SCIENTIFIC ABSTRACT VAYSBURD, I.A. - VAYSER, V.L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001859210003-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

"Analrzia of Lethal C
Chitcome in Typhoid PAtients Treated With
SynthoaVcin," j S. Ye Saapiro and I. A. Vaysburd, S~~alirab-ad
Uivy awz~e-L"'-L of Infectious Diseases, Zhurnal MikrobioloE;ii
L;pidei Oloj;ii i lm;n=obiolo~;ii, Vol 2b, kilo 1, Jan 5-6 P[) 34-3-1:
This wor'~ deals wizh.- investigation of 23 fatal cases of zyphoid waich
had been treated with synthomycin 'etween 1951 and 1955. Attempts were
made to deteri~ine the - -,s of failure of antibiotic therapy.
EiC.-;hteen of the cases were subjected to pathological-tuiatomical autopsy;
the reiaainint; czis;~6 were cliavaiused before deatn by heLcculture or high-
titer Widal reactions.
The article states tnat synthomycin was administered in the generally
accepted dosa6es, i. e., a daily dose of 3 g for adults and less fo:L-
children. In addition to pathogenetic and symptomatic tlierapy, penicillin
and streptomycin were also given on the development of pneumonia. The work
presents tWo case "aistories in winicil the administration of synt'homycin was
begun early Luid -olonLed, but. did not prevent death.
It is corcluded oi,. t-lie basis of these observations t';a-v failure Ua-zal
outcome) was determined by two factors: (1) a particularly severe course
of the infection process with diffuse anatomical changes in tne in-Cestines
and early affection of the central nervous and cardio-,rascular syszens; and
(2) complicating diseasez;, d-iGestive collapse, helminthic diseases, and
other factors which lover the imurological reactivity of the macroorgann-
is'a. (U%

VAYSBUR MELIK-GAYKAZYAN, I.Ya.
'S~~
Equation deacribing radiation accu-ulation of electron centerz
Jn alkali halide crystals. Dokl. AN SSSR 165 no.5:1029-1032 D 165.
(MIRA 19:1)
1. Tomskly politekhnicheskiy institut im. S.M.Kirova, Submitted
~!arch 29, 1965.

-TA3IBYBD.,,_ I..LL. inzh.
Theory of the wtion of-a billet on a slide. Konstr.krup.mash. no.l:
139-154 162. (MIRA 16:2)
(Furnaces, Heating)

VAYSBW,,.~*,, p~onWshlennyy sanitarnyy vrach
- ,
Preventing the action of alternating electromagnetic high-frequency
electric fielde on the human orgenizm. Gig. i son. 23 no.2:68
F 1589 - (MMA 11:4)
1. Zz Moskovskoy gorodskoy sanitarno-apidemiologicheakoy stantaii.
(HISMICITY-SAYM7 HFASURES)

, -VAYSBURD, M.S.; KOM4AN, V.B.; 14'URAKHVER, N.P.; STEPABOV, A.I.
About a book on the design and calculation of refrigerating machines
and apparatus. Khol. tekh. 38 no. 1:61-62 Ja-F 161.
(Refrigeration and refrigerating machinery) (MIRA 14-4)

Vaysbard, P. A., Ganago, 0. A., and Tornovskiy, i. Ya.
"Investigation of the k'orging of Round Shapes in Open and Closed Dies",
Nnuchnye Do'111ady Vysshey Shkoky, iietallur!Jya, 1958, Nr 2 11 1611-191.

80), 24(3) S/105/60/000/03/017/(;~17
AUTHOR- Vayst-drd, P. M., Engineer (KiYev) B007/B0O8
TITLE: Impzovement of the Traction Characteristics of AlternatinF,-jir-
rentc Electromagnets
PERIODICAL: Elektrichestvog 1960t Nr 3, pp 82-83 (USSR)
ABSTRACT: It is necessary in a number of cases to vary the traction
characteristics of electromagnets without changing thEdr design.
Three methods for improving the traction characteristics of alter-
nating-current electromagnets are investigated here. Formula (1)
for the total resistance of the winding of the electromagnet
/
is written down. It follows that fundamentally two different L
methods are possible for reducing the total resistance of
the electromagnet winding without changing its design: 1) by
feeding the winding with direct-current and rectified current
respectively, and 2) by connecting in series or parallel a
capacitor, the capacitance of which can be determined from
= X
the induc-
the condition x
is the capacitance and x
e x
L
L
C
C
tance of tLe winding. The electromagnet traction is raised by
the first method, by increasing the feeding voltage or by rec-
Card 1/2 tifying the feeding current. On the basis of the experiments,

Improvement of the Tractlon Characteristics of S/105/60/000/03/017/023
Alternating-currents Electromagnets B007/BO08
SUBMITTED:
an increase of up to 220 v of the feeding voltage of the relay
RPT-100 with a rated voltage of 127 v results in a rise of trac-
tion(with a gap of 1.5 mm) by 4.6 times its amount. In the
second case the experiments on the same relay resulted in an
increase by 3.5 times its amount. The ferro-resonance is utiliz-
ed for raising the traction of the electromagnet in the second
method in which the total resistance of the winding is reduced
by connecting a capacitor. Experiments on a relay RPT-100 with
a rated voltage of 220 v showed that,with an identical gap,
traction increased by a number more than twice its amount, The
capacitance of the capacitor was 1 pP. There are 3 figures.
July 30, 1959
Card 2/2

VAYSBURD, P.M.
Simple photorelay. AvtOM-i prib. no-4:89-90 O-D 162. OURA 16:1)
1. OpYtno-konstruktorskoye,i bYuro torgovykh avtomatov.
. .: (Photoelectric C'ells)

I i
VAYSBUIPJ.'j~ :-.*m-;, V~D., -'Iriz't-,.
L.- I- I f -1
- --rtlaz;e 'n- th-i .-.,urrant cf elec~r-3a-,
Entire. i pram, 765. (MRA 18:8)

VAYSBURD, P-M-,L YI4ENGAUZJ F.G.
Transistor photorelay circuit vith a thermostabilizing loop.
Priborostroenie no.2.26 F 163. (MIRA 16-5)
(Transistor circuits)

BEREZIN, A.M.; VA~SBURDj P.~L
Increasing the stability of an electronic timer. Prib. i tekh. ek8p.
no.2:105~-106 Mz-Ap 163. (a;A 16-4)
1. Kiyevskoye opytno-konBtruktorskoye bVpro,
(Electronic apparatus and appliances)

BKPtFZIN, A.M.; VIUSEL"IfF)l -.P.m.
Tvo circuits for connecting fluorescent lamps. Energ. i elektrotekh.
prom. no.3s14-16 JI-S 162. (KMA 1811l)

BEREZIN, A.M., inzh.1 VAYSBURD, P.M., inzh.
Condenser braking of small three-phase electric motors. &erg. i
elektrotekh. prom. no-053-54 O-D 164, (MIRA 1823)
1~

VAYSBURD. P.M.. inzh. (Kiyev)
Improving the pn1l of a.c. electromagnets. Zlektrichestvo no-3:82-
83 Mr 160. (MIRA 13:6)
(Electromagnets)

VAYSBURD,, P.M.
Measuring torques. 1=.tekh. no.7:16 JV62. (IMU 25:6)
(Torque--4-leasurement)

VAYSSM, PA., inshoner.;SHAPIMMiNt Ta.A., inshener.
Signaling_the staffagg ... of pW*r to lwCe direct-current in-
stallations.-Prom..snerg. 11 nc.10:6-7 0 156. (MM 9:11)
(sl6was. and ral4s)

2 S'/148/61/000/001/002/015
Al 61 '/A'1 3 3
AUTHORS: Tarricvskiy, 1. Ya.; Levanov, A. N.; Poz-
deyev, A~ A.; Ganago, 0. A., and Kotellnikov, V, P.
TITLEs SPIeCtjOTL Of suitable functions for the utilization of the
Ritz method -In the theory of working metal by pressure
FLUIODICAL& '[7,vef3t_JyrA vysshikh uohobnykh -zavedeniy. Chernaya metallurgtya'
nf-.i, 1, 1961, 73 - 83
TEXT-, The article deals with the application of the Ritz methed (Ret.
11 1 '4 -, Ri,'z. Uebar einki neue Methode zur Loesung gevisser Variationsproblem
der mathematicehen _n~r3ik. Jo.urn. f. d. re!ne und angewand.te Mathematik,
-Bd~ 135, H. 1, 1!)08) for the cnlculatlon of diffPrent praotloal p-oblems
pressure working,. Such problemg consist I~ri determLning the functions oC
displacement components, and the searched for functions are written -in a
seriezi
)y,,,) 4, 6 fn Oy 17.
Uk + fA2'f2(-'( n
where Uk is any, of the '.,oordinate axes; a, - are I-ndefinite (vari-able)
Card. '/2

