SCIENTIFIC ABSTRACT YEROFEYEV, B.V. - YEROFEYEV, I.M.

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SCIENTIFIC ABSTRACT
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Nikolay Sergeyevich Akulov (On the Occasion S/170/60/003/012/014/'015 of His 60th Birthday) B019A056 propertlea of 1vorooole andi after graduation, he became Aspirant at the Ltiboratory of Professor V. K. Arkad'yev. In 1928 he formulated the aniso- tropy law for ferromagnetic bodies, which is named after him. After having become a docent, he worked in the capacity at the lafedra fiziki Gorlkovskogo got3udarstvennogo universiteta (Chair of P~*-sics of Gortkiy State University), where he set up the laboratory of magnetism and established the first Chair of Magnetism in the Soviet Union. Under his supervision, a large number of experts on magnetism were trained (Ye. I. Kondorsk.iy, N. L. Bryukhatov, K. P. Belov, G. P. Dlysacov, D. It Volkov et al.). In 1940 he was elected Membor of the Academy of ScienceL of the Belorusskaya SSR and also Secretary of the technical branch of the Academy. He was axarded the Order of the Red Banner of Labor and the Prize imeni M. V. Lomonosov. Among other things, he was also concerned with the physics of combustion processes and the strength of meta.1s. This work was carried out in collaboration with the Fiziko-tekhnicheakiy Institut AN BSSR (Institute of Physics and Technology of the AS BSSR). Together with Kunavina, Akimov, Solichev and others, he developed a vibration-defecto- scope, which is widely in use. There is I figure. Card 2/2 HITOWICIs Selot USIDT, I.;. C41njupte& deoarboxylation In the autolidat1*114of Dkopropylbewien lit a mixture vith butytlo said labeled with 0' 111 6he carbox7l. geoup. Dokl.AN BSSR 4 no.4tl6o-163 Ap ,6o. (MIRA 13'.10) L Institut fisiko-organichaskoy khImH AN BOSRs (Carboxyl group) (Bans6nO S/080/60/033/04/26/045 AUTHORS: TITLE; On tho Chemism of the Initiation of $*If-Oxidation of Cumenl by Manganese Salts PERIODICAL; Zhurnal prikladnoy khImii, 1960, 'Vol 33, Nr 4, pp 903 910 TEM The self-oxidation of cumene in the presence of manganese salts w"I studied with a view to elucidating the initiwting action of thine salts. Cumene used in the experiments wiw synthesized from loopropyl and benzene chloride and had the following phyaico-chomioal oonstantes boiling point 151.0 - 153.OOC, n20 1.4929, d2D4 0.8625r). It was shoom that at 950C and an o~Vgen pressure of 590 = Hg &7e oxidation of cumone does not take place, and proceeds very slowly in the presenos of manganese acetate. The self-oxidation rate increases, however, in the aame of +J%e purifiewtion of cumene by means of sodium metal. After bolrlng cumene for 3 hours over sodium motal with subsequent distillation the reaction rate Increases 60 tims. Kolmakov and Razuvayev [Ref 14) foand that the Induction period decreases as a remlt of additions of cuman6 4droperoxide oi manganese resinate as initiator. The induction period depends on the purification of cumene and the type of initiator. In the presence of manganese Card 1/2 5/080/60/033/04/26/045 On the Chemism of tbe Initiation of Self-oxidation of Cuawne. by Manganese Salts butyriste it is compj,ste3jy absent. The initiator changes during the process of Self- ox1dation, losIM ils initiating capacity. At the saw time the manganese content in it inareasea. It has been pointed out that the experimental fauts observed do not agree- with the initiation theory of soveral. authors, which includes the alternating oxidation and reduction of the initiator by cumens hydroperoxide. The results agree, however, with the irLLtiation theory, a*aordIN; to which the formation of;free radicals takes place during reduction. of the initiator by. lWdrocarbon. . There ares 7 sets oi! graphs, 1 diagram and 24 references, 12 of which are Soviet,, 7 English, 3 German and 2 American. SUBMITTED: September 17, 1959 Card .2/2 v; 411 2 I ; v 1I u . - flaglj'~ U J;jj4jjv lid IP 4 q 1411 , v ud 49 4 :IV 41 "fill IN 10 1 h 0 4 d is - I M 21i- 4 a S-Ij 1j; j Mud: 31 9 Ile, Ell . I lip lit i! lit 'v .14 m, A IMP rip 1 1-14, Ifl, I 3 63 ?'P2 s158o16 i/Wo/ooo/oo ilro 16 .5- A057/A126 " 0 AUMORS: Yarofeyev, B.V., Chirko, A.I., USkoV, I.I. TITTE- Investigation of I-phenyleyelohexene-1 autoxidation kinetics and the products SOURCE: Yerofeyev, B.V. and 1.0. Tiohohonko, ado. Vildkofaznoyo okinleniya nepredel'nykh organicheskikhoqixhAedyp Minsk, 10161, 3 - 14 TEXT: Products of the autoxidation of I-phenyloyclobexene-1 have been investigated before by H. Hock, and M. Siebert, but not the kinetics. The latter were studied for the first time in the present paper and a new compound was isc- lated from the primary autoxidation products. The oxidation was carried out at 500C during _30 h by an earlier described method. The products of autoxidation %vere separated and results corresponding to those by Hock and Siebert obtained. The new product was prepared by thermal destruction of the autoxidation product and preliminarily determined as I-phenylhexene-2-ol-6-on-I CH,,,iOH-CH2-C142C" - = HC-CO-C6H5. Experiments on autoxidation icinetics carried out- with fresh and stored (2 weeks) siunples in the presence of 1% cobalt stearate showed no differ- ence, and a maximuta of the autoxidation rate after about 110 min. 7he influence Card 113 C! /-t lj/..~Co,16 1/000/wo/oo 1/1) 16 Investigation of I-phenyleyelohexene-I.... A057/A126 of 14 different initiators was tested and the greatest. effect obtained with co- balt and manganeae butyrate and cobalt stearate, which increased the maximum rate of autoxidation by 6 - 9 times. Kaolin, manganese, cobalt, and lead formi- ates showed no el-Tect. The influence of the concentration of the initiator *,%-Qa studied with cobalt stearate, manganese butyrate, and lead dioxide admixtures (0.25 - 4%) and it was observed that the oxidation degree increaseG to a content of 1% cobalt stearate or 0.5% manganese butyrate respectively, while 'Or lead ixide a steady increase can be observed with the concentration. The dependence cf the autoxidation rate on the cobalt stearate concentration can be described by the following equation: a Cul Vm " -1 T-bM (Vrr - rate, a = constant - 0.01042, b - constant - 1.364, Lu] - concentration of the initiator). The effect of concentration of I-phenyloyclohexene-i on the rate of autoxidation wits investigated in benzene solutions containing 0.51,~ cobalt stearate, and linetarity according to Vm - X01-6.3 was observg!d. Zie 1nfluenerl of, temperature was studied at 40, 50, and 600C in presence of 1% co"bolt nolution and fron, the data obtained tYe activation energy was calculated with 16,400 cal/mole. The relatively high kinetic order of 1.63, is explained by the prv.