SCIENTIFIC ABSTRACT ROLSKI, S. - ROMADAN, I.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001445210008-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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L-1

ZHUKOVA. R.R.; ntIDLYAND. AI-Ye., gluvnyy vrach; ROMY.E. Z.Yu., professor, konsull-
twit. v___AmAa__-w_
Streptomycin and para-aminoslicylic acid therapy of osteoarticular tubercu-
losisIin children. Probl.t-ab. no-3:85-86 My-Je '53. NLia 6:7)
1. Detskiy Irostnotuberkulesnyy sanatoriv.'Bakovka'Mos--orzdravotdela.
(Streptomycin) (Bones--Tuberculosis) (Joints--Taberculosis)
(Para-aminosalicylic acid)

- -- -1,------------ ~ . ~- --
I ( .
I L
RDLITS, Z.T4., professor. (Moskva)
Duties of a narse In caring for patients with ostsoarticular

ARKIIIPOVA, O.P., I-And. biol. nauk; BERLD', P.Yu., prof.; VOROWYEV, S.I.,
kand. med. nauk; ZASLAVSKIY, I.D., kand. med. nauk; KUDRYAVT-cEVA,
A.I., prof. [deceased); LAPBIJA, A.I.; MARMON, V.D., prof.; MSSINO,
I prof.; OYFEBAKH, M.I., prof.; POMIMITSOV,
S.V.. prof.; NEZLIN, S.Ye. F
K.V.; prof.; RABUKIIIN, A.Ye., zasl. deyatell nauki RSF,132, prov.;
~ROLIYE,
_Z-Ya-,--zasl. deya.tell nauki RSFSR, prof., SORKINA,. 3.Z.,,
-doxior med. nauk;FILIMONOV, V.I... kand. med. nauk Ldeceased];
YUSKOVETS, M.K., zasl. deyntelt nauki BelorLisskoy SSR, prof.,akademik;
EYNIS, V.L., zasl. deyatell nauki RSFSH, prof., otv. red.;
MUDKOVSKAYA, II.I., tekhn. red.
[Multivolume manual on tuberculosis] Mnogotomnoe rukovodstvo po
tuberkulezu. Otv. red. V.L.Einis. Moskva, Medgiz. V01-4.
[Epidemiology and the organization of the control of tuberculosis]
EpideEiologiia 2' organizatsiia bor'by s tuberkulezom. Red. toma
A.I.Lapina i S.V.1-iassino. 1962. 524 p. (MIRA 15*.6)
1. Akademiya nauk Belorusskoy SSSR i Akademiya sel skokho zyaystven-
nykh nauk Belorusskoy SSSR (for Yuskovets).
(TUBERCULOSIS)

PETRCfV,, Ye.D... Icand.med.nauk. Prinimali uchastiye: POKBITONOVAf M.P.,
prof.; ROLIYE, Z*Yu*, prof. WS1140, S.V., red.; IIATVEYEVA,
M.M,, tekhn.-itd-.--~
[Textbook of methods for the climatological treatmmt of
tuberculosis] Metodicheskoe posobie po klimaticheakomu
lecheniiu bol'mVkh tuberkulezom. Moskva, Medgix, 1961* 64 P.
(MMIL 15:4)
1. Institut moditsiviskoy klimatologii i klimatoterapii Imeni
I.M.Sechenova v Yalte (for Petrov). 2. Institut tuberkuleza
AM SSSR (for Pokhitonova, Rollye).
(TUBERCUIA)SlS) (CLIMATOLOGY, MICAL)

ROL'U,, Z-Yu., prof.; KOVALMIKO, D.G., doktor ned.nalik; KUTSENOK, B.S., dotsent
Use off exercise therapy and "antibacteriological-fiinctional
therkpy in osteourticular tuberculosis. Ortop.,travn. i
protez. 18 no.5:96-99 S-0 '57. (PIM 12:9)
-(JOI1?2S--TUBFACTJLOSIS) (MORCISE THERAPY)

POLITIC, Z.1yu., prof.
Cure of osteoarticular tuberculosis [with summary in French]. Probl.-
tub* 37 no.1:12-22 '59-~ (MrRA 12:2)
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BUGOSLAVSKAYA, T.V.J. dotsent; ROM-BUGOSLAVSKAYA, Ye.S.
Diagnostic value of thrombophlebitis as a sjoptom of cancer.
Sov.med. 25. 25 no.5;55-59 My 162. (MIPA 15:8)
1. Iz kafedry terapil No.2 (zav. - dotuent T.V.Bugoslavakaya)
Ukrainskogo instituta usovershenstvovaniya vrachey i terapevtiche-
skogo otdelenlya 32-Y bolInItsy medlko-sanitarnoy chasti Kha-"Ikov-
skogo taktornogo zavoda (glavnyy vrach -'kand.med.nauk I.S.Yefimov).
(THROMBOPHLEBITIS) (CANCER)

L h6018-66 E"4T(1)/EM(k)-2./T/-PW-1(k) TJF-(c) WG /G D
ACC NR: AT6015137 SOURCE; COD.E: UR/0000/66/000/000/0144/0149
AUTHOR: Kramarenko, N. L. Meshcheryakov, A. V.; Naboykin, Yu. V.;
Ratner, A. M. ; Rom-Krichevskaya, I. A.
ORG: Physico- Technical Institute of Low Temperatures, AN UkrSSR (Fiziko-
tekhnicheskiy institut nizkikh temperatur AN UkrSSR)
TITLE; Investigation of losses and loss -associated characteristics of laser
0D
radiation
SOURCE: Respublikanskiy seminar po kvantovoy elektronike. Kvantovaya
elektronika (Quantum electronics); trudy seminara. Kiev, Naukova durnka, 1915 6,
144-149
TOPIC. TAGS: solid state laser, laser R and D 44 5PR Roq D log r,~6'j
ABSTRACT: A method for experimental determination of the radiation loss in a
solid-statc-laaer resonator is suggested. A 4-level system is considered. The
loss is determined, a plot of output energy vs. mirror trans mis sivity is
constructed, and estimated and experimental results are compared for a Nd-glass:.__
Card 1/2