2jtM
8/148/61/000/001/00P/015
Sojection of suitable functiona for the... A!61/AI33
parametorol fj(xpyjz) .- "twAtable" function~j rofloct-Ing qualitatively the
dAsplao6mento pattern and.satierying th-! boundary ?on~q oondJt,ie)nF.. T lie
problems diAotluaod ao oxamplen &rot uptlett Ing of oyl I ildri fial LJ~ III tita bo-
tween. flat pl.atpaj a parallelepiped betwepn flat plat,?ui a oan., hhere
the purpose is to drtermin,~., thp propagation of plastic deformatti--:~n, with a
aLmyle axisymmetr.loal forging used as an example. The mat hemati nal analysis
of the individual caesom onds w.%th r-;.oo-mmendat1 onus 1) It th,~. II..tz mothod :ia
used, the suitable functiona munt be. (vilrictad no ai to rcflo:~-~t M'.'ro or loa.4
oompletely thn Lounditry oondittons oorreeponding tho purpoon. of Investiga-
tion. ?) Tho oy*tem Gf iuatmblo funotiono describing Lhe deformed state -in
teohnological problema cian be nolooted wl th % oertoa of roil h aotlumptiona
(uniform deformat.i,?n, the hyp~-theu!n cf flat sections, ritc.l. 3) When rhb
propagation of di,splaoement,!3 and d(iformation within the body has to be dn.
termined in detail, tho suttable functionf) will be more complux and contaIrl
two or three variablc parameters, and at the eame time satisfy the boundary
conditions more completely. There are 8 figures and 13 references; 12 Sri-
vLet-bloc and 1 non-Soviet.-bloo.
ASSOCIATTON i Ural I skiy poll. takhnicheak ly insti tut (Ural Polytpchni c IoL, z,,
SIMIITTEr s April .50, 1960 va L A)
Card 2/2

TARNOVSKIYJ, I.Ya.; VAYSBURD, R.A.; YEREMEYEV, G.A.; GANAGO, O.A.
Forces in open die forging. Izv. vys. ucheb. zav.; chern.
met. 7 no.1:113-122 164. (KRA 17:2)
1. Urallskiy politekhnicheskiy institut.

GJUJAGO, O.A.; TUNEV, G.Ya.; VAY3BUfX, R.A.
Rolling the blanks of bore bit shank.,-. Kuz.-shta--I,Frcizv- 4 :20-8:
5-6 Ag 162. (MIRA 15:8)
(Rolling (Metalwork)) (Forging)

ACCESSION NRI AP4019024
8/0182/64/000/002/0013/0019
AUTHORSs Grigorlyevp I. I.; Vaysburd, R. A.
TITLEs comparison of methods of calculating the stamping forcq
SOURCE& Kunioahno-shtampovochnoye Vroizvodstvo, no. 2, 1964, 13-19
TOPIC TAGS: metal forming, metal stampingo stamping stress, stamping force,
plastic deformationp stamping blank
ABSTRAM Nine different analytic~61 foxmulas for calculating the stamping force
in metal stamping were compared with experimental results for the configixration
shown in Fig. 1 on the Enclosure. Equations for the nine formulas are presented
and their derivations and major assumptions are briefly discussed. Three of the
formulas are oemi-empirical, three use integration of approximate equations of
equilibrium and plasticity, two use variational principles of mechanics, and one
uses the method of characteristics. The results obtainee, with these formulas were
compared with experimental results for Dn/H - 3-7 - 69.0. It was found that two
of the formulas gave significantly better r9oulte than the rest; one derived by
variational methodso the other by the method of characteristics. The latter was
derived by Le A. Shol'aan (Oanavy* rascheta, protsessoy shtampawki. i pressovamiya.
Card 1/4

ALCCMION M AP4019024
Maahgiz, 1961); the foraer was derived by 1. Y&. Tarnovskiy, R. A. Vaysbura, G. A.
Yereaeyevv and 0. A. Gaaw (-no re&'erenas)q and was presented for the first time in
this paper ass P Frk + F P3, For round steapimps
3
6, D
14
6
' H,
+
26.4
4+
Ha
HS'
D;.
D2
for eloWted stampings I
HS
2... +
Its
oil:
+
cam 2/4

:ACCESSION M AP4019024
:(where; P - projected area of partp F me projected area of bdimensiong D
diamet r#nB m width)* Although these lormLlan compared best th weperimental.
,reaultat it was found that their application is influenced Goniiderably by the
choice of 6 which is not further discussed in this More Origs arts haag I
table of foadasp 2 tables# and 2 formulas.
ASSOCIATIOIFi none
SUMV11=1 00 D&TE ACOt 27X&r64 IMCLs
MM COM IWL NO RV SOTs 014 Omm,
01
0001
ca,d 3/4

MCLOSURE 101
AC(XSSION NRs AP401OQ02A
fte. I GeOMOU7 Of MMM-ia=W st"P'ng-
Card 4/4
W-M

TARITOVSKIY, I.Ya.; POZDEYEV, A.A.; K011---OGOEDV, V,L.;,VAYSBURD,
R.A.; GIW-, G.Ya.; KOTELIVIKOV, V.F.; T-'RTjOVSKn-I-v----r-,
78KOPOKHODOV, A. I.T.
[Variational principles of' mechanics in the theory of metal-
working by pressure] Variatsionriye printsipy mekhaniki v teo-
rii obrabotki rnetallov davleniem. Moskva, Motallurgizdat,
1963. 52 p. (IIIIHA 17:5)

VAYSBURD, R. A., Cand. Tech. Sci. (diss) "Investigation of
Deformations and Tensions During Volume Stamping wit'n Utilization
0 -
of Variation Principleept' Sverdlovsk, 1961, 16 pp (Urals Poly-
tech. Inst.) 150 cooles (KL Supp 12-61, 264).

TARNOVSKIY, I.Ya.; GANAGO, O.A.; VAYSBM~)_R.A._
Calculating forces in forging. Izv. vys. ucheb. zav.; chern. met.
no.2:51-61 161. (PUA 14:11)
1. Urallskiy politekhnicheskiy institut.
(Forging machinery) (Deformations (Mechanics))

s/i 48/6o/o,50/004/0C, -- I&r,--'-
A161/AO29
AUTHORS! Tarnovskiy, I.Ya, Ganago, 0,A4, Vaysburd, R,.A.
TITLE. Deformations and Stresses In Closed Fiercing Proce~s
PERIODICAL: Izvestiya vysshilch uchebnyKri zavederiiy - Ch,~rnaya metallurgiva,
1960, No. 4, pp. 99-108
TM, The "closed piercing, i.e., foraing the punch InI.-o a billet held
in a shell. (o.- die), is widely used for produ,--tion of cupped py---~,
walled containers, and comes into u,.ze for cold extrusionTlof "-p-in-wallied
tee!. The procqss is analyzed In its threi~ stages.u the
A~f aluminum,\%brasq3 andt.
first stag~-'when metal fills the space, the se3ond stage in which metal is
forced out from under the punch and flows upwaxd, plastic deformation under
the planch remaining at a certain depth, and the third stage., when all metal
-under the punch takes part in plastic deformation. The calc%~lation of efforts
nee:;essai~y for the operation is of practical importanse. The calculation method
had been published previously (in Refa. 5,06, etc.). This article gives a prac-
tical calculation of a problem with analysis of the second and third stage of
the process. A formula is derived (127) fcr determining the F value, i.e.,
es
Card 1/3

