SCIENTIFIC ABSTRACT NESKUBO, P.M. - NESTERENKO, N.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002202210014-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


PROCESSING DATE
12 UNCLASSIFIEW -30UCT70
..'.CIRC. ACCESSION NO--APOlZ7872
:'ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. CATTLE FED FOR 79 DAYS WITH
.--COTTONSEED OIL CAKES AND PODS SUPPLEMENTED WITH OPTIMUM AMOUNTS OF
-LITER SUSPENSION, 15.MILLION CELLS-M PRIME3) GAINED AN
CHLORELLA 112.
AVERAGE CF,119 KG, WHILE CONTROLS GAINED ONLY: 94 KG. CONTROLSo THE
NUMaER OF RBC DECREASEDt WHEREAS IN EXPERIMENTALLANIMALS ir ROSE TO
800, 000-ML . THE WBC COUNT ROSE TO 191000-ML IN CONTRULSt BUT REMAINED
ALMOST CONSTANT IN EXPERIMENTAL ANIMALS 17400). HEMOGLOBIN DECREASED BY
14: MG. PERCENT IN CONTROLS 13UT ~INCREASED BY 24 MG PERCENT IN COWS FED
WIT.H,CHLORELLA SUPPLEMENTw ADDITIOWOF. CHLORELL4.SUSPENSION TO ANIMAL
T-ErED".1IMPIROVED APPETITEV INCREASEb:,-'THt":i)16'EStl;'BILIYY ANE).rASSIMILATION OF
u _GOSSYPOL.:P0ISONING.' FACILITY:
4~ TRJ ENrs :--AND ~ALSO PREVENTED
4
INSTITUTE OF BOTANY, ACADEMY~:OF~-SCIENCES UZBEK-ISSR.

Food Technology
USSR UDC 636.084.52
Z.ES UBO P. M., Scientific Associate, Institute of Botany, Academy of Sciences,
uzw
."Fattening Cattle With Cotton Feeds Supplemented With.Chlorella"
Moscow, Zhivotnovodstvo, No 1, 1970, pp 37-39
Abstract: Cattle fed for 79 days with cottonseed oil cakes and pods supple-
mented With optimum amounts of Chlorella (12-liter suspension -- 15 mLllion
cells/m3)gained an average of 119 kS, while controls.$ained,only 94 kg. In
controls, the rrumber of RBC decreased, whereas in ex-porimental animals it
rose to 800,000/ml, The WBC count rose to 19,OOD/ml l,n controls, but remained
almost constant in experimental animals (7400). Hemo8-lobirt.decreased by 14
mg percent in controls but increased by 24 mg percent.in cows fed with Chlorella
supplement. Addition of Chlorella suspension to.animal feed improved appe-
tite, increased the digestibility and a3similation of iiutrionts, and also
prevented gossypol poisoiiing,

USSR UDC~ 572,214
ZASUHINA, G. D., AESMJ1S1114OVA. V. A. and.,LIVOVA, G. 1C., Institute of Polio-
Moscow
myelitis and Viral Encephalitia6i, USSR Academy of Sciances,
..11The Role of the Reparative Cellular Mechanism in Spontaneous and Induced
Butations in Vertebrate Viruses"
1410scov, Doklady Pademii Nauk,SSSR, Vol 212, No 1, 3.973, pp 223-225
Abstract: The principles of the.nutation process, both sp6ntaneous and induced
by methylmethane sulfc-nate in Western Equine Encephalitis (WEE) virus in
cells.with active and defective reparative systems 4ere studied. Syrian
hamster kidney cells were used to grow the virus and ,.;irall-plaque matpAion~
were measured. It was found that while mutations in t1he defective cells
progressively increased to a large leveli those in the actl e cells rermair,,ed
constzait and small. The mutagen methylmethane sulfonate was also more effe,~-
tive in the defective cells. These results are said to indicate that the
reparative mechanism exerts a specific effect on the mutation process in WEE
-virus.
j,6

I I
. q ( ~ ~ F-- -JIF Cl- -

77
USSR UDC 621.315.592
NESIIELOVA- -1. 11.
BARYSREV, N. S., VOLKOVA, F. P., CHERKASOV, A. P.
WAMOMMOMMAW
"Reflection Spectra of Single Crystals of Cd 11g Te*Solid Solutions"
X. I -x i
Leningrad, Fizika I Tekhnika Poluprovodnikov Vol 6, No 5, 1972, pp 950-951
Abstra6t: A study was made of the reflection spectra of Cd 111 P, _X Te single
crystals as a function of the electron concentration no and the
cadmium telluride content at. room temperature. The s0adies were perforfred on
ri-type single ci-ystals growg by the vertigal zone refining me-thod. The elec-
tron concentration varied from 1015 'to 10~ . cld-3, and rianples were studied
with a composition of x 0. ~7-0.48. For! specimens wit1h an electron concen-
f less than 10 cra , the reflection coefficicrit for fixed wave len-tilis
tration o
increases urith a decrease in the cadmitm telluride coutent in the solid solu-
tion. Thus, the index of refraction increases with a.decrease in x. Obvious
plasma minina were ob erved In the reflection spectra of the specimens witli
n =.5-10-L'-2-1018cs i, by the position and magnitude of i4iich the effective
0
electron nasses were calculated, The tabulated data include the values of the
effective nassess of the electrpns calculated by Eeyn [Canej theory. We experl-
mentally obrained values of ir it r, 0agreeim~witk Lite values calculated by 11.eyr,
.2 11

Orgindt~etall d -C6irpouhds
USSR UDC 547.13:546.72 + 546.14/15
NES. N., KOCHETKOVA, N. S., HATERIKOVA, R. B., PALITSYN, N. P.,
Institute of Metal Organic Compounds,
KSEHZENKO, V. I., and SOBOLEVA, T. S.,~
AcademIy of Sciences USSR
"Reaction of Ferrocene Derivatives With~Bromine and Iodine"
Leningrad, Zhurnal Organicheskoy Khimii, Vol 9, No 2i Feb 73, pp 378-380
Abstract: Reaction of bromine and iodine with ferrocene substituted with
electron donating and electron accepting substituents was studied. At -200
in heptane bromine decomposes ethyl- and 1,1'-diethy1ferrocene; with
1,111",3,31-tet-ra-tert-butylferrocene it forms the tribronide of 1,1',3,3'-
tetra-tert-butylferrocenium. At 500 in benzene iodine does not decompose
ferrocene or its derivatives, forming addition products with various
quantities of iodine. In general, presence of electron-donating substi-
tuents and reaction with strong oxidizers (C12, Brn) favor the decom-
position of the ferrocene ring. In case of hindered derivatives or when
the halogen is a weak oxidizer (iodine) mainly oxidation products are
obtained, with an intact ferrovene ring. 0_xtdation.to ferrocenium evi-
dently preset-ies the system froin,further decompositioa by the halogen.

,7 -412 -,o It UNCL ASSIFrto- 'MCCESSING DATE--090CT7O
~T,171E-INTERACTION OF BENZENECYCLOPENTAC)IENYLIRON FLURUBORATE WITH SODIUM
-u-
...NAPHTHALENE
-~-(03)-NESMEYANOV, A-N-* VU~KE~NAUrN A., SHILOVTSEVA, L.S.
-CGUN
TRY OF INFO-US!~k
~CURC E"DGKL .AKAD. NAUK*SSSR 1970j: 190M 354-6
-,,-bATE PUBL ISHED---70
3JECT AREAS-CHEMISTRY
-%TUPIC TAGS--IRGIN, CUMPOUND, 60RON FLUU81DEs ORGANOSOU PY-1 COMPOUNDi
-NAPHTHALENEt REACHON TEMP'*RATURE, SOLVENT ACTIONv: MPLE C , POUND
~~,G-CNTRQL MARklNG--NO RESTRICTIONS
,'DUCUMENT.CLASS-UNCLASSIFIED
.~P- ROXY REEL/fRAME-1992/2023 SIEP NU--Ul~/k')020/70/19(,'/(.)Oi/035et/0356
CIRC ACCESSION NO--AT0112978
--UNICLASSI-FIE

OIL UNCLASS I FIEO;~~ PROCESSLNG DATE--090CT70
..GlRC ACCESSION NO-AT0112978
A~351KACT/EXTRACT (Ul GP-0- ABSTRACT. THE TITLE kEALTIGN IS: 2(C SU86 H
SUb6 FEC SU135 H SU35)BF SU84 PLUS CC SUBIO H SIA38) NtGATIVE PIJA POSITIVE
RItl4US(THF) YIELDS CC SUB5 H SUB51 SUB2FE PLUS ZC SU66 H:SUB6 PLUS IFE)
_'PLUS ZNABF SUB4 PLUS C SUB10 H SU88. THE.FULLOWING WERE O3SiJ. [RATIO OF
REACTANTS, TEMP., SOLVENTi AND PERCENT YIELD CC SUB5 H SUB51 SUB2 FE
_GIVEN)-.,%j:1, 20-50EGREES, THFt,41; 1:1.25, 40DEGREES, THF, 42; 1:2,
j-5DEGREES, THF-MECN, 61.5; 1:2r 114INUS, .20I)EGREES, rHF-ME
:2( GNI 33; 1:22
2.0-5,DEGRELS,, (MEOCH SUB2) SUB2, 50. WHEN THEREACTION,MIXT. WAS
-TREATED WITH AQ. TL SUB2 SO SUB4~AND KOH.,'C SU85 H,~
SUB5 TL WAS OBTAINED.
fACILITY: INST. ELEMENTOORG., SOEDI N. MOSCOW, USSR.
U X L AS I F 1 -0

112 020 UNCLASStFIED PROCESSING DATE--27NOV70
TITLE-NUCLEAR MAGNETIC RESONANCE.! SPECTRA. OF ARENECYCLOPENTADIENYLIRON
COMPOUNDS -U-
AU'THOR-.(05.)-NESMEYANOV# A.N.* LESHCHEVA*-IF. U S ~T MY U K. iYU.A.1 SIROTKINAt
-r-. N .
E--I'*?- BOLETUVA
:-COUNTRY OF :INFO--USSR
`.--',S OURCE--J .ORGANOMETAL. CHEM. 19 7 0[.3. 689-96,
DATE PUBLISHED ------- 70
1,-SUBJECT AREAS--CHEMISTRY, NUCLEAR SCIENCE AND TECHNOLOGY
~TUPIC TAGS--NMR SPECTRUMt IRON COMPOUND't~ CYCLIC GROUP, COMPLEX COMPOUND,
ORGANIC
PHOSPHATE9 FLUORINE ISOTOPEv ACCEPTO'k
C~ONTROL-14ARKING-NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--2000/2130 ~STEP ~40--t4E/0000/70/022/003/0689/G696
CIRC ACCESSION NO--AP0125714
UNC 1, A S
S I F I F 1)

020 --27NOV70
:22 UNCLASSI FIED: PROCESSING DATE
ACCESSiON NO--AP0125714
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. PMR SPECTRA OF
ARENECYCLOPENTADf FNYL IRON COIMPDS. (XPHFEC SU85 H SU85) PRIME POSITIVE PF
SUB6 PRIME NEGATIVE, tkHOtXC SU86 H SU'~4 MEFEC SUB5 q, SUB5) PRIME
POSITIVE PF SUB6 PRIME NEGATIVEI CC SUB 6H SU96: FEC SU55 H SUf3tt X) PPIME
POSITIVE PF SUB6 PRIME NEGATIVE CONYG. VARIOUS SUBSTITUENTS X HAVE BEEN
STUDIED. P14R CHEM. SHIFFS HAVE t3EFIll CORRELATED WITH THE SETS OF THE
HAMMETT-TAFT SIGIMA PARAMETERS. THE RESULTS ARE (11CMPARED k~ITH THOSE
OBTAINED FOR THE NON-COORDINATED ARENES OR WITH EARLIER DATA.
HEXAFLUOROPHOSPHATES OF RHO 09 ~ltiFLt.)QRCiOlPfiENYLCYCLOPENTADIENYL IRON
HAVE BEEN PREPD. AND THEIR PRIME19 F N'MR SPECTRA !ARE USED TO DET. SIGMA
SUBI AND SIGMA SUBR, PRIMEO OF. THE PEI RANG IN: CC SUB5 Ff SU135 FEC SUB6 H
SUB6) PRIME POSITIVE PF SU36 PRIME NEG:ATIVE WHIC11 DIFiFERS FROM THE
IT IS kSTR'
~UNCOOR-OINAT ED.'PH IN THAT 0,14:G ELECTRON ~ACCEPTOR.
ITY: -ANST. ORG._ELE?4*.COMPD.v ;MOSCOW, USSR
FACIL

~030 UNCLASSI PfED: :PROCESSING DATE--230CT70
OF LITHIUM ALUMINUH HYDRIDt ON KETONES OF BUTADIENEIRON
~TRICARBONYL -U-
--- AUTHOR-.mj 03)_V.,jAZY_AN0V t A.N.t ..ANIS[MgVv~: K*N.i, MAGOMEDOV, G.K.
COUNTRY OF INFO--USSR
~.SOURCE-IZV- AKAD. NAUK SSSR, SER.. KHIM. 1970v Mr 715-17
_.'_~OATE PUBLISHED ------- 70
.....!-SUBJECT AREAS--CHE!4ISTRY
;.-TOPIC TAGS--IRON COMPOUNDt CARBONY.L COMPOUNDw BUTADIENEt LITHIUM HYDRIDEP
ALUM I NUM HYDRIDEt KETONEt PHENOLt ALUMINUM C014PLEXY IR SPECTRUM,
CONTROL MARKING--NO RESTRICTIONS
CLASS--UNCLASSIFIED
PROXY,.REEL/FRAME--1999/1880 STEP NO--VR/0062/70/000/00310715/0717
_.CIRC ACCESSION NO--AP0123668

