SCIENTIFIC ABSTRACT VARGA, Z. - VARGANOVA, A.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001858620005-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

HUTILS, ITire, Dr.; ZSAMBNKY, Pal, 'Dr.; VAWA, Zouzaa, Dr.
Data on the dia&nwals and therapy of solitary liver absceseas. Orv. hetil.
99 no-33:1347-1150 17 Aug 58.
1, A Van Regyei Tannes *Narkunovszky" Xorhaza I. nz. Belgjogyanzati
OnxtalynnAk (foorvos: Vusarhelyi Bela dr.) so Rontgenonztalyanak (foorvos:
Hutan Imre dr.) kozlemenye.
(LIM, abscess
solitary, diag. & ther.. case reports (Hma))

SZUCS,Sandor,dr.; HYIMY,Gaza,dr.I_YALIq~tZoltah.dr.; GAAL,Jozaaf,dr.
Bronchographic aspects of emll bronchi in tuberculosis. Tuberkulozis
13 no.2.-47-50 7 16o.
1. A Budapeati Orvoctudomanyi Z"4tam Tudogyogynezati Xlinika
(iga2gato: Kovate,lareno,dr. egyetemi tanar, az orvoetudomnyok
daktora) kozlemenyo.
(TUBnOUIMIS PUIMONARY radiogr. )

HOILANYI, Janos, dr.; KERENYI, Imro, dr.; VARGA, Zoltan, dr.
LYMPhocYtoma in the 'lungs. Mag7. Bebeszet 14 no.3:171-176 Je 161.
1. A Budapesti Orvostudomanyi Egyetem TudogTogyaszati Klinikajanak
(igazgato: Kovats Fereno dr. egyetemi tanar)., a II. sz. Sebeszeti
KI-tn-ikanak (megbizott vezeto: Stefanics Janos dr. egyetemi docens)
es a MAV Egeszsegugyi Intezmenyek Budakeszi Tudog7ogyintezetenek
(igazgato: Nyiro Jozsef dr.) kozlemenye.
(LUNG NEOFLASMS case reports)
(LYMPHOMA case reports)

VARGA HASzoNITS4 Zoltan
Moisture conditions of soils cultivated according various methods.
IdoJaras 64 no.4.-238-242 Jl-Ag 160. (EEAI 10:2)
(soils)

--V~A HMONITS, Zoltan
Soil temperature diapersion. Idojaras 64 no.6075-376 160.
(EW 10:7)
(soils)

VARGA HASZONITSP Zoltan
fttreme values of Boil temperature of Boils variously cultivated.
Idejaras 64 no.3:181-183 my~e 161.

VARGA HASZONITS, Zoltan .
I
Air and soil temperature in Holland botbeh vi various
heating systems, Oroz meteor int boos tud kut 25:273-277
161 (publ.162).

MORVAY, An.na; VARGA IIAg0!!Jq4,-ZQIImn-
Daily course of plant temperature in a Holland bed. Idajaras 66
Ob-4:248-249 JI-Ag .162.

VABIGA HASZOIIITS., Zoltan
Temperature of grassy and rolled soil. Idojaras 67 no.3.178-
179 My~e 163,,

VAROA WZONITS, Zolt4h
'l. I ~-;4 I.:", 'T -, -,
Hungarian agror~o~eorologistS in the -Zowiet Union. Idojaras 67
no.4.*256 Jl-Ag ~ 163. - .-

VARGA HASZONITS11 Zoltall
"
Times of surface
ineteor int beaz
frosts in tile late spring and early fall. Orsz
tud kut, 26,305-310 162(publ.163).

VARGA-MANYI, Piroska; TIGY1, J.
Separation of muscle eXcitation from contraction. Acta physiol.
acad. sai. hung. 22 no.3/4:287-291 162.
1. Institute of Blopbysics) Medical University Pecs
(MUSCLES) (PERFUSIONS

KAUCR, Gyorg3r, ; VARUDY, Iaszlc).
I-: -: -:.%.
J)irect rapid filter partition electrophoresis with Palfrich
photometer. Kiserletes orvostud. 7 no.2:212-215 Xar 55.
1. Budaposti Orvostudomanyl Egyetem Baboaztovabbkozo Klinikaja.
.
ion,
(BLOOD PROTEINS, determinat
slactrophoresia with Pfalfrich photometer)
(FJMTROPHMESIB I
of blood proteins, with Palfrich photometer)

5.3630
S 071/7 D0
AUTHORSt Sarycheva, I. K., Vargaftik, M. N., Utkina, 0. V.,
Preobra-zhenskiy, If. A.
TITLE: Investigations of Lipides. IV. Study of Unsaturated
Glycerldeo U21ng Paper Chromatography
PERIODICALs Zhurnal obshchey Ichimil, 1960, Vol 30, Nr 3,
pp 1048-1050 (USSR)
ABSTRAM Identification and separation of synthetic glycerides
was studied using paper chromatography. A previously
described procedure (H. Schlenk and others, J. Am.
Oil Chem. Soc., 34, 377, 1957) was used. For the
monoglycerides of oleic (A), linoleic (B), and
linolenic (C) acids, the following R f were obtained:
0.70, 0.81, and 0.91. The R f values obtained for the
investigated triglycerides are given in Table 1 below.
Card 1/3

