SCIENTIFIC ABSTRACT SHAGIDULLIN, R.R. - SHAKHBAZYAN, G.KH.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002202830008-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SHAGI DULLIK, R. R. at al.# Xhimiya Getezotsiklichaskikh Soyedineniy, No 12
Doc 71# pp 1612-1615
a conclusion waz reached that changes In the ring conformation must have taken
placei in the trivalent phosphorus compouads the ring is in form Qf an
envelope with a pseudoaxial chlorine atom, while in the tatracoordinated
phosphorus compounds an envelope ls,formed,with a axial phosphoryl oxygen atom
andan equatorial chlorine atom.
2/2

UDC 546.26'119
CHMOKAL'SKIY, B. D., ABALONIN, B. Ye.,
120SINOVA, S. V.,
aactiCAMAY, GIL'M, Kazan' Chemical-Techn blogical Institute imeni S. M. Kirov
"Mactio-,i of the Esters of Arsenious Acids with Alkyl Halides"
Uningrad, Zhurnal Obshchey 1(himii, Vol XL, No 12, Dec 70, pp 2645-2648
Abstract: It was demonstrated earlier by several of the authors that during
the-reaction of the esters of arsenious acids with alkyl halides, instead of
the:expected alkox-yarsonium salts, quaternary arsonium salts are formed;
it-,was-~of interest to study the effect of the structure of the starting
eater--on.that of the final product.
A~series of esters cf several arsenious acids were studied for this purpose;
thesezdiffered with regard to the nature of the hydrocarbon radical of the
este-r--group. It was shown that the hydrocarbon radical of the alkoxy group
A~ in-,no-cme enters into the composition of the arsenious salt formed.
Mal-

USSR UDC 543 1*12.4:661.718 .1
1. P.,, Institute of OrGanic and Physical
N- and LIPATOVA,
Chemistry imeni A. Ye. Arbuzov, Academy of Sciences USSR
"Infrared Spectra and Structure of Certain Organo-thiophosphorus Compouzzids"
Moscov, Izvestiya Akademii Nauk SSSR, Seriya Xhimicheskaya, No 5, 1971,
pp, 1024-1027
Abstract: Identification of bands ascociated with P-S vibrations and quantita-
-tive data on the intensities of these bands were obtained for several new
thio-orSanophosphorus compounds of the type:
x
SRI
c6H5-
X 0 Se S R'= C2H5, i- and n-C3H7, i and n-r,4f)
R" C2H n-C 1~
5 3
112

:777
USSR
SHAGILULLIN, R. R. and LIPATOVA, I. P., Izvestiya fidt-adwid-i Nauk- SSSR, Seriya
Khimicheskaya, No 5, 1971, pp 1024-1027
an(! P=Se
Wave numbers of band maxirna assigned to the vibrations of P-Sj I )
bonds are tabulated, along vith integral intensities (Ap-S) of the doublet P-S
bands. It was found that the frequency and integgral intensity of vibrations
of the P-S bond are sensitive to substituents at the phosphorus atom.: for
compounds of the type given above, with al-kyl radical ",teaa of phenyl, nup_S
510-540 cm- Introduction of an aryl radical increases this frequency to 557-
578 cM'l. Several rotational iaoru!rs exi st among the ow1mounds studied. Spectra
of certain compounds recorded in the! teTTcrature ronr;,e fj'om +30 to -1300 and
in solvents of different polarity revealad the existencu, of rotational iGo1-.Qrn-
The energy change delta-E of rotational isomers were calculitted froill ricasure-
ments of infrared spectra at different taraperatures. 'I'sle int'rared spectra were
recorded on the UR-10 double beams spectrolmator in the 400-400D cm rangC*
2/2

USSR UM 541-62:661-718.1
RA-YEVSKIY, 0. A., 5TIAGI and PFTR(X-IA,, L. YE., Institute of Organic
and Physical Chemistry ineni. A. Ye. Arbuzov, Academy of Sciences USSR
F: Study of Rotational Isorneriom of the Acid,Dichlor-ide of Mathylphosphoric Acid"
Moscow, Izvestiya Akadendi Nauk SSSR, Seriya Khimicheskaya, 140 7, 1971,
pp 1426-1429
Abstract: Two physical methods were used in assigning reoretrical configuration
to possible rotational isomers of the acid dichloride of metliylphosphoric acid
(AWTA): infrared spectroscopy and di-nole moments. Infr_fLrzed spectra were used
isomeric forms and
to deuenune the existence of a dynanic eauilibriun of
their relative proportions in a non-polar medium. Experimant:0. dipole moi-.-cnts
were compared with calculated values to ascertain which isomeric forr-.G are pres-
ent in equilibrium. Absox1ition bands in the infrared sp2ctra were assirmed
to suecific isomers. .11 well-defined dependence of absorption band intensities
on dielectric nerr2ability of solvents led to the determ.ination of the ratio of
absolute integral band intensities caused by par-tiali-lar k-inds of vibrations of
the two isomers founa to be present. The assiEgment. of:configuration was r-aOea
by the dipole nethod. Me e~,periryental dipole mornent of AYMPA in CCLI,, at 2980A

7--
USSR
RAYEVSKIY. 0. A.J. et al... Izvestiya Akademii Naulk SSSR, Seriya Khizricheskaya,
110 7, 1971, pp 1426-il,,29
is 3.40+0-03D. The moment closest to agreement with the e.,m-erimcntal values
is observed for the equiIibrium composition of 20 percent of the trans and 80
percent of the gauche forms. Me low probability of coiffigurations with layer-
ing of identically directed dipoles P-C an'd O-C led to the determination of
one of the configurations of ARTA being the trans*-fona,