610 ASS[ FI'Eb' --230CT70
UNCL PROCESSING DATE
ACCESSION NO--AP0123668
~-~-.ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. HOLDING Bbi WITH ACCH:CHCH.,Cli SUB2
T114ES FE(CO) SUB3 (I) IN ETO14.IN THE PRESENCE OF NAOH 2 HR GAVE
91PERCENT CINNAMOYLBUTAD[ENEIRON TRICARBONYLt YELLO'dt M- 74DEGREES.
THIS AND LIALH SUB4 IN THF OR ET SU82:0.GAVE iN I HR
1,PHENYL,3,HEPTANOL, B SU67 137-BDEGREESI,N PRIME20 SUBD 1.5040. LIALH
SUa4 AND BETA IONONEIRON TRICARBONYL SIMILARLY GAVE Ar-TER SEVERAL HR IN
THF SOME 50PERCENT BETA IONOLt N PRIM;:20 SUBD 1.5010. 140 HYDROGElslATION
.,OF THE DOUBLE BONDS TOOK PLACE. THE RESULTS OF THESE REGNS. INDICATE
THAT THE METAL BUTADIENE B9ND IN SUBSTANCES RELAT.ED TO I IS POLARIZED SO
AS TO'PROV.IDE A PARTIAL POS* CHARGE ON':FEv AND TRIS SHIFT OF ELECTRON Do
DOES NOT-RECEIVE FULL COMPENSATION FROM CARBONYL GROUPS, SINCE THESE ARE
ELECTRON ACCEPTORS RELATIVE TO THE METAL,.. IT IS SUGGESTED THAT REDN. OF
LAND--:RELATEG~GOMPUS. BY LIALH SU84 STARTS WITH FORMATION OF
ICON TAKES PLACE ON THE FE ATO'%l AND
'FIGURATIONJN WHICH A HYDRIDE ATTACK
THIE'SONDS OF FE THAT ARE LIBERATED FROM BUTADIENEINOWIBECOME INVOLVED
WITH AL TO FORM A COMPLEX OF THE DIENONE WITH AL SIMILAR To THAT FoRmEc)
GPOUP AND AL IN UNSATD.~KETONES. THE C04PLEX PERHAPS ALSO
HAS 13ONDS OF~KETONE GRUUPING TO AL9 SINCE THE REON. OF THE KETONE GROUP
IS,SlMULTANEOUS WITH aEDN. OF THE.METAL TO L.IGAND BOND. THIS IS FURTHER
-S.UPPORTEDIBY-LIR SPECTRA* FACILITY: INST.~ ELEMENTOORG. SOEDIN.j
a owt USSR.:
m
sc

CONTROL MARKING--NO RESTRICTIONS
60CUMENT CLASS--UNCLASSIFIED
0;0()XY REEL/FRAM.E--2000/0766 STEP NO--UR/0062/70/000/003/0727/0727
CIRC. ACCESSION-NO--APOI.24436 -LA ------

71 _7,7 ------
~~721_2 Oil UNCLASSIFIE6 PROCESSING DATE--230CT70
'CJRC ACCESSION NO--AP0124436'
-A8STRAr..T/.EXTRACT"-(U) GP-0- ABSTRACT. UV IRRADN. OF
TETRACARBONYL AND CYCLOPENTADIE14E MONOMER IN
.PWANE~ 2 14R AT REFLUX GAVE 77PERCENT
P1,CYCLOPENTADIENYL)NIOBIUMi M. 77-80EGREES.
,-:.~CYCLOPENTAOTeNYLOICARBONYL,(
_1_ _.~-SIMILARLY WERE PRED. C SUB5 H SUB5 NB(CO) SUB201ENE COMPLEXES FROM
!~.BUTADIENEIF ISOPRENE AND CYCLOHEXA 01 ENEr AS-, WELL ASICYCLOHEPTATRIENE
w~~`(WHCIH CORROINATEO LIKE THE DIENEY., FACILITY: INST.
-,._~zELEMENTOORG.. SOEDIN., MOSCOWt USSR.
1 4 C L ft I IF 21f -
I u

112 017 UNCLASSIFIED.. PROCESSING DATE--230CT70
--..T-ITLE--EFFECT OF THE REACTION COND,ITIONS20N THE INTERACTION OF C SUB5 H
FEICO) SUB2 AR WITH PHOSPHINES AND PHOSPHITES -U-
AUTHOR--(03)-NESMEYANOVt A.N.y. AAKARQVA,~L.G., POLOVVANYUK, I.V.
'tOUNTRY, OF INFO--USSR
'~~":~SbURCE-J. ORGANOMETAL. CHEM. 1970# 22(3)t 707-12
ATE PUBL ISHED ------- 70
'-SUBJECTS AREAS--CHEMISTRY
~,TOPITC TAGS--ORGANOIRON COMPOU.ND# PHOSPHITE, ORGANIC PHOSPHORUS COMPOUND,
PHOTOCHEMISTRY
--CONTROL MARKING-40 RESTRICTIONS
JDOCUMENT CLASS--UNCLASSIFIED
,.:-PROXY REEL/FRAME--1997/0615 STEP NO--NE/0000170/0.?2/003/0707/0712
CIRC-ACCESSION NO--AP0119527
~Z T T_- T T Ti

2/2 017 UNCL ASS IF I ED Pr%OCf':5S I NG OAT[:-- 2_30C f 7 0
CIRC ACCESSION' NO--AP0119527
'.,''ABSTRACT/EXTRACT--(U),GP-0- ABSTRACT. THE REACTION OF C SUB5 H SVB5
FE(CO), SUB2 AR 1,11TH PR SUB3 L) o o
IN BENZENE. IS INDEPEN ENT F THE NAUTRE F
~._~-._ARYL GROUP AND THE PHOSPHINE, BUT DEPENDS ON THE REACTIO,"! CONDrrioNs;
THE PHOTOCHEM. REACTION GIVES C SUB5 H SU85 FE(CO)(PR SU83)AR, AND THE
THERMAL C SU135 H SU135 FE(C0)(PR SUB3)COARt THE REACTION OF C SU35 H
FE(CO) SUB2 AR WITH Pt OPH) SU33 I S.~ AGAIN INDEPENDENT OF THE imATu"tE
OFTHE ARYL GROUP BUT DEPENDS;ONJHE REACTION CON011TIONS.
FACILITY: lNST. ORG. ELEM. COMP1)*j..mOsC0Wt U$SR*

UNCLASSIFlEb;. PP.OCESSING- DATE--20NOV7C
:,...-.T:ITLE--SYNTF,ESIS OF 6XLVI~11YL MEKCUK.Y -DER::I'VArivts -u-
~~-,-.'A'UTHOR-103)-.'VESAEYANOV, A.,"i., kM NSKAYA M. IPOPGVA, T V
XUNTRY GF' 'I 'FC--Z-USSft
'6URCt--ILV. AKAD.. NAUK SSSR, SER. KHIM.'. 14)
94~,-B.
.,.'.~DATE PUBLISFEC ------- 70
SUBJECT AREAS--CHEMISTRY
TGKC SYNfHESISs OKGANOMERCURY COMPOONUP ISON~AIZAT1041
(I'l 'Olt-YOUND tH L 0' 1 N A T HO GRGAN I C 'Cd ti POUN Q td EN I CN E
J I NATED WANIC G
-UERIVA-TIVE
-.CCNTPGL *4AkKfNG--N0 RESTRICTIdNS
QOCUM C .1.4 TC L A!., S- - ONC L A SI F f E D
PROXY R k L L AM L- 3 0 0 b13 1 srEv

J,
2/2 01C UNCLASS IF HED p,-; rCCSS[jjG UATE--, 0 NOV 10
I PC ACt
A,'. S T A A C 'r HLA r I N6 AACIA:~4:Ch,'A WITH 3 ;-1',, L E S
~M L Pi'C(JC Ii:(;HI ; AR IS IM 4. ~7-3utf.RELS;
IN SU82 CIJ 3 jl;~ GAVL
P 9 s",I E C SL;6crt SlitAt Pl. (jGt-GPEES.; P,CLC SUB6 H SUB411 oi btt-51jk~G,~H:S; AND
P,BR-1 SUBC-~ Ff SUB4, ;-I. (j6-7DI:-G1%C-ES. T H E S E~ I L L U M I W'a L D w, i *r I I U V L iG H T I I'l C
CFIjjj~I ; AV. E
SUBb, H SUb6NLGATIVE HG 'JUSPENSION 3-4 Ilk GAVE ARCal-Li, -~UALS
:PHt M . 110DI]GdEES; PiP',tC SU66 11 SU64 M. 107-8()EGYRF-4:,~; 1040 P,(,LC SU36 H
EGRELS, IN 78-9oPFR(;FNT YIELUS. :S~MIUALY WAS PREP0.
~SUB 4 M. 117-18D
A. C C L F, F G 1. t M, . d 3 - 3 5 D E 6 i~ ~- E S THE: PRODUCTS 4CRE' PUfq1,F1ED 6E:3r otri AL SU32
O:SL,83,: AT TIMES SHOM.-NG THE 2.GEOMETRI(; ISGMETRIC. FUAMS, GF 'AHICH ONE
FACILIT~ INST. ELEMENTOORG.
WAS. GENER'LLY GREATLY PPLDUMINANT.
S0EV,1 h MUSUW, USSR.
I F I L D -
-A~

2/2 Oil UNCLASSJFIED~ PROCESSING DATE--04DEC70
~.CIRC ACCESSION NO--AP0140354
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. REACTION IN 1:1,2:1.2 IMOLAR RATIO
OF CH -SUB2:CMECf4E:CH SULIZ) SUB2.FE[CQ),.SU33j ACCLv AND ALCL SW33 OR IN
Il.2:Z*4 RATIO WITH AC SU32 0 AND ALCL~ SU83 1. HR AT 0,0EGREES GAVE UP TO
5708DEGREEES. ITS
82DEGREES CH SUBZ:CMECME:CtiAC.FE(,CO) S1063j YELLOW,: 14.
-FORMAY[ON WAS MUCH MORE FACILE THAN THAT OF THE BUTADI~-NE ANALOG, OWING
'INDUCTIVE EFFECT. OF. THE 2- HE'GROUPS.
TO. THEPOS* FACILITY:
INST ELEMENTOORG. SDEOIN.s MOSCOW:r USSR
t X cr -1 it r i: rl
~99,9

-1/ 2 029 UNCLASSIFIM Pi,'.OCESSING DATE--18SEP70
..",-T..ITLE--PHOTODIS.PROPORTIONATION OF ARENE'CYCLOPENTAD'IENYL
[RON COMPOUNDS
_'.~_:-AUTHOR-(03)-N~~~ovl A.N.v VOLKEPAU, N.A., SHILOVTSEVAp L#S.
'CUNTRY OF
INFO--USSR
SOURCE--DOKL. AKAD. NAUK SSSR, 1970f'J90(4)t 857-9
PA E PUBLISHED ------- 70
-CT-AREAS--CHEMISTRY
--s-UBJE
--IRON COMPOUNDt ORGANIC
_'TOPIC TAGS FERROCENE UV RADIATfON, SOLVENT,
ABSORPTION 'SPECTRUMt PliOTOC HE MI-STRY BORON FLUORIDE, FURANr
D 10 X AN E ,ETl-lYL ETHER9 ACETONITRILE.
'_t %.C0NT:kOL MARKING--NO RESTkICTIONS
i~:IDOCUMENT CLASS--UNCLASSIFIED
'PROXY REEL/FRAME--1984/1562 STEP NO--Uk/0020/70/190/004/0857/0859
CIRC ACCeSSION NO--AT0100180

---18SEP70
~2/2 029 UNCLASSI F [ED PROCESSING DATE
C_: L.R CACCESSION NO--AT0100180
GP-0- ABSTRACT. UV IRRADN. OF C SUB6 H SUB6 Fc
~SU!35-H -SUB5.?,F SUB4 YIELDS UP TO 10OPERCENT FERROCENE, FREE AROM.
HYDROCARBONt AND INORG. FE AS- FE(BF SUB40 :SUB2. THE FOLLOWING PERCENT
OBSD. rN INDICATED SOLVENTS: THF 76; DIOXANE
YIELDS OF THE REACTION WERE
~: - MEOPH, 0;~ETOAC, TRACE; MECNt
42; (CH SUB2 OME) SUB2 15; ET SUB2 0 10,
20; ME SUB2 CO, 15', AC SUB2 Ot 8; ACOH'I 0; H SUB2 01 TkACE; .14EOHY 0;
ETOH, 0; C. SUB.6 H SUB6 TRACE; PHNH SUB2, 3; PYRIDINE, Z. THE YIELDS
WERE 0- IN PETROLEUM ETHER, AENO SUB2, ME SU,32 NCHO~, ME SUB2 SO,
MORPHOLINE, AND PIPERIDINE. NO D.LRECT CONNECTION BE.TWEEN THE ABSORPTION
SPECTRUM OF THE SOLVENT AND ITS REACTION EFFECTIVENESS WAS OBSD. THE
FOLLOWING PERCENT YIELDS OF FERROCENE FROM SIMILAP DISPROPORTIONATION OF
ARFEC SUB5. H- SUB-5 C.ATIONS, WERE_._OBSD.. UNDER.. THESE CONDITIONS. (RUN IN
THF): C SUB6,H SUB6t 42; MEPH, 32; 2t5-ME SUB2 C SUB6 H SUB4, 30;
:,:-1,315-ME SUB3:C SUB6 H SUB3, 20; CLPI-ir,30; MEOPH,.25; HO SUB2 CPH, 30;
WITH ZERO YI'ELD FOR Aft EQUALS PH SU62Y ETO SUB2 rPH, PHCN. THE
FOLLOWING PERCENT YIELDS WERE OBTAINED WITH ANALOGS: lt3t5-ME SIJ133 C
~SU86 H SUB3.-FEC SUq5 " SUB4 ET PRIME POSITIVE-0; C*.SUB6 H SUB6 FEC SUB5
'H-S
UB4-PH PRLME POSITIVE 48; C SUB6 H SUB6 FEC SU65 H SUB4 CL PRIME
POSITIVE:20; 1*395-ME SUB3 C SUB6. H'SUB3 ;FEC-SUB5 ',H SUB4.AC PRtME
POStTIVE 5PERCENT. ALL REACTIONS WERE. RUNE 1IN DRY ,ARGON ATM,
u L S S -11~1-EJY-

s
USSR UDC 542.91:547.257.2:547.514.72:546.725
NESMEYANOV, A. N., KkKAROVA, L. G., and VINOGRADOVA, V. N., Institute of
Metal Organic Compounds, Academy of Sciences USSR
"Synthesis of a-Ferrocenyl and a-Feirocenoyl Derivatives of Iron and
Tungsten Cyclopentadienylcarbonyls"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 12, Dec 73,
pp 2796-2798
Abstract: Reaction of ferrocenyl lithium with n-cyclopentadienyliron-
dicarbonyl brumide yields Tr-rycloperitadienylirond:Lcarl)c)nyl-a--ferrocenyI
(1). Ferrocenoyl chloride reacted with ir-cyclopetitad:LtinyliroadicarbonyI
sodium gives it-cyclopentadienylironaicarbonyl-(;-ferrocanoyl. Respective
tungsten derivatives were obtained in an.analogous manner. Decarbonylation
of-the ferrocenyl-tungsten complex by heating:yields cyclopentadienyl-
tungstentricarbonyl-a-ferrocenyl.- The iron complex requirea,more drastic
~cond
itions and some decomposition takes place in this:reaction.

