SCIENTIFIC ABSTRACT YELESIN, V.F. - YELISEYEV, B.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203630002-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR UDQ C-21.31.5.592
~F.
Moscov En.- neerivg Physics 111n~titute
e ry o~~ 'he Electron- .43pectru;_, 6 1:a Se-miconducto-r With Charped
in a.szron~ E c F-e
eczroraagneta. 4 -a
T enlngrad, 171.zira i T-E-khaa PolunMVadnikov, Vol 4 X a6, Auo 70, po 1-524-
1528
bstrac, -ffecr W~aich im ~t
71 he aurhlor Considers ti,.e a SCacce-ring 'S QZ'
the e1ectron specclurl oz a Semiconductor in. the fteld of a strorg olectro-
magrzac,* cwave. z is s,-icrm. ciac scattering by, chargekd irzrl-uri ties lettds to
rair anni-**,~:c-on, and t~haz the gap disappears at some crit-Ical concentrazfcn,
The reasson is that 11-ito irmpur-I.Ly field acts' with. oppos-ILtel si~.,.ued forces on
tron and oa a ho-le. 41 ch, it; usual ly not
an elec lhis inpurity :scattering, wr,.L
tak-en into consideration in saturation theo-ly, plays a.1 imporr ant part: in
tiie Problem or' coherent Inr-eractior, betweQn t1je-olectromiqne6c L'Ield and
electrons in se-nuconductors. intensity of' the fie!Ci, at: WII'i,_h the gap
appejrG JS CSC4maved. The effect which the density of states.11--s on the
model structure of samicovductor la-sers and masers is dizcu5sed. Thc author
thanks Yu. A. Bykovskiliv and V. V. Nikitin fbr discuss-ing:the uork.
II mv,.!j in

UNCt. ASS IF tM:

11 V 1,:!.
--CTF-C-AC~*-SSIU:: NCI-AP01075-14
U, 4L. L- 0, 31 1 EU

wMENT CLASS-0'-"iGL ASS IF I ED
PAOXY RELA/fRIAME-1 994/1940 SITP NIJ,,-,IJR/ 03644 701000 /003/ Oli 15/ Olt 17
CIRC'ACCESSIGN ND--AP0115746
UNCLASSIFIED

_414- :-'612 UNCLASSIFIED PADCESSING DATE--13NOV70
ACCES51ON NO--AP01157481
ABSTRACT-/EXTRACT--(UJ GP-0- ABSTRACT. ONE OF THE FUNDAME-NTAL STAGES OF
:wTfiE -CONVERSION OF ELECT!kONS EMITTED' -TER IRRAON4" FROM METAL IN-TO THE
Ar
~SOLN.. APPFARS TO BE THE SOLVATION (-OR HYDRAT IDN) IN FHE SOLN. CERTAIN
INFORMATtGN ABOUT THE-PROCESS OF HYDRA T. ION OF, PHOT DELECTRONS MAY BE
ACHIEVED ON THE BASIS OF THE EXPTLt*
OBSERVED 0 EPENDENCE OF
ON THE CONCN. OF HYDRATED ELECTRON ACCEPTORS. AS
ELECTRON ACCEPTORS H PRIME POSITIVE: AND. NO. SUB3 PRIME NEGAT IVE IONS 'WERE
SELECTED. THE ACTIVITY OF H SU83:PRIME!-O POSITI.VE, VARIEO FROM 10 PRIME
TO 0.8M AND WAS CHECKED. AGAINST THEJi E;Lr:CTRC)DE POTENTIAL IN
~JHE SAME SOM THE DEPENOENCE~OF PHOTOCURRENTP Jp~~,TO THE 0,,4 POWER ON
Jkif- -POT ENT I AL ALPHA AT V4RIOUS. H PRIME~PtISLTIVE ACfIVITIES WAS
-P ONCN s: WkS:"t Eb,-'THEt tHARACTER OF THE
-IF ACCC ANG
-E.STABLISHED TCK C, H
-ENCENCE
-OF -THE PHGTOCURRENT.UN: THE POTENTIAL:WAS CHANGEDi AND HENCE
EXTRAPOLAT ICN OF ALL CURVES CONSTRUCTEDIWTHE SAME COORDINATE SYSTEM
MUST RESULT IN DIFFERENT VALUES OF THE THRESHO.LD PCITENT4AL- A L It.-EAR
~RELATICN BETWEEN J AND A SUSH30 POSITIVE PRIME; ONE~ HALF- ;.%r LOW A SUGH30
..POSITIVE WAS OBSEPVED. ABOVE A.SUBH30 POSIIIVE. EQUALS 0.2M THE SATN.
PHOTOCURR,ENT BEGINS. THE 1,41EAN DISTANCE MEAN,VALU~-'~OF X.,, AT WHICH
ELECTRONS ARE PREFERABLY SOLVATED
WAS FOUND FROM THE PHlOrOCURRENr
CONCN~_,ANG WAS 80-100 ANGSTROM. FACLIL I TY: JNSTII ELEKTROKHIM.,
~Ajscaw USSR'.

