SCIENTIFIC ABSTRACT MAYDANOVA, N.V. - MAYOROVA, R.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002202010010-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

2 42 008 Pkl' CFSS ING OAT:-:'-- I I S-P70
UNCLASSIFTEO
CIRC ACCESSION 40--AP0106113
ABSTRACT/EXTRACT--(,t)) GP-0- ABSTRACT. IN THE PP.0aJ(,TIfl?) f)): Cl) SIJ.12 ~~CL
su6z, B~SFn ON A PtEAMON BETWEEN CUCL SU62 AND 4 J)'[SPEr.51014 Qf- 1~
IN A 4 CASCADE PROCESS THE CONCN. OF CKL SUB2 IS 1MIT04ATIULLY 1) E f
WITH A REFRACTOMETERt AND THE REFRACTION ANGLE Is 1--Eo yo ,,4 compiTFR uv~
CONTROLLING T14E AMT. RELEASED INTO THE~AEACTOR VAT5 OF CHALK DISPERSION
AUTOMATICALLY DETD. BY A RADIOACTIVE Do GAGE.
jr-
uz L_ I-

7-
Acc. Nr: A PCO51922' RfA. Code: UR 64 1
PRIMARY SOURCE: Byulletexi' Eksparirnent:al'noy MoWgii i
Mcdits:Lny, 1970, Vol&?t Nr,2. , PI) ijI-119
RAT LIVER TRANSKETOLASE AND ERYTIlRoc)'TJ7!j ACTIVITY UNDER THE
ENTECT OF $OUND
N.
Z.,iporozhl-e""~-I"e"-dic"'aI Institute
Experiments staged oil 113 albino rats demonstrated reduc,!d txans!'~(-.tolase activity
under the effect oi sound (94-96 dB, frequency 2 khz) uhich progres;sed further as
the exposure time was increased from Ii to 2 hours. When Ihe e.xposure time lengthi'lled
to 38 days this effect became weakei! With long-term (110, 130 days) tile
transk-etolase activitv decreasqd by 2 and 4 Wnes mpecl1vt1y, The fall of the eryth-
rocytes transhetolas~ activity becomes apparent anly in ',h lun6rA,1:rm effect of sound
(130 days).
REEL/FWIE
.,!l Q Q2f "4u ~Ir

USSR
MAYDANOVA Ye. G., Vladivostok Medical Institute
ViDiagnosis of Influenza"
Vladivostok, Biologicheskiye i Meditsinskiye Issledov4utiyaa nn Dal'nem Yostoke
(Biological and Medical Research in the Far East), Vla4ivostuk, 1971, pp 137-138
Abstract: During the 1969 influenza epidemic in Irladiv:)otok, a number of
persons were hospitalized with an "atypical" clinLcal p(icturv in the form of
gastrointestinal sympto-Ls, idiich led to an initial r~istaken dill.-nosis of
acute dysenten-,. Beiides the failure to isolate dysentjwry Or typloid inicrobes,
the clue to the correct diagnosis was provided by rectc,romanoscopy which. re-
vealed moderately hyperemic, rectal and sigmoid mucosa wirth protiounced vascular
markings and petechial hemorrhages simil4r to the chanpii In pliaryngeal muccasa
characteristic of influenza.
1/1

USSR
UDC 541.183
LOBANOVA, G. L., KIROVSKAYA, L A and WOVSKAYA L. G. (Oeceased),
Tomsk State Un3.versity imeni V. V: Kuybyshev
"Simultaneous Adsorption of Hydrogen and Oxygen on Gallium Arsenide"
Moscow, Zhurnal Fizicheskoy Khimii, Vol 45, No 8, Aug T1, p 2101
Translation: The paper presents the results of a study of adsorption of
H2 + 02 mixtures on a GaAs se-nicanductor. The absorbent was a finely dis-
persed powder (specific surface 0.3 m2/g, weight 1.4 S~ produced by pul-
verising a single crystal. The experiments were done tn a statistical
vacuum installation with an attainable vacuum of 5.10"(1 -Mm. 1he total $~as
pressure and its mixture for various ratios of components was 0.31-0.99 rmi
at temperatures from -183 to 375*C.
According to the resultant data, the most active component of the 112 +
mixture is oxygen. 'rhe degree of adsorption jA of the 1pis nixtures occup:Les
an intermediate positIon between Q11 and a()2 and lncreaven with an inercase
In the concentration of the most achve component, 0.. At a ratio of H'i:01
- 1:2 and temperatures above 150*C, the value of q b&ories larger than I.he ,
value for the adsorption of oxygen. Basically, the curves for the adsorption
1/3