U S-I s R U D 242
IS- Y, B- L-, I WL, I
ABA LO 1:
L 91-~
t r-j
Che,ruical-Tuchn n s t-, i tu oLn a n iS. Kirov, Ka-zan, Hinis
I;qghor and Secondar'y Spoc-lal`zed Euducation *nd
.4 A. -1:1 u il t,
0
of organic and Physical Chomistry imeni A. Ye. kv-buzov, Academy
f Sciencos USSIR
0
"The Products of the Reaction o--:' -Ar--inous Acid E.~,ter-- With Alk-JI
Ha!idersl,
j. 'j4
rl 0
Zh~irnal Oboloc-Le, IT o
V 1
Pp
b t r a C t -.,-ere carried out b~ o--.G of i"'tM :-iiethod.,l:
aT C- - t .7?1:r iethGr- of acld and eth~fl Jlodidlo i.:ere :M-01;
in an amnula undler C09 atmocmher-- for 3.20 houra at rca:n te:!~-Iez-aLure,
the precl.-"Itatad tet-ract-h7larsoniwr, iodide reci?y~:-tallizcd
from, an -ixtura and sl-lowed a =,D. of 2913; o::- b) t-fte
Same nil-.bure was hz-~r,,-ted to 1000 --;'o-- 2 ho-u~?s in ampL~la unde:v C02
a 1, 7 1 _, 41 - x -C.-I-ion.,
Yielding "he sar-m product. By thezo re~ u
al!-~yl hal reactod wil'.'n w;tcjrj of Iiailcyl-
1/2

USSIR
Zhurnal Obshchev Khimii, Vol 40, No 8,
kiF- 70, ;p -,872-18'17
z-
-oroducts bv vltoz~"-~s oI' IR =d
sinouz acid-s. of t-he
S-0ec"t py -'U-ha- no alkoxy gz~oups LU--3 P-1 --ant
p r o du c t- s .was dete=iinod tha-b in the above react--cayi5 o-,1.11 y
tetz-a-alky.1- and salts are -formed. Tlc~~-ra-
I '- d-
ethyl rt:-2oonizu,-, iodide reacted with magnesiun perchlorau
ax 'Uion yielding te-Urae--
thylarsoniuz%, pe=hlorate
ra, 1) 2 911-1
2/2
M M W-,~,Ifmtlm et if --mlifl, mmut-11"ve
trill

USSR UDC 547-3411139-81+547-391
PUDOVIK, A. N., BATIYEVA, E. S., SHAGIDULLEN, R. R., RAYEVSK-ILY, 0. A.,
PUDOVIK, MI. A., Institute of 0 rc.'"Pa"n"I "a" `Mr ~MSTM-Chemistry imeni A. Ye.
Arbuzov, Academy of Sciences USSR
"Reaction of Amides of Diphenylphosphinous Acid with ~-Unsaturated Acids"
Leninarad, Zhurnal Obshchei ;Qiimii, Vol 40, No 06, Jun 70, PP 1195-1202
Abstract: The mechanism o,' 'he reaction of diphenylphr-sphinous acid a-ides
with r-\ P_unsaturated acids was investigated. Protoriation of the nitroc;en
ne
atom of the amide leads to the formation of an amine ard subsequently th
amide of the unsaturated acid and siphenylphosphinous acid. Association of
the latter leads to the final product, namely P-carbamayl-aL--ji-or alkenyl-
diphanylphosphine oxide, depending on whether an f.4%, h-wizaturated acid of the
ethylene or acetylene series was used. The proposed MINchsnian was confirmed
by IR spectronetry.
..........

USSR UDC. 547.241+60-1-725
GRISHINA, 0. N., KOSOVA, L. bl., LIPATOVA, I. P., and SIKq1DULLB1, R-;R.,..
iment A:'YV'
Institute of Organic and Physical Chemistry Arbuzov, Kazan',
Academy of Sciences USSR
mAlkylthiophosphine Sulfides. 9 Synthesis of Pentaerythrityl 0,0,0,0-Tetra-
kis (Alky:Ldithiopliosphonates) ai2 Their Derivatives"
Leningrad, Zhurnal Obshchey Khimii, Vol 40, No 1, Jan 70, pp 605-69
Abstract: A series of dithiophosphonate derivatives, previously unknown, were
Wthesized in the pursuit of investigation of alkylthiophasphdne sulfides
(1). Four partial cstorG, pentaerythrityl
nates) (II), were propared ~Ui 100~ yields by iiLiying I vith pentaorythritol in
anbydrous dioxane at 900. 11 were clear viscous products. Dropping trie'Lhy-
lamine slowly into a mixturo of I and pentaorythritol in dioxine at room
temperature, then heating the mixture to 100 Fave corre!;ponding quatornary
triethylamon; riscous substances
lu".1 salts of I! (III) (yields 92-9T~), cletr ~
which crystallized on standing. Adding slowly ethyl iodide or ethyl chloro-
acetate to 111 in diox=e at 70-80'j -gave after three hours 605_89,0' yields of
pentaerythrityl 0,0,0,0-tetrakis (Q-dialk3rlditqiophosDhona,~es), extremely
viscous substances which crystallized on standing. S~Ailarly IT! in dioxane
1/2

USSR
GRISHINA, 0. H., et al, Zhurnal Obshchey Khimii. Vol 40, No 1, Jan 70, pp 66-69
solution reactee.with aqueous iodine at room temperature to give 78-8-94-8,~
yields of disulfides
C[(CH20P(3)R-S-h12
where R is butyl, cyclohevjl, or C6HI3. The disulfides -1-1 were crystal!~Lne
products, indentj-fi~d by their melting points. Shaking- II, where alkyl is
butyl or cyclohexjl, with aqueous nickel sulfate in eq-tdxiolar amounts gave
100 yields of corresDonding nickel salts, gray-greenisix powders melting at
.145-1470 and 230-3Y. respective4.
2/2

IISSR UDC 541.6 + 543.422.6 + 547-558-1/2
SHAGIDULLIN, R. R., and A. V., Institute of Organic and
_1hyal-~~StTy-imeni A. Ye. Arbuzov, Acad. Sc. USSR
"Structure and UV-Spectra of Some Arylphosphines arA -Arsines"
''..Moscow, Izvest-;ya Akademii !.,auk SSSR,. Seriya Khimicheskaya, No 1,
Jan 71, pp 183-185
Abstract: UV spectra of aromatic phosphines usually show two bards
in the range )P200 mp: an intense short-wave band around 220 r,-.)j
and -a medium band at 250-270 inp. The first band resembles the K-band of
benzene, the second tand had several interpretations but w'as believed
to consist of three bands: K, B, and R. To check this out, studies
were carried out on.- C6,-'~CH:C1'r-(GC211~)2 (I), (II),
W~P(GC2H5)2 (III), 06H~PC12 (IV), C6~11~)fFo'l 0) )2
(VI , and P-G'-"3CC6j14As(IC2;j'5)2 %'VII),yle d ng datia which showed thaz
the R-band ( --.;,7r transition) are present in the !,spectra of aryl-
phosphines Y~-arsines. For example, (IV) showed three sharp bands
at 225, 245, and 275 mp, the one at 245 being assigned to the R-band.
1/2
111 167 IN, i
HU~11111 I I 'Jill IiIi MII-M

