SCIENTIFIC ABSTRACT SVESHNIKOV, D.A. - SVESHNIKOV, N.N.
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CIA-RDP86-00513R001654120006-6
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S
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December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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'IOV/122-58-12-10/32
Improving Forging Hammer Rods by -9a]-le-r Working their Surface
a state of surfiice coinp::,ossion. but the spherical roller
gives a slightly wtvjy s-uitfaca. The se'cond pass, therefore,
is made with a rol*! 'ei~ a,. cylindrib1il, profile about
4 mm. wide unde:~ abou- '700 !,:-, loatl* This pa~ssjs made with
the roller hav4ng an cang"t-, of attack which 'leads' by,
6 o.'~ f " a
- 80 in the di,~,ect4c,r_ -. foad tr verse (Fig 3). This
gives a smooth surfaoti. '11--itit. oT-Lginal irregularities (with
ground rods from steel of 2~1 - 302 Brinnel hardness)
amounting to 2. 5 Micz,012-11711 can produce surfaces with
1.5 micron irregulavitly using 700 kg load, and 0.7 to 1.0
micron using 1000 kg loading. On the second traverse
the pressurfi is up g'--adually as the roller traverses
the rod. A table is gjJ*_-,?-(-;n ~:t--.owir.g improvements amounting
to 50 - 100% on 11_1N:, -fu:? hammer rods for hammers
with total weight rr-om 1000 4-0 7200 kg, as a result of
roll workIng their surfa~~,;~. M
There are 5 figures and 1 table.
Card 2/2
S/129/60/000/011/007/Oi6
E073/E535
Heat Treatment of magnesium Inoculated Cast Iron Crankshafts
of the obtained results, a heat treatment schedule was worked out,
by means of which a structure of granular pearlite (Fig.1, plate)
with a hardness of H = 207-241 was obtained. In addition to
granular pearlite, S~ ands of lamellar or sorbite-like pearlite
were observed and also rejections of primary and secondary
cementite. The subsequent experiments were made on 70 mm dia.,
700 mm long specimens from twelve different heats (Table 3)
produced in a 100 kg capacity high frequency furnace. On the
basis of the results of these experiments, the following conclusions
are arrived at:
1) For manufacturing cast crankshafts for motor-car engines, a
magnesium inoculated cast iron of the following.composition is
recommended: 3.40-3.'60% Cinitial' 2-2.20% Si, 1.15-1.30% Mn,
max 0.005% S, max 0.120% P, 0-15-0.25% Cr, 0.03-0-06% Mg.
2) To obtain granular pearlite the cast crankshafts have to be
heat treated in ccovdance with the following+y8gime: air hardening
(4ormalization)14y holding for 8 hours at 950 *C, cooling with a
speed of 60 to 30 deg/min down to 6001C, followed by tempering at
Card 2/3
S/129/60/ooo/oll/007/016
E073/E535
Heat Treatment of Magnesium Inoculated Cast Iron Crankshafts
7254* 15a C with a holding time of 8 hours with subsequen t cooling in
air.
3) Practical experience obtained with crankshafts made of this
matertal has confirmed that these are fully capable of replac.-L'ng
satisfactorily forged crankshafts.
There are 5 figures and 3 tables.
ASSOCIATION: Gorlkovskiy avtomobillnyy zavod (Gor'kiy Automobile
Works)
Card 3/3
23101
S/122/60/000/011/018/020
Strengthening eccentric and stepped shafts .... A161/A127
E P1 + P2 P ~E (1)
n :2 ( 1 - 2
where P, is the spring effort in triggered position; P2 - the spring effort in
position at the moment when the striker contacts the work surface; x - work tra-
vel of the stiker; c - rigidity of the spring. If the optimum En is found expe-
rimentally for the fillet radius R, the stroke energy for the other fillet radii
can be calculated from the deformation law of specimens under strokes of a ball.
The work A absorbed by the specimen is directly proportional to the cube of the
ball diameter, and, on the other side, work A is proportional with energy En:
En = kID3, or En = k2R3
(2)
where R is the striker radius, and k2 the coefficient of prpportionality that can
be calculated from the optimum data of the coining process. The obtained depen-
dence (2) is used for calculating the stroke energy for any fillet radius. For
convenience, a nomogram can be built up using the formulae (1) and (2) and the
results of'the spring calibration. Such a nomogram is shown (Figure 1), built
Card 2A
SVESHNIKOVY D.A.; KOZYAKOV,, N. Ya.; GOLUBOVSKAYA, L.D.; ZHIGUN, A.P.
Scale removal from the driven gear of "Volgam automobile transmissions.
Avt.prom. 27 no.6t42-43 Je 161* (MIRA 14:6) /'
(Automobiles-Maintenance and repair)
(Automobiles--Transmission device)
N
26388
S/032~61/027/008/011/020
B!03/B206
AUTHORS. Kotkis, M. A., Sveshnikov, D. A., and Afanaslyevaq V. K.
TITLEs Investigation of the surface of fatigue failures by
electron microscope
PERIODICAL: Zavodskaya laboratoriya, v. 27. no,. 8, 1961~ 992
TEXT: The authors studied the surface structure of fatigue failures of
brand-45 steel (C = 0.49%, Si = 0.17%, Mn ~ 0.77%, S ~ 0.035%, P ~ 0-025%)
under the electron microscope, The steel was in its normal state (0 B
= 67 kg/mm2, 6 S = 35.8 kg/MM 2, 6 = 22.4%,-q = 45.3%). The specimens had..
a length of 450 mm and a diameter of 80 mm. They had a 2 mm deep annular
kerf with a radius R - 4 mm. To produce replicas, zapon varnish ('%
solution of celluloid in amyl acetate) was applied twice to the fracture
surface close to the start of the fatigue deqtrUet4on. The replicas were
separated by means of gelatin and shaded by means of chromilxn. The micro-
photographs of the fracture surfaces were evaluated accordi.ng to the
classification by D. N. Vidman (Vestnik mashinostroypniya~ No. 2 - 4
Card 1/3
S/129/63/000/001/001/017
AUTHORS: Kudryavtsevi I.V., Doctor of Technical Sciences*
Professor and Zyeshniko%;# DLA. .*Engineer
TITLE: Heating of work-hardened components to improve their,,;. ,.
fatigue strength
PERIODICAL: Pletallovedeniye. i termicheskaya obrabotka metallov,..,:.
no.1, 1963, 5-7
TEXT: The effect on -fatigue strength.of additional heatizvg__, _~~_21.1,1-1._
After work hardening was inve4tigated. The specimens were first
1~eat treated (holding at 9000C for 60 mint quenching in oill
tempering for 60 min at 4500C in a nitra~te bath), then work-
hardened by shot-peening and subsequently tempered at various..
The following tests were carried out: bending of
tdmperatures.
f tj 6 mm thick specimens,of the spring steel 55G2 (5550_';___~
s metrical -t-oraxon. mm--diame ter rods of the steel 60C,2
Yin
(6bS2); fatigue'tests on coiled springs made of 41 mm diameter',.--,
wire of the steel C65A (s65A). Results: the fatigue limit of
work-hardened springs can be increased by 9-10% by subsequent~
e,
heating. The optimum temperature for which'the highest increas
Card 1/2
SV-PSFNIKOV,- D.A.
Hardening gearbox pinions of automobiles by shot peening. Av'..prom.
30 no.2:35-38 F 164. (KrRA 17:4)
1. GorIkovskiy avtomobilInyy zavod.
lg~~s a rer!-2-t~ of c eineatud ana --n! ded
parte by Pe-!~al ovei~ tenim. Obr. r.~t.
P.P 164. (MIRA 17-,6)
t 11793-66
CC NM A%ooooo
specimens, 6.0 mm thick, were prepared for shear tests, and circular
Z20steel.) specimens, 8.0 mm in diameter for symmetrical torsion testing.
The thermal treatment applied consisted of 60-minute tempering at 900G, quenching
in oil, and a 60-minute nitrate bath at 450C. Results indicate that with increasing
temperature.of cold-worked specimens their fatigue limit increases,, reaching a
maximum shear strength at 300G,, and a maximtm torsional strength at 200G. In both
cases the heat treatment results in a 10% atrength increase, and further, temperature
increases cause the strength limito,,+o drop sharply. Additional fatigue tests were*-
performed. on the valve lift sprIMal 43ed on the Pobada automobile. The rearats we
plotted and show tb t atmmwddm=ua f atigue . strength is reached with a ascondarj, heat
treatment at 1750 JILes ire performed according to the method of L* L=Ltl (La
Metallurgj We A discussion of the relative Importana(#
size 0 . I
shape# and density of the materials tested is given* OrIg' art* Me 1 5
figures.
