SCIENTIFIC ABSTRACT SULTANOV, M.YU. - SULTANOV, S.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001653910014-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 13, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

00)
2126/2146900/002/001/
AUTHORS: Sultanov, H. Yu.,-BelenIkiyo go So
TITLE: Oxidation of CO and high-degre* oxidation.of *-keptisme o& a.
copper-chromium oiido catalyst'2CUO*CZ.0
F2,J0DICAL: Izvestiya vyeshikh uchabnykh sayodeMy. left'.1 Pai 24*
1963, 50 -.55;~
TEXT: Detailed tests on the abovt reaotions.were o4mied mt vi 4% a fter
to decontaminating exhaust and recovej~y oses.. The '04tal"t A
decomposition of praoipitated copper and chrouium hydroxides ILt I me
heated for 2 hra and broken iuto pisoas of 3 - 3#5 alit
-1
of 52000 hr 85 % CO was ~oxldised at 28.00Z and 80.~.a_40vtssw. at
The size of the pellets di d not influence the aotjv&tI6n,.*a9vV~. SO
of the reaction with CO ahd n-heptane was of thi fi with
0 is V.Order Wift
oxygen zero. The kinetics of CO oxidation in concentr ,&$low or 0.1,684
can be expressed by a simple equation. For-thekinstic ,a -of WI&b4*4r4*
oxidation of n-heptane Ahis equation applies only Ar the tat a', ee~tft-
I actiou Velocity. Iola-
tion is constant, as its increase reduces-the r*
Card 1/2

3/1.52/6vooo/002/09t/
Oxidation of CO and high-degree oxidation ... B126/Ri"
with 2 ~0" vapour in the blend showed that,reaction was de'f*rred abmt i
times. The same decrease in the oxidation'velooity of CO and n_kopt~ vas
also observed after 620 hrs!of work. However the initial oxidation degree-
can be regained by increasifiR the temperature by.200C. The" are 4 fiSbres
and 3 tables.
ASSOCIATION: Azerbaydzhanakiy inatitut nefti,i-Ahinii in. M. Aslzbekm
(Azerbaydzban~Institute of Petroleum and ChenisU7 Is"I
M. Azizbekov)
SUBAITTED: July 17, 1962

hLLEN ' K LY
i','f cc, of cc~~Cxaiticn c~n the proparties of copper-chrorium
oxide catalysts !n 1 the oxidat..'an of carbar. moncxi3ee Izve VS.
wur., neft' 4- gaz J no.9.63-69 162. (HIPA 17-5)
1. Azerbnyjzhan3ki~ institut nefti i khimil in. M. Azizbekova.

7 t 7 0 n, t a b I P. n d
tlmrricic cavity. Azerb.
i1 165
zlnir. 42 52

SADYKH-ZADE., S.I.; SULTANOVIIN.T.
New method of synthe~lzing vLj -,d -chlorogityrones br the direct
chlorination of styr4ne. Azarb.khim.rlmr. no.5:33-36 160,
!I (MM WS)
(Styrene) (Chlorination)

SiTILTAINC) I I ri T.; Al-', VF"I'A , 1.1 A.-, KODZli A Y-E-V A, Sh - Ya . ; SA!Ti7KHZAD-,-, , S . 1 .
I
I ~ isobiitylene. Azerb. kh4M,
Anomalojis cn1c.-intil-Lon 0, - zhur.
165. 1 (MIRA J'B'-7)
1. In.3tltut tiofrekhimJc~,eiklkh prctsessov AN AzerSS11.

SULTANOV, N.T.; ALIYEVA, M.A.;
Chlorination of methyl
23-27 163.
$ADYKIIZADE,
i
i
!b,ethacylate.
1
i
S.I.
Azerb.khia.zhur. no.6s
(MIM 17: 3)

MAMEDOV, Shamkhal; SULTAIIOVj ~.T.; SADYKHZADE, S.I.; YdiODZHAYEVA, Sh.Ya.;
PISWIIAA~ZADtp
i
Alkylation ofok -chioromethylalkyl ethers with methallyl
chloride. Azerb. k~lm. zhur. no.1:81-V 164.
(MM 17:5)