USSR
SHAGIDULLIN, R. et al. Izvestiya Akademii Nauk SSSR, Seriya
Khimicheskaya, No 1, Jan 71, PP 183-185
Introduction of an electron-donor group into the p-position shifts two
bands (K and R) in opposite directions, and the '-*, band appears as shovvn
by (VII). Cxidation of the 'croduct sh~~-vld lead to disalopearance of the
R-band, and indeed that' s what was observe-d, as sho-im. by the grect'rX,," of
anisyldiethylarsine. It lias been .131
'10vai that the ~i--V tvan,,dtion occurs
in trivalent phosphorn!-. and arsenic compounds in agree-n-.ent writh the,
observation that in t-he ground state their unshared- electron pairs are
localized at the heteroatoms 3nd are not conjugated aith the 7r-electron
system.
2/2

PROCESSING DATE--30OCTIO
112 015 UNCLASSIFIEO
TITLE-PREPARATION OF NIPHOSPHORYLATED 2jOX9tlt3j0X"'Z0LlDlNkS AND
..~:'6,METHYL,ItOXO*1,3,TETRAHYDP,OOXAZINE -U-
~__.AUT-40R-(03)-LEVKOVAr L.N.t ALIMOV, P.I., SHAGIDULLL~f R.Ro
COUNTRY OF INFO--USSR
.-,SQURCE-IZV. AKAD. NAUK. SSSR* SER. KHIM. 1970, (2)t 369-9
DATE PUBLISHED ------- 70
_SU6JECT AREAS--CHEMISTRY
-....TOPIC TAGS--0RGANIC PHOSPHORUS COMPOUNDt KETONEt HEI'EkOCYCLIC BASE
~COMPQUND, TRIErHYLAMINE# ORGAINC OXYGEN C0t-!.'0UlNDp ORGANIC AZOLE COMPCUND
:.~:ZCNTROL MARKING--NO RESTRICTIONS
:.--DOCUMENT CLASS--UNCLASSIFIED
:.PROXY REEL/FRAME--1997/1183 STEP NL)--U.
CIRC ACCESSION NLj'--AP0120030
I lkW 1 .1, 1~ c I r. I r "

/Z 015 UNCLASSIFIEO PROCESSING DATE--30')CT'iO
ACCESSION NO-AP0120030
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. TO 8.18 G (E*I'!3) SUB2 P(O)N:CGL
SUBZ TiN DIOXANE WAS ADDED WITH ICE COOLIN 2.17 G 4C.H SUB2 OFO SUB2 AND
7.07 G ET SUa3 N TO YIELD AFTER 2.5 HR AT HOOR TEMP, 18PFRCENT HR
EQUALS R PRIMEI EQUALS H), 8 SUBO.5 121-2DEGREES, 14 PRI-ME20 SUB?- 1.4520,
0 PRIME20 1.2609. SIMILARLY WERE PREP0. 26.5PERCENT I(R EQUALS H, R
PRIMEI EQUALS ME), 5 SUBO.5 108-LODEGREESt 1-4530F 1.2343; 20.5PERCENT I
(R EQUALS R PRIMEI EQUALS ME)# 8 SU80.5 1140-20EGREES, 1.4560, i*1871;
AIND 23PERCENT 11, 3 SU60.5.128-30DEGREES,:1,4565, 1.203L. lp, CURVES (2)
WERE SHOWN.AND DISCUSSED. FACILITY: INST. ORG. FIZ. KHIM. IM.
AR13UZOVAi KAZANP USSR&
d- J L 4A L- U

1/2 024 UNCLAssir-itu' PROCESSING DATE--30OCT.70
__TlTLE--SULFlDES OF ALKYLTHIONOPHU$PHINES. IX. SYNTHESIS.OF
PEYTAERYTH41TOL,0,0,0,0,TETRAKIStALKYLdtfHlCPHOSP~iONATES, AND THEIR
-(04)-GRISHINAP O.N.t KOSOV t
At.L.M.t LIPArOVAt 4 SHAGIDULLINP
RvR*
1"'.COUNTRY OF INFO--USSR
_._"_SOURCE-ZH* OBSHCH. KHIM. 1970, 40(l), 6*6-9
J)ATE PUBLISHED ------- 70
--CHEMISTRY
-SUBJECT AREAS
--,-TOPIC TAGS-CHEMICAL SYNTHESIS9 HETEROCYCLIC OXYGEN COMPOUNDY IR SPzC'FPU,'.Jr
-ORGANONICKEL COMPOUNDt PHOSPHATE ESTERt HETEROCYCLIC SULFUR COMPOUNDi
HETEROCYCLIC PHOSPHOURS COMPOUND, THIOL
..,CONTROL KARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REELIFRAME--L992/1739 STEP NG--UR/0079/1*0/040/(101/0066/00f)g
CIRC ACCESSION' tlC--AP0112727

212 024 UNCLASSIFIED PROCESSING DATE-30OCT70
CIRC ACCESSION NO--AP0112727
.ABSTRACT/EXTRACT-W) GP-0- ABSTRACT. HEATING 5 G IMEETCHPS SUB2) SUB'
WITH 2.24 G C(CH SUB2 OH) SUB4 IN DRY UIOXANE I HR AT 90DEGREES GAVE
100PERCENT VISCOUS C(CH SUB2 OP(S)-(SHIR) SUB4 (1) IR EQUALS MEETCH)f, N
PRIME20 SU80 1.5630. SIMILARLY WERE PREPO, THE AiNALOGS WITH: SHOWN ON
-MICROFICHE. IR.SPECTRA ARE REPORTED,; FACILITY: INST. ORG.
FIZ. KHIM. Im. ARBUZOVAt KAZAN# USSR..

