SCIENTIFIC ABSTRACT KARGALOV, B. - KARIMOVA, M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002201220004-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: July 20, 2001
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

rx-M
USSR LJDC: 8-7t
BRIW[Di, V. , KARGALOV BKUZ tM1 K.
"Interpreting System for the 4Ural-141 Computer Oriented for the Diur-14-1
Controller
V sb. Elektronno-yych-isl. tekhn. i Erogram-ir. (Electronic Ccrnputer Tech-
nologyand Computer Pro.-a=in, -collection of works), i7p. h, Moscow,
"Statistika", 1971, pp 5-18 (from M-Kibiernetika, No 1, Jan 72, Abstract
No lV1011)
Translation: The paper describes the purpose and structure of the IS
DIUR-14-1 Tnterureting system, requirements for standard programs, and
the organization of the standard program board. It is noted that the
DIUR-'14-1 controller-monitor has a modular structure; the operating order
of the modules in the IS DIUR-14-1 interpreting system is indicated, and
a list of possible troubles in operation of the interpreting syster. is
given. Authors' abstract..
42

USSR UDC 539.4
S'~ERDLOV, A. L and 1~&&"4'SKIY V A
"Reliability Estimates of Composite Materials Structures From
Static Test Results"
Moscow, Prochnost' i Ustoychivost' Tonkostennykh Aviatsionnykh
Konstruktsiy, 1971, pp 216-220
Abstract: The subject structures consist of alternating layers of
rnetal and glass reinforced plastic bonded together.
It is desired to verify the design load carrying capacity of the
structures by static tests. The aging bf the plastics due to tempera-
ture, humidity and radiation is taken into, account by testing to
destruction 10-15 specimens aged for different periods of time. The
results of these tests are correlated by the theory of probabilities.
1/2

It is recommended to test the structure statically under the
load equal to the design load increased in the ratio of the original
-specimen strength to the aged specimen. strength.-

Pharmscolo,$y andlToxicology
USSR ~urc 6rj-o8q.3Pl.65
VA?XMKIY, V. L., MWAPOLOV, L. N., Chair of Anesthesiology and Reanimation.,
Order of Lenin 1uaUtuteA0*fA*Trdhd1ftd Trainlzg. of Pbvoicians imeni S. M. Urov,
Leningrad
"Experience in the Application of the New Soviet Myorelaxent Diaxonium in Aneathesi-
ological Practice"
Leningrad, Vestnik Khirurgii imeni I. I. Grekova.. vol lo4, No 6, Jun 70, r-rp 74-77
Abstract: Dioxoaium is the diiodovethylate of 1,2-bis-(W-piperldinomthyl-1,3
diaxolanil-2l)-ethane. In experiments it exhibited a very bigh actirity in block-
ir~-, N-cholinoreactive systems of skeletal muscles. As distinguislied from d-
tubocurarine, dioxonium, did not produce histamine-like effects. Me drug vus
applied in doses of 0.03-0.2 ing/kg in combination with aneathesia in rurgerj of
the heart, lungs, esophagual storach, etc. perfoirwd on 141 patients. It produced
a te--porary depolarizing neuromuscular block which after 5.6 min changed into a pro-
longed non-depolarizing effect. Drbravenous Injection of novoca-in prolonged the
depolarizing phase. Proserine counteracted the residual non-depolarizing -block.
The length of action of dioxonium Increased from 50-60 zoin in a dose of 0.05-0.06
mg/kg tD 160-180 min in a dose of 0.15-0.20 r4g/kg. The blood circulation vas not
affectei. Blood tests showed that dioxonium lowered the activity of specific
cljoliheste rase, and did not affect that of, norispeeific cb6o.nesterase-

UDC 632.95
APOL V 1%
F. V.
KU1 BUROVA N.
KALENICO, S. S. * I I ~
"&.,action of Chlorohydrin Ethers With Aidnes, Phenols, Thiophenols, and
Carboxylic Acids"
V eb. Khim. sredstva zashchitv rast.(Chemical Means of Plant Protection -- col-
lection of works), vyp. 1, Moscow, 1970, pp 256-262 (f rom. RF[i-Khimiya, 'No 12,
Jun 72, Abstract No 1Z-.474)
Translation: In searching for pesticides, ordinary methods were used to synthe-
size derivatives of chlorohydrin with the. general fomulas: 1RXC1-.,C1i(OQC-E,- 2 C1
(I), RXC11 CUOMO[ NR'R" (H), RXC11 CH(OOCRIII)CH C1 (111) 11,XCji2CnClci1 Cl (IV)
2 2 2 2 2
(everywhere R is Ph, substituted Ph, RI and R" = 11, C 1-C 8- alkyl, Ph, substituted
Ph; R111 = C _C -alkyl.,halogen; AN - 0, S),. A mixture of 128.5 grams of P-chloro-
1 3
phemol, 92.5 graias of freshly redistilled epic'Llilorohyrin and .' at of 401' Mueous
solution of NaOH is heated in a boiling water bath for 15 hours, generating
150.32 grams of I (R = 4-CIC 6R 41 X = 0) (Ia), C9RIO C12021 yield 40Z, boiling
point 131-2*/2, n 20 D 1.55131 d2o 1.3202.L S) is obtained analogously,
4
-1/5

