SCIENTIFIC ABSTRACT YURYSHEV, A. V. - YURZHENKO, A. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001963220019-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


TURYZHEVI B"
Results of analyzing title records. Fin. SSSR 19 n0-9:49-50
6 158. (MIRA 11310)
1. Upravlyayuahcldy Kostromakoy kontoroy PromUnkae
(Kostroma-Construction Industry)

Y-Umzlw. B.
From practice In analysing the prospective plan. Yin. 0882 20
no.i:74:76 A 139, (MIRA 12t2)
1. Upravly9,yuahchi3r Mostromakoy kontorov Prombankme
(KOstrOma Provinoe-loonomic polloy)

yinyzlmv 1)o
Are construction trusts nee4ed In Kostrom-m? Fln.SSSa 20
noil2:60-61 D 159. (MRA 12:12)
1. Upravlyayushchiy oblastnoykontory Stroybanka.
(Kostroma Province-Construction industry)

FARMOV, I.Le, doictor takhn, nauk; YURIYEVSDTA, N*P,
Investigating the effect of the wisture content In YAo;cow -3--aln
lignite on the composition of gas produced In coal channals..Podzem.
ga;. ugl. no.1:39-42 _'59, (MM 12:6)
llInstitut gory-achikh iskopa7emych.Aff SSSR.
.04~scow Basin-Coal gasification, Underground)
(Lignite-Teating)

OJO 0 0 0 0 0
oaf'
- ',A S11- it is u a r* 6-9 a-"
r 'I
m-ivm
00
fllc~ctsttl APNC!
-00
0 0 A. Via. *0
j! ke Uniarrad .9.110 Volk. 2-0, 12t
&i. Rol.
00-C -6
~Fbcl r-PONtatial uf diAphfatms (CCIA11n. CrIhs-
BiLim-litc, Mier, iinte" gtilss) dm. not
001
tun paratki Siviiii the changs: in the tuaqwl nl,%. ( ~m.
In th* VkX jtVrCjSW in the clijlM. tA the plirev "j, t,p -00
act Inmaw In the r-fKRcutw to a timmad voluc; Z( ilm
00 same tinve the inuk v&vtA dimini*h. a, C. A. -00
-0*
00 of
so*
00 %1
-00
coo
00
Vo 0
Coo
:Zito
4*0
490
tie*
lack, --------- 114,44 $"SAW
449.46t
W
It u to it a W, Ad
10 a 0 o 0 a 4 0 0
0 0 & to 4 000 0 a 0 0 o 0 0
o 0 c 0 0 o 0 0 0 o

9; ts 14
A A _C AL r
x f-
4f
so
f
00
#3
16-6
00
oil.
plot.
&5A.$ 4 A As IALLU46KAL LITERATU4
plow II.-ODAY4
it
49 0 0 0 0 0 0 S
Ie
*10 0 0 0 0 0 * 0
1 11 0 a a a is a a i in- loll U13 Idis Is" lemps. 41 4241 .46400
0
t AA W.Cr to Ir k-
:-Go
Tilmducillci G=bem at inns as characo"iratim ad
PC*Ptxdes al dialphagms. 1. 1. 1. zhuk(,V
aWA. I. Yunheako. J. APOW C", (11, S. S, R.)
efflevi of celalla, lickellte, day.
am. chdaumis and k-adw an (ht tran.-
("Mm W. al kma was studied. Vcvlh='( .60
of the dtapbatim and lhe Pte aff(vt the IrAftirtIvaw rom,
=60
V. A. Kalklwyaky
2 sG*
CLAISWICatlam
laR, 41.117V
An ad-* N a ft .3
If to al a It
'Q : 'm : : IF ij
a 0 ve 0 * 1 0 0 000 000 000 06 0
a 0 wo 0 * 0 0'* * I

4 La. 0 -_'VAL 16 4) 0 0 : 4 0 6 a 6 a 3 0
'4 fill ffx~V a A x 3 ft zF a tv IF I, V u V a
L A -4 AL. a 4 1 1 W t I-I I _1 4A a cc IV a 4'. 1 A
;L I 1 1
A .FtIpd. with
figas a
*4% toemalin "A Impregnated with 6, t0% CtEatw SdA..
sea bad 10.402. L44 a CmMic dhwbnlc= 'Llo- Ud r-
U. xt__ Znm Ov. - In am expu'# am Sol=, had Pw - I AM
of We
W Cd ad do Cunvat 01MIA IM 20 Ma. TIM
so "d foa thdic ofactrol* "Clak al Me above doubk dtitphr" laccrawd with .00
v
1. Zhu v and A. 1. Vul 0. J, 16MAM in the town. of t1w teltun wW. dhxWfAd an the .60
so -_90M.; . C. A. 70.
C
C
(U. S. S. R. 9,1733 cautak ditphrairs. Tke radius of Pam of the ccumir
otionotoot NKCIdu I=ar- 400
tranderence no
C" Impreguatcd with Caulme) and Cer-
- ; rd
00 a k diapkrums varied (no. ad. CI equal to 0.321--0M8 '00
*00 aid OZ*"JW.rv, V.) v"y Qhtlyw(thin *80", ItUiu- disphratm was 143 m$. and that of (he 1070 Celain
(as a Mit. at OW "Maglisel 00 at djWsihn4m was 20-28 nzs. A dauble dLVhctcm. pccpd. 000
04 '3: :,M'(o")(ard:cccrzmicdixVhracTn- ncefectrakinek fromaccramiC&Iphragm with apace r"uSG(=) mo and
so potential of the ceramic diaPhnLg- filcreasid (in abs. r ISM mv.. and with the above ceta 9*0
-3 mV a tits win., had
value) with Increase in team. by 2 f 6,45 mv. and t' - 9.31 mv.. and that Vr.Vd. from i006
it Turiation in the :hacge am the vjrfsm of the wW body. a ceramic diaphrum with a pore r"us of 12s MO AM ;",I go*
60_r The Cuffent. strenth in CH txpu. *as 20f-au Ms. rwmtr r - -2U to -21 and 24. 10. 9 and 41- gtIA(IM 401a$.,
Of d4aUd
M. lituftumatic famt1gadol J. 1.3. -and 5
16U 1739-44~A dauW dlAplu" lapprox.o.andf
' 2 lo-, getatin win. do a Munk to 0MV.
pcRjOd"MV0-Z diap COM at UYers with different electra.
AM '&
diat;hrgam (Pt~" S um penetration of am kinetic Is dcld' by the tayer with uncter Pore ro*
III:" tc actic
into the ceramic diaphragm). had 8A clec r V"fi tuns. A. A. Podratal
r(cutW (f) tqtW to 2.84 tuv. if the WAUS layer
fuse
aced the cathode and C' 3.14 mv, if It faced the AnO&-
to
be*
b", "
L#Tt*AT#At g Z--
gs$
Rig., 4,1-14V
.10 049 da( 41LASIM11 411111 ad "V Of
I F 1 9 j7F-Vl--r-TT a-w- T-1 -pi- _d3 13 1 v
u ft to 00 a it ad K;Ofi~ I 1A 4134,
0 0 deel too! f
glad 0 0 9 00w.90006 0 Go* *as C0614.066 6 0&90 9 sees a Oe 94'~

~ 'Filelic a e ass a *Go** *go it 0- 6

Ewu =46 (ST (was 4& am
bn
L
IV
'
,
p
w
T
dM(
u
lor 9 tea =
A
00 A =i
*
W
vurf. and G. N. 8krMkm. fe Gk_ Ciam.
kt
- 60
i

OGO 8. . R. 0, 2Is4_Qu(1W01. c(. Zhakay "d V
a
(L
C. A. A11, 2491144.-For tk d=Uc dimphrapst viem
009 "Plata" Conswino; of ccmutia and Vdigum k 02
:f M
*0
104041 a t1tow mmic disphrm" wma WNW a Lv
r, of
the cocklin Was treated with a alksam
of kwWAI(ft "d
Of .
carefoUF washed w(th water. In sm cans a HC1 mAcc. was

*4-8 u" (at to cleetta!yte. The valm of X was detd. from Z
wberaZinthe
=T
an &K"m of the radius of die capWuiti

0 C
i&.
C( the tnM* C*
"01- Is the
dl I= to ti
rim I
I fam mca.
p to c
&aphrogms the ekctrakizietic twupertims of &06
h

0 a .
N at cv
In 1: copOwks cJ itim diaplauva md ca-
p
f
che Ts of C1_ W a free ago
Ceranxic diaphcatm with me doa
[e diaphTr amusdied tbow (A ibm SOWS cc 4-
a
tin layer. The T thrmcgh the dauhk d*&svn%, W.
oo .
' "C 04 aes
p: p

GO j. and 250 (111) me were
expillay radd 11. 186 (U,
l
0
Th
Z
f
d
t
1191
31
6
f
a d

1
2 -
r
. a
ce-
.
or
.
Use
a
.
at
.
0.126 is -277Z. (or EU at 0.145 is
lit 211

ee
Celadu at 0;;14 to WA. lm an acid
dimphragms vem nctadvely chused 2vid 6,- tx"rc of Jc
as*
Cf - %-As decreawd. 11L obs. vahie 6fZ dwreastd with an
, refe"nees ad 3 caliks. W. R. fiefus too
kwcftw im the Adfa. In the d*Lbk
diu9mxvu, the
a
r the same Ceramic dia-
rQuaming vdws wem obtlioed f

SHE"
s with 10% geka". WIN= the 10%

*
-
7
i
M
I
d
t=
=

oo
t
t
for
at W
cg- (
V
an
40
mor Me
`(J"JWx
(ur rj at 010- Q
IWZ was Hsand If
"
O 00
.
.
_
.
wat ISA-19.8; (cc L11 at s'.m- ~=-QJU Z, was 46.1- nom*
WOO. When the 10&Citin I%Fm was WAC the Catit-
'
33
0
(
U
&
"
I
0-1 -O.W
tv
at X
.
.
wu
Ode. for
;
'
l
l
0
m
O
R
-
at O
a
es-
mg-02"Zir"31."
ce.
A
; kr
Tic
l
OJ13 Z
A
d
bl
di
1
4
T
-
ou
was 7
V
.
e
e
1
sp
asopm were
t
Was
btsicmdai.
id
A
h
a
oo
uxt
e
c%-
o
n
m g
@low jjV.vjjV4 $imp va"Amv
7 __

vs 0 calaw *it NAW qtx~
4W4C
Am"in
61440i *0 QWv Is$

, ir to 0 a K a x 11 or a

( K

C
s 4 4d a Is a I W 0 9 a I a T
0
To
0 0 01A 0 0 0 0 0 0 0 0 lip
m 0 0 a
0
0 6 9 a 0 0 0 0 0 a v 0 C a 0 0 v 4