USSR UDC 547-787 + 547-867 + 661-718.1
1XVKOVA, L. N., ALIMOV, P. I., and SgAGIDULLIN, R..R., Institute of Or-
Iganic and Physical Chemistry imeni Academy of Sciences
USSR
"Preparation of N-Phosphorylated 2-Oxo-10-oxazoLLdines and 6-Methyl-
2-oxo-1,3-tetrahydrooxazine"
Moscow, Izvestiya. Akademii Nauk SSSR, Seriya Khimicheskaya, No 2, Feb
70, pp 396-399
Abstract: The reaction of N-diethylphosphonoiminocarbonyl chloride
W
j.
'th ethylene glycol, 112-propylene glycol, 10-butylem glycol and
2,3-butylene glycol in the presence of triethylamine in a dioxane
medium gives N-phosphorylated 2-oxo-1#3-oxazolidines and 6-methyl-"-
diethylphono-2-oxo-lo3-tetrahydrooxazine.

USSR UDC 542.91 + 541.2 + 547.242
CHADAYEVA, N. A., MAMAKOV, K. A., SRAGIDULLIN, R. R., and KAMAY, G. Kh.
(deceased)
"Synthesis and Some Properties of $-Hydroxyethyl Esters of Trivalent Arsenic
Thioacids"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 4, Apr 73, pp 824-834
Abstract: New 6-hydroxyethyl esters of trivalent arsenic thioacids have
been synthesized by the reaction of thiol exchange and exchange of the
alkoxy group by the thiol group. The reaction appears to go by the mechanism
analogous to transesterification of trivalent phosphorus esters. The pro-
ducts are dense colorless liquids soluble in organic solvents, insoluble in
water. They can be distilled in vacuum without decomposition, are stable
in air to oxygen but are attacked.by strong oxidizers. With acyl halides
these compounds form arsenic halides and 0-acetoethyl esters of thioacetic
acid. Prolonged heating of 0-hydroxyethyl esters of alkyl(aryl)thioarsonous
and thioarsonic acids yields respective 1 3,2-oxathiaars-olane derivatives.
Physical properties and IR spectra of the synthesized inaterials have been
determined.

6i
USSR
UDC 547.26.119 + 543.422
GAMAYUROVA, V. S., KUZMIN, V. K., CHERNOYJIL'SKIY, B. D., and.SHAGIDULLIN,
&._R., Kazan' Chemical Technological Institute Imeni S. 1q. Kirov
"Spirocyclic Esters of Arsonic Acids"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 9, 8ep 73, pp 1937-1939
Abstract: New esters of arsonic acids and dihydric aliphatic glycols have
been synthesized. The reaction consisted of refluxing a mixture of the
appropriate substituted arsonic acid, ethylene-glycol and benzene in a
system equipped with a Dean-Stark trap. The cyclic structure of these
esters has been confirmed by IR spectral data.

USSR UDC 541.67:543.422-4:r,47-111-18
SHAGIDULLIN,,_& ULLINA, L_ H., KUDRYAVTSEVA, L. A.,
BELISKIYj V. YE., ASHRAr
IVANOV, B. YE.
"Study of Dipole-Dipole Interaction of Phosphoryl Compounds with the Environ-
meat by the Method of Infrared Spectroscopy"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 11, 1973,
pp 2502-2504
Abstract: A study was made of the nature of the variation of the valence
-phosphoryl oscillation frequency V 0 in different media for phosphory! com-
pounds differing signiricantly witg--respect to dipole moments. The inter-
action with the envirorument of organophosphorus ethers, amides, acid chlorides
and trialkyl (aryl) phosphine oxides having a phosphoryl group takes place by
the same mechanism as the linearity of the variation of the valence oscillation
frequency oil the P--O bond under the effect of the envirom-lent indicates. The
interaction of the phosphoryl compounds with the enviro=ent is intensified
with an increase in their dipole moments which can be caused by an increase in
the polarity of the F=0 bond. The capacity of the phosphoryl compounds for
interaction with the environment depends on the intrazzolenular effects of the
substitutions on the phosphorus determined by the Taft induction constants.
1/1

USSI-~- UDC 541.63:547.1,118
SffAr.Tlxr R SAMITOV, YU. YU., MMMET011, F. S., end RMPOLOMENSKIY,
Nst'~ Au em ~of~' Organic and Physical Cherdstry Imni A. Ye. Arbuzov, Acad.
Sc. USSR
"Stereochemistry of Organophosphorus Compounds. i Commanication. Configuration
and Conformations of 2-Substituted Oxaphospholanols-3"
Yjoscov, Izvestiya Akademii Nauk SSSR, Serlya 1Wmicheskaya,
110 7, Jul 72,
pp 16o4-16ip
Abstract: In continuation of their studies, the reaction of diacid chlorides
of phosphorous, amidophosphorous, and allgl(aryl)phosphor-ous acids with
diacetone alcohol in presence of triethylamine was investiGated. In two cases
of the reaction of the diacid chlorides of diethylamidopliosp1harous and -phenyl-
phosphonous acids with diacetone alcohol two pairs of -p:i-oducts were isolated with
sharp melting points 125-1260 and 3.18-1190 for one pairj and 135-1360 and !64-
1650 for the other pair. Analytical data showed these 'pairs.to have identical
composition. Analysis of IR and IPMR spectra showed them tq be configuratior4al
i6omers of
1/2

SHAGIDULLIN, R. R., et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya,
No 7, Jul 72, pp 16o4-i632
0 OH
0 PH3
and P-e
X OH X4P 'CH3
0(-Hydroxylphosphoryl compounds with open chains exist as rotational isomers
stabilized by intramolecular H-bond wit7a the oxygen of the phosphoryl group or
the heteroatom of the ether group.
1-37FIT-.41. j-7
au Imm j v 1'-
r: N. i 1. 11 wl