USSR
IA)BANOVA, G. I., et al., Zhurnal Fizicheskoy Khimii, Yol 45, 'No 8, Aug 71,
p 2101
isobars Of H2 + 02 mixtures behaye in the same manner as for o%ygen ad-
sorption. In the interval from -183 to 300*C, equiLibrium it; reached in
the system in about 30 minutes. At temperatures above 300"C, considerable
time (more than a day) is required to reach equilibrium. 7he kinetic
curves are quite complex and cannot be described by a sin8le law.
On the basiii of the above facts as well as calculations of heati of ad-
sorption (by various methods) the authors make the fullowlial; statemetati
concerning the mechanism of the Investigated phenome-ijon. Ln the interval
from -183 to O*C physical adsorption takes place, wh9le chentosorption
predominates at higher temperatures. Chemosorption is accompanied by a
chemical reaction of the components which shotis up most noticeably above
300*C. During the reaction Of 112 and 02, the formation of a 11dead-end"
compound H20 is noted as well as tempera----ure conditions for retention o~
water on the surface. Oxygen is first to occupy the active sections un
the surface. Hydrogen adsorption can take place an free sections and on
2/3

USSR
LOBANOVA, G. I., et al., Zhurnal Fizicheskoy Xhimii, W1. 45, 'No 8, Aug 71,
p 2101
sections occupied by oxygen, which is most readily iontzed at relatively high
temperatures: oxygen facilitates adsorption of hydrogm, aild hydrogen ad-
sorption then becomes predominant.
3/3

U~SR 511,:L, 183
KIROVSKAYA, 1. A., IIAYD~j.'OV'14a"~A, C 0,11tZENAp E*. I,,
D. , NAGO IMINA, V. N. , Tomsk StUtO U441 VOaJ31'Y Dr.13111.
XURZITA, G. 1 41
V. V. Kuybyshev, Tomsk, Ministry of Higher and Beolondivy Specia.Uzod
Education RSFSR
"Aduorption of CO on Semiconductor* or the 2inc B!Lend lrype~l
Moscow, Zhurnal Fizicheskoy Mhimii, Vol 111~, No 5, Hay 70,
pp 1260-=66
Abstract: A study is roporto(l on the ad.,~orptlon of morioxide
on somiconducil-OP;; Of thO isoolaotronic sorio4ti of G-z~,
GaAs, Zn3e, and CuBr. Kinetics of the ad.soxT,)tion on n.3.1 ol~~ theso
compounds was studio(! aa well aa the deaorption kino'kilco of
Ifeats of adsorption of CO were calculatod for sav*rnl,
by the Clayperona-Clausixis equation of tho F1urJxfj)4~J)04-P1n3j(j ty!".)a,
using empirical functiona detorrianod by the authora. A relatian-
ship was found botwoon the chemosorptive act,'Lvitly and Whe 0.1,
forbidden gono 4U of the above semiconductors: irith I;ILO incroase
of OU the heat of adsorption Is dacreansd, tiv.'i taimpar-itturo of a4e
beginning of activated adsoi.Ttian is Lnereasod it-g. is I;lj.a axiorgy of'
1/2

-7777`-71-1710~
USSR
KIROVSKAYA, 1. A., et al, Zhurnal Fizicheskoy Fhiidi, Vol 44, Ice 5,
May 70, pp 1260-1266
activation. Relative ad3orj)tion coefficients warii) de'ro=dned for
several terkneratures. An assump-.1on waa made that thij i).dSorpt;on
of CO occurs on one of the lattice al,-,opis of given semic',;)nductors
forming surfaae structures of the type of linear aLruattare carbonyls.
In the case of binary ccmpounds the aotive conter,bec-amus the atom
which is included in the lattice in the form of a negattvely
charged ion.
2/2