L 46018-66
ACC NR: AT015137
specimen. All quantities that enter a total-radiation los,s formula, exceptfor
dispersion loss, are directly measureable. Thus, the problem is reduced to
determining the dispersion loss. The latter is derived from the experimental data';
on the effect of the first-mirror transmissivity upon the threshold pumping energy,
The knowledge of the resonator radiation loss permits determining the optical
transmissivity of mirrors. Orig. art. has: 4 figures And 16 formulas.
,SUB, CODE:, 20 SUBM DATE: 12Feb66 ORIG R EF: 004 OTH REF. OOZ
Card 2/zfI'V

T, 01055-67 T,,T(1)/V-TC(k)-2/T/94P W IJP(c) T,1 n, /17, D
ACC NRt kf6-015136 SOURCE CODE: UR/0000/66/000/000/0137/0143
-1,
iAUTHOR: Ratner, A. M.; Rom-Krichevskaya, I. A.; Tiunov, Yu. A.
ORG: Physica-Technical Institute of Low Temperatures, AN UkrSSR Wiziko-
tekhnicheskiy institut nizkikh temperatur AN UkrSSR)
TITLE: Separate intensity peaks in laser r diation
SOURCE: Respublikanskiy seminar po kvantovoy elektronike. Kvantovaya elektronik
(Quantum electronics); trudy seminara. Kiev, Naukova dumka, 1966, 137-143
TOPIC TAGS: laser, laser theory, solid state laser
IARSTRACT: An integral equation describing high-intensity variations of laser
radiation is analyzed; the number of excited centers of luminescence increases with
pumping and decrease& due to de-excitation by luminous energy. With large reflector~-
misalignment angles, the light energy generated in a given peak does not last until thei
next peak; hence, each peak is formed separately. , The distinguishing features of the
separate peaks are: (1) They are sharper than conventional oscillations;. (2) They
have a longer period; (3) They are regular; (4) No, damping occurs with a continuous
Card 112

i, ()io55-67
ACC NRt AT6015136
pumping; (5) The time of generated radiation does not exceed the period; this time
,
determines the radiation spectruk. (6) Separate peaks are less polarized, and th.eir
polarization is independent of the peak number; (7) The generated energy is smaller
l in the case of separate peaks. A specimen of Nd glass 150-mm long and 14-mm
diameter was used in an experimental study of the separate peaks; the rnirror-axes
misalignment was 2 angular, minutes: oscillograms exhibit some changes in the
generation pattern. Orig. art. has: 2 figures and 16 formulas.
SUB GODE: ZO 5UIBM DATE; IZFeb66 ORIG REP: 001 OT14 REP: 002
r

C rd 2/2

M
I=

R014A(;IWV,i, LiI ke nd. me d. na uk
Clinical aspects of mixed tumors of the macillofecial region.
6tomatologila 36 no.6;48-53 11-D 15?. (MIRA 11:2)
1. lz kafedry propedevtiki khirurgicheskoy stomatologii (zav. - dotsent
G.A.Yesillyev) Moskovsko-go meditsinskogo stoma t olo-giche skogo
instituta (dir. - dotsent G.1f.Beletskly) i Moskovskogo gorodskogo
chelyustno-litsevogo gospitalya (--alvnyy vrach dotsent A.A.Kovner)
(MOUTH--TU14ORS)

ROMACIOVILt I.F., kand.med.nauk; aKSO11OVA, Ye.A.
Systemic diseases of.the salivary and lacrimal glands (Sjbgren'e
syndrome). Stonatologiia 38 no-3:13-16 MY-Je '59.
(MIRA 12:8)
1. Iz kafedry propedevtiki Ichirurgicheakoy stonatologii (zav.
dotsent G.A.Vasillyev), kafedry glaznykh bolezney (zav. - prof.
Z.A.Kaminulat'ra) Moskovskogo meditainakogo stomatolokichoskogo
instituta (dir. - dotsent G.11-Beletakiy) i KoskovskopQ che3~nistno-
litsevogo gospitalya (glavriyy vrach - dotsent A-A-Kovner).
(WLL1VjQVf GLA.03--DISMASHS) (IACRIML ORWIS-DISIMSMS)

im
RORACHM, I.F.; MRIYASINA, G.B.
Novocaine block treatment of some inflaEL-mtions of the mucous
membrane of the oral cavity. Stomatologiia 39 no.1:17-19 Ja-F 160.
WDU 14-11)
1. Iz kafedry propedevtiki khirurgichaskoy stomatologii (zav.
dotsent G.A.Vasillyev) Moskovskogo meditsinskogo stomatologicheskogo
instituta (dir. - dotsent G.N.Beletskiy), Moskovskogo chelyustno-
litsevogo gospitalya (glavnyy vrach - dotsent A.A.Kovner) i
polikliniki No.2 (zav. S.M.Krutovskikh).
(NOVOGAIDE") (14OUTH-DISEMES)
(I-ECOUS I-EMBIULNE)

1. F.

I - -- ~. I ~. I . ~ .