USSR UDC 542.943:547.257.3
NESMEYANQY_,h,_-N., LEONOVA, Ye. V., KOCHETKOVA, N. S., RUKH-LYADA, N. N.,
and BYCHKOV, N. V., Institute of Hetal.Orgahic Compounds, Academy of
Sciences USSR
"Oxidation of 1,1'-Diethylcobalticinium Hex.afluorophosphate"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimiches~kaya, No 12, Dec 73,
2791-2792
p
p
Abstract: In presence of excess lKMn04 in acid medium the hexafluorophosphate
of 1,1'-diethylcobalticinium (1) is converted to the smlt of 1,11-diacetyl-
and 1,1'-dicarboxycobalticinitil. Other=idation agents such as Mn02 and
C 03 in acidic medium fail to react with :(Ill.
r
20

~'Food TtchnoloV
UBBR
RESWdIAMM, AI-N., AcademLcian, Director of the Institute of Hetero-Organic
qccqN=ds of the Academy of Sciences USSR
"Our Food: What Will It Be Like?"
Moscow, Leninskoye ZnwWa, 22 APr 73, p 4
Abstract: While agriculture is capable of supplying carbohydrates and fats,
at1east one bal of the world's people do not get enough protein, tine only
component of food which gives nitrogen. In view of the fact that even the
best protein foods, milk, eggs, and meat,*are the products of the animal stage
of -the food chain and during this stage large percentages (75-9CO) of the
original- protein in the animals' feed is lost, the question has naturally
arisen: would it be more economical to derive the protein directly from the
feed and use it as food. A method has been developed in Englmnd for extracting
protein from grass and making milk and cheese out of it, and similar experiments
have been conducted in the United States, The costs of producing such food are
substantially lower. Industrial production of yeast protein is most promising;
in the USSR the production of yeasts is increasing.rapidly and irill reach 1
million tons in the next decade. At the - Institute of Hetero-Organic Compounds
a cavitation mill suggested by S. V. Rogozhin is used to-extract Drotein from
1/3

U SS R
IUMMYANOV, A. X., Leninskoye ZnaiMm, 22 Apr 73, P4
yeast. Another method, developed iointly by the institute and the All-Union
Scientific Research Institute of Biosynthesis of Proteia Substances, involves
extracting amino acids from the yeast and collecting them together with larqer
protein fragments on an ion exchauger. Both prepaxations are the nutritional
equivalent of meat and offer a realistic4raw material for food during the cur-
rent five-year plan and the next one. Another method involves synthesis of
replaceable and irreplaceable amino acids. These acids can be given to patients
with specific deficiencies, but their use in normal food is a task of the more
remote future. Conce:rming the taste of synthetic foods, all four distinguish-
able taste nens-stions can be developed. - Odor presents n more complex problem.
The. composition of food odors can be anal,)rzed with current chromotqjraphic
equipment, but they contain dozens of components and creating synthetic odors
vill be a labor-consuming task. In the United States, a protein solution is
spun" in a way similar to that used with synthetic yRrrt to reproduce ths., tex-
ture of meat. In the USSR a simpler method in being employed of manufacturing
articles with hmnogenaus structure,~ such as sausages antL filling for "pirogi"
(meat-filled -pastries] - This overcomes the problem of taste and odor, and
there are many products in which protein additives can be used, such as candies,
j JeUies., and fruits - Today the world has entered the 4te of synthetic foods
just, as,, some decades ago, it, entered the age of synthetic fil)ers. But there
W3

PFF
~ ---
I . ~, I I I [III III I[ I. - :. I I "

USSR UDC 542.957:547.559.77:547.559.78:547.1'118
NESBEY USTYNYUK, N..A., BOGATYREVA, L. V., and MAKAROVA, L. G.,
Institute of Element Organic Compounds,~Academy:of Sciences USSR
"Reactions of the Phenyl Derivatives of, the Metal Carbonyls of Molybdenum
and Tungsten With Triphenylphosphine and:Triphenyl Phosphite"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1, Jan 73, pp
~62-67
Abstract: The products of the reaction of (I) with P(C6H
V05W(CO)3005 5)3
and P(OC H )3 -- e.g., C H5W(CO)2LC6H +C0. ". W(Co
5 5 2)LCO C6H5; or
W(CO)3L.Pf ) + (C6H5} -- depeni.on the condition. (L is either of
the P llgands~. A series Of C31 to C57:phospho derivatives of W and Mo
were prepared and characterized by,physical data, elemental composition,
and spectral and NHR data. Stereochemistry,:exchangq,of the ligands, and
'the effects of a limited number of solvents were considered.

5 BA 9:47. lar5.9
USSR UDC 541,41047.1,5
MIR FRYAN OV A
101A, rt'. a., I=Vyyji V. V. It s1 NA A 11. FR,'OT-
RUG,
BERGIK. I., and SPlYSIM, E. I., Noscow.Stuxte Univarni~y imnl 11. V. DX71071o5ov
"Triphenylphosphine "'Somplexes of Banzyl- :,and Vinylgold"
restiya Akademii Nauk SSSRO Soriya Xhimicheskva, B
Moscour I z,,
'o 3, 1972,
pp 653-654
AbQ-tractj Alkyl and aryl compounds of monovualezit gold rioce st-,O)lo only In th(
~form of tripheiiylphosphine complexes. Them benzyl :coripovncl imB syrithealzed
according.to the mation
I C H -OIL Au P (C6R )3
005"12"f9C1 + P']' AU P (C615 5 2 3
The yield waz 85% ih toluene and 40%.in tetrahydrofurano The mrar eprct-ma of
ndicated a proton signal in the phenyl ,;map (in the range of
the product I.
6.9-7.3 m.d.) anct two signals.from tho zathylena~ -,x-oup (in -Wba range ol
2.54 to 2.76 m.d.). By usting the double nucloar ragnotic rescnance of 31,
it was shown that the interaction of the proems from thtt Eethylcna group ultb
phosphorus caused peak splitting., The vinyl conpowid irz~* obtained f-rola the
reaction
VIF
CH2 CH14,,zBr + C1 Au
P
CH Att P (V
06115)3 t5at C'12 65 3
50
The yield was 90%. 1/1

USSR UDC.51d. 124041.571541.10 OLrl .514 72 1446.
OVA, L. G.j~aad,F0LUVYAIIYUK, 1. Institute fo--
HAKU
-UffgaYa---E3.ezdnt9.L uoxpowids, Academy of Beiences WSH
"The ~Infltwnce of the flatuxe of the Phosphom UeAaid oit the ChiLracter of
wriding LirimjdB in 0"'-Aryl
InteractiozBetueen the Central Atom and the:Surrc ;j
:Cyclopontadienyliron CarbonylVonplexes"
Moscow, lzvestiya Akadeial-I Nauk SSSR Seriya, kldmicheshn~~,
NO 3, 1972,
Pp 6o-,-6og
Abstr4ett DurIng the sttbiy of the ch~&mctoristics d, CY'-ai7l cyclopentQ, ien'yl-
iron carbonyl ca.-aplere.5, tre omixmired the :~afluev--ca of -ffi,'i Ilattr-'a of the plxz-
phorms ligand on the character of t h -a intoraction of t I vq irron atc~.R uith thr,
carborkyl and ligands, To do ti-As, a series of fluomp-henyl conpIc-xi.,s
of tho type Y?O(Co) W COV -Plfp Here: synthesi.-ted whove L (C6"5)3
Pe 0":C4, Wtj3NI
Ma CO. The IR ard nmr
narle , Xn the IR spoctra7j
P(OC6115
fo= Is 19271 1963 and'P~018 fo:r th%3 III)OVO "I" sorlozq iind
for th6 meta
0 The m- ipoct2~a of F'19 shoved
for '-be para. f -rrz, 1925; 1049; 1961~ 2015.
p- Nmales of +4.47p +4.29p +2o35 for tho: meta fo:r-A &nd +1:3.634, +4,3A0, Z~-rA-
+10.95 for the para form. The carbonyl group c--x act ar, a dazior throu--h both
induction aria res-onance. The aryl howeverp pLixtielpa-t o only thz-ou&h
induction, 1/1

Y,
SOPM rOINTr OP GROWTIi OF ORGANIC CIMPUS-MY
[Report of Aeademlcian Moncow, V,~- Ak.i-
M.n-Lik ~-rS-_P%jr;rA 41, No R, AiicUZ~t !Q';-A, ~!S_1111
In it brief report otie can spnaL only of a few iragments
of or anic chemistry, arbitrarily relected fr". many Dos5J b1 e
. 9
onoa and qi-:cn on at bimar a :;:zzallt at.tjme~. a very, large plane.
Organic chemistry is the structural architecture of IroliTcules.
Everything therefore will be subordinated-to structure and trans-
torptation in their interrelationt;. The Arrangement . And rear-
r;nge ent of.. the' carbon skeleton I:; them main ta:it in syn-
t .i and hydrocarbons. form the '~sta,~^Unq ra-w material and clars-
-on group'of' comp,,iunds4 natural-to start wtth It.
n of the Academy of Sciences USSR
In 1912, at the zessio.
dedicated to the .25th anniversary of Soviet power, It fell to
me-to P.1asent:a report on organic chemistry- in Une USSR durrinq
tt 25 ars., I bcfjan it with thf? which
'Led - itiatporary re-solts, of inv -,ti , tio~nz 1% D.
sIt up the co; ga of
7
Zzelinskiy and his school.on heterogenic csi:31ytic. transformations
of hydrocarbortz~. That work had "revived chamizitl corp-jes,,* in
he expre!~.,;ion of Zellmskfy, pcbroleum, hydrocarbon-_ and had
~~4:;[L~,rnnnform-d them Into plastic n~lterjal. Along with pyroly;;Ir-,
and al)vyldtlon of olefinn those reactionz scvved
racking
o5 the foundation of petrochemistry. and pptracl,~!nia-
. I n, aromatl=ation, ring scl5sion, and dehydrogenation
-...into olef ns and e-iolefins, achieved by Zelinskly's school, were
_,/'studied exhountively in the works of 5. A. Kazan:0--ly, A. A. 13,5-
olandin and their pupils. llydrocarbons of certain typej of 2truc-
tures eithor &re used an nuch (viirlous fuels, poly neri na t i on In-
to polyethylcn(i, polypropylene, rubbers, etc) or or*, tranaforinrd
nto their derivatives (containing halogen, oxygen, nitrogen,
7~ tc)
AC In recent years polyhedral hydrocarbons have pro,.ren to
be on the crest of the wave of chemical science. Those closed
3D
7

0119W030tkIlloi COOPM d~
USSR UDC 247,13
PEREVALOVAl Be G., LEWNOVSKIY, D. A. GRANDBERG , K. I., band
Ndscov,State University imeai Me V.: Lomono,so.y.
.*Ferrocenylgoldtriphenylphosphine Complexes With Nonovalent, Gold Salts"
Moscow, DoklaAy Akademii, Wauk SSSR, Vol 202,:No, 1, Jan-Fab 72, pp 93-96
Abstracti Reacting hydroborofluoric acid with forrocanylgoldtriphenylphosphine
(I) yields the borofluoride of (triphenyl-phdsphinefoxTocen!rlgold.)-triphanyl-
phosphinegold (II). Excess of HBf4 shows no particular effect on the reaction
course or on the yield. PMR spectrun of (II) resembles the spectra of ferro-
cenylcarbcations, The data of 1[1qR and UV spectroscopy indicate that a consider-
able positive charge is located on.the goldatom next to tho cyclopentadienyl
ring in the compound (N). Compound (II) is believed to to aonovalentC. gold
borofluoride bound with two stabilizing ligandSL- triphemylphosphine and ferro-
canylgold triphenylphosphine; the positive:charge is eviclently delocalized
between the gold atoms. Compa=d,(11) Is also obtained by reacting (I) with
(C H Fe+BF - NO +BF - CH C&BF -, except.that with these reagents their
-4 2 4 4
excess lowers the yield of (II). Reacting (X) with concentrated H2SO4 produces
. ..........