USISR
KUMMIKO, S. S. , et al. , KItim. aredstva zashchitv rast, vVP. 1, Moscow, 19700
pp 256-262
but with heating of the reaction mixture for 6 hours at 115-120*. The I are
obtained (R. X, the molecular formula, the yield in %,'the boiling point in
C,
*C/mm or the melting point in 'C, n 20 Do d20 are given): 2-CIC 11 0, C Ii Cl 0
4 6 41 9 10 2 29
50, 133/2, 1.5519, 1.3260; 3-CiC H 0, C 11 Cl 0 68.4, 154-6/2, 1.5532,
6 4% .9 10 2 21
1._';210; 2,4-C!2C6H30 Cos C 9H9 CI3029 65, .184-5/4, 1.5650, 1.4303; 2,4,5-Cl 2
C6"2 -0':C 9H8 C.14029 30, 58-1, L-, Ph,' S (Ib) , C9if 11 ClOS, 79, 142/2, 1.5880,
1.2427; 4-ClC 11 156-1/2, 1.6010, 1.3437; 4,5-
6 41 S' C9111OC12OS' 501 C12C6H3' S'
C9 H8Cl3OS, 779 185-7/2t 1.6100, 1.4571. To-a mixture of 22.1 grams of Ia and
10.12 grams of Et 3N9 12.32 grams of o-anisidine are added at 806 for 30 minutes.
The mixture is mixed for 15 hours at 85-100% separating 8.3 grams of II (R = 4-
Cic6H 4, R' = 11, R" = 2-NeOC 611 41 X = 0), C16018 ClNio 31 yield 54%,, boiling point
20
13J-714; n D 1.5933, dF" 1.2455. The II.are obtained analogously (R, R', R",
X, the molecular formu the yield in %p the boiling point in *C/r,,-a or tne
20
melting point in *C, n Do d 4 are given): 4-ClC 6H41 11, Ph, 0, C151116C't"021
2/5

..........
777~"
USSR
KUKALENKO, S. S., et al., Khim sredstva zash6hityrast., vyp. 1, Moscow, 1970,
pp 256-262
450 78-80l --9 4-CIC 6 11 4' 11, 3-14ec 6 1140, 00 C16 H 18 ci-IMI-)l 200 69-700 --1
4-CIC 11 H. 2,4-11-le C 11 01 C ClNO A 33, 86-7, 4-C1C If Me, Ph,
6 45 2 6 30 171`20 1 2 6 4$
0, C - H CINIO 33, 203-5/10, 1.5925, 1.2183; 4-CIC Et, Ph, 0, C 11 C1,10
16 18 29 6H4' 17 20 25
250 203-5/5, 1.5872, 1.2414; 4-ClC 6F. 41 111, n-C 0171 0, C 17 11 28 C.U;O 22 131 174-5,
110S, -
Ph, H, n-C 8 11 17# S, C 17 H29 201, 66-7, Ph, Et, Et, S, C1 11 NOS
-3 21
60, 147-312, 1.5430, 1.0722; Ph, 1-1, 2 Me st C 11 NOS$ 30, 214-6/2, 1.6180,
7 C6H4' 16 19
-- 'nos'
h, H, 3-MeC 611 4Y S, C 16H 19 NOS$ 300 46-8f 0 Phi Us Ph, S, C 15 H 17
los 42 46-7 - --- -- Ph, H,
56-8, Ph, 11, 2,3-Ife 2 C6 11 30 S' C17 11 21 1%
2-MeOC H S, C H 1140 so 35, 233-51/5, 1.6150, 1.1852; Ph, 11, 4-CIC 11 S' C
6 V 16 19 2 6 41 15
H ClNOS, 34, 64-5, Ph, Me, Ph$ St C H NOS) 41, 200-2/2, 1.6210,
16 16 19
1,1444:Ph, Et, Ph, S, C H zloss 301 213-15/4, 1.6090, 1.1789; Ph, n-C 11 Ph$
17 2 8 171
-40/3 1.5670, 1.0522, The ill is obtained by heating a
so 033 NMI 25 438 0
mixi-lure of I and the corresponding carboxylic acid in an organic solvent in the
vr ;ence of H SO with continuous redistillation of the Water in the form of
0 2 4