A-T
I L 7Aj
40
c Pbj%RwA4mkd audip cA 4maWAms Gi
hydr(Kabac codduckowttk mvb" ~- -- - I lot
00, ftuft"actalutl6low A I vurzhecj~o. 4 '1
040
040 od ft%m it the P010-V site
so&
'04W 13 1 X 10" tiu.; awt mik cmut44a d Wjpgvim dAWVAcd by
Nm,*%tv. to 4 X III"
qC 41
Mae
too
!1041
law il"ao.
I 7-1w 0
u kip Ll ;ttm
to 0 * 0 : a 0 0 0 a 6 * 0
0 0 a 6* 0 0 0 00 0 - - - - - -I-- - & 0 0 & 0 0 or 6 6.60 00

k-iie 4 4. 4 q f
30 0 111 Ff :11 MIS Ids It 0 111 NO-41
- 4 a .%,
lip
twalstuty =Q(Wi#4W hydfacab"s imonomfics)
spults ~ A - 1-
0f fradwitAt
A It" ILC Mizito (tof~frlr Ptiliff. PlAtiONP, I Cit
Pit .1. 1#~41'1'
read. dirij, me. V.S.S.'v- 47,
-A fit 11h, pO
Via* SJAR, 47, It*$
-fisaft-mo 4 toWfloarlif4c tubsidgeel (1) to emolit?'"i
ft"ttok-W), PAIt 44 11W estlots"wr
worn flum the divVicts of 1tw clutsWilis Into the *it. jmlso~
Itlltun the l"Go"m of tk emumilying vvmt (Ill. Ttw
!
sAy. tic tkv mifftmW W" Acul. by ukAltiod tit ouvvi 4 1
"rithattaq. the" aw"noir Ih,-
8 it A the 4q. phaoct the emukkis (1111) N an AGW m6tv-
t"Issirtfir. The cow". IA I in 0,10 tsy VIA.. r. cakst. -00
(e -- pq)/(oi -- stoltv, Ito 4"', In lKWIC 41W ripff-i-
*O.r islillili
~i'sm 14, - I)AN, + 21 Par III. a purr -4re. 4 If. stid initir
Opq d
1, Trip. It ill ~4411, 44 3 617" Wev '1104~trltt
00.3 Olt Ining t1p JD Of ItUNJOIRCt illtlt *411. 4111 fly- coo
itirOks of 11 fttietl alm'"t lifteatly with s't"44-1t.;
rffict1vrvw- in of4amllsirg 6murne 41offelf'orif ijI Olto
twiter: K Me) Awe (IV), Nff, --Imfo, fe-im ump
1441, A'a #*sjd .-"&kdkxet61f#mtre. Xt
4mlivvir". 4 IV [it slitulliliellog VmFi.ms~ I divIrA-1
III the ord" izoprinoir. siw~. alrylonaffit, Tlw
tile by*"Mcbms air idduutably vA.14W In flatiar-, ftt,-
hvArmacbm litup! tw CM01. chkdy in the mkl4u, n! It.
SiUl the folly. flit OW 4-A"tAl -tatte 44 It it-Cit.
WS
Nit 4
Amwitingly. mit" 44 fvxv NWCI* tit mim,. of . Arati- a
Kchrril, -Ardlowsmi
rerfJ&r. IS. 37"(1944).-The vulcanifAtion fjt4tsill--
WKI
v - Ill qI!t6jc% *".I the "I vvictivist of "IfIlleficril gix"N me
dv-xtIfwt1 aml ("ling etirthiottt our qlkttvw~f tow ddg. (1)
41tv V14,44tiratior" 12) 41-1 stANNIV
-it-$ ski tit
digah-141 hid itif. 11ri-I (3) if* .1.41ANCY 4 ;6lito ~41.lt-itt"f ti
MrAM
o*
I
1"T'Ir-Wa is two a v I w Idi;~o714 00.
to & it vp 99 Itif picift teat lk I Ill
Off,
0-0 0 0 0 0 0 0

. % q " 9, 12 a' W I 1 111-:11 tzu me Kv Mae
q
A - 1. Vat Kakchkom (The 5.
V, lxfw~kv Putit N,42. Q, OWN. f . AC44. Md.
~,,_RA N, 47, Slit aa(tm 1~u t; 110AW W. Mork
A

c . 1-N91[aft the
of panicks a "theck tatrzol
tua a*4 ft( tha cmUlAXII qC UMmtc,

Al 3,0-3j) cnjit. It h qnwfy
the bulk ot UnfS" Of t t1m tpol (I= PCO"'Cils In
yl-
a
H
t
t
i

eme
-
intion Is c _ In
nomW
.
atu
i
'm
ind
tk
f
h
00 A -
z
c%mt
k t
e
%IRV "I cOUOkW m1m. 18 the 44. Ph&=-
m-W
As
M
WIW
h
O
=Ov
"Iti

.
.
C
U
aft cm
R.
w sq. p
=
.ncmmm whkb co"Wirat" Mawr 1c, the mkttks
mrq. I
rutrat"i"dw ghm fc.
AtiltiU In akibules Of PObTW OAbilfwd Agaktist ociagula.
sk" UY the 121011- rA OW cmuilliffbig KMI- As thel dis-
tAy", a-l-Wr Ls and tip. ftw vixtims of it Pao Into
(be sq. Phfi- Thims vilacesti. to the crAckedly
In (he =
vmceeb very
.
The 100cming basic data am In agmEmimt With Ike
it 4tmvc thewy; , (1) By - Onda emut4AC" (beatmit,
if kim4m) no P.Ayakit"41gq "%Wttd probably b"uW
the aq. PhALse is a" hydratropk. (4)
lit'" rale itkicaws With comm. at maUL&T. Other clattku.
16xu twill# ecuut.
Z) Mims

Phase ratfoa showed the pobvicrimcku ra UKM&wa
c
dUwdy wich the rekave vot. of the aq, tuse. (#% rat
h
k
f
lit t
e on
e o
their ability to dfmvd%e Wtombm amo- -
"Awf4- Nis W 'Aft(* ~,- N1f4c&at* > tuslo Amp >twkid

4 > No camlame. (A) UY jWr
1=0LIVIk lWxtcWl*c" tati,ii
in .6t6 WAVA. a dy In Will, gum ttm.,,_
0-0-0 i-I -611 ININ
9 0 a 0 00
.1 a u a SMO
-,;a xwuwf Is dill"Vii,4 I" 64mv. Vic atxrm cunows do not
I L i stuLtue?fCal. 0.4 rrx=.
- APP Y PWYcWd"Cicia c4 cWomVcrw vvhcn a Ono df%-;--
"AT 44i ii~;i 4~t
Aii lu 1-4 L 4 41 eW 4 K a 9 N Wr a 4 3k 9
ip W 12110to of" twit Otis locetc it 4 1 to old
411 0 a 0 a IF
It 0 0 0 0 tv 0 q -0 0-0 a 0 0_0 a
.00
Not
coo
We*
row
C:o 0
9*6
coo
40 0
0 4

EWIMHT~Y*r- 211129EMBM . - -
40 a " -boo P 0 6 o I- a '~. 0 0 6 0, 0 6 6 & 0 0 a 00 0 a 0 a 0 0 4, a
4, 0 a a 0 4 a 6 0 0 0 a e 0 0 a 0 0 0 a
Z " 4, ') *~ ~ ~ ~ M P . ~; . I . I . -0
4--L-A- AL_ -3 1 - IF -A-- 1_1 JLA W~LA_Lr,,. A.
die Froc4sa C4 Palymen=
It. Thatzn~ --- -- .46
of formation of syndledc faces In C4=4CUM with the F'X-
slitutEm of mon=etv in aqums W(udoxts
of 4mulsitittv. A. 1. Yuribeaka (Ixbctfcv All-Union Syn-
the-tic Huh1wr Urtincr-Al - J. Gen. Ckrot. W.9.1n.
Cf. C.A. 10.39910.
cin. study 0 the colut4on i,44vincritatik"i of
A jlhy,itNx+
i"Ittrue, aull louteuliettv wa% inatte. with N* oteate.
Nil, -4-Mr. Mill SCUP. Na tawillite, snit %xilottirl for
It is COMPIctudrit thst the U44111 "IMTPt 4
potymritathm &-I proccciting Ill tht. Iti4pl-r-441 Phalle Ill the
mcmenter is not Mtd44ct(Wy. Tltv~rote a the ent"WrWr
life iftfiff,,rent StAbilivatimt of floluh.4 of
patirmer structurm Since t1w rAtc 4 ac-
:;so
cumut4doll C-C l"yo" it ethnot litwirlY affilvI44 by Ill--
00 concil. (A file Cululvilk-f twillt 14vatfs it bi Intltf q.ITC%:6vv)' COS
this Cannot tic ex1+11twil Mcruly Ily all inctcow.4 intruf4cr
0 fAtatiatt C4."1111110114 Ma P( (tie motol-
mrr 6LuAwti coliflidAlly fit the Afil. m4n, 4.1 thr vinnNfier! i;o 0'
'Drill, d4 wAy. refrowtimuctrivally of Awr1w. ltlrthvlov~
so rttW. I'Alctle. ducl at.1vtollittil., Iltdcl-11 the athovv 1.11till.4.
tic" he A l4tew CC(kr AsAti, rou"'t few file rAle 4 I"tiv.
Thu,. the vultillient PtelYlIttritAtit)" ITMVIA z:O*
A414 takLq pt&lce it, the all, phase in the tnivelles of the colulsi-
fiv". and t1kc role 44 the tattez 1% ciptaineA bv ttwir &Nlitv i !-so
TheftKnIxtion
!.ISO
~~ Nei of taug can fake place without emutir-thIft 01 the
memly an contact of file aq. and the hrlro. tee 0
CIA 4A inteffave ill Cone ~hlnq
carbens phas". I'lle large at t:OO
phasgbythememont'rr, which
is important. sifter the equil, is being contlently qli,turlKl
------ hy mottomer remavw thmigh
G.. M. K;Wolspoff zoo
1~.' 413. tit
4111440 Nit '3.1 off
77
U AV 00 it KI L A P4 0 If a I K 14 1-0 4-3 1 -0
Crtvit CV44 94 1919 f(Clif It lawl3fl IJX4
0 0 *is o 0 0 0 * a * a o a q * 0 0 4 * 0
_0 0 _9 *I* of SO* SOO a a 0 a 0 0 0 0 e *I
fe OOOOCOOS e 0 o 0

YURZ7dEAO; A. 1. (Cont, I d)
"The Meohani3m of the Formation of %mthatic Latexes in Connection with the Proo6as
of Diffusion Monomers in Aqueous Solutions of an Fhulsifier,tl 1947.
(990W75).
Prize im. Lebedev, 1948j Publ*