-Bent autnora Card 2/5 31/'1180/611/0 00/000/00 1/0 16 Investigation of I-phenylcyclohexane-l... A057/A126 with the assumption of complex formation between the hydrocarbon and the Initia- tor. The new product is as-sumed to be 1-phenyloyclohexene-2-ol-6-on-I since the formation of ca:.rbonyl and hydroxyl groups is observed at doatmations of tertiary hydroperoxides. Therefore, the primary formed hydroperoxide ooruld be 6-phanyi- -0-hydroperoxickt-cyclohexone. Formation of the latter is caused by intermediate isomerization of the phenylcyalohexenyl radical, Thus, further investigations of the products of autoyi.~a-41on of 1-phonyloyclohexene-I would be of interest. There are 5 figures and 4 tables. Card 3/3 36323 S1580,16 1/000/Um/002/016 J-j A057/A125 AUTHORS: Yerofeyev, B.V., Chirko, A.I., Urbanovich, .1.1. TITLE: Products and kinotics or autoxidation of phonyleyelopentane SOURCE: YerofeyevP B.V. and I.G. Tishchenko, eds. Zbidkoraznoye okisleniye nepredel'nykh orgainicheskikh syedinety, MinsX, 1961, 15 - 27 TEXT: 7w products and kinatics of the autoxidation of phanyleyelopentane were investigated,, and for the first time the primary product of autoxidation -1-hydroperoxide-l-phenyleyelopenl.,ane- wan separated and specified. Kinetics were studied in the presence of 11 different admixtures. The present investigation was of interest in connection with analogous studies on phenyloyclohexane to de- termine the effect of its structure on the rate of autoxidation. The physico- -chemical characteristics of the phenyloyclopentane used were compared with corres- ponding data published by S.S. Nametkin, N.D. Zelinskiy, and Ya,I. Denisenko. Repaated distillatlon ohowed that an increased purity raises t1,A autoxidation rate of phanyloyalopentane. The effect of the different admixtures was determined b,.r the quantity of oxygen absorbed and the percentage of hydroperoxide formation. The highest activity wasshown by manganese and cobalt butyrate and acetate, and Card 1/2 S-/,- 161100010001002101~6 If _80~ Products and kiru?tics ..... A057/A126 also cobalt acetate and lead dioxide. The latter showed a considerable difference as initiator in comparison with tre other active admixtures, i.e., a greater amount of the hydroperoxide was accumulated in the products of autox1dation in the pres- ence of lead dioxide and, on the other hand, the dependence of t1w autoxidation rate on the concentration of the initiator showed another chaxacter for lead di- 3xide than for cobalt stearate. At higher concentrations of lead dioxide lineari- ty can be observed, indicating different from the other initiators, that lead dioxide does not participate in processes of chain rupture. Another Important oJservation was made In studying the effect of phenyleyalopen-tane concentration on the autoxidation rate, which can be expressed by Vm - K03-5 (VM w rate of autox- idation per 1 liter solution). She relatively Ugh order of kl.mtlcr# (3-5) is ex- plained by the present authors with complex formation of the Initlator and the oxidized hydrocarbon, according to earlier investigations. The equation VM = a [U] I + b [u] Om -i` rate of autoxidation, a andb - constants, Cu3- concentration of the initta- tor), which was stated in earlier studies for other hydrocarb'Ona, la vAlilablry Allub for the autoxidatian of phanyloyalopontara In the presenoo of tiobalt stearate as Initiator. The aotivation onargy for the present autoxidation was found to be 16,00) cal/mole. There are 6 figures and 5 tables. Ca,,ftd .2/2 '8/51M, 46 1 1000,A=10031b 16 jY0 0 A057/A126 AUTHORS: Yerofeyev, B.V., Dutnyak, N.S. TIM: Autoxidation kinetics of eydDhexadiens-1,3 ir,~ benzene solution SOURCE: Yerofeyev, B.V. and I.G. Tishchenko, eds. Zhidkofaznoye okisleniye nepredel'nykh organicheskikh 8WedInwW, MInaR, 1961, 29 - 37 TM: Kinetics of autoxidation of cyclohexadiene was investigated in the presence of cobalt caprylate as initiator, and an original dependence of autoxida- tion on the concentration of the hydrocarbon was observed. !Me present study was carried out to compare the kinetics of autoxidation result1q; in formation of the endo-peroxide typ3 with those carried out in other Investigations resulting in the formation of other types of hydroparoxides. Autoxidation of cyclohexadiene was studied repeatedly before, among others by N.D. Zelinskly and Titov, A.I. Chirko and K.L. Moyseychuk, or V.A. Cherkasov., but no data on kinetia3 s~vro pub- lished. Cyclohexudiene-10 was prepared by the method of B,V. Yerofeyev, S.F. Naumov, and K.P. Yemel'yanov (Sov. patent no. 110964, 1958), Rej:nated distilla- tion of cyclohexadiene over metallic'sodium removed impurities and allowed a high and reproducible rate of autoxidation showing no induction period. The effect of Card 1/9 3/5580/61/000/000/003/016 Autoxidation kinetics ..... Ad5"t/A126 cyclohexadiene concentration on the rate of autoxidation was studied at concentra- tions of 2.14, 1;1.20, 4.27, 5.,m, 6.45, 7.41, 8.45, 9.48, and 10.~5 mole/111ter. Up to about 5 mole/liter an increase of the rate can bo observed, attalning n maximum, there; it decreaseis then until tho content of 10,,Ij mol,io/litm, In mamiod. The ordor of kinetica for tho decreasing part is calculated with -1. Result3 ob- tained in single experiments showed on the other hand that with the duration of autoxidation the rate of the process decreases indicating an order of kinetics +1.5. The existence of two orders of kinetics can be explained by the absence of Intermediate and final reaction products in the beginning of autoxidation (order -1), while during autoxidation these products am formed and, when present, Influ. ence strongly the reaction, thus chmgng the order of kinetics (+1.5). It In demonstrated that the activzttion energy of autoxidation of oycloboxadiene depends upon the concentration of the latter, being for 6.45 mole/l 7,40o cal/mole, and for 10.5 mole/l 9,400 cal/mole. There are 5 figures and 3 tables, Card 2/2 348 S;(615 X6210001,00 3,1`017/09 0 B1 51B144 AUTHORS: Yerofeyev, B. V., Ariko, N. G. TITLE: Effect of solvents on the radical-chain procesa of autooxidation of hydrocarbons PERIODICAL: Roforativniry zhurnal. Khimiya, no. 3, 1962, -1-1, abstract 3P476 (Tr. o khimii i khim.tekhnol. (Gorlkiy), no. 1, 19!61, 89-9j~5 TFXT: The oxide.tion of cyclohexene in the presence of cobalt caprylatle a-. 40-550C in solvetnts (n-octane M V C6H5CH .31 CHC131 0645 110 2) is studied. With increasing polarity of the solvent thekinetic order of the reactiDn decreases. In n-octane the order of the reaction is approximately 3, in CCl4 and C6H 5CH3 1). The order of addition of the catalyst compo_ neNs is of major importance. Fourfold higher activities are ob- tained when CjjH9Li solution is added to the TiC14 solution. The,.ic observations can be explained tentatively by as~iuming the formation of the very unstable complex 2 C4H9Li + TiC14. There are 3 fi6ure& and 1 table. Card 2/2 B/786/61/000/009/00.