USSR
KWALEW1110, S. S., et al., Khim sredstva zishcnityrast., vyp, 1, Moscmi, 1970,
pp.256-262
the ameotrope (R, R"', Y, the molecular form ~ba, t~6 yield in the raelting
point in *C or the boiling point in OC/mm, n D ! d are given). 2-CIC 6H
CCl 42, 184-5/3, 1.5401t 1.4731; ~-Clc H CH cl, 0, C I,, CI 0
31 01 ClP9C'503- 6 41 2 11 1 3 3
58,' 180-1/3, 1.5385, 1.3823; 4-CIC 11 , Et, 0, C, 51, 160-1/5, 1.5194,
6 4 P14CIP31
1.2471; 4-ClC H Pr, 0, G, H Cl 0 50, 170-2/5.f 1.5189, 1.2230; 2,4-C1 C 11
6 41 3 16 2 31 2 6 31
cii2cil 00 Cl_jH 10 C1403F 511, 183-5/4, 1.5493, 1.4556; 2,4-C1 2C611 3' CC1 31 0, C11 a
C1 6'D 31 501 190-3/3$ 1.5510, 2.5178; 2,4-CI 2C031 Et, 0, C 12 11 i3 C1 3039 460 17,c~-80/21
1.51380, 1.3465; 2,4-C1 2C6 3' Pr, 0, C13 11 C1 0 40, 183-90/2, 1.5253, 1.3103;
.15 3 V
Phi Me, S (Ma) , C 57 166-9/3, 1.5520, 1.2203; Ph, Et, S, C 11
11~13C"'2'1 0 12 15
CIO S" 50, 163-5/3, 1.5402, 1.1751$1 Ph, Pr S' C 1i C10 S, 42, 183-5/8, 1.5335,
2 13 17 2
1.15,46; Ph, CH Cl, S, C p Cl 0 St 40, 178-80/2, 1.5740, 1.2900; Ph, CCI S,
2 1 12 2 2 3t
C H CI 0 S 400 215-20/34, 1.5650, 1.2528. Ten grams,of SO Cl are added to
11-:10 4 2 2 2
14 grams of Ma in 30 mk of (fry CCI in one hour at 20-25% the mixture Is held
4
%~S hours at 20*, separating 6 .5 graTas of 111(R = 4-CIC 11 R"' = Me. X = S).
6 41
67

KMALENKO, S. S., et al., Khini sredstva zashcnitvrast., vyp. 1, Moscow, 1970,
'pri 256-262 20 20
cipl2cl 202S, yield 41%, boiling point, 138-40*!2, n D 1.5785, d 4 1.2812.
Fifteen grams of POC1 3 are added to 20.22 grams of 1'.b; the mtass is mixed for 5
hours at 60% separating 19 grams of V1 (R = Ph, X S), C 911 10 C1 2S, yield 86.4'.,
20 20
boiling point 122-4'/2, n D 1.5830, d4 1.2591. Thirteen grams of SOC12 are
dropped into a mixture of 22 grams ofII and 13 grams of C 5H N at -20-0*; the
mass is held for 6 hours at 100% 300 mt of dilute HCl is aaded, it is extracted
with ether, the ether layer is washed with water and a sulfur solution, it is
dried, yielding 19 grams of IV (R = 4'ClC 6H49 X = 0), C 9 H9C1 30, yield 79.80,
boiling point 133.5-4*/l n 20 D 1.5527 d20 1 3455. The IV is obtained analog-
4
ously (X = 0) (R~ the molecular formula,,the yield in 9, the boiling point in
Cjlrm, n20D, d20 are given): Ph, C H Cl 0 82.2, 106JI, 1.5417, 1.2429; 2,4-
4 9 10 2
C1 C H C H Cl 0, 65, 145-7/1, 1.5629, 1.4317; 2,4,5-C1 C I[-)# C it C1 0, 50,
Z 6 31 9 8 4 3 6 - 9 7 5
15&-61/1, 1.5775, 1.5250. Thirty-six milliliters of 30% 11 20 2 are added to a
mixture of 18 grams of Ib and 43 m~ of ice AcOH; the nd~tture is heated for 5
hours at.50-75'. isolating 20 grams of 1-plienylsulLihony~'-3-chloropropanol,
yield 95%, melting point 690 (petroleum ether). The I-IV have herbicidal
and fungicidal activity.
-5/5