S/lh8/6rj/GOO/004/C)01/006
A161/AO29
Deformations and Stresses in Closed Piercing Process
the pressure divided by the punch fac;e ar~,a. For approximatte practical cal-
culations of pressure simplified formilas (,?-8 and 29) are recommfnded for the
sst,,ond and third stage, respecAlvely, The equation fcr hu, = h"f (see fi.-
guze) corrisponding to the transfer from the second stage to the thir-d stage.
is easily found from the equations (28) stad (29). The following final equa-
',:Lon iz obtained~ h_ I IL
- = 0~11 --- D2
D 1-0,85 Dul
D
The:~,a ax-4 ? figures and 8Soviet references.
ASSOCIATIONS Ural'.sk-iy politekhnic-heskily in-mtttat Ural Polytec~viical lnstl'lj%~)
SUBKTIOED. M6~y 2-11, 1959
(;&f,.i 212-1

Deformations and Stresses in.Cfosed Piercing Process
Figure 1:
Card 3/3
S11 48/60/000/004/001/006
A161/Ao2g

PO7,DFYEV, A.L.; TA101OVSKIY., I.Ya.~ YAYPBUIP,-R.A.4 ORLOV, S.N.
Calculating forces during the extrusion of aluminiz alloy loda*
Izv. vys, ucheb, zav.; tavet. met. 3 noi5:20-255 162. '(MIRA 25:20)
1, Urallskiy politekhnicheskiy institut., kafedra obrabotki
metallov davleniyem.
(Extrusioil (Yietals)) (Aluminum alloys)

\v,'A L- V"
MIZE I BOCK KULCITATION sov/4671
hkademvra nauk. SSSR. inst-itut avtcmatiki i telemekhaniki. Seminar po,
pneumcgidrw-licheskay avtcmatike. 2d and 3d session
Vc;pr.-:~,3v pnevmo- 1 gid-ro- av-tan-atild (Pr6blems in Pneunatic and Hydraulic Autanation)
mo-d~.7-171 1960. 21.1 p. Errata slip Inserted. 4,500 copies printed.
ReF p, Ed., M.A. Ayzeiman, Doctor of Technical Sciencea, Professor; Ed. of PublisbAng
A.A. Tall; Tech. Ed.: S.G. Tikhomirova.
1, UY P, P'C; 3 F, Uhls ~-^-11e-~tton of articles is intended for scientific workers., industrial
klt5!gney~,! and engineert, interested in automation and telemechanics.
!he collection of 23 articles Is a continuation of an earlier work of the
At!,.-vlevy of Sciences USSR, on pneumAtic and hydraulic autmation systems, pub-
in 1959, A wide range of problems connected with the design and operation
of pneuinatic ancl hydraulic autaaation equipment is described. An addition to
prot-le-ma based on eirperiments, the collection also contains discussions of new
t.rcradz In the field., such as the possibility of using very low pressure for the
4~

Pr(~-blern; In pn.- cmation sov/4671
_Imatic and Hydraulic Aut
ope,z-,-0-1on of pr-e=atic devices. Same articles of this collection were written in
Republic and in Czechoslovakia and reflect a somewhat differ-
e-w~~ tc autcmation problems. No personalities are mentioned. References
mc2t of the articles.
TABU,' C(IFM.TTS:
GE11FT(AL PBOBLUAS OF FTM314ATIC AND H-11)RAULIC AUTOMATION DEVICES
AnaLysis of tbe, Possibillty of Low Pressure Operation of
Al)t,.-Miti.on Instnmentro 3
fjj-, Ric~-rime-ntal Investigation of Characteristics of Jet
.3~7npr~n-~-tjl-s of Fneumq.~Ic Autr'n-aticin.Devices 11.
Y,~~.A. ('4! the Calculat ion of Characteristics of the Nozzle-Baffle
17
Ke~~Lk.-Lrr,, V.A., On 1Che; Method off Analysis of Dynamics of Following Eystems
Wii~h Hyd..,-r.).*,A1J.,: Executive Mechanisms 24
'51 ~'- 1-i~~v

CHUDNOVSKIY, A.R., inzh.; VAYSER, L.D., inzh.,- POLEVOY, S.N., inzh.
Plastic duplicatdrs. Mashinostroenie no.ldo-ii Ta-F 62.
(MIRA 15:2)
1. Odesokly zavod kholodilino o mashinostroyeaya.
~Plastics)

AMMECHETY L.S.; VAYSERp L.V.; CHUDNVHIY, A.R.
Effect of fillers on the properties of plastic compositions
used in the manufacture of technological equipment. Plant.
massy no.3:37-38 163. (MIRA 1624)
(Plastics) (Building materials)

GHUDNOVSKIY, A. ft., inzh.;-VAYSER, L. Vo, inzh.; GRABOY, L. P., inst.;
MOROZII V. A., inz~.
Using plastics in electropla.ting. Mashinestroenie no-5271-72
S-0 162. (MIRA 16:1)
1. Odesskiy zavod kholodil"nogo naahinostroyeniya.
(Electroplating) (Plastics)

CIIUDNOVSKIY, A.R., inzh.; VAYSER, L.V.j Inzh.; GRABYY, L.P., inzh.
Making die-casting nolds of thermoplastic polymers for casting
parts. Mashinostroonie no.3',,'19-W My-Je 163.
(MIRA 16:7)
1. Chernomorskly sovet narodnogo khozyaystva,
(Die casting-Equipment and supplies)
(Thermoplas ties)

10^3
JUN 25 5
PHASE I BOOK EXPLOITATION SOV16209
Akhmechet, Leonid Samoylovich, Leonid Vladimirovich Vayser, and Arkadiy
Romanovich Chudnovskiy,
Primenenlye plasticheskikh mass v tekhnologicheskoy osnastke (The Use of
Plastics in Engineering Equipment) Moscow, Mashgiz, 1962, 155 p. 10,500-
copies printed.
Reviewer: L. S. Pilipenko, Engineer; Ed. : A. 1. Bykovskiy, Engineer; Tech.
Ed. : M, S. Gornostaypol'skaya; Chief Ed. (South eryta'Division, MashgIz):
V. X. Serdyuk, Engineer.
PURPOSE: This book is intended for technical personnel-'in machine plants
engaged in the design and manufacture of engineering e4ujoment.
COVERAGE: The book deals with the use of plastics In the )na'nufacture of
engineering equipment, such as molds, dies, fixtures, ~Dr,d tools. Sugges-
tions are made on how to design, manufacture. and use - h e p I'a:s t I c
Card 11AII

The Use of Plastics (Cont) SOV/6209
equipment. The properties and application of the more common plastic
compositions are described and listed in an appendix. The authors thank
Z. Z. Trakhtenberg, Engineer. There are 94 references, all Soviet.
TABLE OF CONTENTS:
Foreword 3
Ch. I. Use of Plastics in the Manufacture of Engineering Equipment 4
Ch. 1I,_1: Types of Plastics Used in Endineerihg* Equipment; Com-
ponents and Manufacture 7
Ch. III. Antisticking Coatings 40
Ch. IV. Methods of Manufacturing Equipment Elements From Plastics 44
Card 2/1,,-

L7
J-1 RM
~~AC6 loll DIR: LP5021595 UR/0286/65/OW/01-3/0()69/0069
fu, I-
AUTHOP.13: Bardanshteyn, 1. B.; Gutarts, F. M.; Dymf-_hi+,s., E. L.; NaWay
Vaysar,___~. V.
4
_LiLnita-furfurol resin. Class 39,
TITLE: A math d for obtaining p~4s tic mde of
172484
SO)"TME: Btru.1-letcn, ~.-naklcv, nc,. AQ
TOPIC TAGS: p2astic, resin, IiFmite, fiwfuroi, mirctropine, mn'--thaphenylene
(j 1, a m -1." e
ABSTRAC-'. This Author Certifica'e or-s-97,ts me,,hcd fl-r olctainlnr S --i 4 0
the comros"tion as a hardener.
ASSOCTATION: nee
------ ---- ---

S/653/61/000/000/046/051
1042/1242
AU73MR: Vayser, L.V.
TITLE: The use of plastics as model materials
SOURCE: Plastmassy v mashinostroyenii i priborostroyenii'.
kurvanya rcsp. iiauch.-tckh. konfer. po vopr. prim.
plastmass v mashinostra i priZ)orostr.0 Kiev, 1959..
Kievp Gostc1chizdat, 1
a 961, 515-519
~TEXT: The metal cnstinG of models 'is technologically satisfac-
tory but oxpensive. Recently, the casting !Df plastics in siiaple.
gypsum molds has 8ained acceptance. The'Odbs6kiy pro~ektno-konstruk-
torslciy tokhnologicheskiy institut (Odessa TechnoloGical Institute
of Structural Decign) has developed a suitable-composition based on
polymethylmethaorylate. Its plastic properti -es can be improved bv
adding dibutyl phthalate an((,-Wear resistance,q by adding metal
Card 1/2