USSR UDC 519.2
HAYMNYINK R. YA.
"Densities of Dimensions Corresponding to the Solutiont~ of Differential Equations
with Random Right-liand Sides"
Teoriya veroyatnostey I at. stat. Mezhved. nauch. 9b. (Probability Theory lind
Mathematical Statistics. Interdepartmental Scientific Collection), 1971, vyp.
6, pp 98-102 (from.M-Kibernetika, No 90 Sep 72, Abstract No 9-v"66)
Translation: A study was made of the problem of absolute continuity of the
measures corresponding to the solutions of the differential eqoations
Y, W - n(t) , Y, W + f Wyl(t) - n(t) ,
CO 1
where n(t) r Vk sin kt, ~11 Czo ... are independent identically distributed
k=l
stable random variables with the characteristic index 6 > I Eind a distribution
density p(x). The explicit form of the density for theau me-avures Is written
out.
III

USSR UDC~$19.21
MAYDANYUK,_ R. Ya.
"Absolute Continuity of Measures Corresponding to Series of Irxk,-pervdent Randcm
Quantities with Linear Space Conversions"
Teoriya Veroyatnostey i Mat. Statist. Mezhved. Miuchn. SI), [Theary of Prcbabilities
and Mathematical Statistics, rnterdepartmental Scientific Collection], No 2, 1970,
pp 144-149 (Translated from Referativnyy Zhurnal Kibernetika, No 3, 1971, kstract
No 3 V77 by the author).
Translation: Suppose v is a measure in a a-algebra of su4sets 18 of a certain
separable Hilbert space H, which gene-rates the element
where Xk i5 a normalizing .4cquence of nunbers, fe I is the orthonorlullizecl base
of space 11; EI , E2 .... is a sequoince of indepoilnt, IdeniAcat.11:1- distributed
random quantities with distribution density pfx). SLipposa,A is a I illear, jntcastxr-
able mapping of Ii in 11. lie represent by v the mojsure pro:lvced from p with mapping
A, i.e., -j(B=pA-I(B) for all B6 ra - This work detevmines~condjtions for
which v and p are equivalent.

AGEYEV, V. A., GAVRILYUK, V. r., KLTRYASLIKIN, V. T., tATYS]IFIT, G. D., LYU-M,
I N., MAYDA1TYiN1-X-Z-' ~L%KOVETSKIY, Yu. V., and F-E.04:1'IST07,' A. I., Institute
Oi Ph~`sla-off-the Academy of Sc;-.P--nces UkrSSR
"Study of Conversion Electron Spectrum of Nb96,,
Moscow, Izvestiya Akademi.i Nauk SSSR, Seriya Fiziches5:aya, No 8, Aug 70, pp
1614-1617
ctru,
.1 0 f
Abstract: Individual segments of the conversion elecl:ron 91)(~ b96
associated with the doublet structure of transitions round by ',fonaro and
others are also possible aceor&ing to tha decay scherni! f 'Ib' are iwdied.
The measurements were made on the magnetic j1-spectrc~rrj1!'..Cr ~)Z- t"Ie t'10-1 'T)f2
of the Institute of Physics of the Academy of Scienceii; U~ri!;11. The mea,3ura-
ments showed K-line doublets of transitions in Lhe re!j;ions :351), 720, and
810 kev and K241.3 is apparp-ntly a single line. The o.z the meas~ute-
ments are given in a table. Tlie energy of all trx-.si-tic-s o"11~arved wa!; de-
termined with an error of +0.3 kev. The K-lines of the tran!;icions 350.1
and 352.1 kev were weak anT1 therefore only an elitfmatii! of th--Rir intenslty
is gtvoa. for all trzin~;ition~. obnerv'.~[J' aKwere with rc3nect

USSR
AGEYEV, V. A., dt al, Izvestiya Akademii Nauk SSSR, Seriya Fizicheskaya,
No 8, Aug 70, pp 1614-1617
to the ratios of the intensities of the conversion lfuzs to the intensltie,~
of y-rays. The values of aK for the transitions 350.1 and 352.1 ur,,re esti-
mated. All transitions correspond to multipolarLties MI or E2. The ex-
ception was y812.4, for wI)ich the internal conve-rsion ratio was less than
that established from Tc9b decay. The ground states are evaluated on the
basis of the shell riodel.