Urr,
USSR 547.661-732.5"
KLEAUNK0, B. S., and All Union Scientific Institute of
Chemical Plant Protective Agents
"Chemistry of Organic Pesticides. II. Chloromethylation of 3-Arylbutyric Acids
and Sorre- of Their Properties"
Leningrad, Zhurnal Organicheskoy Khimii, Vol 7, No 9, Sep 71, PP 1816-1819
Abstract: In a search for new pesticides,~chloromethybLted 3-arylbutyric
c CA maldehyde
Ids were synthesized. A mixture of .3-phenfibutyric acid, 3 , for
a
and concentrated hydrochloric acid was saturated irith gaseous IM at 20-250
and then poured into ice water;---3-(4-chloromethylphenyl) butyric acid (I),
m. p. 113-1140 crystallized- 3-(2-Methyl-4-chlorox-ethylphenyl)-butyric acid, m
m.p. 94-95 0 was similarly obtained. (I) with thionyl chloride to yield
I 26eacts
an acid chloride, b. p. 135-1360/3.1irin. d 1.1211, :n~o 1-5444, which when
4' D
treated -with butylamine in absolute ether. gave a butylamide of (I), m--o. 77-780-.
Refluxing (I) with ammonium thiocyanate and anhydrous acatone gave 3-(4-thiocy-
anylmethylphenyl)butyric acid, m.~. 62-63- Compound (1) reacted with potassium
diethyl dithiophosphate. to give 3-(4-dieth ldithiophosphous r7.:-thy1phe-ry1)
butyric acid, a viscous oil, d -1.2o68, 1-54443. Refluxing (I) with
1/2

USSR
KITKAUNKO, S. S. and KA-GAPOLOVA, F. V.., Zhurnal Organicheskoy Xhimii, Nrol 7,
No 9., SeP 71, pp 1816-1819
thiourea In anhydrous acetone gives 3-(4-isothio-aroniw=ethyl-phenyl)butyric
acid hydrochloride, m- P- 2500- Similarly the aminometbylphenyl, formylphenyl-,
andL carboxyphenyl. derivatives were obtained, mp 2309, 27-290, and 2040,
respectively.
2/2

~l ID2
UNtUASSI FlIED 'PROCESSING DATE-30OCT70
OF TRANSAMIDINA-SE AMIDINGTRANSPHERASE ACTIVITY IN THE
~81_0(10 SERUM GF DOGS WITH EXPERIMENTAL PANCREONECROSIS -U-
S.R.s KARELINAtiA.A.9 KARGASHINI I.A.
-OUNTRY OF INFO--USSR
'-~-.'-.-SPURCE,-PATOLOGICIIESKAYA FIZIOLOGIYA I EKSPERIMENTALINAYA TERAPIYAV 1970,
NR 3t PP 8-11
DATE P-IUBL I SHED -70
-BIOLOGICAL
BJECT AREAS AND MEDICAL SCIENCES
't--TOPIC JAGS-PANCREATITISt TRANFERASEe ENZYME ACTIVITY. NECROSIS,
~_o-'.z:~DIAGKOSTIC MEDICINE
Ii, J,
TIROL MARKING-NO RESTRICTIONS
MENT CLASS-UNCLASSIFIED
..,::PROXY RI'EL/FRAME--3001/1923 STEP t4D-UR/0396/70/014/003/000a/OOLI
r -AP0127324
_,IRC ACCESSION ND
UNCLAS&WIED

020 UNCLASSIFIED PROCE :SS ING DATE-20OCT70
ACCESSION NO-AP0127324
G IRC
-,-AB,STRACT/EXTRACT--IU) GP-0- ABSTRACT. THIS WORK WA 5DONE ON DOGS '41 T H
HEMORRHAGIC PANCREONE-CROSIS CAUSED BY'THE ADMINHTRAtION UF BILE I N To
THEiPANCREATIC DUCT. TRANSAMIDINASE (AMIDINOTRANSPHERASE) ACTIVITY WAS
REVEALED IN THE BLOOD OF THESE DOGS 6 TOPJ2 HOURS AFTZER. THE BEGINNING OF
PANCREONECROSIS. IN CASE OF PANCREAtITIS CAUSEO BY THE AOMINISTRATION
OF SUDIUM TAUROCHOLATE WITH TRYPSIN
INTO THE PANCREATEC DUCT,
PANCREONECROSIS OCCURRED COMPARATIVELY LATE AND TRANSAMIDINASE WAS
REVEALED IN THE BLOOD IS HOURS AFTER THE,ONSET OF THE AFFECTION*
FACILITYz KAFEDRA BIOKHIMII I MOSKCVSKOGO MEDITS.INSKUGG INSTITUT,
FACILITY: IM. 1. H. SECHENOVA I LA809ATORLYA ENZIMULOGII INSTITUTA
BlOME:DKHIMIl AMN SSR, MOSKV.A.
UNCLASSIFIED