7777 7 -7~ 71~~v~'
. . . . . . . . . .
UDC 5,47-13
Academician, POSTNOV, V. N. Lsswmu I. F., S vf?xov
. ..... . . . . N V; Lozonosov
4-1 TOVA, V. A., Moscow State~Universitylzenl
fol
pirrocenylviny1carbonium Ions"
~.-)Joscow! Doklady Akademii Nauk SSSR, Vol 200, No,4, 1971t,PP 858-861
.-'Abstractt The vinylog of the dipheny1ferrocanylearbonlun ion.during its
under goes an allyl shift to give an q4errocenyl~arbonXum ion.
~Since..thelp-dimethylamino group is a strong carbdnium ion steLbijizer, the
-i-.;authors.undertook to compare the paxt played by the p-dimethylLaninophenyl
and - ferrocenyl groups simultaneously in the . stabil.1 zat, ion of the allyl cation.
-The! tetraphenylborate, of the Vi log of p-dlmetbylaminodiDhetWlfer=cenyl-
~Py
-,.:.'~'=bonium:was obtained.from P -forrocenylvinyl-!p-dimethylaminodiphenyl-
',,.~~'.carbinol by.procipitation-with sodium tetraphenulborate in glacial acetic acid,
~`The salt.was bound by its ()(-=bon, atom (relative to ferroc6ne) )Kith
'-`:"dimethylaniline.in the p-position. To determine thestructure.of the resul-
carbonium ion,.spectra were taken of its saltsi- tatraphenylborate and
borofluorldet, rum Of nylvinyl-'! dimethyl-
as well as the spect ferroCe P-
azinodiphenylearbinol, The resulis.indica~ta th4t the allyl cation reacts
--4/2

Ref. Code:
e 100859s Metalation of dibenien"hromium Od some of its
-'e .
homoilogs. IN Levchenko
panov A. IN.;, Vur - va. L
S; 11
1. _W Dokl.
(Inst. UAMUi~,.,
oscow, USSR)
Akad..,Vauk JC~hemj1(FUss). Treat-
ing 4.3 g BuLi ih' (CHjNNfe%)t-heia~e over 4 he ~ with: 0.67 g
dibenzenechromiutii (1), refluxing 2 hr,. and adding 46.7 ml, Mel
with ice coolin MeJ3
gave a small am't. is6meric xylcn~s, h, and
1,2,4- and 1,3,5-MesCsHj;. it.;similar, reattion~viith d4oluene-
chromium (It) . and di.t~-xylinechrbmiwh (111):, jave similar
The 1st tiatom ent&i 6_hly-th-
results. benz6fe -ring ond the
Me group is unaffected fil renciien of1l; ~ the 2nd1i atorp tnters
'the benzene ring preddininantlk also.; but: ' il!it doer attack
some 0
the Me group, yieldinj 1,2#4-:s~d: 1,3,5-Nle4t~liw as'wpll as
isomeric rnetllelylbenzenes.~', ~The-fvle.gioup;;directs the Li
atom to M_ ng. In reaction ar III the
an# riitiahs of~ the. i
1.3,5-isomer 'predominantly dso., G.M. Kosolapoff j
d
REEL/FRAME
_49801811

Organophosphorous Compounds
USSR UDC 541-49:547-558-1:541-1113
ANOV, A. N., NERWALOVA, E. G., BAUKOVA, T. V., GRMDBERG, K. I.
."Triphenylphosphine Com
plex of Cyclopentadienyl (Yanganesedicarbonyltriphenyl
phosphine)~Goldll
Moscow, Izvestiya Akademii Nauk SSSR, Seriya K.himicheskaya, No 11, 1973,
2
641-2642
P
P
Abstract: The triphenylphosphine complex of cyclopentadienyl (manganesedicar-
bonyltriphenylphosphine) gold (11) was obtained.
PI
abou sva
CO C'O i-O CI) CO 11PI13
The structure of the (II) complex was established on the basis of spectral data
and.confirmed by the chemical behavior of the compound. -In the infrared
spectrum of (11) a shift of the two intense absorption babds of the GO groups
toward the long-wave range is observed by comparison with the spectrum of
1/2

T~
USSR
NFZMEYMIOV, A. N., et al., Izvestiya Akademii Nauk SSSR~ Seriya Khimicheskaya,
No-11, 1973, pp 2641-2642
cyclopentadienyltricarbonylmanganese (I). This usually occurs on replacement
of the CO groups in the eymantrene bya stronger electron-donor ligand
sanov, D. N., et al., Izv. AN SSSR, Ser. Khi.-a., 2842,~.1962/. In the Para-
ur,
L
magnetic resonance spectrum of (II) signals are revealed from the protons of
the phosphine groups along with two multipleths of the protons of the substi-
tuted cyclopent"adienyl ring shifted to the stronger field by comparison with
the signals in (I). In the nuclear magnetic resonance spectrum of 31P of (II),
two signals of the phosphorus nuclei from nonequivalent triphenylphosphine
groupings are observed.
When (II) reacts with concentrated hydrochloric acidp ('III) and tho tri-
phenylphosphine complex of gold chloride are formed.
Hal
Q.,
-AW11IN
\IT./
CO 0 P1,11i
CO CO PPI13
The complex (II) in less stable than (I) especially in solutions, and it decom-
Poses during chromatographic studies in acolumn with alutainum oxide in contrast
ta
2,/2

Organori6tallic Compounds
USSR UDC 542 -944:546.114:547 -258 - 11
NESIGN YANOV A. N. CSHr
NOMA, 0. V., DROGUNOVA., G. I., and WY IT', B. V.,
iatero-Organic Compounds, Academy of Sciences USSR
omination of PentameVnyleyelopentudienyltitanium Tribromide"
Moscow, Izvestiya Akademii NaWk BSSR; Seriya Miimicheskaya, No 2, 1973,
pp 406-410
Abstract: Studies were conducted on the reactivity of the titanium-cyclopenta-
dienyl bond as influenced by the substituents on the cyclopentadienyl rings.
PentamethylcycloT)entadienyllitanitLn tr,"bromide (I) was obtained by dropwIse
addition) with mixing, of 8.8 g of acetyl bromide in 4 rA hexane to 7-7 9 of
C in 7 n1 of hexane. Ihe:crystals for-"-IKL ovei-night represented
5 (CH3)5'T' (GC2H5)3
a Oldo yield (9-36 g) of c Br , m.p.' 242-2560 (frorn hexane), and were
5-(CH3)5T' 3
dark-red. 11he synthesis and other experiments were cond-.wted in an atmosphere
of inert gas. I was characterized by IR, PMR, and '219411 spectroscopy. The sub-
stittetion of a single bromine atom for a hydrogen atom in a methyl group was
achieved under the folloving con(Litions: 1) 2-34 g of bromine was added ,dth
mIxing to 5 9 of I in 250 MI of CC1) - Me mixture was irr~vliatad with a 220
watt lfg-quartz lamp for 10 h at 45-;)0') at 6 diotance of.-,f50 en'; the yield of
1/2
1 1-11.1 AHAI I.;-i t 1~. 11

USSR
NESMMINOV, A. It., et al., Izvestiya Ak-ademii Nauk S3SR, Seriya Rhimicheskaya,
No 2, 1*6-41o
'1973, PP
: C5(CHJ-)4CH3 BrI TiBrPi) was 4M;.2) II could also be obtainedwith an excess
of bromine and longer erposure times in 48% yield. Bromiftation of I could also
be obtained with N-bromosuccinamide in the presence of eil;her azodiisobutyro-
nitrile or Of irradiation; the respective yields were 13 =d 28~i. Introduction
of even a single bromine atora into I Yro-l-kedly alters the reactivity of the
tits-nitun-cyclopentadienyl bond to nualeophilic reagents. Ethanol was capable
of breaking the V -bound ring of I! even after a few minjites at, room tempera-
ture. - The data indicate that in addition to breaking the Ti-Crz(CH-2)jLCH2Br bond,
there occurs dehydrobromination of the organic fragment of thejmol~c~].e vhich,
apparently, results in fulvene forration.
2 /P.

WSR UPC 547 P-4i
19 k WJA LO-V A, -11- RYBIN, L- V., GUBMO, N. T., PETROVSKLY, P. V., and
EMNSKAYAt H. L., Institute of Zlemetts~l Organio Compo:unds~Acadezy of
Sciences USSR
"The Reaction of Triphenylphosohine with Iron Carbonyl Complexes of
-Substituted 13 -Unsaturated Kbtones"~
Leningrad, Zhurnal Obshchey Xhimli Vol 42(104), Vyp 11, 1972, pp 2473-2477
Abstract: It was shown that the stability of the metallignad,bond in mono-
complexes of iron may; be deterained by the reaction of the com-
olefin
plex with triphenylphsophine suoh as in the fOllowing z
catibrocil=UX + (CG115)3P +
k(coh
+
0 1,Fe(GO)2"(COU6)3
4) X Coe. It,, 6) XCOOCI 4.
1/2
-13

USSR
WZMANOVt A. N. et al. Zhurnal Obahch Dimut Vol 42 (104) Yyp I I
ey
1972, pl? P-473-2477
The reaction of trans dibenzoylnethylene and trans metbyl esters of 19 -benzoyl-
acrilic acid with triphenylamine in methyl alcohol andbeptane in room
mme ure eating-to.60-70*0 resulted in the replacement of the CO
ligand with the formation of couplexes 11 andp III above,. The order of
Ancreasing ease of oubstitutions:of the ligWAS I$
-CO-CH-CH-CO CO -CH-CH-Co-.
x can seen a a re aa 0 C
Vith the increasing strength of the aoldz. Structuxes uere confi=ed
by: IR wA NMR spectra.
2/2

Or&io~
USSR UDC 542-91:547.1'13:546:72
M"~w ,No, MAKAROVA, L. G., and VINOGRADOVA,, V. N., Institute of
Le
organic orrpoiands, Arad. Sc. USSR
Synthesis and Properties of")T-Cyclopentadienylirondicarbonyl- 6-ferrocepyl"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya, Khimicheskaya, No 7, Jul 72,
pp 16oo-16o4
Abstract: Reaction of diferrocenylmrcury vith.cyclopent,,.Ldienylirondicarbony1
iodide yields Ar-eyelopentadienylirondicarbonyl- 6--ferrwenyl (I) -- a
crystalline co=ound of orange coloro 'In solid state it is stable in air,
dissolves easily in organic solvents, but the solutions ai.-- less stable. The
structure of (I) was proven by IR, PMR and XGR spectroscopy as well as by
react
ions with 017 bromine, and mercuric chloride. Reaction f (I) with
-evidently one 00 group being
_(C6H P takes place without rearrangement,,
replicad by (C6ff5) P.
3
7
L__L

'G
,03T 1:
cLASSVFlED-, OC~~S S I -N DATE--020CT70
um PR
R
T.ITLE-CHEMICAL EFFECTS OF: EL~CTRO*l C;APTURE.; BY CERTAIN IDDIVE-125
tOMPOUNDS STUDIED BY THE MOSSBAUER~EFFECT 0 NTELLURIUM-122,15 -U-
""A UT IQ R E.V.~, LEBED EVv V A., NESMEYANOV,
--~-,(.04)-BABESHKIN, A.M. 9 LAMYKINv~
`-A fN
C -OUNT R YOF. INFO--USSR
I I (J) 117-1a:
'~-'SOUNCE-VESTN. MUSK. UNIV. KHIM. 19701
Q AT 8PUBLISHED ------- 70
,:,:S U 8J E C, TAREAS-CHEMISTRY
pIC TAG,S--SPECITROSCOPIC ANALYSIS, MOSSBAUER EFFECTp TELLURIUMt IDDINE,
ROZEN-FLOWt NITRIC ACID* AQUEOUS SOLUTION', ELECTRON CAPTURE
C 0 N T Rif) LMARKING--NO RESTRICTIONS
7 00CUMP47 CLASS--UNCLASSIFIEO
PRUXY,RLEL/FRAME--1989/06I5 ~STFP I J./00 1 /0117101 18
CIRC ACCESSIUN NO-AP0101212
UNC LASSI F [ED

0,37, UNCLASSIFIED PROCESSING DATE--O?OCT70
ClIRC ACCESSION NQ--AP0107212 4
ST.RACT/"-zX TRACT--(U) GP-0- ABSTRACT. A STUDY WAS MADE OF THE MOESS5AUE-4
'EFFECT 'OF RRIME125 TE, WITH THE ABSORBER BETA PRI.ME125 TIE3 SU83 AND THE
SOURCE PRIME125 to IN VARIOUS CHEM. FORMS~INAI, NA1.211 SUB2 0,
KIO SU33,
:---NA SU03 H SUB2 10 SUB&* FROZEN SOLINS. OF NAI IN H SUB2 0, AND OF NA 5IJ83
OR NAI A SINGLET LINE -OF REGULAR
..H~SUB210 SUB6 IN 0.1 N HNO SUB3). F
-SHAPE AND,WITHOUT BROADENING WAS FOUND., FOR NAI.2H SU62 AND THE
~-','FROZEN SOLN. OF NAI IN H SUR2 0, A, SPECTRUM. WITH QUADqUPOLE SPLITTIN3
-WAS- OBTAINEOw DELTA IS GREATER THAN .1.0 MM-.SEC. FOR KJO SUB3 THE
-SPECTRUM,,WA-S BROADENED GREATLY, ASYM., AND SEPD. INTO 2 SINGLETS WITH AN
lkTENSilY RATIO OF SIMILAR TO ONE HALF, INDICATING THAT, AFTER ELECTRON
-ARTORE. JN-KTO SU83# THE TE IS STABILIZED JN MORE THAN I FJRfi. FOR THE
t
0l4N,;_SGLN_ ~OF NA SUB2 H SUB2 10 7.S086 IN 0.4 N HNO 5U63, THE SPECTRUM
S-.GREA`TLY~,,.6ROA-DE-NED-- AND ASYM;. - DUE~:~ TD- ~,THE- PRESENCE OF MORE T~IAN I
ABILIZED FORM OF TE4
U N C L A S S I F I E D

UNCLA SI JED PRO.CESSING DAT~--02jrT-10
VROP I UM AND DYSPROSIUM VALENCE.STATES JN LAVES :PHASES AND IS3'AER
-U-
'S"J FTS ,IN IAGESSBAUER SPECTRA
-.,4-UTW0R_J03)-'YEFRFMGVt E.N.v BABESHKIN,11_~W NESMEYANOVi A.N.
tt(A T P YOF INFO--USSR
-_ ~SCURC E--- V ESTN. MCSK. UNIV. KHIM. 1970 II(I)t 46-8
ATE~ PUBL ISHED---70
,7: SU3JECT AREAS--MATERIALS
:~JOPIICTAGS--ELECTRON Di:NSITYt ISOMERs ELECTRON STRUCTURE, RARE EARTH
r
ZINC COMPLEX* NICKEL COMPLEX, ALUMINUM COMPLEX, COPPER
~,MET
__ALt MPLEX,
~--_"--~-QYSPKVSIUM, EUROPIUMP GALLIUMv RHODIUMv '~PALLADIUMI:MOSS34UR SPECTRUM
__'~Ca4TROL MARKING--NO RESTRICTIONS
_'DOCUMENT CLASS-UNCLASSIFIED
:`-PROXY F,EEL/FRAME--1989/0610 STEP NO-,?-UR/0169/70/011/001/0046/0048
CIRC ACCESSION NO--APOID7207
UNCLASSIFIED

