SCIENTIFIC ABSTRACT VORONKOV, M.G. - VORONKOV, N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001860920006-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

209449
S/079/6 1/0311004100 3/00
B1 18IB206
L100
AUTHORSt Toronkovp M.G. and Rabkina, 8,M.
..........
TITLEs Studies in the field of alkoxy silanese 1~
XVI. Reaction of tetraalkoxy silanes wit6 keteines
PERIODICAM Zhurnal obshchey khimii, va 31t.no. 4P 19,~19 1259 1265
TEXTt In addition ot their paper (Ref. 14 ZhOKh.;,
3-0 955 (1960)), and
considering the available methods of synthesizing aldehyde and ketone a,,e-
tals, the authors of the present paper studied the eft~ct of substitutiag
methyl radicals for the ethoxy groups in tetraethoxy ailane on. acetali-
zation. For this purposeq acetone and methyl-ethyl ke:tone~were allowed
to react with methyl ethoxy silanes of the formula
(C11 ) si (00 H (ri.&1-3)- Substitution of methyl gr"ps Cor ethoxy groups
3 n 5 4-n
on the silicon atom considerably reduced the capability of'efhoxy- sil~ae�
to acetalize ketones. The diethy'l ketal yield in thel~lreaotion of metbyl-
-ethyl ketone with dimethyl dieth.oxy silane (n-2) waa' quitie:lov, wherEa!~
no ketal was formed in the reaction of acetone with t:r~imet~yl ethoxy BJ...
0 iard I Zf

3/07 6i10311604100,21006
Studies in the field of alkoxy B11eYB200
lane. As acetals in general, and ketals in particulart sp1tt off alcohol
at elevated temperatures, the synthesized acetals wer:91,1distilled in the
presence of Na or its alcoholatep the aceta1s.otherwisi-,-:be#g contamina-.ed
by alcohol and the corresponding ex&-uneaturated ether!, ThIp katals c-4'
cyclohexanone and its derivatives readily split off alaoho:~ during di-
stillation, and are converted to I-alkoxy cyolohexenes, Thin ability,of
Ill-dialkoxy cyclohexanes easily yields i-alkoxy cyclohexe~es which (re
formed immediately from cyclohexaLnone and tetraalkoxy~::Bilanesa
n 0 + Si(OR) H+ :~ C~>_on ;.I- (no , Si + nROH.
4 M ( : :"j.Pn n M
CD= A'
Synthesis was performed by simple distillation of a mixtur.e of cyclohexa-
none and the corresponding tetraalkoxy silane in theiiprese'nce of H PO
3 4'
This mixture had previously been,boiled,for 8-14 hr.,i ffeatlZ all. the al-
cohol is first distilled off, and immediately afterwards ihe reaction pro-
duct containing some alcohol, It was purified by di~tilla'tion on Na, most
Puitably at low pressure. Five I-alkoxy cyclohexehe,~.wer ;jj synthesize~l in
Card 2/0

3/079/6 31/d~,4/003/0065.
Studies in the field of alkoV Bi'l 081,
this way with yields betwein' 55 a~d 70% The, 'presence of a cer-
tain quantity of alcohol in the-reaction-product,is important in acetali-
zation. It was shown .that the reaction of teira -alk;xy~jeil&Aes with ali-
phatic and alicy~lioi ketones takes' 'place" In the piesenaie of''anhydrous
orthophosphoric-acid as a.catalyat,and.in,the absence 6f aldoholeg for-
ming the' oo"rrespending ketals. Eight keitidi waie ;btained and identified.
i-1i_-tbis.-iwayj, as,-well,.-as, the, acetal of butyraldeh~de. The opinicn expressed
e aceiaftzed mor6 6a' iT uiaa* ketones, may
n..publications that.aldehydes.ar si,
qn~y be-43~pliine.4 b3~ the f a,ct th~t'ke tali; hy-drolyze irioi4a ra~iai thane il-
l . I I! ~ Y
dehyde -acetdlso Yu.No' ftaAonov 'is. thinlod for ia*ing ~he o4a,lyse-so
There are I .-figarep .1, table I and126 ref~r~neep. 1 14' So-~Let-bl.oc and .121
n'on--~'Sov'iei!--bloo'A;- The ~. r6fer'e'~cib, to Engftsl~'-Lngiiaga !publications .read
4LB- ioll6ws S' -, Hits, Carswell p H.! Adkins I JJLmadhem,Soc r, 9 150,. 235 9 1 (1928))
0. T4 Pf ~if ei,-.9,.'--Adkinst-'J.Am&Ch~m4'So6o"$* 539 1043-0931)'0
ASSOCIATI6NV -Ifi9tituV,,kh1iA s"1l1kht6v.Ak&deih1i~'ia-1L; SSSA
(tnetitiite " of - Silicate Chemis try of. th6 Acadplgy of
-'Seleices USSR),
3

I IVAII it Hi
Apt 11, 11111,14 11 ;,fik".1
W4 U
SERGEMA, Z.I.; MATVFMAP Z.M.; VORONKOV., M*G*
-------------------
Organosilicon ethers of Jwtoxlwa and of benzaidehyda and
o-hydroxybezaldebyde oxbies. - ~WWr.obkbin, 31i no~60.017-
2023 Je 161 (ICU 14:6)
1, Laningradskiy goaudariftennyy universitet i Distitut khImii
silikatov AN SSSF..
(Silicon oigaa1c, compounds) (Ketones): ~(Benzaldehyde)

