNESENSKAYA, So V.,
.=AjAXh._"- Lt SHARFATYYt V* A.j and KOCHETXOVp N. K.,
#Radiation Chemistry of Carbohydrates, XII. Effect of Structural
Factors on Course of Radiolysis Processes of Aquoous Solutions of
Methylglycosides"
Leningrad, Zhurnal Obshcbey Khimiiq Vol 40, No 5, May 70, pp 1133-1137
Abstract: The authors studied regularities reflecting the relation-
sHip be weezi the structure of the glycoside molecule and processes oc-
curring during and after irradiation of aqueous solutions. The ob-
jects of study chosen were 04-methyl-D-glucopyramo side -methyl-L-
arabinopyranoside and U-methyl-D-galactopyranoside. The radiation
sources used were a Co-60 device and an electron accelerator for fro-
zen solutions. The periodate oxidation method was used to determine
the glycoside concentrations of the irradiatfed solutions. It was
found that the stereochemistry of methylglycosides has a significant
1/2

Obshchey
Xhimi Vol 40, No 5, MAy
KUDRYASHOVt L. I., et alep Zhurnal
70t PP 1133-1137
effect on their radiation resistance. There is practically no forma-
tion of free monosaccharides in the radiolysia of dilute aqueoua solu-
tions. The principal process in the radiolysis of CL-methyl-D-galac-
topyranoside and a -mothyl-L-arabinopyranoside is the formation of
deoxy sugars. According to EPR measurements, the composition and
ratio of radiolysis products'depend on the structure of the initial
molecules and the reacitivity of the intermediate particles that fom

A_
USSR UDC 541.15
Corresponding Member Academy of Sciences USSR; KUDRYASHOV,
L I and SENCHENKOVA, T. M., Institute,of Organic Chemistry imeni N. D.
Zelinskiy, Academy of Sciences USSR, Mosco,w
"Racemization of alpha-Amino Acids under the Action of gamma-Radiation"
Moscow, Doklady Akademii Nauk SSSR, Vol 195, No 2, 1970, pp 410-412
Abstract: The racemization in frozen 2-3 X 10-3M aqueoxiii solutions at minus
78* of L- and D-glutamic acids under the effect of gauma-irradiation was
studied. The solutions were irradiated in sealed glass tubes tinder N2 with
doses of 0.3 - 1.5 X 1022 eV/g at dosage rates of 0.6-2 X 1016 eV/g.sec.
On irradiation of L-glutamic acig, a glutemic acid fraction was isolated
which had a specific rotation aT, -+8.5* and m. P. 1900 V118. a20-+13.6* and
m. p. 236* for L-glutamic acid. The alphanaphthy1hydantoin gerivative of
this fraction had m.p. 180-186* vs. m. p. 2250 for the corresponding deriva-
tive of L-glutamic acid. Conclusive evidence indicating inversion of the
configuration of D-glutamic acid as a result of irradiation, was also ob-
tained; the specific rotation was lowerediand a fractiouvas Isolated by
preparative separation on paper and elution that was shown to be L-glutamic
1/2

USSR
KOCHETKOV, N. K.,
-al..Doklady Akademii Nauk SSSR, Vol 195, No 2, 1970, pp
410-412
acid by applying L-glutamic acid dehydrogenase from bull liver. The extent
of racemization could not be estimated from the quantitative standpoint at
this stage.
2/2
82