-1/006 zosvrW AUTHORS: B.V.Yerofeyev, S.P.naumovat L.G.Tsykalo .d;:== - TITLE: The mechanism of thermal polymerization of lv3-cyclohexadione SOURCE: Aka,demiya nauk Belorueskoy SSR. Institut fiziko-orgwiiche- skoy khimii. Sbornik nauchnykh rabot. no.9.1961, Monomeryq evoystva i protsessy poluchenlya polimerov, 71-79 TEXT: The thermal polymerization of 1.3-cyclohexadiene *ith the simultaneous formation of the dimer (l,4-ethylene-l,4,5,6,9,l0- -hexahydronaphthalene) and polymeric mat6rials of unknown molecular weights has been studied by Hoffmann and-Damm (MitteilunC Schle- sisch.Kohlenf'orschunginstitutp 29 97-3-46 (1925); Cheia.Zentr V it 2342-2344 (1926);-Chem.Abstr. 27, 1249 (1928)). The purpos; oT this work was to study the mecra_~ism of this polymerization. 113- -cyclohexadiene was prepared from cyclohexene hy(lroporoxide. 'rho monomer was placed in ampuleal connected to the,Vacuum system, Card 1/3 3/786/61/000/00 9/00 3100 C The mechanisim of thermal polymerization..10615/1242 degassed and bouled off under vacuum. The sealed ampule.- %ere placed in ba-ths thermostated at between 80 and 2000C. The polymer was precipitated by the adaition of four volumes olf methanoi. The precipitate was dissolved in benzene, reprecipitated. with wethitnol and dried to constant weiL:ht in vacuo. The dimeric waterial wafi isolated after thE first prec!'TiTaton by vacuum distillation of the solvent and monomer. The quantity of trimer formed va:_'w ated by difference. Polymerization runs were carried out at 180, 160t 130, 100 and 800C. The dimer and triraer are probably in- capable of propaCsating the polymeriiation reExtilon. The pure oimer did not under-go thermal polymerization. The rate of polymerizatiol I increased with ri-se in temperature, but the molecular weights of the polymers formed were practically identical. Longer polymeri~.u- tion times did not change the concentrations of dimer) trimer and polymer formed. The formation of the dimer is thus a parzillel reaction and 4not an intermediate stage in the polymerization. The first stage of polymerization is the formation of an activated dimer molecule which can react in three possible ways (a) it can Card 2/-3 S/786/61/000/009/003,/006 1065/1242 The mechanism of thermal polymerization... lmdergo inactivations giving an 1naotive dimer as Mal productq (b) it can react with a monomer to yield benzone and-cyclohexetne through disproportionationg or (a) it can form,an active trimer molecule which can either form a "dead" trimer'Urough inactiva- tion or combine with a monomer and form an active totramer which will propagate the polymerization with the formation of high poly- meric material. There are 5 figures and 2*table;3, Card 3/3 3/186/61/000/009/004/006 1065/1242 AUTHORS: B.V.Yerofeyev, S.F.Naumova, T.P.Makeimova TITLE: The effect of TiCl on the polymerization of L#3-cYclo- hexadiene in heptuh solution BOURCEt Akademiya nauk belorueskoy SSR. Institut Miko-orgeniche- skoy khimil. Sbornik nauchnykh rabot. no.9.1961~ Monomery, svoystva i protsessy polucheniya polimeruv,, 80-87 TEXT: The yields vary nearly linearly with VMC14J- In all ex- periments an insoluble polymer (30-50%) was also formed, the quan- tity being dependent on the conditions of the eiperiment. The molecular weilKhts of the soluble polymers (determined cryoscopical- ly) were dependent on both monomer and catalyst oonceritration, Highest molecular weights were observed at intermediate TM4 con- centrations (0.06-0.105 moles/liter). The molecular weights of the osoluble polymers were found to be independent of the 'temperature of Iv polymerization (temp. range studiedt 0 to -4000. All polymer Card 112 The effect of TiGI4 ,,/786/6:L/OC:O/'GC ~1,0041006 1065/1242 samples studied viere founa to contain about I atom chlorine Ier molecule, indicating the direct participation ol' TiOl~ in the ini- tiation step. The molecular weights of the polymerS Aormed in heptane solution vere of' the same order of magnitude as those ob- tained from polymerizations in other solvents. A polymerization scheme is suCj;,,estedj based oti the formation of a growing radical. Termination takes place by disproportionation ot two growing chains. There are 2 figures and 4 tables. Card 2/2 8/78 5Y61/000/009/005/006 106 12 42 AUTHORS: =' D.V.Yerofeyevq S.F.Naumova TITLE: The kinetics of the TiCl -initiated polymerivation of 1,3-cyclohexadiene in toluene solution SOURCE: Akademiya nauk Beloroeskoy SSR. Inatitut fiziko-organiche- skoy khiaiii. Sbornik nauchnykh rabot. no.9.196l.-Nonomery, SVOY.BtV8 i protsessy polucheniya polimerov, 88-95 TEXT: The polymerization of lt3-cyclohexadiene in different -ol- vents has been studied by Yerofeyev and co-workere (Ref. 1: Lokl. Akad.Nauk BSSR s 5 (1'MM. In all the casevi studledt polymerr. of rather low oie,callar weights (aboUt one thousand) were obtjined. In order to elucidate the reasons for ~he early termination of chain growtht kinetic studies of the polymerization were carried out at temperatures ranging from -70 to +200C tat cyclohexadiene concentrations of 5.7-6.6 moles/liter and TiC14 concentration of 0.017 to 0.16 moles/liter. Details of the polymerization technique are given in reference 3 [B.V.Yerofeyevo S.F,Naumova, T.P.Maksimova, Card 1/2 S/7 86/611/000/ 00 9/(' ' ;0 5/GO 6 1069111242 The kinetics of the TiCl 4-initiated ... Bb. nauchnikh robot IFOXh, AWad.Nauk no.9, 96 (1961)]. Tile rate of polymerization of 193-cyclohexadiene in toluene is approxi- mately first order with reepect to monomer 06H ) concentration. The extent of polymerization was proportional t� [TiCI 4P~ and inde,cendent of' the initial monomer concentration Tho m8lecular weighte of thv polyinemi obtkilned in tD1UIDnQ WOD j)rII0t;IWoI)y id0ii- tioal to thooe found for other nolventa, There tire 4 figuren jind it tables. Card 2/2* S-,/786/61/000/009/006/006 ibwrM AUTHORS: B.V.Yerofeyev, S.F.Baumovag T.P.Makelaova TITLE: The polymerization of dialin SOURCE: Akadlemiya nauk Belorusekq SSR. InetitUt f1s4ko-organicho- skoy- khimii. Sbornik nauohnykh rabot. ho.9.1.961. Monoinery, evoystva i protsessy pblucheniya pollmerovo 96-100 TEXT: In polymerization of cyclohexadiene under widely differing conditions only molecular weights in the range 500-4000 were ob- tained. In order to find out whether the.high rate of chain trans- fer was caused by the cyclic structure of the cyclohexadiene mole- cule, dialin (dihydronaphthalenep C10Ho)-containing the cyclohexa- diene Btructureq was chosen. Dialin was prepared by the