USSR ()'24.L)74.4.o4
ALM-VI SH. 1111.1
I"" M-MOV, G. D. (rgikk~i)
"Concernin--, the Calculation of an Oval Shell,' Rc1iY.%rco.1 by Annular Ribo,
With Account Ta-ken of 11lieir Discrate Disposition"
Moscow, Stroitel'nayu Meakhanika i Niccoet Sooriizlicniy, NO 1., .1972, rp 11-14
Abstract: The article deals with an infinituly lor_~; diull 1-.1f oval crc,si--
section, which is lcaded by internal pronsum awl is rCaiforc~-d Ly eq-.iUti~~ittint
annular ribs, account ~Leinil tak.2n of thoir al.acrete d:Ujj)o,Ati.otj. Tno rr,-,1j1em
is solvod on -,;lie basis of it for the calciilitioii of L;lj!!IILI, -'a b'v
X. K_qn. The itana dusi~inatiow~ 11M, 111'40r"ted~ Lit) fliol;!1I in i,1111 G P1.1 -J
Tho chell und1jr invei;tA.:_z,tion cl:wni.lLixteni n v1jjj,Ljj)jy
system. In order to evtduate the applicOill-ty oi' tlio ot
the rib riClditj, a forr~.tla for tying tosether 'd1rL,9 bagda ~-Aramaturr of t!
container is given. An example of the c4lculatlori is givon. 3
5 references.
1/1

!Illllllllr
P110CE S"~ ING DATE--- I IS F070
V2 019 UNCLASSIFIE 0
I'TTI.E--OXIDATTON OF HIGHLY CONCENTRATED SULFNI Oln.VrDE U!Sf.NG TECHNICA'l_
I
-.GRADE OXYGEN IN A CONTACT UNIT WETH FLUIDIJEO CA14LYST RE')s -ti-
0. V. MALK I MAN v I.- KONORA'ryE~,A4 G. R KA AVCH erlOO
;-IbUNTRY (IF INFO--USSR
ISOURCE--KHIM. PROM. IMOSCOW) 1970t 46(l)-24-7
'.'0ATE PUBLISHED ------- 70
-SUBJECT ARE4S--MATERIALS
TOPIC TAGS--FLUlDfZED REOC CATALYSTr WEAR RESfSTANCE
-CiINTROL MARKING--N(I RESTRICTIONS
CLASS--UNCLASSIFtED
.PPOXY REEL/FRAME--IQ96/0012 STFI~ Ni)-,-Ult /00 64/ ILI 104 J'ol 1/ 002", o,')7
CIRC ACCFSStON NO-AP0102112
s-s1 1-

. ......... . .................... .... . . . ......... .........
212 019 UNCLAS*s I r- I Eb PRIXMING DATF-11SEP70
CIRC ACCESSION Nn--AP0102112
A8STRACT/FXTRACT---(tJ) GP-0- ABSTRACT. A GA S EOUS '41 )('F . CIDNTG . 511. 5 V
PERCENT S9 SUB2 AND 42.6 VOL. PERCENT 0 SLIC12 VtAS !3i%!3SF9 (AT a
OF 1600 VOL. PEA HR? THRGUGli A CATALYTIC Rt-ACTOR o?R,rH I I:L'Jli)ll-l) 11FOS
OF A WEAR RESISTANT CATALYST; THE TEMPSt [IF TIfF PIRST, SFCOV,ol AN"
BEDS WERE 600, 550t 4N0 500DEGREES, RESP., ANO THE PRESStJQE WAS L At-M.
T14E DEGREE -OF OXION. OF THE SO SUB-) AFTER THE TH1111) BEO dAS 93. 111':
EXPTS. IN A PILOT PLANT RE?%CTOR tONFIRMEO THAT STMItF QI)FkM~IN A",), AF
ACHIEVED WITHOUT PREHEATING THE GAS.- A FLOW ~IIEET I-OR A LARGF SCALE
OXIDN.-PLANT-IS OROPOSED.
lf!lt7U_A-C~TL_C- rn