'SUB GOESS n/ SUH DATICS 24AWO/ OM RIW# 008/ OM MWo 001;
2/2'
ACC NR:
k,z/mm2
.49
-00
O.P O~s as 1.0 zo V FrtF4e
Fig. 1. Residual stresses in the surface
layer of rings (at depth of 0.1 mm) versus
depth of hardened layer and ratio Fk/Fc:
1 - HRC 55; 2 - HRC 45
compressive stresses which increase the fatigue strength and durability of case-
hardened and tempered parts. Engimeers L. D. Golubovskaya and A. 1. Badlin took part
in the work. Orig. art. has: 5 graphs.
SUB CODE; 11, 13/ SUBM DATE: none/ ORIG.REF: 002/ OTH REFs 002 L
SVESHNIKOV, G.B.
Ferromagnetic properties of minerals. Vestaik Leningrad. Univ. 5, No-7,
83-7 '50. (MLRA 3:11)
(CA 47 no.22:11833 '53)
Cand aoul-,:ill 'Sci-(di~;r;) !Y6 F.".reryles
_EJT 0::; Of 11
n Ol y: CA a 1 ic
Oi -ir of L,,-i,.Jn li,i '-.A. Zh(I-11(w)
19
s7zSRNIKOV, G.B
Weetrcde potentials of minerals and their role in dissolving sulfide
ores. Tich. zap. LGU no.249.-278-295 158. (NM 110)
(Sulfides-Blectrometallurgy)
6,.B.
I i~atinn-redur,'--Ion po~anti-ln of 4-- th-r- Rudwr7 Altai cov.-ilem
-,~ -11 dapi- - ~ - " I -"
1 -t, Va~41. LIM 11 no (IJI-RA 12:7)
. . '~' -Ct t), .
(Altlai Y~-nntai----Kint, water)
SVESHRIKOV, G.B.; :DOROFL7WA, M.K.
Certain electrochemical characteristics of sulfide minerals.
Uch. zap. IGU no.278:149-153 159. (MIRA 1312)
(1~,rites--Klectric properties)
(Galena-Slactric properties)
SVE SMTIXOV G.B.
Effect of electrochemical solutign of sulfides on the chemical
composition of waters in polymetallic deposits of the Rudnyf
Altai. Uch. zap. LUG no.286:130-14.1 160. (MIRA 14-0)
(Altai Mountains--Geochemical prospecting)
(Water, Underground)
.1
SVESIINIKOV, G.B.; DOBYCHIN, S.L.; SHKORBATOV, S.S.
Possi$le ro~e.of electrochemical solution of sulfAdes in the
formation of aqueous halos of nickel dispersion. Uch. zap. IGU
no.286*42-148 16o. (MIRA 3-4:3)
(Geochemical prospecting)
(Nickel ores)
IT,
S/-169/62/000/005/037/093
D228/D307
A THOR: Sveshnikov, G. B.
AU
TITLE: Factors -overning the Lo.-mation of a natural electric
field in sulfide deposits
PERIODICAL: '.Q,.efera-'-ivnyy zhurnal, Geofizika, no. 5, 1962, 34-35,
abstract 5A268 (V sb. Vopr. rudn. geofiz., no. 2, 'A.,
Gosgeoltekh-Jzdat, 1961, ~8-78)
TEXT: It is stated (that the main cause of the formation of a na-
tural electric field in ore deposits is the difference in the po-
L,ential j-umps at, the boundary of the electron conductors, which
consitute the orebody, with the ionic medium, represented by inun-
dated rocks. The potential jump at the orebody's boundary is de-
Vermined by the ore's electrode potential, which depends on a
whole series of factors (chemical composition of the minerals and
the solutions, the pH value of the waters, etc.). It is emphasized
that, the influence of these factors is assessed differently by va-
-rious authors. The work of a -number of research scientists As. con-
Card 1/2
7Z
4116o
S/169/62/000/009/054/120
D228/D307
AUTHOR: Sveshnikov G. B.
TITLE: Role of the chemical composition of subsurface waters~
in the formation of a natural.electric field in sul-
fide deposits
PERIODICAL: Referativnyy zhurnal, Geofizika, no. 9, 1962, 41, ab-'
stract 9A272 (In collection: Vopr. rudn. geofize, no*
3, M., Gosgeoltekhizdat, 1961, 22-29)
TEXT: One of the chief factor8o determining the natural electric
field'a intensity in sulfide depositep iq the variable chemical
composition of watere circulating at different depths. The concen-.
tration of hydrogen ions (pH value) and also of ions of redw? eye-
tems -- for example, Fe 2+ and'Fe 3+ -_ playa the main part. In the
-event of the influence of one of these factors -- for example, thei
pH value -- it is possible to estimate quantitatively the natural
--field'B emf. The sharpest differences in the chemical composition
Card 1/2
SMUNIKOV, G.B.; SHFAII CHZHAO-LI [ShAn Chao-li]
Hydrochemical itudies in the ore-bearing region of the Irtysh Valley~
Uch.ziLp.WU no.303.**301-319 162. (MM 15:11)
(Irtysh Valley6--Water., UWerground-Analysis)
(Geochemical prospecting)
SVESHN SEENI CHZHAO-LI [Sh6n Chao-li); SMIRNOVA, F.F.
Effect of annual charWps in the climatic conditions on the nature
of hydrochemical anotalies in theRudnyy Altai. Uch.zap.ILU
no.303:320-333 162. (MIRA 15:11)
(Altai Mountains-Water Underffround- vAis)
(Geochemical prospecti
SVESHNIKOVP G.B.; KEDRINSKIY, I.A.
Electrochemical solution of sulfide ores. Vest. LGU 18 no.12:
62-71 163. (MIRA 16:8)
(Sulfides) (Electrochopistry)
SVESHNIKOV, G.B.; RYSS, Yu.S.; AU21N, A.K.
Natural electric field as a factor in the formation of zones of
secondary enrichment in sulfide deposits. Uch. zap. TLU no-320:
122-133 163. (MIRA 16:9)
(Electric prospecting) (Sulfides)
I
MWA U I 'Al
LEMMV, V.:1.; SVESHNIKOV, G.B.
lbericim Boienti3t at lAningrad University. Vest. LOU 19 no.M-
177-178 164 (MIU 17 W
R-161", ; SVEL~1:1,"IrKc"V, , G. ;5.
Gece I e C, In lical ---cc es se 5 in ge, : c r~ -
19 1,- 1 Ov I i -ru, 1, 7 ; - - "
j C~, . -1,
G.B.; Iii,11N, Yu.T.
y electrode t:ctent a-is of cre deixisits. Uch. zap. LGU
S +-at i ona n "i -
no.324!317-332 164. (MIRA 18:4)
S v C-- S t-j 1,4 x K OV, -N.
USSR/ Scientists Clbituexy
Card 1/1 aib. 41-08
Author Kochina, P. Ya,., Blokh, E. L., Koswdem'yanskiy, A. A., Rabotnov, Yu. N.,
Byeshnikov, G. N., Talitskikh, N. A., Finikov, S. F.,, and Chetayev, N. G.
Title To the memory of Vladimir Vasillyevich Golubev
Periodical Izv. AN SSSR, Otd. Tekh. Nauk 12,.3-4, Dee 1954
Abstract A brief review of the life of the recently deceased Golubev.
Institution
Submitted
VORONKOV, I.M., prof.; GERNET, M.M., prof.: DOBRONRAVOV, V.V., prof.;
KOSMODEMITANSKIT, A.A., prof.; LOTTSYANSOT, L.G.. prof.;
prof.; EWBODYANSKIT, M.G., prof.; TABLONSKIT,
A.A., prof.; POGOSOV, G.S., doteent
[Program in thaoretical mechanics for majors in machinery
designing, mechanics, instrument designing, electrical engi-
neering, and construction at advanced technical institutions
(220 hours)] Programma po teoretichaskoi makhanike dlia mashino-
stroitel'nykh, makhanicheakikh, priborostroitelInykh6 elektro-
takhnicheakikh i stroitelinykh spetsialinostai vyeshikh takhni-
chaskikh uchebnykh zavedeaii (220 chasov). Moskva, Gos.izd-vo
*Vysshaia shkola," 1959. 10 p. (MIRA 13:2)
1. Russia (1923- U.S.S.R.) Ministerstvo vysshego obrazovanlya.
(Mechanics, Analytical)
MSMIIKOV. G.IT GOLIUMG, G.K., kand.tathn.nauk; IDZffMOVA , T, I, ,
-st;rshiy prepodavatell; SHAYALOVICH, A.F., red.; CHISTYMOVA,
K.P., tekhn.red.