Milk,
USSR UDC 534.322.3+534.83
GENKIN, M. D. , YELE YABLONSKIY,:V. V.
"Methods for the Active Reduction of Vibrations With Mechanism s"
V sb. Dinaw-ika i akustika Tiashin (Machine Dynamics and Acoustics Collection
of Works), Moscow, "Nauka", 1971, pp 76-88 (from RZh-Fizika, No 3, Mar 72,
Abstract No 3ZhSO2)
Translation: The effectiveness and stability of two systeirs for the ac-ive
L
reduction of vibration are analyzed. The. systemis show prozdsc for application
in sbockproof mechaninma over wide frequency, ranges. The basic- elcament in the
system is an electromagnetic or electrodynamic vibrato'P controlled by an ampli-
fied signal f-tom the vibration pickup or, a dynamomev-r.. The vibrator partially
-orber. 15
compensates for the vibration effects at the~base in the shock abs
ref. Authors abstract.
F "991.5

~2/2 .011 UNCLASSIFIED PkOCESSTNG 0ATZ-11SEP70
Cj RC ACCESSION-'NO-AP0050859
'-.-ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE COMPRESSIBILITY OF SF SUR6 WAS
STUDIED EXPTt. BY USING A STAINLESS STEEL 'ItOrYfFIED CONST. VC.L.
PIEZOMETER (IS SIMILIAR TO 110 MLI. - THE: SATO. VAPCI~ J)~",FSSUQES WERE
MEASURED AT 7-2 TO 40DEGREES. THE PRESSURE TEMP. 0. RELATIONS OF THE
GASEOUS SF SUB6-WERE MEASURED AT 40:TO:230DEGREES~AND 20 TO 300 ATM.
THESE C04DITIONS NO REACTION OF SFSUB6 WITH THE MAT~-RIAL L
OF THE
~_PTEZOMETER WAS OSSO. THE COMPARISON OF THE MEASURrEo VALUES WITH THE
--RELIABLE DATA, SHOWED AGOOD AGREE14ENT (PLUS OR MINUS.0025PERCENT).

Acc#. Nrs
RIV043772 Ref Code: UR 0056
PRIMRY SOURCE: Zhurnal Eksperimentall v i Teoratic.-heskoy
2.. Fixikit 19700:1-Yal 511 Ar.'3, pp j~
ENERGY DISTRIBU"ON -OF piEroTotjECT~o
IN A QUANTIZED -MAGNMC FIELD - FAG
,AND ~MOTO~ XM,,c
0SCUXATIONS 00 THE'.GUREV.1C* YWOV TYPE
A. S. Aleksandr~v,
La
Relaxation of noneqidlibrium electrons produce .d4a a sern1Ronductor by light is
considered for -the case of a quantized elic Up d. The k
Ji!jelic equation for the
.0
eltergy pbotoelectron distribution function when'. tbty electrons *1 teract -with optical
Phouons and equilibrium electrons can ba reduced to' a set of: alij-61naic equations with
shifted arguments. The small parameter iu, this Case 45 the quantity q vrhich is the ra-
t1o of the Fermi energy (or temperature for nonftenerate) e0tilibrium electrons to
the Larmor* frequency hP. (ultra-quantum case)., An exact: solutioii of the algebraic set
of equations for the distribution function nith small quaTitum niimberi is found. Tho
characteristic relaxation times.in a magnetic fieW are calculated for electron-electro'n
intenction. It is shown that electrons with, ener .gies~ smaller than fig, in general do
REE
19770179

USSR uDc 615.917.547.2621.036.1i.o7:616.36-0081.~re2.1:.616-oo8-939.633.2-074
Second Moscow Medical
Chair of Cytology.and~Histolq,~Y,,
Institute im-eni 1. Pirogov
"The Effect of Acute Alcohol Intoxication on OyidativeoPhosphorylation in Rat
Liver"
Moscow, Parmakologiya i Toksikologiya., Vol 35, No 2, Yhr/Ap:r 72, pp 198-199
Abstract: Tests conducted on rats demonstrated that acute m1cohol intoxict.,-tion
causes dissociation of oxidation and phosphorZ~lation iii the liver. After
intragastric introduction of 22 ml of 50%,alcohol per kg bod,*T weight, phos-
phorylation in liver tissue begins to-fall in 15 min, reaches a minirmm (about
50% of the control level) in 24 hr, and then-.gradually~returns to normal over a
period of 8 days. aqjgen cons-imption Alpo diminishes but to a lesser degzee.
Thuslo tile 11/0 ratio docroaaes from a control value of about 'P to a minimum of
0-177 In 24 hrs and is restored to normal, in 8 days. ftwse findinor, conf iri.-,
the previously expressed idea- that,disturbanees in redox processes -play a
major role in.the developient of p4tholodcal changes im the. liver fOllQ1riDr1
alcohol-intoxication.
46