dehydratibn of tetralol - lp2t3s4-tetrahydro-/7-naphthol. The polymerizations were carried out in a three-necked,flask equilped with stirrer, gas inlet tube, and 0dropping funnel. The polymer zations were carried out at -75 to 0 C for 1 to 10 hre. At the ended each experiment, Card 1/2 S/786/61/000/009/006/006 The polymerization of dialin 1065/1242 the precipitation of the polymer and decomposition of initiation was achieved by the addition of 4 volumes of methanol. The polymer was purified by re-precipitation from benzene solution, and dried in vacuo at 400C. In the reprecipitated polymer no traces of the Z-at-ary-st were found. Two polymer fractione were iaolated in all experiments: relatively high-mol.wt. fraction comprising 76-88~, of the total, and a low-mol.wt. fraction (probably diamer and tria- mer) comprising 12-24~!. The molecular weights were determined cry- oscopically (in benzeno). High yields (90-100,A vere obtained in chloroformg and lower yields in heptane. In both solvents the alolr-- cular weights were practically identical (- 600). The molecular weights obtained with a TiCl4-Al(isO-C4H9)1 complex were higher (-1000) than with TiC14 alone, The polymgrs of dialin are white amorphous powders, soluble in aromatic and chlorinated hydrocarbora-. They are not oxidized on exposure to air and have a den-4 *ty Of' 04, - 1.138. The absence-of chlorine in all polydialin proparations ,the lower molecular weights (independent of solvent composition) indicate that the mechanism of polymerization is different from that in cyclohexadiLene. There is I figure and 1 table. Card 2./2 S11 9016110051011,1012/0 16 211 O/B 101 AUTHORS: -,Y.,xrofeyjy,-D---V--, Naumova, S. F., Kulevskaya, 1. V,, Mardykin, V, P., Tsykalo, L, G.~ TITLE: Polymerization of ethylene in the presence of the triethy'- aluminum anisolate and titanium tetrachloride complex PERIODICAL:- Vysokomolekulyarnyye soyedineniya, v, 3, no, 11, 190611, "V~N .. 1707 TEXT. Initiators from triethyl aluminum anisolate (A) and TiCl (T) for 4 ethylene polymerization have low self -in*f lammabili ty.. Tho authors atud:.-?d the properties of polyethylene (PE) produced with them, ani th~- effect !~f the A;T ratio on its properties. The Al(C 2H5)3' CH3OC6H5 was prepared by reaction of bromo ethyl with Mg-Al alloys (g0% Ali 60% Mg in aniscle). 1.0 mole/liter of A (boiling point 97 - 105 C/4-5 mift Hg) was dissolv~,d L77 n-heptane. The TiCl 4 concentration in ti-heptane was 0,4 moles/li*ers Ethylene was pressed into the reaction vessel at 12 liters/hr. At f!--rst n-heptane, after this TiCl 4 in n-heptane, and then., durine, I mLn. A .,n Card 1/3 S/190 ,61/00 3/0 1 1/0 12/0', 6 Polymerization of ethylene in the.... 131 to B101 n-heptane were added. After 20 min, PE was precipitated by means of CH3OH with 3% RCI, The tabulated values were found under atmospheric pressure at 300C. The density determined in water-alao-hol mIxture wa!i 0-95 - 0,.97. With increasing A:T ratio and oonstant T, the molecular weight of PE drops. Then, the amount of A determines the number of rpsulting polym,or macromolecule chains, The A.,T ratio was < -, in 166-119 1 - 5, and 1.6 :Ln test 6t. While PE obtainea by means of trL~scb~;tyl al*um~.num and T""34 (Raf,, 5, see below) had molecular woighto Ulf 67,000 - 940,000 and melting temperatures of 116 - 139 0C, the aioleau,ar weLgh*,- of the authors' PE were 91 .000 - 316,000, the melting ttimperStur4?s 127 130 C, The de--,rease of the molecular weight with deereasing Al-compc!und., TiCl4 ratio observed in triisobutyl aluminum polymer:IzItticni IB probab!y due to the high excp5s of th-i former. Thijo~ the TICI4 amoixil, detP.rm,.n+i, the number of resulting polymer chains,. There are I table and 5 non-Scv!-., ref erence-s -The two referpnees to English -language pablications read ae- followe. Ref, 2: A.. Grosse, J Uavity, J, Org, Chem.., .9,, 106, 1940; Ref, ~): E., Badin, J. Amer. Chem, Sej~, ~ 80, 650~ 119'lfl. Oard 2/,5 3/19 61/003/011/012/016 Folymeri,~-.atiori of ethylene in the... B110 YD 101 AS-30CIATION: Institut fizikoorganichoskoy khimii AN BSSH ~,(InGtittlte Of Phyr,ical and Organic Chemistry AS BSSR) SUBMLITTED: December 26, 1960 Table. Ethylene polymerization. Le8end: (;) test no.; (2) amount of initiator components; (3) milllm8lea; (4) polyethylene yieldt g; (5) molecular weight; (6) M'eiting point, C. Table 3 4 5 6 "m lcomnwmo Knunonenles UNIIJIUSTOPS I RUM I an" I C T. nn.. A"O-t T, A/T 1 1 13 0 0 0,21 1 137 M6000 128 2 2:47 6:0 0 4t 1 98 M000 130 3 70 6 0 , 0:62 2:00 iso 000 121 3:51 5:0 070 2 34 1 - 4,05 6 0 0:82 2:89 130 6,57 4:0 1164 2,52 91000 130 Card 3/3 8/844 69/00-0/000/122/129 D207YID)307 AUTHORS: Yerofeyev, B.. V. and Protaahohik, V. A.- 0 TITLE: o on the rate of decomposition of cobalt Bffle7ct of foratate SOURCE's Trudy II Vaosoyuznogo ooveshchaniya po radintaionnoy khi- mii. Ed. ~y !,. S. Volak. 1-loacowt,.1zd-vo iLN SL;jR, 1962, 703-708 60 TEXT: The effect of introduction of.Go into cobalt formate on the rate of its thermal dooompoeition at .21800 wan invoutigato(I manometrically in (initially),--10-5 md Hg vacuum, Teots were car- ried out after storage periods ranging from 9 to 44 duys and the decomposition runs took from 85 to 250 min. At tho end of a dc,,.,om -position test the pressure in the system rose t6.0.6 - U.7 mm Hg. 60 Three samples were used: (1) free of Co (2) containing 0.71 me '-Qf C060/g, and (3) containing 1.42 me of 0060/g. 2he decomposition Card 1/3 60 S/844/62/000/000/122/129 Effect of Cc 046 D207/D307 curves of the -three samples were all S-shaped. The times taken to reach the maximum decomposition velocity (the points of inflexion on the B-curves) practically coincided with the times necessary to decompoBie half the sample (Vj/2). The times 'r112 for the samples containing Co 60 were considerably shorter than for sample 1. The value of T' for sample 1 increased a little with the duration of 1/2 4 60 storage before testa while T' for the samples with Uo increased 1/2 considerably after long storage. Differences in the maximum velo- cities of'the composition between the three samples were conuido- r-bly smaller 'than the differences between th.e values of 7~'1/2- The following topokinetic equation described the decomposition process: O~ = 1 - exp (-ktn) f . M where eA is the decomposed proportion of the sample, t,is the time, _-and n and k are constants (n varied from sample to sample). The Card 2/3 60 Effect of Go &*~ 8/844 62/000/000/122/1,-29 D207 D307 YD above equation was obeyed for values of ot from 00-07 to 0.95. This equation is dincussed in terms of the Composition mechanism which occurs via electron transfer from formate ions to, electron traps such as anion vacancies. There are 4 figurge,, ASSOCIATION: Institut fiziko-organicheakoy khimii AN BSSR (Insti- tute"for PhyBiCo-Organic Chemi'atrytlAS BSSR) Card 3/3 toenail WFIRF III, I U.492111113 Jill YEROFEYEV, B.V.; BE.LISKAYA, R.I. Expprimental wthods of debydrogenation of isopropy'l alcohol in a :rLuid-bed catalyat. Kin.i kat, I no-4050-555 Jl,-Ag 162. (HIRA 150) L Institut fisiko-organiahaskov Mixii AIN BSM. (Isopropyl alcohol) (Dehyftogenation) (Cata4sts) $1250JW40061WS100710DI I.,001/10(a AUTHORS: YIT9qffJM Naomi, & F. ad TOW96 L G. Swination of benanse in thank p0bMerbatiots Of CYdoh~xadicn&lI Akedemiya nank Belartakay SSR. DDkh*, V. 6. me. S. 1962. 