.616 1111 11 Ii,11 I NL;.I
22435
SI/080/61/034/00;7/010/016
D223/D305:~~;
AUTEORS: Voronkov, M.G.p Sharonovp GaPop and Dolbinvi T.V.
TITLE: Effent of the nature of sulpho-organic~oompounds in
041 on the frictional wear of metallicisurfaces
FB"RIODICj',L: Zhurnal prikladnoy khimiiq v. 34p no. 7 1961
1562 - 1569
TEXT: The in"lal wear of new machine parts duringi.the,"Ir-anning
ill" time can be accelerated by use of sulphurated 6ils;: actual
trials have given a time period of 1.5 - 2.0 hours..(Ref. lt G.P.
Sharonov, V.S. I-Tikandrov, Tankiet, 9, 54,11957). In.this connee-
tion investigation into the effect of sulphlar compbund6 in oil .,n
running-in and initial machine wear is im portant b oth f'rom tile
theoretical and practical aspects. The ariiele g~~voe IUhe reaults
of investigations on sulphurated. oil, its natux~~-, ,jnd -iurv,:-ys new
sulphurous additions to the oil. The bulphurat ed oilo "industrial
50" and "spindle AV" were produced as followat To 'the tLeated jil
Card 1/7

22435
S/080/61/04/00:7/010/016
Effect of the nature of D223/D305:.'';
in a bath at 130-1350C, slowly a:ad with continuous !stirring 4.5 wt.
% of sulphur flour was added the additions takii~g 2 hours -
and gradually raising the oil-temperature to 15000~1 Th6,oil was
kept at this temperature for 24 hours~ oontinuotisly stirring, the
total heating time being 28 hours. The sulphurateCoil-11industrial
50" was obtained containing 4.23 1~ of sulphur (Ref !~ 3:~Yoj.Ya. An.-
ten, N.V. Mitrofanova. T.N. Abramova, C.P. Sharonov, V.S, Nikandravy
Avt. svid. 20319, 195~). The testing on copper sheets ahowed the
disappearance of corrosion for "spindle AV" after 9 hotirs of sul-
phuration and for "industrial 50" after 6 hours. The removal of
corrosion by the action of sulphur and with increa6e in the sulphu-
ration time of oil is probably due to the transit16n o:t free sul-
phur into compounded, as well as the elimination from the oil of
H2S and decomposition of mercaptans, since H2S is a product of the
reaction of sulphur and hydrocarbons# The fricti6qexperiments are
then described using machine TJI and lubricant MT~1~, obtained from
sulphurated and emba natuTal crude oil. These oils;hadisimilar vis-
cosities and contained 11.11. and 0.41 % of natural'sulphur respec-
Card 2/7

22435
S/08 61/034/ob7/010/016
Effect of the nature of ... D223YM305
tively. In addition to emba crude oil, sulphurate&!oiLOas added
containing 1.11 % of sulphur, of which:0.41 % was I IlatUlal sulphur,,
al
The frictional drum was made of steel 40X having miciohardneen
300-310 while the brake was made from steel 45 which after heat
treatment showed a microhardnese of 660-680. Pig.~2 shows the
curves of temperature change of the surface laye~,of the brake olid
frictional movement against the working time of steel samples.
Since experimental time was 8 hours per day the cuivesoshow dis-
continuity. It follows that pretreatment of samples using emba oi'
BIT-16 is complete in 68 hours (curve 3, PA g. 2). ff~ this time the
frictional movement and temperature of the surfacejayer,measured
by a thermocouple have reached their minimum values. The pretrea-t--
ment of samples in emb-a oil to wbich ouipburated oil was added
containing 1.11 c1t of sulphur, was complete in 5 hours (curve 1,
2) and the minimum values of frictional movement and surface
layer teMDerature did not change af-,.er an addition6J. 65 houra.
Samples lubricated with MT-16 from erude o-A'.1 with 1.11 .%, of natlu-
ral SUIDIlUr viere not complete in 70 hours (curve 2t Fig. 2) and
Card 3/7

35
5/080/61/034/007/0-10/016
Effect of the nature of D223/D305'~
movement and temperature curves show small era-duai Idecrqase with
Is on, -
time. The contal-~t area of brake to dri)m wa ly '351 40 compared
to the sulphurated oil of nearly 100 114. Tr-otla tvith 6ils.11K with
0.6 % of molybdenum disulphide, ILK-10 with addJtions of'dilferent
quantities of IP-22 and industrial 12 with 1.5 % of'tsicLtim-5 did
not give positive reaulta, since they behaved In the same manner
as natural zglphur. The sulpaurated oil protects thte working parts
of mach.:;Me by -.he formation of thiii layer of sulphi Ldes PeS, FeS2,
Fe3Si. Wi-~h the formation of iron sulphides, the cubical lattice
of a pha-Fe chLnges into hexagona-, lattice FeS which, by analogy
0
with graphite, possessea i'.1brizatnig properties. T investigate
the problem of effect of interrl-~tion products of Vand hydrocar-
bons and also the addil.-Iona of aifferent organic coinpounds of Sul-
phur, tests were done with a series of organic compounds (mercaptan
sulphide, de- and polysulphidest thiophen etc ). The results show
that disulphides, in particular dibenzencdizuiphide,have the same
effect as 6ulphux-ated oil, while cther groups of sulphur organic
compounds have not. This necessitated om examinatid,~, of:organic
Card 4/7

S/080/61/64/007'/010/016~
Effect of the nature of ... D223/D305
polysulphideB ROn,.preterably dibenpenepolysulphides 06H qH SnCH.,
-These were prepared by addin nding quan-,
'C H with n > 2. g. co~~Iespo'.
6 5
0
tities of sulphur to dibenzekedisulphide at 150 C#'1hese ~compounds,'
-with 0.9 1.0 % of sulphm: were found to be quite ~effe'otive.
There are 5 figures and'.3 references: 2.Soviet-bloo~ andil non-Sov-
iet-bloc. The reference. on reads
to the English-language publicaii,
as follows: Diesel power, 35, 11, 32, 1957.
SUBMITTED: February 1, 1961
Card 5/7

MIMI
I

iv
ojwyk
PHASE I BOOK EXPLOITATION SOV/6'267
Davydova, Viktoriya. Pavlovna, and Mikhail Grigorljtvic6 I pi Lq v
Polffosfazeny; polimernyye i monoinernyye fosfonitrillnyye soyedineniya
(Polyphosphazenes; Polymeric and Monomeric Pho6p'honift-Ile Compounds)
Moskva, Izd-vo AN SSSR, 1962. 86 p. 2600 copies prlntedo~
Sponsoring Agency- Akademiya nauk SSSR. Institut khfiAL silikatov.
Resp. Ed.: M. G. Voronkov, Doctor of Chemical Scienoes; Ed; of Publisbing
House: V. D. Piastro; Tech. Ed.: G. P. Areflyevd~l.'
PURPOSE: This book is intended for scientists, engineers, aspirants, teachers,
and students in advanced courses at schools of hig~e'r edtictition working in
the field of monomeric and high-molecular compoun0s.
Card 1/4