USSR ;UDC 612.821.6
AGADZHANYAN, N. A., DORONIN, G. P., andX"MV A-1
"The Effect of Pressure Chamber Trainini on.:Chain Moto,~ Conaitioned
Reflexes in Rats
Moscow, Zhurnal Vysshey Nervnoy Deyatel'nos,tii Vol 22, No 1, Jan/Feb 72,
pp 37-45
Abstract: Experimental rats were subjected to training in the pressure
chamber at a simulated altitude of 5,000.m. Rats were.kept in the chamber
for 1.5 to 4.hr/day for 10days. Befor& and after the chamber training,
the anirialfl were exposed to a simulated altiLude of 10,000 m and in some
cation to 1.2,540 m. One grotip of rats wnt3 conditionall" trainod to f!,e-,L food
by a coir6inaLion of reflevcs. Glomactomy wa performed on rinatlier eroup
of rats before croining in die r
p. easum chamber. 111e; 01.17d ~1;roup was train-
ed at 3,200 m altitude ia Tuya-Asha mountainsi and their survival was checked
exposing them step-wise to a 12,000 m simulated altitude at a rate of 25 m1sec,
In the case of untrained. animals in the.-first group, seveile and prolon-cd
disturbances in conditioned food reflexes weTe observed, stayting with the
5,000 m altitude. A complete inhibition of these. refl(Mes w,--s Observed at
7,000-8,000 m altitude. AdapLatioji to hypoxin in the court;e of 10-day
1/2
36

USSR
AGADMANWIT, N. A., et al., Zhurnal Vysshey Nervnoy Deyatel'nosti, Vol 22, No 1,
i /Feb 72,.pp 37-45
an
training in the pressure chamber secured:the necessary physiological abifts,
which were expressed in a more effective use Of oxygen..: This prevented
severe disruption of motor reflexes and facilitated the readjustment of
rats to high altitude conditions. In..animals~devoid of sinocarotid receptor
zones, the adaptation to severe hypoxia was very slmt (13 rats died at 5,000 m
during the first two days, and others perished at 000 m). This indicates
the importance of chemore.,-~eptors in the compe,nsatory-ad~ptive reactions of
the animal organism.
2/2

uw 61.6.273-2:6lp,-1~88
AGADMATIPM11, 11. A., T SIAV, 1. 6.) K01,12,A) ~E. A., li-SAKOVA N. h. and
-Lr
MMOV A 1, m5titutc of Plvrsiolo ineni 1. P. Pa,,r:Lotx, Acade j of
-StTe- SSI
ndc~ UO 1, LmainE~ad
'The Role of PcriT_,henal Cheiroreceptors in Reactions of Ralts Subjl~,cted to Short-
Tern and Prolonged
V noy 1 10
Byulle'ucnl 117,ksperinen"al _jioIo_rJ i i Maditsiny,:,Vol 1, 10, 19,m"
-15
"ic 1-cle ril thc s..,mocno-oticl, ar-cl- nortic rcfIc.~c'.C)-;Cnic
Abstract:
%on,-,s
oil reslaratcr-l'!, of I
-'c- to -ict
':ijj,~ VC-A
s1fbJec A "*Ia~J.Oji irj intac,` wats, bicr.thim,
u ~d.
with the air con6-c!J.,-Ii;a,-I 114;,' Uo~, 83.6 ift-0, incroased 20---` ca:-marod
Di"
N'a notiac,-~ble chan_i-os i,!cyc obioi-,ru: on rats
vith V i e Y., nno. 1a i,_
aro'.jds, or, 1-.;-)th sides ar~ i :,7":
vi a deaff rem: brcathin,,-, J:I
V
was ~,Lzc for A,ats with aort-1-c _,onc.
k ia
It xf~pid, of iut~.f~,t raLs ,-,0 1.1-~,.r.1.4
brcuthiri-.
L; nats
lvater and wz-_.s In ir)",%etu rato. ib. rarlbcr CI' he').r-L,
in, bolth I-volqls Of CA,), sir;l:~ fi Q01"
Ij( th

