SCIENTIFIC ABSTRACT TROFIMOVA, G.M. - TROFIMOVA, L.L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001756710005-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Peculiarities of solid-phase...
S/020/62/147/002/016/021
B101/Bla6
the solid phase. The following causes are assumed for solid-phase
radiation polymerization: (a) formation of short-lived excited moleculesi
(b) loosening of substance along the tracks of primary particles and
6-electrons, which imparts properties to the substance similar to those
that occur near phase transitions and near the melting point. There are
4 figures.
ASSOCIATION:
SUBMITTED:
Institut kh.imicheskoy fiziki Alcademii nauk SSSR (Institute
of Chemical Physics of the Academy of Sciences USSR)
August 3, 1962
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with which Ns N. Sem-mv has foLloved the work, Z-mS viau Raj their thaaks to
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AUTHOR: -Pmt, E. V.; Troftinava, G. M.; Yenikolopyan, N. S.
f,Tt!^nJP polymerization of liexamet~YLI~.):(2-1-11risiloxane In Lhe solid phase
'Vvllqr)'r,--~mol2kulvari-ty'v-~! suvedinonlya, %,. flu. 11', Ij6-1,
TOPIC TA(-!'~.
P. L~ IT-at-111,-'r A~,
11-Irvelotrisiln.,cme was 1),,)Iyr -rizxW lo, Lhe Il, I SI U11c
1 Ilv I vroiYSIE
I t 7-
A 11 i i
77,~fn ~,Jvn r-rization te. nperawre,
7-
Mol, !j L
11 ell' --ell
ti on. 17-11c~ M-arat interestln~ ri~- qklltr i 11 c
I - 4.
i!-rnt. Phenomenon calmot .~e bv the -xj-;;tjSg theurlpi~ orl
Iza-Hinn Inf4 rl--quir~-, further exu'rsl'.e ~11t~ i 9. 711- c4
0-tg. ?r'. has.- 2 figL res.
Card

BkRK&WV. 1.N OOIZMKrT, V.I., TENIKOWFUR; M.S., TFlDFrHDVA, G.M.,
TEDElaMVA, S.T.
Radiation-inducod solid-state polymerisation.
Parti..Polyme-rization of acrylonitrils.*
PartIl-Polymsrization of vivyl acetates
Various "a of po2ymerization rate temperatures dependence*.
Report submitted for the International 3ymposium of Niscrewlecular chemistr7s
Paris, 1-6 jvay 63

BARKALOV, I.M.,- GOLIDANSKIY, V.I.; YENIKOLOPOV, N.S.; TEREKHOVA, S.F.;
TROFIMCJVA,_~
Specific features of solid-phase radiation polymerization
in the course of irradiation. Dokl. AN SSSR 11+7 no.2.-395-398
N 62. (MIRA 15:11)
1. Institut khimicheskoy fiziki AN SSSR. 2. Chlen-korrespondent
AN SSSR (for Goltdanskiy).
(Polymerization)
(Radiation)

d
(b)
R*dIs1Ilm-ImI~d NlymerInthm of Nilmomers In the Solid 5(4te
I. M-11st-kalar, V.I.
If. 17. tercWts and 0, M. Trollm,"s
The authors in-teiligated the Unatks of the radiation-indixed polyffs.-rization Of A number of vinyl mman"ers
(scntoni(rilc. me hytructhacryfale, vinyl ncetate, formaldehyde), The polymeri7ation was carried out using 1.3
Mev clevrcni. 111c temperature ranze studied (from -196 to 0*Q Included the melting point of the monomer.
'Me temperatureAependence of the polymedization rate near the melting point charged in a v.,4cty of ways. 'Me
polymer yield In Cu: solid phase reached a limiting value with increasing dose. ne influem of phase transitions an
he kinetics or polymerizalfors, was established. The results are Interpreted on the basis or the theory dcvcfopcd and
presented by N. 1%. Semcnov sit the International symposium or Macromoletular Chemistry (Moscow, July 1960),
and at the 18th Congress ct Ilum and Applied Chemistry Mosstreal. August. 1961).
fly- USTP. ltl~,m-