Ou ''.P,:) "I
US.3R
A Tzr~ J-H Fam, Animals.
The Swine.
AB") - JOUR. RZhBiol., Lo. 3s 1959, ~10. 120610
AUTHCR k-liomyakova,, A.; Romachuk# L,
T !T L-.-,' The Interspecies Crossing of k1g3a
ORIG. rUD. Kollchomoye proiz-vol 1,)58, No 2,, 30
AB5TRACT No a7b9tract.
CA.ID:

LATVIA Organic Chemistry. Synthetic Organic Chem- G
istry.
A,bs Jour: Ref Zhur-Khimiyaj, No 20, 1958, 67498.
Author Romadan I. A.P Lauberte L.,
-Inst fro-r-rvmr.-
Title Alkylation.of Naphthalene with Isobutyl and Isoamyl
Alcohols in the Presence of H3PO4- BF3 Catalyst.
Orig Pub: Latv. FSR Zinatnu Akad. vestis, 1957, No 12, 151-
154.
Abstract: Alkylation of naphthalene (I) with alcohols in the
presence of H3P04 3 catalybt (K) results in the
formation of ~6-aik'ylnaphtalenes (11) with 72-78%
yield and of I-4-dialkynaphthalenez (III) with 8-
Card 1/2

J3(';C),5-3j11OO
SOV/79-30-2-14/78
AUMOR1.1 - Noilludall, .1. A., RojuLdrin, Yu. P.
TITLE: Alkylation ot' Benzene With lk-,xyly Heptyl, and Octyl Alcohol's In
Presence of Boron Trifluoride
PEHLODICAL: Zhurnal obshchey khImii, 1960, Vol 30, Dir 2, pp 420-424 (USSR)
ABTMACT: This paper is a continuation of a series of articles on alkylation
of benzene with various alcohols (Romadan, 1. A., Grikit, E. Ya.,
Shuykin, N. I., Izvest. Akad. nauk SSSR, Otdel. khim. nauk, 1959;
Romadan, I. A., Pelcher, Yu. E., Zhur. obshchey khim., 28, Nr 1
(1959)). In this' work the authors studied allcylation of benzene with.
he,4yl, heptyl, octyl, and do4ecyl alcohols in presence of baron
trifluoride, under various conditions: at atmo:-Aieric and higher
PrCOSUI-es, with and without solvent and at various ratios of reactants.
Alkylation at atmospheric pressure gave rather low yields (57-68%)
of' alkylated benzenes (a mixture of mono- and dialkylbenzenes was
obtained in each case). Therefore, most of the experiments were
conducted at high (30 atm maximum) pressure (see loc. cit. for the

mf-thods). The alcohol, saturated with boron trifluori.
de (2ROH BF3)
Card 1/4

77863 SOV'79-30-2-141-t8
was mixed w ith benzene in an autoclaire and heated at 170-2000
for 3-4 hr. Results are shown in Table 2.

E Le-
i C,t fl 130 H 1:1 1 F).5 (o) 80 26 613 62 M -
C,.,IIj:,OII 1.5: 1 Ilis(o). 90 24 76 38 58 4
C611,1011 1:2 158(o) 120 83 58 88 12 -
(~71115() i I t:I 11MO) SO 28 6 t 61 37 2
C711 11011 1:2 15510) 120 81 57 86 14 -
C,11'3011
, t:2 171)(30), 165 42 74 86 12 2

3011
Goli;
l
1 1 1 (CCIO
t 71) (125)
420
1 t
90
88
12
-
cGif'.1ml
(.'7111,01 1 I: 2
1 :1 1 (CC14) 2W (35)
170f 110) 200
120 122
15 16
88 72
go 24
to 4
-
'('7111101, t:2 175(30) 200 136 6 t 8 t t 6 3
CS 11, ; 0 11 1:1 170 125) 160 99 62 42 58 -
c,11,011 t: 1 21)0 (30) 160 93 64 40 48 12
Table -'Yie-l-d.s--.-o-f-alkylbenzenes unde r various reaction conditions.
W Starting alcohol; (2) molar ratios alcohol: benzene; (3) boilinc,
p oint (pressure in mm); (4) quantity o f benzene used in reaction (ml.);'

,
(5) iantity of recoltered benzene (ml) ; (6) yiel d of -alkylb-enzenes

) content of alkylbenzenf-s in ob
(~,) ~
7
tained product (a)
MoTio-, (b) di-, (C) poly-

Alklylation of Benzene Wj th Hexyl, jfj~ptyl, W863
and Octyl Alcoholo in Presence of
"OOV/79--jO-2-14/78
Boron Trit'luoride
The use of carbon tetrachloride Lis solverh (ratio 2ROIPBF~
benzene : CCD, = 1 : 1 : 1) alowed a raising of maximum pressure
to 125 atill (at 1700) with a consequent increase in total yield of
alkylbenzenes (and an increase in the yield of monoalkylbenzenes).
Reaction of dodecyl alcohol with benzene was performed over
BF 3 'H3POI,; the mixture (alcohol : benzene : catalyst
1.25 : 1 : 0-5) was heated at 1700 and 25-28 atm. for 3 hr.
Repeated fr actionatton.yielded only unsaturated compounds. 'Table 1
shows analytical results of the obtained alkylbenzenes. There are.
2 tables; and 5 Soviet references.
ASSOCIATION: Riga Polytechnical Institute (Rizhskiy politekhnicheskiy institut)
SUBMITTED: January 24, 1959
Uard 3/4