L 44582-66 jjp(-
Wjj I i3m
L_A_L_
AkC NRa CE CODE: UR/0413/66/000/009/0077/0077
AF-60'5674 A ROURI
MrENNTOM Sadykh-zade, .. L. Sultaqov,.,H,_.T.; Aliyeva,_M. A
Akhmedova, G. G.; Radchenko, L-L; Reykh, B. N.; Krchmarek,:!'. V.
ORG: none
TITLE: Method for obtaining n hetig Class 39, No, 18129
roe
(announced by Ifistitute of P'"erochemica recesses, AN Azerbaydzhan
a rec
_5SR (Institut neftekhimicheskikh protsessov AN Azerbaydzhanskdy SSR
SOURCE: Izobretenlya, promys~lennyye obraztsy, tovarnyye znaki, no. 9,
1966, 77
TOPIC TAGS: synthetic rubber; butadiene styrene rubber, copolymeriza-
tion, polymerization Initiator
i
ADWRACT: An Author Certificalte has been issued for a method of obtain
Ing syntheti bber by water.~:.emulsion copolymerizationlof butadien
ru i
with_.~~rene in an alkaline medium In the presence of c6nventional
ini lators,!Iuffers, emulsifiers, and regulators. To improve.the
physical and mechanical propei-ties of the rubber, the copolymerization
Card 1/2 uDc: 678.762.2-

ACC NRj Ap6ol5o'74
is carried out In the presence of methyl a,p-dichloroisobutyrate as the
third comonomer for butadiene~ (Translationj (NT)
i -
SUB CODE: 1l/ suBm DATE: 04jun65/
2/2

AUTHORS:
TITLE:
? 0 0 66425
PERIODICAL:
ABSTRACT:
Card 1/2
Petrov, 1. D., Corresponding Xember BOT/20-128-6-30/63
AS USSR, Ydovin, Y. X., Sultanov, R.
Synthesis of a,0-iDi-(cy&no-alkyl) Tetraalky! Disiloxan*s
Doklady Akademii;nauk SSSR, 1959, Vol 128, Nr 6, pp 1204 - 1207
(USSR)
On the basis of analogy with organic dinitrilot, it is to be ex-
pected that also!organo-silicon compounds having 2 fragments fA]
in the molecule ~!('L Si(CH dn"' where a > 2) may be used as
initial raw matirials for the-production of aw-difunotional com-
pounds utilizabia for the synthesis of organo-silicon polymer&.
The present paper refers to the synthesis of a,c--dinitriles of
type CBJ (see Diagram). The addition of 2 moles of allyl cyanide
to HR2SiOsiR2H by means of 1. L. Speir's (Ref 7) catalyst (Ta-
ble 1, ExperimoInte Nr 5 and 61 was not successful. Ethyl-methyl
chlorosilane has already been jadded to cyanous olefines (Table 1,
Experiaents 30). The synthesis bf the desired a,v-dW%rile's was
possible by hydrolysis of the monochlorides obtained, Water was
used as a hydr6lyzing agent. By use of concentrated M and un-
der harder conditions, the corresponding a,CJ-acid was formed
Vr

29520
s/062/6 I /C),- )/0 11/007//012
B10 ~'/3147
7 0 D
A C R77-Z
V~ 3ultanov, R,, Sladkova, T, A.,Fr3ydl4n. L~ !~h-,
.nd ?etrov, A,
Addition of --:.lkbxy silane h~-drides to unsaturated nitriles
trld I-,-.'drLt4.nn of the co-eyano-alkyl-alkoxy silanes produced
?--'RICDICA7-: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 11, ia~61, 2007 - 2012
.-XT: The authors studied he addition of alkoxy silane hydrides to:
a) allyl cyanide; b) p-cyano-ethyl ether of allyl alcohol; and c)
it has been!found that the addition takEs place as follows;
RI IIIC'~ 31H ~ CH CHC~ X----)~R' (R0) Sic H CH X, RI being --CH -OC H,, or
~ ~2 2 - 2 2 2 4 2 39 2
--Cciiz; R being --C.11 . or -C a ; and X being -OCH CH CN, or --CN. The reaction
3 2 5 2 2
t --, "k L~ -,'-acp already at atmoipheric pressure, if a mixture of equimolar
of the reagents is boiled in the presence of Pt/C (20~ of Pt)
r -i solution of H PtCI in isopropyl alcohol. The yields in
2 1 6
-i5OJ,~o related to the components used, and up to
tion pro-,ucts were 40
Ca-d 1i