Polyphdisphaz enes (Cont. SOV16267
COVERAGE: This book is reportedly the first effort to review dnd systematize
the existing literature on polyphosphazenes. It is basi,d on'Journal articles
and patents published up to 1961. It is expected that materkils prepared
from phosphonitrile polymers will be better than materials from the poly-
organosiloxanes presently used. The chapter on. nomeI~iclat6re was written
by M. G. Voronkov, and the other chapters were prep ared 6y,V. P.
Davydova. There are 23 Soviet and 218 non-Soviet referencels.
TABLE OF' CONTENTS:
Preface 3-
Introduction 4
Nomenclature
6
Phosphonitrile Chlorides and Bromides
Card 2/4

v0'q01vk0v) /Y),C-,
PHASE I BOOK EXPLOITATIONf SOV16034
Konferentsiyapokhimiiiprinieneniyu'fosfororganichoski#h,,soyedineniy. 2d,
Kazan, 1959,
Khimiya i primeneniye fosfororganic lies kikh soyedineniy-~ trudy (ChLIMistry
and Use of Organophosphorus Compounds; Confek-enc e Trans ac tions) Moscow,
Izd-vo AN SSSR, 1962. 630 p. Errata slip inse:rted, 2800 copies printed,
Sponsoring Agency: Akademiya nauk SSSR. KazaAsikiy Iflial.
Resp. Ed. A. Ye. Arbuzov, Academician; Ed.., Of Publishing House: L. S.
Povarov; Tech. Ed. : S., G. Tikhomirova.
PURPOSE: This collection of conference transacltions~ is intended for chemists,
process engineers, physiologists, pharmacis,ts, physicians, veterinarians,
and agricultural scientists.
COVERAGE: The transactions include the full,,'iexts of most of the scientific
papers presented at the Second Conference 6n the Chemistry and Use of
Card 1/14

Chemistry and the Use of Organophosphorus (ContJ SOV/6034
Organophosphorus Compounds held at Kazan' from 2 Nov through I Dee 1959..
The material is divided into three sections: Clie'inistry, containing 67 arti-
cles; Physiological Activity of Organophosphorui' Compounds, containing 26
articles; and Plant Protection, containing 12 articles. ;, The reports i,eflect
the strong interest of Soviet scientists in the cher'nistry and application of
organophosphorus compounds. References accompany individual r e p o r t s.
Short summaries of some of the listed reports h~nre b(~en made and are given
below.
TABLE OF CONTENTS: (Abridged]:
Introduction (Academician A. Ye. Arbuzov) 3
TRANSACTIONS OF THE CHEMISTRY SECTION
Gefter, Ye. L. [NII plastmass (Scientific Research Institute of Plastics,
Moscow]. Some Prospects for the Industrial Use ()f Or~lanophosphorus
Compounds 46
Card 2/14

Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
The preparation and uses of organophosphorus compounds are
discussed, and prospects for obtaining new high - molecular organo-
phosphorus compounds are outlined. Gefter recommends 1) the
preparatidn of.* new .organophosphorus ~polymer6', based on oxides
of unsaturated tertiary phosphines, 2) the utilization of thermal sta-
bility and good mechanical properties of known organoph:osphorus
compounds as a basis for creating new heterochain'i phosphorus -con-
taining compounds, and 3) application of the latest md1iods currently used in
the chemistry of high-molecular compounds to organophosphorus
polyrn ers.
Orlov, N. F. , an~L~ ~Voro~nkov [Insfitut khimii sil'kato (Institute
of Silicate Chemistry, Leningrad)]. New Methods of Synthe'sis of Tri-
organosilyl Esters of Orthophosphoric and Alltylphosph onic Acids 212
New methods have been developed for the synthesis 6f trii3-(triorgano-
silyl)-phosphates (R3SiO)3PO, bis-(triorganosilyl)m ethyl~hosphonates
CH3(R3Sio)2PO, and organophosphorussilicon polymers based on
H5PO4 and CH,PO(OH)2. One method is based on the interaction of.
Card 3 /14

11 li
ORIDVv N.F., VDFd)NKOV, M.G.
New ways to synthesinn'se triorganosilyl asters of OAIwphoophoric and
alkylphospidnic acids,.
K-himila P" j "toy'll
PA-i nT~ichm,ski 1e h Sl p-dixj
aimlication of A'~ 71"
Colitction of nwnrj; T. th(i v~~i5ll
Cl- mistrv of
ic

33988
S/062/62/000/0~02/013/013
S-- B117/BI36
.2 L11 0
AUTHORSs Shchukovskaya, L. L., Voronkov, M. G., and,~Pavlova, 0. V.
TITLEs New method of N-dimethyl-B-difluoro boraze~e synthesis
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheakikh
nauk, no. 2, 1962, 366
The new method consists in the separation of hydrogen~fluoride from
N-dimethyl-B-trifluoro borazane heated with aluminum duet in~vaseline oil
medium. C 2H7NBF3 (boiling point 149 1500C (5 mm Hg),:~dry aluminum duBt,
and va8eline oil (boiling point 210 2300C (2 mm Hg)).were slowly heated
in a distilling flask on Wcod's alloy. At 2780 hydrog6n started separating
energetically and the collecting vessel connected with.'the asoometer by way
of a cooling trap rapidly filled with white brilliant:ff-dime.-thyl-B-difitLoro
borazane crystals. Owing to the vaseline oil the couttie of~the reaction
6(CH 3)2 NH-BF3+2Al-6(cH 3)2 NBF2 +2AIP3+3H2was very smooth ana easy to control.
Yield of N-dimethyl-B-difluoro borazenet 85 - 606- Some codipounds of the
type R 2N BF 21 which are still being examined, were ob Itained,in a similar
Card 1/2