HCA,111TOVY 1-1,; T9, COVA, G.P.-, KCJI~IIAGINA, Y e. F-. ;K ANI.
I _~F'PL _ GIJ IM , ~ A
Gelat,lon [:-rcces--es and ~f
I
Zlhur,.Pr-jkl.kh!-,m. 38 no."'.638-611.3 !~ -I f,-.
I IT .,
O~gpA
1. Submitted Ma--cb 19, 19;~4 -

!T.
M
SCURC-7 CODZ: TTR/r
0'2/6,/ooo/cc6/i 0r,9/10!6
D 0
-A.UTHO. Golubtsov, S. oroo0v V 11 (Deceased);
PoDkov, K. K.
atokaya. R. A., A ndrianov, K. I 't
Tuz- t; Mli k o v a Z . V ;Golosova, H.
Aristova
V. G.
ORG: none
TIM : Reactions of formation of a2kyl(aryl)chlorosilanes in a direct interaction be-
tureen alkyl (aryl) chlorides and silicon. Report 111o. 6. Role of cuDrous qhjqride in
'he forvm~ - cliall
L. tion o.L -- -.1
y1dichlorosilanes
SOURCE: AN SSSR. Izv. Ser khim, no. 6, 1966, 1009-1016
TOPIC TAGS: silane, chloride, silicon compound, copper compound Cllftrlle'll~e-
ABS'MACT: A nechanism is proposed for the formation of dimethyl(diethyl)dichlorosil-
ane and rothyl(ethyl)-',,riel-Aorosilane durin- the reaction of methyl (ethyl) chloride
0
with silicon on cuDrous chloride. The proposed mechanism for the formation of dial!-yl
dichlorosilanos is as foLLows:
Card Ih, UDC: 546 1+
eA-Zt5~ ~-

ACC NRt AP6024019
RCI+Cu-RCf-Cu
2RCI - Cu --~- ZCuCI + 2R
Si + 2CuCI - MCI?. + 2Cu
SLGI, + RGI - CU --- RSiCIz + C11 'd
RSIC12 + RCI - Cu - BzSiCl? + e UCI
CU
Si + 2RCI --):112SiC!Z
The formation of alkyltrichlorosilane is represented as follows:
Si + 2CuCI ---)- SiCIz + 2Cu
SjCI,. + RCI - Cu-b,- RSiCI3 + CU
Zxperimental data obtained confirmed these mechanisms. Therrodynamic calculations of
the initial stages of the reactions of methyl and ethyl chloride with silicon were perl
formed. The formation of dichlorosilene is thermodynamically quite probable under the
conditions of syathesis of alkylchlorosilanes. Ulf spectra of the products formed by
the reaction of culDrous chloride with silicon showed a group of bands characteristic
of the sneatrum. of-SiCl?. Orig. art. has: 2 figures and 5 tables.
SUB COD,-,.' 07/ SUM DA7-r,; 12Feb64/ ORIG REF: 008/ OTH REF: 012

TROFIMDVA, I.
A Polish miner, Marian Pszebyt7nski. Mast, ugl. 5 no.8:
22.,-24 Ag '56. OLRA 9:11)
(Pszebytynski, Marian)

41724-65
_41. '13
Author Cer.ifAaAtgk -~,rppcmtg
in-
i aone
M; I flum
all NWX251 a