20MMAJ=
[#a 6 w w w
All 0 4k~* 4, # 6 0 a 6 * 0
N-1 1. 23 m is 76 M 1, b A
A a L a A_.j
It- j -A.--
;F
* F;1 F.
Dispecoi4o of synthetic t4talet at distreat gtips al
their lqtmdWin, -A. 1, Vooit,,Ao-ind It. MinA.
is
Frt'd-mi'l. I.i~
by JN4VInviiiAllott tif 1.34na4thrile
in Ail, i'11111144m. liv 4.,It";. N,
utcttv . Me .ice
tile 144yinct paffick~4 ittmil-.4.41 witti
I'l the littm CI'Kt 4vtv"Ient 'Au (ound %Att tile CquA.
tion t - W!" 'AlIcte 0 it flit! av. t;tdjil~' b it Allit
etmen. I'm "N .3", 14tex f - 0.2411 tno (f,huld)
T Ptw I.Wi' lAtt-% t1w
v-.11tic, I'm f wCTv 0, 11)11. A1141 (1.01,11. test). SlIwIrr parvidr.
Ne,~&! wa~ wK41 in 14acr tit Nia Acme.
wt re 0,taiurd wtu-n
.00 (Cf. C.A. 40.4'5:;:P' Ifri4s). Ernet A. Winter
440
171 Zoe
11006 ~01190 Ivir
Ice 0
IR*
A I I A A AITALLURCICAL UIESAY1.111 CLASUFACATIC01
C.C
A- v 14
uis AV to w to 4
w of it fir off, Qrl fix*-&
0 6 a a 111 0 0 0 0 0 G
0 0 Q 0 0 a 018-0 r 0 0 0 0 0 0 0 0 0 0 0

alt PoIrmailatils" oft hyievark"s "14144KNI Ag4iltil CWgUtAtloa by Ike ,,,kVUfe .1 the
(a sauddan. A..! ~ Y! 01-Alf-'smillitt-1 M. Kof v;1m,v % "1"049 29cul, %,- lite dit"%vil matt"Wer Is
(efluipt. rem), :lead. ~d. 140. 4T.:U.4 Ul - used UP, new put6m, q( it p;Lu OIla Jim min-mu.
IUVILtady, 114*4, Natik WON 47- 114-7 1. This MUCCU. owitia to life alackedly im-
(hem. Al,,, 1946, 49, 49341),-Smer flic mr,i it ill the elt.u"#a, pr-o'C4. I,
f,tjIjfl4 III CIIII decrement .14
01 (ki f?.07 ltvit And lhat of file clituNoltv 0 ov-111MITI lite alxi%e fliecIlY. (i) Ify uliftc Whd gfuVi4irfas
3.4 AM 1111d. it 1, Uttlikilly IhAI fVI1);IWfiA1iI.ll Omatnuite qIc kjo(itl) no pv1ytllcTi~AdOa retahe4
prewe". its Ifiv hulk It mAlfur J thq. tlv~ftlawt P"'t"i'tY IiCMEL*C dW WitteclKila Phtfle is IVA kydto'
tfolkir. (if) 17M poly(neri,41j"n r*(,: jCWfM%ft Itith
i. macciiied A, (vnirentrallon Of clituNricir, other roadif6mi, W"..
Im.mliggig flimuch the "AV a Colloidal sigution
tioll--
111C wjuceu~ jjm~c- fly Culp&.Viag 2gmp *)to t-mill-M rate
&A rultINIM4, the A-JUVOCI. Pfigsi coutaim W-15", mcgrawi stilwtv ailh the mWivir %Aquic j The
4 the UYInufnel whirl) WAialy in the A(14"s [141C. (k) The fvqW6a4 tAJc, of Ike
mirtlk, of Oil; i~ap VAvsi%triwW4 m"utA in the entulti(ving Agruls ia%V*4i~Atirl I jife itt JIM ,a" "I
1.4saw re..4161,V $is rWMICS td 1"41-clicr their aNucy to dit"4ve ldvat-coC44,
W IN Uiltg C44vtu4 llv,tt,IIjWf1b Litex W44 it,
m"llwitilms" Fl,l-kotly ill 11.14. CAC the jluW,jtj
6 ditAved in U.411. IU atpl.%ir C.MLICC1.4% &I (too
whele a

46
Uthdamoltic dtyittg ad based an poIydIe4es_,A_A__
YzAhmm&twe-N. 1. SlArchenku, and 0. L ('111111MRA.
1101straf. Jlfoi=,4~rnt 1950, "No. 9, "29-31.1. --,rlw lj~v of a
%jrnthdie substitute fur linseed an is dim-rilied. The ad).
%tatwe i~ jx4yiliene. a kyw-m4A. dicair ptArn" (v%xn the
hr-lwolu.-t* 44 synthetic mbbcr prWtmioms. tt Gmint
6 SUS SPOMASICUISAT at fO-Xn IMP. in " day!$. White IddT
40 L".Oq, IN-coute. dfkr rcidom the time to 10-13 hts.-
Cis and Ca rainates are " cdec-Ove. The crude product.
ahtained (rum the punt. Is PobwerUm 4am-hAt fur-
p1m%hril by hcating at IM' with t1w aliuve drier,4 until dr-
.'Ifed VI.C4"itv Is rrached; R ltfw Coliv 6 Ictif"I the Illiffi
OUPOW not Im Added UUM after (he 0041441 lW4YfRC(U&tkM.
Testo Afth offset p"Kvu rubber sheds showed that very
little swelling (if the latter mun on immersion Into the
synthetk-od.- Color printing run an plant scak with the

M446aiwag wow "d "Naldd WeAuti to
N14'T ~4,- M422(11961 vc t L of NA
WAS, a=m tcl (he
CQWQ. clwt. at (4 . "X ut
On furtber fikltM Of C, f URnWW (0
demewdo pcomaubly bmauft Lim scat-
toroIL' v/u by hatoda, iktwem 9 m OSro
4 Vle r~=fg I= of c sw Was ocater to
1 6% thta in. U*G (PH 6-6) > OAL N ~~ >
i1
Tl N&CU-, The admilar at. (whkk Is pvop*mi=W to
o
f/c at 4: - 0) IM I9!nC20M AS", and 3MW in thicoe 4
wivents. 6up. Tie .019k,
sa-AdUU, swri mer
than at O"C".
imm at FIVIS. a Uttk Unn at PH O.G. Lum s(UJ in
0.01 X N Im 0,01 N violl. I.e.. **.
iFtCftAWd *~= to An wlvmts, the amt, of
SAMAJI d"hed b.1 1 9. 1 WAS lRd"%4C"j Of C 13COMN
0 71' " 3&- - at pil 12 It Was TOOQ4 C. One C, %*a okate
ii; 61 i4t -''*. POZ.
w"t"tion of tcrrttw w bopt= also Is umce rap" In &I .
(h" (a oeutml or aM moWs. of 1. The micefUr wt. Is Im-

YU I[,,- GUSYAKOV, V. P.
Effect of the concentration and nature of an e=lsifier on the degree of dispersion
of latexas. Dokl. AN SSSRO noo 1. 1952.
9., Monthly List 'Of Russian Accessions, Library of Congress.
1952. Unclassified.

C/9
Study q the dispettivity 41 "UtItatic latex" by meactif of
the latteMity 09 4ht WAVAA114. A. 1. VUfJhCQk:41 AM V.
(' 14
tuttviifity v of syllibetic Welts 'In,
ml-~l with the ccmcit. i: of the Lac" first littrady. then
jm:iwif thirmigha it=%.. and finzilly drefrAiech the peatrot
Omni. studied wus 0.570. At the saine C (C.) at which
file lirwar iflcrca~c CA r C,=AC41. the lkht ah~omckm Ily the
Wric becalm. nwslurthk: it repOr Itimau4i with e at
Jachrit, The t. w4if (I-(## I% f4w Igo ta4kene Weil (1) "fig.
As 111104i-W and.3%,~ V4 (Ifeme 44 fullillo-
W-r, AM 11.01 % (fit it 1101Y41 YM10 WO' 4 (111, 1111441`111W,11411-41
illy 3% K
tAurate. Retwetu the vorave le"tths A 44 4711 wit Mill nts
the lenglit 44 the linear stretch wit" 9frutef the MAW wAs A.
At v" sin411 c values (k*s than F1.11=34MM11 ~'). r wA, a
hn-r futt"ion ul h --. i.e.. the Rayleigh Low fit hilit Walter.
lisol w4s YA61. Frimp Ihis Nior i he p4olikk rafffiv; f wi4s 'U4-
10 film (,ill #,kttttpf" 0114ful Mo tilgi fiff IL IIcbvr,vlrqtfAfii"1
% tel-led 0, vAlurs 44 !54 -52.ma ftW I Anil 19 1141 f4w 11, Portion
111tutilikTo-volik qb~rorvatims r 0( 1 was SO tri Mo. F(W A
mi-11 elplulAfmv, the inma%r tit r with r WA. Come ralm the
grt,.ter, the 'Ircrer X C4 P'AyfilefirAtion. , The r im-fr-Avf
neArl-v 1-nWortiorially to X; this imhow, thAt pairnwori"firm
"I 'Lit rmuWmi Iffocceds by grow It of 1lartict" mvhrr than
Jlvirwre,i,,n1tWrnusufx-r. The polymerization was c~o-
Rikcmtan

Tke Mkdw wdsfit it dt+t-
soteftm, A, Yarshmko aM R. V,
Ndk( -110
Lwm). d.'jW.'U,
Cf. C.A. 45, 9MO.-Ught omctcring rwas tk-td. for wave
IvWN &NO-A-Aticht-fil(ret. On dif"-r tw4mmm. ("s-
mniwotqy~ wall wk" tlw cuwn - tinu ~ br(uw eke "it.
M, and toxw2w M rcq Na ckxw1rItwtucmvAtf%.m&tL- it). Na
dibutylbetuenmiAmate III) xW Na dibut1hutthdi4lette.
to the difficutty of packW tuphthAirm f fvx%~ At higher
Mm.
at 1/f (a rem cmim. Jim the mkdkr at. aw., This wait
-:XXW (or [it. Oftalkir a. 444 13ww for 1. *pin showing-
the acric hwamm Fag aggluffiewim of napitthakIN rwirs.
Aiw &Mn. of OAl C.-equiv. V&OH (to PIC If-P-11AL on
Weressed to 3WX# 91M) aud MOOD "w, and at pff t 14
ji. 0.01 s twhl w ;;; lwm. dfi6d. Z4 10firip.
ItmMahly, MOM roduc" t1w, (me mly. of 1. AM III
txv%uqc of its mm" km. *her"% ackt-I kmvv bemuse
mitmell" d the free acM facm. 0.1 X N"SO* frw;r=d sm
to =M) aM 7-7000 fac 1U and ff, C"p. Ausms the l"o
00(m. of fu fis fIgU-Millf mitts, lbov- In 40% F(Ull bad
The greatro r(s&mt 506mewthat [a 11.0). wheveav for 1% .
TWA(SCAUK(f
try the 4chptmtwz effect of HIM. suf(A~m temko T ill
IfrO in lowered by I mme than by Ut whkh L4 wme "ve
than Unt cVWu%A.cwmw..1 -vbW-4OcW/*q.ctnAmu.(XM
m wins. PCVtktCOM 09 Ofittle filOU Of U (*AM WAS
in Us muccut swft~.-

TSVLTKOV, B.S., aspirant; YMHZMm A.L, professor.
Effect of promoter oncentration oWtho speed of polymerization
of styrene in an emalsion. Dop.t&.pov.L'viv.uu. no-3 Pt 2:33-34
152. imm 9:11)
(Styrene) (Polymer* and polymerization)

YMZIMNKO A. I. TSVFTKOV, U.S.
The conjugated affect of the Initiatqr and emulsifying agent on
L
the rate of polymerization in emulsions. Soob.9 nauch.rab.chl.VOO
no.1:24-33 '53. (HIRA 10:10)
09mulsions) (Polymerization) (Smulsifying agents)

Chemical
Vol. 4p
"-,,y ifj, 1-!-)4 11y,
r -
c,enc~ral and
1he sulubiRzation of Stiidan ill in aqtteous anjutiona
_!1Lk~1bcuzcr%esu[Fonic, acid derivatives
IV,
IT

1. GUM OVA, V. F.; YURMEENFO, A. 1.
2. USSP (60-ONI
4. Disperzion
7. Study of the dispersion of synthetic late~ms in relation to the nature and
concentration of the emulisifier and monomer, Koll. zhur., 14, No. 6, 1952.
9. MonthlZ List of Russian Accessions, Library of Congress, Zaj:~, 1953. Unclasolfied.