USSR .57:54--).11:547.1'113
uDc 541
LIPATOVA, 1. P., VAC9UGOVA, L. I., C~IRKASOV, R. A., and
&I. , Institute of Organib and FlWsical Chemistry Imeni
A. Ye. Arbuzov, Acad. So. USSR, arA Kazan State University Ineni V. I.
Ullyanov-Lenin
"Hydrogen Bonding in Dithio Acids of the Fentavalent Fhosphorus"
Moscow, Izvestiya Akadenii Nauk SSSR, Seriya Khimicheslviya, B'o 4, Apr 72,
PP 8147-851
Abstract: IR spoctra of a 5tyries of liquid pho:,-phinic, phoophonic and phos.-
phoric dithic, acids ai--l their solutions in CC14,, vmire ~;ttldirjd LI toluparaLure
range Z53-2930K. In pure liquids and in concontrated CIOII~ solutions dix-iors
were found to form via the hydrogen bonding. The SH group acted as the
proton donor, the ac~.eptor being the thione sulfur atom in the phosphLnic
acid, and the oxygen atom of the ether group in phosphonic an-, phosphoric
acids. The hydrogen bonding betvaen the Sli group and thiophosphox-jI su:lfur
in the phosphinic acid is stronger than the SH hydrogen bond~xtg with t1he
o.xygen of the pho5phcnic and phosphoric acj,-l derivativers, or of the dioxnne.
In dilute CC14 solutions the noneyelic dithiophosphonio and phosp-noric iicid.-
exist in form of two rotationil isoraers; the cyclic ani the phosphinic uo"I-
pounds exist in a single foria. The stabilization of th-c isoniirs. is due
e-,O-dently to intramolecular 11-bonding.

UDC 541-12~-21546-181547.1'118
MRNOVA, A. V., and MILLIN. R. R- Institute for OTganic ahel Physical
Chemistry lraeni A. Ye of.sciences USSR
Conjugation in SyStatm Containing a Phosphorus AtotV
Moscov, Izvosti)a Akademii Nault &9SR, Beriya Khimicheak-aym, N03, 1972, Pp 722-
724
Abstracti Tho Rai= zDoc-1LTa wid ulti-aylolet zp2ctra of compoiaids 111th d-tffexx-ent
nuzbers of phenyl and etyreyl group at tho phtwPhorw ULOM 1.'vxo stxdi-:~d to
deterzine the rolo of phosphorus la altering the eleot-ronic LIZZ"wturc. Spectral
character3stics for ten phanyl and -;,ityxyl coz.-,vauzzda vu~ro
From Vie UV dzta it conclui.-ied tho pvmiorvirLioa c-f t1w fino vibratior-,d
atructurra of the B-band tind tho adOtiva incrtav!o :Ln ita ~Inten-~dty viih
inm-anin- nu-mWers of phenyl gznupa ind-icatos tho phosphorua exorts an it-wiLdLng
influence, that iat tha phenyl rings, do not fora a single conjti~;atEd syst-via.
The Ta~n spactra also sboiwal that the into r.-ated intsnslty Wi ) of the
.c
frequency v AR vas a linear function of 1*4, nwaber of phonyl groups present.

UDC 541.6l5~',3.4-2-2.4i547.l'il9t547.22
FAG I-103DIOVA, S. V., CHERIKEAL'SIClY, V. V 0 M, B ' Y:31 A
aLP. 4~ ~ttl- Ute University 'ITilanI V. 1. Wyanov-JAnln; I1,15t.1tuto for Or anic
and Physical Chemistry imeld A. Ye. Arbunovp Academy of Bciezxi~a USSR; w"d
Mzan' Chemical Toobnolo&v Inutitute Imeni S. H. JUrov
"The 1. R. Study of. the Structure of Pxoduatz Rnsulting II.-o;4 tbo Reaction
Bet'Men Tertiaxy Arsine Oxidee and Alkyl Halidos"
Moscow, Izvestiya Mcaderdi Nauk SSSRt Serilya YhWcb';-,aJmya0 No 3, 19721
pp 695-697
Abstracti The IR upctra of fR As HIT do not dArtingrulskj b~,-tween tha
3 OJZ
fo=' -a R -As - 0 -- As F3 k fon A) wrid fR s ---? 0 k~~ 0 -,~- As-
CH J%
(fom B). Ve attomp'13d to olucidate the cornlation tho of
ttwse compounia wid their IR spectra, wing tho syst,;;u-.8 ("k., )"AGO /,III
z
(compou-nd 1) )~AsO for X I (conpo=d Ila), X Dr (coiazxjiuid,
(C21 5 ; - -
M), and X - C1 (compowid 11c)j Z-(C R )3WL7 an, d
2H'

USISR
-MUDUITal R. R. et al., lzmostiya AAaderd i Eaauk C
silrlya
No 3. 1972t pp 695-697
fPh-Aso-7 for X - Br (con 0u A 1YO and X - XIO (cvmpo-emm~ Nb). Vida
2'V' 1 -P -1
intense diffuse absorption Imilds; be twaaan 550 culd IC~00 c3i Oic--raotexictic
of these syatan3. The differeace b'3ttfeen 201-113 A and b is thmi in ell, yxotori
intexaction is possible botneen the ocyg---n azd the h--aG,-.en bfut in B, it is
butueen two oxygen ators. lit s-LP-otra move u3ing ch1or*,;To.-m an-d ac-toT
the (880 cm-1) was ol)aoxrved, Indicating the fallowills di:~-'Ociation
2(C2H AsO - ~M (C2H ) AsO - NX + (C2H tozo,
5 3
It mas concludod that the wide adsorption in tho awea '?~'O - 1POO cm." appro;~:i-
matoly divided into threa bandsi may bo attrlbuted -to i4briox-PlUon by the, 011
group, particirzting in a atrong oymetrical bond.
212
1?