29520
5/062/61/000/011/007/012
Ad-lition of alkoxy silane hyarides. B103/B147
r~,Iated to r-3acted unsat rated nitrile. Yields can be increased and
U
time essential4 reduced in sealed glass ampullas. The main
anied in all cases by a disproportionation of the
-i- as accomp
n.!~, _,y r~i of the initial alkoxy silane hydrides: 2(C H 0).,SIH
2 5
4Si L(C2ifz~o)2 Sik2-hereby the dihydride formed continued to
f --CH groups were absent in the
,rlic!nute The frequ~encies o 3
lnfr-ir,,-~J absorption spectra~of the W-eyano-alkyl trichlorosilane, For V-is
the structures: Cl 9iCH CH CF CN and Cl SiCH CH CH OCH CH CN were
2 2 2 2 2 2 2 2
3
to these nitrile~ The 0-cyano-alkyl-trialkoxy silaries whLch
Pro-iic-d by addition oA~ both trialkoxy silane hydride and HSiCI, to
identicz~l properties. Thus, it is concluded
tha', a~, -; i t. ior. o f be t*" (SO) SiE and Cl Si-H to these nitriles proceeis
-,iav. ,, 4? , thaf the trialkoxy silyl group is placed at the
I "n e Cu 1 eThe interaction of CH (OC H ) SiH and unsaturated
3 2 5 2
S - P t ucts added to the double
s perharz3 in, a mixture of prod
T 1 r t t hl! boilirg rarf;es of these products. An
IM-

29520
s/062/61/000/011/007/01 2
A-1dition of alkoxy silane hy4rides... B103/B147
a !di tion to t~e triple bond L-C-=I~ which could be possibly expected (in
;inalo~-,-; to the data of Ref. II, R. Calas et al. Compt. rend. 252, 420
t'11,1~~,!)), did not occur, Add('itior- of (C2H50)3Siq to acrylonitrile was
.ei.ievoi~ ncithi!r at atmo3phiric ror at elevated pressure in the p6esence
Of _--nd other aubst~ances (in glass ampullas at 150 - 180 C);
acr~lnnitrile .vas pqlymerized and triethoxy silane disproportionated,
:?r trie ini-Jal substances remained unchanged. Theta-eyano-alkyl-triethoxy
silaric3 oro,~uced were hydral~e6 to the relevant primary amines in the
,)res-,n:e of Co or Ni skeletoln catalysts under pressure according to the
crevio.isly described methods (A. D. Petrov et al. Dokl. k1l SSSR, j2
1064 (19501); L~ Kh, FreydlirL et al. Izv. AN SSSR, Otd. khim. n. 10, 1878
I 'C "
I I et al.' E.Uthor's certificate, SSSR 1173C-63: Byull.
rc) ; 7 : 7dovin
SSR 23 (10160)) '~Table 2). It has been found that the
zat,,.11.ist tipe and the structure of the nitrile have a remarkable effect
:)r-- ~he yield Jr. .1-n primary amine. The reaction was more selective in
of Co cat_A~st3 thsti of Ni catalysts, The yield it, amine
on ai..'ration off_cyano-alkvl-triz-lkoxy :7il-ne than on reduction
Cf 0 n D t I'l U t hD Xi In It has b,~t~n that
h,-d-
rat 0-1 of to ti,,~ ruli-v .~nt
Card I/"