TuRZHMMO, A.I., professor; KUCMM, R.V.. assistant.
Study of the speed of diffusion Of colloidal electrolytes In
aqueous solutions. Dop.ta pov.Llviv.un. no-3 Pt-2:35-36 '52.
MU 9:11)
(Electrolytes) (Diffusion)

YURzRZM, A.I., profelsor; GUSYAKOV. assistant.
on of g7athetic lgLtexas in relation to the
Study of disperal tration Of the emul2ifter and the monomer@
nature &nct concon (MLRA 9
Dop.ta POV.Llviv.un. no-3 pt.2:36-37 '52-
(Latex)

YURZHMftO
Inveotigating the double refraction in a stream of solatiors
of emulsified polymers of 1.3-brutodisne. MAut.XaP.L'vIT-Un-
21:36-145 152. (KLRA 10:7)
1. Kafedre fisicheakoy i tolloiduoy khimii.
(Refraction, Double)'. (Butadiene)

TMMKO, A.I.; YtM2HKM. T.S.
on the polynerization rate of
Effect of phase correlation
-butadiene in emulsions. VGuk.zap.Lsvjv.un. 21:46-54 '52.
1
,3 (HLRA 10;7)
(Butadiene) (Polymerisation)

A
j
USSR/Chemistry Polymerization Augi~ 52
Peroxides
Effect of tbe Concentration of the lz~ltlator
Olt' the Rate of Polymerization in Emulsions'," A. I.,
Turrienko and N. S. Tsvetkov, LIvov State lu
MR SSSR" Vol 65, 140 5, PP 1099-1102
i~6;~ erf ect of the conen of org ~nd inorg peroxides.
0
A~:,the rate of Polymerizat on f styrene ~n em
Oi6nd~ at varioTLS pH of water and conct of; emulsi-
The i1nitiators used were potassiua~ persul-
hAe$1 sodium perborate, bydrogen peroxidi~, and-
Alliethylpheny1carbinol hydrogen peroxides With
239r2q
Ithe peroxide type of initiator, the polviaeri-
Mti6n rate first increases with increased coMcn
0i initiator, but then s.lows sown. Thisl Is'
i6vh graphically by a max on the curve.f Lower-
ing the pH r esults in shifting the max ~o the I . I )
ld~ of increased concn of initiator. Submitted
Acad P. A. Rebinder 4 Jun 52.
V7i
239T29
j7,1

USSA/Chexistry M-a-11sifiers Aug 52
"The Weights of Micelles and Some Colloidal
~Properties of Sulfonated Emulsifiers," A. 1.
Yurzhenko and R. V. Kucher, Lvov' State U imeni
Franko
"DAN SSS.R" Vol 85, 110 6, 1337-134o
Theo, size and forms of the micelles of .9. no of
641fonated emulsifiers were studied 'With respect
to conjugated solubility of oleophillic'sub-
istances, surface activity, mech properties of
adsorption layers, and their behavior in emul
,,aion polymerization of hydrocarbons. Thesize
238T19,
and form of the Na salt of dibuty1naphthalere-,
sulfonic acid, Na salt of dibutylbenzenesulf6iiie
&aid, and Na salt of eicosylbenzenesulfonic nald
Vere detd. The colloidal solubility of a typi-
cal oleophillic dye (Sudan III) in an aqueous:
soln of a sulfonated iBmalsifier was studied
apectrophotometrically. By.comparing weights
of micelles *-tith the molar conjugated solubil-
.ity or emulsifiers, it is seen that, as the
former increases, the capacity of the soap'to
dissolve oleophillic substances increases. Sub-
23 Jun 52
0
i-

J
U8,63R/Chemistry Rt;~ber,~ Rubber 1 Sep 52
'S=mlsif iers
"The Effect of CorcentriLtion and Type of Emulsi-
f I er on the Dispersion of Latexes,", A. I.' Yur-
zhenko, V. P. Ousyakov, LIvov State U imeni Tv.
Franko
d~
"bok Ak Vauk SSSR " Vol 86, No 1,
PP 129-13L
Ot no and isoprene latexes were prepd in the
yr~
laboratory and tested with the following emul -
nifiers: Na salt of'dib enzenesulfonic acid
utylb
Ita. suit Of-e -06ni nzenesulfonic acid.
.6t di~utyi-Ltathiizaphthal 11i.-
Ne p&1 ones
acid Decreasing the
(nokal) arA sodium oleate
conen of;e~iulsifier' in the latex increases the size
of the particles, This it true for all emulsifie".:
;VUen the, concn of the emulsifier is over the crit
!conen, the diipersicn of the latex is detd by the'&Ls-
I*rsion of the emulsifier. At the c.rit conen, high
arsion latexes If with those emulsifiers whose
~dispL OrM
or;it concns are loves,t (Glulfanoi). what happens be-
I*the:crit concn is still being investigated. Pro-
tented by Acad,P. A. Rebinder 23 Jun 52,

2011

TSVF6TKOV, U.S.; YM,'WNKO, A.I.
Concentration of the emulsifier as a kinetic factor during polymerization
in emulsions. Koll.zhur. 15 no.4:308-315 133. (iTRA 6:P,)
1. Llvovskiy gosudarstvennyy universitet imani I.Franko. Kafedra fiziche-
skoy i kolloidnoy khimii. , (Polymers and polymerizt4tion) (Emulsions)

Study of the dtilicnsloa~i and Mtcj~* Q1 su!!c~czp m= I
th
met ffu. lon. R. V,~K(~Ir~r awl .1. V
ti
F. Fr-.ntn ~iv.,
-Cf. C.A. W. e I
Stoll wa-4 deltd. rfractullicukally. In IV) V (if Na di,
t V.-A.C. Ili I"i'alul 1.3
flGinte (11) %vas approx. 3 X 10-1 cm
s
X-10-6 Ili 6% An. lit 0A jv 1) dvjtQltd(,1I little
(114 COICIL MI(I %VRK 111MIF LI X If)-' VIU(I 0.8 X W
Both I aittl It had gottelicat N;%
Sullollate hall D - 0,311) X 10-0. alld it-; 1(mg,01 Va-,~70 !jIll"
its width. The iniceltr_% of I in O~ I N Na!S(), lmd rt~rfii r
of 2L-17 A. in 0.5-221;' sohm Dk-ht, of Sudan I I I (0,R
13 X 10-1 imTra~ud r to 21-!8 A. t

conc,2. of emulsifter at whA it is attairwd, decreasn with
the ccaca. of KjStO, initiator; r also im-Tcascs with 6-cTcas, in
the micellar weighi of the ernuLsifier. The mol wt- of th, polym-r
increases with the enulsfflcr coaca. R. C. MuZRAV.

al of Aa--j - & a
tl'o -d,;jtkg
'C'11g.'.Yq, -Ned.
~914; C11. -1. ill, -13,11
paruele, radins r oi !1: c-nuhiiosais, produced by
in the I~~f~-.ence o( -',67, %'a di"butyl-I-naph.
;~Z . -w, In'xCaling Of whdn
Nfelplicrx)~1 -,,is ule infultw, r1s.-I tncmastd
PH whell W~; ',V.A 'o-, thp. Witimor, p.g., at
40" art] K-AOI. v vis -',I, -`Q, and 42 mp wh" pH
wai 1 A, ~ i, and 10 8, j-"p . ii,,j at 45" ;t!,d 0.02 Af (8zO)I,,
. WEL, 2~1. 11: and 43 fn~ at pl! 1 1. ~3.9' and 11.5; "Im pH
V-'" V.1juled witb Nt-f. ).';. tir U*80,. aad I, wiLa'
C-Alcd. i'min Ow t1--.rbLfi7) Tlie fmil no of OL- ~vlu w-
~:,Oj O~m --I the emml-~ifiet tnkelle2:
q,-4!t3 71 Ar, -v- ptitzr ki Lhp. pli (they
C91-ltll-l '13. ai~Lf V7, rA13 It ILI -Zi 1.9, 6.6, Rnd 12.0.
. . ,v pr~
trWTI ;Nrfj-!f!"fL p ilk- ielas_ wd their
C:)'Wr~ '; t3 ~ILT'CW, This is the case
of p re) ~ In 'ht in itunv! ~'f jqitft4tof~;' the no.
of UCTI'Q r~Ljicajs of th~! inili"'vT ~s greater In &A. sGin.;
thcr-,'ore. in wid 3nln. not a!! mice-Iles av, as tuelei for-
vjrj -,it , :i gTcater at ~rnaer pi(,
- '- --' " : :1 tz GO 05 ,If) lo~ertd'
';Li.-x-J , 3M.-O dAt'113 ifICIRaSe(l,
aik,,Uts "I KC1
"i-hp. wt. '
vhez tf"
-41 0
J

. A -
A - :1 - - ;?
- . . . :-,- I -r -1 .
Subvil t ta~ I A -r I I n , .-I

'Nt

TURZHENKO. T. S. 9, YMIIENKO. A. 1.
MOM1w%qQw_%Tw&_i1~1
Effect of nonelectrolites (alcohols) on the rate of styrene
polymerization In emulsion and on the dispersion of stTreae
latexes. -Haut. "p.L'vIv.un. 34:A5-25 (WBA 9: 10)
(Polymers and polymerization) (Styrene) (Latex)
M

C
Catogory USSR/Atomic and Noloculer Physics Physics of High- D-9
Molecular Substances.