S/653/61/000/000/046/051
1042 1242
use-of plastics as model mat-orials
The
or mineral powder; a mietal framework is sometimes used to insure
V/
structural strcn,~th. The c6nstraction of molds, the entire castinL;
finishing; of models are discussed in detail. The
procedure, and the
structural requirements for different-size models are given. An ad-
vantage of the above Comp.osition is the case with which additional
a L U
rts may be attached. "he technology and preparation-of plastic
p
adjusting,devices'is discussed. The plastic OITKTH (OPKTI) consistine
of 5Cr/o' polymethylmethacrylate arid 50% dibutylphthalate is more sui-
table for this piu-pose. The advantage of OPKTI and the disadvantages
of other plastics are listed.
.A~,_Card 2/2,

3/19IJ63/000/003/011/022
3101/9186
AUTHORSs Akheacheto. L. Sp X_4y~ei~s-Lo-yot Ghudnovsklyp A. R.
TITLEs Effect of Alle're an the properties of plastic compositions
used for producing Industrial equipment
PERIODICAM Plasticheskiye massy* no. 3, 1963, 37-0
TEM Without specifically mentioning details of tbair own publicatiou,
the authors give a review of various filler and of~their application In
the West, based'on publications In the "MashinostrOyoutye as, rubeshom*
and I'Vestnik mashinastroyeniya". There are 2 tables*
Card 1/1

AKIW.CRETp Leonid samoylovich;-YALTdR-..-,Leomid-UOimirovich;
CIIUDIIOVSKIY, Arkadiy Romanovich; PILIPFNFO,-r.-9,-, inzhof
reteenzent; BYEOVSM, A. I., inzh., red.; GOPIOKIIATPOLISWA,
M.S., tekhn. red.
(Use of plastics in technical equipment]Primenenie plastiche-
skikh mass v tekhnologicheskoi osnastke. Moskva, Mashgizt
1962. 155 P. (MIRA 15:10)
(Plastics) (Machinery industry)

USMAtedicine - Naval Var 1947
Medicine - Vereral diseases
"The Question of Aetiology of Salvarsan Icterus
According to the Data of a Base Polyclinic of the
Red Banner Caspian Fleet," M. D. Vayser, 5 PP
OVeetnik Venerologii i Dermatologii" No 3
Discussion of data leading to the conclusions that
cases of icterus (jaundice) from syphilis treatment
became more frequent after mapharsen vas used.
During the var there was a large number of liver
complaints in the fleet traceable to syphilis
treatment.
i(YT81

vity3' Ry
Gonorrhea
Treatment of a cute gonorrhen in men vitK nulfarAltim"de orepfirn ion-9 and penicillin.
Vast. ven. i dorm., No. 3, 1952.
Monthly Idst of Russian Accessioni, [Abrar of Congress October 1952 UNCLA.-.,SIFIED

PA 66/4AA6
vm/chd~klstrj --qyclohemee Aug 49
Oxi~ation-
OKinetice and Mechanism of the Slow Oxidation of
Cyolohexene," V. L* Vayser, Moscow Petroleum
Inst imeni 1. M. Gubkin, 4 pp
"Dok Ak Nauk SSSRO Vol L=' No 5
Gives time-rate of change of absorption oxygen,
02 In the fom: dxldt = kxl(l+-kZx) where the
k's are deternined after integration. Fram. this
fo~" and the following-. 2.3 log (k.lkz) (E1R)
(!r2- ) the energy of activation is found: E
25,000 k/cal (approx).; Submitted by Acad A. V.
Topchiyev 20 Jun 49.
66/4K-26

Preparation of cyclohaticne pemilde and deleinnna-
tion of the petoside number of Unsaturated hydrocarbons
L. N'jl5,r. Pokkuly Akad. R ON, 50
1111"). C), It'liv%em- If X, Ili I I %t.l~ 411 ... led t"
41111. 0 until 1111, 0 *.A, (A' it Ilp. At. I tthwll it
t% A, Sid,ject"I to lattilkhtlK %%lilt I I it W. ' f4st 'C' V~' %%Ill It
c ~.' t' ~ 4."1t V k t %wil ~ ter it I t V, t It- 11, . l, t '~ 111 PW,
'y,loilwxenr perovadf, W.. -11.1 1
Which v.111 lie qwol milt Ill Ill, Ill
Ill 4.11 1.mg I.. OW -still it tilld,
evc1ollexentille. A neir Method 0.1. fl'-v4-l"jKql f"r Ill-
'Iam. 4 the peroxide w, ,( isimit.l. I-,, i,:Ire
c ycl,Ate wite 6 a,ldcd A Lnmt it mut. t-f t't'.JIVdM1
IL.11110SAICSIV 1*1`111111L, .11111 the MINI., Attvt I Ill. %%itil
.Ill*:. AcOll indewc-of lit" K1, I, lit[Mr.1 kwk %ith
Wl).`i N N.irSO~ un,l the 11". 1, e.11"). ..~ U411A.
Tlic re,ult obijin-1 in (1111 111-11113.1' s4 jdju,wd by a cvr.
r-tion Ncwr which allowi for varwtoms lit the ctincis.
of ioxiiiie and of the gwroxide. Tht-,c courct-tifin facturs
wk;rC found exlierittientally frotit knowu ntixts. and -arv givvii
gr.tphically. It the 1wroxidt im. ii caled. in ml. 0 per
list S., the citirection facwr~ rangv j~ follow*: 1. 19
for prroxitle no. 21, for V5. ).3 lar 268. 1.33 lur
1.37 fow 9A), The uw of tlirw eittructimi f4ttiori give%
remilts well wilbin (lie exptl. crtur. G. M. K.

Alkylsth;n of some aromalls; hydi-ttsbonts with 4cp I V It fit
,vith the aid of a catalvilt based oil bolon fluoride It 1.
P41.1dy Akad. 70. 6A I
I1Ji:ih".-AIkvLi6m it( ttotlmff~ '.." I..,
Astir ell[, .110 a eafalyt. ishich - 4,
pirl.). fly cralm. -,f W' . 13C.Stilig In T4,11" 1111111
A,-- I " 9) A. T'j. Iwd -1114 thr 1 04. Ml fit
C,It, %.%. grom.ted hy 101 livAtiorof d C.6C,
-$fft 11,~4 Is. (IfIcti, .611.1 awd m a '(111rd #,.,, C,4 J.v 1~11,g
mto .1 Imilloto ol.-Iting in life I h,- , luo #:,
o-A na- 1-4~ ml. of HIM), 11,1. with IlF,, I M. 11)(0. ".$.1
1161 1111 'Ailil .1 1 1 5 1 af-upti-,
rAte it :41 IW, will, It i, wAT-1 to (h..
,411%, With C.U.. Ater file of L., I C It
tile fills-#") W-11111 111,01P I 9-tv IMAJ -4 1-
ter i.16 1). 2141 fu), j fill al"Vr ~:!O) , .. . .,sv I Iw -,I ~ I
pyotthirl i Ill fill ). It. '-118 75', identifiLd a, I'h,k:IfM, ,
i'me"d of X,tvr but 3 g. 111SICICNIV,
Similar re.triton of 1111NIC ith 11;110,141~, mi.l ife, kt-
M%ms g,t%-e .4, tile ol-titt pro,luct :01 oil.
"to) ;0*', d.- I)AW'S. Nil 1.5617 j PY
Utilil"I NIEP13); U II.,CJ),l-A1AIY41 jf~kvr but
,~mtjr. only in list. disolylethane. Xytene ii-inivir tit,-
Itat"ll g.tvc 32 list. AIMme -wg. 14 s;. 11mi"r pro-hict.
It. NVP WC11filiell aq distirlyletim-'r; a llj.%~O.
JO
"Ve 'out 'It' t4l- C"tAYLLtv, cklills. J fill. slitylvleilmitc,
G. M, h~I,j,,jj

q,
pprr-Imm 1-1 1
.011

Alkyludon at Savle ArOmiktk 0SYNTS COMPOMOdd Of
04
on FIvw4& CAW
f 11
Aid
W
h
h
-
tw
o
it
t
Y
t
Arrsylest
(in V. L Valiff, Doklady Akademil Nauk
SSSR (Hrimab of OW-Ardiltiny of Sciencri of the
USSR), nrw u-Y.. V. 74, Sept. 1, IQW, p. 57-N,