DAT E-20%
N M)
0 u c- iJ"I Lj~ ~i
T I TLL-S I AL CGLYCLL I P ISJl "HE s r AJ f- I svi i i16 LA S 1 U kAS f PON T RUC TU E OF
THE CL 1 11, _- ChA IN' -U-
ALTHf-jR-( C4)-.' LCFE IKC%jK ZHUKU"'VAI G SfllxP.jVA G P . 30GJANOVSKAYA
T . A
CCUNTRY CF li\,IFC--,.SSR
SOURCE--DCKL. AKAD. NAUK SSSR 1970l 191(.Z)t 35f! bii tHEIM
DATE PUBLISHED ------- 7C
UbJECT AREAS-61UGGICAL A,%() MEUICAL SCt,(:N(;ES
--STAK"FISfi, LIP10, FRACTIGNATICN, CHAOMATG4~RAPHIC SEPARATION,
TOP I CTAGS
-SILICA GEL
CUNTRCL 'MA)~KlN.G--N0 RESTRicrIGNS
_"0CCuAEHf CUASS--LNCLASSfFJi:&
-PROXY kEEL/FRAPE-3003/1489 SrEP
CIRC ACCL-5SICiN Nu---jAF013-jtflS
J.%~ t A S 51 Fj

-2/2 UNCLASSIFIED. PROCESSMIG DATE-20NOV7C
CIRC ACCESSICIN NIC-ATC31:30418
:ALSIKACT/txTRACT--(U) CP-C- A3, S T I-,, A C TCHkONIATOG. CN SIL[CA GEL ANO ACID
v 'T HA NO L Y 3 1 S A' 0 l-, 1-" T HY I AT I ON A I T I- IE L T a
FYORCL'(SIS 'i%ERE USEJ ALl,"N' I.ITH M(7
SHU%~Tf-:Al ThE STARFISH YIELOS AT LEAST 3 GLYCCILIPIOS (A., b AiNO C) WHICH
',iEThAv.(.,LYSIS YICLO PHYTOSPHINGOSiNE AND ME ~SrFRS OF Ht(HER FATrY
ICIGS. AND C CGNTAIA CNLY 0 6' UC.GSE WHILE C CtINfAINS 1) GULC(JSL- MiD L)
-SE, EQUAL ANTS. P-4Rl'14L SlRi~ -S A~'
GALACYC IX XF
FA(;IL.ITY. ms,r. GRG. Kiiim. im. LEL INSKUGUI MOSCOIN-1 USSR4

uDc 621.762.,669.71
KOTTYEVA, L. U., FILICFMMI 11. P.0 and ROCIMTKOV, P. C.; Noscow Aviation
TeeMological Institute .... ...
"Study of the Effect of the MineralimtIon Agent on Properties of SAP Frolucts"
Ordabonikidze, Izvestiya Vysshikh Uchobnyhh Zavedeniy, Tsvetnaya kletallurgiya,
No 1, 1973, pp 145-i49
Abstractt In order to increase the inechanIcal. properties of products. tzlade
of SAP (sintered aluminum powder), an attempt was made; to increase the con-
centration of Ci -Alz 03 phaze in. to Al powd e-- by adding to.it the mineraliza-
tion agent AlF3 j Aluminum powder with AlF j, ifas subjected to sintering at
0
8
23 C for 3-8 hours and the percentage of oxida phanei~ in it vas neasured.
The obtalned results showed that the addition of 3 AlF3 to Al T~Ovder
increased the, quantity of oxide phases by 1.5-rur trith. predor-0.11ant exEmulle
fractions of -0.074 + 0,,044 jaa after sinterin& at 82-30C% At this tenrRxature
AlF Teacts directly with AlO(OFI) and Al C1 -A:L,)O ariall
3 (QH)3 by for"""'e 1. 3
crystals, uhAch becoze cryztallizatlon centera capable of producing q -'k120 3
phase during the recrystalliv.--tion heating. Reactions of 1073 with 1,10(c"11) alva
AI(OH)3 also produces HF, which reacts directly with 7-%-Al20., a--d ti-an2fo-=.s
1/2