USSR UDC 5 7.13:
PEREYAL011A. E. ~G., LT3N1EN'(WSFIY, D. A., BAUKUM, T. Y., PMYSTffM':.Y1".
Z'Si
I. and EL ;P'YAII0V, A. lie Ecosepy State Univaxsity i. 'i
lie Vt. Loronof~ov
"Reaction of Ferroconyl- -xd Phonyl (trlphonylpho$phino) gold, vith Electlro-
Phil-ic Reagents"
ady Akadondi Vauk SSSRg
Leningrad, D o.U Vol w6., 1,o 4, Oct 72, pp 833-0-06
a phenyl (triphenylphuz-,I)i tic) [-.old with
bstraett Reactions of ferrocenyl- ard
A
ad. No eloctro I IUC au~13.1.i
electrophilic roa-gents vas atudiL Ph tution at the
atom took placu in theze reactions, the produatsArdic-Ltia-q th-'
gold
horllolytic process occarred in thv.:~;e reactions, For example, when Eccvrocenyi-
actcd with acatic anhydriete or :xyl cli 'iU(113 0-
z (triphVnyjj)hot;ph ire) Gold rL~, -
Itcatic or trichlurvacntic acidLojr only forroranof biferrOcerY1 =1 V. ca)-t of
13 C vhaz* X - CI or QCMIH Waxv formvUl.- No ar.-A.-
th OmPos't'orl -"F(Y',
ferroce-ne vas isolated. Ana-1qpur. reactiolis occar with phoriyl(-Lvipht'~Dll 1-
phosphine)gold, no clectrophille substitut-lon tWng placo. The r--svl-'V-s
obtained can, le ernlained b,,Y, L1,4a sin.310 Clect"n 't=-.nr'fer
baina tho firot step in a serios cIL reztat-Jona. The election 9`:rtx~i tinc: C-;%u
bond is tratisfurred to th-I splittinj reagejit, which aicts its an electrun
aCcoptoile

OrganoMOWU6 COMPOWds.
USSR UDC 547-13
GRANDBERGj K. I., BAUKOYAj T. V., PEMALOVAI E G. 1"PIM1902"Vir, A. N.
Academiciang Moscow State University1meni 14. V: Lomonosay
-Tolyl-(triphenylphosph:Lne)-go]L-d7-trJphenylphosphinegold Borofluoride"
hoscow# Doklady Akademii Nauk SSR, Vol 206,: No 6, 19?2-, PO 135-,"-1358
Abstracti The synthesis of Eferrocenyl-(triphenylphosphine)-gpld7ltriphenyl-
phosphlnegold borofluoride a new type of organo old Coripound containing
two. gold atoms per molecule was reported earlier FB. C6 Perevalova, et al.,
DMI. t Vol 202, 97~ 1972 . The formation of this t of complex is not a.
91 y
specific property of fe-=oconyl-(triphonylpho.-3phiner-gold6 Organogold
compounds of the benzene series -tolvl-(triphonylphosphine)-gold (Il~
And phenyl-(triphenylphosphine)-golct (III)' ~-- also react iiith JfBF4 yielding
similar complexes; e -tolyl-(triphenylphosphine)-gold was obtained froa
q -tolyllithium and the triphenylphosphine complex of gold chloride. The
reaction of II and III with an ether solution of HBF leads to the forma-
tion of borofluorides of~~re -tolyl-(triphenylphosphhe -golff-triphenyl.
(IV) and 1'Jd
phenyl-trl:.Venylphosphine)-gold -tj#heny:lphosphine-
v1d. (V) respectively. The auriferous ligowd, QH,11,H in
4*Au~!P C6H5

USSR
GRANDBEFC, K. I., et al. Doklady Akademii Hauk SSSRP vol zo6 No 6l 19729
pp,1355-1358
combination with IV Is easily replaced by other electron donor ligands
-(tr:Lphenylpbo p
tripheiiylphosphine, morpholinej.ferrocenyl~ a hine)-gold. In
the presence of an aqueous solution.of sodium chloride, II and the tri-
phenylphosphine complex of gold fluoride are formed. The paraziagentic
resonance spectra . and ultraviolet spectroscopic data of some of the above
organogold compounds were analyzed. The experimental procedums and results
for the reaction HBF4 and II, HBF4 and phenyl-,(triphenylphosphir_e) -gold,
sodium chloride and;1V9 1V and triphenylphosphinet
an aqueous solution of
IV and ferrocenyl- (triphenylphosph.Ue) -gold ~ IV, and: morp~ioline land IV and
fe=cenyl-(t3~lphenylphosphine).~gold~axe doicribed.
2/2

Organometallid,Co'mpounds
USSR MC 542.957.5tri -357.2
I
C BORISOV., A. YE., and r
SW5 YAN -TOVIKOVA, N. V., Institute of Ifetero-
0;rgplic~Conpounds, AcaderW of Sciences USSR
"Reaction of Some Orgranometallic Monohydrides With Ethynylferrocene"
Pbscov, Izvestiya Pkaderdi Nauk SSSR, Serlya Miimicheskaya,: ro 6, Jun 72,
pp 1372-1375
Absti-act: Contin-.11in.- their studies in the field of bimetallic derivatives of
the ethylene zeries R.-114 which cotitain variotia combinations of
elements (Sn. Cle, Sbl As~ Si, HfY) in the, molecule, the authors studied the
addition of i;r1p'hcnylstannf-%qe, triphenylgermine anit diphenylstibine to ethynyl-
ferrocene and obtained
(I), (1-ferrocen.,ti-2-ti,i-,)her.,fLS--rmyl)ei...,3y!cne ard (.1-ferrocLxiyl-2-(iiplif~~r~)rlotibyl)
ethylene. I reacts with corrorAve sublimite to for-m 1~f -ferrc)cen:flrir,.y:Lr.-.ercuric
chloride, symmetrizition of which with KI gives di-(/A
hich linde-r the action o-' corrosive sublimate is readily converted again to
ferrocenylviny1me-rcuric chloride. Under the action of brcmine I is converted
into -bromoviny1ferrocene. a -Chlorovihylfqrrocenl~ reactu~.,,rith lithitmtriphenyl-
stannatte to give (1-ferrocenyl-l-ti,.iphonylrtanhyl,)-ethylere,

.95. _04
.3
=_YA I GRAITDBEPG K. I 674YSLOVA, YE. I., and PEREVALOVA, E. G.,
-Ineni M. V* Lomonos
Vate niversity
0v,
iphenylphosphinegoldacetone"
lobscow, Izvestiya Akadewdi Nauk SSSR, Se r iFhirlichesk
ya ari, No 10, Oct 72,
~p 2375
Abstract: Reaction of vinylgoldtriphenylph6ophine with an acetone solution of
potassium perrmiganate at OP triphenylphos,,hin--I,,o!6.acptone (1). Hcl,
AW12, and Br2 add to (I) in the 1,2-position, while acetyl chloride reacts via
1,4 nd triphenylphosphineL~old chloride.
-addition yielding isopropenylacetate a
now

i7 UNCthsSTF-leb--- C t$ S I N"'
Pk OATE--IISEP70
0
0
JILE4-REACTIONS OF.TRITIUM RECOIL ATOMS IN ~Pl HFXANE-DENZENE BINARY
T ~
-MI-XTURES -,U-
E.N.1 ELZAKHIRp A.,, NE~MEYANOVj A.N.
_66NTR~, OF INFO-.-USSR
,~,:-~S'CURCE-VESTN. MOSK. UNIV., KHIM. 1970l jl(il,~:42-5
bAT .-PUBLISHED ------- 70
E
SU BJ E C TAREAS--CHEMISTRY, PHYSICS
','TC.TAGS--HEXANE, BENZENE, TRITIUM, NEUTRON RADIATION,, CHRawATOGRAPHY?
EMICAL ~LARELING
-'C ONT POL !4ARKrNG--N9 RESTRICTIO'NS
012CUMENT CLASS--UNCLASSIFIED
"~-.PRCXY RcEL/FRA4E--1989/0151 STEP NO--UR/0189/70/011/001/0042/0045
ClqC ACCESSION N[3--AP0106811
UNCLASSIFIED

0 DATE-1
UNCLASSIFIO PR t~~SIIN~J tSEP70
1~*-~ORC ACCESS-ION NO--AP0106811
A8STPAlCT/EXTJqACT--(.U) GP-0- ABSTRACT. THE INTERACTIONS OF T PECOIL ATO'~S
~WITH HEX
ANE AND CtSUB6 H SUB6 IN THEIR MtXTS. WITHOUT 1 010 l,"4 THE
~:PRESENCE OF 1 (5 TIMCS 10 PRIME NEGATIVE3 KOLE-L.) -.4FRE STJDIci) BY
IRRADIATING TtfF MIXTS. IN QUARTZ AMPULS FOR 15 MIN WITH A N FLUX OF 1.2
TIMES 10 P.RIME13 N-CM PRIME2 SEC AT170DEGREES AND FOR 2 HR. WITH A N FLUX
-OF 9 TIMES-10 PRIME-19 N-CM PRIME2 SEC AT.141NUS 170DF!3REE.S. THE WALLS
!OF THE AMPULS W~RE COATED WITH LI SUB2 CO-SU83 POWDER TO ACT AS THF
SOURCES _f)F J RECOIL ATOMS. JHE COMPNS.. OF THE REACTION PRODUCTS WE, E
DETO.. BY Gh'S LIQUID CHROMATOG. ANDI BY ACTIVITY MEASIJREMENTS. THE ',*,AIM
PRODUCT OF THE-REACTION OF T RECOIL ATOMS WUR HEXANE WAS HT (SIMILAR TO
PRODUCT ar-,
~.55PERCENT) THE HIGH BOILING FRACTIONS AND THE 'iEXANE
-CLEAVAGE CONSTITUTE 7 AND 11PERCENT't RESP., OF THE TOTAL ACTIVE
':".,PRnDU-CTSO. 'THE INTRODUCTION OF I HAS NO :EFFECT ON ACTIVITY DISTRIBUTIO
THE PWODUCTS OF THE T HEXANE REACTIONi BUT DECREASES THE YIELD OF
THE-HI.GH BOILING FRACTION AND INCREASES THE ~YIELD OF ACTIVE C SU65r H
:SUB6---rN TTS REACTInN WITH T RECOIL ATOMS. THE RECOtL T ATO-~AS ARE
STABILIZED IN THE FOLLOWING REACTION PR06UCTS: 'HTvjHE SUM OF LA6ELE0
GASES FORMED BY THE CLEAVAGE OF HEXANIE BY THE RECOIL T ATOMSI AND
PRODUCTS CONTG. T ATOMS IN THE COMPONEINTS OF THE INITtAL ~~IXT. ANO IN
-DUCTS FORMED DURING THE REACTrONs THE TOTAL YIFLD CF GASEOUS
COMPLEX PR9
PRODUCTS IS L.INEARLY DEPE14DENT 04 THE MIXT. CONCN. THF CONCN.
0EPENDENCE OF THF YIELD -'IF-LIC. AUD HIGH BOILING REACTIfIN ?ROD.UCT$ IS
~ALSD CL05E TO LINEAR AND IS ALMOST INDEPENDENT Or- THE PRESF?qC nF
HOWEVERy T"E ACTlVfTY 0ISTRI6UTION, IS MARKEOLY DEPENOENT (IN THE PPESENCE
lJfllC L AS S I F I E

:~T
'685.849-112
USSR uDc &6.24-002 1.-
NESPEYANUVA E. I.1 Municipal Clinical IlospitAl) Vladivostok
use of Merowaves in the Comprehensive Therapy of Acute Pneumonia'
Moscow, Voprosy Kurortologii, Fizioterspii i Lechebnoy Fizicheskoy Kul tury,
No kr 1972, PP 3k5-347
Abstract: A series of 79 patients with serious forms of acute pr-ewronia were
treated vith microwaves, sulfanil=ides, antibiotics, cardiovascular stimulants,
and vitamins while a control group received the same therapy without exposure
to microwaves. The course of r1crowave treatment (50 to 60 w) consisted of
10 to 14 daily procedures lasting 15 to 20 minutes. After 3 to 7 procedures
chest pains., cough, moist rales, and crepitation disappeared or dirdnished
considerably compared to the control.: Sleep,,,appetite, and sense of well-being
pneumnia dis-
Improved more rapidly than in the control. X-rkvs signs o,%
appeared completely after the course of nicrowave therapy in 56. All the
patients-tolerated the procedures very well and none~showe4 any adverse cardic-
vascular changes.