Ailing"&
u IS AT 10 Is 01fills' r A4
=10 0
fee 4606000 IL
1 0 u w Is
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2

VAYSER, VA., Icandidat tekhnicheBkikh nauk, dotsent.
Kinetics and mechanism of slow oxidation of c7clohezene. Trudy XII
no.11:221-244 151. (M12A 10:3)
(Cyclohaxons)

VAYSEP,, V.L.
USSR/Cheinistry - Alkylation 1 MAY 52
"Alkylation of Isopropyl Benzene'Witlf Acetylene
With the Aid of H PO BF and HgO Catalyst," V. L.
4" 3
Vayser, A. M. poll karpova
"Dok Ak Nauk SSSR" Vol LXXXIV, No 1, PP 71, 72
Two moles of isopropyl benzene combine with a mole
of acetylene-by addn to form ethylidenediisopropyl
benzene. The reaction was studied by varying the
time and quantity of catalyst (H 04-BF3 and HgO).
3P
Optimum yield (20-23%) was achieved by using 10
ml of catalyst per 100 m! of isopropyl benzene at
60 - 700 for 3.5 hrs. Presented by Acad A. V.
Topchiyev 4 Mar 52.
224Th

VAYSER, VA.
USSR/Chemistry - Alkylation I Jul 52
"Alkylation of Ethyl Benzene With Acetylene," V. L.
Vayser, A. M. Polikarpova
"Dok Ak Nauk SSSR" Vol LXM, No 1,PP 85, 86
Expt has shown that 2 mols of ethyl benzene add on
to one mol of acetylene. Presented by Aced A. V.
Topchiyev 28 Apr 52.
224T9

q 1-0
7 mean
Ivo Curn InStK'
4L AGUT RX-5
(1052).-Cill, ivxi pas-sed into a %ohi. of 86-344 S. MePh
contg. 5-40 mi. 11,P04 satd. with BFj; after usual washing

d. InCrCILSIng H2POrBFS Catalyst
the products were dis
from 5 to 20 mi. per 100 mi. MePh increas" the yield of the
alkyLite by only .3-75b; varying the reaction time from 4-10
lirs. does not affect the yield; a temp. of 60-70* sklipean to
_giyo~ best results, as lowering the temp. lowers the yield.
The highest vield of alkyhte. based on MePh consumed,
Was 59-M%.-when 5 mi. catalyst was used with go g. meph
in a 4-10 hr. reactiorl. 11, .111 C-,,Ls,!s 19- HgO was added to
tile 11,PO,-BF, catalyst. Thealkyl,,,tc ron%isted of MeC11-
(C1110fe-P)n Ll,, 29fl-W. b, to()
Similarly treated
iso-Pr'C'll, (coul. material) gave tile best yield of alkylate
(-'~'%) whe" 1() mi- c;lt;lIY5t WW; employed per 1()() ml
iso.
,
PriCsIL, and tile reactiall Was nin 2 hrs. ;it 6&-70a; higher
or lower tellipi., eq)cci,,jjjv the fermer, reduce the yields.
Tile product, b.
which sOllie 13, w3i Wild. illto fractions from'
isoj~jted. Illis
b4203-S*. lti~g"vcjjtjles
1 .3,1. (1 istribution of tile Sub'Aitu-
vIQ radical" %vitholit exPil. -Pport for thk. howevr
The rest of t1w prohict, -r.
-Ire iiiii(II-Iltili d. Tile pr luct,
c (x b.
fill
lik- "lot. Wt. thAn. ind
allalvsis.
G. M- Kosotapoff
S,

r4

-d WT~ ptiovrlariq ~,:W vat
vA
It
and ethy.,

V. L.
USSR/Chemistry - Alkylation
Card 1/1 1 Pub. 22 - 26/46
Authors I Vayser, .V. L., and Polikarpova, A. M.
Title t Acetylene alkylation of phenol in an alcohol solution
Periodical : Dok. AN SSSR, 97/4, 671-673, Aug 1. 1954
Abstract I Experimental data are presented on acetylene alkylation of phenol
in an alcohol solution. It was established that the number of
first fractionation and polymer products obtained depends upon
the catalyst concentration, reaction temperature, rate of acetylene
flow and time of reaction. The two stages of alkylation reaction,
are described. One USSR reference (1950). Tables.
Institution The I. H. Gubkin Petroleum Institute, Moscow
Presented by: Academician A. V. Topchiev, April 16, 1954

L.
-gut
acid ='1l? _--- I -
8VT -V-V-.-R~na~r and W -T-. 7a
~u ia H." LIE in prr-ez--e -oz-ftpOt
lino (1), mo-F. + tr9r) (11). Rtao-Br. -4 .4ici-RUT
Ll rb-

IUSSR/Chemiotry catalytic reaction
'Card 1/2 Pub. 22 - 20/52
Authors I Vayser, V. L., and Ryabov, V. D.
Titlo, S The mcchanism of alkylation reaction of phenol with acetylene in the
prezenco of 'Y04 . DF3 and 111~-O catalysts
Dolk. AN SSI-R 100/2, 271-274, Jan 11, 1955
Abstract L-periments ware cond"cted to dutcrW.ne the muchrmisii-of phonol
alkylation vrith acetyleno in an aq t, ous acid solution of an 1131,01 -DF,1
and 11CO catalyst. It uras found that 'Voll,'B"I lor's 110110 of US
activity and in spite of the fact that tho molar watur/c,-Laly5t
ration was only 12 the yiold of the reaction product - 4,10-
dioxydiphenylothane - was appro:cimately I;Q'J' of the oretical,
Institution ......
Presented by: Acadentician A. V. Topchiev, July 7, 1954

Periodical
Card 2/2
Abstract
Dok. AN SSSR 10012, 271-274, Jan 11, 1955
Pub. 22 - 20/52
The structure of the reaction product was determined by oxidation
of its dimethyl ether. The role of water in the reaction is expiaincd.
Thirteen references:' 2 USA; 2 German; I English and 8 U35R
(1881-1953). Drawing

~;, 11 ~ -:
f , , -
, 5-N-- ; ~--- -"*
-r,.' ;
-~,

- -~ f ~,, - - - -. "",
11 IV v - r ~~ \11

'Periodical I Dok. Ali SSSR 106/2, 271-274, Jan 11, 1956
Abetwa,Ot I Experiments were conducted- for the purpose of obtaining p-methylstyrone
from asyr=etrical p)p-ditolylethane and to investigate sow, catalysts
under conditions of cracking. The.basic constants (boiling point, den5ity
and viscosity) of p,p-ditolylethine, after I-everal vacuurn distillations,
were estp-blished. The results obtainud during the application of a spithu-
tic aluminum silicate catalyst (Al 203 : SiO 2 = 1 : 1) are lirted. The
offect of, temperature on the crnclkin!~ charac turi f:- tics is analyzed. Sf--ven
references: 2 USM, I Germ., 3 USU and I Canad. (1923-1954). Tphle;
1~-,raphs; din-wing.
In-,;Utution 110scow Petrolcur, InstiLuto ii-a. I. M- Gubkin
I'ruscnL~A by: tcn(!tzri-d~-ian A. V. Topchiyev, J111Y 11, 1955

I
~ I .. I f i
\ .:I-, - ~l --

- - - - . - - - --- -1 - - -- I -- -,-
. --I - ll~ - '! - - - -
~~ -1_1;1_~'-!t,~~- i w . -- ... .--
- ~ .. , ~;, I .-.
k I-
. t