Abs Jour No 64,56
Ref Zhur - Fizika, No 31 1~57,
Author i _Yur7,hQn1coj 1,91., Knrtynyuk-Lototokiy, YU.Yo.
Title 3 Invoot!6,iion of tho Elasto-Viacous Froporties of Solutions
of Synth6ttc Rubbers.
Orig Pub Nauk zap. L'Vivs'k, un-tu, 19155, 34, 3o_~8
Abstract For the purpose of clarifying the offect of molecular struc-
ture and the chemical comros
ition of a polymer on its de-
.
formation properties in solution, the letter were investi-
gated in solutions of rubbers of various chemical nature
(natural rubbers, on voll *is polyrtyrols with varioun moloc-
ular weights) and synthetic rubbers (poly-isobutylone,
butadiono-styrol, ond.nitryl rubbers). The investigation
was aarriod out with tho Shvudov appPratus. It was shovm
that tho corArosition of tLa rnacromoloculoo affocts sub-
otantially the ~lavto-vi,!couv proportion and the structuri-
zation of the soltitions of polymoro, end also the viscosity
of solutions that have no elastic properties,
Card

11 .1cA
I U C) A,
USSR/Thermodynamics Thermochemistry. Equilibria. B-8
Physical-Chemical Analysis. Fhase,Transitions.
Abs Jour : Referat Zhur - Khimiya, No 6, 1957, 18530
Author : _4,J_Ymnzhenko_, V.D. Yenallyev.
Inst, : Lvov University.
Title : Study of Distribution of Isppropylbenzene Hydroperoxide
between Styrene and Water Phases.
\jdL-
Orig Pub : Nauk. zap. LIvivs1k. un-tu, 1955,.~4,445-50
Abstract : The distribution of isopropylbenzene hydroperoxide (I)
between the styrene and water phases at 200, 350 and 3
was studied. The distribution factor (K) describing the
ratto of molar parts of I in the water phase and in Bty-
~,ecieases with the temperature riz~., frcm 0.0639 at
2(Y'- to 0,0314 at 43o. Addition of small arounts of NaOH
ko-u~jl to 0.025 n.) causes a decrease of K due to sal-
ting out., but at the increase of KaOH concentration to
0.1 n., K rises due to the formation of a I salt soluble
in water. Addition of Na2C03 and KSO4 causes salting
Card 1/1 209 - btLt of I and a decrease of K.
,I j 1~ I fil

.
~4
Ind

Mill'.
i2

aA rtuv-
,E-. Th~,
fi,
its.
.,;p4

Ito

Rj 1,111KO. A. 1. Gusyakovy V. P.
"Dispersion of Synthetic Latexes in connection with the Concentration of
Micelle Emulsifier" (Dispersnostv sinteticheskilch lateksov v sVazi s
kontsentratsiyey mitsell emullgatora) from the book ZLuk of the Third
All-Union Conference on Colloid Chemis ppl+20-428p Iz. A14 SSSR, Moscow, 1956
(Report given at above Conference,
Minsk, 21-1, Dee 53)

USS~/Chemis try of ILLgh Molecular Substances. F
Abe Jour-,, Referat Zhurnal Khimiya, No 6, 19571 19442.
Author
N.S. Tsvetkov, A.I. Yurzhanko.
Inst-
Title Influence of Inorganic Salts on Process of Polymeri-
zation of Styrene in Emulsion.
Orig Pub,. Kolloid, Zh., 1956, 18., No 3, 362-368.
Abstract The influence of No S04 and KC1 (in quantities of up
to 0.1 - 0.02 13-e~X) on the speed of the emulsion
polymerization of styrene in presence of initiators
K2S208, dimethylphenvlcarbinol hydroperoxide (I) and
benzoyl peroxide (II) - and of the emulsifier salt-
less Nekal, as well as their influence on the molecular
weight of the polymere were studied by the dilatomet-
ric and viscosimetric methods. -1be polymerization-
apeed curves in -pre3ence of K2S208 and I depending on
the concentration of salts possess a maximum (at 0.02
0.02, g-equ/1) that is the sharper the higher the con-
Card 1/2

UWII~Chewiatry of High Molecular Substances.
Abs Jour Referat. Zhurnal nimiya, No 6, 1957~ 19442.
-centration of the initiatpr'and Ph of the aqueous
phase are. 9he authors .explain the discovered pheno-
mena by the influence of, 'sults on the colloidal solu-
bility of the monomere. In presence of II, the salts
do not influence the polymerization speed within the
limits of the stud-Led concentrations. The molecular
weight curve of polystyrene depending on the salt con-
tent in the polymerized"mixture also passasthrough
a maximutii corresponding to the Gult co(Icatitration. of
0.01 0.04 ~;_oqu/l.
Card 2/2 _19-
- --------- --
7 IF -
_,,-*"Category. UMB/chemistry of High-X016CUJAr SubsteAces
AbsJour:-Referat Zhur-Shimi7a,50 9, '19571 30899
Author : Kucher R. V., yurzhenko A. I
Iust : not rox in
Title : Fate~Of DeCOMPOSitiOn'Of ISOWOPYI-Benzene Hydrope ide
Aqueous Solutions Of:EmUlsifying Agents
orig pub: .Kolloid-,zh-, -15,56, No 5, 555-561
coqpa jt jotL of jilopropyl-ba=eMe- hydroy*=14011)
Abstract Therml do,
-at 9.8,5o, cor -at order.
for&$ to the.1
Rate of decomposition of I increases in the presence of acids
and bases, and also On adRti= Of emulsifiers (K-steamte
and jaurate, Na-oleate). Addition of ITeke.1 accelemtes decom
position in acid medium, Mud retards,it in:83k&"" on increase
of nekal concentratiOu-in aqueous solutions from 0 to 3% decom-
position velocity constant Of I (K - 1013 MID-4) increases from
U-4 to 31-4 at PH 0-9, ZrOM 67.183 to 0-336 at PH 5.8, and de-
creases from 1.57 to 0-974 at PH 9-9- change in order of re-

Interaction between organic h,7droveroxidef, PrA forrous salts.
Dop. ta pov. Liviv. un. no,'l pt.3:195-197 157. (141RA 11: 2)
(Chemical reaction. Rate of)
(Hydroxides) (Iron salts)

YENAL'YEV, V.D.;,KUCMM, R.Y.; TURZHENKO, A.I.
Effect of interphase distribution of hydroperoxides on the
rate of_rjrr~n reactions in emulsions. DDp. t& pov. Liviv un.
n0.7 P-1 -U 9 (HLU 11:2)
(Hydroxides) (Chemical reaction, Rate of)
(Emulsions)

-11 I~N~11
YURZEICIMO, A.I.; MALEYET, I.I.
Studying the adsorption of hipt polymers on carbon black. Dop.
ta Pov, Llv!7. un. no.71AsU04-206 '57.. (hIMA 11.12)
(Adsorption)
(Macromolocular compounds)
(Carbon black)

art!

A VO
l
,-
e
ce" ;I
'
. - j
, :,
Z
&r,

to

20-4-26/52
AUTHORSs Kucher, R, Ve, Yurzhenko, A. I., Kovbuz, M. A.
TITLE: The Oxidation of Cumene by Molecular Oxygen in Emulsions in---
the Presence of Various Emulsifiers (Okisleniye kumola
molakulyarnym kislorodom v emullsiyakh v prisutstvii
razlichrqkh emullgatorov).
PERIODICAL: Doklady AN SSSRq 1957, Vol- 117, Nr 4t PP- 638-640 (USSR)
ABSTRACT: The present report studies the velocity of the oxidation re-
ferred to in the title in connection with the ratio of the
phases and with the nature of the used emulsifiers. The puri-
fied hydrocarbon was oxidized in glass retorts by bubbling
pure oxygen in a thermostat at 80 Ce Specimens for the ana-
lysis with respect to the content of hydroperoxide were taken
in certain intervals from the reaction mixture. The cumane-
-phase was further analyzed with respect to the total output
of oarbonyl compounds. A diagram illustrates the kinetic
curves of the output of hydroperoxide of cumene at different
ratios of the phases with lacking emulsifier. It results from
these data that an increase of the volume of the acqueous
phase considerably increases the velocity of accumulation of
the hydroperoxide of cumene. These data can also be checked
Card 1/ 3 in other systems,and show among other things the following:

20-4-26/52
The Oxidation of Cumene by Molecular Oxygen in Emulsions in
the Presence of Various Emulsifiers.
ASSOCIATIONs
Gard 2/3
The acqueous phase is the essential kinetic factor in the
oxidation of hydrocarbons in the emulsions, since it acts as
initiation zone of the process and the hydroperoxides are pro-
duced in it. The importance of the acqueous phase for the
amulsionlike oxidation still increases substantially in the
presence of colloidal electrolytes (emulsifiers) containing a
surface-active anion. The emulsifiers accelerate the pro-
duotion of the hydroperoxidee at otherwise equal conditions.
In the amulsionlike oxidation of the hydro-oarbons the
initiation of the reaction and the production of hydroperm
oxide occur mainly in the acqueous phase* The primaz7 initiation
of the processes discussed hare consists in the production of
free hydrocarbon-radicals. Besides the specific influence of
the emulsifier on the decay of hydroperoxide of oumane the
solubility of the hydroperoxide in the aoqueous phase connect-
ad with this process must also be taken into account. There
are 2 figures, 1 table, and 6 references, 3 of which are
Slavio.
State University imeni Iv. Franko, L'vov (Llvovokiy
gosudarstvennyy univereitat imeni Iv. Franko).

The Oxidation of Cumene by Molecular Oxygen in. Emulsions in 20-4-26/52
the Presence of Various Emulsifiers.
~
TVZ
PRESENTEDs May, 21, 1957, by P# A* Rabindero Academicians
PX
OU,
BUBMITTEDs May 3, 1956
AVAILABLE: Library of Oongreas
A
Card 3/3-~

YF~W): A. I.., and KHONMGVMY, P m
"'The racebaniurn of unAlgion polym-rizat1w."
Mort Prounted at the Yourth AU-Ualcn Ccufa%ws m CoUoUWJ Ch=lmtr7,
Thalsi, Georgian MR. 12-16 Noy 1958 (Rn zh=, 20,5, P-677-9, 158, Taub=np A.S)