USSR
UDC
'II,"FAKATYK7G-,N, 0. 0., YUNDIYEV, Yu. I., MYNA, G. G., F*-14-P'; 311111,
IIRYSIIKO, F. I., DEMACH, V. S., KI-OVSHIM, 0, P., IaRYE-VOI A.
TOMAS I I
A. N., KOVAL'OVA, G. I., MUMINA, A. M., M-V; NA, A. 11-,
C le and Oc t n 1.
Institute of the Work Ilygi L
~VQI,'.qX cupa io .1
aaJOI;j;
Diseases, Kiev
"Nervous Emotional Stresses as a Problem of Modern Work 11hysi(Ilogy"
Kiev, Fizioluhichnyy Zhurnal, Vol 18, No 4, Jul/AuS 72, [)1) 5:1!k--546
Abstract: The introduction of mich!ncs and automatic coi:ttrul
into production line3 at plants and factories and -it matty otlt-~r
requires of workcrs rapid coordination of actions wilii rental zietivi.ty.
The volume of informacion input -which requirci a c-j~:!An.4!tion of phy~Acal aild
mental ability ha!~ been increasing tritinenclously for the L.-ist decade. This has
produced nervous aad enational stresses and disturbancwi~ iT- Lh(! I':I;nCL-fO--)S
of wany human organs. Analysis of z--!~~ny workors fr(~ii- varla-cs bran-ches o-.: inl'us-
try as w,Al as people occupied with mental worl, hat; Shf;-,,111 0111~ t-Cldel:n
imposes hotvy stressos on an individual w1iich are accul.,11al-ica.tly Aw:~-niW11. r"l,,C-
tiou of the adrenal glands, and hypothalamus, and the hypophy:,;J~-;I aid
adrenal 4ysCcin!;. I-leasuremento have Miovii that corticoi30troii.' blood and urinc-,
1/2

A
USSR
NAVAKATMAAN, 0. 0., et al., Fiziolohichnyy Zhurnal, Val 18, No 4, Jul/Aug 72,
pp 535-546
levels exceed the norm by as much as 42-57% in people kinder heavy stri!ss.
Emotional stress with distortion in the function of ai.-AXY1, sysceir's were wore
often encountered among the young (17-18 year olds). Aese nalfunctions
included the secretion of adrena-lin and noradretialin, azd disturbanccs in
hemodynamics. Shifts in physiological functions among, dIffereat occupational
groups under identical stresses occur at diffurent timuz --ad are cIc:3e-!V rL-
a (.31-40 vears old).
lated to age. They were more pronounced anon- older peqmpl
The cardiovascular system occupies a prominent place in labor physiology,
and there are many methods and approaches to study it. Some liter.-.ILure
methods and those of the authors are described, includiuZ in.,itTuTcnt--tIG;n.
Mental work which is nccoinpanied by tia-vous-emotional stress4is infiucncL;~s
profoundly the cardiovascular system within a wide range of de,,iaions, in-
cluding pathological functional disturbances and hypert-a-risiom. The na:Le is
true for other occupitions as well. The authors recommand the rational use
of working hours and rest periods to avoid overstresses.
2/2

USSR 1JDC-- 547-944/945
IMODMAYEV, V. G., b
L. Kh., YTRIMOV, S. Tu., "Order or the Red Banner
of Labor" Institute of the Chemiatry of Plant Yatterialt;, 4bek S-111 Academ.y
of Scienees
OInvestigation of Alkaloids of Thalictrum Longipeftnciaatum. Structure of
Thalicsin"
Tashkent, Khimiya Prirodnykh Soyadineniy, No 3, 1971; pp 4,4:1-442
Abstract: An attempt is made to determine the structuTe of tbalicsin
isolated from the aerial part of Thalictum longipedunaulatunt. Elementary
analysis gives the empirical formula C211il9W, but according to the =ass-
spectrometric& lly determined rioleoular veight the formila siioiad be C211flljo511.
An analysis of the UV, IR, NMR and tass spectra and a t;=-.parison Nrith the
properties of thaliglucinone shows that the correct eltilArical formula is
C21H1906 N with probable structure
1/2