Investigations of Lipides. IV
78309
3 011//79-.'qj CJ -3 -63/6.;
Table 1. Rf values for, triglycerides.
Key: (a) Triglyceride; (b) Number of double bonds;
~L) linolelc acid; (S) stearic acid; (0) oleic acid;
Ln) linolenic acid.
Card 2/3
b
4 010
SLL (11) 4 OA2
LOO fill) 4 0.16
sl.no (IV) 4 0.20
1,01, (V) 5 0.24
1.1,1, JV11 6 0.26
SLOm (VII) 6 0.32
1.nSbi Will) 6 0.40
LI'111' OX) 7 0.47
I X) 7 0.49
Unim (Nii 8 0153
I.AnLri (XII) 9 0 618

v L; f~' Irj
t I--! ('I -ated afid IdE.-rit-Ified by
the abovi-, There are 3 flfrul'es; I table;
and 6 2 U.S., I U.K., 1 Swio3, 2
Soviet. Tihe U.S. and U K. referenceo are: D. Chapman,
A. C. Davle;.,~, J. Chem. ~Oc., 1502 (1957); J. W.
Dieclcer!', R. Rel,,7er, J. Ant. Oil, Sou., -33, 123
(1956); if. Schle-nk, 1. L. Gelleinan, J. A. Tillotson,
H. K. Mart.---old, J. Am. 011. Chem. Soc., 34, 377
( .1 c--) 57 ) -
ASSOCIATION; Moscow Institute of
(Moslcov;;Iciy institut
tekhno1,),.r.L1)
SUBMITTEDr January 6, 1959
Fine Chemicals Technology
torLkoy khimicheskoy
Card 3/3

81862
3/020/60/133/02/35/068
,-6>7 3.2 0 0 B016/BO60
AUTHORSt Moiseyev, I* I., Var ftik, M. 1,,-Syrkin, Ya. K., Corre-
sponding Member of AS USSR
TITLE: The Mechanism of the Reaction of Palladium Salts With
Olefindlin Hydroxyl-containing Solvents
PERIODICALt Doklady Akademii nauk SSSR9 1960, Vol. 133, No. 2,
pp. 377-380
TEXT: In the authors' opinion, a participation of the HO ions in the
reaction mentioned in the title appears to be little probable. Under the
conditions mentioned'in Ref. 1, the reaction of the q-complex with the
HO*- ions is evidently accompanied by another reaction with the halide
ions. This reaction leads to the formation of organohalogen compounds
which are fairly stable under experimental conditions (the concentratio 11
of Br- or Cl- was 1010-1012 times higher than the OR- concentration,
Ref. 1). Reverthelesa, such a scheme does not explain satisfactorily the
high selectivity of the oxidation process in which the yield of the
Card 1/4

The Mechanism of the Reaction of Palladium
Salts With Olefins in Hydroxyl-containing
Solvents
81862
5102016011331021351068
B0161BO60
carbonyl compound attains 95-99%. It may be rather assumed that the
charge of the nucleophilic particle attacking the C-atom of the olefin
double bond does not play any essential part, and the addition of the
HO ion takes place by reaction of the IE-complex with the solvent
molecules (2). Basic data on the mechanism of the decomposition of the
Tt-complex can be obtained by studying the reaction between PdCl and the
olefins in nonapeous solutions. The authors' experiments reveaied that
the (PdCl 2oC2H 4)2 comPlexisyntbesized by the method devised by M. S.
Kharash (Ref. 3), which reacts instantaneously even with atmospheric
moisture, remains unaltered in a glacial acetic solution for even 10 days.
This complex is rapidly decomposed in solutions of ethyl- as well as
benzoyl alcohol and phenol. Experiments conducted by the authors further
revealed that palladium chloride in acetic acid solutions containing
oodium acetate is reduced by ethylene according to equation (3). The yield
of vinyl acetatelis 97% if referred to the reacted ethylene. The
(PdCl 2* C2H4)2 complex also reacts with sodium acetate in glacial acetic
acid to form vinyl acetate. In the presence of substances capable of
Card 2/4

81862
The Mechanism of the Reaction of Palladium Salts S102016011331021351066
With Olefins in Hydroxyl-containing Solvents B016/BO60
oxidizing the palladium developed in the reaction, reaction (3) can be
evidently used for the preparatory stage in the production of vinyl
esters. The overall reaction in the presence of benzoquinone (see
scheme) shows that also palladium is oxidized besides reaction (3). The
authors' experiments further revealed that the above-mentioned complex
reacts readily with alcohol and yields acetal as the main product (4).
In the presence of p-benzoquinone, the reduction of PdC12 is accompanied
by an oxidation of metallic Pd by way of ethylene in alcoholic solutions.
This makes it possible for this reaction to be utilized in the direct
production of acetals from olefins (see scheme). Also copper-salt
solutions can be used as oxidizers in alcoholic solutions. The data ob-
tained confirm the opinion that the decomposition of the H-complex in
the hydroxyl-containing solvents takes place by way of the intermediate
formation of vinyl compounds. The information supplied by the authors
does not answer the question as to which of the two reactions (conver-
sion of the 11-complex into I or into II) represents the first stage of
the decomposition. However, the assumption of conversion of II into a 1W
vinyl compound proceeding more quickly than the acidolysis of II, and
Card 3/4

81862
The Mechanism of the Reaction of Palladium Salts S102016011331021351066
With Olefins in Hydroxyl-containing Solvents B016/BO60
the other assumption of reaction (2) representing the first stage of
decomposition, are held to be less probable. There are 4 referencest
2 Soviet, 1 American, and 1 German.
ASSOCIATIONs Moskovskiy institut tonkoy khimicheskoy tokhnologJ.i im. 11~r
M. V. Lomonosova (Moscow institute of Fine Chemical
Technology imeni M. V. Lomonosov)
SUBMITTED: April 23, 1960
Card 4/4

VARGAFTIK, M.N.1 MOISEYEV, 1J.; SYRnNj YajK6
Kinetics of cyclohexane pxidatiOn-by paIWIum salU in aqueous
solutions. Dokl. AN SSSR 139 A0.60396-b" Ag 161.
(MIU 34:8)
lo Mopkovskiy institut tonkoy Aimicheekoy tekhnoloAli im. M.V.
Lomonosova. 2& Chlen-korTespondent 'AN SSSR (for SyrkZT.
(Cyclohexane) (Oxidation) NlWiun chloride)
-a,
as~t i

VARGi,,-',,'TIK, M.N.; 1,101ISEnV, I.I.; SYRKIII, Ya.K.; YAKS11.0, V.V.
Formation of allyl eaters in the reaction of high -er olefins with
palladium chloride in oolutiona of anhydroun carboxylic acids.
I2v. AN SSSR. Otd.khim.nauk no-5:930-931 My 162. (MIIV, 11 :6)
1. Institut tonko khimicheakoy to'chnologii im. H.V.Lomonosova.
(Olefins~ (Palladium chloride) (Eoters)
-M 2
.0E."