313-31:5 1EXII: This is a continstation of& previow work an pobows tionoteydohnadim-Wattempnow= 1601~=OC (B.. V. Veroteyev, S. F. Nausnova, L 0. Tydcok, W naudwykh inulov JF0Kh, no. 9,1961). In the pnomt work the sPectrophotOmebic iuvediPtiOn was Applied tc mcnOmn ObWW4 in exPerime"" with diffaent depwi of polymerization at vadow tunpustum. It was aabWW, that In the process of the chemical chanps of cyclohexadienc-1,3 dimerittation and polymerintion to higher deStees, am accompaided by a dhiproportionation. A formula is given for calculation of the amount of tin the monomeric products. Thas are 2 figures and I table. A MATION: bwftt Ilzilco-otpaklasim Ithi" AN MR (Inedwe of PhydadjOrlwac Chemistry AS BSSR) SUDDaTTED: Febrary 2L 1962 cold fit MWSM,, B.V.; SMOKO, T.I. (Minsk) New tM of depmWence of the autoozidation rile of cumve on the initiator concentration. Zhur.fix.khim. 36 mo,.8:1717-1722 Ag 162,, i (KERA 15:8) 1. Institut fisiko-organicheskoy khImli AN iSill. 3/020/62/147/001/016/022 Blo6/ssoi- AUTHORS: I"erofe Academician,AS BSSR9 laumovat S. ?-t Tsyka op L. G. TITLE: Products containing an odd number pf monomer links# which J!orm on the thermal polymerization of op)1ohexadiens-10 PERIODICAL: ikkademiya nauk SSSR. Dokladyt yo 147P A()- 19 19620 io6-107 TEXT: Monomer products contained in the crude polymerizate mitre spectro- photometrically studied in order to clarify the mechanism which underlies thermal polymexization of 1,3-cyclohexadienit. The content of a triaer product in the liquid portion of the polymerizate was determined. The monomer products contained 16.1 + 3.9A benzene after an 8-hour polymerize- tion at 1800C, and 21.6 + 5-1% b7qnzsne after 10 hre. After 2.j". 40 hro polymerization at72000C, the monomer products contained 47-1s 40649 .and 23.5% benzene respectively. At polymerization texperaturos of 140, 150, and 1600C no benzene resulted. The molecular weight of the liquid Dart of'the polymer, separated by methanol, was d*torained cryoscopioally in order to calculate the amount of trimer in the polymerisato. The result ng values (160-240) indicate that the liquid part of the polynor Card 1)3 8/020J62/147/001/016/02'2 Products containing an odd ... B106./DIOI contained only dimer and trimer. 0The trimer percentage a changes between 0.6% (10-hr polymerization at 140 C) and 11-1% (70-hr polymerization at 1600C). The results show that active monomer radicals form on thermal polymerization of 1,3-cyclohexadiene, which either add to a dimer so as to produce a trimer, or else disproportionate into benzene. The first stagsact polymerization are; a6Ha + C6H8 -,:~O C6 Hi + C6H; (1) C H* (or C H*) + 0 H C H C Hj (or 6 7 6 9 6 a 6 7 ' 6 Y99CA') (2) eta* Visproportionation may occur simultaneously with reaction 2: c6fli + 06Ha C6H6 + GO; (3) C6Hj + C6H; C 6H6 + C6HjO (4)o The polymerization mechanism assumed by P. S. Shantorovich and I. A~ Shlyapnikova Uysokomolek. soyed., 4, 1369 (iq6i)) which first yields diner biradicals reCOmbihing into the polymer, is therefore impossible. There Card 2/3 8/020 62/147/001/016/022- Products containing an odd B YR1 0 1' is I tables ASSOCIATION: Iristitut fiziko-organichookoy kbinii Akademii nauk BSSR (Institute of Organic Physical Chomlstry~of the Acadoxy of Sciences BSSR) SUBMITTED: Jume 4, 1962 Card 3/3 m TEROFEM, KKOLO"j. Natallya, Dmitriyevna; Ukbn. red. TKACHEVA T.p red.j,A re A S~ Ap$ I'Tables for calculations involving the topokinetic equa- tion O(Al - exp(-ktn)] Tablitsy Oda raschatov po topoki- neticheskomu uravneniiu KeI-exP(-ktn)- Wnskp Izd-vo AN BSSRp 1963. JL31 P, (IQU 17: 2) - . - .- --- -.-- - .1.1--l!'......11-1.11 I.. U.- H, -I 9.11W~ I I. JAUUI~,llll I I j I ILI 3-I'mot lul I it liqua N111:111 I YEROFEYEV II.V. [graf"u, B.V.lj ZHAVNERKO, K.A. [Zhaumrkaj, X.A.] l1iMtlOd Of tM AdUattd liquM-~ph$09 oxidikUmn Otgolohaxanol, Voistai AN BSSR. gar. fie.-takho nav, no,3153,-~ll 163. (MIRA 16110) Uk -Ma PMXDDICArAYtDdklajw Akademll na TW Twhe b 6f -a rature do p or~dd mii* a ~tiwl -towpims, Ibil I:i of t;o molecular wiolgbts of 1,00 1 &.)1 93 0 9 0 cop I I ft), and 613,900, and of tl~~ poly-a-methyl atyrtljn6a of, thamolkul . Jioid- U 6f C06,NX) and 54,800 was me"ired by way of reduclne;'thel p'rq~wmr~ "1 44, rwroo emm 400 to kg/cm2, as des~'pribed by'K.M. Martyn3mk, ami Se"Im ~:o ( 2D0 M~loidrwy zhurnal, v. 25, no. 2, 1963). Themononwro-ie, 1"1 13 (1 1 antic nila Tolpmri.- ~ Card 1/3 J 1! 1 "'2&a u "m . . ii LU-11111i LUAL LU LLJI FIN TT.Trrf-l I TL1 12 11 '63A 0'jt/dQj-/006/N)6 .126 de~iji-~ictlon of, lake Wreiirphotjs ac-, 63 imi; ii 4ia' above 7, 7 YEROFSYEVp B,V,j xRAVCHUMp L.S. cbrmatp)graphic determination of brdr*gen in bifwY nixtures of gases. Dokl. AN OSSR 7 no.,4t247-450 J,p 063. (MIRA 16t11) FROTASHCHIK.. V,A. - YEROZLjjX"&j2 Deterntination of the surface of products ofCM therac. decomposition of KHM ty chamisorption of 2, DOM. AN BSSR 7 no*5 4 W 163. 026-72 WRA 16 t 12) 1. Ingititut fisiko-6iganiahaskay khiaii AN BSSROI YEROFEYEV, B.V.; NAUMVA. S.F.; MAXSIMOVp T.P. Kinetics of TIM - Induced polymerigation of 1,3-oyalohmadiene in bentene soluti7on. Vysokom. isoed. 6 no.4016-721 Ap 164. (MIRIL 17s6) 1. Institut fisiko-organichaskoy chimli AN BSSR. KHACHATUROV, A.S,; BAZHENOV, N.M. [deceased); NAUMOVA, S.F.; TSYKALO, L.G.; MOITM B.V. ...... . Nucloar magnetic resonance spectra and structure of ollgomers of 1,3-ayclohexadiene. Dakl. AN BSM 7 no.7s459.,463 11 163. (MIRA 16tio) 1, Institut fiziko-organichookoy khinii AN BSM L In3titut vyso)rc&olekulyarnykh soyedineniy AN SM. -ISIV - GD/JK J:g SWwZ 0MR; ACC NR: ATW31600 UJV0wD/64/000/0w/M85/0l69 AUTHOR: Terofwev. Shlyk, V. G. j Kazakey1ch, V. OFfi: none Trf=: Similarity of the initiating action of salts of wtalS capable of assuming several valencess in autocatalytic oxidation and po2ywrization. 