AWZM#
Now Tra"m of Colield Che"stry (savm putt raermys,
kellolifter MALU)
ICALs To$"" Akattall Moak =31. 1959, Ir ". pr 44-5 1 (Von)
AJffMCTs At present. ogile&& nbentatry playa an oopaolallr Important
'Is" is political O"Nomy " It is a so once
ovater"m watou"No or imadors eactowertur. it to or
-
~
on
91~mstlml Importance "*I as present it is poa6itl* te
must4rrupted. transitions free l7opublo to Irophil
oyalram. This*& it to possible to obtain asohnioally japortant
uired Vro
ertLea
Extb4losews with the re
.
p
q
Us theory of MgMr malowelar sabatanoos End their solutteem
6" demlop*4 Late an Independent breach of colloid ablota".
Thes, TUSIAST of 004am 0011.614 obasistrr is proved by
tags that it privaus" WSA7 NOW lAdopendmat branches OZ *agenda.
rKriber, the author dowerilpas the wourwe of
mk-U-v. -Z-YA- 1-w".t--*-4om*rSbod the synthesis or
structure.
at &I. exasised tb* optical properties at
-SPromelto ar solutlom sad SIL*lr straotaral peaullarillies.
Its
I. A. P-AlAkis "A "llaYmmikorm royerud an questions of
4`9118111M. ot p*ly**"-"d ft&Lr solution*.
1. A. Xit'ml zuta. "A discussed the
r AM ZEN role Ilk atiaklad
raferte, to the coincidental
a" Allatometrioal &xamInation
-C~"JJAI-Nothodo sr~t- transitlam. of gelatin. jolly late. a It ml
miles st - rise I& toviversturs'
and mellabarmse" (L
slarICUSURa of
sho-stale or dispersion.
'U, P. ~Pla-
he
XWWW ant collaborators a 4
of evUre fillers an the proommess or structural f9rus,119a
ar.polMrs.
W11M him awboal. 12 IT. 0. T.
SU
xcaLin d the p;*p*1rTr47Q J cap
r*Nd wall"Oresors
NO %&age IS &O=901191%. with lkb*lr street*%." peoullarlstam
I
am
am the theory of "nexas"t lubrIe"Im.
%a Coremse OIL questleam at disport on Eye pol7mers
0011014
imsew" the mijiltr of a proleft, 1:
Ob"Istry End the orelsol ah"datry or polyware. The veralts
iMI4060 VMS, b*MIAMI Unitas 00014%tatioge
ANK lr4LvUlus4 Antentifte problems. 49opreba"i" conervesse
"s.ra &Iet assful and sweassav7. amitiW the lav*atlgolorm End
*Mrlo&mW Me remats, of ackl*,~mwvmte in wide field& of
0"60". There IN I Movids "farreomew.
Geed 6/6
-Or 4P*1k1SAi;-.. ii- "w""24al, :arts
OPOV*zm Of **Ili stilts. wapselally. we"
'16's-rame-Assive surromadl.".. NEI
Tus APP*&MAQO Of n4morplivo
as
as
as
astir *at an of Iw" sma tin at mai toap.,.Cares
Vj-4h.y End sol2aborstors osenj..4 the 1DIRG
t rh
i'_
Of x%* lacteal properties or pru%,Rc color* on their
IN
14
W*hM~vl:r AN I tprinting proace..
4- reported an *be rMulAtIon or arys 11444
SfihL`;:-
*a as ON .6
rusts"m In U. pred.atta. or be
butter.

YURZRM,TKO, A. I. and IRUTEV, 1. 1.
(Lvov State Franka. University, Lvov, USSR)
-"Adr.orption of Certain Hi&h Polymers by Carbon Black in Dilute Solutions,"
paper submitted at Soviet High-Polymere, Int-1. Conference, Nottingham,
Uk.,m '21-24 Jixly 1,9501,
E-3,109,661

777-
(2), 5 (4)
AdTHOR- Ivanchlov, S. S., YurzhenkAT-1-.7r~. SOV/153-57e-4-3/22
TI TLE Thurnr-ll
Preaunce of Salta of tho Aoidn oV tho AIAPhidJo Sorino
(Termicheskoye razlozheniye persullfata ~aliya v pri-
sutstvii soley kislot zhirnogo ryada)
PERIODICAL: Izveutiya vyashikh uchebnykh zavedeniy. Khimiya i khimiches-
kaya tekhnologiya, 1958, Nr 4, PP 13 - 10 (USSR)
ABSTRACT: Potassium p-e-rsulfate f
poly?.11crization processes in emulsions, which is
widely used in industry products of a free-radic-al type are
formed in its thernal decomposition. In this
.,connection more and more attention is paid to the
kinotico and procono of ~th--;.t decomposition, in
dependence on tho conditiona. A otirvoy of the publication.-I
so far available is presented (Refs 1-3). The influence
exercised by salt additions on the decompooition
Y rate of potas2ium persulfate is interesting, because
Card 1/4 in pructical use the decompocition takeo place in the

Thermal Decomposition of Po-LLnvium Poroulfaluo 1i) tbe 50111153-58-4-3122
Presence of Salts of the Acids of the Aliphatic Series
presence of -various salts. Accurate data on the in-
fluence of the salts mentioned in the title are not
available. In the present paper the influence is in-
vesti-r-ated that is exercised by sodium salts of
.low fatty acids (from formiate to laurate) upon the
poly,merization kinetics in the emulsion, if the poly-
merization was initiated by potassium persulfate. Further-
more, the influence is investi,gated that is exerted
by the above salto upon its decomposition rate (this
propertion of' the oriuInt-riern. Piguro I prooolito ux-
perimental results of tha decomposition of potassium
pe rsulfate in aqueous solutions a) without additions
and b) in the presence of salts of fatty acids of
various concentrations. A~ may be seen (Curves 1-3),
the decomposition rate of the persulfate increases with
increasing sodium-formiate concentration -,,fithin the whole
range of the concentrations investig6ted. When the
next salt - sodium acetate - is introduced, the de-
Card 2/4 composition rate of the persulfate is increased only to
4

-W
Thermal Decomposition of Potassium Persulfate in the
Presence of Sults of the Acido, of tho Aliphatic Serien
SO-1/1-553-58-4-31/22
the concentration of the acetate of 0,0211. Further
additions of acetate slorg down the decomposition the
more, the higher the acetate concentr_z~tion is. That
applies for all ot1her salts up to capronate incl.
If sodium caprylate and salts of higher acids are
introduced, the persulfate decomposition in all con-
centrations is accelerated, i. the more, the higher
the concentrZItion of the additiono introduced has been.
The authors have come to the concluaion that the colts
investigated can exercise different effects in con-
centrations above OqO2N. These effects depend on the len.-th
of the hydrocarbon radical of the anion: the lower salts
(up to capronate) slow dovin -the decomposition when large
additions are introduced', whereas the decomposition is
accelerated by higher ones; sodium formiate shows an
anomalous behavior. If the anion radical is lengthened,
the persulfate decompocition is accelerated in any case
by introducing amall quantities of salt. The above
M,
Card 3/4 mentioned influence is explained by two effects: 1) By a

,4 7
Thermal DecomDosition Of Potassium Persulfate in the
/22
Presence of Salto of the Acids of the Aliphatic Serlea
Purely chorilical, vthloh is connected with the interaction
between the salt and the Versulfate, and leads to
accelerated decomposition; 2) By the salt-effect which is
analogous to that of inorganic salts and slows down the
decomposition (in increased concentrations). The latter
effect (2nd) is decreased,if the hydrocarbon radical
-of the salt,anion is lengthened' and is no longer
visible above caprylate. The behavior of formiate requires
further Investigationos There are 4 figures, 6 tables,
and 4 reference--, 2 of which are Soviet.
ASSOCIATION: Llvovskiy gosudarstvennyy universitet (Lt,vov State University)
Kafedra fizicheskoy i kolloidnoy khimii (Chair of Physical
and Colloidal Chemistry)
.SUBIJITTED: September 16,*,1957
Card 4/ 4

AUTHORS:
TITLEi
Yurzhenkoj Aol., Storozh, G.F. SOV-69-20-5-5/23
The Effect of Ethylene Glycol on the Colloid Properties of
-Aqueous Sodium Oleate Solutions (Vliyaniye o-tilenglikolya
na kolloidnyye svoystva vodnykh rastvorov oieata natrlya)
PERIODICAL: Kolloidnyy zhurnal, 1950, Vol XX, Nr 51 PP '550-555 (USSR)
ABSTRACT: The addition of alcohols, e.g. methyl~ ethyl, n-butyl, and
isoamyl alcohol, to aqueous sodium oleate solutions i increa-
ses the turbidity and viscosity of these solutions~ The ad
dition of ethylene glycol to these solutions is investigated
in the article, Figure I shows that the vii3cosity of soap
solutions increases with the oontent of eth;fleie glycol. The
curves for the changes of the relativevisco3ity of 0.1 M
solutions of sodium oleate, depending on tho concentration
of ethanol and ethyleneglycol, are shown in'Figure 2"a,
The measurements of the specific, electroconifuctivity are pro-
.-sented in Figure 3. The addition of ethyleieglycol reduces___
_the-, electroconductivi-+.yi---biit.-ati-max:th6Ll visoosi y the. elec-
7 _auctivity_-:iea6h&es- a~- stant v,lue 11he' turbidity
trdc,on p. on
. Ur,veIS.- tha.~solu Th turbidi
tions a e-giv.4n V~Vl gpre -5 e
of
lZra ter-a ditioll'of alcohols -attains a
d
maximum, and'-decreases again. This,fact is'.in accordance
'Card 1/2 with the theory that the alcohol causes a dehydration of

SOV-69-20-5-5/23
The Effect of Ethylene Glycol on the Colloid Properties off, Aqueou5 Sod-luz
Oleate Solutions'
the solutions. An increase of the NaO11 content decreases
the turbidity and at a concentration of alkali of M005
mole/l hydrolysis of the oleate is completely suppressed
.(Figure 6).- The dependence of the turbidity on the sodi-
um, oleate concentration in the prenenco of various quanti-
tioa of ethanol and glyool laahowti.in Vigari 7, It La evi-
dent that alcohols-do'crease the turbidity of soap solutions
without suppressing hydrolysie. Ethanol and glycol, like
alkalis, lower the critical concentration )f sodium oleate
micelle formation. There are 9 graphs and 9 references,
2 of which are Soviet, 3 German, 2 English., and 2 Swedish,
ASSOCIATION: Llvovskiy universitet im, 1-. Frankc (Livoir University im.
Iv. Franko).
SUBMITTED: December 24, 1957
1. Sodium solutions--Colloids 2- Sodium solutions--Properties
3.-Ethylene glycols-41hemical ren!".ions
Card 2/2

Mr, IOMWIrl"m MIN
YURZHEKKO, A.I. ,-[1Ur%henko,' 0.1.];, YNWIIYFV. V.D. (11nalliev, V.D.]
Investigation of the reactions of organic bydroperoxides with
salts of ferrous oxide. Mauk.zapoLlviv,un 4-6:7-12 '158.
(KIRA 12:7)
Okydroperoxides) (~Zon salts)

MIMI
R.T.; TURMENK01, A xovwz. 14.0.
J#
Heana of accelerat "action of isoprop7lbenzens
In tho liquid phan 46:17-20 158.
12:7)
(Cumene
'11-10"MM
gm
.9, ff"m i
0

,
wm,~
1AMINEW-0 -11M

YEIaLtYEV, V.D. (INnalliev. YURZHEMKO. A.I. [Urrzhenko, 0.1.]
C~
Effect of the relationship of phase to the kinetics of redox
polymorization In amulatona. Nhuk.s&p.L'viv.uu. 46t2l-25 '58,
(High 12:7)
(Polymerization)

YSNALITET-0- -T.D. 7-.D.-J- -YURZHERKO. A.-L- [-Wrthenko-
fIgnalliev
,
Effect of the concentration of the Initiating System on the kinetics
of redox polymerization in emulsions. Kauk.zap.L ,vIv.un 46:
26-33 '58. (HIU 12:7)
(Polymerization)

GUSTAMV, V.P. [Millialcovt T.P.I.- YUMINNIKO. A.I. ClUrshanlco. 0.1.1
Iffeet of saturated aliphatic alcohols on the'scattering,'Light-
by protein solutions and on their viscosity, Yank zap*L'vjv*uao
Zi 1P17)
(Aldj6ld) (Videddity) (Prot altig.-Optied wworbidi)