f
U.
SSR
AGADMADW.1-11., i,,. A. et ~-l
Bytille ten Bkoperim-n-Lal noy Biologii i 1';edits1,qy-
L
Vol 74J, No -30J 1-972, PP 11-15
the cardiovascular anctivity. A decrease in the ~ p02 in the thim ix,-=1c of
the deafferentated ra:[-.s i-ras iriore noticeable imdle.r severe hypoxio.. I.,lien anirlaIS
levation (DO, = 85 1 r, Ifg), t1he -~nzwlbcr Of resrira'-ions
U
OPellt 30 ~in 30 T! C ' e.--
P
increased durii,." the first 10 mdn arid uras liirth durinC. 'Uhe. enLir-- exposition
wer In d-~--fferortated -rats. niere werc no sii-,rAficant differ-
tine, but was lo
enc-2c in the reaction- Of the thoi moral,,
,his elevution. A cc-..iplete excj'.-.i,,,ion. of thf~
in p% presswre in ta- th-Up i.iasr-le'i of ratG Ct :~l
"ll low O-iom
elevation 0 arocha-'er) I;-.LL, c (I] Ic; -It'l 111- i 0! 1 and renta
re.-lUX, died within 0"'i and 63, nt 1.2, ~180 III eluva'-io:1. 11C
~grjificant Challf'os In the warc: 01)~;.urrud vlwqjr~ J,q) ~11)
1
5
of rat:; placco, Ill ch:t!1-i~.),!r", v.1.V1 wcyguni Por 30 dayo. 11;
tile perijkler,13. clvn;~Gruceptort; p*lay a dwrinitc,, Pole, ill rj. Lr,.ptu`Q~', on o1' th,-,
a
niml organism, -to oyy;,,zal fit thc sa.ie time; tho oynocaro"lAd
chemrccepto--rs do rot p? VT aly
17,- - tificant role in reactioi-,~i of the
in res -; - Since -61,,,---,
to ht L I
vascular and c a i 11 ai 011,241 Y.
d-id, not prod-uGe f.,ij-p-lifica-mt chnn,[~~-s :~n the
entilation in re-spon.,u to hypo,"Jut '11.4. Can be 1,=,twod th"tt (:A-her
v U
-his
GN'Stemo, yet I' p uale v, t roec,,
art ii, .
27~
do -

-17 7-:7
USSR uDc 612.ili,3+612,275.1
AGAMBANYAH, N. A., ISABAYEVA, V. A., BEBINOVt M M., and 9Q
"Role of tie Arterial Chemoreceptors In Adaptation to 11igh Altitudes"
Frunze, Sovetskoye Zdravookhraneniye Xirgizii, No 6, 1971, pp 8-13
Abstracti Experiments were performed on intact and denervated rabbits and
rats imported from k1loscow (sea level) and.marmots.al, 4 altitude of 3,200 m
ar
to study.the part played by the sinocarotid:zone In adeptation to a mountain
climate. The criterion of acclimatization was the "suxvival time" at an
altitude of 12,000 m (elevation in a pressureichanber at a velocity of 25
a/eec), Tolerance for high altitude did noiincroase in the intact and
denervated rats until after 30 daya of acclimatization, The "riurvival timall
at the "altitude" of 12,000 a was significantly longer in the intact rats than
in the anir.Lls vrith excised sinocakotid glomera. The results uere essentially
the same in the exi)-e-riments idth the rabbits.- Bu:t in the experiments with
the ma=ots, the "survival time" of the intact animals at 12pOOO m was 780
Sec compared with It280 sec for ths glorectomized aiaimalri, High altitude
tolerance was therefore greater in-marmots- 'than in the::animals living at --ea
level (rabbits, rats) and a glomectomy caused opposite changes, Whereas high
1/2
Li

USSR
AGADZHANYANI N. A., et al., Sovetakoye Zdravookhraneniye Kirgizil, No 6, 19?1,
PP B-13
altitude tolerance of the rabIAts and rats decreased after denervation of the
sinocarotid chemoreceptors, it increased, in the naxmott3. The dynanics of
changes in the RBC, prothrombin time, fibrinogen.concentration, and other
hematological indexes showed the same pattern. For ex4anple, the number of
MC and hemoglobin content increased considex-ably in the glomectomized rabbits
-(more than in the intact animals) :but decreaped in the;., rArmots. Thus, the
sinocaxotid- chemoroceptors play a significant role in ihe process of adaptation
to.high-altitudes.
2/2,
IN InM