47000-66 EWP(k)/i~14T(d)/E11T(m)/94P(w) IJP(c) M/RIX
ACC NR" AR6027168 SOURCE CODE: UR/0264/66/000/005/A008/Aoo8
AUTHOR: Aleksandrov, A. Ya.; Trofimova, E. P. -2 t,/
ORG: none
TITLE: Local stability of three-layered Plates with honeycomb fillers at longi-
tudinal compression
SOURCE: Ref. zh. Vozdushnyy transport, Abs. 5A50
REF SOURCE: Sb. Raschety elementov aviats. konstruktsiy. Vyp. 4. M.,
Mashinostroyeniye, 1965, 5-18
on
TOPIC TAGS: stability, honeycomb structure, elastie deformation, compressi
ABSTRACT: A study has been made of the local stability of three-layered 21~tes i
with honeycomb fillers, having 6-face and 4-face cells, under uniform longitildinall,
compression of the plate in one and two directions. Equations have been obtained
by an energy method for determining critical loads. The results obtained extend
to a region of elastic-plastic deformations and are verified by experiments. Com-,
Card 1/2 UDC: 629. 13:539. 4:620. 1

L 47000-66
WC-Cl4k, -A-R6027 168
parisons of critical loads were also carried out for plates with 6-face and 4-face
honeycombs. Orig. art. has: 8 figures. Bibliography of 3 titles. [Translation of
abstract). [NT]
SUB CODE: 11 V
IV-Id 2 / 2
Card

SM DRATIMT, 1. S., -AOID FRIST-2;Al R. A.
Dr2vert, I. S., Pristina, it. A., and Trofimova, I. L. "An
2n2lysis of V~e illness rate of scarlet fewr in the city
of Kirov in the post-war period," Trudy Kirovskogo in-ta
epidemiologii i m1krobiologii, Collection 2, 1948, p. ~4-1021
- Bibliog: 13 items.
SO: U-3736.9 21 May,53, (Letopis 17jxrn2I Inykh Statey, No. 17, 1949).

MhVUU, 1. S., FRISTINA, R. A. and TkOFILIOVA., 1. L. "An analysis of the illness rate of
,,!,-Iem-
scarlet fever in the cit-37 o--:' Kirov in the post-War :period, " Trudy Kirovs,Co,-o in-ta e -'-' -
iologii i mikrobiologii, Collection 2, Ic/48, p. 0/4-102, - Bibliog: 1-3)
SO: U-3736.1 21 May '53, ~Letopis 'Zhurnal InykIi Statey, No. 17, 1949).

MANt, K.T&;YXRIVANSKAYA. L.&.: TROPIROVA. IlVQ._"_.
Mechanism of the catalytic dehydrocyclization of paraffin hydro-
carbons. Doklady Akad. Nauk S.S.S.E. 82, 9rl3-16 152. (YT.RA 5:4)
OA 47 no.13:035 133)
1. Institut tonkoy khimicheskoy takhnologii imeni K.Y. Lomonosova,
Moscow.

"A Study of tho Kinetics ,jjcj Roactioil NachmAl' 'nil of Via L1,0apic Fkchange of 1~fdroT
carbons With DevtceLum in the Pr,-:;erice of zi Cataly, st.- Chromiwa Oxido an Xlumirium C/.Ide."
Cand Chem -'-'ci, Order of the L.~bxr RrA 3amner 3ci-Res P~V5iconi-erAcal Inst ilreni L.
Karpov, 17 Jan 55. M11, 6 Jan 55)
Survey of Scientific and Technical Dissertations Defended at USSR 111gher
Educatioual Institutions (13)
SO: SUr- IT 'S, 29 Jul 55
,L. 1..o. 59 -1