USSR
EMODWAYEV, V. G., et al., Khimiya Prirodnykh Sayedineniyj No 3, 1973,
pp 441-442
R
R
NC
0
0 6:
2/2

USSR UDC 538-113
KGARIM I. No, NIKOLOV, 0. Too and II&M# Io
"On the Structure and Stability of Free Hadicals Prod%Lced in -Irradiated
Glycinell
Kiev, Teoreticheskaya i EksperimentalInaya Xhirdyap 1k,1 4, Jul./Aujr 70, pp
561-566
Abstracti The article deals with pont-radia Lion proco~sises Ln
glycine. Folycrystalline and monocrystalline sNiciinitrnju of a',,.-glycine vmz-3
studied. A &0 source with a dose rate of 3000 roont(rens 4 " minwe w,,15
used, The total dose was 105-107 roantgenso Post-roxii I,ti all heating Of
irradiated specimens showed that three types of free riLdica~m; are farms~,,
under normal conditionss CH2CO0- '~3-1 CH COO- aril N.d?CHOO-,. Specimen-,
freshly irradiated at room temper;ture3contain about YI, 58 and 4'~u of Ui.r,
free radicals, respectively. The last free radical is Uie nost st,:;.ble,
,3e fi~-st is the least stable, With irradiation doses of abtiut 105 rcq.~nt,,'or~s
recombination of all three free radicals is doseribod Vy firiit. order proc(35503.
Electron paramagnetic resonance spoctra of polycr,.rst4la~Lne azo Monocrynt.:111ine
specimens of normal .,~. -glycizte :LrruU&ted at roon tompt%rature are identified,

009 UNCLASSIFAEO OlAOCeS$ING DATE-30OCT70
TITLL-INITIATED DECARSOXYLATION Of MERCUAY SALtS 115F CK1.014EXANC ANO
CYCLOPENTANECARBOXYLIC ACIDS, SYNTHMS OF CYCLOb-EXYL AND
AUTHUR-(03)-GLDEKOPe YU.A.o MAYER* N.A.o OUTKOi YVvDo
~ICOUNTRY OF INFO-USSR
~SOURCE-ZH. 08SHCH. KHIM. L970v 400)o 641-4
-DATE PUBLISHED 70
AREAS-CHEMtSTRY
~-TCPIC TAGS--ORGANGMERCURY COMPOUN09 CYCLOHEXANEv CYCLOPE&NTANEa CARBOXYLIC
ACID* ORGANIC SYNTHESIS
CONTROL MARKING-NO RESTRICTIONS
-;DOCUMENT CLASS-UNCLASSIFIEO
PROXY REEL/FRAME--200010927
STEP NG----UR/00~9/70~11040~1)1)3/0641106tt4
CIRC ACCESSION NO-AP0124588
UNCLASSIFIF,D

212 009 UNCLASSIFIED PROCE5.5ING DATC-10OCT70
CIRC ACCESSIGN NO--AP0124588
ABSTRACT/EXTRACT-IU) GP-0-- ABSTAACT. AUDG* A SOLN. OF PEROXIne
(CYCLOHEXANCYLt BENZOYL, ACETYLI TO REFLUXING SOI,tv- OF HG DIACYLATE IN C
SUB6 H SU66 AND hEATING OURING GAS EVOLUTIGNP Oft A SIHILAR REACT10ti RUN
LN UV LIGHT9 RESULTED IN DECAR80XYLATUON OF NE H,G SALTS Tu FORM
LYCLCALKYLMERCURY SALTS. THE BEST YIELD$ (92-3PEA-CENI'l WERE OUTAI14ED
WHEN THE PEROXIDE USED HAD THE SAME ORG. RADICAL AS THE HG SALT. THUS
WERE OBTAINED SALTS OF CYCLOPENTYLP AND CYCLO'HEXY1.14ERCURY. ALSO FORMED
WERE MINOR AMOUNTS OF HG(I) SALTSv HG* AND SALTS 1',)F PH11G. WHEN AC SUB2
U SUB2 WAS LSED, 23-9PERCENT MEVro SALTS WERE IS01.01JEO. T HE
DECARBOXYLATION IS A CHAIN RE-ACTION COURSE AND THA CHAIN LENGTH IS
SIMILAR FGR REACTIONS IkTH 8Z SIJU 0 SU82 ANO-AC $UB2 0 SUB2.
FACILtTY: INST. FIZ. ORG. KHIM*v MINSK,r USSR.