R,
orohometan
USSR We 547,,242+5412.957
N. A. and REMOV# O..A., AMdemiciant 140SCOW
-state University Imeni M. V. i;;jw6nos
ov
"Reactions of Arsonium Salts With Or6anolithiux Compounds"
,auk SSSR, Vol 2051 No 3p 1972, pp'.996-598
Moscowl Doklady Akademii IN
pounds the
Abstractt In reactions of arsonium salts with,organolithiwa com,
initial arsonium salt alkylates the ylide and:is regenerated upon completion
~of the reaction. Heating decomppses the ylids.. A 50% to 100% excess of
C6H CH.Li reacted vith H ) AsrBr in tetra*dro Ifuron toyleld diphenyl-
5 (C6 5 4
nethanal 112-diphenylethanel diphenyli triph6nylarsine (80,1G); and benzene.
an excess of mothyllithium witb tetraphenylarsonium b=rdde: Yields metbane,
Ariaethylarsine# dimethylphenylarzinal, mathy1diphonylarsine, triphanylarsine
as wenas dipheny1methane# tp2-diphanylethanaj diphenyl, and benzene.
Butyllithium heated with benzy1triphenylarsohium.lodids y1v1ds triphenylaralne,
trans-stilbene, diphanyl, diphenyl=thane, io'2-diphenylet4m, butydiphonyl-
aniner and dlbutylpl*nylarsine. Thusp, unlik ar~&logous phwsph=us coa-
.youndsp,compounds of pentacovalent arsenic do'not decompose, into hydrocarbon
and ylide.
1A

USSR UDC 542-91i547.54!v54?-539,1.6
-Utte Univ;=zity
BUFAIll S. T., ",t REUTOVI ~0. A., Mosoov S
m Losav
nReaetion of Phosphorus YlAds with Ferfluorobenzeno"
Moscow, In-vastilya Aadorail Hauk BSSRO Sariya KhlmiaheskzrAyq~j No )p 1972#
pp,605-606
Abstractl Perfluo-robenzene is known to loze ow of the f ju% -j -,:~ ato
oi. 14 m duzb~~
n pounds ware pre-paxods cl
Ucleophilic at+,--ck. Five co4k -.eialoal equatioun wid
HMR data mv prese&,.ed for seveml of. the compounds, All 3.1mat ons mro
Carri
od out in anlirarous solvents in an atmosphere of dry jai=- nit'rogen. For
tanlui4 were ua-ad.
the nur datap a uo&,Iag frequency of 60 Mi :and a CY CW
111:d~ henylpho;sphLle_Da-ritafluorophanylmethylone '(III) wms -Dravitxed'as folloimt
a Pi:
(C4H5)-P=Gf1R. + Q Fe (w1s)3P -CIIFG
Q F&
C4F&
24

USSR UDC 5/12.91047-341t547.5)39,16
Hommov. 'N. A. et al. Izvestiya Akademii~.Na~k 6331j, Sarlya Xhimicheukaya,
i~"
1972.,,pp 605-606
-bensyltripliraylphosplioniiLm" Iodide was
From (III 2j3t4*5,6-pantafluor4
ared rmr &xta gave. m,d. 1 58*5. (Multiplat) t 72-7 (triplet) and F52.2
(multjplat), Compound (IVA)# 2p3p4*5t6-pentafluoio-41-nit-~ostilbvno v-as
syathcaizod from (III) by the rvactioll
Clio (C4H 6~'J 13 0
I
t
110A)
where R' p- R02C6H4-
There am three peaks (2j112)# m.d.t 66e0 (multiplf.,,t) 78.5
.
I. , I -chlorc-
(triplet), 66.2 (multiplet). Compound (10), 2j3~4o5r'6'-T'3ntax.1!1Ora-1r
:stilbeno was prapaxtd using an analogous:"actiall for ~jhlch p - M
COW
The rmr cha-racterristien were sWltxt Rith-t6 triplet allifting to 79.2 the
forzer multiplets to 66.2 and the lzstt*r rea"'tinLig at 136.2. Vxzpoiind (V\f
------bv the xva-,,-,U-on

771147,rMa

USSR UDC.542.957+547.~42+51~7.512
KE Nik. A and FJX LISHINA, V. iv.
L11Ef 21 OVA
OReactions of Stable Arsenic Ylides with:Activated Double Rwids and the
Synthesis of Trisubstituted Cyclopropanes"
Leningrad, Zhurnal Organichesko Khimii, Vol 7, No 4, 4pr 71, pp 696-699
y
Abstract: By reacting the stable As yll-des Ph ks=CHC(U)R (I; R = Me. Q-1e, Ph)
with transdibenzoylethylene (II) arA the dimoZi este'r of fumaric acid (III),
difficultly accessible trisubstituted cyclopropanes with electron-acceptor
substituents in the 1, 2, and 3 positions vere obtained with good yields.
he As yjj: es w re prepared
Ph3As formed f rom compounds I in the reactions. T1
Nos~wyanov et al in DA:q SSSR, 155, 1 0
fro-,4 arsonium salts as described:by 3"4,
1964. On reacting compounds I (Rz He,: 0.3e, Ph) with, II, the cyclopropanes
CNR
Me, OYe,,Pb) were obtained. The reaction of
Fh'(Q=)C C( --O)Fh
compounds I (R = Me, oXe) with III led to the cycloprapanes q(=0)R (R Me,
OXe). The reactions were carried out in anhydrous benzene
1/2

-~ 43 -

USSR UDC 620.193.23
i'The Effect of Oxygen on the Corrosion of'Steals in Steam-Water Flows at
280*C"
Moscow, Atomnaya Energiya, Vol 29, No 2, Aug 70, pp 86-91
Abstract: The effect of oxygen on the corrosion resistimce of structural
steels in high-temperature steam-water media was investigated at 2800C in a
series of experiments in which lKhl8N9T austenitic stainless,steel and 22K,
20, 12KhM, and l2Kh2MS perlitic carbon steels were tested in,'flows of water,
*osion of perlitic
in.a steam-water mixture, and in saturated steam. Cori,
steels in water and in a steam-water mixture was loweT:than corrosion of
austenitic steel in deaerated media, BoO.Itypes of steal corrode in ap-
ately the same manner inde 'adently:oUany prese-11ce of oxygen in the
proxim Pe
saturated's team# The investigatiM results were,couftirned by control tests
of 5000-hr duration in oxygen-wntaining VISdia.

Z_-V/2 007 UNCLASSIFIED' PR06ESSING DATE
--090CT70
"KnE
-ADDITION OF A GRIGNARD REAGENT TO THE DOUBLE OUND OF CYCLOPROPENE
-HYDROCARBONS -U-.
-:AUTHOR--~,(03)-LUKlNAj M.YU., RUDASHEVSKAYA,:Y.YU., NESMEYANOVA, D.A.
OUNTRY OF INFO-USSR
5OURCE-DOU. AKAD* NAUK SSSR 1970, 190(5)s 1109-12
,OATE ~PUBL ISHED---70
'_~~UBJECT,AREAS-CHEMISTRY
'TqplC TAGS-GRIGNARD REAGENT, PROPYLENE,-CYCLIC.GROU.P, CAR&OXYLIC ACID,
IR: SPECTRUM
M4
tONTRUL 14ARKfNG-NO RESTRICTIONS
bOCUMENT:CLASS-UNCLASSIFIED
PkOXY REELIFRAME-199212007 STEP ND--!-URIOOZO/'FO/1110/OU5/1109/1112
CIR(, ACCESSION NO--AT0112963
UNCLASSIFIED

007 UNCLASSIFIED PROCESSING DATE--090CT70
'ClRC ACCESSION NU--AT0112963
'.':A'a5lTRAC T/ EXTRACT- I U) GP-0- ABSTRA(;T. REACTION OF RMGX ,WHERE R WAS
SELECTED FROM ME* ETY PR AND BU ANQ X FROM BR OR It WITH
1.0,3sTRIMETHYLCYCLOPROPENE (1) UR 19METHYLCYCLOPROPENE f(l) WAS RUN
-::-:WITH 10-15PERCENT EXCESS OF T14E HYDROCARBON~ AT SIM11-Ak TO ODEGPEES
_~.;OVERNIGHT .IN -INERT ATM.* AFTER WHICH THE: EFFLUENT GAS w S IDENTIFICD
'~.___(THIS.AmOUNTED TO 1-4PERCENT CH SUB4-C SU84-H SU810., RESP.5 ANDTHE
-~A.EACTION MIXT. POURED ON' DRY ICE AND ACI.DIFIED, ro (GIVE THE RESP.
CARBOXYLIC AGIDS, WHICH WERE CHARACTERILED BY THEIR NMR,SPECTPA EITHER
NECARBOXYLXC ACIDS WERE DETECTED
.,.DIRECTLY OR AS ME ESTI:RS. NO CYCLOPROPE
N, ANY. OF-THE EXPTS. I AND tllEMGI:GAVf_:183PERCENT
ACIDt N. 117-18DEGREES
1HYPROLYSIS OF. THE REACTION IMIXT,GAVE, lii,Z#29YE'TPAMETIIYLCYCLOPROPA.NE);
:-f:AND ETMGB'R GAVE-4GPtRGENT"!':
~11: CIS*2,2i,39TRIMETHYLv3tETHYLCYCLOPROPAN.E#ItCARBOXYL,~IC ACID* M.
80-IDEGREES; 11 AND RMGBR:GAVE
-~-,,,~CIS#20'METHYL,2*[R,SUBSTITUTED)CYCLOPROPANEY19CARBOXYLIC ACID: R EQUALS
R EQUALS PR#
-.ET, 78PERCENTv B SUB12 106-70EGRf.ES# N;PRIME20 SU80 1*4468;
L*9.5PERCENT, 8 SU87 108-10DEGREESP..1.4489~; BUv 3bu5PERCENTP 8 SUB26
156-8DEGREESY 1.4485. THE GEMI.NAL POSITION OF THE TWO ALKYL GROUPS IN
REACTIONSI.OF II WAS CONFIRMED BY THE NMR SPECTRA.Q: THUS THE MAIN
DIRECTIONZF THE REACTION IS CIS AD[)N,.:DF RMGX TO THE DOUt3LE BOND WITH
-THE ALKYL GROUP GOING TO THE C ATOM OF,CYCLOPROPENE WHICH IS
SUBSTITUTEOP WHILE MG GOES TO THE UNSUBSTITUTED C ATION OF THE RING.
ONLY 1-4PERLENT OF THE REACTION PROCEEDS VIA REPLACEMENT OF ACTIVE H*
LITY., INST. ORG.:KHIM. IM:,4ELlNSK0GOt,HO5C0Wr USSR*

UNCLASSIFIED: PROCESSING DATE--020CT70
1/2 0,19
_T I-TLE- ELECT ROMYOGRAPHI C INVESTIGATION. INT-a INVOLVEAENT OF TriE BODY 4-ND
LOWEVEXTREMITTES MUSCLES IN.THE:.LQCOMCTOR-ACTlVITY IN PATIENTS WITH
~.4UTHOR-(02)-NESMEYANOVA, T.N., TRANKVILLtTATI, A.N.
COUNTRY OF. INFO--USSR
URCE--BYULLETEN' EKSPERIMENTALINOY BIOLOGII I MEDITSINYs 1970, VOL 69,
-44
-~~NR: 4,: PP, 40
PUBLISHEO---70
'~~_UBJECT AREAS-BiaLOGICAL ANO M ED I CAL SCIENCES
TAGS--SPINAL CORDr CENTRAL NFRVOU$;Sy~TEM, 141JSCULAR DISORDER,
:FXERCI.SE, ELECTROMYCOGRAPHY
E S TIT I u",S
_-:1)U -~E'sT CLtSS--UriCLASSIFIE
~Pk IXY ;LFL/FRAME--I938/159Z STEP 44t
C I RC 4C(*LSSIC~N NCj--APol0-',)338
UNC t,,X S S I F I E D

-212 0 19 IJINC L AS S I F I ED PROCESS15IG L)ATF--02JCT70
GARC ACCESSION NO-AP0106338
,~_-ABSTRACT/EXTRACT-7-(U) GP-0- ABSTPACT. THE POSSI31LITY OF THE L114B
TO PARTAKE IN THE VOLUNTARY ACTIVITY IN PATIE~,ITS WITH :OMPLETELY
PA~_TIALLY'SEVERED SPINAL CORD IS DEMOMST RATE D.~ ' THE:PATIENTS ARE. MADE
TO UNDERGO THERAPEUTIC EXERCISES CONCURr%ENTLY i4im PYROGIEVAL liEDICATfON4.
IN THE C0URSE:,0F TREATMENT THEY PRACTISE IN WALKING, CLIMBING THE
.,:STAIRS UP AND DOWN AND IN MAKING OTHER MOVEMENTS. THE-AUTHORS BELIEVE
THAT ACTIVE -,INVOLVEMENT OF HUSCLES INNERVATED FROM THE DISTAL LENGT~i OF
i, -:-JHE__,SPINAL CORD BECOMES POSSIBLE THANKS To PLASTIC PROPERTIES WHICH THE
;SPI14AL CORD-ACQUIRES IN CONDITIONS OF~DVSSOCIAT[014 WITH SUPERJACENT -
OF` THE CENTRAL NERVOUS: SYSTEM, AND ALSO SECAU SE OF INTENSIVE
USE'
UNCLASSIFIED

USSR, UDG 6214791.89.546.56:546.78
NESMIKII., V- S MALEVSKIY, ~YU. B., GUBENKO, B. G. ,and KHORLINOV,
F.,~Institute of Electric.WeldingImeni Yel 0. Paton, Academy
of-Sciences UkrSSR
"Contact-Reaction Soldering of Copper With Refractory Metals"
3-ev
Ki Avtomatisheskaya Svarka, No 8, Aug 70, Op 59-61
Abstract: A method for the contact-reaction soldering of copper
with tungsten, molybdenum, chromium, and other metals using a
titanium iinterlayer was developed,by the authors. Experiments
were conducted in a vacuum chamber.with electron-beam heating.
The 10-mm-diameter cylindrical samples were made of tunrsten,
molybdenum , chromium, niobium', and' copper, The tit(,irlium, foil
was 12 microns. The s'amples wer'a -subjected to com-
pression at different times during.soldering (before the appearance
of the liquid phane, immediately afte'r contact soldering, or
after a certain isothermic holding, time). Thx-I soldered joints
were testeA for tensile strength and heat reaistance. Phase con-
tent and joint structure were studied by metallographic and x-ray
Spectral analysis. The resuLta show that: pre~~sure application
imn-ledintelt after tha and og cont6at soldering is the mont expedient
procedure. A technology for tha.pr6duction OP x-ray tube onoden
wns developed on the brasis of these results.