YURMETM. AL--[-IUrzhouko, 0.1.1; MALUN, I.I. (Malietev. 1.I.]
~Adsorptton of polystyrene. methyl nethacrylato polymers, and
nothyl acr7late polymers on carbon black. Yauk.zap,.LIvIv.un. 46:
41-47 " (MM 12:7)
(P.1yers) (Adsorption) (Carbon black)

TURZHENKDO"A. I. ClUrzbenko, OJJ; STORDZH. G.F. [Storozb. H.F.]
-Rffect of lower aliphatic alcthols on the colloidal properties of
sodium oleate solutions. Hauk.zap.L'vIv.un. 46:48-52 '58.
(MIRA 12.7)
(Colloids) (Alcobols)

--WAL IYEV. Ignal I jev V Dj; YUWR
MCM9 R.V..,,Y 0 ~NKO, A. I.,
ClUrzhonkos 0-iolf Kovbuz, 14-0.
Effect of the molecular weight.of tortlary bydrocarbons on
their oxidizability in the liquid phaso an& in 6mUlSiOnu- Vaulco
Salp.1i'viv.un. 46:13-16 1113o (MIR& 12:7)
(Hydrocarbons) Oxidation)

Y=1MIKO A.I. [1Ursboukop__O.I-1:-1VAMHCHGV-$
-3 an! mmulaimi In the presene. a of
of styrene I
ISadium Salta of lower. gliphatic acids. I1kuk.%-%'P*L1viv-.un., 46.
l6l-i67 '58- (KIRA 12.7)
(styrene) (Pol"erization)
(30diun malts)

AUT111 irts: Yur zhenko, 11. 1., Ivanchov, S. S. S0111 2o-120-2-35/63
-------------
TITLE: Influence of the Salts of the Lower Fatty Acid Series Upon
-tion (Vliyanniye soley ryada nizobil:h zh-;rviyl:h
Emulsion Polymeriza
kislot na emullnionnuyu polimerizatsiyu)
PERIODICAL: Doklady Akadenii navk SSSR, 195Si Vol. 12o, 1Jr 2,
PP, 349 - 352 (USSR)
A13STRACT: Firntf ral'orence iz- m ad eto a ni=bar of portinent papcrr
published previou -nly. The infliience of the oodiimt Oftlts of
the dories of lower fatty acids ran,ring frovi sodium acetate
to sodium la-urate upon the polymerization of otyrerie in emulsion
is invest ir;ated. The initial styrene (vahich is by 99,8;fo a
monomer) was treated with a 201,'1o solution of 1[a0H. It vr~,,c; stored
on metallic sodium for some time and then sublimed in vaoiium.
The data documentinIg the infli-tence in question upon tile poly-
merization velocity are given in a dia.-rati. The introdiietion
of amounts of salt (up to a concentration of 0,02 1.1)
increases the reaction velocity. At concentrationa above 0,02 M
Card 1/3 the introduction of the electrolyto IJEL., v.,iryin,-, off'ooL

Influence of the Salts of the L~,,,.,er Fatty Acid Series SOV/2o-12o-2-35,/63
Upon Emulsion Polymerization
according to the nature of the anion. The lower homolo-a
inellidille, "todium c:.kprotu,0'.o nhor, an increaio of Volymorization
Veijot)ity wboll nalto aro 100od to tho j)OIYrlC'rJ.-.'A loll ljyjjtvm~
When the concentration 0,0 M is okdeaded pol~-~mwri,"Ati oil in
retarded. Further details -are given. The salts of the fatty
acids belong to two rg-roups according totairinfluEnce upon the
polymerization process: i) Salts of the lower fatty acids (frorm.
the acetate to the capronate). They give the hijhest poly-
meri?ation velocity, according to the concentration. 2) The
salts of the hiGher fatty acids (above capronz-te). The reaction
velocity increase'S continuously viihthe coneentration of the
oalt in the reaction mixture. The influence of these salts
upon the molecular vicidIlt of the resultinig polymersis similar.
The influence of sich additions of nalto unon the inititAion
velocity is diocuased. In V:c homolog rories of the ,,alts up
to capron-to the of feet of oaltin,-, out upon the evoili.-tAor
doninatee. Iferice, the polyrierizzation velocity ...;.' the initui,.~.tion
-velocity are -rodup~11y roducod. With the naltn of capTylic
Card 2/3 acid and of h i,ghor acids the stabilizing effoot predomin-too.

Pl--ttv Ac"d 3
Irflilor;Q0 of tho !;~,ltr, Of th(; Lo,.7.
Upon Emillf3ion
There are 4 fi.-ures and 6 references, 3 of which ltre Soviet.
ASSOCIATIGINI: Llvovskiy Cosudarstvennyy universitett im.Ivana Franko (Llvov
State University imeni Ivan Franko)
FRESEIPTED: January 13Y 1958, by P.A.Robinder, Member, Academy of Sciences,
USSR
SUBMITTED: January 13, 1958
1. Styrenes-Folymerization 20 1,&tty aelds.-Chemical properties

5W_
AUTHORS;
TITLE:
Yurzhenko, A. Tvanova, N. ya., SOV/20-123-2-32/50
Yen-A-17-y-ev, V. D.
The Participation of the Emulsifier in the Oxidation Reduction
Initiation of Emulsion Polymerization (Uchastiye emullgatora v
okialitellno-voestanovitellnom initsiirovanii emullsionnoy
polimerizatsii)
PERIODICALt Do.k1ady Akademil nauk 383% 1950f Vol 173l Nr 2, pp 324-326
(USSR)
A.BSTRACT; One of the moat imDortant factors influencing the kinetics of
polymerization in emulsions is the nature of the emulsifying
agent. The nature of the emulsifier used influences not only
the velocity of the polymerization process but also the
properties of the polymer formed. When investigating emulsion
polymerization in the presence of various emulsifiers, the
authors noticed several particularities in the development of
the polymerization process in connection with the application
of cetyl pyridine bromide. In this case the part of the emul-
sifier is played not only by a purely colloidochemical factor.
Investigation was carried out by the dilatometric method in a
Card 1/4 dilatometer which prevents contact between the polymerization

The Participation of the Dmulsi.fier in the Oxidation SOV/20-123-2-32/50
ftoduotion TnttiAtion of Fmitlaton Polymerization
system and air. In the case of all experimenta, the ratio
between the hydrocarbon- and the aqueous-phase was I : 9.
The hydroperoxide of isopropyl benzene served as initiator,
and otyrone wan noed ao monomer. Polymeri'zation kinetics was
invoatigatod tit varioun tompovaturoo. Tn tho ootirni of one of
the test series sodium.carbonate was introduced into tho
aqueous phase. The results obtained by the experiments are
shown in a diagram. Conditions otherwise being equal, Doly-
merization develope much more ra?idly than if other classes of
emulsifiers are used. Cetyl pyridine-bromide warrants auf-
ficiently rapid polymerization also at low temperatures
-(-4--6iid-i-s~)-P--whi-ch--is-.not--the-oase with other emulsifiers. If
sodium carbonate is present in-the aqueous pha-s-e-,paly~
merization velocity passes through a maximum at increased
temperatures. In the course of experiments carried out without
sodium carbonate, polymerization increases with rising tem-
perature, in which case linear dependence is conserved up to
a rather high degree of polymerization. An addition of sodium
carbonate and an increase of temperature acts in the same
Card 2/4 direction (increase of polymerization velocity). The velocity

The Participation of the anulaifier in the Oxidation SOV120-123-2-32/50
Reduction Initiation of Rmulsion Polymerization
of the polymerization process is due to the velocity of
initiation. The decay of isopropyl benzene hydroperoxide in
an aqueous solution is considerably accelerated by the intro-
duction of cetyl pyridine bromide also if Na is lacking._
2C03
is still more accelerated if cetyl pyridine bromide
and sodium carbonate are present at the same time. Data con-
cerning the kinetics of this decay at various conditions are
given by a diagram, An increase of temperature increases the
initial velocity of polymerization and reduces the final yield
of the polymer. Also an addition of sodium carbonate produces
the same effect. A comparison between these and other data
makes it possible to draw the following conclusion: The
surface-active emulsifier may play a double r'olle in emulsion
polymerization; Firstly, it may act as an ordinary emuloifier
stabilizing the original emulsion of the monomer, and,
secondly, the emulsifier may have the functions of a poly-
merization activator by causing an induced decay of the
hydroperoxide.~There are 4 figures and 7 references, 4 of
which are Soviet.
Card 3/4

The. Participation of theEmplalfier in tbo Oxfdation ~~Q'1/20-123-2~11P/51,9
Raduo'llon Initiation of Emulelon Polymerization
ASSOCIATIONt Llvovskiy gosudarstvennyy universitet im. Ivana Franko
-(Llvov State University imeni, Ivan Pranko)
PRESKITED: July 3t 19569 by P. A, Rebinder, Academician
SUBMITTED: May 16, 1958
Card 4/4

~ - . .- I. . .- It v- -- _- I- .. .
- - '18ome Peculiarities in the Course of Chain Reactions In 11~drocarbon Emulsions Sta-
- - bilized-by Surfface-act_ive,~ 2=1sil"I'erS. ff-I- - -
report presented at the Section on Co" oid Chemistry, VIII Mendeleyev Conference of
General and Applied Chemistry, Moscow, 16-2'.", March 1959-
(Koll. Zhur. v. 21, No. 4, PP- 509-511)

1
A
a
ll Aj-
A I
z all
3j
I
Ira
Eli
UA;
I L-9 A
ilia
lit
.;Wag I-".
M35 lot u
ju ~ at
3
-3j -to -14
i-i-i 41 ?-P -1, 1,
!I ~21 11 ;
Al
ivs c I..,! av'sell
"
W.
.5 Alffis 2a
R
rV

5(2) SOY/21-59-1-16/26
J., and Yurzhenko, A.!.
AUTHORS: Kucherg R.V.9 Storozhj G.P
TITLE- The Viscosity of Water Solutions of Sodium Oleate in
the Presence of Some Alcohols. (Vyazkostg vocLnykh
rastvorov oleata natriya v prisutstvii nekotorykh
spirtov).
PERIODICAL: Dopovidi Akademii nauk Ukrains1koi RSR, 19599 Nr 19
pp 60-63 (USSR)
ABSTRACT: The water solutions of 6oaps are usually character-
ized by means of the so-called first and second
critical concentrations of the formation of micelles.,
It was proved in the described experiment, that apart
from the.critical micelles concentrations CMC-l and
ChIC-2, there exists one intermediate concentration
which can be quite accurately determined from the mini-
mum of the concentration curves of a given specific
viscosity. Small quantities of--alcohols-(ethyl.- -
Card 1/2