US S it UDC 546.26.13.9
KAI,'NY, C. Yji . (deceaseddl) B. Ye. , C I I E 1,-Z 0 Y-U I s [,, ! Y , B . D . , I Z 0 S E '-'o VA,
S. V. , and SFl!jUjT ~TT.I'-- Z , 11"a-zan' Cheamical Techuclogical Institute
S. N. Kirov, and lustitutc of Organic and Physical Chemistr-v ~Uleni A. Ye.
Arb uzov, Acad. Sc. USSR
"Pmaction of bis-(DialkylarsinQ) -oxides With Alkyl Iodides"
Izi,estiya VUZ -- Khirmiya i Khirrzicheskaya Tekhnologiya, Ila! 14, No 5, 1971,
pp 724-727
Abstract~ Bis,-die thvlai!~ inc) -oxide rcacts cnergetl.caily t-lith benzoic an~'
Cd of tl-~~-
acetic acyl Jn ti-le firs" C,2--e 0 zlix anhylhr f
thylarsincus zmd ben2oic the prc,_lucts of ,-2 secon-1 reaction
insQparulble. E"':~CrIC'n K',!: witli all-.yl 11--alides icz
nore comple,.: E!-h-,,- `od Ldc. a c~:T,-st aU ina -ur- at -tic ob ained f ro, i
'Vnich a carerul worlwn .1
in
~j j
r"M i - j. c ti va r.~n
Y _~ - .1 ~'. c~
notbyl iodidc arc ,,a tLat a !;ulvei~t
oxide, hw,.x_-;cr, C_Ven afLef lleat:it-it, for _9 hirs to 100 vra.:t.

USSR TJDC 539.lZ4t547.l,li8s541-57,51~6.ii
GIDULLIN R., CIERNOVAt A. V., KrKW2rOV, F. S., FaZFOLOZHEINSKIY,
S H 4A~_U ff-N A-R C'
tftfte
Institute of Organic and Physical Chemistry imeni A, Ye. Arbuzov of
;
the USSR Academy of Sciences
"Study of Electron Effects in a Series of 2-substituted oxaphospholanoles-3
by the H-Bond Method"
Moscow, Izvestiya Akdemii Nauk SSSR- Serlya Dimicheskaya, No 11, 19?2,
pp 2585-2587
Abstracts The studies of the electron structure of phosphorus-containing
compounds (R. R. Shagidullinj et,al. , IzY. AN SSSR. Ser. khJ-a. 1123, 1966; Doki.
AIN SSSR. No 173, 135, 1967; R. R. Shagidullin, et al., lzv. All SSSH.
Ser. khim. 183, 1971; R. R. Shagidullin# et zl. , Izv. All SSSH. Ser. khim.
n68, 1971) are continued by applying the method introduced there to
2-substituted oxyphospholanoles-3. The proximity of the P atom causes a
change in the acceptor capacity of the diethylamino group with respect to
the proton. The variation in the acceptor capacity is connected with
delocalization of the electron cloud of the substitution on the P atom.
This. phenomenon is explained,by partial shifting of the unshared 'pair of
electrodes of the nitrogen atom to the phosphorus.
TwIlMn, ~lEmmnmvnf ##
on

90919v Dependence of the molecular. weight of, gas-Ohn"
(ie~hylene
rt(,Ihes
on particle sizes. Shairil Vs. I A.- V. aqj3laevgat.
SS~
R). Vysokama Soedin.. WT 5 -19T7VW,-T2 99 (Russ).
of the title -polyraer, preptiJ. br'polymn. of C2H.. in 7 the
presence of various ainti. of EtvUTiC 4, were divided into.frac-
tions of different particle size 'by sifting.' The particle size, a:,-
fected the mol. wt. during polymn; , with activated Btlikl, but hat
With unactivated EtjAl . Migrationiofth~Ti-compo4e6tfromithe
catablit surface and formation of now ktive centers. during Mac-
tion.with the Al romlonent (which.exceeds by, seveial times:the
equiniolar ratio during activation) apparently explsin~the results
obtained. DBJR
REEL/FRAME
198006402~

USSR UDC 339.4#1762.4.011.1+624.01~~
SIL'YESTROY, A. V.t and SHAGINARDAKOV# R~ M.
"The Influence of Low Temperatures on.th e Carrying CapRcity of StandAxd
Subassemblies of Steel BuiWag Structures"
Irkutsk, Probl. Oledostoykosti Konstrukts. Staley - 5bornik (Problems of
the Cold Resistance of Structural Steele.--- Collection of Works), 1971, pp 67-
72 (from Reforativnyy ZhumaIg Makhanikap No 2p Feb 72p Abstxact No 2VII76
by M. Kh. 100Ybur)
Translations A study in made of the influence of low temporaturos upon the
istrength arA deforma-tion of utvx1rzd elements of steel structures for &
nuaber of objects of power and industrial construction. On the basis of tho
&sign criteria of structural Imcomplateness, the elements were divided into
three categoriesi 1) concentrators in the basic metals, brought. about by
change in the geometrical shape of the part; 2) concentrators in the forA of
melded connections (joints) of the elexental 3) concenUmtors in the form of
adjacencies of seconaary parts to the main working alemonts. Used as the
material for experimentza large-size samples wan rolled. dead-,nelt V11 St 3 steall
n1ding ns perfoxned. by electrodes of tho type W (0101-5) in accore=co with
the zaterial of the exwained atructures. It is notad tMt. tho decisive
1/2

OPRS 5~333
25 October 1972
MI CROELECTr-,!! CS
0 mxcerpts rrom itus s ian- language book eaitad by 1. V- Lukini
-Akroelektronika, No 5, 1972, Sovetakoye Radlo Publishing House,
Moscow, UDC 621.382:621.396.6-181.5.
CONTEN PAGE
Annotation ......................................... ............. I
01).8tuary of Fedor Viktorovich Lukin .............................. 2
rd ......................................................... 3
................... .........................