USSR
KMYEVA, L. U., et al., Izvestiya VysshJJch UchebayTth Z "avedeniy, Tsvet-naya
Hetallu=giyaq 11o it 19?31 pp 145-149
It into the Q(-A1 0
2 3 phaze. Without HP this transfwnaation would Le
impossible, In the presence of AlF3In Al powder, a triansformation of Al(Q:j)3
Into AlO(OH) takes place at roon teriperSture In hexretically sealed contain,::rs,
which uould be possible only at Ili -625 C without, the U-necalization arert
583 0
AlF,# When samples of Al powder with 3 wt,% AD.'3w*z-a heatvi2at 823 0 for 6
hours, I.-he tensile strengath of sampl(3s waa within 28-42 krv!~14 , and the
relativo elongation within 8-15%, compana with 22-40 ft_q/Li2 and 3-7;5,
respectively, without AlF 3' The beot mechaunical propertlea of SAP r-)-m-ples
were obtained with powders containing - 0.074 + 0.0114 = paxticleu, SAP
products containing Alri3miner9aization agent can also be velded.
2/2
- 26 -

L/Z uzz UNLLA55 I P-1~13 PRUCESSING DAIE--IISEP70
i-TITLE--ON PATHOGENESIS OF PUPILLARY DISORDERS IN DIFFERENT r-O;tMS OF
SYPHILIS OF THE NERVOUS SYSTEM -U-,
AUTHOR--K
BRAYSEV, A.Vo
j,COUNTRY OF IVFO--USSR
l,:SOURCE--VESTN_IK DERMATOLOGII I VENER0LOG,lIv 19701 NR 39 PP 53-58
ij.:DATE PUBLTSHED ------- 70
f:'SUBJECT AREAS--BIOLOGICAL AND MEDICAL SCIENCES
'_T.QPIC TAGS--EYEv VENEREAL DISEASE* NERVOUS SYSTEM DISEASE
~;_CONTROL MARKING--NO RESTRICTIONS
.-..DOCUMENT CLASS--UNCLASSIFIED
REEL/FRAME--1986/0627 STEP NO--UR/0206/701000/003/0053/0058
CIRC ACCESSION NO--AP0102613
UNCLASSIFIED

212 022 UrqCLASSIFIED PROCESSINK; DATE--IISEP70
~CIRC ACCESSION t4O--AP0102613
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE PATTERN OF STRUCTURAL
FUNCTIONAL CHANGES IN THE PUPIL ANn OF PUPILLARY REACTIONS MAY BE USED
TO A CERTAIN EXTENT FOR THE JUDGEMENT OF THF DURATION Or SYPHILITIC
INFECTION OF.THF FORM OF THE NERVOUS SYSTEM SYPHILIS (MESENCHYMAL OR
PARENCHYMATOUS)t AND OF THE LEVEL OF DISORDERS OF THE REFLECTO-RY'ARCH OF
PUPILLARY REACTIONS. PUPILLARY DISORDERS IN CONrAGIOUS FORM OF SYPHILIS
ARE CHARACTERIZED RY MILD CLINICAL MANtFESTATIONS AND ARE DETERMINED BY
THE INVOLVEMENT OF DISTAL AFFERENT AND.EFFERENT FISERS OF THE PUPILLARY
REFLECTORY-ARCH,' I-N-EARLY MENINGO VASCULAR SYPHIL'[S OF THE.NERVOUS
SYSTEM A FURTHER IqVOLVE4ENT IN Tk PROCES'S OF- ROOTS OF TWE OCULO,-40TOR
NERVE OCCURS IN THEIR PASSAGE IN THE SUBARACHNOIDA1. SPACE OF THE BASIS
or- THE BRAIN. IN THIS FORM, AS IN CONTAGIOUS FORMS OF SYPHILIS,
WEAKENING'DF PUPILLARY REACTIONS WAS OBSERVED COMPARATIYELY RARELY.
LATE FORMS nF MENINGO VASCULAR SYPHILIS 4RE CHARACTERIZED BY DISnRDERS
OF PURILLARY REACTIONS DUE TO THE INVOLVEMENT FIRST OF INSERTED NEURONS
THE 4108RAIN AND THEN OF ITS PARASYMPATHETIC NUCLET. t'UPILLARY
-DISORDERS IN,j.fjTE FORMS OF SYPHILIC OF THE NEgvnus ~SYSTFM ARE OBSERVEr)
IN ALL PATI~NTS, ARE CRUDE AND DUE MOSTLY TO THE AFOECTION OF
PARASYMPATHETIC NUCLEI OF THE BRAIN STE14 WHICH IS ACCOMPANIED, IN
ADf)ITION TO THE LOSS OF PUPILLARY REACTIONS TO LIGHT, BY DISORDERS IN
THE ACT OF CONVERGENCE AND ACCOMODATION,
tlltlqf t_jA, 4;
O_ TIT