SOTI/21-59-1-16/26
The Viscosity of Water Solutions of Sodium Oleate in The Presence
of Some Alcohols.
n-butyl, isoamyl, ethylen-glycol and Glycerine) in
solution lowered the middle critical concentration9
and larger quantities raised it. Experiments have coli-
firmed the theoretical data contained in the referred
literature "and, therefore, the authors recommend
it for guidance. There are 3 graphs and () references.,
2 of which are Sovietq 2 German, 1 Scandinavian, 2
Japancsa,, and 2 American.
ASSOCIATION: L9vovskiy gosudarstvennyy universitet im Iv.Franko
(The L9vov State University Imeni Ivan Franko)
PRESM.TTED: JulY-199 1958.3 by- A.V. Dumanskiy, Member of the AS UkrSSR
Card 2/2

5(4) SOV/69-21-3-12/25
AUTHORS: Kucher, R.V., Yurzhenko,
Kovbuz, M.A.
TITLE: Some Emulsifiers as Kinetic Factors of Cumene Oxidation
in Emulsions
PERIODICAL: Kolloidnyy zhurnal, 1959, Vol XXI 1. Nr 31 pp 309-3.14
(USSR)
ABSTRACT:
Card 1/2
The authors report on the effect of a number of emul-
sifiers (potagsium palmi -tate, Nekal, Leucanol and
cetyl pyridine bromide) on tfie kinetics of oxidation
of.cumene (isopropylbenzene)(IPB) and on the yield of
hydroperoxides (HPC). The maximum rate of oxydation of
IPB in emulsion and the maximum yiold (70-800/o),of HPC
were obtained with a 0.5-1% potassium palmitate concen-
tration. Nekal and Leucanol also speed up the acoumu-
lation of HPC (-M/S), but this process is delayed by
a certain period of induction. The effect of Nekal,
IJAQ that of 001(jr Volloida). oloatrolytoo, Ifj c-onnoctod
to a conoidorable extont with the change of the rate

SO Mar -2.1 -3-11212"r,
some Emulsifiers as Kinetic Factors of Cumeno Oxidation In
EmulGions
of decomposition of HPC in the presence of these sub-
stances. The effect-of-the-emulsifiers on-the rate
of oxidation of IPB depends in the main on their col-
loidal properties (micelle formation, colloid solubili-
ty) The cation active emulsifier cetyl pyridine bro-
mide, if introduced into the initial oxidation mixture,
noticeably delays the process of HPC accumulation.
The introduction of 0.1% cetyl pyridine bromide 30
hours after the initiation of the process stimulates
the reaction. In this case, the yield of HPC reaches
nearly 80116. -The authors mention the Soviet scientists
K.I. Ivanov and N.M. Emanuel'. There are 5 Fwphs,
t,,blos mid 11 reforence:31 8 of which are Soviet alid 3
English.
ASSOCIATION: Llvovskiy universitet .(11vov University)
SUBMITTED.- 14 September, 1957
Card 2/2

8/084, 61/000/020/076/089
Bi 06YB1 47
AUTHORS#,, Kuoherp Ho V~F Kovbuzj M. A.,jur
TITLE: Decomposition of isopropyl benzene hydroperoxide during
hydrocarbon oxidation in a homogeneous liquid phase or in an
emulsion
FERIODICALt Referativnyy zhurnal. Kh 'imiyal no. 20o 1961t 321p abstract
2OL46 (Bbs nauohn, rabot, In-t Piz,,-organ. khimii All B89Rp
no. St 1960, 22-31)
TEXT: The conversion degree of isopropyl benzene (1) into hydroperoxide
(HP) at different oxidation degrees of this hydrocarbon was investigated.
HP was found to be the only oxidation product in the initial stage of
reaction* Wh6n the oxidation takes place in an emulsion, the reaotion is
more intensal and higher concentrations of HP are reached. A study of HP
decomposition during the oxidation of I in a homogeneous liquid phase or
in an emulsion indicated that rate and meahanism of HP decomposition vary
with the degree of oxidation. When the oxidation takes place in an
emulsion# the HP decomposition in the oleophase has a similar course as
Card 1/2

8/064,141/000/020/076/089
Noomposition of isopropyl BI o6/B'1'47
during the oxidation in a homogeneous liquid phase, and the rate constant
of HP decomposition drops with progressing reaction. In the aqueous
phasel the decomposition of HP is monomoleoular throughout the oxidation
of oumone in an emulsion# anil tho dooompooition ooniitant rise@ with
increasing degree of oxidation. if the oxidation in a homogeneous liquid
phase is stimulated with cobalt stearateo the denomposition rate of HP
rises, and by-products of the reactions are formed in a large quantity.
After the precipitation of the catalyst, monomoleaular decomposition sets
in. The results of the investigation can be explained well by a radical
chain mechanism of H? decomposition. [Abstracterts note: Complete
translation.]
Card 2/2

-YURZEOK=O A _I -_IVANCHOIV2' O.SO
-S.S.; ZARECHNYUK
Comm1parative initiating activity of peroxides of Rhenylearb.-mi-11-c
dtyremer4-joor -nauchirab-.-
fiz.-org. khim. AN-BSSR no. 8,:63.,69:160,, (MIRA 14:3).
1. L'vovskiY)gosudarstvennyy iiniversitet im' I.-Franko.
~Styrene (Peroxides) (P;lymerization)

$1081J621000101210611063
B156/B101
AUTHORS: Yurzhenko# As let Ivanchov, S.'Se, Zarechnyuk, 0. Be
TITLE: Comparative initiating activity of diacyl peroxides of the
paraffin series during polymerization of styrene
PE RIODICAL: Referativnyy zhurnal. Xhimiya, no. 12, 1962, 661,.abstract
12R42 (3b. nauchn. rabot. In-t fiz.-organ. khimii AN BSSR,
no. 8, 1960, 70-75)
TEaT"- A study 'was made of the dependence of the initiating activity (IA)!
of symmetric diacyl peroxides of the-fatty series: peroxides of dienanthyl
(I), dicaprilyl (11), dipelargonyl (III)p dio,aprinyl'(IV), dilauryl (V),
dipalmityl (VI) and distearyl (VII) on the length of the hydrocarbon
radical in th4 molecule. It is established that all the peroxides studied
'have identical thermal stability, but.different,.IAg which is greater than,
in the case that the polymerization'i6i,initia'ted with benzoyl peroxide.
The dependence of IA, which may be evaluated fkom the.rate of polymeriza-,
tion of styrene, on the length of the organic radical chain of the
peroxides studied is represented as a curve.with a minimum, With
Card 1/2

-dx.W-~* wfa'-
W'R arm"
SlOalj621000101210611063.
comparative initiating activity of B158/B101
reduction in the length of the organic-radical in 'he"p
etoxide molecule
in series V to Ip an increase -in the polymerization rate is observed;
then increase is observed with lengthening of the hydrocarbon radical in
the series V to VII The intrinsic viaooloity of tho polymore did not
depend on the length of the hjdrooarbo'n radioal of the peroxide and Was.
determined only by th6 concentration-of the latter. [Abetraoterfs note:
Complete translation.]
Card

L
IKUCIMt R.V.; KAZI14III-0 S.D.j. XURZHMG, A.I.
Sd-"e kinetic 4haractqj~js.tlcs,-6~ tho ezason 03X&,,On of
dorcarbons. SbDr. nauche rab. Inst. fiz.,-org. kb" 0 BSSP. _
V no.8tl32-137 160, (14M 14:3)
I' Llvovski
7 90sudarstv4imyy'unlv6rsitet Im. I, Rranko.
(Hydrocarbone) (Oxidation),

66701
67,7~3 Ot/,4) S/069/60/022/01/007/025
D034/1)003
AUTHORS- Ivanova,, N.Ya. and Yurzhenko, A.I.
TITLE: The Emulsion Polymerization of Styrene in the Presence
of Emulsifiers of Varying Molecular Weights
PERIODICAL: Kolloidnyy zhurnal, 1960, Vol XXII, Nr 1, pp 37-41 (USSR)
ABSTRACT-. This is a study of the effect of the molecular weight
of emulsifiers (sodium salts of fatty acid fractions)
on the rate.of the emulsion polvmerizatiorilof styrene
and on the molecular weight-6r-the- p mer. The poly-
in dilatometers
merization of styrene was carried out
0
fRef 3,7 in a water thermostat at 60 C. For all ex-
periments the equation phase of the m9nomer: water
1= 1 - 9 was maintained. In order to keep-constant the
pH of the system, in all cases 0.1 g-equ/'l Na 2 CO3
was introduced into the aqueous phase. The results of
the study of the colloidal-chemical properties of the
Card 1/4

68701
S/069/60/022/01/007/025
D034/DO03
The-.Emulsion Polymerization of Styrene in the Presence of 1-i"mulsifiers
of Varying Molecular Weights,
most efficient emulsifiers will be given in a special
paper in this journal. As polymerization initiator the
authors used isoproDyl benzene hydrogen peroxide with
a content of ?Wo' active oxygen. Its concentration was
equal to 0,01 14 with regard to the hydrocarbon phase.
The rate of polymerization (Vn) in mole/1-hour was
calculated according to the equation
r 6 S//-'\ 1.000 d,,(k
Vn 100 TA
relative colume of the hydrocarbon phase;,?'- re-
lative volume of the aqueous phase; djA - specific weight
of the monomer at polymerization temperature; M 0 - mole-
Oular weight of styrene; S - depth ofp(iymerization
Card 2/4

68701
S/069/60/022/01/007/025
D034/DO03
The Emulsion Polymerization of Styrene in the Presence of Emulsifiers
of Varying,Molecular Weights
(quantIty of polyffierizlo d monomer in percent);'C- 'time
in hours; tangent of the angle of Inclination
of the kinetic curves for each emulsifier of the adopt-
ed homologous series). The investigation has shown that
the rate of emulsion polymerization of styrene in the
presence of the mentioned emulsifiers (molecular weight
166.2-336.0) increases linearly with an increase of the
molecular weight of the emulsifier from 1.66.2 t,o 296.8.
On further increase of the molecular weight of the
emulsifier, the polymerization processq after having
passed a maximum,slows down, For the given homologous
series of emulsifiers the maximum corresponds to the
mean length of the hydrocarboa portion. of tho uoap
C17 - C19' The retardation of the polymerization process
is associated with change in the colloidal properties
Card 3/4

68701
S/069/60/022/01/007/025
D034/DOO3
~The Emulsion Polymerization of Styrene in the Presence of Emulsifiers-
of-Varying Molecular Weights-
~of the emulsifier, i~e.j the size and.shape of its
.micelles, which are the main sites of polymerization
in emulsions.-The formation of large asymmetric mi-
cellular~aggregates hinders diffusion of the monomer
in the micelle, leading to decrease in the reaction
rate. Up to a given limit the intrinsic viscosity of
polymer solutions increases with the molecular weight
of the emulsifier. The authors express their grati-
tude to F.V. Nevolin, who put at their disposal the
fal,ty acid fractfoiis. There are 3 graphs, 1 table and
6 references, 4 of which are Soviet and 2 English.
ASSOCIATION: Ltvovskiy.,universitet im. Ivana Franko (L'voy Uni-
versity imeni Ivan Franko)
SUBM M ED: December 13, 1958
Ca.rd,4/4