AL?ylat.Lon of' Btiri,.~iiiw With flexyl, Reptyl, 77863
and Octyl Alcohols In Presence o-f' SOV/79-3NO-2-14 /78
20 20
Table 1. W Hydrocarbon; (2) boiling point; n D d 1, (3) found
N); (4) calculated M; (5) molecular weight; (6) found; (7)
Calculated; (8) sec-liexylbenzerie; (9) ii-dihexylbenzene; (10)
trihexylbenzene; (11) sec-lieptylbenzene; (12) ii-diheptylberizene;
(13) sec-octylbenzene; (14) dioctylbenzene; (1 5) dodecylberizene;
(10 didodecylbenzene.
n
c 11 c (7)1
9* 2M-2030 1.4850 0.8982 8S.S2 11.19 88.88 1 IA2 164.7 162
~_:-,5-260 1.47:13 0.88.55 87.74 f 2.24 87.80 12.20 211 216
294-296 1.4465 0.8589 87.0t 12.62 87.27 12.73 - -
226-227 I.48M 0.8920 M. G 7 t 1.45 88.63 11.37 173.2 176
/~2 264-265 1.41M 0.87M 87.47 12.54 87.51 12.49 263 276
248-250 1.4812 0.8901 88.30 11.67 8,4.39 11.61 1 U 1.7 i9l
28.5 .9 ~,),:,726~ 87.21 12.73 87.34 12.66
719 - - - -
23:1 2T!, 1 If., q
266-270 1.4502 0.8761
Qird 4/4 ccl
use as solvent

3/076/60/034/04/31/042
BO1O/B0Oq
AUTHORS: Y!gorov Yu. Pq: Romadan~ Ghly&pochnikov, Vo A. 9
Shuykin, P. X. kX1WWVUWj
TITLE; Investigation of the Structure of the Radicals of Substances
Obtained by Alkylation of Aromatic Hydrocarbons by Means of.
Alcohols in the Presence of,Boroa Trifluoride
PERIODICAL: Zhurnal fisicheskoy khimiiq 1960, Vol- 349 No.,4, PP- 888 893
TEXT: In a number of earlier papers (Refs. 1-6) 1. A. Ronadam. described amethod
for the alkylation of aromatic hydrocarbons with molecular alcohol compounds of
boron trifluoride at 165-1700 in an &4toclavo, or at & pressure of I atmosphere.
The results obtained do not agree with those given by other authoret, and itis
P1 assumed that a different reaction mechanism pr*vailo,und*r such conditions (with-
ral out activator and at 165-1700), For instance, in the alkylation of naphthalene -
.tit with n-butyl.-n-amyl, and n-propyl alcohol alkyl naphthalenes Iwith,nornal radicals
a.re were obtained. The structure of n-butylnaphthalons was confirmed spectroscopically
(Bef. 13) and by a special methoa-or-aeuTerium. exe &age at the fisiko-khiaicheakiy
,inatitut im. L. Ta. Karpova (Physicochomical Inatitute.ia*ni L. Yad Karpov) in the
,4rdl Card 1/2,

AUTHOR: -Romadan, 1~ A.
TIME:
PERIODICAL:
1.13STRACT;
Card 1/3
SOV/79-29-1-23/74
Alkylation of Naphthalene by the Molecular Compound of
Ethyl Alcohol With Boron F.Luoride Under Pressure (Alkilirovinive
nafte.lina raolekulyarnym soyedineniyem. etilovogo spirte, s
ftoristym borom pod davleniyem)
Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, pp 102-102 (USSR)
In previous papers the author proved (Refs 1,2) that naphtha-,
lene is comparatively easily alkylated with the molecular
compounds ofth6.~,alcohols with boron fluoride under ordinary
pressure and a~ 165-1700. Under these conditions*, mixtures
f rom- cie - and /3 - alkyl naphthalenes and dialkyl naphtholenes
0 c
are obtained, the portion of Of -isomers being 45-5 In
further papers (Refs 30) it was found that, if this
alkylatioft reaction of naphthalene takes place at the same
temperature but at 20-30 atmospheres absolute pressure, the
main product among the monoalkyl naphthalenes is formed by
the /6-isomers. On the alkylation of naphthalene with the
molecular compound of the isoamyl alcoh o1 with BPI under
3
identical conditions, for instance, mainly the

Alkylntion of Naphthalene by the Molecul,-r SOV/79-29-1-23/74
Compound of Ethyl Alcohol With Boron Fluoride Under Pressure
Card 2/3
13 -tertiary amyl naphthalene resulted (Ref 3). Similar results
could be seen in the reactions with other alcohols as well. As
,is known, the alkylation reaction with ethyl alcohol proceeds
in a more complicated way than with other alcohols. The author,
however, succeeded in carrying out the Plkylation reaction
of naphthalene with ethyl alcohol and in obtpining a mixture
from oc- and /3-ethyl naphthalenes in which.the percent .age of
the 13 -isomer ans 85-90 ~fo. The monoethyl naphthalene yield
was 58-63 ~a, referred to the initial naphthalene. The alkylation
was performed in the steel autoclave. The reaction vras carried
out in two steps: The molecular compound ofethyl alcohol with
.BF previously obtained was put into the auto.clave together
3
with naphthalene (2.5-3 mols ethyl alcohol per I mol naphtha-
lene). On a gradual temperature increase up to 1650 the
pressure increased to 25-27 atmospheres absolute pressure.
After cooling the content was poured into water, Pfter the
usual treatment (separation Pnd desiccntion-o'n calcium
chloride) on metallic sodium the product wps finally distilled