USSR UDO 621.285.144
ZEMY-011SHY, BO-1., KCCF---TKOV. V.1.
"Grid Unit For Beam Tetroden
USSR Author's Certificate No 272238, filed 7 Jan 69, pAblishad 13 Dec 70 (from
R"h--Elektronika i yeye prim-on niye, No 4, 1971, Abstract No 4.a45P)
Translation: A grid unit for a beam tetrade is proposed which containe a cer-
amic ring inzulator and two planar grids __ screen and control. With the ob-
Ject of increasing the precision of interolectrode spacing device, both grids
are fastened to the and face of the ceremic ring insulo4o r, the screen grid di-
rectly and the control grid through a separatinv metalllic rin the thic?nCee
of which determines the a-aacing, between the grids. With the o'Dject. of simplify-
ing assembly, the separating ring consists of t,,jo rings euper,_i-_-i-.)csed one on the
other. The thickness of the supporting ring is ecraol tc, the thicknesa of the
acreen grid and of the adjusting ring to the,eepar6tion batwevn grids.

USSR MC 517-53
ns"
flMultiple Differentiation of 31nole-Parameter Familes of One-Sheeted Functio.
Novosibirsk, Sibirskiy Matematicheskiy Zhurnal, Val 12, No 2, 1971, pp 367-373
Abstract: This article proves multiple differentiability bazed on the para-
meter of a family of one-sheeted functions an-A gives an inteTral representa-
tion of the derivative of the fuzictions for the pararetar. From the values oil
functio, e 3 mrz integral, a
the LI ns at the domain boundiary, with the ai of th
function is consLtructed that is regular in the domain. The.-ofore, the essen-
tial consideration is findin, the rolqtionships which connect rhe value. at the
boundary of the do--min of the function being constructed witli V!,Gl,m quantities.
Using a function which is regular in the ring, the author coostructs a func-
tion that is regular in the tmit circle. The author proposes three theoreyas
and gives, proofs thereof. He t;hen proceeds to xhow -wjuivalency of the varia-
tion formulas and co-aronts that the difference in. variiitionn eor he constant
is Insignificant and due only to lack ofinorm-Alization of 0 (w, t). The
article contains two bibliographic citations,
1/1

'1/2 024 UNCLA~SIFIO POOCESSING 04TE--18SEP70
TJTLE--COPRECIPITATION OF SMALL AMOUNTSbF GALLIU14 WITH SOME METAL
HYDROXIDES -U-
,AUTHOR-(04)-PLOTNIKOVv Vol.1 GIBOVA, E.G., KOCHETKO A..V.L.t CHINAEVA? V.P.
-COUNTRY OF INFO--USSR fell,
'~'~,'SOURCE-VESTN. AKAD. NAUK KAZ. SSR 1970, 26(219 67-8
~~'DATE PUBLISHED ------- 70
..SUBJECT AREAS--CHEMISTRY
TAGS--GALLIUMP HYDROXIDEt ALUMINUM COMPOUNOP IRON COMPOUNDi TITANIUM
COMPOUND, ZIRCONIUM CGMPOUND9 CHEMICAL PRECIPITATION, RARE EARTH
COMPOUND
~C_O%TkOL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
~.__PROXY REEL/FRAME--1981/0440 STEP NO--UR/0031/70/026/002/0067/0068
CIRC ACCESSION NO--AP0050461
UNCLASSIFIED