29520
S/062/61/000/011/()07/012
Ad-lition of alkoxy silane hydrides... B103/B147
~zrinary-.z,,w -diamines is possible (Table 3). The c4. W -dinitriles mentioned
.""r4! for-~.~,d as by-products o? etherification of ~.)-cyano-alkyl-trichloro-
1 1~ o Tlh-~re ar,~ A tablHol and 12 referLnces: 5 Soviet and 7 non-Soviet,
:,cost r,~c,_,nt refvrohces to Engli3h-languaee publications read a3
f 5: L, H. Somme!r et al. J. Amer. Chem. So'c. D
2764 (195A
V 3 Jex, J. "I'ah'on, US-Patent 2907784; Chem. Abstr, ~J, 4388
Ref. 111: B, 7. Aller~, J. Appl. Chem., 130 (1957).
is f i 'u t or,
I ~ar. cheakoy khimii im, N. D. ZelinskoEo Akademii
z.auk SSSR (Institute of OrEanic ChemistrL~ imeni N. D.
I i n 31- i.'~ a L- Acad~~my of Scienccs U'.~Sq)
1 f __D: 'T
Fr-j:er-tiE!o of crg-nosilicon nitriles and dinitriles,
L boilizni_ -,oint (7, (2) found; calculated,
n cf alkyl-c-ano ~~ilanes 'n the presence of

5-- 11 c, o
AUTHORS: Vdovin, V. M.,
Sultanov ' R.
Mi~fi-b~Zr~ ~S;SF
TITLE: Derivatives of
Si Atoms. The
pentane
PERIODICAL: Doklady Akadem
TEXT: rhe authors studied t
AlBr 3 on 1,1-dimethyl silico
bridge compound in which bot
to the Same silicon atom. Ex
assumption that, under the i
be more reactive than the :-'~
formation of a reactive radi
88571
S/020/61/136/001/019/037
B016/BO55
ushchevaya, K. S., Belikova, N. A.,
ate, A. F., and Petrov, A. D., Corresponding
ilanes With Hydrocarbon Bridges Between the
lymerization of 1,11-Dimethyl Silicocyclo-
nauk SSSR, 1961, Vol. 136, No. 1, pp. 96-99
effect of aluminum halides (AlCl 3 and
~clopentane. "hey regard the latter as a
ends of the organic radical -R- are attached
rimental results confirmed the authors
'luence of AIX 3' the ~-Si - (CH 2)4 bonds would
- CH3 bonds. As expected, this lead to
.1 -Si(CH3)2 CH2CH2CH2CH 2-' and in the presence
Ca=d 1/3

Derivatives of Silanes With E'drocarbon Bridges S70120/61/136/001/019/037
Between the Si Atoms '
. The Pol merization of B016/BO55
1,!-Dimethyl Silicocyclopentl
of AM 3 or AlBr 3 to a specif c polymerization reaction (A).-
(CH 3)2 Si(CH 2)4 Al2X6 [( CH 3)2 S1 (CH 2)41 *A1 2X6
(CH 3)2 Si(CH 2)4-j-Al 2X61 ) -[Si(CH3)2 CH 2 CH2CH2CH 21 n - + Al 2X6(X
This reaction is very rapid if the silane and the catalyst are heated for
a short time. The authors verified the structure of this product by
synthesizing it from corresponding fragments (B). Infrared spectroscopy
proved these two products to be identical. Differences between the spectra
of these two polymers and that of the monomer are explained by the spacial
position of the carbon chainsl(isomerism). The authors thank Yu. P.
Yegorov and Ye. D. Lubush for;performing the spectroscopic analyses.
Finally the authors discuss the polycondensation of 1,4-ditrimethyl
disilyl butane. The reaction product was a colorless, rubbery insoluble
polymer similar to the polymerization product obtained in reaction (A).
There are 1 figure and 6 Soviet references.
Card 2/3

885n
Derivatives of Silanes With Rydrocarbon Bridges S,/020/61/136/001/019/037
Between the Si Atoms. The Poiymerization of B016/BO55
-yelopentine
1,1-Dimethyl Silicoc I
ASSOCIATION: Institut organicheskoy khimii. im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni. N. D.
I
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: October 1, 1960
Card 3/3