UDC: 621.396-983
BBLOUSOV, N. N., YELF114OV, V. I., and KIRSANOV,.N. i.
"Optimal Algorithm for Measuring the Dispersion of a Random
Process With the Effects of External and Internal Additive Noise
Taken Separately Into Account"
Kiev, Izvestiya VUZ SSSR--
Radioelektronika., No,101 1972, pp 1291-
1-294-
Abstract: The problem of measuring the dispersion of a normal sta-
tionary random process on a background of normal stationary noise
is considered, where both signal and noise processes are noncor-
relational. An equation is given for the conditional estimate of
the signal dispersion for an accurately known noise dispersion.
does not
Although the solution to this equation is well known, ;L
take into account the separate effecta of the external and internal
additive noisea. To correot this omission, the prerjent brief corn-
munication offers a method of eliminating the effect of the in-
ternal noise of the measuring. device on the accutacy of the signal
dispersion measurement. In developing the algorithm for the dis-
persion measurement, the authors assume.that.the.samplings of the
1/2

:7
SHIS-IflaRr B. YE., YELFIMOVAI S.,N.,,and NO, B1. 1.j Vol&grad Polytechnical
In5titute
"Conversion of Hydrochlorides of C-Phospborylated Imid4ates Into Amides and
Phosphonylearboxylate Esters"
Leningrad# Zhurnal Obahchey Khimii, Vol 42(104), Vyp 10, 1972, pp 2346
Abstracti Thermal decomposition of the hydrochlorides yielded alkyl chlorides
and amides Aing to
of -dialkyl!phosphorW~carboxylic,acide adpi
(RO)21(0.)G"IC1'2C(011)=NII - IICI (RO)211(01
+
The reaction was carried out at 110-1300clalkyl chlorides were collected in
0
a -trap cooled to -70 C, amides were viscous liquids which Matallized in
1-2 months. Hydrolysis of (I) yielded -dialkylphosphonylpropionate eaters
(0) Olt+,
112,

MC 614.?I5o6I4-72
,YELPIMOVA, YE, V..Candidato-of Pledical Sciences, GWEV,41. I., Frofet3sorl
NOVIKOVt YU. V., Docior of Medical Scienciast YWIRAJ To V* # BERGEDYBV, A. F.,
CarxUdate of medical Sciences# Mwcau, Scientific Reseam~h Institute of Hygiene
F. Ex-Isman
."Study,of the Combined Resorptive Effect of AtmoBpheric:Pollution (Gas ajid
Moscow,, Gigiyena i Banitarlyaj No 8j1972;.PP 11-15
Abstracti A study was made of the combined effect of riulfur d1oxidet carbor,
monoxide# phenol and finely dispersed dust characteeLstia of the air p-~Ilution
caused by ferrous metallurgy onterpa~ises, Experiment A ~ etudies hzaro- Iyarfomed
on white ratn for 96 dayu in the pnisence 9f an aeroBul Ath the following ,
concent-mationst S02 0"05 mg/d, CO 1 mg/a , iphenol 0.01 jng/m,3 tmd 0.15 ng/U3
of dust. Significah-L changes took place in the animals, with resI)ect to all
to-sts, The effect of the. aerosol in a concentration o;r 0.5 MVn) iraplies a
reduction in the total nucleic acids and the parmeabillt~ of tha histo-
hematic barriers in the ovaries. one group of ~ rats w, :de,vrent &-table ch.'_.III,8'O$
in bohavior and bioche mical and physiological reactions.~ The total combina-
tions of fractional concentrations of the substances with respee" to their
threshold values at a level less than one 067.6) has no offeci on the a_nimals-

Im "'.IJA
USSR
YELFIMOVA, YE. V., et al., Cigiyana i Sanitarlya, No Bt 19?2, pp 11-15

tMC ~616.61-002.12"1-02
AGAFONOV, V. I., Maj Gen Med Serv, Docent; LEV, M. I., Col Mad
-e'of Medical
Serv; ROSKOV, F. S., Lt Col Ned Serv, Candidat
Sciences; ~rC_-:,11KL0VFA Ye.., Candidate of Biological Sciences;
Cahdidate of Kedical Sciences; GP..VRILYUK,
B. K. I .D 0 C t FF-oT- P-e-c"Ri c a I S c i e no e sKULIKOV,.I..A., 1~t Col Med
Serv; YEPRIOV, L. S. Lt Col Med Serv; SERGEYCHIK, I. I., Capt
Ned 5erv; B=AYEVA, H. S.
Etiological Decoding of an Outbreak.of~Hemorrh&gic Fever With
a Renal Syndrome
Moscow,. Voyenno-1-TeditsinskLv Zhurnal, No 9, Sep 71, DP 46-49
Abstract- In June and July 1970P in the southern area of
Khabarovskiy Xray, an outbreak of hemorrhagic fpver~with a
renal syndrome (URS) occurred amon,-
workers employed on con-
3truct-ion work and housed in a tent~ca= located on a hill sur-
rounded by swarpy meadows. Despite repeated radent extermina-
tion, the caiap Pres waS infested with rodents and ticks. Relo-
U
cation of the workers 1-o a nearby village halted 'he outbreak.
Only one of tho 34 hoopitalizad worlIcers died. The onset of the
112