V2 024 UNCLASSIFIED PROCESSING DATE--18SEP70
-,,CIRC ACCESSION NO--AP0050461
ABSTRACT/EXTRACT--fU) GP-0- ABSTRACTs THE EFFECT OF THE NATURE OF THE
HYDROXIDE COLLECTOR ON THE COPPTN. OF GA WAS STUDIED. THE COPPTN.
r INCREASES WITH HYDROXIDES OF THE FOLLOWING METALS AL IS LESS THAN SC is
LESS THAN FE IS LESS THAN TI IS LESS THAN ZR IS LESS THAN TH. AT THE
BEGINNING OF MAX. PPTN. OF GA (PH 61, THE HYDROXIDES ARE NEARLY
COMPLETELY PPTD. IN THE CASE OF LA AND MGj THE COPPTN, CURVE IS MORE
COMPLEX. AN INCREASE IN PH LEADS TO THE OISSOLN* OF THE GA HYDROXIDE
PPT, BUT WITH THE BEGINNING OF OPTN. OF LA AND MG HYDROXIDES, IT IS
AGAIN PPTO. THE COPPTN, OF GA WITH HYDROXIDES OF THE RARE EARTH
ELEMENTS INCREASES IN THE SERIES ER IS LESS THAN DY IS LESS THAN TB IS
LES-S THAN GO. THE COPPTN. OF GA DEPENDS ON THE NATURE OF THE HYDROXIDE
COLLEC-T.O~. GA IS. CAPTURED aY THE METAL.HYDROXIDE,S;FOR141NG COMPOS. OF THE
i GALLATF.TYPE. THE EFFECT OF THE. ORDER OF MIXING OF THE SOLNS.t TEMP.,
AMTS.-OF*GA AND COLLECTOR IN THE:SAMPLEI' CONCN. Qr- SALTS, ETC. DIFFERS
FROM LITERATURE DATA7 E.G., FOVIN.

7-,
7
AA0030206
stroke of the sUde-block, compressed air Is
suppbed to diaphragm 12. AirLs ejected from
under diaphragm The low-.3peed packs of discs
come together ai;d the htgh-speed ones separatp,
the working stroke 9f the slide-block takes palace
at low speed.
-rKnv
23.10.67 as 1195585IZ5-27. MALTG I if F.V. 6 gp
V.M. GOAKII MOTOR WORKS W.6aM
_'TMIs47c. Int.C1. F 16d.
FACILITY: Gor'kovskiy kitomobil'nyy Zavod
MEMO=

.4, 114P, N
A-AO030206
A3
IT;

,.`112 020 UNCLASSIFUO~:~ PROCESSING DATE--230CT70
TITLE--INTERACTION OF 14IGH VOLTAGE PORCELAIN WITH GLALE-U-
AUTHOR-(02)-14ASLENNIKOVA* G.N., KOCHETKOVAY NoF.
4c"
:,~_COUNTRY OF INFO--USSR
:SOURCE--IZV. AKAD. NAUK SSSRt NEORG. MATER. 1970t 6(3)t 542-6
PUBLISHED ------- 70
SUBJEC*T AREAS--MATERIALSt PHYSICS
_~TOPIC TAGS--PORCELAIN, THERMAL EXPANSIONt SPECIALIZED COATING# HIGH
~VOLTAGE LINE
":.CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
V-PROXY REEL/FRAME--1997/0632 STEP NO--UR/0363/70/0061003/0542/0546
CIRC ACCESSION NO--AP0119544