S/020/61/158/004/011/023
D B103/'B203
AUTHORS: Vdovin, V. M., Sttlta~ovv R-; Lubuzh, Ye. D., and Petrov, A. D.,
Corresponding Member AS USSR
TITLE: Organosilioon compounds with hydrocarbon bridges between the
silicon atoms. Alkylation,of u.-cyano-alky! trimethyl silanes
by means of halogen methyl trimethyl silanes
PERIODICAL: Akademiya nauk SS SR. Dcklady, v. 138. no. 4, 1961, 831-834
TEXT: The authors studied the prcduction of bridge disilanea
(CH 3)3 31 -R -Si(CH 3)3 containing a cyano group in the hydrocarbon radical R.
Such disilanes may be used for:producing various polymers. These compounds
have so far been obtained with difficulty, The authors point out that the
cyano group bound to the P-carbon atom (with respect to Si) can be trans-
formed into various functional groups without separating the cyano-alkyl
raoical from the Si qtom. The reaction was conducted according to the
scheme (CH ) Si (CH ) CH CH [(CH ) SI(CH CH(Na)CN
3 3 2 n 2 ether 3 3 2)n
Card 1/5

1
0 W138/004/011/023
~O 2
10' IB203
Orgarosilicon compounds with hydrocarbon- B03
XCH2Si(CH ') I a
3 3" (CH ) Si(CH i C CH Si (CH NaX, (1) under the conditions
3 3 2tn 1~ 2
Cx
of alkylation of acetonitrile. ihere n is I or 2, and X is Cl, Br, or I.
The structure of the compounds Otained was studied by their Infrared
spectra, The frequency 2238 sm .1 of disilane nitrilea lies in a region
characteristic of the cyano grotp, but is a IAI;tle lcwer than Its value in
4)-nitriles (CH 3)3 Si(CH 2)n CN (fo~ n -2 and 3, 2249 cm-I). This may well be
reconciled with the reduction o the frequency of an electronegative group
with increasing branching of th radical bound to this group. Besides, the
structure of the compounds prodiced was confirmed by their transformation
into ketones. The highest nitrile yield was obtained according to reaction
(1) for (CH ) SiCH I (about 40 %). In the case of (CH N SiCH C1, the
3 3 2 313 2
disilane nitrile yield was lowest (about 20 In parallel to reaction
(1), numerous by-products were formed which corresponded to the dimer of
the initial 0-cyano-ethyl trimet~'-yl 911ane. The dimerizati,-,n of silicon-
Card 2/5

Organosilicon compounds with
S1020 64,/.138/004/011/023
rocarbon... B103/003
free nitn-les under the action of sodium is known, and was confirmed by an
additional experiment. Frcm tie two structures aacribed to such dimers,
(A) and (11)
R~H C -C -- R
RCH 2 -C -CH -R 2
(A) NH NH2 CN
the authors choose (B) on the asis of Ispestral data. inhere R--CH 2 Si(CH 3)3*
Here, they find the frequency 201 cm- (apparatus VIXC-12, IKS-12) which
they consider to be that of th valency group - C=N. This frequency is
reduced, apparently owing to a chain of conjugate groups. The frequenciee'
3400 and 3448 cm- 1 correspond o the symmetric and asymmetric stretching
vibrations of the NH 2 group, n the infrared spectrum of the solution of
this substance in C0141 the fr qu9ncy 1630 :m- 1 Is characteristic of the
- G -C bond , The ultraviolet spectrum of this substance showed an intensive
frequency 248 M4 (E -465oo). n the alkylation of the w-nitrile of the
type NC - CH 2 -CH 2 -0 - (CH 2)3 Si [- (CH 3)3' a different reaction occurred:
Card 3/5