--27NOV70
It?3 018
UNCL ASS I F IEG: P.ROCESSING DATE
,*..,T-',l:TLE`--.S,TRUCTURE OF THE SOLAR CORONA ON 29 1968 -U-
A.T.
C,.OU,NT. RY 0 FINFO--USSR
._~CURCE-MOSCOWr ASTRONOMICHESKIY VESTNIKr VOL IVt
NO 2, 1970t PP 123-172
,"PROXY REEL/FRAME--3008/0070 STEP NO- UR/0454/,70/00tt/002/0123/0172
-CIRC-ACCESSION-40--APOL37252
UNCLASS1FIED-

2/3 OLB UNCLASSIFIED PROCESSING OATE--27NOV70
-CIRC ACCESSION ND--AP0137252
i.as THE STRUCTUR
1.4 TRACT/EXTRACT--(U) GP-0- ABSTRACTo E OF THE SOLAR CORONA
'WA,
S' STUDIED ON 22 SEPTEMBER 1968 USING MATERIALS OBTAINED DURING A JOINT
~----EXPEDITION OF THE DEPARTMENT OF ASTRONOMY.KIEV STATE:UNIVERSITY AND THE
KIEV DIVISION OF THE ALL UNION ASTRONOMICAL GEODETIC SOCIETY. THE
EXPEDITION MADE ECLIPSE OBSERVATIONS BY:RADIOASTRONOMICAL AND OPTICAL
METHODS. FOUR TYPES OF STRUCTURAL FORMATIONS tN TRE CORONA WERE
'DETECTED. (1) ARCHED SYSTEMS. IN THE 4NNER CORONA THERE ARE A NUMBER
OF ARCHED SYSTEMS
AT WHOSE BASE THERE ARE PROMINENCES WITH A SMALL
EXTENT ALONG THE LIMB. T14EY ARE EVIDENTLY!0RIENTED ALONG THE PARALLELS
AND THE ARCHED SYSTEMS OVER THEM LIE.IN;THE.MERIDIC~NAL PLANE. CORO,-qAL
SURFACE BRIGHTNESS OVER THESE PROMINENCES IS GXTREMELY :NONUNIFORM,
POSSIBLY ASSOCIATED WITH THE PRESENCE OF ARCHED SYSTEM& OF COMPLEX
STRUCTURE IN THESE REGIONS WHICH 00 NOT LIE IN THE,'MERIDIONAL PLANE.
CORONAL REGIONS ADJACENT TO PROMIN ENCES~WITHIN THE:ARCHED SYSTEMS ARE
-wCHARACTERIZED BY A REDUCED BRIGHTNESSO-OVeR THEN THERE IS AN
'ALTERNATION OF LIG14T AND DARK ARCHES. ~(2)-PLAR RAY SYS-TEM. THIS IS A
-SYSTEM WITH AN EXTENT OF 20PERCENTOF THE.LIMB, OBSERVED ONLY IN THE
SOUTHERN HEMISPHERE AND ARRANGED ASYMMETRICALLY RELATIYE TO THE SUN'lS
AXIS OF ROTATION. THE EXCESS OF RAY BRIGHTNESS OV,-ER THE BACKGROUND IS
INSIGNIFICANTo (3) CORONAL CONDENSATIONSO' AT THE, WESrERN AND EASTERN
LIMSS THERE ARE TWO BRIGHT DOUBLE CORONALCONDENSATION54 ACTIVE REGIONS
ARE PRESENT AT THE BASE OF THE CONDENSATIONS, (4) LARGE CORONAL RAYSS
LINEARITY AT DISTANCES GREATER THAN 29 SUN ARE CHARACTERISTIC FOR LARGE
CORONAL RAYS. FACILITY: KIEV DIVISIONr ALL UNION ASTRUN6,41CAL
.GEODETIC SOCIETYo

.47,962
USSR vDc
ERSM 14 VCHE li.KO, L. A., and
LIME YH, G. I., FROMY, YL ITEq.U LE
UQ IL F11
SKLYAR,~:YU_S., Institute of Chemical %;dicsp Ac"ademy of Sciences UMI
Moscow
"An Investigation of the Structim-e of ~i: Modeled Iron,~Sulfur Protein by the
Hathod. of Spin and Dudne!5cence Labels"
aya Biologiya, Vol 6, No 2, Ehr/4r 7z, Pp 201-209
Moscow, Molekulyarn
Abstracti The research described in the present article concerned the pro-
blom of the mutual armngenent and interaction of Ixon ions 'An iron-sulf ur
proteins. ArtifIciall i1ron-sulfur proteinst synthesited froa humian senzi
albu.,Ant were zumlyzcd by the n, ethod of. spin and lumi-nescance labelz, with
the aid of an electron mAcxo~-.cojx), paramagnetic zoitrAl nuclear gazz-a-
resonance, ard aru,_lytic ultracentrifugatipa in the don-Aty r~fr,-Aiont. The
spin lab-31 method is based on lChe speciiftc reaction of the iron- an't sulfur-
colit-aining centers of the given proteins teith it paraillagnetic iuinoxyl
derivative of n-chlorriercuro'benzoate. The luruinesconce la:beals Method is
ba-ged on the phenomenon of the migration of ererar via wi inductive -re solianc e
nechanis-m between luminescence donor -euters ani lun-iiiest,-~Lnce-extinguish-,Liig
acceptor canters. The results cbtained -Iry both riethods indicate that the
iron Ions do not act as individual active centers, 'but instead fonr, a
1/2

USSR Author's Certificate fio 366286, Filed 9 Jun 70, Published 16 Jan 73 (from
Otkrytiya, Izobreteniya, Promyshlennyye Obraztsy, Tovaamyye Znaki, No 7,
Mar(a) 73, Claim No 1445447/25-28)
Translation: A bilateral hydrostatic bearing containing a cylindrical pivot
with a ring-shaped section, forming a ring-shaped central chamber in the pivot,
with a radial-throttling aperture, two ring bands with scrolls, in one of which
an axial aperture is formed for delivery of the working medium, distinguished
by the fact that in order to improve the shock-absorbIng properties of a socket,
each of them
the front parts which penetrate the scroll band ringq,IfoimdnjL with
a supporting chamber and two concentricring-shaped aportures, serving as
-and outlet of the working.medium for the chamber.
delivery

USSR uDc 617-oc)i.28-o7:616-153.756-o92:616-36-07
DOROFEYEV, V. M., ZYABLITSKIY, V. M., SOBOLEVA, E. L., and IESTAYKO, G. V.,
Institute of Medical Phdiology, Academy of Medical Sciences USSR, Obninsk
!fRole of the Liver in the Me chanism of-Lowering the Mood Serotonin level in
Acute Radiation Sickness"
Moscow, Byulleten' Ek-sperimntallnoy Biologii i Medit'siny, No 1, 1973,
PP 33-34
Abstract: In rabbits ir diated once at 600 r (Co6O gamma rays, dose rate 1-20
Wmin), the serotonin concentration in.the:portal vein was the same as In the
control, showing that the entry of serotonin from the argentaffine cells into
the blood was not blocked,at the height of acute radiation sickness. However,
the serotonin concentration in the vena.cava inferior was almost hah:' that in
the portal vein. This suggests that. at the height of acute radiation sickness
a-substantial part of the nerotin coming,from the inVal3tine ims destroyed in
the liver before reaching the bloud~by!monamine.oxidase whose activity in the
liver increased sharply in the irradiatedlanimals.
69

USSR UDC 616-601.28-036.11-07:616.155.25-007
V., Laboratory of
DOROFEYE,V, V. M., ZYABLITSKIY, V. M. , and N E S-1 14440
Fxperimental Hematology, Division of Radi, )nVa"Eh-101itysiology and Group of
Mectran Microscopy, Scientific Research Institute o0ledical Radiology,
Academy of Medical Sciences USSR, Obninsk
"Changes in Thrombocyte Aggregation Brought About by ADP and Serotonin in
Acute Radiation Sickness"
Moscow, Byulleten' Eksperimental'noy Bi6logii i Meditsiny, Vol 72, No 11,
Nov 71, pp 32-34
Abstract: Changes in the aggregation of thrombocytes under the effectn of ADP
and serotonin x-.-ere studied in experiments on rabbits subjected to irradiation
with gamma-rays.in a dose of 600 R. The aggregation of thrombocytes under the
effect of ADP was significantly lowered on the Ist, 7th, and 15th day after
irradiation and the thrombocyte aggregates became less stable vs. those for
control animals. The aggregation of thrombotytes under the action of serotonir,
was lowered only at the peak of radiation sickness (an the 7th day after ir-
radiation). The reduced capacity of thrombacytes to be aggregated under che
effect of serotonin was presumably associated with a reduction in the amount
of 5-OT-raceptoro or a change in the State of these inembrane strucLures.

USSR UDC 616-001.28-092.9-07:[616.153.757+616.155.25-008.937.57
DOROFEYEV, V. M., and NESTAYKO G. V. L aboratory of Experimental Hematology,
ion at;~o_ysro_To8'_y'~. Scientific Research Institute of
n
Departme t of Radiat
Medical-Radiology, Academy of Medical Sciences USSR, Obninsk
"Cbange in Blood Serotinin 'Level and 5-HT-otganelles in Rabbit Thrombocytes
During Acute Radiation Sickness
Moscow, Byulleten' Eksperimental'noy Biologii i Meditsiny, No 10, 1971, pp
Abstract: The blood scrotinin concentration of rabbits decreased 35% and 50%
on days.1 and 4, respectively, after whQle-body gammaArradiation (600 r, 140
r/min), and by day 10 it was one-tenth that of the control. The decrease in
thrombocyte count at various times after:irradiation was not as pronounced.
The serotoninopenia was caused not only, by a reduction in the number of blood
platelets, but by a decrease in.the serotonin concentration of the thrombocytes
themselves, as indicated by the sharper,drop in serotonin level compared with
the thrombocytopenia and by the slower restoration of the serotonin concentra-
tion (by day 21, 66% of the control an&same as the control, respectively). A
count of 5-HT- (5-hydro-qtryptamine) organelles also indicated a decrease in
the eerotonin content of the thrombocytes. There was both-a decrease in the
number of aerotonin granules at the different stages of acute radiation sickness

iiiii, ii6m ~ va~ iMal ~ j
vild ~13 ~i;V-1.7in,4 b!
"6~i~ , ............. 1---a'! ~ 4 --- -- - --- - ' 4mm i ii,; mj

ies,
USSR UDC 669.2930ff69-018 2+53?.311.,fi669.787
YERMKOVA 11. P. KALINM, 2. G., and IMT9104KO A,
on
"Study of the Effect of Small Quantities:of~oxygen the Properties of ITiobium"
Blektron. tekhatka, Nauchno-tekhn, sb. Materialy (Electronics En6ineexing.
Conection.of Scientific and Technical Work's i llaterWs) , 19701 vyp. 5,
pp, 6-9 (from M-Hetallurgiya, 110 -3p Har 71, Abstract Jiro 31762 by authors)
Translationt A procedure was devised for introducing onall quantities of 0
into Jib by the anodizing nethod. Data -,tere obtained on the effect of szail
O:c oncentrations (0,001-0.1%) on the haxcbiess, microhardness, and electrical
resistance.of Hb. The results mAke it possible to deta.,cminp the 0 concen-
tilation of 11b by simply measuring the~ph
ysical propoi ics of the metal.
IA

7 a~
UUC:
riRsT.ALL-RUSSIA!, C014GRESS ON THE COwROL OF HEAVY DRINKIN4G
(Article by thl. IdeVShik, candidate of medical sciences, and
411~~'candi4ate of. medical sciences, A11-Union'Scientific Remearch
-36cial Ilyplene.ijild 1public Healt.]h Organizatlem.1me= .4-A. Salnarhko,
hascow, !L~ayartsk ~~atieniye, Russian. 2. 1972. subm.*tted
29 July 1974 Pp 61-65)L
The ll_*&cncV. of the problem of controlling alcoholism mlekes It imperative
to study lot only its state today, but also to pursue an irldepth historical
analysis' UnLilLnOw.there. hAdLftmt been an exhaust"Ve andL generalizing
study_den1irZ_wLth the histor . cttssive drinking t4ereof in
y of. ex
lvolutl6nary Viuziala ard the Soviet Union. In the dais iLmant of history of
prar, S~je'jific tMSC!tutaL imen A. Semashko,
medicine of't1vc'.,A_1l7Union it 1;
Work 1-0 t;Ling done In order to fill the gap in this area. The preselit article
Is one of the parts of that investigation.
The culminati ng clezent in the history of studying alcolmolism In
prerevolutionary Russia was the First All-Russian Congress on the Control of
Vleavy.Drinking. which convened in Pcturaburg from Za December 1909 to 6 January
-,1910. ThLe. congreiss was an extremely interesting eventin Russian public
~Olife. In it,; work were reflected several of the sc~cioecono=ic phenon,Lna
typicall of Ruusla in the early 1900s. An effort was mzlde there, to consider
the pro .alem of alcoholism in all its diversity fron rwdlcal-bealtb, socio-
economic, ;olitical, legnl. and moral-ethical poiltions. , Tbe congrews parti-
Y
cipants Inevitably encountered a wt&~ "rcle of social hygiente problems.
Tile program of the congress was Lxtremcly brand. Yore than VW? papers were
delivered and discussed at plenary sessions and three sectilons ("Alcohol and
the,liuman Organism,". "Alcohol and. Society," and "Ht-arls. of Controlling Alcoho-
The RUllaiallL Community Was draw n more and more to the problem of
controlling he*y drinking since the late 19th century. , Ad it became inert and
more ulid"pread, alcoholism became nn cliLremly "UtaLLS"I"tant"'it problem.
spito of the fiCt'that tile government hypocrItictIly ctovtzvd up- tile
nopoly on sdle.of alcoholic beverages initiated in~ 1894 ~by aspirin6 to
Muce. 6avy'drifikp~j; the share of re Iv,Ott.ue in tite fiat 'budget. f"m tile
e'
olcoh6lic belieiagea grew cons stet
'sale of I ItIv. The., Inecitie from liquor
also Sr" from .44.9,Lpaj isL
cent 1894 to 30 percant~ in 1905
65

USSR UDC 621.315.592
ROZILMNY i TK V. T. NESTERENK0, B. A. , TSBULYA, G. G., LI$ITSA, M. P., SN- KO,
~T
of Sciences of the UkrSSR, K5ev
0. V., Institute o micorrctuctors,' Academy
"Optical Propcrties of Germanium with a Clean Surface and with an Oxidized
Surface"
Leningrad- Fizikai Tekhnika Poluprovodnikov, Vol:4, No 9, Sep 70, pp 1770-
1775
Abstract: 11e authors investigate the effect x1nich the: physicocher.:,.ical state
of the surface has on the reflectivity of semiconductors. `-e study specimens
were single crystals of germanium with atoaically clean and oxidized (etched)
surfaces. In addition to reflection, thd specimens were studied for edge
absorption and photoconductivity, It was found that the reflection spectra
um with an acoriucally clean surface have two peaks;with energies
or germani
of 2.6 and 2.8 eV in addition to the peaks at 2.1.and 2.3 eV inherent in
spec:Lmens with oxidized surface. A surface origin is zittributed to the
maxima at 2.6-2.8 ekl, while the maxima at 2.1-2.3 eV arc. assumed to stem,
frow. tramltiono within the opecimen. The atomically clean su:rface. also
shows a shi_-ft of 0.02 eV toward the ahort-wave region ps cor.-~arud with the
P
oxidized surface in studies of edge absorption'and. pho~oconduaivity. This
1/2

~T
USSR
ROZOMW, V. T. , et al., F-)zi'%-a t Te"Khnika Vol 4, No 9,
Sep 70, pp 1770-1775
shift is attributed to the simultaneous effect o.-. various mecha-isnis involv-
ing optical transitions or. surface levels, quantum effects associated with
the strong electrical field an the atomically clean surface and simple physi-
cal.changes such as surface tension.