2/2 020 UNCLASSIFIE0 PROCESSING DATE--23OCT70
CIRC ACCESSION NB--AP0119544
ABSTRACT/lEXTRACT--(U) GP-0- ABSTRACT. THE INFLUENCE OF THE INTERACTION
BETWEEN GLAZE AND HIGH VOLTAGE PORCELAIN ON THE CHANGE I.%, THE THF-RMAL
EXPANSION COEFF. OF THE INTERMEDIARY GLAZE LAYER WAS INVESTIGATED. THIS
REACTION CAN BE CONSIDERED AS BEING A REACTION 01: THE OISSOLN, OF THE
SOLID PHASE OF PORCELAIN IN THE LIQ. PHASE OF THE GLAZE. IT IS THUS
SHOWN THAT DURING THE FIRING OF PORCELAIN ARTICLES THE PORCELAIN
INTERACTS WITH THE GLAZE THEREBY FORMING AN INTERMEDIARY LAYER, BEING A
GLAZE WHICH HAS ASSIMILATED UP TO 40-5PERCENT POACELA-1,N (i320OEGREES).
-AS A RESULT.OF THIS, THE CHEM. COMPN. OF THE GLAZE CO,AiING CHANGES, AND
CONSEQUENTLY ALSO ITS THERMAL EXPANSION COEFF., TitEREBY EXERTING AN
EFFECT ON THE MECH. STRENGTH VALUE OF THE GLAZED 5AMPILES. THE THER44AL
EXPANSION COEFF. OF THE INTERMEDIARY LAYER DECREASES AS COMPARED TO THE
THERMAL EXPANSI*ON COEFF. OF PORCELAIN, WHICH ENHANCES INCREASED MECH-
STRENGTH OF GLAZED PROCELAIN ARTICLES AS COMPARED TO THE 1*q9NGL4zE0 ONES.
WHEN SELECTING THE GLAZES FOR INTERACTION WITH HIGH YOLTAGE PORCELAIN
ONE MUST TAKE INTO CONSIDERATION THE ROLE OF THE INTEEPMEOIARY LAYERV THE
THE PHASE COMPN. OF WHICH DIFFER FROM THE CHEM. AND THE PHASE
COMPN. OF THE GLAZE COATING. FACILITY: M0SKa,INZH.-EilON. INST.
IM* ORDZHONIKIDZE, MOSCOW, USSR*
UNICLASS IFIED

USSR UDC 542.943:547.257.3
NESMEYANOV, A. N., LEONOVA, Ye. V., KOCHETKOVA, N. S., RMILYADA, N. N.,
and BYCHKOV, N. V., Institute of Metal.Organic 66mpomnds, Academy of
Sciences USSR
"Oxidation of 1,1'-Diethylcobalticinium Hexafluorophosphate"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 12, Dec 73,
pp 2791-2792
Abstract: In presence of excess Y14n04 in acid medium the hexafluorophosphate
of 1,1'-diethylcobalticinium (I) is converted to the.isalt of 1,1'-diacetyl-
and 1,1'-dicarboxycobalticini=. Other.oxidation agents such as MLn02 and
Cr03 in acidic medium fail to react with (1).

Organome~ta~iii pound
USSR UDC 547.13:546.72 + 546.14/15
Q\tA,,K, S., MTERIKOVA, P- Z., PALITSY
NESHEYANOV, A. N. , !~_q~HETI~~ N. P.,
KSENZENKO, V. I., and SOBOLEVA,T. S., Institute of Hatal Organic Compounds-,
Academy of Sciences USSR
"Reaction of Ferrocene Derivatives With Bromine and Iodine'
Leningrad, Zhurnal Organicheskoy Khimii, Val 9, No 2, Feb 73, pp 378-380
Abstract: Reaction of bromine and iodine with ferrocene substituted with
electron donating and electron accepting substituents was Btudied. At -200
in heptane bromine decomposes ethyl- and 1,1'-diethy'aferrocene; with
1,1',3,3'-tetra-tert-butylferrocene it'forms the tribromide of 1,1',3,3'-
tetra-tert-butylferrocenium. At 500 in benzene iodine doe* not decompose
ferrocene. or its derivatives, forming addition products with various
quantities of iodine, In general, presence of electTon-donating substi-
tuents and reaction with strong oxidizers (C12, BrZ).favo-c the decom-
position of the ferrocene ring. In case of hindered derivatives or when
the halogen is a weak oxidizer (iodine) mainly oxida 'tion products are
obtained, with an intact ferrocene ring, Oxidation to ferrocenium evi-
dently preserves the system from further decomposition by the halogen.