AUTHOR VAYSER V.L. - 20-1-24/514
TITLE Alkylation of i- and 8-Naphtols with Acetylene.
(Alkilirovaniye atsetilenom a-i B-naftolov -Russian)
PERIODICAL Doklady Akad.Nauk SSSR,1957, Vol 115, Nr 1,pp 91 - 93 (U.S.S.R.)
ABSTRACT The alkylation was carried out in a reqctor with a solution of na-
phtol in 50 ml ethyl or butyl alcohol and a catalyst H 3PO4TBF
+ 1g
3
mercury oxide. Acetylene was supplied from a steel flask with con-
trollable speed. The testa no.1,2,17 yielded 41-W; alkylate.Thooe
as well as the tests no-4,8,5,9 show that they may be reproduced in-
dependently of the application of ethyl or butyl alcohol as solvents.
The optimum yield of alkylate was 68% at an 18 % concentration of the
catalyst and a temperature of 65-700C.The optimum temperature was
75-8ooC at a 14% concentration of the catalyet.Increasing the speed
of the passage of acetylene from 2 1/hr reduces the yield of the al-
kylate only by 16%. The alkylate is difficult to solve in benzene,
but easily soluble in acetone,acetic acid,ether and chloroform: in
carbon tetravhloride and n-heptane it is soluble on heating; it is
neither soluble in alkpLli nor in a weak acid. The alkylate is iden-
tified as ethylidene-di-B-naphtol-oxide and its formation schemati-
cally demonstrated. This heterocyclic compound faay be considered as
a derivative of the xanthene 9-methyl-1,2,7,8-dibenzoxanthene (struc-
tural formula given) or of the p ran 4-methyl-/di-naphto2111":2
3;
,
1121:5,6/-pyran (structure given~-Such a compound was produced by
Claisen from condensation of 8-naphtol and paraldehyde in the pre-
Card 1/2 sence of HC1. From the oxidation of the alkylate crystals with a

Alkylation of a- and B-Naphthols with Acetylene. 20-1-24/54
melting point of 1940C were obtained.This reaction proceeds in a
manner that the radical is oxidized into a carbonyl group and a
corresponding ketone (structural formulae given), is developed,na-
melY C21H1202 i.e. dinaphtho-f~-pyrone. Wentzke and Nieuviland did
not succeed inisolating such crystal from the solution obtained.
With a-and 8-naphthols they obtained a certain amount of crystals
with a melting point of 1730C.According to t.'err acetal develops from
B-naphthol,whereas ethylidene dinaphthol oxide develops from a-naph-
thol.They did,however,not gJve a sufficient explanation for this.The
alkylation of a-naphtol was carried out by the author under the sa-
me conditions as that of 2-naphthol.The alkylate is neither soluble
in benzene nor in camphor which renders the determination of its -no-
lecular weight difficult.
(2 illustrations, 1 table,3 Slavic references)
ASSOCIATIOIT Moskovskiy neftyanoy institut im. 1. M. Gubkina
PRESENTED BY TOPCHIM A.V. Member of the Academy, K-.rch 15, 1957
SUBMITTED 16.6.1956
AVAILABLE Library of Congress.
Card 2/2

AUTHORS: Ryabov, V. D.,_YUporj_V,. L. 20-118-5-32/59
TITLE: Catalytic Cracking of Some Asymmetric Diarylethanen
(Kataliticheskiy kreking nekotorykh nesimmetrichnykh
diariletanov)
PERIODICAL: Doklady Akademii Nauk SSSR, 1950, Vol. 118, Nr 5, pp. 964-966
(USSR)
ABSTRACT: This cracking makes it possible to produce vinyl-aromatic
compounds with a high yield, this method being superior to
other methods. It consists of two stages: a) the synthesis
of diarylethanes, and b) their cracking by way of aluminum
silicate catalysts. Besides the aromatic compound and
acetylene no other reagents are needed. In previous
publications the authors investigated the catalytic cracking
of 1,1-(4,4'-dimethyl)diphenylethane and of 1,1-(4,4'-di-
-isopropyl)dipheny-lethane (references 1,2).-The present paper
shors the results of this reaction of further asymmetric
diarylethanes. The following compounds with their constants,
yields and methods of production are treated here: 1,1-(4,41-
Card 1/3 -diethyl)-diphenylethane. It was produced from the alkylation

Catalytic Cracking of Some Asymmetric Diarylethanes 20-118-5-32/59
reaction of ethylbenzene by acetylene and had a melting point
of 164 - 1670C/lo mm after a double distillation. The 133 -
1340C/748 min fraction consisted of ethylbenzene. The 93 -
950C/38 mm fraction was 4-ethylstyrene with 12,5% diethyl-
benzene. For the perfect identification of the first
substance its dibromide was produced as white acicuIar
crystals with a melting point of 65,50C. 1,1(3,3; 4,41-
-tetraphenyl)diphenylethane (ethylidene-di-o-xylene) was
produced by the alkylation0of o-xylene with acetylene. The
cracking took place at 550 C. The 55-55,50C/36 mm fraction
was o-xylene, the 94-1040C/36 mm fraction was a mixture of
vinyl xylene and ethyl xylene, the 105-1o60c/36 mm fraction
was 3,4-dimethylstyrene.
1,1-di-(2-naphtyl)ethane (!ethylene-dinaphtyl) was produce'd
by alkylation of naphtalene with acetylene in a solution of
carbon tetrachloride. It is a highly viscous transparent'
substance, fluorescent green, boiling point 236-2380C at 3 mm.
The cracking temperature was 5500C. For the identification 0
of the 0-vinylnaphtalene the filtrate was brominated at -2o C
after crystallization. White acicular crystals with a melting
point of 86-86,50C were obtained. Thus the chemism of the
Card 2/3 cracking of the respective diarylethanes is analogous to that

Catalytic Cracking of Some Asymmetric Diarylethanes 20-1-18-5-32/59
ASSOCIATION:
PRESENTED:
SUBMITTED:
which had been found in previous publications by the authors
(references 1,2). There are 7 references, 3 of which are
Soviet.
Moskovskiy neftyanoy institut im. I. M. Gubkina
(Moscow Institute for Petroleum imeni I.'M. Gubkin)
October 8, 1957, by A. V. Topchiyev, Member, Academy of
Sciences, USSR
October 8, 1957
Card 3/3

20-118-6-22/43
AUTHORS: Vayser, V. L. , Ryabov, V. D.
TITLE: Alkylation of Naphthalene, /3-Methyl-Naphthalene and Tetra-
line With~Acetylene (Alkilirovaniye naftalina, A-metilnafta-
lina i tetralina atsetilenom)
PERIODI CAL: Doklady Akademii Nauk.SSSR, 1958, Vol.118, Nr 6, pp.1126-1130
(USSR)
ABSTRACTt The authors who occupied themselves with naphthalene-alkyla-
tion (r'eferences 10 2) were of opinion that this could not
be achieved-because the naphthalene-molecule consists of
2 cycles of different character, viz.of an aromatic and an
alicyclic one.. The authors of the present report, on the
other hando maintain that naphthalene has simply one stable
molecule (rule by Fris). After varinus tests they were in
a position to state that the solvent plays a decisive part,
here. With alcohol the alkylation (catalyst H PO -BF 3) could
not be effected, but it was achieved with chlgroform and car-
bon tetrachloride. Alkylation of naphthalene. The conditions
Card 1/3 of reaction, together with the test results, (table 1) are

20-12,4-22/43
Alkylation of Naphthalene, A-Methyl-Na#thalene and Tetraline With Acetylene
given in a kind of experimental part. The maximum experimen-
tal temperature was 50 to 550C, the concentration of the ca-
tallr8t 16 $. Molar ratio naphthalene: acetylene f- 1 0. The
alkylate forms at room-temperature a scarcely yellow trans-
pareni soiidified mass, which is soluble in benzene, chloro-
form and ether. The alkylate could not be oxidized. The con-
firmation of the structure C22 H16 (ethylidene-dinaphthyl)
was achieved by means of its cracking. P-Vinyl-naphthalene
was isolated from the products of the latter. oc.-vinyl-naph-
thalene was not proved. Alkylation of 0 -methyl-naphthalene.
The results given in table 2 were achiev6d under equal condi-
tions. The product is ethylidene-di- A-metliyl-nafthalene. It is
a thick, green, viscous liquid which is soluble in benzene,
chloroform, carbon-tetrachloride and n-heptane; irsoluble in
alcohol6 Alkylation of tetraline. Temperature of rtactioni
60 - 65 C. The test results are given in table 3. Thq alkylate
boils at 214 to 2160/5 mm. The product is ethylidene-ii-tetra-
line G,2H26* The alkylate i-s similar to the previous one,
but pa e yellow. There are 3 tables, and 6 references, 3 of
Card 2/3 which are Soviet~ ..