Jpws "/0'1-/z-
SCATTFRINC OF Vir 6-PULSK FHOM A PEM.'T.L, REMI IN' THE SEA
(Article bi, A, H.
,,, ;c,ja~,~nivgra~,. 012tika
okpan it i -"9s I a I I, 'st'.0 Nau)ta' 197-2. bl-
lit ijivctstierttiaiit, of nori-statitmary Iirhr rieitis arising
4uring the work -ol. sightitir it") Lora Lion systemst an important
place is occupica by the (ju~stirni or the proparation o9 6-pul-
Na from a narrowly directed radiation source. (Te zitrrain the
hape or the signal. received by a receiver during an impinging
p%21zq different from a 6-pulsf-q it is sufficient to irttroduce
an operation or integrotion or the typ* of rairune, witii the",
or the scatterinr function of the 6-pulae.. This, is touch more,
precise and-si.pltv tku,4i mod-Ilinr a signal extend-d in time.)
A considerable number of theotetical uld.-C-Perim-ntal-
.ork.s,hawe recentlY OPP47"red-ill which studics havetivon made or
th~ laws of tirht I ields, arialtir during the illuminaLlon or
scattering and absorbing media by short nArrowly, direcrod sig-
nalki (1-31. 1;owever. with reference to specific coodirions of
watur that question remains opon. lit the present, "par the
scattering of 5-pulses rrom a narruwly directed radiatitto source
in the sea is main nttitntion being Civ.11 ~to
the ti-t and angular structurn or the light fiold.
Precis- o7mLyticul. solution of th. equatino or r-iiation,
tratisf4~1' for,a statio"ary and non-statiottary narrow with
is strounly prolate indicatrix or scatteritte is vtiry, tiovioWy
tind Little ouited roe practical. purpnwes~ Th,!ref'ore the main
importance is acquired by ntimeeit:aj Methods or Computation, anti
especially the Moatr-Carl.o mothod. which also is used in the
Paper.
lit solvinC the posed took the following stochastic model
of light propagation wax adopted& radiative energy is trans-
ferred by aL proton flux,i the motion or which can be considered

USSR UDC 621.373.826:621.396__~
ZEGE E. P. IVAITOV, A. 2.t IaTSEV, I. L. MiGII-T, B. A.,
KUMETSOV, S. V., and MIMIMOV, G. A.
"Some Yroblems of Optical Nase Radar iti Natural Dispereing
Formations"
Moscow, V sb. X Vses. konf. po rasDrostr. radi01701n. Tezisy dokl.
enth All-Union Conference on the Propagation of Radio Vaves;
Report Theaes--collection of 'works)JIllauka," 1972, pp 337-341 (from
RZh--RadiotekhniI.-,.a, No 10, 1972, Abstract No IOD440)
Tx-anslation: A method is given for computing the siVial/noise ratio
ofe an optical radar system combining receiver and transmitter,
under the condition that the sigrLsl.is propagated in a medium char-
acterized. by
the probability A of photon survival. Lith increasir-C
distance between the object and the transceiver,ithe signal/no-ise
ratio varies according to the law
exp (+ +
whore T is the distance between -the object and the rz,.dar and fi~;
the eigenvalue of the charz;,.cteriotic eqtiation. Bibliography of
f ive. A. L.

USSR UDC 621-373.826:550.3
IVANOV, A. P., MGIN, B. A., KNNEETSOV, S. V., and SME LIN, A. L.
"Propagation of Short Light Pulses in the Upper Layers oi' the
Atmosphere"
Moscow, V sb. X Vses. konf. Do rasDrostr. radiovoln. Tezisy dolrl.
(Tenth All-Union Conference on the Pro-pagatioli of Radio Waves;
-3 336
Report Theses--collection of.works)' "11- (from
'auka," 1972, 3
Mlh-Radiotekhnika, 110 10, 1.972, Abstract No 103537
Ti!anslation: Results are given of an analysis, by the Nonte-Carlo
method, of the radiation of a laser'bcattered back by the up.,Ier
layers of a nonuniform atmosphere. The material obtained was used
to estimate the signal/.noise ratio in the* obseintation of distant
objects.-
BiblioGraphy of one. A. L.