77
US S R
jT
~K-V.A I
ard T:GC
"a.-Iraction of Trivalent Actiniaes and Europiwa Wi til I- Pbez-"y' - -
3
Benzoylpyrazolone-5 Solutions in the Presence of Some Doilor-Active
Noscow, Zhurnal Analiticheskoy Khimii, Vol 25, tl~) 4, Apr 90,
pp
Abstract; Due -6o synergistic effect, the distribution coel"IticlenTs
1-iion oi
for trivalent Am, Cn., bk, and i~u increase corsiderab.Ly an aad
tributyl phosphate I or trioctylphosphine axiae (r_;,6pC) to
)-methyi -4-be n-zoylpjraiol one- 5 solutions in cyc_lohexane. T h e
extraction of Ara, Cm, bk, and Eu by 5olutions of ?,'i !-P-T~-? anc~ i~'0~1~_i-
TOP6 mixtures in cyclohexvne has been examined in relationshiD to the
concentration of TGFQ (for Am, Cm, Lou), of ;~_nd 1-.2.1b) (for C'm, Eu),
It was determined that all elements -nay be quanti-catLli-e-ly extracted
from 0.1 N '-;,N03 with a mixture Of 0.05 Y, PMBP-0.25 li4l or oy a
P.',.'.B?-0.0025 TOPO in cyclohexane. A mixture of
mixture of 0.0
1/2

USSR
t al, Z,,,urnal Analiticheskoy !,hi,,T,!i, Vol 25, No 4,
CE141UTOVA, M. K., e
Apr 70, pp ?10-?14
-0.025 TO-0 extracts quantitatively C.-,. iLrd Eu 4
0.05
0.3 and 0.4 N respectively. on the basis ol- Gm and zu the
authors propose the structure il,eal P.T.~P for tk.*r,-.*., material extr--cted
from the mixtures., Cn t~e basis of --U-zerat,,ire data as well
as their ovm, the authors assume formation of two compounds ~rwn the
other extraction processi WAeA3-2T0?.0 and IfIeA2(['103)-2T0P0.
2/2

U8SR UDC 61-5.616.21[-003.656.6
BEZROMNIMI, A. A., KASPAROV, A. A., AZUROV, V. I KOCIIETKOVA
T. A., .AZD"DOVSKIY, !T,. F., SIDOROVA, N. V., ma
r-G-AIMT-SINA, I. Z. , ZA)IAPALYCVA,, T. V,
"Antifibrosis Effect oC Polyvinylpyridine-N-Oxide as a Compound
to Prevent the Development oE Silicosis"
Nauch. tr. Irkutsk. med. in-t (Scientific Works of Lhe Irkutsk
Medical Institute)) 1972, Vyp 110-, PP 52-53 (from PZh--Farmalco-
-ticheskiye Sredstva. Toksikologiyaj
log�ya. Khimioterapev No 3,
Mar 73, Abstract No 3.54-874)
Translation: The polymers polyvinyl-pyridine-2- and d-N-oxides had
an effect on the de-rce of expression of histologic ilterations in
the early stages of the development of experimental r:dIico6i.-' (10
days) when administered intratracheally and ', especially, hypoderm-
ically. These polymers normalized the indexes of the oxidation
processes in the lun-- tissue and the myrocardixLm. After one,
three and six months of the experiment, the polymers wIth a violec-
ular weight of 40,000 to 80,000 retarded the development of fibro-
sis, reduced the amount of neutrally soluble collagen and
1/2

J
U'SSR
BEZRODNLMIIJ A. A., et al., Nauch. tr. Irkutsk. med, in-t, 1972,
vyp 110, pp S2-53
normalized the amino acid composition of the lung tissue, the
indexes of the oxidation phosphorylation and the activIty of the
intracellular enzymes. On intratracheal administration of poly-
mers with a molecular weight of SO.-OOO to 1,500000 the develop-
ment of catarrhal bronchitis and bronchiolitis was noted.