AUTHORS: Romaden, I. I., Polcher, Yu. S. SOV/79-29-1-24/74
TITLE: Alkylation of Benzene by Molecular Compounds of Alcohols,With
Boron Fluoride Under Pressure (Alkilirovaniye benzoln molekul-
yarnymi soyedineniyami spi-.-tov s ftoriatym borom pod
davleniyem)
PERIODICAL. Zhurnal obshchey khimii, 1959, Vol 29, Hr 1, pP 103-106 (USSR)
KBSTRACT: At present, monoalkyl benzenes (e.g. ethyl benzene, isopropyl
benzene, isobutyl benzene, and others) are frequently used for
the production of the valuable orgpnic raw product which is
necessary for the manufqcture of plastics and synthetic fibers.,
1.4-dialkyl benzenes are transformed on-oxidation into tere-
phthalic acid which is the initir-1 product for the manufacture:
of the synthetic fiber "Terilen". The important role of alkyl-.
benzenes in industries induced the authors to devise a new
alkylation method for benzene with alcohols. They performed the
alkylation reactions of benzene with the molecular compounds of
ethyl, n-7propyl, isopropyl, n-butyl, isobutyl,- and iso,-,myl
0
alcohol with BF 3 at 200-230 and 75-120 atmosnheres nbsolute
Cr-rd 1P pressure. Mixtures of mono- and dialkyl benzenes were thus

Alkylation of Benzene by Molecular Compounds of SOV/79-29-1-21/74
t1cohols With Boron Fluoride Under Pressure
obtained in yields of 60-90 '4, referred to the initial benzene
Card 2/3
On the alkylation of benzene with ethyl alcohol, a mixture of
mono- nn4 diethyl benzene in a yield of 60-64 % was thus ob-
tained, wherein ethyl benzene was predominant (65-70 ~'fl of the
mixture). The remaining part of the mixture consisted of a
mixture of diethyl benzenes with a small amourt of triethyl
benzenes. On the n1kylation of benzene with n-propyl and iso-
propyl alcohol only one product, the isopro-pyl benzene, was
obtained. If'n-butyl and isobutyl alcohol were used insteRd of
the propyl alcohols~'oniy one product resulted, nimely isobutyl
benzene. Isopropyl and isobutyl benzene ivere obtained in good.
yields, the quantity of the alcohol used playing a certain role.,
The structure of the products obtained was substantiated by
~analyses and confirmed by the.infrared-spectrum analysis. Tne
constnnt3 of the alkyl benzenes formed are given in thetable
and compared with data to be found in publicntions. There-nre
1 table and 10 references, 5 of which are Soviet.

50)
AUTHORS: Romadan, I. A., Orrikit, E. Ya., SOV/62-59-4-22/42

TITLE: Alkylation of Toluene by Molecular Compounds of Alcohols.With
Boron Fluoride Under Pressure (Alkilirovaniye toluold molekul-
yarnymi soyedineniyami spirtov s 'Lt.oristym borom pod
davleniyem)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskilch nauk,
1959, Nr 4, pp 705-709 (USSR)
ABSTRACT- In the present paper toluene was alkylated in the aut,oclave
'with n-propyl, isopropyl, n-butyl, isobutyl, isoamyl, and
n-hexyl alcohol in the presence of BF at 1,70-1800 and under
40-60 atmospheres., As a result 1,A-dialkyl- and'1,2,4-trialkyl
benzenes were obtained in a 62-87 j~',yield of initial toluene~
1-methyl-4-alkyl benzenes amounted to 53- ~,b
78 " of the total
quantity of the alkyl-benzenes obtained$ whereas the yield in
1-methyl-2,4-dialkyl benzenes was not more than `-17 The,
nonoalkyl toluenes precipitated from the catalysates had con-
stants similar to the data for synthetic alkyl toluenes. Upon

Card 1/3 alkylation of toluene with n-propyl alcoho12

Alkylation of Toluene by Y.olecular Compounds of 3O1r/62-~:.9-,*.-22 '42
Alcohols 'i'lith Boron Fluoride Under Pressure
1-methyl-4-isopropyl benzene ras obtained-,~ meltinG point, 177.4',
n20 1-4915t d 20 0.8575 au compared to meltin- point
D 4 .770,
n20 1.4909, d 20, 0.8573 (Ref Upon alkylation with isoIpropyl
D 4
alcohol, 1-metbyl-i~-isopropyl benzene was obtained: i-.ieltin~
point 1770, n 20 1-4911, d20 0.8573 as compared to melting point
20 D 20 4
177.250, n 1.4909, d 0-0573 (Ref 7). The constants of,other
D 4
hydrocarbons obtained are shown in table 1. The experimental:
data show that the yield in alkyl.toluenes depends on the
molar ratio of the initial reaffents. At a molar ratio of
toluene : alcohol.= 1 : I the yield in alkyl toluenes was
about 20,25 c1lo' lower than at a ratio of 1 : 2 (Table 2). In
addition to the mentioned monoalkyl toluenes, disubstituted
alkyl toluenes were obtained, as, e.g. 1-methyl-2,4-diiso-
propyl-p 2,4-di-n-butyl; and 1-methyl-2,4-di-n-propyl-,
1-maethyl-, 1-methyl-2,4-diisobutyl-, and 1--.ieth-_.-l-2,4-diiso-
Card 2/3 amylbenzenes

t 4
Alkyla Lon of Toluene by Molecular Compounds of SOV/62-59-4-22/42
Alcohols With Boron Fluoride Under Pressure
r,hich were not yet described (Table 1). There are 2 tables
and 12 references, 7 of which are Soviet.
ASSOCIATION: Latviyskiy gosudarstvennyy universitet (Latviya State Uni-
versity). Institut organicheskoy khimii im. N. D. Zelinskogo
Akademii nauk SSSR (Institute of Organic Chemistry imeni
It. D. Zelinskiy of the Academy of Sciences, USSR)
SUBMITTED: July 9, 1957
Card 3/3

YEGOROV, Yu.P.; ROMADAN, I.A.,-. SHLYAPOCHNIKOV, V.A.; SHUYKIN, N.I. (Mopcow)