USS UBC 541.15
SUMOV, F. F., SIA)VOKHOTOVA,N A.j peased),_.Xjj,,&g, Institute of
Physical-Chemistry imeni, L. Ye. Kati
"The Yechanism of Radiation-Tnduced Dehydrochlorination of Polyvinylchloride"
Moscow, Xhimiya Vysokikh Energly, Vol 5, No 4, Jul-Aug 71, PP 364-365
Abstract: A very broad band in the infrared spectrumpre-viously observed
during vacuum irradiation of PVC is caused partly by the formation of HCI
ccqplexes with ox~gen-bearing impurities in~the starting poly7ner. The fact
that the 2300 cm band does not reach maximum intensity until very high
dosages indicates that the polymer is continuing to accumiLlate sone light-
quenching particles near this band regardless of the presence of oxygon in
them. The fact that part of the absorption in the 2300 cm-1 band disappears
when the iiTadiated polymer in heat-ad to 200011C suggests that the particles dis-
aPP(baring at 2000K must have a structize similar to KCI coutplexi~s with ethers
and.sarbonyl groups, and further that-this disappearance is caused by CH
valence oscillations in the carbonium ion ev., C%-6ff_CH2 Spectral studies
confIrmed the proposal that the 2300 cm-1 band is reUted to the ion pair
1/2

F

"w'sumERS WITH, :CARBO'NYL'. GRI NltkiLE GROUPS WITH METALS
-,*t' -~-Z~LM,E REACTICNS OF THE RESULTING ANIONkAL)ICALS -U-
A(JTtiGR-(e5J-PANASENKO, A.A., GOLUBEVY VoS.1 ZUBOV.,~V.P.s KABANOV, V.A.t
COUNTRY OVINFO-USSR
SGURCr-,VYSUKOMOL. SOEDIN.r SER. A, 19M V94) 865!--72
"iDATE PUBLISHED--TO
SUBJECT-AREAS-CHEMISTRY
'T.01PIC TAGS-1VONOMER t-CAR13ONYL RADICAL* NITRILEs SODIUMIr iwcGNESlUM.v
-~,_--ACRYLATEs ACETONEv BENZOIC ACIDI.FREE RADICAL, OLIGUMER
CGNTROL MARKING-NO RESTRICTIONS
VOCURENT CLASS-UNCLASSIFLED
?~ROXYIREEUFRAMI~-2000/0683 STEP NO--UR/0459/701012iOO4/086510872
ClRt-_ACC6S'lON NO--AP0124355
UNCLASSIFIED

~-ziZ 022 UNCLASSIFIED PkOCESSING DATE--30OCT70
r-IRC ACCESSION-NO-AP0124355
ABSTk:4'CI/'EXTRACT--(U) GP-0- ABSTRACT. THE VAPORS OF NA OR MG WERE
'..~CONDENSEO ON A SURFACEr COOLED WITH LIQ. Nt TOGETHER 141TH THE VAPORS OF
~,-..ME METHACRYLATE, ME ACRYLATE, HE BUTYRATEs ET BENZOATEr ACH, ETCHOv ISO
:-PRC140, TERT BUCHO, ACROLEINr ACETONE, li SUB2 C:CHCN, H SUB2C:CMECN# OR
.~,ETCN'm THE CONDENSATE CONTAINED FREE RADICALS* THE REAcriONS OF THESE
MON014ERS WITH NA OR MG GAVE ANION RADICALS* SUCHLAS IJE SUE12 CO), WHICH
INTIATED THE.OLIGOMERIZATION BY ANIONIC~MECHANISM*; FACILITY:
HOSK41- GOSO UNIV. IM. LOMONOSOVAs. MOSCOWv USSRO',
UNCLASSIFIED