AUTHORS- --Vayser, V, L., Ryabov; V. D Z! 0 14, /22
TITLE: Alkylation of Phenol by Acetylene Under Elevated Pressure
(Alkilirovaniye fenola atsetilenom pri povysbennom davlenxi)
PBRIODICAL: Doklady Akademii nauk SSSR, 191:8. Vol., 121, Nr 4,
pp. 648 - 651 (USSR)
ABSTRACT: This reaction was for the first -time investigated by the
authors at atmospheric pressure (Refs 1 - 5). Water and
ethanol were used as solvents for phenol (Ref 2). In the
water medium which guarantees a more selective process of
the reaction, phenol reacts with acetylene by a formation
of acetaldehyde. The yield of 1,',-(4,4-d1oxy-)--diphenyl
ethane does not exceed 50% of the stoichiometrically computed
amount. In order to clarify the influence of pressure ana
to find the optimal conditions of alkylation under pressure*
experiments were carried out in a rotating autoclave., By
application of pressure the concentration of acetylene in
the gas phase may be increased by the manyfold. A great
disadvantage of the rotating autoclave is that it is ncT
Card 1/4 possible to maintain the pressure on the same level. An un.

Alkylation of Phenol by Acetylene Under Elevated S011/2o - 121-4 -2 -,/:54
Pressure
dangerous reaction can be brought about without a particul;Lr-
solvent for acetylene (nitrogen); vnpors of the reaction mixtijf-
served for this purpose,. The authors applied the mentioned
method with full success,, The autoclace (250 cm3 capacity).
made of stainless steel was loaded with a mixture of phenol,
solvent, a catalyst H 3PO 4" BF3 and HgQ,, before loading the
autoclave air was removed by blowing through acetylene., The-i
acetylene was pumped in until 20 atmospheres of excess
pressure were reached., Figure IA and table 1 show the de
pendence of absorption velocity of acetylene on the temperature.,
The higher the teiperature the lower will be the pressure
corresponding to a minimum velocity of absorption. The
optimal conditions of reaction are 110 - 1200 and 20 16
atmospheres of excess pressure. Table 2 shows the dependence
of the yield of 1,1-(4,47-dioxy) diphenyl ethane on the
amount of the catalyst, The yield decreases only inconsiderably
with a reduction of the amount of the catalyst, Figure 1 B
shows the dependence of the absorption velocity of acetylene
Card 2/4 on the amount of the catalyst. The mentioned velocities

Alkylation of Phenol by Acetylene Under Elevated 3011/2o-121-4-21/54
Pressure
are about the same in all cases. Table 3 shows that a
catalyst used once has about only half the activity of
a fresh one. An addition of mercury restores its activity.
There are 1 figure, 3 tables, and 7 references, 7 of which
are Soviet.
ASSOCIATION: Moskovskiy neftyanoy institut im. I.I,',.Gubkina (Moscow,
Petroleum Institute imeni I.M.Gubkin)
PRESENTED: March 22, 1958, by A.V.Topchiyev, Member, Academy of
Sciences, USSR
SUBMITTED: March 20, 1958
Card 3/4

L-OV/20-122-3-24/57
XTJTHORS: Topchiyev, A. V. , Member, Academy of Sciences, USSRj layser, Y. L.
TITLE: Hydrogenation of Some'Unsymmetrical Diaryl Ethanes (Gidrogen4_
zatsiya nekotorykh nesimmetrichnykh diariletanov)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 122v Nr 3, pp 409-411
(USSR)
ABSTRACT: by the alkylation of toluene, isopropyl benzene, diisopropyl
benzene, phenol, cresol, P-naphftl by means of acetylene and
the catalyst H 3P0 4' BF3individual compounds - diaryl ethanes
with a common formula Ar-CH-Ar or HO-Ar-CH-Ar-OH i. e. oxy-di-
CH3 3
aryl ethanes were produced.
The authors carried out the hydrogenation of these compounds in
an apparatus by Musayev-Gallpern with an industrial catalyst
Ni on kieselguhr at increased pressure and temperature. Further-
more the hydrogenations of 1) ethylidene ditolyl, 2) ethylidene-
diisopropyl benzene, 3) ethylidene-di-diisopropy"L benzene, 4)
Card 1/2 phenol-alkylate, 5) ethylidene-di-o-cresol, and 6) P-naphthtl

4ydrogenation of Some Unsymmetrical Diary! Ethanes
/ r:
SOV/20-122--zl-24'.)7
alkylate are discussed in detail. The constants of the Droducei
compounds are mentioned. 'The hydro-compounds produced for the
first time by this method may serve as basis for a detailed
theoretical and practical investigation of the hydrcgenatien
reaction of diaryl ethanes. There are 5 references, 1q of which
are Soviet .
ASSOCUTION: Moskovskiy neftyanoy institut im. I. M. Gubkina (Moscow Petroleum
Institute imeni I. M. Gubkin)
SUBMITTED: May 29, 1958
Card 2/2

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175 copies Lict Of -Ut'~,O*r'.,' 01ir", TIT 21-2.,, (2,-, ~i tics)
(',,'L, 27-59, 11~3)

uYsBEY11, S.G. (14oskva)
Comatose states. Hed.sestra 18 no.7:17-22 JI '59.
(KIRA 12:10)
(COMA)

50) BOV/20-125-3-22/63
AUTHORS: Vayser, V. L., Ryabov-, V. D.

TITLE: 1-
Alkylation of 1,1-(414 Dioxy)-Diphenyl Ethane by 19obutylene
(Alkilirovaniye-1,1-(414 1- dioksi)-difeniletana-izobutilenom)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 3, PP 547-548
(USSR)
ABSTRACT: The process mentioned in the title has been thoroughly investi-
gated for mononuclear phenols. The alkylation of binuclear
phenols is, however, not described. The authors point out again
the production method and the properties of the phenol men-
tioned in the title (empirical formula C 14H1402). The tempera-
ture of the reaction in question usually amounts to 60-900
(Ref 3) at which the phenol is melted and no solvent
necessary. However, the reaction should be carried out at ap-
proximately 130 0 without solvent, in which case C 14H1402 could
be
de8omposed in acid medium. Therefore the authors chose
-
15 20 and used thioether as solvent. Isobutylene was obtained
by means of dehydration of isobutyl alcohol over aluminum oxide
Card 1/2

1- SOV120-125-3-22163
Alkylation of 1,1-(414 Dioxy)-Diphenyl Ethane.-by Isobutylene
0
at 36o . The details of the reaction process are described.
Table I shows the results of the initial experiments. The frac-
tion 216-219 /5 mm is a solid yellowish substance which is well
soluble in paraffin-, naphthene- and aromatic hydrocarbons. The
substanoe obtained was analytically identified as 1,1-(414 1- di-
OXY-515 1- di-tert.butyl)-diphenyl ethane (structural scheme
given). The optimum reaction conditionst concentratiog of the
catalysts 15 percentages by weight, temperature 18-20 , molar
ratio isobutylene i dioxy diphenyl ethane - 4th supply velocity
of.the first 2-3 1/hour were determined by the second experi-
mental series (Tabl-e 2),. There are 2 tables and 3 Soviet ref-
erences.
ASSOCIATION: Institut neftekhimicheekoy i gazovoy promyshlennosti im. I. M.
Gubkina (Institute of Petroleum-chemical and Gas Indus'try
imeni 1. M. Gubkin)
PRWENTED:. October 24, 1958, by A. V. Topchiyev, Academician
SUBMITTED: October 24, 1958
Card- -2/2

5 0)

'AUTHORS: SOV/20-1-215 -4-291/74
Vayser, V. L., gyabov, V. D.9
--Ofisfr-ou~mova, A. K.
TITLEt Catalytic Condensation of 9-Methyl-(1$2), (7,8)-Dibenzoxanthene
With Ammotia (Kat alit i c'heskaya.-kondensat a iya.. 9 -metil -~ (1, 2),
(7,8)-dib.enz'oksantena s ammiakom)
PERIODICAL: Doklady Akademii.naak..SSSR,.1959, Vol.125, Vr 4,--pP 799-800
(USSR)
ABSTRACT: The authors obtained the substance mentioned in the title (1)
by alkylation of V naphth& with acetylene in an alcoholic
solution in the presence of the catalyst H 3 P-04'
BF3and one
.
gram.meroury.oxide (Ref 1) (see scheme 1). Compound I forms
white crystals with.a melting.temperature of 1730-and a.boiling
point of 268.-269/8 mm,.which are well soluble in acetone,
acetic acid.and ether and soluble on heating in n-heptane and
benzene. The interaction between I andammonia is explained by
means of a scheme (Ref 2). A derivative of acridine 9-methyl-
-(192), (7,8)-dibenzo-9,10-dihydroacridine is to be expected 4a
a result. The authors carried out this reaction on a device
Card 1/3 (Fig 1). Many experiments were necessary for determining the

