SCIENTIFIC ABSTRACT PIMENOV, I.F. - PINEGIN, B.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002202420013-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

-,",-1/2 022 UNCLASSIFIED PROCESSING DATE--23OLTIO
-ITLE--GAS PHASE REACTIONS FOR THE PREPARATION ..010 TRAN FORMATIONS OF
5
CHLORINATED ETHANES. CHLORINE INITIATED BEHYDROCHLOR INAT ION OF
."AUTHOR-(05)-KRISHTALv N.Foy FLIDt R*M.t PjtjFAQY_jL I.F., SONIN,. E.V.,
X-REGER, YU.A.
6-6U.NTRY OF INFO--USSR 00--.
(oo/p
4
OURCE--ZH. FIZ. KHIM. 1970, 44(l), 248-9
--~-_QATE PUBLISHED ------- 70
Ff*~7.SUBJECT AREAS--CHEMISTRY
:TOPIC TAGS--CHLORINATION, CHLORGETHANE9 CHEMICAL KINETICS, CHEMICAL
-'~-REACTION RATE, CALCULATION, ACTIVATIOWENERGY
~-CONTROL MARKING--NO RESTRICTIONS
-.60CUMENT CLASS--UNCLASS[FIED
REFLIFRAME--l'995/1405
STEP NO--Uft/Ot)76/70/044/001/024ii/0249
~CIRC ACCESSION NO--AP0116852
UNCLASSIFfE0

022 UNCLASSIFIED PROCESSING DATE-230CT70
~~..,!CIRC ACCESSION NO--APO116852
-ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT.
THE TITLE REACTION IS A HALF ORDER
REACTION WITH RESPECT TO CL AND C SUB2 H SUB" CL SUB4, TO DET. THE
KINETIC PARAMETERS, A SERIES OF EXPTS. WERE CARRIED OUT AT
350-425DEGREES BY CHANGING (FOR EACH INVESTIGAT.ED:TEMPt.) CL AND C SU82 H
SUB2 CL SUB4 AMTS. 'THE REACTION.RATE CONSTS. WERE CALCO., AND A DIAGRAM
WAS PRESENTED OF THE DEPENDENCE LOU K EQUALS F(I-T)o THE ACTIVATION
ENERGY WAS 23.8 KCAL-MOLE, AND THE COEFF. 6.67 TIMES 10 PRIME7 SEC PRIME
NEGATIVEI. FACILITY: INST. TONKOI~KHIM. TEKHNOL* IM,
:LOMONOSOVA, MOSCOW, USSR.
UNCLASSIFIED

jpRs 58764
17 April 1973
DISPOSAL OF RADIOACTIVE WASTES
Collection of papers sronsored by the State Committee for the
Use of Atomic Enerily of the USSR, 1*312, Mvscow
CONTENTS PAGE
Th4ital =14 T~"Ozic Ampac of HAndling Liquid Waste
With Inter"41*t. and Mph I Radioactivity
(V. L. SpLtayn. mt. at.) ..................... I .............. 1
Study of the P?%*L14lity zf U~ing hituathization for
rroc.malog HIghly Active vxages
Zakhatovo. .................................
Itebuit.1-ecopoatc. Co=pmrj&*,o,vf the Mcthods.tj
S~*lldlftcatLon and IT~k Storage for Highly Active
L14uld Wastes From the _Pro-essing of. Spent Fuel
Elements of Wattr-Couted *Watet-Hoderatod*Powee Reactors
(Le G, Az'vaaye". ot al.) .................................. 36
Scientific Prerequisites for burying 11tably Active
Llquid Wastes in Dump Ctological Formations
(V. L spitayn. at al.) .................. I........ I ........ 47
be velaptwntat Msthod4 for frapartax the Wastes kcat
Hevalluorl4e Technology for Awlal
(Lt. V. Krylovs, at al.) .................................... 62
11 - USSR - X)

SW.WrIrv: PREP-11QUISMS EOR BURYING HICHLt ACrIVH LIQUID WASTES 114 D"s,
GMLGr,CAL FOMMATIONS
[Papar 67-_Y.. 1. Spitsyn. V. D. Solukova. F. P. Yudin, and
State Committee Uoj~th. gy of Me USSR; IAE.1 I.H
SH-163/40, HC%Cvw, 1972/
In th~ V3511. *toragc- sivAtex hwee been cre4.tcd for liquid wastes of inter.
m"diat& And,low~ radioactivity In il"p aquiltra of the Earth, Composed of
jointed anA porous rack, reliably ImolAted Ivy water-light clay layers L-1-1, 31.,
T).P wtorage Areas In operntion are engineering structures, the basis
of which in found in d-?finite hydrolynamic schemes, constructively outfitt.d.
wells and apparatus inaking it possible to regulate the filling of live storage
sp4,.e anq to monitor the state of th" wastes taken Into it,
A complex of scientific research.-ork pertormed ard the results of
the operation of-such otor;sgt spaces at the prement time make It possible to
m:%kt a dolinite evaluntion of the possibility of such burial for highly active
liquid. It Is netesviary to comment that with.the removal of liquid highly
active wa item Into a geological medium it I# not their simple diachargeAnto
some formation or other that Is curvaldered, but the creation of a atorage
area (if definite dimensions and operating rcginve. with a series of dcvleas
controllinR Its operation- special plants. and instruments.
The introduction of highly active liquid wastes. which are. an n rule.
nitric -at id solutions in which corrosion products and a considerable qunntity
of soluble mvilis (such as nitric-acit; salt, for example) are contAined, into
undargrnund strata to accompanied by a number of physicv-chemient processes,
which m4y cause undestraZite conmequtnces.
This communication is devoted to the basic physlco-chemic~l factors
dettrmining the operation of underground storage areas for the type of wastes
under consideration.
47

The cnlii,rtor strain, with renpect to their Characteristic., differ
~~a~icaily from the physico-chemical mystem of he highly aciave dibcharges
4-1 all rLemic,11 re-ctiolia Ito the reacti- J y-teins -v directed t,,-
ward geochemical equilibritims of thv atrkila. However. in this case essential
changes occur b,,th In the composition of the wastes and in 'he system of
strata.
Thr batir changes in the solid phase of the ittrmn are asaocioted with
effectxexf hvdrogen ion4 and with the saltntra~zon of the surfacelaycr4 of
tt-.e rock ;-rucles. 'rite effects af the acid, in %h~ (lost analyst*, turns out to
~v most e((ective and le.ads to the formation Qf,a rritchanical eornpos%tion or
to- --ki. A d#creistj in the darienoions of th,, course particles and solution
nf the fine par%icles occurs, which for slum,)silicate rocks with an effi,cti.e
porosity ~f thi, strata of R-IZO, may cause destract= of 10--39% of the
A-46d phase.
In a moderate elf-!ct or acid no failure of the skricton of the rocks
o