7- -7~--
Wo -

USSR/Organic Chemistry Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhurx Khimiya, No 1, 1957, 841
Author: d Rendel, T. 1.
Institution: None
Title: Alkjlation of Diphenyl with Alcohols in the Presence of BF3
Original
Periodical: Zh. obshch. khJ 11, 1956,, Vol 26, No 1, 202-208
Abstract: With a view to the production of heat-transfer agents, diphenyl has
been alkylated with C2H_0H MY C H OH (II) iso-C 3~7 OH (111),
I OH (IV) iso-C4H OP (V), iso_~ 5KIOH (V'!'),, and C6H OH (V1I)
C4f e 3' t alkyN
in.& presInce of B~ Mix urea bf mono- and di iphenyls
were obtained (Usually in equa '1 amounts). Products of highest purity
and in the best yields were achieved when normal alcohols were usel.
The authors~are of the opinion that alkylation proceeds by the forma-
tion of the complex ROBBF 3; Procedure: to 40 gms of cold V! satu-
rated with BF3 add 25 sms f diphenyl and heat with mixing to 165-1700
for 1.5- hours (in general, 0.5-1.5 hours for iso-alcohols and 3 ho,,j-rs
Card 1/2

USSR/Organic Chemistry - Synthetic Organic Chemistry, 9-2
Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 841
Abstract: for nor-mal-alcohola), dilute with water, separate, and steam distill
the oily layer. A mixture of mono-and diisoamyl diphenyl is obtained
in which the disubstituted compound predominates slightly; over-pall
yield, 98%'. Wracteriatics of isoamyldiphenyl: bp 298-3020, freezIng
point -550, n 1.5075 d20 0.8876,rtr V 12.91642y. DiisoamyldiphenY14
breezing ploi~t -530 D20 1.5102, d 0.8976.- The alky,
bp 310-3130) J, D 4
lated derivatives of I-V and VII are Q'Otained by a aimila~(pethod; the
yields (percent), bp in 0 Clm~m, freezing.points in 0 C ' nD , and d~
for the mono- and di- derivatives are given in that order: 1, 85.3,
mono: 281-282 Jq -51, 1.5681, 0-9793; V: 304-3 -50, 615, 0,95470
11, 100, mono: 299-300Y -48, 1.5349, 0.9343;vt 27-a411495 32-201
di: 328-3301 -41 1 5340, 0.9297; 111, 74, mono: 295-2-~, -55,
k 5, -48, 1.548o, o.8949; Iv,
1.5475, 0.9123, 18 *94; di: 315-31(
100, mono: 308Z10, -70, 1.5259, o.8950; di: 324-326 -66, 1.5248
0.8939; V, 88, mono: 282-286, -51, 1.5295, 0.9070, 126 16.89, 15
30-96; di: 306-308, -46, 1.5142, 0.8952. When 80 gms of VII are
saturated with 27.1 gms BF3 and reacted with 60 gms diphenyl (3 hours
at 160-1700) quantitative conversion to a mixture of monobexy1diphenyl,
(bp 313-315, ~M) and dihexyldiphenyl (bP 330-331) is, observed.,
Card 2/2

AUTHORS:
I. A. Ber/,a, S. E.
Homadan
,TITLE:, Alkylati on of Diphenyl With Alcohol in thc Precence 01- a W if PO
L
K
l
a4;~
Catal.-;st (Alhilirovani-ye difenila spirtarai v prisutstvii ka
tora BP H PO
3* 3~ 4
,PERIODICAL: Zjhurnal Obshchey Khimii, 1950, Vol. 28, Mr 2, PP- 413 -417 (USSR)
ABSTRACT: In the preaez-.t --iork the authors investigated the reactiono bet-ween,
dinhonyl and isoamyl-, isobutyl-, isopropyl, n.-pro.)yl- and n.-bu-
tyl-alcobols in the pre.sence of BF *11 PO .They viant~id to determine
Llie conty-ollin,.," action of an acid gltEyit such as BF At the same
time they wanted to delterraine the pos:~ibility of an -i~ordcdzation
of the secondary into the tertiary radical, ahen a stronE electro-
phile rea.-ent i3 present. They again tried to confirm theassuription
an the mechanism of the alkylation with alcohols --ccordin,- to
structure. Kenna and Sova (reference 11), Pres and Lund (reference
12) c.:,presscd their opinions on the ailcylation meclianisi with F-1-
cohols in the presence of BF Later ocher authors (refer(inces 13
*
the reaction mechanis--1. But concrete
and 14) Llso tried to explain
asir,!.1--tions on the course of the reaction accordin- to the struc-
L>
tLre of the alcohol were apparentl'y not emressed. In the obser-
Card 1/4 V-'.tion of the al!':ylation reaction of naphthalene (references 15