2 W5,4
S/020/J/138/004/011/023
Organosilicon compounds with hydrocarbon, B103//B203
y-hydroxy-propyl-trimethyl silane and an acrylonitrile Dolymer mere formed.
In a c3ntrol test (without XCH 2 Si(CH 3) 3 ). a y-alcohol was aisu formed
according to 3cheme (4) (a -ethr, b -polymer). Decomposition of the
systems -Y-C- C-C-M (Y --lee ronegative. M - electropositive atom) was
thoroughly studied by A, N. Nes6eyanov and co-workerg (Ref. 14: Izbr. tr.
(Selected papers), Izd. AN SSSR,1, 1959, P, 549, 678, 684), and is a
characteristic of these systems1if M is a metal, In a special experiment,
the authors found that the alco~olate (CH Si(CH - ONa formed in the
3) 2)3=
reaction did not react with XCH P Si(CH 3 ) under given conditions. There are
I table and 16 references: 10 Poviet-bloc and 8 non-Soviet-bloc. The
three references to English-language publications read as follows: Ref. 8:
S Nozakura, S Konotsune, Bull. Chem, SOc, Japan, 29. No. 3, 322 '(1956)1
ibid,, 29, No~ 3, 326 (1956); f. 10: _R~ A, Show, J. Chem. Soc.4, 1956,
2779; Ref. 11: H. Adkins, J. ttman, J. Am.. Chem, Soc., 64, 150 (1942).
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institt'ite of Organic Chemi9try imeni N, D, Zelinskiy
of the Academy of!Sciences USSR)
Card 4/5
7
5/0-20 62/A45P0)PA9/029
aol
orresy swo 1 .1
tro I L. 01 'f 6o6-609
?e to. jous j962s
Wad, C Ts S 145, no. 59 j,10%eAes
FI_90,!
a
a
,Vne 13
a
~Lja'&j Sao t-011
syl etbil I -Do 8,6 Btu&
tetT GIS11jd's -tetT 959)) V
Vto. 6
Axe. 1289
,-)-
?S00DIC I",
~Xcttoll of et a, wit 1 C"a ).10
trod 00-IrTle ( ,
,pr0a' Ve i,ef e 51
-TOT to k. 0 D_ o"M0111
r e 06C C
9,cie( 0,110111116 Bt.
~P C"2~ C1. .
%
octISC11% IOLA
'~ 11
IjAcCIAPA I
j
00~ i
MINIM
r ra, 1/4
'a

S/020/62/143/003/919/029
Synthesis and conversiorsof B110/B101
produced were highly viscous iiquids. Their viscosity index was close to
I
that of dimethyl polysiloxaneo. In a similar way, disiloxanes with
reactive CN-alkyl- and Cl-alkil groups were obtaineds
INC (C1f2)4Si(Ct18)'jj0 +n ICIC1135i(C1101110
- 2114C P10'spi (CH3WSI (Q~)ICHJCI + (n - i) IC1CHjSijCHv)jj,0. (4)
At n - 7 chloro nitriles with 70-90 yield were obtained. According tot
NCCH2CH 2Si(CH3)2 MOE 3)2CH 2al acetone !P NCCH 2 CH2Si(CH3)2OSi(CH3)2 CH2It
the iodide was producod with ~34 yield. There are 2 tables. The most
important English-language reierence ist M. Probert J. Am. Chem. Boo., 77,
3224 (1955)-
ASSOCIATIONt Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
Card 3/4

Synthesis and
SUBMITTEDi
conyersiona~:Offl,oo
December 11, 19,61
S/020/62/143/bO3/019/029
BIIO/BlOl
r)
Card 4/4

S/0249/63/0
Acussiou im: L"4022012 1910121002510031
AUTjio,1Ls: sady*kh-Zade,, S. I.;',Sultanov, R.; Gasanova., F. A.
TITLE: The incorporation of h~drosilicones into glycidolallyl estor and some
transformations of the obtained additional products (Presented by Academician
A. M. Kuliyev of the Azerbaydzimn Acadeqj of Sciences)
I
SOURCE: AN AzerbSSRs Dokla4~yj Va 19, no, 12, 19631 25-31
TOPIC TAGS: opoxides., qooxVy drivative,, glycidol., glycidolallyl cstcr,, silane
hydrosilicone, alk-lysilicone., rialk-flailane, alko.)qsilane, catalyst, chloropla-
tinic acid, oreanosilicon compound, alkene
ABSTPJ,,' T: A method presented Lre permits the synthesis of siloxanes by catalytic
incorporatlion of silanes and disilanes into Glycidolallyl ester. It was shown
t1=t trialk-ylsilanos., alkoxysiianes,and disilanes of the HRIRSOMRIH type are
readily 1-ir-kod to glyvidQlailyl e6ter at atmospheric pressure in the presence of
chloroplatinic acid, accordinZito the reaction
7 0
H20CH2-C/-t-\cH3
H;Ptcl
RR;Se+CH
Card 113