USSR UDC: 54-1 -4-9: 541-6
DWYM11A. S. L. PLATE N. A.,
,.decease.,
"Synthesis and Che,-,-,Ical Couverzions of M--tal-containlnfr
-0 C
Mosco-w, Us--Oel:hi Vol 39, " -12, Da 70) 22c~6,~-2286'
-Abstract; 7.10 artic",'O i, a sur-,-ey coverim- the most i-im-artatil; c-1
synthesis and chen-ical of matni.-containin-, 0'. war Cu S
types. In 1--his re-i-e- the term, P.*~!~tal-con-Laining pc2-,)-me:r co,,7,,pounds
orfranometailic po2~,n-:!ro with or,,-%nic princi-ial chair-.:~ i ~:here -1
direct cafoon-metal b--nd of tale tj7pc cf
DJ. crule-oxyi~-Dn
particularly 4"'nos-- wit-, Lncro.::
poly.-,-r Commounds Cil Contain Cooiniination bovdcd at,:)ws of
vosr
tals. Mnere D.1-, the reactivilUes of the metal-c-lantaind -!-.roi. :~!Qc~ 1-:as
and their lo~w-molccuiar TnL-
y
attCmpts at synthesi'zin- UlDir coriyer,,joll
C a TS a U 5~, of
from the in of ~-c, rac-tliori
SeCtj-r%~:: 1'n-fry
the fol
derivatives of ,,ntai- oj,' jlroui)-~ 11 arld 131. Uza Of
polyner'; fo, iniitd,"!.,~:

USSR
DAVYDOVA, S. L., Uspekhi 10iinii, V01 39, No 12, Deec '(0, pp 2256-:2236
3- Organomietal polymcrs -- derivatt'vess o'f~ )jc,,jj-y met~iis. 1etalli, ned polnLars
-ancl stabilization; 4. Coit-mlexes of tra"SitiOrl tals With mcl-0::o-fecular
ligands: a. reactions With participation of the metal-lig,mid bond; b. r--actions
of the coordinated rirlacromn~lecule; 5. Fnctors which determine the properties
of various types of polrm~r-mctal chemi"al bond; 6. PecUliaritier~ of chemical
conversions of rp-tal-containirg macromoldcules due to their polymer nature.

I/?; oz6 UNCLASSIr-LEU PRUC~SSING OATE--2iQG(7O
TITLE--ROLE OF THE COOPERATIVE INTERACTION OF GROWING CHAINS AND
MACROMOLECULAR MATRIXES DURING POLYMERIZATION -U-
~AUTHOR-(05)-OSAOA, YE*t ANTIPINA, A*D#t PAPISOVP I-oM-t KABANOVt V.A.i
KARC3,INt V.A.
C OtM.Wr '-FUS-SR
SOURCE-D09L. AKAD* NAUK SSSR il970t''191(2)t 379-40P. (PHYS CHEM)
DATE PUBLISHED ------- 70
S UBJ ECT.,4.RE AS--CH EM IS TRY
TOPIC TAGS--MACROMOLECIJLEt METHACRYLIC ACIDt POLYMERIZATION# HYDROGEN
BONDINGt CHEMICAL REACTION RATEr MOLECULAR INTERACTION
'CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLOASSIFIED
PROXY REEL/FRAME--1997/1127 STEP NO--UR/0020/70/191/002/0379/0402
CIRC-ACCESSION NO--AT0119981

2/2 026 UNCLASSIFIED PROCESSING DATE--230CT70
CIRC ACCESSION NO--AT0119981
40STRACT/EXTRACT--(U) GP-0- ABSTRACT. K SU82 S SUB2 0 SUBB INITIATED
POLYMN. OF.METHACRYLIC ACID 11) IN AQ*: MEDIA AT 50DEGREES IN THE
PRESENCE OF POLYETHYLENE GLYCOL (11) OF VARIOUS MOL. WTS. WAS STUDIED TO
ESTABLISH THAT THE PROPOSED COOPERATIVE INTERACTION BETWEEN THE GROWING
POLY(METHACRYLIC ACID) (111) CHAIN AND THE 11 MATRIX AROSE FROM .4
BONDING BETWEEN CO SUB2 H GROUPS AND 11 0 ATOMS. THE PULYMN. RATE OF I
FELL GREATER THAN 10 TIMES AS 11 MOL. WT. INCREASED FROM SIMILAR TO 100
-TO SIMILAR TO lOtOOO* LOW MOLs WT* 11 010 NOT FORM STRONG COMPLEXES
'WITH III AS*SHOWN BY INDEPENDENCE OF THE REDUCED YISCOSITY OF III IN THE
PRESENCE OF 11 ON H MOL. WTo LESS THAN 1000. THE INITIAL RATE WAS
INDEPENDENT OF II CONCN, APPARENTLY9 I 11. MUST ATYA IN SUFF [CIENY LENGTH
FOR COOPERATIVE INTERACTION WITH 11 BEFORE POLYMN. CONTINUES ON THE
MATRIX. AFTER ATTAINING A 3-4PERCENT~YIELO (BASED ON III OF III OR
ADDING THE CALCD. AMT.9 THE POLYMN. RATE INCREASED TO THAT OBSD. IN ITHE
ABSENCE OF lie AT HIGH PHt WHERE MONOMER AND III CHAINS WERE TONIZ6,
THE REACTION RATES IN THE PRESENCE AND ABSENCE OF II COINCIDE; DUT WITH
LOWERING OF PHt THE RATE INCREASED INSIGNIFICANTLY IN THE PRESENCE OF 11
WHILE THE RATE IN THE ABSENCE OF 11 INCREASE FACILITY: MOSK.
D.
G05* UNIV. IM* LOMONOSOVAw MOSCOW# USSR,