AIA

USSR/ PhysicaLlChemistry Kinetics. Combustion. Explosives. Topochemistry. B-9
Catalysis
Abs Jour : Referat 2hur ntmiya, No 4, 1957, 11M
Author : Andriano* K.A., Golubtsov S.A.9 Trofigova, I.V.., Denisova A.S..,
T&Litika;ki R-A--
Ilist" : Adadifay 6f -Sdi;n6ii !USSR
Title : On the Role of Copper in the Reaction between Ethyl Chloride and Silicon
Orig Pab : Dokl. AN SSBRI 19560 108, No 3, 465-468
Abstract k'study-wad i6de of'thd influence of Cu;:~6nteht 6f -silicoii-~cop~er &llbys
on-their interaction vith-C Cl (I);-amaong the-rea6tion. prodxi~ts w~r6
found ~ -) - iumbar
-Ce5S'HC'P-
of - liquid eKd gasi6ud '~roaiic s. tal~tfii
tid'6ji the-bdiis-6f"thi C'O-i-ite-n-t,-,"'iu*"thi'ro-A;-~ti6ii pfo"6td,--O-f -3:1','-'the--for-
mation of vhich takes plade- a6d&iding t6'thi'mo6t idvdiitdgi6ui-r'6ac'tioai
Wg,--Cl-~, Si ----iiiVdIvihg-zio ioi6 Of-oiOiLIi:'r4&Cal8-.- -Vith--
5
diciiis6 in-Cu-coi2el R- T94"allo~'ftom' 70'to 5%.,''c6utint ofll'iii the'r'e-
6:6tibli-pi6"~ts"i-n-ar'e'a-se-'s 66ji'20'to 45-50% It'is ihoifi thit d3r6j-in car
talytic activity'of alloys with high Cu-content is due not to thermal
1/2

USS~/ Mysical Chemistry Kinetics. Combustion. Uplosives. Topochemistry. B-9
Catalysis
Abs Jour Referat Zhur Khimiya, No 4, 1957, 11292
de6omposition of products (vhich is slight under the conditions of the
iynthesis),*but to catalytic decomposition of I in the presence of Cu,
according tp the reaction-.- C-U,
CA-Cl ---,~C!2~4 + HC1 and subsequent reactions: C2 Cl + 2HC1 4 Si
H5
7
C05s'al 3 + H2 and 2C,)H' cl. 4Hci - si -CL, -~ 2c2H5siHcl2 + ~2-
5
2/2

.- I
,. t I
I.I

vl .7. v~
AUTHORS - '*rylov, V.D. , Yef remoy, Tu.N. 76-11-22/35
TITLE: The Structure of Cu-Si Alloys and Their Catalytic Activity in the
Reaction with Chlorethyl (Struktura Cu-Si splavoy i ikh kataliti-
cheakaya aktivnost' v reaktaii a khloristym etilom)
PERIODICAL: Zhurnal Fizicheskay Khimii, 1957, Vof.31Nr 11, pp.2522-2525 (USSR)
fiBSTRAM The phase composition of silicon-copper alloys (20-35% Cu) and their
modification in a reaction with ohlorethyl was investigated by the
X-ray method. It is shown that all alloys of this composition, in-
dependent of their activity in the aforementioned reaction, have a
two-phase stxuoturei a silicon and a cu si (q-phase). It is shown
that in the case of interaction with 2orethyl the silicon con-
tained in the intermetallio compound cu3 Si reacts in the first moment.
This leads to the destruction of the given compound and to the forma-
tion of metallic copper, which is now the catalyzer of the further
process of ethyl-ohlorine-silone synthesis. The copper separated
settles on the surface of silicon particles and deteriorates contact
with chlorethyl, which is bound to lead to a decrease of the alloy-
ing activity. It is shown that the difference in the case of a be-
Card 1/2 ginning activity of Cu-Si alloys in the reaction with chlorethyl

76-11-22/35
The Structure of Cu-Si Alloys and Their Cataly-tio Activity in the Reaction with
Chlorethyl
is connected with the difference in reaction velocity between
ohlorethyl and the silicon contained in the intezmetallic compound.
The investigations connected with the chemical part of the pro-
cesses mentioned were carried out by 1J.Trofimova and R.A.
Turetakaya. There are 6 figures and 7 iie?e-renoes, 3 of which are
Slavic.
SUBMITTED: August 27, 1956
AVAIIMLE: Library of Congress
Card 2/2