AGAFOITOV V. I., ot all Voyenno-Meditsi iy,Z No 9,
y __41isj; hurnal,
Sep 71, pp 46-49
disease was acute, and fever of 39-410C lasted 3-15 days. Renal
and cardiovQscular insufficiency developed in five patients.
The alinical picture was atypical, suggesting both HFRS and
loptospirosis. After test for Leptospira proved negative in
all paiients, two types of tests ifor~ h-emorrhagic fever antigens
were Performed: indirect hemar,
'glutination inhibition and agglu-
tination with fluorescent antibodiesi In the indirect bemagglu-
tination tests, sheep eryth--ocyte's,sensi-tizeci.with antibodies
against the 10-10 strain of hemorrhagic nephrosonephritis (HNN) S
were used. All tests were positive..~ The fluorescence tests
tk
yielded green granular fluorescence in spleen smears. It is
concluded that the green granular fluorescence is sDecific for
HNN, and that the granules represent areas of replication of
'the HNN virus.
2 /2
41

USSR ujjt,: 661.326
BRILLIANT, M. D., YELIMELEFM I M.
"Pneumatic Keyboard of a Typese'tting Program Computer"
Pnevmatich, sredstva i sistemy up7r. (Pneumatic Devices and Control Systems),
Moscow, Nauka Press, 1970, pp 351-354 (from.M7&tomatika, Telemekhanike i
vychislitelnaya tekhnika, No 9, Sep 70, Abstract No 9B478)
Translation: This article contains a description of a typesetting program
computer used to prepare a program for controlling a typ"etting machine..
The schematic diagram of the pneumatic equipment is presented. The pneumatic
keyboards have been tested and can find application in ke*board devices of
typesetting program systems: for example, in'computers,. control panels, and
so on. There are three illustrations.

...........
USSR uic:615,779-9:0512-886
YELIN ~D. M.) Col Yled Ser and GRUZDLV, A. V., Lt. Col Med Se:r v
~"Toxic Effects of Preparations of the Streptomycin Series on Cochlear and'Vesti-
bular Functions"
Moscow, Voyenno-Meditsinskiy Zhurnal, No 4p 1970P pp 82-83'
Abstract: T~ae deleterious effect of streptomycin preparations is :-'.en in
military service suffering from tuberculosis were given one gr,-.:,, aa:.1 of strepto-
mycin, -intramuscularly. Complaints of noise in the earsi dullnes5 and dizziness
appeared in some men, who had received 15-60 grams of streptomycin. More serious
..damage of the acoustic nerve usually occurred in older mn.- Caloric nysta-mus
tests showed that the vestibular apparatus was involved less freqvently than the
Cochlear apparatus. Treatment was instituted on the first appearance of :~yraptoms
of intoxication. Streptomycin vas discontinued,* Patients were,given a s,~Iution
of ATP or Y-AP (myo-adenyl preparations which bas-a similiAr metabolic role to ATP.
The use of these products either cougAetely:removed or markedl,-yr: Al ml nishe the
toxic effects of streptomycin.

USSR
YELIMELEM, I M., and SIDORKIN, YU. G.
----------
Struynaya Avtomatika (Pnevmonika) (Jet Automation (Pneumonics)), Leningrad,
."Lenizdat," 1972, 211 pp, Annotation p.2,.Table of Contents pp 210-211
Translation of Annotation and Table of Contents: The book sets forth the
basic principles of jet pneumoautomation (p4euno.nics)--- a now automatic
control technology, which in many cases ha 's significant advantages over
electromechanical, electronic, and especially pneumatic (with moving
mechanical paxt:5) technology,, Examples are given of:the use of pneumonics
in vaxious sectors of industry,
The book is Intended for a wide range of engineering-and-tachnical
and scientific workers occupied with problezz in the.development, planning,
and use of new automation haxdwaret~asyell:as students in the respective
specialties.of secondary and higher technical educational institutions.