(Geometrial statics; lecture abstract] Oeometrichealmia
statika; konspekt lektaii. Soat.G.K.Golldberg i V.I.Shakhidzhanova.
Moskva, Koak.aviatsionnyi in-t im. Sergo Ordzhonikidze, 1959.
78 P. (KRA 14:4)
(Statics)
ZINOVIYEV, V.A.; -_g!I~O, I.K.; YAKOVLMV, K.P., red.;
RYDITIK, V.I.,, red.; AM-A I S.N. , tekhn. red.
(Short handbook on physics and mechanical Kratkii fiziko-
tokhnicheskil spravochnik. Moskva, Gos.izd-vo fiziko-matem.
lit-ry. Vol.2. (General mechanics, strength of materials,
theory of mechanisms and machines] Ob9hchaia mekhaniks, sopro-
tivlenie materialov, teoriia makhanizmov i mashin. 1960. 411 p.
(MIRA 13:12)
(Mechanics) (Strength of materials) (Ma chine ry)
ZINOVIYEV, V.A.;_5U TKOK, G.N.; SNITKO3 I.K.; YAKOVLEV~ K.P.y
SM
red.; RYDNIK, V.I., red.; KOLESNIKOVA, A.P., tekhn. red.
(Concise physical and technological handbook)Kratkii fiziko-
tekhnicheskii spravocbnik. Moskva, Fizmatgiz. Vol.2.[General
mechanics strength of materials, theory of mechanisms and
machineryiObshchaia mekhanika, soprotivlenie materialov., teoriia
mekhanizmov i mishin. 1962. 417 p. (MIRA 15:12)
(Mechanics) (Strength of materials) (Mechanical engineering)
GMIET, Mikhail Mikhaylovich, prof.; SVESHNIKOV, G.N., zasl.
deyatell nauki. prof., retsenzent~-VMLOVSM, I.N.p
doktor fiz.-mat. nauk, Prof.P retsenzeent; FOODSOVI, G.S.,
kand. fiz.-matem. nauks dots., nauchn. red.
[Course in theoretical mechanics] Kurs teoreticheskoi me-
khaniki. Moskvaj Vysshaia shkolas 1965. 406 po
(MIFLA 18:7)
1. Moskovskoye vyssheye t-khnicheskoye uchilishche im. N.Ye.
Baumana (for Veselovskly).
SVESHNIKDV, G.V.; DOBTdHIP. S.L.
Galvanic sulfide dissolution as a formation cause of the
hydragooebemical balo of heavy metal diessajdatiqn.rVith
English summary in insert]. Gookbimiia no.4:70-75 156.
I.. (MLRA 9:11)
1. Leningradskiy gosudarstvennyy universitet, Leningradskly
tokhnologichAtkiy institut.
(Sulfides) (Altai Mountains--Geochomistry)
04
KOZLOV, V.Sh.; SVESIINIKOV G.V.
-- 1. 1 .-- .
Experimental construction of a-building from machine-cast
elements. Prom.stro-J. 39 no.805-40 1,C1. (MM 1419)
(Kiev-Precast concrete construction)
LIB:RMAN, A.D., kand.tekhn.nauk; KOZLOV, V-Sh., inzl,.; SVESIINIKOV, G.V.,
inzh.
Design and construction of a mechanically assembled building for an
automatic machine-tool nlant. Prom. stroi. 39 no.10:42-47 0
161. (MBIA 14: 10)
1. Nauebno-issledovatel'Ekiy institut stroitel'nykn konstruktsil
Akademii stroitel'stva i arkbitektury USSR (for Liberman).
2 Kiyevskiy Promstroyproyekt (for Koziov). 3. Kiyevskiy sovnar-
k~oz '(for ~veshnlkov).
(Kiev--Precast concrete construction)
1 -62411 5-6c. F-.7 VFWc- t cS 'j2
R/02 el-4,/65/000/012/0127/0127
VUJTHORS- Yurchen ov Ge- 7
k -Shevehuk, F. Ye 3aeshnik Veseloiskiyj- -j
Ciass 00, No. 1-1220d
-LEi A ~Ievic3 for maxing cellular cone-rete.
?rLlleten' .zobret-eniy i_ tovarnykJ-. znakov, no. 12, 1965, 127
TOPIG TAGS: construction material. concrete, cellular concrete
ABSTRACT- This Aathor Certificate presents a device for making cellular concrete
(see Fig. 1 on the Enclosure). The device consists of a mixing container mounted
on a hor-izcnta.~. hollow roller and carr3ning an internal endless worm. screw. To
th- i--ree of cone-rots mlxinga, the mixing coqtainer is produced in the
FTr, I i_ "narie i.oiw -)ana-L.9 wi ii
Derforated wa.!I~�. Theae
A"
SUP 4~~
T-
Fig. 1. 1- -LLxing container; 2- hollaw roller;
3- nnjd~w i-isk, 4-- worm screw; 5- holiow panela
f) rd 7~p 9
n' - 1. (DDC64) --- -
~
"Production Workers Prepare to Enter Highe r Educational Institutions, -
Cmrses for Construction Workers," VecherrXVaya.Moskva, 7 June 1957, P. 1.
Director, Moscow Inst. of City Construction Engineers
Trans - U-~-3,055,385
Automatic washing machine. Zhilo-komo khoz. 3.1 no.900 S 161.
(MIRA 3.4 -.11 )
1. Nachal7nik proyektno-k)nstruktorskogo byuro Akademii
kommunallnogo khozyaystva i direktor Eksperimental7nogo zavoda
Akademii kommunallno 0 khozyaystva.
~Washing machines)
SVESHUMOT, I.A.
licitation of qynchronous motorg vith an slectrolyzer oyotem* PrOms*
energ. 15 no.10:25-2? P 160. (MIRA 13:11)
-,(J;lectric motors,.Synchronous)
SLESAREV, P.A., prof.; SVESHNIKOV J~, ,, inzh.
I ~,
Studying the physicomechanical properties of rocks. Izv. vys.
uchebo zavo; gor, zhur. no.5t47-52 161. (MMA 16:7)
1. Kharlkovskiy gornyy instituto Rakomendovana kafedroy
stroitellstva gornykh predpriyatiy.
(Dnieper Basin-Rocks-Analyoip)
SVESMSW, I.A.; SHATALINA, V.D.
Raising the performance efficiency of electrolyzers. 14asl. -
zhir. prom. 27 no.-12:33-36 D 161. (MIRA 14:22)
1. Predpriyatiye 'Energotekhnaladka".
(Electrolysis) I
(Oil industries-Equipment and supplies)
POLYAKI M.S.!
Increasing the durability of cable-tool drill bits by the
method of hard facing vith new wear-reisistant KhGI alloys.
Nauch. trudy KHGI :L1:101-103 162. (MIRA 16:11)
SOV/137-59- 1-281
Translation from: Referativnyy zhurnal. Metallurgiya, 1959, Nr 1, p 35 (USSR)
AUTHORS- Sveshnikov, M. A., Sobchuk, Yu. I., Vasilyev, B. T.
TITLE: Placing Into Operation the First Fluidized- solids Furnace for the
Roasting of Pyrite (Opyt OLIska pervoy pechi dlya obzhicra kolchedana
v kipyashchen-i sloye)
PERIODICAL: V sb. : Vopr. polucheniya sernist. gaza izkolchedana i sery.
Leningrad, Goskhimizdat, 1957, pp 58-68
ABSTRACT- A furnace for roasting of pyrite by the fluidized-bed method was de-
signed in 1953 and placed into operation in 1955 at the Voskresenskiy
chemical plant. The furnace is designed for maximum utilization of
li,~at of the fluidized layer (iminersed coils) as well as of furnace
gases (heat-recovery boilers). A diagram and a detailed description
of the furnace and its associated equipment are presented. The fur-
nace is rectangular in cross section (2.2x6x2.45 m) and is equipped
with autornatic controls for regulation of fuel and draft; the rated
output of the furnace constitutes 90 tons of pyrite per day, the height
of the fluidized- solids layer being 0.7 m. The roasting output at-
Card I ILI tained amounted to 55 tons per day; the S content in cinder, and in
,c,, ;.v , r v~,, rT 'A .
u 11 -1 i
Dollshe rrinerallm-kh udobrenii (17ore mineral feltili~~OrL~). Eoskva, ralhocilili'll
3- ~-, r. J! .[71 - .