IF
par'amiiters on temperature of tile surrounding atmosphere. Thuy
give a comparisov, of the parameters of thwi rlhotorenkntorn dur-
Ing operation ir longitudinal and tranaverae rodQti.
Th:.articla contains 11 figures and 6 bibliorrAph!c
r4f#rence
UDC ~21.303.)Il
Analysis of Severol Characteristics or the, Operation of a
Resonance High-Frequency ilybrid-rilm Amplifier Made ~cccrding
to a Circuiz With a Common Emitter. Aksenov, A.I., Olyaci-
_x~ov, 7.1., Forobeynikov, P.-Y- lhagl ind Xutlr-
_~4 -;I __mura.~PY'. '.I-,
U. _ ~~ _ , I --f -a d 1 t a
n e ~61,0 ction t 1k r,~ -,ktrcnikz. ZY
F.V u,< In 'use.
1;3 5. P 310, ~Oveza, 7115h.t1r, i10
1972.
,Ile a-- I CJQ Z4 Z43 an analy-.sis of thz operAtWn of a
resonance rl*crominiazure high-frequency amplifier. operating
In a linear node. Tne authors qhow that with a cvTi#,tc.!it tima
of zre amittor circult equal. to =Lro,, The mapnitudic of t"
capscivance cf the bioc*king condenser I= folind to Ile the lca=t.
They also eztab!-161~.ed that, for contemporary case-filull high-
frequency dynamic capacitancoa on the frequency r-hliracteris-
ties of the cascade can be ignored.
The article contains G fi.Curlssl 2 tableav and r tollb-
liographic refore nc as
-END-
11~734
CSOt 0702/73-S
-15-
J.,

HYMIOMETIoOlil) L06i CAL it: or AAmynl", w;
i 61''
No 12, 072, .4.,bmittoG T! pr
I ty vl tho or At ' s -mv-t
Thu Wsl(-vr.Wrv M6Lur, af ~;ov;-% lncli.:t~e,4 t!i, t ,:t
j;rvi,t 1,1V1,; 1~1 I -111J -. Tl-
v~--ty of. Lt- rop0di" It, !0,-.iltict.z of
n I; :I nd CUAL.r~ rrc tit,- r,.;,t
-i,r(vlt.v tit, llie workvra. To-%(t%i:r ~trh all the w.Nrk~-~ oZ till
T~'o! the Ovl_
-aartw - ',;all qrviQe ol Ar~mi. are nz)k_,F
Lllbl~tOlrl LQ the C.ita."n ;W~l. L.
M= Promotion or SucceNif.l. de.clopmc-It f Ow natirnal
Ltt pLeruv,il.titicttary Aviaenla utere v~s no ser. .
Th'! Individwil metcomlogic.11 ~tati.ng dr.4 utttr ~t,lt lvn. r *:
that time Lt% CW terrItory of vo~t~rn ArTimi" ware %wJ D r.
p.irLm,,jts .11,1 walk~j 3,tpar;,.~ly '10w."t
At tllC bi~t7inning o, 1914, d,srtil,: Lt., -Nl-= o~v,,I.P=rt If r,: . .....
t,id hydr4,:IVlc r%ct.;,)vk. in Atv.,nit thevc
pol"logicAl ntatif,liv. 30 nj`-,0ro~c%;j,4,,j L-.itv~;t,, -d 2,-, -y4rpjj,,,!.,
The Grenc Oc-Obe- soclalist
of tiat ndL,.Iv,,j veLith of L%tt I~CXIEV: 1.1~11~
mitAtintil contribution. In 4;tllving ttie prvb'v=, c.1 ctc,w," -,~
thu ontir,,t com~.try, o%i-. rvjkalblic.. a si-in~fi,:alit r,le :111, 1411.
tit htudyUkA tl,L -Li=cl~: and wat~,r ml,Cl~rC(16.
0.11! Of (h,. lirt~c cuncer.'s of t!w 5ovIet
pianizin,; the itictooroAugicnI obeervation syntesti u3n ;:=hinatiaii ic t1w
WsJcal Rorvicei o( dtff,rent -lepart-inceI exiatit%r. at Glac tlm- t;. I
-JM;
7'~
,~l -75

USSR uDc 616.89-ooB.46-053.2-085-356:577.i64.1
DERGACOVj V. V., PIVOVAROVA, G. N., MWIAGANOVA, T. G., Q,,1T.~GILXWLN, Ye . V..,
UMIRJSHKENA KIY - _~ 14iltd 0';~oBi clogs I t a I
., N. A., K1JLIKOVA,, N - V -, and MOMM , V. B.,
Faculty, Second ~bscow Yedical Institute imeni N. 1. Piroj5ov and Department of
Higher Nervous Activity Institute of Hygiene~of Children amd Adolescents,
Ministry of Health USSR
I'Orotic and Folie Acids and Vitamin B,2 in the Treatment of Child-ren with Memory
Disorders"
Moscow, Sovetskaya Meditsina, Vol 33, No 7, Jul 70, pp 78-82
Abstract: Since the genetic apparatun contained in all cells pmcarves not only
phylogenctic but also ontogenetic information, ari(I sitice ivucleoproteins and nucletc
acids are essential constituents of the mmory neal=tsm, a otudy 'm undertaken
in which the cofactors and precursors of proteins and nucleiv acids -- orotic acid,
folic acid, and vitamin B 12 -_ were administered to a group of children vith disturbed
nemox:.r. The results indicated~that even though short-term mmory, attention, and
certain other mental functiona were not affected, long-tem nemory improved signif-
icantly. Positive results can be obtained only if treativnt, is begun early, before
marked organic changes develop in the central ner4-aus system.
END -
5915
CSO: IM

1/2 014 UNCLA SSIFIED~ OROCESSING DATE--27NOV70
TITLE--MECHANISM OF PRIMARY PROCESSES DURING THE PHOTOLYSIS OF
TRIS,ETHYLENEDIAMINE,CGBALT #111, CHLORIDE -U-
.AUTHOR-(03)-POZNYAKP A.L.r BUDKEVICHt B.At, SHAGISULTANDVAv G.Ao
OF INFO--USSR
7S0URCE--kH'LM. VYS. ENERG. 1970t 4011 286-7
DATE PUBLISHED ------- 70
SUBJECT AREAS---;CHEMI--)TRY, NUCLEAR SCIENCE AND TECHNOLOGY
TOPIC TAGS--COBALT COMPLEXt ETHYLENEDIAMINEt PHOTOLYSISi DEUTERIUM
COMPOUND
MARKING--NO RESTRICTIONS.
DOCUMENT CLASS--UNCLASSIFIEf)
PROXY,REEL/FRAME--3008/0864 STEP NO--UR/0456170/004-/003/0286/0287
_CIRC ACCESSION NO--AP013,7692
UNCLASSI'FIED