701-2-2(VG'1
r
11 7- y 1 a t i o n c fDin'=~Yi With Alco'nol in U,.e Pre--ence o--" --- BF:ZVH PO Catn-lyot
3 4
and16) and diphenyl (reference 10) -.vith normal and with isoalco"hols
in the presence of BF- it was possible to establish somm assurl,07-,
tions on the alklylati8n nechariis:.l vihichare based an the follo-vin,
facts: 1) 'Jith noruial.alcohols al'-41naphthalenes an3diphenyls only
form with normal radicals. 2) The products of olepline pol.yraeriza-
tion arc absent in the alkylation with normal alcchols. 3) With
no,rmal alcohols the reaction taketj place 3,!j tivies nlowlier Vlan
In the alkylation with isobutyl- and iooaFlyl-
alcohols, ,.ilylnaphtlicilene-cliplitiiyls con"a inirE tertiary radicals
form. 5.) In the reaction with alcohols vithan isostructure dimers
and trimers of the olephines are always contained in the rli-~:ture
of products.. 6) With isoalcohols the reaction is.term-inoted within
1 - 2 !,ours. Those observations i:inke assum2 that with norma-1
...lcohols*a condL-noation reaction Lakes plaice, whereas 'Llith alcohols
01 all Isootructure urhich split off viater more easily, the alkyla-
Lion rC-UCtiOn -JaC~~ -,r4,'h intt3r,.i,~,diate olephines. In the re-*
uIction with t-~u c---~talyst BF ;H FO, equal facts a-~ in the presen.ce
oa.Ionly BIP are observed: wi h 3no~--Ml alcohols p--a,.-al',zjldi-phenyls
Jer,,~ obc~,iLd and vith isop:copyl alco',Iol, -isopropyllip%an-1.
With iso'jutyl- :,n,! i~~owayl-alcohols p-t-ortiary-butyl- and P-'Certi-
crystalline substances forned. Beside
,Card 2/4 the uonoal1zyldip-ienylzi,t*ze :authors obt.,ined dialky1diphonyla vlrith

7*:'-2-2t
Allcylation of Di-rhen-1 Tl-Lh Alcclol in th- P"o-ence of a W HT PO C'-1t:-J"st
3* 3
radicals in t*,p'---'o:3ition. T'IiZir yield -Ms not exct-ed 3
Pol.~-..iers of isobutylene and i2oamv-lene were groduced .-rd investi~;at'-
ed. Some cilarac 'Leriu tics of ~-.1ky1di?henyls wo ~;iveii in the table.,
Conclusions: 1) It is assumed th,.-A on hau-;TTog of dilhanyl with
nomal alcohols a condensation reaction ;MRM plice.-...-Pierefore only
Subjtance3 -aith nor!.ial radicals are productyl. 2) With alcohols
of an isostmeture the --iain reaction is d.i-*icted to th-, flkylation
U
With interm2diate clei~iinas as a conseqnence of ~,hich all:,-,lnaph-
thalencs and ..tlkyldiphenyls containirg ~i~;Rry r0ldic.,ls for:a.
3) In the allKylation of diphen.,71 with alnabAts in the presmice of
BF If-PO 3 mol alcohol on 1 mol of b-'gV"'1'KV-'Aon are required. But
in 3.th3 Ahzylation with -molecular alcohol iompounds 'mith 13F 1,5
mol are suf "icient. 4) in the alkylation of aliphenyl with ~Ioleclz-
lar comimunds the yield of alkyldiphenyl mmiolklits to so - 96 2-'.
In a reaction with mixed catalyst th-- yield, however, does not ex-
ceed 65 co, althouah the di..,ration of heatin, Lslybout 2 times longer.
There are I table, --,.nd 17 references, 7 of veldich are Slavic.
Card 3/4

504) SOV/153-2-3-13/29
AUTHORS: Romadan, 1. A., Pelcher, Yu. E.
TITLE: The Production of,Simple Ethers From the Molecular Compounds
of the Alcohols With Boron Trifluoride
PERIODICALt Izvest iya vysahikh uchobnykh zavedeniy. Khimiya i khimicheskays.
tekhnologiya, 1959, Tol 2, Nr 3, py 381-w383 (USSR)
ABSTRACTs The authors investigated the formation of simple ethers from
the ethanol-, propanol-, butanol-, and isoamyl alcohol in the
presence of BF as catalyst under different conditions. So papers
3
have as yet been Published on this suojra-,t, (,-ily the alkylation'
of phenols in the presence of BF3 has been dGaIt with. Zavg6rod-
nyy (Refs 3-5) is mentioned in this connection. The alcohols
were dried over calcium oxide,and then distilled. The dry alco-
hole were saturated in a special glass apparatus with boron
trifluoride with the flask being cobled with ice.- normal salt.
The molecular compounds formed were heated to the necessary
temperaturewithout special purificationin a~steelautoclave
during 30-120 minut'es, After colling the'reaction mixture was
Card 1/3 washed with a 10 % soda solution and.subsequently washed with

The Production of Simple Ethers From the Molecular SOV/153-2-3-1
3/29

Compounds of 1
,
the Alcohols With Boron Trifluoride
water and dried over potassium carbonate. Then the formed
ethers were isolated by fractional distillation. The maximum
yields (60 - 87%) are obtained when the reaction is carried out
at a molar ratio alcohol: BF' 1 : 0.25, at a temperature of
3
200 - 2250, and under a pressure of 50 - 70 at. By this.method
also mixed ethers may be produced. Thus a mixture of n-propyi
isoamyl ether and diisoamyl ether is obtained in the-reaction
of isoamyl alcohol with the molecular compound of n-propanol
with BF It was, found that in the formation of the ethers from
3'
the molecular compounds of the alcohols with BF no isomerization
3
of the radicals.takes place. The results of the preparation of,
several ethers according to the method described under differ-~nt.
conditions (pressure,' temperature) are summarized in a table
There are 1 table and 14 references, 7 of which are.Soviet.
ASSOCIATION: Latviys kiy gosudarstvennyy universitet Kafedra organicheskoy
khimii (Latvian State University, Chair of Organic Chemistry)
Card 2/3

PWJ I Welt W1,01TATION WV/=6

RIC.. Univeraltate
't.t. 4 V-1 14,

iski, t. 14, Ithi.1oh.Aly, f.kul (ScIvAttfic Not
UP
clamad try faculty, 4) RIC., 1957. 251 V. W e.plaa printd.
at*. (TILI. paCS)l i.r. ly.vin'ab. Professor, Doctor of Chi.1str7l L.K. 1,4pin' ,
Newsber of the A~ bdamy, of' S~i.m.s Lt,17.ksy. Wa, Pmf ... or, Doot.r of
Chemistry, 0.7m. Vamag, Prof .... r, Doctor of Ch-latrys T-~h. Lt., A. F,t.rson.
This book is Intended for Inorganic chassists and scientists I. it* ceraaic.
PaRPMRs
InAw r1om
t
Us book contains 22 articles an orplo ch-teal qnth,sL, ..I anal"Is

'
4
sicwhmdc&l properties " cowpa.1tions of ceramic
and tbo o
7
q
r r. r m .
3
mlerials. Ito personallties are m.ationed. TIC~res, tables. :
wemp=z the article@.