, - 31 ,
., 1 17
El- : 1-.onthlv List of ftuc-,ian Accass-I.GT-', W.L. !, Ito. 7, Oct. 195h
SVESHNIY,OV.s M.A.
USSR/ Chemical Technology. Chemical Products and Their
Application - General Questions
Abs Jour : Referat Zhur - Xhimiya, no 4, 1957, 12311
Author : Sveshnikov M.A.p Andreychenko A.M.
Inst : Voskresenek cal Combine imeni V.V. Kuybyshev
Title : Twenty-Fifth Anniversary of the Voskresensk Chemical
Combine imeni V.V. Kuybyshev
Orig Pub : Khim. prom-st', 1956, No 5, 41-42
Abstract : No abstract,
Card 1/1 - 1 -
TSZEN LIN (TSO^ng Ling]; KW' LET [list Lei]; GREBENNIKOVA, Ye. (translator];
NOVAK, L, (translator]- SVEWHIKOY 9 9. obahchiy red.; LOGO-
VINSKAYA, R. , red.;
[Currency circulation in the Chinese People's Republic] Denezhnoe
obrashchenie Kitaiskoi Narodnoi Respubliki. Vatup.statlia i ob-
shchaia red. M.N.Sveshnikova. Moskva, Goofinizdat, 1959. 182 p.
(MIRA 12:12)
(China-Money)
SVESHIIIKUV, M.
-_- w" - I- I .Legal certification of accounts in the State -Bank. Men. i kred.
17 no.11:32-39 11 '39. (MM 12:12)
(China--Economic conditions,'!
AYZENBERG, Isaak Petrovich, doktor ekonam. naukj ~p JKQ -
OHN . V-~' K, . otv,
red.; NADEZHDINA, A., red. izd-vaj LEBEDEV, A., tekhn. red.
[The new rate of exchange for the ruble] 11ovyi valiutnyi kurs
rublia, Moskva, Gosfinizdat, 1961. 76 pe (MIRA 14:10)
(Foreign exchange)
wx I u on A 31 12 u id a Is v a 39 40 41 42 43 44 '~IT CM &T III rs
'
I
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sol oroxi TIN
A f Q b - d - I I L A I - - ~
U
161 A.0 3W
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* JINDIFtlell ).D ! .-
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-~-
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f
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.
:
V
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nll r
Vl
3104
2.2 ag-ILT411111 l
0 0
I wl V Pug *dnoil
qA'lA-Niw 'H a" , if puv
'uA*=s';Pj vgala!jla
q
-H
:
J
O
M
V TM" remual aql JO 'Pd- I qUA WaA"
son ou
3"M " P ;*Uwljd alp tq p-u4mw am SSW"
1e .2nV .1gf.99
-R-
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N Pug Aao
A
NaL I - ~1~ ... J
00- 00
600
66* 100
ol f1
0- Ir fe
F 11F~~ A.
I I A
ALC a A-9-9 -8-JIL-L
L" f !-I-- . , - -
09 A Iga-e
01
I-alelayele and Its wheyt bactuAw wft the t"'S"MIS A.0 14CF147.1% .Pg. -oo
lei
"690 of 2-cwthylb4magdasols. 1. 1. LevkoL;r, N. bf.
0e A Swftbni. V. V. Durmashkhja. J. Cws- Ckw-
104 1
00 (U., R, lo,.77"(INO); cf. C. A. 34, 7111t- -00
04 U*,
Y It hown that the anll of 3-byelroxythin-
napb -2-aklehydr (1) and Its vinyl barnolop react
9 "Is th 3-hydroxythlanaPhthene (U) with Cleavage of
00 compd. vniftoul'tue
A ,tolorms . polymethine dyes. 1twesfoundthat Lialting poly-ethine chain. was prepti. from It and etbo-
of it and Its rem"
0 A aMyI iodide salts 2-met =ylb..Meol. W) 'M 0.4abummulfonate deriv. of 2-meth tobeftembia-
Of
and Hauser -00
polymethine dyes of the "metocyanine" t T% (C. obtained by the methad of =
:0 drusatiou can be effected by Ftfluxing ;'=* ."." 7(i -A. 33, 25-141). It forms Yellow needles. m. 214-1$*
so x and JU &BITS. With snhyd. NsOAc in ak. for 0.6 hr., Of VAM an Increase of the length of polyVarthine chain by I
u I treatinf the 2 reactants in dry C&H&N coute. a little the m4z. absorption b "led in the -WW 0
a j M tisespectrumlAY82-90mR. These---
00 ine in the dark at room temp. for 24 hrs. I and Its TE" E r-tber
ET adyes on A#Br emulsions "IM fu In- a~00
#e 0 logs weBe prcpd. by the previous method and the N- w4fintion. Chas. Biane
Mel Ftl PrI and thil defivs. of IM by kno methods.
J The ;~~tU .1,h I ga., :-(J'-wdhy(brxw(* t-
ro(kinikkeow~'en. 0,%0*
do k W =ds h waldf.M.210-11* coo
~=rp..: :- Mt =-dles oc ~= with metallic lustef;
goo
the Pr a 1. m. 208--9*. (decomPtA.), red-violet needles;
the Bu analog, m. 177-8% red needles with a green gkw. 2. goo
AnD of 3-hjrdroxythUnapbtbese-2-vinyfw4LMebyde and
I N-Kti wIt of 1u gave.
IL
a butne3iidt",r) - 3 - axo - 1,3 m. goo
2I%-:k)' (decompn-). green needles. S-(31-Etky(b~- woo
- S - #" - 2,3:
dikyJroAkwapQAm* (from 3 - hydramblites0thm-2
0.8 - butadimyl - w - sJdehyde), m. 177-11'. bhw-grren
a .Iglassy needles. 2 - (S' - Rhylbe"WhiasolixyliArm - V)-
two
AITALLOGICALLITINATURt CLASUPICATOON 'Woo
:[:~A 16. 11 A
*00
&ALIBI an; QRV LSI
U AV 00 All" 11 dB 4 3 1 v
to, Ita 4 a it x 01 At a cc it K A I N A S 41 1W a a V I w a
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 9 0 0 0 0 0 oil
s o~ Ullhe 3-0.,iyLhiorl-
On th~ of
L:!.,-. of 3-0:-,V:u~
'Ioiliolo!~u-, from '~-.-atc-narr ~7alts
o 2-1-1 '-'rl ~) -a i.hia scd,~ ". Z`iur. Obsrich.
1.), :70.
-~c 27 Oct
'l1 Ja!i t-:2
m 6 Rt Ali
4 3 6 r I I to 11 tj I) u 11 4 0 a it u a Alt 4 A 9 x 0 4 41 a a
-A
palymethine dyes afthe J-hydro 3
11. Some subWtut*4 2-1243-MY114"t
Vothismpktheass. pren primia., tit. 2W 70". d-.VP,X. d4irk crevit placitt'.
'111t DurnJILAsk ills. tit. 2134% 6-AcNII. d4trh- Itreen amll"
1. L lxv al"I its. xtkw~ 301'.
.'hew- W."'S R.) 14. IM W20i"OU ill 1, 11 Yh4rt limile, ill. 273 d", d"'4emw'. brown
00 41i. unkillary); %'L C.A. 31; - V, - The alid (A m. dArk ml nevdics tit,
slid the q-tmtltrY salt "' 'b"
led ill liloll
11CIVIMYclic b0c iuv rrflu
:0 J1. witil \a(lAv to give ilcliv*- Of !,"I 243'ethyl-21:1) -be"Lu-
all. . 2 3 - dilly'lluthiA -
titu-af. CHCH.
c%Mtg- tho 0),
I'llsothialute fillelcu.: 6..tte. dark OftVit Ile"lle" N
Prisms ut. 211'~-20% 6.EIO, gretit
equ 236 7*, 6-Atr(p. PVC91 or reil-brow"
primll. sit, IM it , 6-Mrs, Smell tril'i"'A
00 A h Jim, fit, 210 -19". 6.0, YrIlaw- H t
iicv.llr~ with IL Kfccllis' h (LI). ICA-Iff-mil
tit. 2RI 2% G's('
00 x i'll tlul. d-11"fillt. .1-if 3:11)". 4-Nill? 441k
'Alth A If'"i
Ole iusuductiou of the stiWiturnts ha, a ImIlulchnanic
vffvvtizsjnostcw-.e*.