33988
s/o62/62/000/002/013/013
New method of N-dimethyl-B-difluoro... B110138'~
.manne
r. Hydrogen fluoride could not be separated from 114imethyl-B-tri-
fluoro borazane by heating with KF. There are 2 non-Soviet references.
The two references to English-language publica'ions read4s followas
J. F. Brown, J. Amer. Chem Soc, 1219 (1952); A. B. B;urg, :J. Banus, J.
Amer. Chem. Soo. 76, 3903 6954
AS50CIATIONs Institut khimii silikat0v Akademii nauk SSS& (In* ~itute of
Silicate Chemistry of the Academy of Scienc4s USSR)
SUBMITTED: August 10) 1961
Card 2/2

339231
S/079/62/032/002/006/01).
D204/D303
,6-~ 0 ? 0
AUTHORS: Orlov, N.F. and Voronkov, M.G.
TITLE: Silico-organic eaters of methyl phosphinic, acid NPA)
PERIODICAL: Zhurnal obahchey khimii, v.32, no. 2, .1962 608 -612
TEXT: This is a description of the methods of oiyatheais' of th* hitheria
unknown biz (triorganosilyl) methyl phosphinatecl based~!On in'teraction
of CH P(O)(OH) with: (1) Triorganoisilimols: C11 P(O)/-dS!.u'Pt wall pm1wed
3 2
in 68% yield from Et SiOH (2 moles) and MPA (I mole), by~ heating for 2
bra, removing contingously the water formed* (2) Trierganosilanes:CH P(O)
CH P(O) closiEt -7 -,~ CH P(O) 01e(n--Pr) - CH 3
rOS'Et2Me 12' 3 3-2 3 2.1 2' 3P(0)
LoSiMe(Ph) and CH were synthesiz,Pd from the
-J 2 3P(O)roS'r,t (Ph) 2-12
2
corresponding trisubstituted silanes and MPA in the molar! ratLo of
2:4:1, in 0presence of colloidal NJ. in 70-906 yields2 byjheat~ng for -.73
hr at 130 C. (3) Triarganoalkoxysilitnes. CH 3P(O)COSiEt 31 2 and CH 3P(O)
Card 1/,_x

33923
S/079/62/032/002/oos/oll
silica-organic asters of oos 1)204/1)303~
-ere obtained from Et SiOMe and (Ph) SJOBt tak"n in the
f'OS'(ph)3 3 3
2
molar ratio of silane: 1,1PA equal to 2.4:1 and 2:1 respe~tiyelyq in 60 and
70% yields. The reaction of HPA and tetraothyl disilaxane (1i1 ratio)
was catalyzed by colloidal Ni and yielded Et. Et CH
si- 0 S-1 0 P 0
Et t 0
whilst another polymer. Cit- C113 was obtained:!'from~'an equimoltru-
0 CH3
n
lar mixture of MPA and dimethyl dLathoxysilane. All the ph4psph.-inates,wi,04'
the exception of crystallint CH P(O) C Osi(pil),~., we.Tit colorless, high-
boiling liquids, readily hydrolyzed by water. Tito polynters:iyfere palt
yellow oils. Experiment9l details a-re given and physialLl canistants of
C&rd 2/3
SOMMMMM M IN

33923
S/079/62/032/002/000,/Oll
Silico-organic esters of D204/D,303
the products are tabulated- There are 1 table and 17 ro~ferericast 11
Soviet-bloc and 6 non-Sovi*t-bloc. The 4 most recnot r0ferences to tho
English-language publications read as follows: 11.0. Sauejr, J.'Ani.Chem.So4,
66, 17072 (1944); W.H. Keeber and H.W. Posts J-Org-Ch-p'.21, 509, (.1958)1
Canadian Pat. 496,623 (1953)i Ch.A., 47, 41289 (1953).
ASSOCIATION: Institut khimii silikatov Akademii nauk SSSR (institute of
Silicate Chemistry of the Academy of Sci4n-ces, USSR)

S/079/62/032/002/OOP/Oll
D204/0303
AUTHORS: Orlov, N.F., Bogatkin, R.A., Sergeyeval Z.T., Und Vororkov,
M.G.
TITLE. Interaction of triorganomilanes with car6p'Xyli5 acids in
the presence of colloidal nickel.
PERIODICAL: Zhurnal obahchey khimii, v. 32, no. 2, 3.962, 6150-651
TEXT: A short note on the reactions of triethyl silane, with carboxylic
acid, using colloidal Ni as a catalyst. Monocarboxylic; acids reactsd
giving the corresponding triorganoi3ilyl eathers, in 50"~85% yield. Esters
of general formula Et SiOCO(Cil ) OCOSM~ were syntht~lzedln. 60-80%
3 2 n j e
yields frora simple dicarboxy~ic acids. Colloidal Ni promoted hydrogens--
tion as well as dehydrocondensations as was shown by tile reactions of
Et SiH with halogenated and unsaturated acids* Monochloracitic acid
yAlded either Et 3SiOCOCH2Cl or (Et SiOCOCH3 + Et3SiCI), depending on
ths molar ratio of the reagents. Vnsaturated acids yield hyarogenated
Card 1/2

I I] If 13 ;11 P,
S/(Y79/62/032/002/009/011
Interaction of triorganosilanes too D204/D303
productai e.g. crotonic acid gave the n-butyrie ester.,i Act.ioa of
H2MCI 6 as the catalyst is similar to that of colloidaf, Ni.i No experinten-
tal dttails are given. There are 3 Soviet-bloc reforepeaso*,
SUBMITTED; July 17, 1961
Card 2/2

- ---------
VCHONKOV, X.G.
---------------------
ate*. Zhw.ob;!~Iddmu; 32 w.742Y?I-
Hature of Si - 0 bonds in allic
2392 n 162.-
(MM 15:7)