ACCESSION hR: AP40220032
0
-4, --RR;S1CH2CH2CH,0CH2-CH-CH2,
where R-CH.
R'-C.,H.l. C3H, OCH,
-C3Hs, OC,H,
Eleven new organosilicon commpo s were synthesized. Tho process is exemplified
by the technique of Gamra=a-glye ol-oxypropyltriethylsilane synthesise In a
flask provided with a roflux c , enser and a thermometer vere placed 23-3 Sm. CC
frcs~ distilled Slycidolallyll czteri. The flask was then heated to 90C. and
to it were added 3 drops of a 0!41 rormal. solution of chlroplatinic acid in
isopropyl alcohol, followcd by gradual admixture of 21.6 gin of triethylsilane,
,When 6 ml of (C2H 5)2SiH were added, the temperature rose spontaneously to 3.30C.
After the non-reacted componont6. were removed by vacuum distillation, 16,4 gm,
of the desired compound were produced. Boiling point of this compound was 120-121C.
arc?/3

ACCEssioN NR: AW22012
It was established that the trialkylsilanes were linked to the rlyc--*dolallyl
ester according to Farmer's lays Orig. art. ,has 1 13 formlas and 1 tables
ASSOCIATION: IMP im, Xu., G.IMamedaliyeva (IMP)
SUBMITTED: 13Nov63 DATE ACQ: OBAPr64 RICL: 00
SUB CODE: CH zm REF sov: oo6 CTAER: 000'
313

11 1 ~' IT, , .
- I , -) 1.; -1 1. 'J" , R.~, F.M.
j .1, ~ .. . 9
- -- - '. - -,- - I - I ~ !
Aidit.lon of ,31.1,lcon 6drides .,o /3-propargy-.-hydrrxy
proplonitrije. Azeib. khIrl. zhuro no.1;57-62 '64.
(MT.RA 17:5)

Fj- I I , , . I-, , , - L; M -V, jj-,.~jp E , S . T
p. , ~ SQYF
. _14'7a, 1 4.7 -TAIL . 1 1.
I------,-:-,,-,,-- I . I
i
~)ynthr~nls of slllcon~ccntalnlng unsaturated acetates.
Azerb. kh1m. zhur. n6.1:97-103 164. (MIRA 17:5)

SADY',11-7ATiE, SULTANOV, GASHOVA, F.A.; i-sC)F,(-VnY, A.P.;
110?,*CVA*rP .0, V.A.
~TF
LITVINOVA, O.V., I
Synthesis of epoxyar,,ino ganosilanes. Dokl. AN Azerb. SSR 20
no. 6:25-27 164. (MIRA 17:9)
akademikom~N
1. Institut neftekhimic eskikh protsessov AN AzerSSR.
A
Predstavleno
AzerSSR M.A.Dalinym.

WT
PC 4-/Pr-41
k:L C-
rs-4 ljpt C j D
CCESSION Nit. J4 49602 S/0316/64/000/004/0047/0053
-1 1OR: Ga&-ariciva, F. A.; ~u it?y, R. ~Wkhzade, S. F,
77TI of sflJcon-",i0j!j~,, clilot-ohydrins ~nd their oxides
'Tl('F- Azorbaydzhanskiy khin.-tchc:;kiy zhurnal, no. 4, 1964, 47-53
-AGS: silicon chloroh.-frip, sillco hydride. silane, silicon chlorohydrin o7ade
.-k k,' Z'IL,%CT- This is a cantinua.Utin of previous work by the same authors on methods of
sN krithes.'.Ang silico-olcfin oxides. " t Was found that silicon IWdrides and dihydrides, in the
',;CM - Of platinum catalysts, r adily react %1th 3-allyloxy-1-chloropropanal-2 and
(Jda-i~.,'l ether forming the cor7'esponding sillcon-containing chlarohydrins and their ox-
.3s. By verif,-Lng the structure af these compounds with the aid of th~ opposite synthetic:
-ctlo It was proven that slJlco)h hydrides under the alyjve condittona become bonded to
-aRylt y - 1-chloropropmol-2 and to ULe glycidal.14-1 ether orl4r at the C-C double bond,
according to Farmer's rrvle. Theibest yields of siffco-organic oxides are obtained by
directly compoundinIg silicon hydrides writh aycidallyl ether rather than with 3-allylo,\v-1-
chloroprofanol-2 with subsequent deh-,drochlorination. Iffie, follouing compounds were
-,;3,-Tn-