112 018 UNCLASSIFIED OATE--j)4L)FC70
TITLE--INITIATED DELARBOXYLATION OF MERCURIC ViltERIATE, GAPROATE, Ahl)
CAPRATE. SYNTHESIS OF N iAUTY(.j N AMYLv AND N N0N'el_MEQ.CURY COMPOUNOS -U-
AUTHOR-104)-OLDEKOPe YU.A., MAYERv N,A,r ERUMAPir Ai.A.t 0ZHO11110AVIt, I'U.A.
COUNTRY OF INFO--USSR
SOURCE-ZH. OBSHCH. KHIM* 19701 40(3)t 637-41
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TOPIC TAGS--DCCARBOX-Y.LATION, ORGANOMERCURY COMPOUNOr UV k.IGHT, ORGANIC
- PEROXIDE
CONTROL .4ARKING--NO RESTRICUONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--3006/1472 STEP
CIRC ACCESSION NO--AP0135142
UPIC LASS IF lr_~D

2/2 018 UNCLASSIFIED PROCESSING DATE--04DEC70
CIRC ACCESSION NO--AP0135142
ABSTRACT/EXTRACT--IU) GP-0- ABSTRACT. HG(JI) VALERATE III CAPROATE (11),
ANO CAPRATE (III)v ARE OECARBOXYLArED OY UV LEGHT 10R. Al".YL PEROXIOES TO
FORM SALTS OF ALKYL MERCURY IN GOOD YIELDS. (11, R. 94i0EGkEES (11), M.
104DEGREES9 (11), M. 112-13DEGREE'So- HFATJNG J.0G I 'WIThl 10 G VALEROYL
PEROXIDE AND 200 G BUCO SU82 H AT 97-BD1:-:GREES ONTII:" GAI EVOLUTIO.'i CEASED
(I HR) GAVE MAINLY CO SUBZv TRACES OF BUTENES-i AND SOMli 1: SUB4 H SU1310
IN THE EFFLUENT GASES; THE RESIDUE GAVE 7!i.lPf:R(,ENII* SALTSr
12.3PERCENT HG PRIME POSITIVEt 12.6PERCENT HG PRIM,1:2 POSITIVE. TO HG 5
AND BUCO SU02 H 100 WAS ADDED HNO SUB3 0.8 ANC)v UVIER 19 AIN 30PERCENT H
SUB2 0 SUB2 12 MILLIMOLESv TNE HIXTo STIRRED 0*5 Hill AT ROOM TEMP" AND
0.5 fiR AT 85DEGREESt TO FORM A CLEAR SOLN. FREE 01; HG 1"111 HGH) 51tM.s
AND CONCD. TO GIVE 99.5PERCENT 1. SUCH A SOLN. AFTER REMOVAL OF MOST OF
THE SOLVENT WAS TREATED WITH 1,5 14ILLIMULES DRY NA VALFRATE AND 4,2
MILLIMOLES VALERIC ANHYDRIDE, COOLED TU MINUS 50H;RCES 11140 IREArp -4tm
12 MILLIMOLES 60PERCENT ff SUB2 0 $11021 KEPT 40 MINI( RAPIOLY HEATE-o ro
980EGREESI KEPT I HR DURING GAS EYOLUTION, FILp":itco 1'O 110:MOVE 0.45 G HG,
AND CONCO. TO YtELOr AFTER ADON. OF KCLv g2owEitabir Bt)1'1(;CL;
ACIDIFICATION OF rHE FILTRATE GAVE ON tREATMEN'r wvr~i H !it.iBz s o,,oz s
HGSo SIMILAR REACTIONS WITH SO01s, OF 11tv USING CAh*