N, M-11,15mu
ORLOV,,, N.F.; BOGATKIN, R.A,j SERUM)! Z41,; 10ROWIt M.6.
Interaction of hydroMIJAnes with'saturated, Oido ;1z, the
presonce of colloidal nickel. Zbur.ob.khim.'~2 nom,W561-2566
Ag (o2. k1RA 15:9)
(Silane) (Acids Organic)
""mum
U-M
4111INYWHI'l

3/08Y62 035/003/015/024
D227 D302
.AUTHORS: Lasskaya, Ye. A. and Voronkov. M. G~~
TITLE: Application of organosilicon co*mpouricis ~or hydrophobing-
heat insulating articles made of exp,~Lnded.perlite
PERIODICAL: Zhurnal prikladnoy khimii, v. ~5, rio. 3,' 1962, 612-617
TEXT: To improve water resistance of articles made of expanded
perlite, the authors studied the useof organosilicon compounds as
possible hydrophobic agents. The compounds tested were: aqueous so-
lution of polyethylhydrooiloxane PK)K-q GKZh-94) and aqueous solu-
tions of sodium methyl siliconate M.)I'- MG-9) EeLnd ethyl silico-,
9
natd GKZh-10. The solutions were deposi ed onto air-dried perlite
t
esamples in one or two layers and their effectiveniess"was determined
sby immersing the samples in water and measuring the amount of water
absorbed. The results showed that water-proofing,of 6rticles sub-
stantially reduces'the water absorption capacity. Por perlites bon-
:j ded with concrete,,glass and silica, GKZh-94 (---110%):proved to,be
very effective. Thd high hydrophobic,activity oT,1Po1yethy1hydro;3i-
.Card 1/2

;11, HIM W, 11111 .1 Ii! I",- i 11 "'ill HIA H 11 1:11 1 1: '1111,
...............................
S/080/62/Q35/003/01 5/024
Application of organosilicon ... D227/D302
loxanes on the alkali-containing materials is explained by the che-
mical reaction of the surface materials with Si-l~.bond giving an
organosilicon film and also by hydrolysis of thiol' bond resulting in
fusion of the polysiloxane chains. For gypsum and lizie-bonded per-
lites2 sodium alkyl silicates (3 - 40/a) proved more effective. in
.general, treatment of various perlites with the mentioned silicon
compounds tended to increase their water resistance by up to 65
times. A series of experiments has also been conaacted to determine
,the effect of hydrophobing treatmeriton other properties of expanded
,perlite such as water desorption and frost stability..' It has been
shown that after the treatment with up to 5~o sOlu'tiOnB.Of the sili-
con compound, the samples could withstand up to'25 "freeze-thaw"
cycles and up to 30 of "wet-dry" cycles. There are 8-tables and 2
Soviet-bloc references.
SUBMITTED: September 26, 1961
Card 2/2

LA6SKAYA,
Imp-xrting hydraphobii- propertiegi to nattwal. ilicebuz--.L-~Ostm, e
materials bry treating tl'e-- With OrgWIIO-SiliCOJ~ comF*unds.
Zhirr.priLX.khira. 35 na.3:1C93-1107. My t62.
OUMA. 15;5)
.1-0,ding rm-WrIal-ij)
"Iti.k.on orpnlkt compou~ S)

SHCHUKOVSKAYA, L.L.; VORONKOV, M.G.; PAVLOVA, O.V.
Now me-Wods of synthesizing I~Lmonahalo.-Su~sUtuto;ll R-dialYyl-
borazines and X-trialkylborazanes. Dokl, ANASSR '~143 no-4;
887-889 Ap 162. (MIRA 15:3)
1. InBtitut khimii ailikatov AN SSSR. Fredsiavlen~o: akademikom
A.V.,Topchiyevym.
(BorazaneY (Borazine)

$1020,6~~ 45/P04/017/0
24
BI 1'0 B144
AUTHORS: Lukevits, E. Ya., Rotadan,'iYu.,p.,:Gi114!r, 5..! 4.0'Academician
AS LatSSR, and Voronkov, X :Go
TITLE,: OrGanosilicon compounds of:tho.ruran so ies.l; Organosilioon
derivatives of furyl.carbihols and,~5-3:~"iti`ft'
u s vii ad furfu ryl
alcohols
PERIODICAL; Akvdemi3anauk SSSa. Doklady, Ni', 1452' 40i' 1962, 806 808
TEXT: .Furfuryl: oxysil2zos viere produadds (1) by r4lactia''n'of trial~yl
chlorosilanes with furyl alkyl and furyl ar',Y1 carbi~ols,1(2) by reaction
of silanes with furfuryl alcoholi 5-methyl furfuryl;ja:lcobol~. and furyl
alkyl carbinols
R1
+ Hj
Q, - Oh CA Call
CH& ; 1~ "I,
-5
using 0 moles of H2FtC1 6 per 1 mole of: isopropy~l,~ alco,61 as catalyst at
Card 1/f
- ---- ----- ---- -----------

3/02 2
OY6 /145/004/017/024
Organosilicon ccmpounds of the 311 B 144
80 - 100001. Their composition and properties are i4dicaied (Table).
5-nitro-furfuryl oxytrimothyl silane Tras obtained ftom ethereal solu-.ions
Of 5-nitro-furfuryl alcohol, pyridine, and trimethyl chloirosllane-
Silane reacts with H PtCl, in isopropyl alcohol to give furfuryl oxyidilene.
2
Dioxane containing 0.05 moles of H 0 hydrolyzes triothyl;ailane in 16he
2
presence of H PtC1 to give triethyl silanol. Trie-thyl silane reacting
2 6
~,--,ith triethyl silanol in the presence Iof H2PtC16 yil~olds linall amount:i of
hexaethyl disiloxane by anhydrooondensation. There~is 1',table.
-ASSOCIATION: Institut organicheskogo sinteza Akade:t*ii naiuk LatvSSR
(Institute of Organic Synthesis of th~p' Academy of Scie.rces
LatSSR)
SUBMITTED: March 12, 1962
Table. Furfuryl oxysilanes (R'- RI). Legend: (I)miode of production,
(2). boiling point, OC, (3) pressure, mm Hg.-
^a-d 2