1. Comparison of the efficieticy of carbojWlates differing in the 1Wdrocarbon chain laq,,th SOURCE: OeterogenWe reaktaii i roaktaionnays sposobnostl (Heterogeneous reactions and reactivity). Minsk,, lzd-vo Vjsshaya shkolk, 1964# 185-189 TOPIC TAGS: chemical initiation, polymerization rate,, autocatalytic o3ddation,, cobalt,, carboVlate., manganese atearate, leadt stearatej styrene, tetralin kiydroperoxide., auto- catalysisj chemical valence ABSTRIM: A Au4r has bm w -ib of the effect of ~ carbwWlates - of matsle capable of assudag seweral valwe" on tbe, 1=14--f.11Mq rate at-AbMNwM In ths Presence of tatralin bydroperoxide. The expakriints were cdnda;tii--w1th sa4~1-al cotklt car- boxylates (flormiate,, adetate,, butyrats, caprylate, and stearato),. and,with manganese or bead stearates, The dependence of the polymerization rate on the IV-droperoxide Card 1/2 L 01083-67 ACC MR: AT6031600 and carb)iWlate conconization was studied. It was shown that the polymerization rate of iftyrene, in tho presence of bVdroperaxide-carboiWlate systems, depends both on the r:witure of the wital and of the anion. The Initiating efficiency of the carboVLites increased with the hydrocarbon. chain length,, that of the metals in crossed in the order: cobalt< manganese < lead. Thump the initiating motion of the carbojiylates considered in polymerization is similar to that in aut4ocata3ytic oxidation. A scheme is proposed which explains the initiating action of carboigrlat-es as a reoult of the substitution of bydroperoxide for acid radicals. Orig. art. has.: 3 figureis. LbDD SUB CODE: 07/ SUHK DATZs 12D~c 64/ ORIG HU., 007 Card 2/2 4- L 01082-67 ACC NR. AT . . .. . . .. . . .. . . . . . . . . . . .. ... . . .... . . .. .. .. . . . .. . EWT(m)/T/FdP(j) IJP(c) GD/Mt 4)0~0/066/0i~0,6194 SOURCE CODE: AbTHDR: Yerofeyev, B. V.; Shlyk2 V. G.; Bachovokayn.N. P. ORG: none TIME: Similarity of the initiating action of salts of metals several valences, in autocatalytic oxidation and polymerization. the ;polymerization rate on monomer concentration in the presence or stearate Al copa6ble of assiLming 2. Dependence of of cobalt form~Late 111 SOURCIE: Geterogennyye reaktsii i reaktsionpayn sposobnost' (Heterogeneous reactions and reactivity). Minsk, Izd-vo Vysshaya shkola, 1964, 190-194 jL~Ixj- Ajo- TOPIC TAGS: Yinitiation, polymerization', styrene, tetratin hydroperoxide, cobalt stearate ABSTRAC ' A tte of re b,:tudy has been made of the dependence of the polymerization a tyj nekin zene nolutiont; in the presence of cobalt i;tenraw ITinafatal on t1io mon oncentration. Inie experiments were conducted in the absence of initiators, or in tn-~! presence of tetralin hydroperoxide or of the system hydroperoxide-cobalt stearate(w fbrudate). The polymerization rate increased with an increase in the monomer concentration, and to a certain limit with an increase in the stearate con-,,.*- centration. The formiate increased the polymerization rate to a lesser degree. I was shown that polymerization of styrene, in the absence of initiators, and in the presence of hydroperoxide alone is a first order reaction. In the presence of the L 01082-67 -ACd- NR, AT60316ol system hydroperoxide-stearate, polymerization was a second order reaction, I)roving that, In this case, styrene reacted with the stearate rather than with the hydro- percxide. Orig. art. has: 3 figures. [BO) SUB CODE: 07/ SUBM DATE: 12Dec64/ oRiG REF: 002/ OTH REF: 001, 1 10 vlk YEROFE'YEV., B.V,,; PROTASHCHIK, V.A. New relationship In topokinetic reactiona. Dokl. AN BSSR 8 no. 1:39-40 ja 164. (MIRA .17: 5) I* Institut fiziko-organichookay khimii AN Mcl R. NAUMOVAP S.F.; MAKOVETSKIY, M.I.; Sulfomcid cation exchanger based on 1.3-polycyololiexadiene. Dokl. AN BSSR 8 no. 3:161-164 Mr 164. RMA 1715) 1. Institut fisiko-organiohookoy khimii AN BSSRo YEROFEYEV B.V., akadmik; PROTASHCHIK, V.A. "Zzzzz;;~z ,w4,,. . Compenutlon re'ation between n and X in topoklnot:lc react,lons, Dokl. AN SSSR 155 no. 3:647-650 Mr 164.. (HIPA 17s5) 1. Institut fisiko-organicheakoy khimii AN BSSR. 2. AN RS-SR (for Yer,DfeYOV). MACHIONISO Z.A. LMacionis, Zjj YMOFEyEV., B,V, Ratio of Siggine constants for monodisperme and betei o0loperse solutions of Polystyrene and poly4-methylstyrons. Dai. AN MR 8 no.~4237-240 Ap 164. . OURA l'ls6) 1, VilInyussidy gosudarstvannyy universitet imnl V. Kapsukasa I. Beloruankiy gosudarotvennyy wAversite-lw' imeni. Lenim, i . ......... . .... .. ........ YEROFEYEV, B.1f. (Erafeeup B.V.); SHLYK, Y.G. [Shlyk, V.It,.); MUSIK, A.Sd Analogy between the initlating action or salt-s (if netaJis of Variable valency in the resctlons~of oxidation ind pnlymerization. Part Is Reart-ion rate an a function or initiat-or conventration. Vestsl AN BSSR.,iSer. fiz.-tekh. nav. no.3M-79~ '64o! (KRA 18:2) YEROFEUV, B.V. [Erafeeu, B.V.1; HAII,V~IA, S.F. [Jlavujr.~~,Ijj, S.I..1; A',JT'mTSKjy, .---i If".1arkavetskiy Study, of the thermal stability or the IMn-1 aulfonated caticn exchanger. Vestsi All BOSR. Ser. fiz.-tokh. nav. 110-4:44.U-52 164. (:-IIPI-. IS: 3) IVANIKCVTCH, 'fe.F. [IvanIkoviah,, IA#Foj; ZAR78KIT, M.Vo [" "arleitakig M.Vol; YMMYEV, Bev* [Srafeau, Bev,] umummomm" SpInels as carriers of catalysts for n-hoxano &romatimation. Vestal AN BSSR,Sor.khlm.nav. no#295-9 165. (MIIM 18:12) . ......... NAUMOVA, S.F. [N&vumava, S.F.]; SLOBODCHIKOVA, L.K, (S-Im,bod(ihj,ksv,~, AL.K.); YERC,PEY-zV* Me [Erafeeu,, B.V.) ---------- Epory rosin based on poly-I 0 ~-cyc lohexad ions. 7outui All BSSR. Perokbimenave no,2:10-15 165. W;Ik 1802) f 11 K I *y of c:-,,- jpr and chi -c..~ n, r-trv;i ton -tivity. Vestal AN 65.3,3~,r.kLr..rav, itAlyc4a a( ,YERQFMV B.V, akadomlk; NAUMOVA, SoFe; T.SYMO) L.Gli Chrr,mtogrAphic ropuratinn of (olignoars, Dok:L, AN 83P 163 no,4188/.-886 Ag 165. 1818, Is Ins,tltut fiziko-organichoskay khlmii AN BSSR. 2. AN BSSR (for Yerofe;rev), KRAVGHUKP L.S.j POiTYAK., A,L,;YEIiOFLFYSVI D.V* Mectran paramagnetic resonance olgni4 in a bright bl,,;vv modift- cation of anWraus copper formlate. Zhur. strukt. khJui. 6 no- 0645-.647 Jl-Ag 165 (KIRA 19:1.) 1. Institut f lziko-organialieskoy khJmJ.i AN BSE'A i Belo-rueskly gosudarstvannyy universitat imeni V. 1. Lenina,!Mlnsk. Sulnitted December 7, 1964. MACHIONIS, Z.A.; YEROFEYEV B.V. Viscosity of solutions of two-conF -ent, mixtures Of POIYzer homologs (as exemplified b7 polysirmne and pal:r-+-metb3rlstyrene homaloge. Dokl. AN BSSR 8 no.lOs657-660 0 064. (MIRA 1893) 1. Villnyuoskiy gosudgkrotvenrqy Univeraitet in. V.Kapsukaf:a i Belorassidy gosudarstvannyy uni"raitet im. VoLL-eninao YEROFEYEV B,.V.; OSIPENKO, I.F.; DCROSHKEVICH, M.N.; ARAPOVA, L.D.; & T.N.; ROZENSM, A.Ya.; ZERNOVA, N.M.; 2VIZZIfOV, V.V.; KATSEVA, N.M. Antiblock composition for cellopbane. Kh1m. volok. no.4:64-66 1.64 (MIRA 18:4) 1. Institut fiziko-organichookoy khimii AN BSSR (for Terofeyev, Osipenko, Doroahkevich, Arapova, Birullchik). 2. Mogilevskiy zavad iskusstvennogo, volokna (for Rozenberg, 7arnova, Zvizzhov, Katseva). .,-.