I", that caumvil by the "nic suintiluenti Its sym. thia-
riulkwyokkiltieft, Moo of the tlyrs, with the neepthm a
:j 11, housit4c AS Itiollile rimul-logm It, M. Leicester
21
&sN.$LA 01TALLURCIKAL LITIMAItiAt CLAUIPICATION 1.2
t
b AT PQ 11
u 0 At
TO (1, to (W a K 9( Il t[ It it it a Iwo Itillwillsais 3aw-
o
coo
see
:j It 0
me*
%Joe
lialsvilboo Game
r 2.0 049495 f
'socitigs Aim "Grieffift matt
00 A
1. Law.
so
~
, S~
k0ev, and XSveshuLkov. ;TA-S.R. 60,11TO. Aug. 3 1.
-
-
IM. Then ctkffW
..
VhW effective PhdosewiliKs,
06
r am obtained by in~~104 Ot quatern"y sidis elf 2.
. I
l incthylbentoth6sole or Its derin. and arthoesten of cm.
Wxytic iteitts. Thetrac ion is cwTicd out itt Cj4N.
00 U. floseh
egg
09 A
I I-so
-00
*90
-96
496
=00
doe
0-00
use
Al*-ILA 141AMMICAL UMATM CLASSWICATNU
Eve
1"m Sl"BIA" -- view *"Inv
14.40 -A' 0"1 '1" OU1111
Ir W 9 dB a 3 01
I NIS
b u is AV $a It win M 1 0 * 0 a 0 0 0 0
4:M22 :6064*410064640:
so R a no *vowed
00 AN
000
OOA
000
Ogg -
004
*0
E
sod
::
00
0*
-1 -------- :"-
1 6
-its
-00
:lee:
'too
=00
,Ire*
niko S. byn'
IfIfy,am U-S-S-R- 64X1. Aui.
3-%itrp4-&mincunhrAe nr it,6 acyl &Tiv, is bc,ted
With an aq. alkali Wis. 110wh
tf-$LA WTSLLLVGKAL MCNATURt CLAISWCATION
12dw 61"411" -
NO*
of
are
400
ire 0
Nee
do*
vels
its 0
~91/ Idnom, tylaso PIP 0mv 99C MILASI ad 4mv Ali
10 a W .1 W ON i 7 0 31 Vq_=
:10 0 0 0 0 0 9 0 0 0 0 0 0 010 610 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0
Oul I I t I I I I V) it 11 it It 1-1 4 t V 0 a of a 111 0 ople
-A-041111 (A go MIS I t J- t I I -A i k's
I.-
00 41
* o . ,;
go
-eia
Ditrivativeofbimito"zole. 11. Action otpotasakimi
0 1''
0 Al (JI forrocyasidst an tWo"ittyl-m-italsidine. N. N. Sveshrii-
kov and 1. 1. Levkoev. J. Gitte. Ckein. (IT. ,$'Affj 16, with soda, 7% 1, tit, 3R.I$ V ffrom licriAn); Pifrak tn. -0
11717140M)(In RusslariN cf Kiprijinov anti Klimpal,
00 *1 1 16"' (from 111011), molkintlido mAng W(from M011): -00
C.A. 38, W.-m-AnIsIdIne j12.3 ii.) suspended In &) dAW44 m. 187-S' (from MOM: He
0 CC. HtO wait treated with 12.2 g. AcO at 13-w" to give tn. IM-0 (from abs. MOM. I w-a synthtsiml 1,* -00
91.5% N-actlyl-m-axisidiRe. m. 79-M'. This (3,3 1.) In identification purpmes by an Indleperident method at
16 cc. boiling CJfo was treated with 0.9 g. powd. P18% aud follows. 3-Nitru,4-bromoanisole (11.6 X.) in 20 cc. tt'il- -00
boiled 20 min.: the Cjfa cit. of the gummy residue and
Ing MOU was treated over 30 min, with a Na polnulfide .00
the original soln. were combined and extd. with 4" Wri. from 6 C. rmt, NxtS and I ~02 a. S. and the mist.
N&011 - the ext. was neutralized with AcOlf and (reated Csole
boilled 3 bro.; the sepd. oil was boiled with 10 cc. MOIL
with We to lipt. N4hiowlyt-n-axijidine (37.110/v). m. then treated with Ftr0 to Induce crysin. of bitt(ti-mothasy.
51.5-2' (from 25% E110H). This Rn g.) in 145 cc.
of .2-SitropAnyl) 1611jut M. 161-1, (from CJ14) (a
4% NaOll wa added at 3-5* to.16.5 1. X (effo
11yanide 'Ind crystn. ave a m.p. of ICA-7'). This (3.68 g.) ant)
2
0 j In 165 cc. IfI0 with stirring and allowed to sta oitti. 6A7 g. Zrt Ilutt were mixed anti llowly added to .31) c 11 Co
0 nislit. to yield. after RettO iturt. and treatment with pk%-ic AcOll at 111(11~10(11% heated fit 100' 0A hr., trntM wic' Z
acid. 77.5% picrory of wired 6-adkoxy- (1) and 7-mell- 6.12 it. Ac%0. h#~ated .1 hm. at 114-17'. co,4vI to M-W'p SOO
00 2-mdkytbr%zdkiax*L- (11). m. 133-40' Dccom ito, *
Tt~e picrates with soda gave 6.61 t. ofa ;u~e batte en I. dild. with 50 cc. 11,0, heated to boiling, and filicre,l
rapidly; the filtrate was made alk . anti the oily I "a.
which, warmed with 2 cc. ligroin, cooled, acid pairtiall ell 41
y
ntd. with Etjo, which was then removed its sueare ofirr
mpd., gave 37.8% (U). In. W-7" (from 11grain) drying to give 91.7% of a product. m. 3&5-W (from
5- jfrom
m. 162-3' (from MOM; metkiadide m. 2W- ligroin), Identical with the product of ferrocyanide o&4Li -
propiodide
HIM); dhWi& In. 181-3" Umrom EtOH); tion given above. G. M. Rosolantiff moo
in. 191-3* (from MOH). The mother liquicisr U
from the
was converted into the pkr4k. m. 141-3*. which after
12; crystn. from Moll M. %M-2* and gave, after treatment
!.i ;
:at
14; A S A I L A METALLURGICAL LITERATURE -CLASUPICATIOM CIO 0
-:777-
4j.zj'. Got a.. as, N
U is is '0 IS: --Y- '5--' V f-An J, S 4 N 0 N 0 -1 if IN 5 A3 0 1
I " t7 it or it Is a x st K a it it K Kw n s ;Ya doe
0 0 0 4 Ole 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4,
0 0 0 0 0;* 0 0 41 0 0000 0 9~0 0 0 0
0 0000
00 A
.4
C
Of
*et
qjI3
000
God
OOW
ISOM
a it M a M a 9 a it 0 a a 41
"ON'111
Clasidise dyes. It. Certala hictmeds: merdwilYthl-eirb(le-
lxvkoev. NO =,I S. A.
Mww"w). J. ("elf.
tu 16, 14M-94(lil-16~6. Rwv4au); Cf.
Chem. S.S.
C 1. 40. "21M'.- '"Vral 4.4'-, 6.5 -, 6,41 '-, and 7.7
%rit sytithr4ird. awl their
alasslitkirs was Studi"J. Introduction of %[so Smut" in
the A- and IvnixItuva ties atintiost evqual, cou-
pAderalsk Imatheichtotnic cffcvt. while Rulmitution its the 4.
and 7-p&witk)exs shifte, th~ ab~xption titan, wily slightly to
I r water lengths. This kidicatits that in the 4- and 7-
=be 5- tied 0-tictivii. estructurra with l4bitilurly chextged
Naltel tbow with ImAlivirly chargerd 8 rr-juate with a
I gettex.
rqu~l weight. 114(mcirtyl-st-anisitfine ('217.1 1.) it 10 cv.
4% NACIII VVAI fle'lle'd at 0-V With IM 9. R fVIIkY4II1'1r
in 4W cc. water; MhWt IstAildilig ,vrt night. tht itsixt. isv.t~
-tic acid
cxtll. with HiA steed the ext. IrrOrd settle a1c. 1,11L
to virld 'MM';, 4 - ethal Y.... mirth 144 rates 111,
v (fron, titon),free baii. is,. s7-ml (rimn.
I
milhiMue. Ill. :N*; U, Main NIcOll). elkistfide, i I KS 46
(hons VtOll): os-propsodUis, est. 1F41-7' 0~
UtOll), El m. M-7' (front HtOll).