UN-
2/2 014 LASSIF118b PROCESSING DATE--27NOV70
CIRC ACCESSION NO--AP0137892
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE PHOTOLYSIS OF (COEN SUB3)CL
SU33 A.ND fTS DEUTERATED ANALOGS AT 77DEGREESK IN A H 5UBZ SO SU84, 14
SUB3 PO S11341 OR 0 SUB3 PO SUB4 MATRIX LEADS TO THE FORMATION OF CH
SU82 NH SU63 PRIME POSITIVE BIRADICAL IONSv H OR 3 ATOMSP HYDRATED CO
PRINE2 POSITIVE, AND HYDRATED ELECTRONS. ABS* CONCNS6' OF PRODUCTS ARE
GIVEN AS -A FUNCTION OF IRRAON. TTME. FACILITY: BELORUSS. GOS.
UNIV. IM* LENINA, MINSKI USSR*
U 1NIC" LA S1 F I F D
mum

i %OEM
G C UNC CA 5 S I FED PROCESSING 0;lrE--20NQV70
TULE-COMPLEXES u,"F GERMANIUM, IV, WITH MANOELIC ACID -U-
AUTHCR-(04)-5J-AGISULTAN0VA, G.A.* KkiRNEVICHt G.I. VISHNEVSKtY, VoB.,
dOGDANOVA,
COUNTRY OF lNFC--LSSR
SOURCE--ZF. NEERG. KHIM. 1970t 15t.3)t 6L48-51
:.~'-.DATE PUBLISIIEI;-----70
~SUBJECT AREAS--.CHr'_MISTRY
.-TOPIC TAGS-GERMANIUM CGIPOUNDs COMPLEX COMPOUNDw CESIUM COMPOUNDI COBAL's"
CUMPLEXP PLATINUM COMPLEXr-GLYCOLLIC ACID
MARKING-NO RESTRICTIONS
DOCUMENT CLASS-UNCLASSIFIED
f~AHE--2000/1 705 -1817t)10 15/Q0 3/06/ia/0651
PROXY RE SfFP NO-UR/00
CIRC ACCESSICN NC--AP0125326
UNCLASSIFIED

2/2 009 UNCLASSIFIED PROCESSING DATE--20NOV70
~-(;IRC ACCESSICN NO--AP0125326
-.A8SfRACT/EXTRACT--(UJ GP-(J- ABSTRACT. MIGE(BZCO SU8Z)SUa2.PHCti(OH)CO
SU132.1-1 SU62 0), WHERE M EQUALS K PRIME POSITIVE, 1*1 SU134 PRIME POSITIVE,
CS PkIME POSITIVEr (CG(EN)SUB2CL SU62JPRIME POSHIVE, .((,T(NH
SUB3)SU34)PRIME2 POSITIVEr Oil (CO (NH SU83)SUB6)PRIME3 POSITIVE SEPO. AS
SOLIDS DURING REACTIC-N OF GE( IV) WITH MANDELIC ISG-HOLAR SERIES SHOWED
FORMATICN OF COMPLEXES OF DIFFERENT:COMPN. STRUCTURES ARE PROPOSED FOR
JHE CCP.PLEXES OF GEIIV) WITH 1.
U NC L-AS-S TFIED

112' 014 UNCLASSIFIlED PROCESSING DATE--160CT70
TITLE--SENSITIZi:0 PliOTCOXIOATION OF AMINO ACIDS IN FROZEN SOLUTIONS -U-
'.AUTHOR-(03)-POZNYAK, A.L., SJALGISULTANOVAt G.A.v ARZHANKOY, S.I.,
~_.COUNTRY OF INFO--USSR
S, OURCE--BIDFIZIKA 1970, 15(l), 2a-1
------- 70
,DATE PUBLISHED
'.-SUBJECT AREAS--BIOL.OGICAL AND MEDIZAL -SC-I-ENCES
TOPIC TAGS--AMINO ACtDj, AWUEOUS SOLUTIONvUV IRRADIATION, FREE RADICAL,
ELECTRON SPIN RESONANCc, PHDTOOXIDATION
'CONTROL MARKING--NO RESTRICTIONS
-POCUMENT CLASS--UNCLASSIFIED
,.PROXY REEL/FRAME--1996/0633 STEP NO--UR/0217/701015/001/0020/0021
CIRC ACCESSION --AP0117859
UNCLASSIFIED
MINOR,

now
2/2 014 UNCLASSIFIED PROCESSING DATE-160CT70
CIRC ACCESSION NO--AP0117859
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. Cit SUB2 NH SU83 PRIME POSITIVE
~(J) I CHUNH SU33 PRIME POSI TIVE 114E, CH(NH SU83 P;z I~ME POSIT I V E) CH'4E
SU82t AND CH(NH SUB3 PRIME POSITIVE)CH SUB2 OH RADICAL 10NS W~--RE
OBTAINEO BY ImKADIATING. AT 7?DEGREESKt WITH UV LIGHT, F;-i0ZEf4 Ao. SOLINS.
OF GLYCINE, DL,ALPHAyALANINEt DL VALINE, AND DL SSERINEt RESP., IN THE
PRESENCE OF NH SU84 FE(SO SU84) SU52 OK. CSCO(SO SU64) SUB2. THE
PRODUCTS WERE IDENTIFIED BY ESk SPECTRA. THE RATE OF ACCUMULATION OF 1
INCREASED wITH INCREASING PH OF THE SOLPIS. UP TO PH 8 AND THCN
DECREASED. THIS SHOWS THAT THE RADICAL IONS WERE FORMED MAINLY FROM
THE LWITTERIONS OF THE AMINO ACIDS. FACILTrY: V. 1. LENIN
BVELORUSSo STATE UNIV., MINSK, USSR.

USSR uDc 612.6-054.o17.4
CEIEFUMMOVSKAYAL, I. Yu., S----G Sh., and SVET-MOLDAVSKIY, G. Ya.,
--ii-
Virology Laboratory' Institu f a-pental and Clinical-Oncology, USSR
Academy of Medical Sciences
"Correlation Between the Degree of Trichinella spiralis Invasion of Mice and
Suppression of Transplantation Imunity"
Moscow, Doklady Akademii Nauk SSSR, Vol 196, No 6, 19'11, pp 1,49