Catalytic Condensation.of 9-Methyl-(1,2), (7,8)-Di- SOV/20-125-4-29/74
benzoxanthene With Amm nia.
optimal conditi onst temperature 11.4700, at which on.the one
hand no unreacted product.(as e. g.-'at 350-4009).is obtained
and on the other- hand, however,, (.I),, a, not decomposed product
(as at 5000).,The-volume rate of the.added.benzene.solution
of (I)..amounts..to 0-4/hour. The.reaation proceeds under.milder
conditions. and yields better results if.in..1 or. 2 experiments
an.already used catalyst. is..taken.,In.the case.of.distilling
the reaction. pr-oducts..in most caseB..t*a--..fractions, are. obtained.
A.90 - 1400/2 mm. uh-ich.'s,olldified to-a--.white crystalline mass
and B. 240 - 2900/2 mm. wh-ich b.ecomes a,yellow crystalline mass.
After a car-eful.fractionation and.re-arystallization.white-
crystals with a melting point of 112c)-and a boili-ng point of
131-1320/2 mm, were produced from fra.ction A. The authors
identified them as -0-naphthylamine..By similar operations light-
yellow crystals were obtained,from fraction.B with a melting
point of 2130 and a boiling point of 251-2530/2 mm. These
crystals were identified as 9-methyl-(1,2), (7,8)-dibenzo-
-(9,10)-dihydroacridine C 22H17 N. The authors were the first to
Card 2/3 obtain this substance. There are I figure and 1 Soviet reference.

5/020/60/132/02/29/067
14 00 BOII/BO02
AUTHORSs Vavser~ 1. L yabovg V._ o, Piryatinskiy, B. M.
TITLE: The Production of Vinyl Phenolsiby the Catalytic Cracking of Some
Dioxydiarylalkanes I
PERIODICAL: Doklady Akademii nauk BSSR, 1960, Vol. 132, No. 2, pp~ 349-352
TEXTs The synthesis of a number of vinyl phenols hitherto has not been put
into practice or has been little known. Data on this subject are contradictory.
In their paper the authors suggested catalytic cracking of dioxydiarylalkanes
in the presence of an aluminum silicate catalyst as a new method of producing
vinyl phenols. For this purpose they used a continuously working apparatus
(Fig. 1). The following substances were used for cracking at 5500, 10-W,411-
dioxy)-diphenylethane (1), 1,1-(4',4"-dioxy-51,5"-dimethyl)-diphenylethane (2)
and 2,2-(41,4"-dioxY)-diphenylpropane (3). The authors give the methods for the
production of all three substances, The solvents used for cracking dioxydiphenyl-
ethane were acetone, sulfuric ether, phenol, and acetic acid mixed with benzene.
The best results were obtained by using the aluminum silicate catalyst with 50%
of Al 203 and ether, or a mixture of acetic acid and benzene, On d-istillation of
Card 1/3

The Production of Vinyl Phenols by the Catalytic S/020/60/132/02/29/06-1
Cracking of Some Dioxydiarylalkanes BO11/BOO2
the catalysates almost always three fractions developed% 1. phenol; II. phenol
mixed with ethyl phenol and p-vinyl phenol; III. p-vinyl phenol with slight
admixtures of ethyl phenol. Under the condition of selective cracking and of a
high concentration of p-vinyl phenol, p-vinyl phenol crystallized from fraction
III. in the form of palish green lamina. The yield in fraction III. and the
conversion of dioxydiphenylethane into light products increased with a higher
volume velocity of the dioxydiphenylethane solution. The authors describe some
of the most successful experiments. After several processes of recrystallization
of benzene, p-vinyl phenol crystals with a melting point of 71-50-720 were
obtained. Crude cry3tals dissolved easily in benzene, alcohol, and ether, and
not so well in water. After left standing in the vacuum exsiccator, for a short
'time, the solubility was reduced due to polymerization. The crystals dissolved
in lye turned the solution brown. An admixture of p-vinyl phenol to con-
centrated H2SO4 gave it a vividly red color. An admixture of a ferric cblori-de
solution to the aqueous solution of p-vinyl phenol gave it a brownish green
color. In the dark, p-vinyl phenol rapidly polymerizes into an indissoluble
white resin., In a protective gas however, it keeps u to 50 hours and morel On
cracking dioxydimeh-ylethane (ethylidene-di-o.-crenol5 in acetic acid benzene,.
the following substances were obtainedi o-cresol, 4-etbyl-o-cresol, and 4-vinyl-o-
Card 2/3

The Production of Vinyl Phenols by the Catalytic 30432 S/020/60/132/02/29/067
Cracking of Some Dioxydiarylalkanes B011/B002
cresol. The latter is a white, crystalline substance with a melting point of
730-740- It is soluble in ordinary solvents, and under the action of air trans-
forms into a sticky resin from which after treatment with benzene the polymer
of 4--vinyl-o-cresol precipitates in the form of an indissoluble white powder.
Dioxydiphenylpropane (diphenylolpropane) was obtained from a commercial
product supplied by GIPI-4 (Gosudarstvennyy nauchno-issledovatel'skiy i
proyektnyy institut-4, State Design and Planning Scientific Research Institute-4)
by distillation and recrystallization. Cracking was the same as above, but was
conducted in acetone-benzene, White, scale-like crystals of p-isopropenyl phenol
with a melting point of 80-50 was obtained from the catalysate. Exposed to air
they transformed into a red redn difficultly soluble in organic solvents., There are
I figure and 7 references, 2 of which are Soviet.
ASSOCIATION: Institut neftekhimicheskoy i gazovoy promyshlennosti im.. I. M,
Gubkina (Institute of Petroleum-chemical and Gas Industry imeni
I. M. Gubkin)
PRESENTED: November 5, 1959, by A. V. Topchiyev, Academician
SUBMITTED: Rovember 5v 1959
Card 3/3

SAYSENBERG-,
Doe phys-Math Scix Diss -- "Experimental Investigation of the
properties Of ~U-mesons". Dubna, 1961. 9 pp, 21 cm (Joint Inst of
Nuclear Research High Ener Lab), 160 oppiess Not for sale (KL,
No 9, 1961, P 174, No 24238TY. Z61-5304_V

TARNOVSKIY, I.Ya.; VAYSBURD, K.A.
Selecting appropriate functions in appl7ing the Ritz Method to the
press-working of metals theory. Izv. vyo. ucheb. zavo) chern.
met. no. 1:73-83 t6l. (MIRA 14:1)
1. Urallskiy PolitW"icheokiy institut.
,(Metalwork) (Deformations -(Mechanioe))

2
S~0050
6Y61/000/007/002/005
B124 E206
ATTH~ORSs Vayser, V. L., Ryabov, V. D., Bolotin, B. M.
TITLE& Synthesis of polycarbonates and epoxy resins on the basis of
1, 1-(4, 4-dioxy)-diphenyl ethane
PERIODICALi Khimicheskaya promyshlennost', no. 7, 1961, 24 - 25
TEXTs For the manufacture of epoxy resins, polycarbonates etc., the
authors propose, instead of diphenylol propane, another diphenol, i. e.,
1,1_(4,4-dihydrox~-diphenyl ethane (D), which had already been produced
in good yield in 1904 by condensation of phenol with acetaldehyde. In
previous papers (Ref. 2s DAN SSSR, 21, No. 4 (1954); Ref. 3: DAN SSSR,
i-01, No. 5 (1955); Ref. 42 Sbornik trudov 9-y nauchno-tekhnicheskoy
konferentsii Moskovsk, neft. inst. 1954) the authors described the synthesi
of this compound by condensation of phenol with acetylene in aqueous or
alcoholic solution in the presence of an acid catalysti 2