Tb. Va. or 5.11
.'
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2.
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3. am
-
.17
Alminum Oxide tty~.t.
4. ALJOI I R lissists=e of the B~dary Lay-or, M*ctrod. P*temt-sl,
'
GM;l= of Alwsictum In Alwd- Sulfate Sol.tiou 25
and -h:
Upin as a Rome rcr,Q~aalltstivw Det4reination of
~~;m C=pc=ds 35
6a Tanag, G.Te., acl A I ir-n Th. Intorectloa of
'
"..
ith Mkw

Ctlthe Prdictel )Wchni- of the Alk7latt- of ls;'b
7.

49
th A]tohol. Using . Uj Catalyst
so, ~,
a. 'Ah%,FmY- Z. KlnIL7 -1 G. Vill.ro. study or Usnirdcc "d end
M. -
--
63
D*ri,." Ives_
9. 'Grinsht0n, T-, and Tho Concentration of Phytot"Ins of
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Ad Acid B
1
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9Q
It. liftks, :. Pmprtleg of ~rypj,.l Cl.y, or the Lst,jan =
12-
PmP-rtil- of Orpr- Calcirt,d at L~ T-p-tur.. 121
Th- Use of LigmphosphoKrp r.r tho P-.., tion
or Undlog 155
N' 14. 'fraydauNI'd, 9. Zh. The Production of Camsti. D~loalt. 161

of
~:rl ~k
es for S-r~,tunl c
16. z. Zh.. and -be Po..Ibility of
aLv for its of BI.11.g r~bat~.-
17. YZY*At In-I&. R4t&rd..-s of th4 satttng period of Gr,-n
at Lov Trp..-.tw..
19. rh* tutor-etlon of a ftr~lajy iiefracti-.7 With a
71wrins-contalminc Glass utch 195
19. 'Fr*yd..f*l'd, E. n-, 410 PhjT.tr.ch-!z.j Pmp--j,3
of Co"Po"t'ams of the 4'.- C'0-B-O---iQ2 201
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211
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;
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of "NY pieltinfFil.", Glass.
225
ATAIIAHM Library of C,ng~,.
card 411.

S/079/60/030/007/009/020
B001/B063
AUTHORS: Romadan, I. A., Stipniyek, G. T.
TITLE: Alkylation of Phenol by Means of Molecular.Compounds From
Alcohols and Boron Fluoride
PEPIODICALs Zhurnal obshchey khimii, 1960, Vol- 30, No- 7, pp. 2193-2196
TEXT: Considering the results of many-previous investigations on the
synthesis of alkyl phenolsiand alkyl-phenyl ethersl(Refs. 1-11) the
authors have found already earlier that naphthalene, diphenyl, benzene,
and toluene can be easily alkylated with molecular compounds formed from
alcohols and boron fluoride (Refs. 12-17). The present paper describes the
alkylation of phenol with ethyl-, propyl-, n-butyl, isobutyl-, and iso-
amyl alcohols in the presence of boron fluoride, at ordinary and
elevated pressures, with and without solventsp and at different tempera-
tures. The yields and-the ratios between alkyl.phenols and alkyl-phenyl
ethers were found to depend on the temperature and the solvents used.
Alkylation of phenol with the above molecular compounds led to almost
pure p-alkyl. phdnols (yield of 10-80yo as referred to phenol).- A mixture
Card 1/2

Alkylation of Phenol by Means of Molecular S/079/60/030/007/009/020
Compounds From Alcohols and Boron Fluoride BOOI/BO63
of alkyl phenols and alkyl-phenyl ethers in the ratio 86-85 ; 20-25 is
formed under pressure.The latter can be easily isomerized into p-alkyl
phenols already during distillation. This isomerization proceeds even
more easily by heating in a CCl 4 solution to 130--1400C at 12-15 atm
(Table 1 and Fig.). These experiments showed that the phenol partly
resinified when it was heated in an autoclave to 160-1700C. In order to
determine the optimum temperature at which the above molecular compounds
decompose and alkylation takes place simultaneously, temperature:was
measured every five minutes (by means of a thermocouple and a potentio-
meter). It was found that each alcohol had a specific maximum temperature
at which an intense exothermic decomposition occurred. lecomposition and
alkylation take place within a short time (Fig.). The products obtained
and their physical properties are listed in Table 2. There are 1 figure,
2 tables, and 22 references: 18 Soviet, 2 US, and 2 German.
ASSOCIATION: Rizhskiy politekhnicheskiy institut (Riga Polytechnic
Institute)
SUBMITTED: July 6, 1959
Card 2/2

M,xi
ROMADAN. I.A.; SHUYKIN, N.I.; YEGOROV, Yu.P.
Determination on purity of ~ -and 0-n butylnaphthalones by
#-.h. mof-AinA ^f iiltrnvinlAt unnt,4rnsatn-nv_ Tvv-' AN sssR- n*A ichim-