VO LNKOV, M.G.; SHORDKHOV., N.V. (deceased]; DYMABSKAYA iO.,, ~Gd.;
PILADZE, Ye., takhn. red.
[Water-repbllent coatings in constniction]
shchie pokrytiia v stroltellet4e. 14g&, Iid~-'vv 044. inauk
Latviiskoi SSR, 1963. 189 P. (MIMi 16:4)
(Waterproofing) (Silicon organic compoum6) I

~17 ..
I ', T.'l I , 7,CA' r tv V7,-q~j
ACCESSION NR- AR4048174
30141
SOMIM Ref. gh. Ab!t. !)T.1!21.(;
AUTHOR:
TITLE: 'Muciear qut-Armpole resinarive in tl~e
Crj"LED SOURCE: In. LtUv~ fl-511. Sor. ldl!~lm Vo:.'Al, 1066,
T OPIC TAGS: methirtch7-or-7ft~Aan a, tillicoorgihngo vom1poland, nuall-ellirl. quPidwulicb- rvic-
riance ch`o~4 ne res-ir, i-no.- -v. o.
wel. 11 if-, CH2-CHCH2 > CH2-C11 C6H5
C2H5
The same order is arrived at by studying the angles of wettin6 of the polysilomie
films. Orig. art. has: 3 figures and I table.
SUB CODE: 07/ SUMI DATEs 26Ju165/ ORIG REF: 012/ OTH REIF.- 064.
2/2
6r4
A.

ACC--NRI--AP6033300------------------ OUROB-CODBi7t000)
-in,
AUTHOR: Voronkov, 14. G.; Zelch,
ORG: Institute of Organic Synthesis Academy of Sclenc6s LatSSR,, lUga
(Institut organicheskago sinteza Akademli 'nauk LatS~R)
TITLE: Atranes, VIII, 1-Aryloxysilatranes
SOURCM Khimiya geterotaiklicheakikh soyedinenly::no.,14.- 1966# 511-514
TOPIC TAGS: aryloxysilatrane, 'b44*tQ;5 phony].
compound, heterocyclic base compound, esterificatioll', aromiaLic hydrocarbon
ABSTRACT:Ths previously unreported 1-aryloxysilstrllaues,~M
(R - a L-A).
were obtained by the previously describe4. tr&i14e$ter1fiC&.:
tion (USSR patent Moo 165722# 1964)s
0)4+ HZCH:)3N OSi (OCk12C $)jN+4R'OH,
~OH +S1 (OR (HOC. -R
where
R---agryl, RI-CH3, C2Hs.

Card
14R,'_AP6033300------
The reaction takes place on distilling an equimplar mix-
ture of tetraethoxy- or tetramethoxy6ilanes'p~ triethanol-
aminet the appropriate phenol (or naphthol)ip an~imert sol-
vent (xylene or toluene), and catalytic am6iiifttsiof an
alkali metal hydroxide or without its, in '014 ciso of
phenol and its derivatives, the presence olij tha~jc~ntalyat
increases the yield of I by 5-40%, while L":the case of
nitrophe'noxysilatrans, the yield of I decrelkeed :~by~ 4-25%
in the presence of the catalyst. Compooitl6n# gialds, and
melting points of I are given in the_t&ble.!;I'Th4 L-aryoxy-
silatranes are colorless crystals (with th*excaption of I
1-nitrophanoxy,silatrane,'.which is a y4llow~~Tyaiai)' solu"
ble in organic.solvents and to a ceriain axItent;'ia water,
Data on dipole moments and IR and PHR sp6ct~r& indicate
that I have the follovinIg structuret
C11.2
HzC CIFS
13C
0'.
OR
2/8i

I-Arvloxyti latranes ROSI(OCH31UHa)M

OC
FO
7

-229,
---
C -4 H;, 40 i,
2-C" CA 218-219.5 CjjH,vNO4Sj
3-CH3cH4 162.5-163.5 CUHIINOIsl

4-CH.C,144 188-189 CisHjt%'O
252-253 "
No
st
C1
6
n
i
-2
5-C11
clicji
(C"
) 217.S-218,5 C3jinNO4SI
-
3
,I
l
3

4-CICII44 166-167 Cialil&CINO,Sl*
4.6-cl3c4HJ 230-230.5 C12HUCIINOISI
2-0,NC4H4 233-234 CIIHIIN30#si
3-0.tNcg% 197.5-198.5 C,sHjsNjOjSl

4-OaNCJ44 182.5-184 C"HuNaOsSl
2-CloHl 184.5-185,5 CaHisNOA

Lable cont.
Calcld.' %
v
Rold A
-.C
H Sr. 4-4 1 it. X.:
7,
r5,41 6,24
10,03 55~M 6,69 5.04 9,9S 55.49 6-. 8- 1403 -98
83#
10,03
10.22 55,86 6. 96 5.23 9.98 SS,49 6,81 OS 69
10.14 - -
9.73 55A 7,05 5.15 9,9S A49 6.81 4X 98,
9.97 56*
B.S9 58.95 7,64 4:31 8.68 59.41 7.79 4,M 70
8.74 59.60 7.59 4.53 8.69 $9.41 7.79 4.33 90 i
8.81 81*
%51 47.61 5,6D 4.5 9.31 47.76 5.31 4,t4 ;.1W.
I
%49
7.48 38.69 3,88.4.06 7,58 38.88 3,81 3.78
28
7.47
9.20 4S,93 5,33 8.73 8.99 46,14 5.16 8.65 53
9.35
91
9.10 46.50 5,13 8.6 8.99, 46,14 5.16 8.65 87
8.67 46.42 5.22 9.17 8.99 46.14 5.16 8.65 75
US 6D,4S 6.01 4.6118.85 60.54 6.03 4,41 88
1
*Without a catalyst