VARGAFTIK., M.N.; MOISEYEV, I.I.; SYRKIN, Ya.K.
Kinetics of ethylene oxidation by palladi= oalts in
.aqueous solutions. Dokl. AN SSSR 147 no.2-399-40;2
N 162. (MIhA 15:11)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii
im. M.V. Lomonosova. 2. Chlen-korrespondent AN SSSR
(for Syrkin).
(Ethylene) (Oxidatic#)~,(Falladium sata)

MOISEYEV, I.I.;_VARGAFTIK, M.N.; SYRKIN, U.K.
Kinetic isotope effect of ethylene oxidation by pall-dium chloride.
Izv. AN SSSR. Otd.khim.nauk no.6:1144-1145 Je 163. OaFIA 16:7)
1. Institut tonkoy khimicheakoy tekhnologii imeni Lomonosova.
(Ethylene) (Oxidation) (Palladium compounds)

VARGAFTIK M.N.; MOISEYEV,-I.I.; SYRKIN, Ta.K.
Effect of chlorine ions on the rate of oxidation of ethylene by
palladium chloride in aqueous solutions. Izv. AN SSSM. Otd.kI-Ain, nauk
no.6:1147 Je 163. (MIRA 16:7)
1. Institut obshchey i neorganicheskoy khimii AN SSSR.
(Ethylene) (Oxidation) (Palladium chlorides)

MOISEyEV, I.I.; VARGAFTIK, M.N.; SYRKIN, Ya.K.
Kinetic stages of etbylene oxidation by palladium chloride
in aqueous solutions. Dokl. AN SSSR 153 no.1:140-143 N 163.
(MIRA 17;1)
1. Institut obshchey i neorganicheskoy khimii AN SSSR.
2, Chlen-korrespondent AN SSSR (for Syrkin).

140ISEYEV, I.I.; VARGAFTIK, M.V.; SYRKIN, Ya.K.
Equilibrium of complex-forming process between palladium chloride
and ethylene in aqueous solutions. Dokl. AN SSSR 152 no.1:147-150
S 163. (Wn 16.. 9)
1. Inatitut obshchey i neorganicheskoy khimii im. N.S.turnakova
AN SSSR. 2. Chlen-korrespondent AN SSSR (for Syrkin).
.(Palladium c(tpounds) (Ethylene)

MOISEYET, I. I.j'.VARGAFTIK, M. N.; SYRKIN, Ya. K.
Newjr-allyl complex of palladium. Izv AN SSSR Ser Khim no. 4:
775 Ap 164. (MIRA 17:5)
'K -Complex of palladium with triphenylcyclopropenyl. lbid.:775-
776.
1. Institut tonkoy khimicheskoy tekhnologii im. M. V. Lomonosova
i Institut obshchey i neorganicheskoy khimii im. H. S.
Kurnakova AN SSSR.

BIUDVP A.F.; VARGAFTIK, M.N.; MDISEYI'-'V, I.I.
Bromination of//-allyl complexes o.f palladium. Tzy. AN
SSSR. Ser. khim. no.3;1551-1552 Ag 164. (WIRA 17.9)
1. Inatitut obshchey i neorganichaskoy khimii Im. Kurnakova
AN SSSR 1 Institut tonkoy khimicheskoy tokhnologii im.
Lomonosoira.

MOISEYFV, I.I.; WaGPY11K, M.N.
Carbwtium Ions in the reactions of oxidation of olef'.rs by
palladium chloride. Izv. AN SSSR. Ser. kh1m. no.42759L-760
165. (MITRA 18,5)
1. Institut obshchey I neorganicheskoy khimii im. N.S,Kurnakova
AN SSSR.

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Ocaduotivity, Thermal
Temperature Measurements
01~,elatlcn Of Therml Cmductivity of CAses io Temper.;
ature," N. D. Vargaftik 0. N. Oleshchuk, Pbysioo-
tdohnical Iaboratory, 91 Pp
VIzvest vTr No 6 (134)
'Brief general description of the forwiUs vhIch are
use& to caloulate relationship of thermal ocnduativity
to temperatare. Dismses methods of meamwament and
desoription of experimentea eqAxlyment, resu.1ts of the
measurements, and evaluation of the experimental re-
Pults Iments arkjj&3
to Ica1%'%oraZOz7$ jogo?X on at the I?hysico-
,ohn or XDSUcerI4
3 2

VARGAFTIK, N.B.; GOLUBTSOV, V.A.; STEPAMNKO, U.N.
[Electrical method of determining moisture content in petroleum-
products] Mektricheskii metod oprodeloniia vlashnoBti nefte-
produktov. Moskva, Goo. izd-vo tekhniko-teoret. lit-ry, 1947.
58 P. (MLRA 7:2)
(Petroleum products)

U4
3~7~,/Chemlstry - Electrolytes Feb 1947
Ch-e-nistry - FMuls1(,ns
OTbe Influence of the Concentration of Electrolytes Ir, Water Pnoent in OV. oi- the
Dielectric Convt~zt of the latterg I" It. fl. Sterawnk4j 17. B. Vargaft1k, I-4-Of I.Vevo
Fbyslas Laboratorys, Institute of Construction,, lbosovets, 2 pp
"Kolloldnyy Zhurnalu Vol IX,, No 2
Several scientists# among Mom Ftenkell have advanced the t1wory t)-at It might be
povoible to app],Y Uolubtwvfs electrical metbod fGr determining the mlsturs content
of jmtrolaum products. As a reaultp t~* authors deacr!tA the axperk-ente which t1my
conducted to detemlno the offect of t1v eoncentraticm 6f electrolytevo In water ubldh
lo founa in oil, and tho effect this i=s or. the dielectric constant cf the ollo In
the experiments'the dielectric connotant let.-rm'ned the Capecity of the CorAbn-sor.
PA 34711