'n"
- ",- p
PITIT, I. Ul~Wllu .14i 66iiiiii
;l: ~ 111-ILAW, EIME11, IM111.11111
-"- - 1. - ", 1--: - -l'77 , i-i -1-1.1
I,- - - - - - -.. .--. , y , ~,, ~ -, --.- I I

USSR
YELIVXLEM, 1. M., and SIDORKIN, YU. G., Struyti-aya Avtomatika (Pnevmonika),
Leningrad, "lenizdat,".1972
Chapter IV. REALIZATION OF L40GIC F .UNCT ION .S USING FLUI ID-
JET 0 8 a . 0 a a a a 0 a 0 4 a a 1 0 a 0 a 4o
1. Bazic Principles of the Algebm of Logic ...... 40
2. Realization of Simplest LogidFuhetions by Maans of
bidumonic 46
Basic Evaluation Criteria for'Fluid-Jet Logic
Circuits... of ........ a'. a
a a a 0. a 0., 50
4. Basic Design Principles of:Fluid-Jot Logic Gir-
cuitsesslys0#6100a"Wasse 0,4 0 4 0 #a 00 0 a a 0 a a's a a a a 4 a a 0 v 0 a 0 a 51
5, General Methodology for Construction of Fluid-Jet
Discrete 53
Chapter V. TRANSMSSION OF PRESS M. SIGNALS OVER COM MWICA-
TIM MAIINKS.. 0 .............. 0 0 0 a a 0 9 4 0 4 0 2 a I g I a I a 6 a a i a a 0 4 59
3/6

USSR mc: 621.396.69:0621.318.4(088.8)
YELIN, L. B.
tance Coll"
An Induc
USSR Author's Certificate No 2669217, :filed.2 Aug 68, published 1 Jul -10
(from RZh-Radiotekhnika, No 12, Dee 70, Abstract No 12V,390 P)
Translation: An Inductance coil is proposea w2hich. cons3ists of a coil form
with-winding located inside two cylindrical ferrite cups and equipped with
.&Ti adjusting element. To improve. the electrical parameters of the coil,
these ferrite cups are cut along the~&neratrix of the -cy-linder parallel
to -the axis of the coil.

USSR WO 669.72lu,472(088.8)
TEI,2,, 11. R., B;Z-
YU. 11., MLOaTMEY, A. V., CMWAY , I. A.,
M, TSIDVITUSEVt G. V
a,# PIljrk, G. P :;U~~t'-Kar-enogorsk
Titaidum-IrIagnesium Combine imeni 50thInniversaxy of October
"Vacuum Iadle"
"4104, filed 28:No
USSR:Autho--Is Certificate No 21, V. 66,-rublished 5 Jan 70
(ftom RZh-Metall=-g-4,ya, 11,10 1.1, Nov 70, Abstv-ct No 11 G139 P)
Translationt A design is proposed for vacuun ladle uh-Ich consists of a lock
and- a-tap hole. To,simplify the servicing of the. xagnusiun electrolvtic
-"duction eellst it is equipped with a b en:ig- device,-ithich is irzde'in the
ha of a branch connection'with bottom closing devices nownted on the lid
S
pe
of- -the ladle.
29

-vw
2/2 014 UNCLASSIFIED PROCESSING DATE--040EC70
~CIRC ACCESSION NO--AP0136712
--ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. MICROFICHE OF ABSTRACT CONTALNS
GRAPHIC-INFORIMATION. THE RESULTS OF THE:CONTINUED S,TUDY,OF DIPHENYL
ARYLAMINOPHOSPHONATES ARE GIVEN& THE P-f'S.S[B-ILITY OF: TRAINSESTERIFICATION
~OF.01PHENYL ESTERS WITH ALKALI ALCOHOLAT ,E-S tS DISCUSSED Atli) THE
~:STABILITY OFDIALKYL ESTERS IN.ALKAL.LNE:MED.IA FOLLOWED BY COMPLE'rE
HYOROLYSIS IN ACID MEDIA IS OESCRIOE01P .:A S,-TUOY WAS.AADEOF THE ALKALINE
HYDROLYSIS OF DIPHENYL ARYLAMINOPHOSPHONATES IN AWAQUEOUS KOH SOLUTION.
SUBSEQUENT ACIDIFICATION.YIELOED FREE ARYLAMINOPHOSPHONIC ACIDS. THE
ACIDS,-RECRYSTALLIZED FROM ETHANOL; HAD: mELTING.POI NTS 41GHER THAN THE
INI.TIAL ESTERS THE HYDROLYSIS: REACTI ON OCCURRED ~AS FOLLOWS: THE
"POUNDS OBTAINED BY THE ALKALINE HYDROLYSIS ARE,S-fiOWN IN THE FOLLOWING
A6LE:' ITABLE SHOWN ON:MICROFICHE),~ FACILITY: LNSTITUT.
ZIKO ORGANICHESKOY KHIMIlt ANIBSSR:; PERMSKIY,ISEL:SKO.KiiOZYAYSTVENNY-
UNCLASSIFIED