~ACC NRAP6033300
Physiological activity of I in considerably i6tier~than that*
of 1-arylailatranes, esg,, I-phenoxysilatrana!!is 5.00 timea
lasts toxic than 1-pheaylailatrane, The iatro4uctkou of
aubstituents into aromatic ring of the aryplazil*illitwanes-
(CHIP (CH 2CH9 Clv and N02) further decreaseli.thiLir toxic-
ityl-as ag.,wn from the LD50 data obtain!ad f o ir whi ~.ft mIcat
R LD..% =S./kg J:
R, !00
C

SOV/120-59-1-48/50
AUTHORS:Berezin, I. A., Voroakov, M,-I,~
TITLE: A Capillary Tap (Kapillyarnyy kran)
FTMODICAL: Pribory i tekhnika eksperimenta, 10.,59,,'Nr 11 P 152 (USBR)
ABSTRACT: The device is illustrated diagrammatically in~ tile f igare
s If: a two-W11V
(see lower half of P 152). It i in the form a ~
valve with two apertures in its plug. The',i ape:ttuxe 2 - i3v used
in the preliminary evacuation of the tube leading.to the 1,ras
oontaine-r. The gas is let in through the capillary tube I
whose diameter can be arbitrarily eniall. Vhis;p6rmits a, -rery
accurate regulation of the pressure of thelgas~which is admitted
into the vacuum system. The paper containsil figure.
ASSOCIATION: Fizicheskiky institut; AN SSSR (Physics Ins'titute of ~h,e
Academy of Sciences USSR)
SUBMITTED: January 20, 1958.
Card 1/1

SOV/120759-1-47/50
AUTHORS:Berezin, I. A., joronkov~, 11. 1-
TITIE: A Device for Loadin3 the S4~aaples into:a Va6uwa!System (Bunker
dlya zaerruzki obraztaov v vakuUMnVu ustano'vIcu)
PERIODICAL: Pribory i tekhnika eksperimenta, 1959~;Nr 1 152 (US)SR)
p
ABSTRACT: The devic6 described is shown diagrammaically in the fi,-,,-
ure (see upper half of 1) 152). The tube~3 coritains a pol-
ished plug 4 with a helix 2 The tube 3~ is inserted
into the system in such a way that the op6 I
n end 1 of the
helix is above the crucible of a vacuum D.Irnace-, The sam-pies
are loaded through the open end of the helicaLtube in suzh a
way that each turn of the tube contains oxie sw'nple. The plu3
is then lubricated with vacuum grease andtiineetted into.the
tube. The samples are loaded into the fjij~nao6 by turninE; the
plug. In this way-, the samples are progr6ssi:~ely displaced
in the helical tube and fall into the ovda froin the open end
of the tube. The paper contains 1 figured
ASSOCIATION: Fizicheskiy institut AN SSSR (Physic's~ Institute of the
Academy of Sciences.,USSR)
SUBIETTED: January 22, 1958.
Card 1/1

ZAGOSKINA, Yq.D.; SIKORSKIY, X.P.; ZEVINA, A.H., otv. red::.l VORO
I.I., red.
(Reco=ended mathemgLticis curric4luw for the sd~rcond balf of
the 1962-1963 sehool-y%ir (grade.5.,to 11)] P4=rnyl plan
raboty po matematike vo vtorom polugodil 1962~1163 hchebnogo
goda (V-XI klaasy). Moskva, 1963. 83 P- IMIU.16:8)
1. Moscov. Gorodskoy institut usoverAppstvo-vinlya ~uohiteley.
i
2. Direktor Moakovakogo gorodukogo ineiltutai ~Isove,'Vohenstvo-
vanlya uchitelay (for Zovina),
(Mathematics-Stqdy and toaehi6)

VORONKOV,-H.P dots., otv. za 1(1~p-
(Papers published by the Physics Department] Sii6rnlk na-
uchnykh trudov katedry fiziki. Dnepropetrovsk," fio.~. 1960.
48 P. (iURA 16;10)
1. Dnepropetrovsk. Inzhanerno-stroitellnyy Inskituti 2. Zame-
istitell d1rektora Dnepropetrovskago inzhenernq~ ~~Iotroitellnogo
inatituta po nauchnoy ribote (for Voronkov). f'
(Paramagnetic resonance and relaxation)
(Luminescence)

vo k V /t/, t,~
AUTHOR: Voronkov, F.As, Mining Engineer 127-12-2/28
:TITLE: Analysis of the Economic Efficiency of tha~~ Scrapor and Screen
Systems of Ore Conveying (Analiz ekonomichn6sti skropernoy i
grokhotnoy akhem dostairki rudy)
PERIODICALs Gornyy Zhurnall 1957t lio 12, pp 8-12 (USSR);
ABSTRACT: The author analyzed th expenses of Oro ocn4~eyinl g.in the mines
of the Kursk Magnetic ;nomaly (the chamber .and-piXlar system
of mining is used), of the Krivoy Rog Basin (thi system of
breaking off the ore from the sublevel galieries) and of the
Tyrnyauz Combine (the level stoping system:~withiore breaking
by blasting charges). Considering all thelitemp composing the
total cost of ore conveying, the author co6cludois that only
expenses for driving preparatory and development openings de-
pend on the height of the level, and thest'expe ;nee$ are equal
for both the scraper and screen systems,,. Expenses independent
of the level height are less with the scraper conveying system
the sum of expenses
than with the screen system. Therefore,
1
with the scraper system will be lower than that with the screen
system for any height of the level.
Card 112 The article contains 4 graphs.'

-----------------
2-2/28
127-1
..Analysis of the Economic Efficiency of theiScraper and,~areen Systems of
.Ore Conveying
~ASSOCIATION: Moscow Institute of Non-Ferrous Metals and Gold (MDakovskiy
institut tevetnykh Met11llDV i Z010ta)
AVAILABLE: Library of Congress
Card 2/2

I M I Ir,Ir:Ur.4 I A I il I! ~-~ N ii a I T~111-'A I I N!"; I J I UU! I ~ III 10 Ik,. M U71111111112 1 19111111,41; It I I III H I I I I I I I I RII I I I In Iii I I IT I! III III I I I! III M I I! Ill 1110.113 Il I al 19=11 I U;54R I I
mw~qw~lf
Iowa,
"..w
65
........ .....