-P.j~!.;_YEHEL'YANOV,, N.P.; BELISKAYA, M.; LAR2UTINA, E.A. jgBqZJUW Two rum mett-is of preparing I-c7clchaxen-3-ona. Dokl. X11 ESSR 8 no.:Lls720-722 N 164. (HIRA 180) 1. Inatitut Miko-Organicheskoy khWi AN BSSR,, .131 Om S/136/61/000/00.1/002/010 AUTHORSt Parfanovich, B. V.# Gnedin, 1, 1.0, and Terofeyev, 0. 1. TITLE; Methods of Suspension'of Continuous Self-Baking 10 Electrod'es in Celle-for Electrolytic Extraction of Aluminium AIRIODXCAL0. Tevetnyyo metally, 1961, No. 1, pp. 40-52 T13XT: For the last 25 years, the most widely used system of suspension of self-baking electrodes, has been the 111(isdom" sysiem,' based on the application of a band-brake mechan tam. In addition to \31. other short-comings, this system in manually op~eratad and, as such,.../ does not lend itself to automation. A system. developed recently both in the Soviet Union ("Gipronikeill and "Giprostall" Institutes) and in Germapy (Demag), and based on the application of pneumatic- ally operated, split steel bushings wtth rubber-coated working surfaces, is free from these disadvantages, The principle of this system is illustrated in the figure reproduced below which shows: I - electrode; 2 - bellows-operated clamps of the current leads; 3 - split bushings with pressurized rubber tyrei; 4 - air cylinder;~ 5 - pressure regulator; 6 - presaure.gauge; 7 -~3-waY valves; 8 - springs. (The insert in the right-hand corner of' the ill.-uztr11-, Card 1/4 S/136/6l/000/001/002/010 E193_Z583 Methods of Suspension of Continuous Self-Baking,glectrodes in Cells for glectroly,tic.Extraction of Aluminium 10 illustration shows the position of the 3-way valves (1) when the electrode is stationary, (2) when it in being loveroii down, and (!;) when the -top split bushing is being returned to its original position). fAz*nv P"Wr AMC". 7 2 Amt 0 h V Card 2/4 5/136/61/000/001/002/olo Z193/Z583 Methods of Suspension of Continuous Self-Baking,glectrodes in Cells for gloctrolytic 9xtraction of Aluminius During normal operation of the cell, the electrode it stationary, being hold in position by the two split bushings, pressed firmly against the upper part of the electrode shell by the action of the pressurized rubber tyres. In order to lower the electrode into the bath, pressure in the bottom tyro in released and the electrode, gripped by the upper bushing only, slides down %=der its own weight until its movement in arrested by stops incorporated in the bottom bushing. The lower bushing is then made to grip the electrode by -applying pressure to its tyro, pressure in the tyro of the upper 'bushing in released, and the upper bushing is returned by the action of the springs to its initial position, preparatory to the next lowering operation. An empirical formula for the force, required to grip the electrode of a given size, has been derived by the present authors, and a table has been compiled, giving the main characteristics (dimensions of the split bushings, pressure in the rubber tyres and bellows, etc.) of the mechaniam discussed for electrodes ranging in size from 650 to 1400 mm Card 3/4 S/136/6]L/000/001/002/010 9193/&583 Methods of Suspension of Continuous Self-Baking Electrodes in Celle for Electrolytic Extraction of Aluminium in diameter. There are 2 figures, 1 table and 3 references: 2 Soviet (1 a translation) and I non-Soviet. ASSOCIATIONt VANX, Gipronikell Card 4/4 PARFANOVICH, B.V.; GNRDIN,, I.I.; YEROFEYEV, D.I. Self-baking electrode auspension systems, 75yet, unt. 34 no.1. 48-52 Ja 161. (MIRA 17:3) 1, Vsesoyuznyy nauchno-issledovatel'sIdy allyuniniyavo-magniyevyy buititut i Nauchno-issiodovatel'skiy i proye)ttnyy itistitulu- "Gipro- njj:el 1". tat Lw!wjI,-w [jUfijwwLLLHJjUVH NJ p Ghistoe,Nat Works During A of Ulce,7T= Machines *1 Abet Wo 'Vol., 14 No. 4 Season* Lempertp'E. K. and Erofeevt G. No . (Tor'f.. From. .0ot. 1953 (Beat Ind.s Moscow)p Apr. 19529 /+-8; abstr. :Ln Fout Abstr.o Natural Solid 1 Feb. 19539 z~-8-8p 14). Figureo are given for Lhe colloo- Fuels$ Winning tion and drying of hydro-peat. YFROFEYI-.V,, 1. "Countries of the world; concise eaDnomics mamLal." Reviewed by 1. Erofeev. Geog. v shkole 26 no.lt92-93 Ja-F '63. (W-.RA 160) YEROFEYEV, Igor' Aleksandrovich; SARKISOVp M.A., red.; SAFRON07A. I.M., (Mood transfusion in a policlin.1c; pract iceslo~ the.Loningrad City Blood Transfusion S atioilpereUvanbo krovi v ~$Iloviiakh polikliniki; opyt Laningradob6i,jorodskoi stafit~mli p4r~livanila krovi. Leningrad, Kedgts, 1962., 50 po (MIW~ 16t2) (BLOOD-TRANSFUSION) ACCESSION NR: AP4012S28 J/0056/64/046/001/0099/01.05 AUTHORS: Trebukhovskiy, 1!u. V.1 Yorofeyev, 2. A,I.Tikhemirev, 0. V. . , ~- 41;04 4." dwoor.. TITLEs Investigation of inelastic collisions between 2#8 BeV/c negative pions and protons SOURCE: Zhurnail eksper. i teoret. fix.* v. 46# no. 1,.1964 99-105 TOPIC TAGS: pion proton interaction, pion proton collision, in- elastic pion proton collision, Rho meson, mass deticit, residual mass, momentum transfer 0 ABSTRACT: The reaction 7r + p - p + 7r + m7r. with 2.8.BeV/c pions on hydrogen was investigated in -a 17-liter propane-xenon bubble chamber. The production of a p meson in.demonattated, with a cross section a = 0.30 + 0.07 mb in the momentum-tranafer region 0.2--0.4 Bev/c. The distr~17bution relative to the residual.masses shows a peak at MX = 1.00 + 0.01 BeV with a half width 60,�,20,14eV, cor- Card ACCESSXON NR: AP4012528 0 0 responding to a final state 7r 7r, 7r . The iso9pin of this state is T > 1 and the cross section is a - 0.16.� 0.05 irb in the range of momentum transfer to the proton 0.2--0.4 BeV/c. "The authors are grateful to the operating crew of the ITEP accelerator and to the scanning crew of the ITEP for collaboration in the woil,,kr te Acad-e- mician A. I. Alikhanov for suggesting the problem andIfor cr t ca analysis of the results: to V. V. Vladimirskiy and B. L. lc~ffe fo a discussion of the results and for critical remarlcs;~to V. A. Kol- kunov for calculation of the phase curveal to V. V. Birmin, Yu. S. Krestnikov, A. G. Meshkovskiy, A. G. Dolgolenko,.and V. A. Shebanov for help with the work and for a discussion of the results." Orig. art. has: 7 fi4 res and 3 formulas. AF SOCIATION: Institut teoretichealcoy i ekeperimentall,nay fiziki .z"Instituto of Theoretical and Experiftntal, Physid,'jl Card ZERMMO" I.A. C4wthlctlou of system for aleir, rabanhol operation. ITO. i tekho okop,' no45:146-1411 8-0 ~63. (MIU 16:12) WWAWO valey Qaayevioh;, Y3MOFMY#I.A*, red.; NMW, N*Ia, teldin, redo Camide to simerals wA rocks; mm&l for ItaUnts -in pedagoeltal institutes] Oprodelitall idnomlow I gorvr~h'pqroo; posobie dlia studentoy pedagoglahoWelkh institutove IEL34: Moakra, Goo, uchabno- pe&M, izd-vo Wom prosy VMM& 1952. 