AUTIMS: Andr-'Lano-, X. A., Gclul~ti~olt, S. A. 62-2-r/25
Trofino-.,.... T. V.. .2. V. D..
TITLE: On r,;f 11lie Ca~~-J~rti lct*vity f Sil con-
-00-0, A", lo-s il P-_,oc~~3s o-' D-r--,ct Syntliesia of Ethyl-
per I ~ I, JL -
chlorosilanes (0,1- i-_m;eno11iy?,':h %Etali.tichec3';:oY a7ctivnosti
kremn-a-modny',-h IT pryvj:iuC;o sintez-a etil-
khlorslilanov) .
PERIODICAL: 1~:veatiya 1"14 S"SSR Otdc~ieniyeKhd.-- *Jc1,.eG':i1zh Ja-,fc, 1958. _TTr 2,
pp. !'57-165 ~USS;t)-
ABS-22ACT Th-,~ direct synthe3is of all:yl- a-ad arylchlorosilanes by the
influenc.e of 'Clla haloid derivative upou elementary silicon
i_ the of a catalyst was already described
se-.reral papers.. But only scazce and insufficient data ex-
ist on 4.hc, 'L&~,t t"hat the a~;tivity of the 3ontart sili,;on-
-copper maaj slowly dt2c:!._-.ass~~ in "lie process of synthesis.
Concrete reports on t1he reao0r. for the modification of activ-
ity have hith,~rto not been publish-ad. In the present paper
the following is said on the result of the eyperiment: It
was found that in the interaction of the sili con- copper
Card 1/2 alloyo w-fth ethylene c.11oride their activity is lighly re-

On -the Modif.-1.cations of the Catalytic Activity of Silicon- 62-2-5/28
-Coppe-" Alloys in the Process of Direct of Et;iylchlorosilanes.
duced, i.e. to the exteat to which silicon enters into re-
action (formation of Q-thyl-chlorosilanes). It was found that
for alloys with a lovi content of co-oper (5-91"-) the lines of
the. -eneral actIvity in the reaction of the formation of di-
ethylchlurosili:%ne rLin crrer 2 inaxima. In alloys with a high
copr.-ir-conte.nt 'ev2511~J) th~-; of only one selective
maximum -and cne maxi:,ium of the generaj. activity was determin-
ed. It --s assumed- that ths interaction of et'kyl chloride with
silif;on-copper alloYs is co-.iposed of two parallel -,rocesses:
aN the reactiz)n --with silicon. of the intermetallic com-lound
Cu Si with sii.:ultaneous separation of active copper; b) re-
3
C10
.ion
with free silicon in the presence of the separated
c 0 r. ly
.Per as cata" st. On the baais of this hypothesis the
variability for alloys with a diverse content of copper can
be explained. DurinE; the reaction carbon is to a consider-
able exteat dc-,'.o2ited at the surface of copper which may also
contribute to a decrease in t,,,e activity of the mass. There
are 2 fignreu, 7 tables, and 5 Slavic references.
SUB1,2ITTED: AuE:ust 22, 1956
AVAILABLE: Library of Conrress
Card 2/2 1. Silicon-copper alloy catalysts 2. Ethy1chlorosilanes-Synthegis

SOV/80-59-1-A2/44
jM1103- Andriano7, K.A., Go-lubtsov, S.A., Tishina, Y.N. and Trofimova,
i.V.
TITLE.- Direct Synthesia of' Pheri,' ltrichloro:3ilane in a 'IPIuidized" Bed
(Pryamoy sintez feniltrilhlorailana Y "kipyashchem" sloye)
j
PERIODICAL: Zhurnal urikladnoy khimii, 1959, lir 1, pp 201-207 (USSR)
A13STIULCT- The authors investigated the synthesis of phenyltrichlorosilane
out of chlorobenzene, hydrogen chloride and silicon in a "flu-
idized" bed in the presence of copper and iron as catalyzareat
a temperature of approximately 6000C. The experiments performed
showed the possibility of attaining the high efficiency of the
process, the satisfactory yield of phenyltrichlorosilane,. ap-
proximately 11 g from 100 a of the contact mass per hour, and
sufficiently complete utilization of silicon,