The otherriesuincerei wrre prtlxl.,.iijtiLLrly according it) Jacob-
son (Reer. 19, 'Fhe com4tionding 2-tuethyl-
stirthozybernsutlikizuk-s wrre heated %ith it 51"10 excess of
Ut GW 6 let$. ill 14(l .50" to P"I'- til"
3~j in t 1e
a-, ~T 4 Lfflifiltilite CLASUPICATIM
cue of the dinwilsyl d.riv.. else h*,,t,ng Was t. 130-5,;
fe .%It, me Ir In
aird uilh pyridille and
te curresi"llbils ottho rstrr (Ft '"Ife'd4wilutc, (Wtho.
ai-vtate, or twilsolwoo.ulate) and firailrd to 1,30 V file
'PA) cleire.. aftcr which the dyers liver i-)Ltnl by pptn.
with lit'0'.-4n. III hill Al"011, and'i'llill. 451~ "III. KI.
The
Invivistir-% and yk-I'l, 14 the pileths'.1.1 wv: 34, 'IWA~d.
4.0 i"dide
siterelks, dermitip. 2 11 * (jr,ent
Its. "Lu. 561) lit,;
wdodip
jsgcille~' devollill. (Invest
abs. Illis:
wlllim~
(
PlaIr'. drinse'lls. 21V
(1111411 MC011). dt^. Initis, MN step;
Awtarblnmnixe wjkir rea4vown
'-N"' Yls'ni NIVI(ill). 'it". MAX. .5401 Ms.;
-41 P"'th"t 'thi", QFN% )RI mind,
lehle ncrilkes, Itectitilp. (11,141, R1010. ithm. Ista%. 5711
nix;
"U'r GO-,), steel) vitelet neerdicts, decurnp. =I- (fresus
Nicoll), able. Max. &% nil&; Jj',941idAyI4.5'_jjmej6xy.
tkid-Carb"Xisse Wide (32'se), crcca prisrues, dcoornp.
241 ' (from EtOll). abs. trax. MI in*; 8
Wide N'70. brown.
gmes rectaks, devon ~17 (I I Nicoll). sb,. nux.
ro"
). via-di"A;y
224 rA4 16-
kt pri . decomp. 2M* (frow Nicoll),
abs, max. 572 nip:
a ate
t
_09
00
'00
1400
coo
too
goo
goo
goo
ON U a AT 10 L11' .an& seftcs pri-ex
a SIP10,111104K Niqww Ka
0 0 0 0 0 0 0 * * 0 elf 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 a 0 0 0 0 0
NO 000 0000000004 -100 0 : :. 1 990000000 0 W 0 0 0 0 0 0
tkiacarbocyawix4 iodide (36%). gray jw!%~js, decomp.
IPMTU
*
:M7
(frarn AfeOll), abs. wax. V7 nio; j..?
6,6'4imdkoxyWardrbmyuxixr jadide Ilerp lifilc
ptissits, decomp. 21421* (train NicolD. Alm. us.&I. 563 1110,
-1,3 pitine W. 00
00 dide (46'1_ titown." primils, q1tcollip. (holil 00
00 NIC010, aim. nw. SM M40; 3.3,-d,W*vi-7,#--dimfIAdxy_
I" 00
iodide (M
), Illur-%401vt l-4iIlIL4.
41r-
7
,
1
l 00
09 .11
CIIIIIII. 26IJ-
(floon Nicol
), alp-4- litax. .
.T
-111 lum. V.
00
'
*
viol"I
-se'l ItmIles. TV
(11,111i NIT011),
mal
Mll t
040
10
00 k.
ism;
f m# .xe iodide (30CO. vickt-arcen t"VdIcs. decomp. 2(1:1'
'
t
X 00
.Mi a
m. a=. US injoi J.3
-dimethyl-941kyl.
' V
-
A
d
A
00
00 -
imW
aTv(
~ua?bjcvuxiNe iodide (40
r). ird
VAJ
I
oll
t
N
l
.
rtimill'.
Omni
tr
". 11WI'l, Mi
in,.
), A
*41
to so
so so
00
X
09
00 09
00 00
00 00
09 to
00
L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 41 0 4111
0 0 0 0 * 0 * 0 * 0 0 0 0 0 0 * 0 0 40 41
a W gave 2 a a It Sea fis 6Q asset s " It
0 0 0 0 0 0 0 *Is 0 0 - 0
I I I is 11 U 11 14 It U it W if Is It
ad
A I r -0 A_J_ _A.- r__ J__IL_ L a - It_ ?-,Q R 4 - J _11 _V_ AA A CC QQ.K It ~ I I - 0 - 11, 4 N. I I ii_s
to _ , , - .1 . . I I
.41
'
'
6
l [)Pit$. by C(A, Wt. thh.jCtlyj j4ffjr.. 111. [IN)
.
-
wttevome
,S
y
Cyanine dyes. 111. Certain 4,3,4 C
FtOlf; clurce-J). The Liter (41.1 J
4"
) in N) CC 09
L I. L4vkogv wo N. N. avesh- .
.
,
'NA011, slowly added to 14.2 g. F:'FC(C.V)4 in #y) CC. lfKj
'
tit 2-3
and allowed to stand ovvitight, yki(W w;
-
.
J. G401. MAN.
uflwv (Killo-llcilo Rcs. Inst.' lmotieb*~ L"Att'i 44 tit'!
*
r
te
b
17
(1
f 00
.
A
(U.S.S.R.) 16, cf- 41, &WX)c.- ;-
a
ree
-8
ait
) m, (
(from HtOlf). 1 100
60 a Substitution of tetramethylene rings in place of 4,5,4'.4D'- ind 0.5 g. p-UcC4ff#S0,Ht were heated to Itio-pit lu
hirs
und
d
d
h 00
I benso groups in thiocarbotyranine dyes r6ittited in increased .
e7 a m
uz con
enser. wit
protectiou from moil.
I soly. and in a hyinuchromic shift of the aba. max. of 21
i
t t
th
b
h
h
i
ff
h
W wre. and the resultitiQuaternarY salt tras treated with
t-3 -
drY PYTwj- 0
IN
11C
013
d IS&
-
ect
n respec
o
e unsu
oc
tom
c e
e
t
mp; t .
-
K.
0, an
hrAted
(
to 139-W' I h
h
d
stituted thiciewbacyanines is about 17 mit. Replacement
l
th
It
i
d
j
20
h
i
l
b
M
f It i
9
i e
r.; t
ye. scpd. by arldn. of EtO. 116-
iolved in W011
and treated with lot-; KI
olo
00 of -
ew
s
on
e
n
yes resu
n a
e
-pos
t
o
n t
ft
7 ,
s
., yielded
'
1
'
21
3
3
di
h
nip shift of the trial. to shorter wavelengths and is .1milar
'
7'
4'
S'
7
dil
5
i 6
d
j -
.
et
.3
yl-4,5,4
%
.5
-bij0dramethyie"Aiocarbocy-
"Ni'm Wi
tle
shi
dl
-
- ant
lenzo
cr
vs.
to tfutt ollocrved in 4.
.
4
.
.
, t
ay green nee
,
es. in. (from Etoll).
(Brooker and White, C.A. 29.29.Al). The tetmmethyl- .-tbs. max. 574 mm. Use of WC(ol-q), in tile abav, gAve
ene derivs. air sensitizen of attedium effectiveness, their 15% at the corresponding 9-Ve deriv.. rcti-vicilet prisins,
7*
204
d
=60
I u-Et derivs.. it, Contrast with the com-sporuling dibenzo -
in.
(
ecompri., froin abi. EtOll). ibs. tual. a54
00. cornpds.. am little inclined to produce sensitization of the rim. Etc(OH02 SUVC 10.27a of the corresponding .9- 7, zoo
004 2nd order. ar-Fitrahydro-1-saphAyfamilis (7.35 g.) in D deria., violet prisms, in, 107-g- (from abs. Etoij)
XO*
00 Z & cle. dry CJI. and 1). 12 g. Act(). heated an
A c deriv
led
ielded 7
Nrith at3
14
il
5 h
d
0
V bl. max. WA mij. I anti an equiv. arAt. of p-3ofe(:ji,
SUIDAie heated to INHO"
5 firs
iclqlcd 71%
t 2S
.
.
.