Vtti~AFTiK, 14. B-
Gases - Thermodynamics_
Jan 1947
"An'Antineientific' Book on ThOrmDdYnwdOSpI'
N B Vargaftik,, M A TAcntovioh and M P shirocov, 6 pp
112hum Tekh Piz" Vol XVII, No 1
7he author in the revised book famulates a now
law of therml capacities according to vhich (at
00 Centigrade) for gases ancl vaporst,;v = 2.2-0075
Cal/degrees, Formila for solid-and-llquld bodies
also given.
gT36

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nurl = V. V. Kambestay 9 1 Im. S. Onhhoni-
xhim. 24,
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IU ad. pumugm of HOAr mW K X 10-6am. 0, 41,2;
2D.40.0; 40,41.1; OD.41.9; 9D,48A,,:4100 409ciLl./
W. 1?~-
cm. ow. d"m. M;,.

VA;~GAFTIK, N. B. -- `T"El~?'AL IVITY OF CCf-,FrE:n~-Cr, t E~
-Arz r~2 , F owcr, Eur i tirc, i Nl~~ I N7,T I PF N I G. P. i'Q I DIAMOVI~V, I Y , A CAD C II-,T AT
FOR THE 0C45RCE OF DOCTOR m TFcHmfAL jCIFhCF!-,)
30: VECHER?JAYA MOSKVA, JA.'IUA.-7Y-DZccmoEr, sr4-2

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?1W;IkITf. uf hl%it intvy'hiced throtigh the Ug. The
fir"'I ~'11, wa, liv,
a~nrvd with :1 nj(~lirwd a.tw:il,f
'I lit_ 11 Nl;t~ IIivA%ijT,.,1 ill all "C:
M. 'Sirmlwy

VARGAITIK, N.B.
Dissertation by N.B.Vargaftik "Heat conductivity of compressed gases and
liquids." Izv.AN SSSR Otd.tekh.nauk no-5:790-791 My 153. (mT.RA 6:8)
(Vargaftik, M.B.) (Heat--Conduction)
Work is the Dbators dissertation at the All-Union Thermal Enoineoring
Institute imeni Dzerzhinskiy in 1951.

VARGAFTIK,N.B.. doktor takhnichaskikh nauk; OLZSHCHUK.O.S., inzhener
Heat eapacity of slagis of different fuels. TeplosaargetIlra 2
no.4:13-17 AP '55. (XLHA 8:9)
1. YeesoyuzVy teplotekhnicheakiy inatitut
(slag)

VARGA FTI.X,--N -B.,, professor, redBktor; AYZ3CfSfl2AT. I.I., redaktor; FRIDKIN,
A.M., tekhnicheskiy reduktor; YOROIFIN. K.P., takhaicheskiv redaktor;
IARICHOY, G.Teso tekhnIchoakiy redbktor
[Thermophysical properties of substances; a reference manual) Teplo-
f12icheskie evoistva veshchestv; apravochnik. Pod red. 11,BxVargaftika.
Moskva, Goa* energ. izd-vo, 1956. 367 P. (HLTtk 10:1)
1. Moscow. Voesoyuznn teplotekhnicheakiy lastitut.
(Thermodynamics)

AID P - 48oo
Subject USSR/Engineering
Card 1/2 Pub. 110-a - 3/17
Authors Va Dr. Tech. Sci., and Yu. P. OsIminin,
-4a"Pffda.- Phys.-Math. Sci.
Title Thermal conductivity of water solutions of salt;3, acids
and alkalies.
Periodical : Teploenergetika, 7, 11-16, Jl 1956
Abstract : The authors present the results of experimental research
of various solutions for a wide range of concentrations.
Detailed investigations of the thermal conductivity of
electrolytes at different concentrations and teriperatures
are described, as well as the experimental equipment and
the methods of measurement. The use of the same equations
for liquids and electrolytes is discussed. Tabi.es,
diagrams, 12 references k9 Russian).

USTS~~ia~`Mechanic' s
Abs Joui,: Ref Zhur-Mekhanika, No 5, 1957, 5714
Author Vargaftik, N B Smirnova, Ye. V.
Inst
Title On the dependence of the thermal conductivity of steam
on temperature,
Orig Pub: Zh. techn. fiziki, 1956, 26, No 6, 1251-1261
Abstract: The thermal conductivity of steam, , was determined by
the method of a heated filament (1), and by the method
of coaxial cylinders (2), in the temperature range of
up to 6000 and at a pressure of 1 atm. abs. Correct-
ions for extraneous heat flow did not exceed the follow-
ing magnitudes: 2 percent for loss of heat from the
ends of the measuring wire, 3 percent for radiation
from platinum wire (at 5000). The results obtained
agree very well with data on :~, from previous experi-
ments conducted at the All-Union Power Engineering In-
stitute (VTI). measures were taken to decrease Sub-
Card 1/3
USSPt/Fluid Mechanics
Abs'JOUr: Ref Zhur-Mekhanika, No 5, 1957, 5714
Abstract: stantially any extraneous heat flOW from the region of
measurement; for example$ centering devices were re-
Moved from the region Of measurement itself, and protec-
tive heaters were installed at both ends of the region.
The internal system of cylinders was centered relative
to the external cylinders with the aid of six cones of
high-melting glass (clearance between cylinders was ap-
proximately 1 mm,). Regulation of the electric heaters
in the Protective cylinders made it Possible to maintain
a texape' ture difference of 0,1- 0
and extera M between the interior
rior cylinders. Axial flow of heat (loss) in
the equipment for method (2) through the rods connect-
ing the cylinders.. through the gas layer (5 Mm thickness),
through the thermocouple wires In Porcelain tubes, and
through the 10011W wlft& A& the primary heater, totalled
tO.04A kcal -or d't . 10, or not more than I percent of
the 4uant*W3 heat transmitted radial-ly through the
Card 2/3 layer of the gas under investigation, Data on;~, Pub-

VARGAFTIK, 11. B. (DR., Prof.)
All-Union Thermal Technical Instintute, moscow.
"Thermal Conductivity of Liquids and Compressed Gases."
paper presented at Conf. on Thermodynamic and Transport Properties of Fluids,
held by the Inst. of Mech. Engr-, London, 10-12 July 1957.