GAYELI) A.G.; TOR01.7,OV, N.A.
ftool- sy,stem oil' the Scotch pine (Pirru.13 silvel3triti, L.) .1 t~e randy-
r, r
soils of Mzakhstan and th-;~ Don Tlalle7. Bot. 50 tio.4:503-
516 Ap 165- 1.8.
1. Vsesoyuznyy ntiu--Iinc,-i.9zlf,,dovat,-Ilskiy inotitup, agrodesomeliora tsil
Pushkino, Moskovskoy oblasti.

mm, IM, 11, MIF, FIN
NOW,
GAYELI, A.G.; V40ROKKO-V tM.A.
kati6f~ In
Interrelationship between trees and herbaceoua vel
isolated pine%woods',tf Kasakhatan. RauchIdokI.vysshkoIy;,
biol.nauki:noS2Il3i-UO,"63. 16:4)
1. Rekomendovana kafedroy goobotaniki. Mookovokogo Paud ratven-
nogo Optyersiteta im. M.V,D)monomova.
("TANAT PROVINC&:-PINE) (FORIST BOOL661)

VORONKOV, N.A.
Water econwq and the formation of young pine grMhapp the sands
of the Middle Don. Hauch,, dokl. vys. shkoly; bi6l. ndiai no.31
131-138 163.
(MIRA 16:9~
1. Rekomendavana kafedroy geobotaniki.HonkovskPjjo goo4daretvennogo
universiteta im. M.Lomanosova.
(Don Valley-Pine) (Plants, Effect of aridity 'on),:'

VORONKOV NA-, I ;,I
i I

AIEKHICHEV) S,P.., kand.tekbn.naul:; VORONKOV, N.A., kand~takhtajaukj
TdltdRMllNOV., I.A. , kand.takh-n.-n-sLU-
nMining and mine timbering" b7,G.D.Chuprunov. Re~-e$w b7 S.P,.
N.A.Voronkov, and LA Turchaninov.,,Por. Oar.
Alekhichev 0
no.12:67-68 D 161. (141RA j~.-2)
a
1. Gorno-metallurgichaskiy institut Kollskogol AN SSSR,
g, Kirovsk., Hur-manskoy oblo
(Mining engineering)
(Mine timberi~ng)
(Chuprunov,

.d ,Study of jol moans
Gand rech Sci.
V!
VORONKOV, INA 41
in rd
of conveying ore on -n of 141jrher"
ores.11 Ifos' 1958, 13 PIP (Mi
thick deposits of hard
St of Non-Ferrous vetals and f7old!im
ljos
TjSSp -in
Education
ies (KLj 23-56~ iW
U.I. Kalinin) 110 cOP
53

Mal W, 6W,

-10-3/25
SOV-127-58, lo
AUTHORS: Voronkov It A and Ouliy, Y.M., Mining Elt'gineers
TITLE: A Comparison of the Scraperand Sifter 1~thod'sli for Deliv,ery
at the Tekeli Mine (Sravneniye skrepern4 i griokhotnoy
skhem dostavki na. rudnike Tekel i)
PERIODICALt Gornyy zhurnal, 1958, Nr 10P PP 11-13 (USSR)i
ABSTRACT: Research conducted by the autho rs showed that'. under the
conditions of the Takeli kinep where th6 minIng is done by
the level caving-in system, the sifter~6~chem
4 of ore de-
livery must be preferred to the ,
scraper method. Even.though
the cost of installation of the sifter;~ methd Vis 80% higher
than that of scraper method, it its mor;O advhntageous because
its productivity is 45% higher. Thes~fter. .mothod also has
a lower safety factor than the scraper!:method. There are 3
tables.
Card 1/2

A Comparison of the Scraper and Sifter Methods for Ek---Uv~.X7 at the Tekell
Mine
ASSOCIATION: Vloskovakiy institut tsvetnykh wto-Uov i',mlotai (The vioscow
Institute of Nonferrous Metala and Gold):~
Tekeliyskiy svintsovo-tainltovyy kombinat~ (The T;iikeli Lead
and Zinc Combine)
1. Mining industry-USSR 2. Ores-Rand,1,4g
Card 2/2

r WIN.
pH;
Iff 111 hill Ill'i 14
DAVYDOVAO, M.B.f ZAKORKIYA# TN.-, MEIN$ Vi*.G.; TOIR011KOV, N.A.;
NAUMOV. R.Lv; KHMINSKIY, P.Go
Characteristics of an area of endemic tick-borne.i~ancsp~alltis in the
conatruction zone of the Krasnoyarsk Hydroelectric Power Station and
development of measures for the protection of wd~,kers !aj~ainvt ticks;
preliminary report. Med.pnraz.i peraz,bol. 27 nd:01:644 Ja-F 1586~
(MMA 11.4)
1, Iz sektora entomologit Instituta malyariiO moditsihakoy parasit,)-
logii i gellmintologit Ministerst.va zdravookhrahianiyalf MW (dlr.
instituta - prof. P.G.Sergiyov, zav. sektorom.-:~prof~ T.H.Beklemi-
shev) I Omakogo Institutti epidemiologii, mikrob~:iologll I gigiyony,
(ENCEPHALITIS, epidemiology
tick-borne encephalitis In construCtion tone, proteatton
of workers (Rua))

VORONYOV, N.A.
-52 1 4P
P.chv. -flo -2 143
P,115atloa (MT_ItA 17:10'
jr. 6
sana.s. veat.
163-
09,
1. YaNdra gaobotanlld-

Pill,
v NW.G -OPNORIK, X11.1.
Metbylpheny1difluorosDane* Zhur.ob.khJmo 33 np ,'10:3400.0
163* (MMA 16:11)

PRIDNYAXOV, G.S.; VORONKOV, N.D.
Automatic pressirg of mstal powders with a bydr,kmlic,preas. Avt.pron.
29 no.10:29-30 0 163. (MMA 16:10)
1. Nauchno-issledovateltakly inatitut avtomobillmoy p'romyshlennosti
i Michurinskiy zavod imeni Lenina.