.
coo
g.
r. an
y
l
1. 12 s. obtainable from the mother liquor), in. 10(~-L*
-
. Y
UA errw
q
y
salt, in. 2fr2* (from NfeCo); this with lqC(0Ht)l in
ee
YronilltOll). Thi%, txjikA ita.'N) VLrts dry Cjis with 0.3 pyridine as above yiekled 214,/'~ 3X-dimdJEyi_9.eshyj_
.1 mol. PA I hr., trichled. after extri. with aq. NaOll and ' 4A4',5'-bij (tetra meikjkXe)jAi0CaF6oCyUN,iX&Wji~, brown- 4`11111*
fixil priim%. in. 193 rt (train abs. litoll), aln. IZ. nzi
go*
hl.
J
0
1
0
ties
A S N-SL A 1611ALLUAGICAL U111FRATIME CLASSWICATION 94-:! -r. weet
1
W* 0
*0
Noel -4 salas-3 .11 O~v ONE V111116411 oilill ONE 0%. IS[
U 11 Al' 10 it;;
jV IV ON 4C at . 't It a it L N I IN " I Aala 60 3 a
"I I
11111
11
16 000:010000000**0*00660 4100600 0 0 &0 0 0 0
"
:1
40 000 010000000000000000 too006000000000060
600
u
IF
1 I AA. N IZ I
It ... LGL -JL
-1'-* 0
00
6"whaikay, AW L. V. Rosirsdorakaya
S
U
S
68
789
R
.
.
.
.
-
,
,
00
I
whem R Is 11, alkyl, "kyl, or aryl. R, dud R, drt 1(,
alkyl
hukwn
auuny
acytox
oc m nitru
Ar I
m 0 0
00
,
.
.
s
V
p.
j,
an ArawAtic MIUMI
OW a Is
1
or 2
m obt
i
l b
d a
nca
.
. a
.
y
conden*atkm of thissafidine-2-thkme4-otie or its 3-alk
l
y
.
aralityi
of ar
l IIIIAtit"thm
"Xi
t with
l
o -0
.
&w
(Itmiu
l. t
p
y
the :
8414M IS MMW k"At 10 PYV16RIAC At tI%%n W01 0
00
a
09
roo
-00
00
coo
~
t L zoo
!;Joe
z
.A SI
TALLIJ46KAL LITINATLON CLAStWICATION oo
am- cat
u AV go Ail;
,
0 0 4 *Is 0
0 o 0 0 4 0 0 0 0 a a 0
1*see so 0
44 000 0 4D 0 0 0 0- 0 0 e 0 0 0 11 'a 41 0-411
t 14 1
00 A
Sol
t? W is W V 4
1. 1, Lev-
it
toe DclOnOti&2YA and L. 1).
Zht 96, Sept. 30, 1947. In the pro-
duction of tbeoc cyunincs by heating quattr=y salts ID1I
2-mctbyI4,5-bcnrobcnxothja2oIc with esters c4 cmr-
bOxylle acids In pyridine, the prom" ii carficd out in the
presence o( ArA
AIN.SLA "YALLURGICAL WINATU01 CLAMPICATIft
I
A[~ woo* .4 losali w4r O"v oot toe!
U It All 10 IS . 4 F I is P F o
, to tPV or 49 Or a a
00 0 0060 00 0 0 0 0 9 * 0
0-0 0 0 * *is ** 0 0 * 90 0000 0 *
a-?
!-so
46
2 WO*
met
too
.Zed
Cleo
M I 1 0 N 0 0 IN I of to I
0 0 41 * 0 0 a 0 40 00
i-O-S-0 *0 4141e 00 090:0160-ss
LWKOYBV, I.I.; SVWNIKOV, N.N.
-, ~ 7.
Some by-products of carbocyanniue condensation. Trudy NIKFI no.7:
13-16 V. (MIRA. 11:6)
1. Sinteticheakaya laboratoriya Nauchno-isoledovatellskogo kino-
foto-inatituta, Moskwa.
(Gyanine dyes)
LLWOYEV, I.I.; SV3SHNIXOT, N,N,; GORRACHNA, I.N.; VOMFE, A.F.
Optical properties of some thlacarbocyanines with substitutes in
heterocyclic radicals, Trudy NIUI no,7:25-33 147. (MIRA llt6)
1. Sinteticheskaya laboratori;F& Nauchno-iseledovatellskogo kino-
foto-inatitutat Moskva.
(Thiacarbicyanine-Optical propertiosY
sorptiW spectra Of Illerilcy!jBille 114VIIIJ tilt IAASIC
stnicture I, Ui which Ill, itilmitnt-jaxivrn i-i N-vmitg.hrterr~
cycle, xav't the I"lit'"itlK tells ill Hijill and CIRT.
houcture of reterocyaninp dyei. V I. s-evatoev. reslij: Wthids'.1SX0,51:".
ind It. Lif,hil- 'All Union Cine-Photo W, (c) bin==4f "4:21, ;~12. id; trx.-flexavie
jkaj. Vank R. let beitizaAww1e, .1,41: t.f,
1 34.
74 -lictillit. of the, 'it.. -M. 536; (r) *-qhzn, hn, th - tht-j--le 55S. -5:-A: 11
. "mimohme 640, IU5. i r- (k) 1-i'lethvi-
X17. C..thexv.mines ill) limunt -mal.
henzinudar,k -'
524
0 ,
orteus subl it atents rv,p.: 1,,) 545. (6) 44.'.. 4,"o.
CIICII let 4M. 492: (dih7(l. 57s. fr, .67. X1. it)513. 5211: 1~
oil.tilo; ih-41,1:1.5-7iii: ,j 712; Q (ki II.P.
495. As file lusicitv 4 the licterum-le inctca-~. thr
hyp~vhrornic shift drups at fir,1. itirn 1,,-gm, to incrtA~;
E, t thii behaviir - -gurs jg:km~t tite usu.111V acerpted licto-elifill
fonilulatior of Such 41 ve~. Vshich evolild be e%lw(,tm to give*
a unkfirtclional IiyI^(Whr'mIic Alift. Forther r1juill. fit
the specte-3 in Mcoll, L1011, lite' M. CIICL. C-11-- CCI..
and sho"vel lh,a 1%cs I,j-d on 3.3.1iructleviind-
C11 -Clf--Cll ~
'~mrt livIthia, Im, vie. and thi.'anline
beterothLanic
lenine
.
.
show a Anit of file fna%. I-) ~Iiortrr ma%rs i%ith .1,ctejuA
t -Avellf JWPLirity: dyes "ith more, lm~ic groups (thiazole.
I't pyritline, :ind henzintidwolel give a b4thochrotnic shift.
followed by rever-W (allitut the Isuoll "r ClICIF wctwn of
lite %cries). Hence, tile Ist votip of the, rurrocyanines di--
play all aplj:txich toa covalent krto -,tructure. while tornIxIs.
of the 2nd grouls at first al- approath a micturc itarr-
meeliate betm-cii the keto artil the iurne: cuol forell, threet te-
versle thc trend and alljormich tile keto frorin. In aics. the
'tructim" I;Itl" n liprimtheb the ionic forimilitiiin.
9%f7
SWESHNIKOV, N. N.
USSR/Chemistry Photography Mar 52~
"Some Derivatives of Benzthiazole. 111. 2.5.6- and
2,6,7-Trimethylbenzthiazoles," I. I. Levkoyev, N.M.
Sveshnikov, N. S. Barbyn', M. P. Pashin, All-Union
Sci Res Inst of Cinematography and Photograpliy
"Zhur Obshch Khim" Vol XXII, No 3, 19520 Pp 516-521
When oxidized, 3,4-dimethyl thioacetanilide and
3,4-dimethyl phenyl thiourea, through breaking of
the thiazole ring in the o- and p-positi6ns with
reference to the methyl group, form mixtsdf 5,6-
dimethylbeazthiazoles which contain methyl or amino
groups'.. respect, in the "2" yosition. These compda
and some of their derivs were studied.
209T49
Cn
WSSR/Chemistry Photographic Dyes MY'52
"Investigation3 in the iield of Cyanine Dyes, VII.
The Properties, 6f Tetrar~'ethyl ' Thiacarbocyanines,
I. I. Levkoyev, A. F. Vqmpe, N. N. Sveshnikov,
N. S. Barbyn', All-Union Sci-Rec Ginematograph Inst
Zhur Cfbshch Khim, Vol 22, No 5, pp 879-686
Authors produced 23 symetrical tetramethyl thill-
carbocyanines Witt methyl groups in different posi-
tLions on the benzene nucleus of the heterocyclic
radical. -They c1otain6d 2,5.9-f-
trimethylbenzthiazol 'es and some of their derivs. In
the transition from dim~thyl to tetramthyl
2 3T38
C-Mroocyan MIEtauce MR~77ne CLytx
,was shifted to the long-vaire portion of the spectrum
in all cases. The introduction of the m6tbyl groups
at the 5,5' and 6,61 position gives a markedly greater
bathochromic effect.