Public Health, jiygi~ne and Sanitatt-on
q. USSR UiL 616.24-004-092.9-02:0~lo'-OC.-~1.66(~
ILIBA, V. A. and KOC~E-`OV Institute of Labor Hyi,rLeno and C;Cc4pational
Diseases, Academf'50777licall Sciences USSR
"Experimental ?ulmonary Sclerosis After Inhalation of AerGsolzi of
Lithium Alloys".
~ioscow, Gioiyena Truda i ProfessionalInyja Zabolevaniya, 1~c .2, -'t~RC. pp iv-,;i
.4bstract: Rats i-nhaling alloys of rin-nesium and in d--i4`fcrcnL pr~?Crt--Ons
over a period of 4-1/1) months developed tracheitis, brcric-41tis,
Pneumonia, diffuse sclerosis, and emphyuema. The higher tne porc~onta,e of liz-.,Iium
in the alloy, thle more pronounced the cha4gez. It single LqtraLrachoa-, inzj~-~ctlipn
of an aerosol of the magaa 5 ium- lithium alloy gave rit;e to tru stmo sfdf-,,3 -ir. ~.h-;
lungs as those pr"uced by inhalation, b4t the patholo;~-ic;L! procasi wa5 !Q1;z; pro-
nounced and the course slower, because considerable anounlila olf:the dust vere
elizinated by the bronchi and lymph aystam.;

Ace. Nr: Ref. Code: UR 0391
11P003-6570
PRIMARY SOURCE: Giglqena, Truda i Professional'nyye
Zabolevaniyap 1970, Nr PP
EXPERIMENTAL PNEUAIOSCLEROSIS FOLLOWING INHALATION
OF MAGNESIVAi-LITHIUM. ALLOYS AEROSOLS
T.
Ilina, V. A.;_.K_qchetkova
Summary
Being endowed with well-pronounced alkaline properties inagnesium-lithium alloy
aerosr.1,z produce, when inhaled. irritaUng action on the nnu-.-osa of the upper respiratory
;3- a-.ii on the pulmonary tissue and cause i number of cha. g s In respiratory organs.
irclude: moderate catarrhal tracheitis. bronchitis, Interstitial pneUrn0nia, diffuse
and emphysema of the lungs. the extent,of the padhologicai process becomes
as the lithium proportion in the alloy increaso.
D. 4L
RH'EL/TRA',11E
42:,~
J"L, -1 dell,
I M-11.1

USSR UDC 615.332-0W-015-2: (615-31:54?.745
V Hoscow P. A. Hetsen Oncological Institute
KOCHETXOVA,.,._V_
4Effect of Polyvinylpyrrolidone on Toxic:Properties of Stre-ptomycin and ~Iono_
Mycin't
tMoscow, Anti:biotiki, Vol 15, No 1. Jan 70, PP 71-76
Abstract: The toxicity, cumulative effects, and the 1ethal doses of strepto-
mycin and monomycin were determined anerimentally, T.hezi, -Po1yvLn_y1p,,rrroiidon=
in the wide range of various fractions-and molecular was tesi~ed for
4 e detoxifying propert4es against strepturVain and polymycin. it was found
th
-,0.000, an!
that all fractions of the po4,mer with atomic weights 1~,600,
48,000, reduced the toA-city of the antibi6Lics. Further uxperi.-,ents proved
that the polymers with lower molecular weigbt were nore pot;erful deLoxicants.
In animals given lethal doses of antibiotics, those were completely saved to
whom the polymer was administered within 1-9 minutes; if given 30 iiuivtes later
-rue for
onlY 50-60,~ were saved; if later, all animals dicxl. The above is
streptorqcin. honoraycin was fourA to bo more toxcic; ~ 70-d(j.v aninials were saved
Od
when treated with the polymer with'in 1~.2 ninuter,; A.f latk,.ar, -AU aritmaA.5 di
However, if given the pol~nner simultaneously with mwiormycin, o4' the
animals were savel.
1/1

Pomj~~wwwii
P100
7 "Ace N --29763 Rof. Code: IUR'0297
PRIXARY SOURCE. Antibiotikii
Vol 15', Nr 1, pp 71
iROLID'Oll
EFFECT OF POLYVINI LPY RQLIDO., 'E ON T