r" 101288s Theo7of necking -during polymer iflongation. An
drianova. G. P.-. margin. V. A. .(Inst. Ntftekhirn. Sin..im. OR
chii-x-a-Mr-1cow, _UR"SW7_vY__qIOh6 O-WIM.1,ser. A ISTU, 12(l),
3-9 Mus,%). A theory of necking4as developed in terms of the
free vol. theory. The theon- was. based on 2~
assumptions;
the glass transition temp, (T had:a certain const. value relat-ve
to free vol. regardless of whettir & resulting fr4 vol. was due'to
a change in temp. at external stren; (2) the cht,e in sa~mple vol.
w
during deformation below T,,,, (where 7' Ois Tor thout .4tress) re-
flected the total increase in free vd. ln&easin~ the sirm low-
ered T,. and if the drawing was 'carried OUE belpvv T,, necking
occurred when the stress was gieldenough to' loiver ~N,rn T,
to the operating temp.. CKJR
REEL/ TRME

Ali
Abstracting Service: Ref. Code
k.4,0100_197
ClIalICAL ABST. 010 -4 .0
111989k Highly elastW deformation of 1.4-buti.nediol di-
methaerylate-hexyl methaerylate copolymer. Kiark -JxL. A',
Khatikov D. Kh ~ Sht e.' P 'Plate N III V5 Ova.
Li ~_- -NT-.W *S8ft).__ -
A. F Mosk.
A k- -- -Ar W SS.1, .1976," 19C
-D-W' ad, dii ?k IYVs
(Russ)* An attempt wai made 40,00 tile Valtier, of0e indi-6du-
at. terms of the elastic, stretching force f = (iW/ZA)p.4 -
the de roe of
7jdS/OA)P7 = OHOA) 1+ T(Oj1j7)p.,- where A
stretching: H = enthafl.)Ty, S = eriLropy, P - stress, an r
at- t-ernv.-. as w.ell as f,11, where & he energy component:of f,
for- 1,4-butanediol climethacrylate-liekVI methacrylate copolymer
(1). The stress relaxation and ther~noiqastic piperties of I rilins
(30 X 5 x I mm) were, measured: vOth. a special clyoamometer
a identi
(M. E. Misyureevich, 1969~. The f. wai ~Imou Cal at high
and low,tenips, This, together with'the al~senca of re4i~lual defor.
mation. indicattd the complete r&b6ihifity of the- liighly elakie
deformation. However, despite theInci thiit 0116T)pj for I at A
> 1,10 was pos., f was not directly proportional to T. DBJR
REEL/FRAME

Acc. Nr Abstracting Service:
Ref. Code
APOD4682'r -CHEMICAL ABST.
7C, V 0
9033v Adsorption beha:vior or~~lne polyester and
polyamides in a:w e~atuZ nqe. B~gevgka-a. T. A.
ra_
)k
-
Gatovskaya, T, V.; JN41%in, V-A-4tiz. Khim. n t nrnova-
-
lwo
scow, MISR). .. U'Soedin., Ser- A IPTO, 120~, 243-1
(Russ). The*ad,,;o tion propefties of polk(ethylurie sebticate) (1),
rp
rlycaprolactam and hexameth 'vlenediamthonium adipate-
e
xamethylenedia nium sebacate-11 copolymer (111) wete
m1no
investigated at 30-225'. The:adsorption of EtOike by I films was
described by byperbolic isothirms, indicating a st.mng interaction
between I and EtOAc leading io increased flexibility and mobili-
ty of the individual structural. elements. Significant structural
changes were detected at the same temp. at which "capi.1lary con-
densation" of the sorbate vapors is obFd.: Struc~ural transforma-
tionx in this case also apparlo t1v wurre(l via millting of material
with low ordering, Decompri 4 th6 supromol.~eiiirkiLtur6,o(,,curre-d
At >95*. The melt of the c t. polvmerwas OoC a homogonfx)us,
ryi;
mot. dispersed syaem but co tainea ordered rejions. Uttle ad-
n
sorption (