SVISIINIKOV, N.N.; JEVKOYSV, I.I.: KRASNOVA, T.V.
Action of nitrous acid on o-nothozy-19, N-dinothylaniline. Zhur.
Obahchey Khim. 22, 1170-2 '52, (MLRA 5:8)
(CA 47 no.13:6363 153)
1. All-Uaion CinsPhoto Inst.. Leningrad.
USSR/Cbemistry -Photographic Dyes I Jun 52
"The Action of Almines on Some Thiocarbocyanines Con-
taiming Alkoxy or Alkylmercapto Groups in the Meso
Position," N. N. Sveshnikov, 1. 1. LevRoyev, B. S.
Portnaya, E. B. Lifshits, All-Union Sci Res Cime-
photo Inst
"Dok Ak Nauk SSSR" Vol 84, No 41. PP 733-736
Studied action of primary and secondary amines on
9-alkoxy- and 9-methZrlmercaptothiocarbocyanines
which ~,ielded the previously unknown thiocar*-
bot-j'aiine -~(-b O*'d##. the.;,, amino group -in the -9-
9-butylamino and
232T9
9'Oit6ridi'ne"thio'c"a'rbocyanine's, 3031-alethyl-q-
Phemylamihothibcarbocynniniodide, 1,3-bis(3'
(2), 1,3-bis(31-ethylbenzthiazolinilidine-2l)-
Proponone(2), 9-phenylmethylamino- and 9-acetyl-
Pbenylaminothiocarbocyani,nes. Studied reaction
of meso-alkoxycarbocyanine iodides with ter-
tiRry amines, which resulted in the splitting
Of~ of alkyl halides to form 1,3-disubdtituted
Propanones. Absorption spectra of these sub-
stances show that increasing the electron -
aoner character of the 9-substituent results
in a shift to the lover*vave length. Presented
by Acad V. M.'Rodionov 3 Apr 52.
232T9
TISSR/Chemistry Photographic Aug 52
Sensitizers
"The Influence of Ste'ric Hindrances on the
Color of 5,6,5',,61-Tetrasubstituted, Thio-
carbocyanines," I.I. Levkoyev, N.N. Sveshnikovi
N.S. Barv-yn,, All-Union Sci Res Cinepboto Inst
"Dok Ak Nauk SSSR",Vol 85, xo 4, PP 805-808
A series of 5,51-dimethoxy-6,6,-bis(acylamino)-
and 6,61-bis(N-methyl-N-acylamino) thiocar-
bocyanines were synthesized from quaternary
salts of corresponding 2-methylbenzthiozols
and their absorption spectra measured. This
revealed that introduction of a,methcxy group
227TIP
in the 5,51-position of 6,61-disub 'stituted
thioeexbocyaniner. contg amino or substituted
amino groups results in a bathochromic shift
of the abs max in all cases except 6y6f-bis
(dimethylezaino)-derivs. The anomalous color
of 5.51-dimethcxy-6,6--bis(dimethylamino)
thiocarbocyanines is explained as due to spa-
tial hindrances preventing orientation of sub-
stituents in positions more favorable for theiX
interaction with the basic chromophore. Pre-
sented by Acad V.-M. Rodionov 30 MaY 52.
227T12
SVESMIMOV, IT. Y.; IINKOYEV, 1. T.; ZHIRYAKOV, V. G. t)nd BARVYIP, N. S.
Studies of Cyanine Dyes. 711L On bowe 5, 51- and 6, 6t- Disubstituted
7niacarbocyanines, page 1263, Sbornik Statey po bb shchey ;r-himii (Collection
of Papers on General Ohemls'vxy), Vol II, Moscow-Leninegrad, 1953, pages
168o-1686.
All Union Sci Res Cinematography Inst, Moscow Inst of Fine Chemical Technology
imeni M. V. Lomonosov
f
lie W~- itfi 1 g-, vo) f
'ia .10 int. HG, F.Itcred and tr,~aud wa 0.6 g, MVv(C-14)c in
IcV) uil. F110 u 4-5', yielding after I fir. 0.78 g.
:--I. J20' (frorn LtOll!). lq,~arirlj, 5-
)nlltlic)x-.,-2-iiieth~,lt~-ii7othLizole with fIBr . (d, 1.475)
A lirs. pive SV;~ In.
(frana F"toll). Siuiilufly %,.as prepit. 76% V-4--y-
"try-, -I&-mrotAiefole, I, -2'. '- r
--ntetA2 b, 23' m, 161 1 (0., .)
"and 11.1 ig. Ma in 3 .0- EtOH Licated with 0.74 g, Cl('F[,-
Co--Ft 20 min. to 125-31P, thiu shaki~m out with i% KDR,
klibeii --III
ppive -Itlya 5-carbtflioxyumthox),24nel
picraie,tuAIL9-3 . '.iirallaf.mact'a",
--..,ith guve s6%
1hpixCA" b,.-? 1-10-1 % w base pic"rJel m , 11;7-81. The mie of,
1-!;(',H,Cl Similarly gave tw%
i(com iiarpilic); pic:ale, m. 1~4-5*.
Vilauing 13.2 g. 6-iiydroxy-2-,nethy!Lenzothiazu!,! ~.-ith
1,1.154 g. CICII~CO,Et anct 11.06 g. pawd. K3CO3 i-% dry'
p' lvIe-,C0 A lirs. Live 52%
,Wazw1c, m. .4&-8' (Irvin li&mhm); Picra-le, in ' M-1-5';
rid4iodide, m.: 172-3'; clhiudidc, in. 149-W. Similarly
Aile u" -if Cllj-.CHCH,13r Lave .15% 6-allylvx,,2-h;eilqt-
bi 152*. ut. 31-2- (cf. Ochimi2 and Nishiv,wzj,
CA. 36, 6476, ); PiWdlo~ in. 153-4"; inelAkdide, in.
ahl'odide M. 126-7'. Sinillarly PLCH:Cl Enve d9l,"o C.-
&otiz-vto m 7il-4*; pirraM, in. 144-
AV. me g iodide, ni. 206-7*; ehialls, tn. Heating
0.2 g.
ml. 100/p' KOH 0.5 hr. an a stearri, bath gaee after acWifica-
-no 5- Rod
Ivere Fitaft'A with 5~"' CXCC5.i P-N-lc-:
C.11,903E't 0 hrti. at 140-60' tr, ykld x6t cosmiprialin,
quatv"iar-y m-tft%, wbi,,h nrTe trtatuii with pyr-Win-7 ard the
di;sircd orthricarboxylic acid? c~tcr and ficated I lir, at 13LV-
.5*, the pi:oduct t3kert up in EtOH and trejud with KI
soln. to Yield Ifie following thia~_trbwyanbie iodides (~Ub-
.5tituents Nive.): gmen, d-comp.
2&0'; green, devernp:
grecia, th-comp. - 11:17',
red, de"nip. 212*: 3.3'-
4idhyf-G,6'-di&hOxY, green, decorrip. 2;YJ'; 3,3-dirthy!w9-,
red-violet, cl~omp, 265*; J,j',9-
green, &cornp. 210*; 3,3'-JinrrthyI-
"AWAW-didhoxy, rml, decomp. 231,)*,
dibewyloxy, violct-hrown, c1ccovip. 221*;
red-brown, ds!comp. 2""',
JridhyI4,5'-4ibcHzy!ftVy. blue-violet, dccoinp~ 185'; J,3'-.
dielhA6,6'-dibewyloxy, green, deconip. M'7*;
red-hrown, dtconili. 238*; 3,3',D-
tri4AyI-6,6'-di4k.uyfoxy, blue, docomp. 211'; 3,3'-dimrIhy(-
red-bromm, clecomp. 22.1)*; JX-
~iahyl~S.Z'-dkarbe.,A~oxylrciko.%Y, violet, decamp. '201 *; 3,31-
red-brewn. de-
c=-). 2230: hWe.
decamp. 132',
Oxy. red-trown, dc,~omp. 242'; 3,J',9-iridA)i-G,6':jktjr-
bethorymeth,axy, re-vifAut, decamp. 163';
ell red-Aolet, &cornp. -"W;
green, decamp., 2zo*; 3.3'.
grecu, decomp. 247'; 3,3',-
94riethyl-5,5'-diallytm, green, deccrup. 227'; 3,3'-d~dkyln
6,6'-dLaII>ioxy. green, decamp. 230';
6,6'-d:'aUyIuy, violet, dec