TIKROT, D.D., doktor tekhn.nauk; RIVKIN, S.L., kand.tekhn.nauk; SUROTA, L.M.,
kand.takhn.nauk; VARGAYTIK, H.B., doktor tekhn,nsuk; MIKOIAYEV, Y.V.,
red. MEDVIDIV. LYa-T.-te-M~.M;
(Tables-of thermodynamic prpperties of water and steam] Tablitsy
tormodinamicheskikh ovoistv vody i vodianogo oara. 1zd. 2-oe, dcp.
Moskva, Goo. energ. izd-vo. 1958. 106 p. (MIRA 1114)
1. Moscow. Vseeoyuznyy teplotekhnicheskiy inotitut.
(Steamr-Tables, calculations, etc.)

AUTHORt Vargaftik, N,B., (Dr. Tech.Sci.) SOV/96-58-12-14/18
(Rogineer)
TITLEs
TITM The thermal conductivity of slags in the solid and jzoltsn condition,,
(Teploprovodnowe shlakov v tverdoz i rasplavlonnom sovtDyanii)
PMIODICAL: Teploonergetika, 1958,,NNo.12. pp. 79-85 (USSR)
ABSMCT& There in little published data on the thermal condur.-ti7itioc -;f s~;:Ijd
slag and of porous slags such as are used for heat, insulatAon.,
This article dee4ribes determinations by the method of -.ovxial
cylinders, in which the temperature difference betwean ~.wo cylinders
is measured when the space between then in filled wi-th ths slag.
The necessary forn I&* are stated and the experAzen-tal Is
illustrated by a sectioned drawing in Fig.l. Tests at tenTerat-ares
up -to 11000C wore made in the thermostatic oven illustrated in.FAg.Xa.
and at higher temperatures in the one in Fij.lb. The o-Tene wer,& of
stainless steel and porcalaia respectively, The tircuit dirgxam of
the elettric thermometer is given in Fig.li. As the method in a
relative one, the instrument was oalibrated on svlatar,.ies of knovt
therinal conductivity, su.--h as water and castor oil at room Wzptir&tvms
and molten salts at a temperature of 2000b. Before meascrembata were
made on slag, both instr=ents were used to measure the thermal
conductivity of different glasses similar in composition to slag.
The analysts of the glasses used, one of which contains 4% cahalt,
Card 1/4 "s recorded in Table.,I, The test results witla glass are totqd in

The thermal conductivity of slags in the gol4d SOVI/96-58-12-14/1 8
and molten condition.
Table 2. and plotted in Fig.23 they agree with prblished data for
glass of comparable composition to within 2% in the temp4ratvre
range from 0 to 5000C. The first tests with slag were made wita slag
of 16an Donbass coal grade T. The test results show that the thermall
conductivity increases with temperature in both th.,, eoUd #ad molten
conditions. It will be seen from the curves in Fig,3~ that tht
platinum and atainltss steel cylinders gave very s~miJl&r results.
As with glass, it was very difficult to remove the slag from tht
cylinders and they could be used only once. Thtrefore, foT
subsequent work on al&gs, only stainlase steel cylindera rir4 =ed.
Further work on slags made use of the combustion produ-,te of waatexy
wastes and shales. The work on the latter was of partic-alar
interest because of the high content of CaO. The analysts of the
various slags are given in Table 3. and the thexz&l corduztii-ity
results in Table 4. and Fig.3. It will be seen from Pig.3. that the
results pertaining to different fuels are very similar, thi deviation
from. the msan line for any slag being 3%. A fomala in gilren
that represenis the thtrzal conductivity curve for aX2 the slags
over the temp6rature range 0 - 10000C and a furthsr- fo?mnla with
Card 2/4 different constants for high temperatures. Debya's thsory of the

The thermal conductivity of slags in the solid SOV/.96-58-12-14/1.3
and molten condition.
thermal conductivity of materials of this kind is d'-se.-asesd and
his theoretioal formvla for thermal conduativity in it--=a of
specific heat, v~&looity of sound and mean free part oX phono7,tv .1~5
written. It inditates that the thermal conductivity of ' gltvp*4
and slags should in,~rease with temperature? ths test res"-Ata
confirm this theoretital idea. Values of thermal condu~-,tiTity,
specifio hiat and the ratio of thermal condu.-ti7k~y- to apsci;ti*
heat for slag in the solid condition over the tempsrature rang,6
0 - 1000OC9 are displayed in Table 6. and Fig.5. "'t wl-L'll be. mrtn
that the ratio is pra:~tically indepandent of the temparature.
The physizal -.on.-ept of thermal conduativity of slag and glass at
temperatures above the softening point is much more -,~amplex.
Above the malting point the +,h6rmal ccnductivit-y increas~as sharply
with increase of temperature. Theoretical work on this sv-bjs,-;t
has recently beer publiahsd. (lit.ref.7.). The deposit's on
boiler surfaces may be of solid or porous slag. Me thermal
conductivity of porous slag is, of course, lower than that of
solids. Previously published experimental data for the former
is plotted in Fig.6. and an equation is given that represents
the experimental results approximately. Further work req-m,~res to
Card 3/4 be dong on ths thermal oconductivity of porous slag, pctticalarly