172 V,O* (KIM Ut7) Nineralogy-Classification) (looks Classification &M, noosadlaturs) NAGORNYr, B.A.; M .,,Ted.; YXDOTOVA, A.I., -boldm, red,j PON " tekha, rodg rimoresting questions in 4*09ftpbro wmxwl f6i szovi-cuirlau2m wort] Zemi*tellap Yopromy po geogWli; pomotle diiihi vlwkl&svuol rabaty, Noakra, Goo, uchabno-podagog. lsd-" 14-ira prosy. aspaut 1901. V49 P. (KIRA licio) (Goognphy-Skmainations, Iquestions,', eta.) ALMIYWA, Irinn Vikolsyevna; YMMAYXV. 1.A., red,; MAMIXIOVA, X.S., tek:bn.red. Efba Chinese People's Republic; from practice In pnpuring geography lessons for the Oth grm&l Kitalskmis 11srodnals Respubliks; rasrabotim urokov po geografli v VIII klesse. Is opyte raboty. Kookwa, Goo.uchobno-pedagog.lvd-vo X-va promv. Rsm, 196o. 7o p. (KIRA 13:12) (China--Zoonomia meography) 41. BMYAVLIWSKI*r, GeorgLy Pavlovich-, MMCN%Yff. I.A. p red.; MUMIKOVAq [Annotated bibliognp4 on the geography of foreign couutries; textboi* for teachers] Annotiroymanyl ukasstell literstury po geogrefil serabosba7kh stran; posoble d1la uchItelel. 36oakwas Goemabobno-padagogelad-vo N-v* proov.RRSRp 1960s I" Pe matA 14:1) (Bibliography-Geography) (=IN, Isruill Adollfovich; DANWG' Boris Moiseyevich; IMFJFYJIT,, .1a"red.; 2MYAKOTA, N.16: red.lartS TSYJPPO, EComintries of soutbmetern Asla.and lorth Africa; economic- gaiNraphical survey. lextbook for U80~ArSl' Strafty lugo- Sepadnol AsIl I Ilevernal AfrlkL: skonomiko-mograflabaskil obitor. Poobble dlis uAitalsim, Moskva# Gon.uchabno-pedegog. 1241-To M-4a prosy.21M. 1960* 279 po (MMA 13:5) (Africa, Nortb-acomosic conditions) (Near last-Sconomic conditions) YEROFFYEV, I. A. Cand Chem Sci - (diss) "City of Vinits. (Econ6mic-geographic features)." Moscow, 1961. 14 pp; (Ministry of Education RSFSR, Moscow State Pedagogical Inst imeni V. I. Lenin); 2CO copies; free; (KL9 6-61 sup, 201) MELIKHZYZV 9 Hat"y Nikolmpvioht TWFIM I.A. a md. j KOIISHINAp V.A. v DRMIZDVAp H.S.P gm. kode WoograyMa ammi topodW di ationaryi Uxtbook to:r ral Cloolp*fiabookie Imemal toponWoMoldi alovarl, Pow ucUl to3Ai. Mask"# Woo uol-.obw-podavg. isdo" "L RSFORp 1961. pe (VMRA l512) 099=800 KOZIJDVp MiklwU Vasillyevich; SKU410VA, I&P.9 rodsj XRWMwit I.A.0 r*di,l ZffTSVAj KeY.9 red, kart; [Ze(womic geograpby; concin, textbook for to"iberm) Mmaoiv chanksia goografiia; kratkoo pooobie dlU uobitolla,' Nawkwap' Goo., uobobno-pod*gog. iod-vo W-va prosy, RSM 19"it 239 ps WRA ut 8) KWS.,11ekasy Aleksandrovicb; MAIAYEVAp S.L.; RYAZANTSEVj S.N.p Otv. ......' red, 1 TWFEM I A red.; KONOVALYUK, I*K.# mladobiy red.; GOIAA;,7T.T.-, rW".km;t; VIIZSUYA, E.Na, ~ekbn*. red& (Th~ Moscow eavirons; economic and geograpbical featucreal Pod- moslcovle; ekonomiko-geografichealmia kharakterlsti)a. 14oskvap Gosoizd-vo ogr. lit-ry, 1961o 301 p. (MIRA 15: 1) rMoscow region-toonamic geograpbV) OVDIYENKO,, Ivan Kbaritonovich; ZAYCHIXOVp V.T., doktor gwgr. nauk, prof., retsonse#1 IZWFEUV,, I.A., red.; EOR=HA, V.I., red. kart; KARPOTA, T-la-mr.- M-. [Tho Mongolian People's Republic; a survey 0 its economic geograpliy] Mongoll skals. Narodwda flospublik*; skoulmaiko- geogWichookii obsor. Poso0io dlia uchitiloil. "oskva, Uohpodgis, 1963. 150 P- (MIRA 16M (Mongolis,.-Sconmic goograpby) BAM, N, 14.K.; BUTANTUTEV, B.R.; FOMUS, M.I.; RADNATEV, G.Sh.; GOIDWIN, D.A.;.GB=R'79VA,, A.A.; KFIOTOVO V.A.; DONCHENKOp K.Ya.; KOBZHUYZVt S.S.; SHATSILD, TeS.; KOSMACHF,Vp K.P.1 NAUMOV# G#V.; LIKHANOVt &N.I.PSTUKROV, V.G.;'TIKHONOV, A3.1 NEDESH&Vp A.A.; SIMAMYSM, G.M.; SHAKHUNOVA I-A. red P.A.; SHOTSKrY,, V.P.; TERM119 POLOMENTSEVA, T.S., mladshiy red.; red. kart; VILENSKAYA,,- ", tekhn. red. [Eastern Siberia; economic geography] Voqtochn4~ft Sibirl; ekonamiko-geograficheakaia kharaktoriatika. 14obkva, Gsog- rafitdat, 1963. 885 P. (MIRA 16:10) (Siberia, Eastern-Economic geography) YERarETV, I.A. Aah,tjjv~nts of the national econoW 6f the luring Um :rmw yeam or tm omn-y"r IpUn. Geog. -Y. shko3m 26 no.2,19-34 mr-Ap 163. (NIRA 16:,4) (Russia-leanamie conditions) k~t~v 9 W, eit! YIROFMV I. PubLishin prog. for 194 of the (begrephy Vapartwnt of the $tat* ftblimbing Som for PO&VOcal TAtomto,", v slAo2a 26 no.31" My-Jo 063. (VIM :16161* (Blb3lcgmpW--QGcgMpby) TREBUKHOVSKIYP Yu.v.,-__?~~OFFtY I?A.; T11010MIROVO G.D. Study of inelastic interactions in collisions between 2.8 Bev./c. )7- -meBonB and protons. Zhur. eksper. i teor, fix. VP no.l.- 99-1051 Ja164- (MM 1712) 1. Inatitut teoratichoskoy i eksparimantallnoy fitsiki, ACCESSION UR: A24043608 S/0056/04/047/002/0400/0403- AUTHORSt Grigorlyeve V. Ks; Gris'hint A. Pq; Vladimirskilpp V. Vb;'. Trostina, K. As; Yerofeyevt 1. A&I Tikhomirovt Go Do + + TITLE: Investigation of the 'reaction w + p-*p + ff + 7r + 7r at 2.8 BeV energy SOURCEs Zh. eksper. i teor. fiz., vir 47, no. 2, 1964, 400-403 TOPIC TAGSt pi meson product, negative pi meson, pbsitive pi meson, pion scattering, scattering cross section, resonance scattering al used by Yu. V. Trebukhovskiy ABSTRACT: The experimentail materi et al. (Phys. Lett Ve 6, 190, 1963) to investigate+the reaction 7r + + p -* p + w +W ffO (1) at'a primary pion momentum 2.8 BOV/c, was used by the authors to analyze the analogous reaction with chargea pions in the final state, namely woo + p . p + Woo + ir+ + (2) About 70% qf-the photographs .(total 30,000) obtained in the earlier lewd 1/5 AP4043608 ACCESSION URt investigation were used, and 350 events'were selected to check the distribution of the latter reaction relative to the three pion Imass. The"selection criteria are brl4fly described. The'value obtained for the ratio of the-cross 94ctions of reaction (2) to Ithat of M'.10 '8 + 0.4) offers evidence that these reactions are more likely to proceed via three-pion' resonance than via fo6ation of P and A"-resonances (p meson and A 'isobar). The irregularity in v/c2 the three-pion--mass distribution in the vicinity 0.9--1.0 Be l'indicates that three-pion resonance can exist with T = I or T = 2. (T -- isotopic span); "The authors-are .grateful to V. A. Sbebanov,,' Yu. S. Krestnikov, and V. V. Barmin for supplying the material, to Yu. V. Trebukhovskiy for participating in the.work during its earlier stige and for useful discussion# 'Y6. M.-Lapidus" V. M. Polyakova, and V, N. Lyakhovitskiy for guidance of themathematical reduction of the measurement dataf to-.the accelerator crew, and'*to the computdr crew for collaboistions Orig. artv! hex 14 f igures and a formulae. Cwd 2/5 ACOSMION KR&W4043608 SHOLOSURS101 IV CaM 4/5 I! III JIM~ 1"[Fill sit Ill""W 1, MAmmutm ONSAP4043608 mclOsuns 02 wow it it 11 1 1 1, , x-&. -a 0. 0 "11 - -U.J. 00 0 0 0 AP 11111tAM 11", 0 0 ad a 0 nd G 00 160 large Ilion lenst c"I' n Wo W1. 1111111 Ti *I a 20-1--1 01 so Wartw Olptimurn &."itior, USTI mail. 00 8 lot A kA v IF Tit - -,; It 1, 11 41 mt 0.0 of 9- Z it FA Ila 0 0 0 L*d"b &-,Bee 09- 1 T Z 0. 0 .00 40 fee see tees bee