uDc 681.326
ZBARYSHEVSKIY, V. M., MAMMKI A. A. j, pandPANCHISHIN, V . I .
L2stitute of Tiathematics, Acadeqj of oclonpea-uKrU7137an. ZO."
"Device for Controlling the Structm\- of aComputer Medium
USSR Authors' Certificate No 332273, Cl. Go6 g 7/46, filed 7 Apr 70,
-published 7 Oct 71 (from W-h-kirtomatika, 2elemel-hanika iIrychislitellnaya
Tekhnika, No 5, May 72, Abstract No 51Q21P)
Translation: The invention has to do with computer devices used to control the
structure of an optron analog network. in:the solution of partial differential
-,ntial eo4ations
equations. Special-punpose devices for solving partial differt.
by the modeling method are well known: for example, the "USM-l" and the "Vega.."
which use a network of .-esistors as the analog medium. However, the USIRMI-1 net-
work model does not permit control of the network structure at sufficient
speed; i.e., changing of the, resistances of thc- resistors accordinG to the
necessary lav. The auto.,rzted Vega network model perraits the, resistances of
the resistors constituting the networks to be changed automatically according
to a given program as an eTuation is solved. This is done by connecting to the
g from an available set by mans of
network a resonator of the requisite ratin
un electromagnetic re].4y,, Such a -principle of controllLw, the structure of

USSR
ZBARYSHEVSKIY, V. M., et al., USSR Authors' Certificate No ~12273
the medium mkes the entire device exuabersone and requires the presence of a
large number of precision resistors with~ various ~ratinr,?s. The purpose of the
invention is to develop a device for electronically setting and controlling
the structure of a computer medium (analog network) that is based on optrons.
The proposed device makes it possible to'set the resistrince values of the
photoresistars of the optrons automaticEQ-Iv according to a given program and
to change them according to the requinite law during tSe solution of an equa-
tion b :changing the f ilament current of, the optron light sources accord-big
-to the corresponding law.
2

WSR UDC: 681-325.65
MARCH71C, A. A. B., Institute of Mathenatics, Academy of
-Sciences of the UkrSSR
."An Analog-Digital Converter"
USSR Author's Certificate No 329668, filed 16 Oct 70i published 10 Apr 72
U~rom RZh-Av-tomatika, Telemekhanika iVychislitel1naya Telthnika, No 1, Jan
73, abstract No IB467 P)
Wanslation: This invention, which pertains to the field of computer tech-
nology, in designed for converting the internal langilage of an analog-
-digital complex. Translation devices for analog-digital complexes are well-
knownj e. g.; the "Saturn". However, use of. the M-2,20 computer in the
."Saturn complex makes specific demands on'the translation device. The
device made in accordance with these reouirements cannot be used in a small
analog-digital computer complex utilizing a keyboard~computer.
The proposed analog-digital cowrerter differs in that,its functione.1
possibilities are extended by adding a~kipp oscillator, trigger device,,9nd
rewrite device. One input of the trigger.device is connected to the com-
puter module, and the other input in connected through a frequency meter
1/2

:4
USSR
YARCHUK, A. A. , NESTERENKO, B. B. , USSR Author's Certificate No 329668
and a converter to a network model. The output of the trigger device is
connected through the kipp oscillator to the rewrite device, which is con-
nected in turn.,to the computer module.and to the counting decades of the
frequency meter.
The output of the rewrite device is connected to the first inDut of
the computer module. In addition, the converter is simplified by incor-
porating an inverter, coincidence gate, and register 'in the computer module.
The input of the inverter.is connected to the first input.of the computer
module, and the output of the inverter is connected through the coincidence
gate to the register whose output is connected-to thi--coincidence gate.
The input of the register is connected to the second input of Lhe computer
module.
2/2

USSR uDc: 621-396!6-181.5
SUPLIVENKO, V. N., NESTERENKO, B. 0., OVCHINNIKOV, Yu. 4,
"Recording the Static Parameters of integrated Circuitry"
V sb. Obmen opytom v radio2rom-sti (Experience Pooling in the Radio Industry
--collection of works)v vyp, 1, Moscow, 1971, pp 53-55 (from RZh-Radiotekh-
aika, No 5, May 71, Abstract No 5V177)
Translation: A method is outlined for recording the stetic parameters of
Integrated microcircuits by using the appropriate measuring device and the
N-373-2 microammeter-millivoltmeter chart-recorder. Aniattachment is de-
esults from the chart. R ume.
for reading out the measuremnt r es

USSR UDC 546.45:543.27:543.544.25
DRUGOV, Yu. S., NIURAVIYEVA, G. N., GRINBERG, K . M., NESTEP.BKO, G. N.,
SOKOLOV,,D. N.
"Gas Chromatographic Method of Determination of Ber Ilitun in Air"
~Ioscow, Zavodskaya Laboratoriya, No 110 1972, pp 1305-1306.
Abstract:, The authors have developed a gas chromatographic method for 6etermin-
ation of microquantities of beryllium in the air at~industrial enterprises,
based on the formation of a volatile beryllium chelate with trifluoroacetyl
acetone. A linear dependence of the signal of the detector on berylliwii content
isiobserved in the range of concentTatiOns.of 0-4 to. 2-10-S mg/mI Be. The
sensitivity of the determination is 1-110-5 mg/ml Be.:
-37

UZI UDC 632.936.2
PRISTAVKO, V. P., D L. P and DOVZHENOK, Ukrainian Scientific
Research Institut ant rotection
Study of the Activity of the Sexual Attractant of the Codling Moth"
Moscow, Khimiya v Sel'skom Khozyaystve, No 9, 1971, pp 37-40,
Abstract: The present work is devoted to isolating the sexual attractant
of the codling moth and testing its activity under laboratory and f ield
concUtions. The research has been performed since 1968:at the Laboratory of
Biophysical Methods of Controlling Harmful, Insects ofithe Ukrainian Scientific
'Research Institute of Plant Protection. Solvents suitable for extracting the
sexualL attractant of the female coddling 'moths and the concentrations to which
the. males react were investigated.
Methylene chloride, ethyl alcohol and ethyl ether were the most advantageous
solvents for extracting the sexual attractant from the glands of female
codling moths. The biological material had to be ground before extraction.
When testing extracts containing.5-10 female-equivalents of attractant,
5 to 10 minute exposure was sufficient. With a lower concentration the
exposura time had to be increased. The Minimum attractant cvncentration
1/2

. ,

I T7
USSR ~MC 546.791'161
OPALOVSKIYj A. A., KUZNETSOVA, Z, M., NESTERENKO. M. NA.~, and: SHINGAREV, V. G.
~'Tbe System-RF-UF6-NH4F'r
Leningrad, Radiokhimiya, Vol 15, No 4, 1973, pp 615-618
Abstract; Study of the isothermal solubility in the systems HF-TN1oF6-NH4F
and RF-UF6-NH4F leads to several observations. One of:the universal
characteristics of this system is the formation of amm6niumbeptafluoro-
molybdates and uranates with the formula NHeMeF7, repreBenting a new
synthetic route for such material6. In this system uranium,hexafluoride
is more soluble than molybdenum hexafluaride with increasing concentration
of ammonium fluoride in the solution, probably because of the formation ok'
NH4UF7. The- reaction mechanism4a this a stem consists of dissociation of'
-the NH4F followed by formation of.[NeF7]-land finally -of the reaction
-product NH4~IeF7.
1
~_4

W-771~--
USSR u-Lc 621-378-325: 65C~ -
-TO T EV, Yu. 1.
PRONIN, V. R., VYSOKOSOV, Ye. P.., NESTERE! LAZAr
"Recommendations for Setting up TemporiLry S an i t ary Miles for Working With
Lasers"
Moscow, Kvantovaya Flektronika, No 2, 1971, PP 87-91~
Abstract: The authors consider recoj=iendations for settizig up sanitary rulles
in working with lasers. The r ecortmiendat ions are based oD analy.,ing current
Soviet and non-Soviet data in the literature on problems Of e'--luating the
biological effect, levels of thi-eLihold action and saf*e lc-:vc,-,.s of laoo~-r
sion from studies with consideration to the optical ~nd pilyf;i0logical
properties of the eye Requirements for production areas vl)ere quarftir.,I
lectrordc devices ar; located are also considered. One table, bibliog-
e
raphy of 25 titles.

USSR UDC 632.951:633.63
Toxicological Laborat ry, All-Union, Institute of Plant
g N. 0
Protection
~-Ilorganic Phosphorus Preparations Against Sugar Beet Pests"
Moscow, Khimiya v Sel'skom Kho aystve, Vol 11, No 2, 1973, pp 33-36
ZY
Abstract: Organic phosphorus compounds have the advantages over oti-er
pesticides of possessing relatively low persistence and of decomposing almost
totallyin the course of one grow-Lng season. These advantages encouraged
tests of baytex, phthalophos, phosalone and demuphos against gnatiing pests..
at the Cherkasskaya Agricultural Experimental Station, the Salivonkovskiy
Elite Seed Research Sovkhoz and the Experimental Fam Clevakha of the
Academy of Sciences of the Ukrainian SSR'. 'llie various; Preparations proved
highly effective in dosages ranging from 0.5 kg/ha to 1.6 kp,,/ha. Demuphos
is of special interest due to its low toxicity for warmblooded antmals. It
had a high selective effect on beet tic-evils when sprayed on beer sprouts
at a dosage of 1.5-2.0 kg/ha., and whej used to treat seeds at a rate of
2.0-2.5 kg/c. The effectiveness,of bromophos and trichlorometaphos-3 was
studied for control of sucking beet pests, while for aphid control, bromophos,
amiphos and trichlorometaphos-3 in dusAges from 0.3-0.5 kg/ha. were tested.
Sayfos was found to help in controlling both aphid infestation and virus

USSR UDC 632.95
PROTOPOPOVA, G. V., NESTEREMKO, N. I. NESYNOV, Ye. P., BESPROZVANNAYA, 1-1. M.
PEK'KIS, P. S. q
"Insecticide Activity of Some Ary1hydrazones. and Aryl Esters H of Iminothio-
acids for Rice Weevils and for Grain and'Chard Aphids"
Fiziol. aktivn. veshchestva. Resp, mezhved. sb. (Physiological Effects of*
Compounds, Republic Interscience Symposium)-, Vyp~4, 19,72, pp 68-71 (from
Referativnyy Zhurnal Khimiya, No 4(11),..1973, Abstract No 0613 by T. A.
Belyayeva)
Abstract: Insecticidal properties of the compounds PhDI=C( !0SC6H4R (compound
1), PhN+C(NHPh)SC6H4R (compound II), (EtOOC)2C=N1NHC6H4R (compound III), and
the 2-arylthiobenzazols were determined., The highest Lnsecticidal activity
for the rice weevils was sitown by 1, (R = p-Me), 67% mortality for a 1% con-
centration; I (R = p-Br), 94% mortality;: 111(R = m-Cl), 100% mortality;
2-parachlorophenylthiobenzothiazole, 95% mortality for,a 0.1% concentration;
-and III (R = o-0,4e), 100% mortality. It should be noted that for the
stereoisomers, the insecticidal properties are stronger for!the 0-form
than the a-form.

USSR UDC 632.954
BUZAKOV, I. F., r4ESjjW"_, N. I., MOVETS&M, K. A. ,All-Union Scientific
~Resea rh Tnstitg-t-e of Sugar 1467s'
"Testing Ronite on Sugar Beet Fields"
Moscow, Xhimiya v Sel'skom Khozyaystve, No 9, 1971, pp 47-50
Abstract: In 1968-1969, astudy was made of the effect of ronite (S-ethylcyclo-
hexylthiolcarbamate) on weeds and. sugar beets (under f ield conditions) and also
on some physiological processes occurring. in sugar beet plants (under laboratory
conditions) . Application of the herbicide roni~e to the sugar beet f ields
either before planting or before-appearance of shoots destroyed 40-80 percent
of.the weeds. The ronite was identically effective against monocotyledonous
and dicotyledonous weeds. Increased doses of ronite delayed the shoots some-
what and suppressed the young sugar beets plants. During the initial period,
as a result of suppression by the.herbicide the sugar:and hydrocarbon content
increased in the plants, and the respiration, intensity ~ decreased. The herbi-
cide had practically no effect on-the intake of mineral nutritive elements.
On application of the ronite, the sugar beet root harvost did not drop, but
the sugar content and quality were reduced.

~.'tGUNTRY'OFANFO-USSR
~`--50URCE--KHIM4- SEL. KHOZ*
1970, 8(4)o,382-3
lz'~~PUBL ISHED ------- 70
~SUB JECT AREAS--BIOLOGICAL AND M ED, I CAL SCIENCES
..PROXY FICHE N(3----F070/60500Z/C0-5 ~STEP t4C.--UR/03C)4/7-0~0,,Iseo04/039,2/,";3.~'3
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USSR UDC: 632.951:661. 718. 1
xica-logi6al.Laboratory, All (Jnion Institute
I. , Ukrainian TM
Agricultural Sciences
~~t Protection, Leningrad, A11,Union Academy oX
3-meni V. 1. Lenin
"Utilization of organophosphorus Prepekatio'ns as Substitutes f or D1)T and
HOCH.in Control of Sugar Beet Pests":
Moscow, 102imiya v Sel'skom. zyaystve: V61 8, No 4 (78), Apr 70,
Xbo p
42-43
Abstract: Organophosphorus insecticidos, leybacid, plithalophos, and
phozalon may be used instead of DDT and HCCH in
controlling common sugar beet snout beetle and other sugar beet pesc--
with suckling or gnawing mouths. FhozaLon is also active against cabbixq~o
moth caterpillar, sugar 1-jeet caterpilla1r, sugax beet root, and mag(,Iots of
sugar beet agromyzidae. Its insecticidal action is' longer lasting
that of metaphos, chlorophos and polychloropinene. Leybacid also proved
to be active against the above pests, :being stronger than polychloropincne
lorop.
or even beptachlor. Phthalophos was More,elfective. than polych nene
against sugar beet snout bectle :mid showed: activity aga.~nst sugar beet; root,
sugar beet agromyzidae, leafhopperst and others.