The Thermal Conductivity of Slags in the Solid
and Molten Condition
2 - 2.4/118
as a ftmation of temperature. However, an eq7jA-*4-:T-,on is cffeied
for calculating the Wue at various temperatures I.Y. the e~Zid
condition. Date. required in these calculativzz Evee p7-irfLd!A :1.7-1
Table 7. Th
ere e-re 6 figaies, 7 tables slid 13 references~ rf
which 12 are Soviet and 1 Enp~lish.
ASSOCTATION: VaesoyuzW teplotekhnicheskiy inatitut (All-11niz--- T%he--mc.-
Technical Institute)
Card 4/4

SOIr/96-59-9-3/22
AUTHORS: Var
(Doct!-.r of Technical Science3), and
rz 'A. (Engineer)
Tarzimanov, k.
TITLE: An Experimental Investigation of the Thermal Conducti--4_ty
of Steam at High Temperatures and Pressures
PERIODICAL: Teploenergetika, 1959, Nr 9, pp 15-21 (USSR)
ABSTRACT: Previous work on the thermal conductivity of steam is
EX 4
briefly reviewed. i-sting results at a pressure of 1 atai
are in good agreement at temperatures up to 900 OC., The
influence of pressure on thermal conductivity has been
studied less7 and available data at high pressures Is
clearly inadequate. It was, therefore, decided to st-.;dy
further the thermal conductivity of steam at high
pressures and temperatures, particularly at pressures up
to 300 atm and temperatures of the order of 700 CC, The
tests were made by the hot-wire method which has been
previously describedi the experimental apparatus is
illustrated diagrammatically in Fig 2. A number of
advantages are claimed for this method of measurement.
Special attention was paid to the risk of formation of
hydrogen from water in the autoclave as a result of
Card 115 oxidation of the metal. The autoclave was accordingly
lined with seamless tube of pure silver. k number of

SOV/96-59-9-3/22
An Experimental Investigation of the Thermal Conductivity of Steam
at High Temperatures and Pressures
other special features of the equipment are described.
One of the measuring tubes used is illustrated in Fig 3
and the leading dimensions and correction for eccentricity
are given in Table 1. The coefficient of thermal
conductivity was calculated by Eq (3). Corrections were
made to allow for the flow of heat from the ends of the
heater, the temperature drop in the wall of the measuring
tube, linear thermal expansion of the measuring section,
and radiant heat exchange. Hitherto in measuring thermal
conductivity of gases it has been assumed that radiant
heat transfer is independent of conductive transfer,
However, as steam at high pressure is an absorbent semi-
transparent medium it is necessary to elucidate the
conditions under which the effects of radiant and
conductive heat transfer may be considered separately.
This point is considered and it is found possible to usa
existing equations for the separate calculation of the
two components. The thermal conductivity was calculated
Card 2/5 by Eq (3) and the radiation from the Stefan-Boltzmann
formula. The experimental data and the corrections which

SOV/96-59-9-3/22
An Experimental Investigation of the Thermal Conductivity of Steam
at High Temperatures and Pressures
were used in determining the coefficient of thermal
conductivity are given in Table 2. Because of the small
diameter of the hot wire the correction for radiation was
less than 3% even at temperatures above 700 OC. The
correction for loss of heat from the ends of the heater is
about 1-2% and that for expansion of the measuring section
about 0.3-0.7%. Analysis of possible errors in the
determination of thermal conductivity showed that the
maximum error did nct exceed 1.5% at temperatures up tri
60o OC. The error increases to 2% at higher temperatures
and in tests on the 350 and 300 kg/cm2 isobars at a
temperature of LF50 OC. The data for the temperature range
350-720 OC and pressures up to 350 kg/cm2 cover a region
hitherto unstudied. Where comparison with the data of
other authors is possible it is shown that the greatest
divergence from previous test data of the All-Union Theimo-
Technical Institute at 450 OC is 3-1+%; at 350 OC up to
100 atm. the difference is less than 1.2%. It should be
mentioned that the new experimental results are
y tematically lower than the old ones at high pressures,
Card 3/5 s s 0
the difference tending to increase with the pressure,

SOV/96-59-9-3/22
An Experimental Investigation of the Thermal Conductivity of Steam
at High Temperatures and Pressures
The values published by Keyes for the 350 OG isotherm
appear,to be 5% low. It is of interest to apply Eq (1)
to the experimental data; the corresponding curve is
plotted in Fig 1+. The results show that the change in
thermal conductivity from the value corresponding to 1 atm
bears a simple relationship to the specific gravity.
The new experimental values of thermal conductivity may
conveniently be compared with the values quoted in the
tables of the All-Union Thermo-Technical Institute by
constructing similar curves, as is done in Fig 5. Here
the lower curve corresponds to the new test data and the
upper curve to existing test data using Eq (2). The
greatest difference between the curves is 7%, but there
are so few earlier values at high pressure that the
coefficients in Eq (2) could not be determined very
accurately. The new data fully confirmed the existence
of the above-mentioned relationship between the change in
thermal conductivity from the value at 1 atm and the
Card 4/5 specific gravity, which is very important in formulating
tables. The tests also showed that the relationship i:i

SOV/96-59-9-3/22
An Experimental Investigation of the Thermal Conductivity of Steam
at High Temperatures and Pressures
somewhat different from that previously assumed. The
tests that have been made at pressures up to 500 atm
may be used to draw up a table of values of thermal
conductivity of steam over a wide range of temperatureB
Card 515 and pressures and to correct existing tables.
There are 5 figures, 2 tables and 25 references, of whic:h
15 are Soviet, 8 English and 2 German.
ASSOCIATIONs All-Union Thermo-Technical Institute (Vsesoyuznyy
teplotekhrxicheskiy institut)

sov/96-59-10-13/22
AUTHORS: Vargaftik, N.B. (Dr.Tech.Sci.) and
Oleshchuk, O.N, ~Engineer)
TITLE: An Experimental Investigation of the Thermal
Conductivity of Water
PERIODICAL: Teploonergetika, 1959, Nr 10, pp 70-71+ (USSR)
ABSTRACT: Earlier determinations of the thermal conductivity of
water are briefly reviewed. Previous work has not
covered a sufficiently wide range of temperature and it
was considered desirable to make conductivity measure-
ments over a wider temperature rangeg as near to the
critical temperature as possible. This is of particular
interest in connection with the formulation of unified
international steam tables. Thermal conductivity
measurements were made by the hot-wire method with a
quartz measuring tube of the same construction as was
used to measure the thermal conductivity of steam. The
experimental set-up was also much the same as before
(Zhur.Tekh.Fiz. Nr 13, 1940). The method of calibration
is described; the calibration was repeatedly checked
Card during the course of the experiments, and the results are
1/3 plotted in Fig 1. The experimental results are giver, in
Table 1 and Fig 2. Corrections that were made are

sov/96-59-10-13/22
An Experimental Investigation of the Thermal Conductivity of Water
described. The maximum relative error of the experi-
mental data is 0.8%. Scatter of experimental points from
the mean curve (Fig 2) is mostly within 0.4%. The tests
were made over the temperature range from 20 to 350 OC at
pressures of I to 217 atms. It was not the object of
this work to investigate the influence of pressure on the
thermal conductivity of water. Table 1 gives the values
of the test pressure and of the saturation pressure; in
some tests at high temperatures corrections were made for
the influence of pressure so that the values of thermal
conductivity given in Table 1 relate to the saturation
line. The magnitude of the pressure correction is given
in Table 2. The new experimental values for the thermal
conductivity of water as functions of temperature are
plotted in Fig 3 along with data of other authors and
values obtained from the tables of the All-Union Thermo-
Card Technical Institute. The data of the various authors is
2/3 compared and it is pointed out that little information
is available about the region near 0 OC. Powell has
recently made a careful analysis of all the experimental
data available and he recommends the values for the

SOV/96-59-10-13/22
An Experimental Investigation of the Thermal Conductivity of Water
thermal conductivity of water given in Table 3.
Table 4 gives the authors' recommended values for the
thermal conductivity over the temperature range 0 to
350 OC, at intervals of 10 OC. The difference between
these recommendations and those of Powell is not greater
than 0.4%. The test results given here indicate that
the values of conductivity in the Tables of the L11-Union
Card Thermo-Technical Institute are somewhat high.
3/3 There are 3 fi&ures, 1+ tables and 13 references, of which
7 are Soviet, German and 2 English.
ASSOCIATION: All-Union Thermo -Technical Institute (Vsescyuznyy
teplotekhniaheskiy imnst.:Wt)

VARG&WIK N.Be, doktor tekhn.nauk; TARZIMAMV, A.A., inzh.
lxperi,%ental Investijption of the heat conductance of
steam. Teploenergettka 7 no.7:12-16 Ji 160. (KIM 13:7)
1. Veeso7uznyy toplotekhnicheskiy institut.
(Steam-4bermal properties)

VARCAFTIK, N.B., doktor tekhn.nauk; TAFZIMANOV, A.A., kand.tekhn.nauk
-------
Generalization of experimental data on the thermal conductivity of
steam. Teploenergetika 8 no.6:.5-8 Je 161. (MIRA 14:10)
1, Voesoyuznyy teplotekhnicheakiy institut,
(Steam--Therml properties)

2174
5/09k/62/000/012/003/003
jet) 0 E194/E435
AU'PHORS: Vargaftik, N.B., Boctor of Technical Sciences,
.OT-es uk, O.N., -Engineer
TITLE: The thermal conductivity of heavy water steam
PERIODICAL: Teploenergetika, no.12, 1962, 64-66
TEXT: The thermal conductivit.y of D20 in the gas phase was
studied at 7 pressures in the range 1 to 250 kg/cm2 and *
temperatures from 145 to 5000C, with amounts of superheat ranging
from 5 to 200*C and approaching quite closely the saturation line.
The same method was employed as that used in previous tests in the
liquid phase, namely the hot wire method lAtomnaya energiya,
V.7, no-5, 1959). The results are tabulated and plotted (Fig.2).
Tables are also given of the ratio of the'thermal conductivity of
heavy water to that of ordinary water in the liquid as w:11 as in
the gas phase. It is shown that at a pressure of I kg/ m
~the experimental ratio is in good agreement wit *h the results
calculated on the basis of modern statistical physics. There-
are 6 figures and 4 tables.
ASSOCIATION: Vaesoyuznyy teplotekhnicheskiy institut
(All-Union Heat-Engineering Institute)
Card 1/2

S/096/62/000/012/003/003
The thermal conductivity ... E194/3435
kcal Im. hour-
~Zfl HII,
Fig.2.
12
Card 2/2
.0
: ~g
rat zoo .:## 170~0 C

00

rR,

KOSTIYIVKO, A.I., red.; KIVILIS, S.Sh.,
red.; SKURLATOV, V.I., red.; MYUCITINA, V.17., tekJin. red.
[X'anual on the thermophysical prorerties of gases and liquids)
Spravochnik po teplofizicheskim svoistvan gazov i zhidkostei.
Moskva, Fi2matgiz, 1963. 708 p. (MIRA 16:12)
(Gases-Thermodynamics) (Liquids-Thenaodynamics)

30,11c,21631000100310041005
AUTHORS: rar-- -t i 7c
Xor,-; lov, N. i. Lapushkin, S. A.,
Pyatibzatov, 5. iN. , Sokolov, S. N.
,erl-40j~ 34' monoisopropyl, dinhen-I
TITLE: Thermopkysical nrC)-
P I"' R 10 j) I C A L1-4va.;tiya vys,;,,,ikh uchobrylich --avedeniy.. Nleft' i gaz,
no. 1963, 75-76
EX T : Results are given of dek,ailed investigations into thc thermo-
physical properties of monoisoll)ropyl diphenyl in the liquid phase and the
pressure of its saturated vapor. Properties of the sample investiCated:
25 0 3
molecular woight 197, nT,. = 1.5696,dennity at 20 C r = 0.90-9 3/cM
boil4- point 286 0C (7060 m" Hsi- Con-;entional measuring methods were used.
' 0
The specif-ic heat (C and the der~_Jty measured with a calorimeter
Lt 20-593 0C and 10 atm wi-ch a, (,;?ror of 0.3/0' for the densit,,,, and
for the spocific heat. Tito h~,,Lt c,)nductivity (eQ -~.ao mcasured with
0
nea-ted-1,,4-re a_,~,_30-209 C, under atrjop'neric prcs~ure, wi-th an aac~;uracy of
rated-monoisopropyl- -
Tne viscosi* e-r t -..e preosuce d'Matu
Card 1/131

V 521/64/0CO/
1 -7
Therm-3-physica proze~ i
diphtjnyl vapor war measured at 20-340 0C with a maximum error of 1'. The
P
pressure of the saturated vapor (i),,) ,ua; moujured at 1116-30900. The error
was 0.2 QC for the temperaturo and 2 m,%-i for tne
To determine the t~ermophysical I)roT-,,3r'L-,es of monoisopropyl diphenyl, the
exDcrlmental amounts we~a generalize6 for s.-.-,oothed temperature values, ar,
tabulated (Table 2). The table also ;-;iv,,-:3 calculated values of the heat of
vaporization (r) and the ?randtl nu.,.ioer.-I requirod for calculating the heat
exchan.-e. There are 2 tables.
AK"OCI.-MON: ii,losk-ovskiy avi--tsionny.. institut im. S. Ordzho.,iil:idze
(M:,sco~a Aviation Instituto imeni S. Ordzhonikidze)
january 17, 1963
Mable 2. ",moothed values for 'he thcrmophy3ical proper 4 JLI
I) 'a of
monoisopropyl diphanyl.
Card 2/2,

c

t3

.~

i,~-- 5 ~ 1
Z~
-7 /- -

al/ 4~ I

r
20 0,969 0412 303 1-1,1 V)
40 0.962 G.432 297 6,29 91.5
60 0,953 0,44C 289 3,47 53,4
80 0,9.13 0, 4 G -2 283 2,22 36,2
100 0.032 0.478 278 1.37 I's 77,0 27.0
120 0,920 0.49-1 27 2 1.17 3'.5 75,5 21,3
140 0,907 0,.-Io 266 0,3vo 55 75.0 1-..1
IEO 0,893 0,52G 261 0,4`190 10 7 4 13.9
ISO 0,878 0,542 255 o~5"r, 39 73,3 11,8
200 0,8G1 0,m0 2.17 ().-IM) 77 72,5 103
220 0,845 G.578 2.11 (). 31 & 1 142 71.6 9,1212
2-10 0,627 0,597 2-36 0,150 219 70,5 8,35
2G0 0,609 0,616 230 0,21" 418 69.2 7,74
280 0,791 0,637 2-2 i 0.254 671 67.7 7,19
'100
0,773 0,658 216 0.22-1 10-12 65,7 6.76
,320 0,7.53 0,631 211 O'm 1-570 63,5 6,39
3.1.0 0.73.1 0.705 205 0.17.5 1.129 1 60,9 6,02
360 0,714 0,7310 2 0 0,155 32 6 6 579 5,66
380 0694
' 0,758 192 0,,37 54:5 5,41
'100 67-1
0, 0,788 .183 0,1,.-4 6194 50,9 5,34
Card 3/3

AP3000437 S/0170/63/006/CO_/Or-'03/000--'
AOIRS31011? HR:
AtMM: irargaftikc, N. B.; Zaytseva, L. S.
TITLE: Heat conductivity r-f deuterium in the gas phase
sCURCE: Inzhenerno 1 5
41zicheskiy zhurnal, v. 0) no. 5, 1963, 3-6
T0111CITAGIIS: Deuterium; heat conductivity
_~~ACT The heat conductivity of D sub 2 0 and H sub 2 0 vapor was
measured by, the hot-w1re method, using the apparatus shown in Fig. I O;r
U curves (Fig. 2) have been obtained for a
the Enclosure. Dmerijnentu
pressure n = 9.8 x jo sup 4 nm sup -2 and te-nueratures ranging from, 100
to 500C. The experiments have shown that the ratio of the heat conducti-
vity of the two isotopes is a function of temperature (Fig- 3). A theo-
retical explanation of the results is offered in terms of statistical
mechanics. Orig. art. has: 5 equations, 4 figures, 2 tables.
;Card 1/5

I-ACCESSION -ZIR:- - -AP3000437 - - - -
ASSOCIMION: AvlatslcruWy institul, ims Bergo,Ordzhonikidze (Aviation
Ins.titute im..Sergo Ordzhonikidze), Moscow
s.JBMITrED: 24-Sept62 DM ACQ: lOJun63 EITCL: 03
SUB CODE: 00 NR REF sov.. oo4 OTHER: oo4

ACCESSION IIR: APIM0417

4

Card 3/5

'K
Fig. I Experimental apparatus.
I
1 - mercury, 2 - liquid investigated,
3 - electric heater, 4 tungsten spring,
5 - platinum heater, 6 external rceist-
ance thermometer, 7 - measuring tube,
8 - leads to potentiometer, Hi. H H -
21 3
thermostat heaters, Tl, T T thermo.-
2 3
couplea.

ACCESSION NR., AP30oo4-x7
Car-d-
ENCLOSURE. 2
6M