USSR UDC 547-574-f-241
K
'YE, ti
N. S.j M, V. D. Institute of Physico-
Organic Chemistry, Academy ~or~of43ae~nmgc'-.o-~s-h~BeloruBsian SSR; Perin Agri-
cultural Institute imeni D. N. Pryanishnikov Perm, Ministry of
IxA i ulture USSR
gr a
"Obtaining Aminophosphinic Esters and Their Acid Doe om,pos, it ion"
Minsk, Vestsi Academiyi Navuk BelaruskU SSR, No 2, 1970, PP 87-90
Abstract: The esters of a-minophosphinic acids were obtained by co-
condens tion of aromatic amines an-d-,aldehydes with dialkyl- or
diphenylphosphites, and also by condensation of;aromatic Schiff's
bases with the above phosphites in the,:.-presenco-of a catalyzer,
concentrated HCI or SnC12. They are white or yellow oryst, al S
soluble in ether, alcohol, benzene, dioxano and;acatone. Attempts
to 'use azomethanes with ortho"substituents gave. negative results.
The authors prove experimentally,that 1IT-ary). substituents of
"he aminophosphinic acids are compl tely decomposed in hydrocialoric
and acetic acid3:
1/2
85 -

-:.. P/P

'JD C:547 574+241
0SR
Institute of Physice
KOZLOV, N. S., PAK, V. D. ,YELIN..p
M ~-Jrl
Organic Chemistry, Acad ences.Beloruss.ian SSR; Perm Agricul-
tural Institute imeni D. N. Pryanishnikov, Perm, Ministry of Agri-
culture.USSR
"Some Properties of Diphenyl Est6rs1of::N_aryl Substituted Amino-
phosphinic Acids"
Minsk, Vestsi AkadeDdyi Navuk BSSR,: No :2, 1970, pp 102-10L,,
Abstract: Failing to achieve transesterification of diphenyl esters
by aliphatic alcohols, the authors Accoraplished'it readily with
of alkaline.metals
C H CHNHC H _R
6 6 4 5~11NH0611[t7'
51
+ 2RIONa 20 H ONa
6 5
0__p(OC H 0-- .(OR
6 5)2 2
where R
113
H, n-CH m-CH R, CH C H
3v 3 3 7"
C H
4 91

zi I
ij
ZSSR
XOZLOV, N. et al, Vestsi Akademiyi Navulc BSSR, No 2, 1970,
pp 102_10,~,
The-authors also succeeded in obtaining IT-aryl substituted emlinophos-
p =c aci -in; solution of potassixm
hi d by heating the esters An aqueous
"'_-hydroxide and saponifying the*m,,and subs6quently:treating then with
_a,we
ak solution of HCl:
R _-R
KOH
CH-NH_ + 2C H OK
6-5
0__P(OC H 0--P(OK)
6 5 2 2
H-Cl
RI
P OR)

USSR twc 547.861 07
YELINA, A. S., MUSATOVA, I. S., and SYROVA,.G. P.
"Pyrazines and Their N-oxides. III. Synthesis and Properties of N-axides of
:2 and 20-substituted Pyrazines".
Riga, Khimlya Geterotsiklicheskikh Boyedinenlyt No 9, 19721 PP 1275-1280
Abstracts The synthesis of H-oxides of 2 and 20-substituted pyrazines is
described. Under the effect of alkaline reagents, the synthesized di-H-
-oxide of pyrazine-2-carbaldehyde in which the aldehyde group is In the
hydrate form, undergoes oxidation-rjduction leading to deoxidation of one
of the nitrogen atoms of the ring and oxidation of the dihydroxymethyl group
tubercular activity in
to a carboxyl group. In connection,with,the high anti
vitro of the di-N-oxides of unsubstituted andli-substituted amides of
quinoxaline-2-caLrboVlic Acidp the corresponding derivatives in the pyrazine
aeries were synthesized and their, biologicaL. activity, iras studded. Para-
-magnetic resonance and Infrared spectral.data am also:gIven.

USSR UDC 547.863.1'7811861.o?
YZ"AA*,Ac~5,o# MUSATOVA, I. S., TSYRUL'NIKOVA, L. C., All-Union Scientific
Research Chemical-Pharmaceutical Institute imeni S, Ordzhonikidzej Ploscow
"NI-Oxides of Imidazof4,547quinoxalines and Imidazof~,5-gpyrazines-
Riga, Khimiya Geterotsiklicheskikh Soyedinaniy, No 9, 1972, pp 1266-1270
Abstracti Thn synthesis of mono and di-N-oxides of methyl derivatives of
imidazo-,C4,5-bfiquinoxaline and, izidazo6t5-9PYr;azine1:is described. High
reactivity of the 20methyl group in n-oxides,'of. 20zeth~limidazOLW,5-9-
-quinoxaline was found by comparison with the correspor4ing unoxidized
derivative. No noticeable antibacterial activity was, detected~ Experixental
precedures and results are presented. for the synthesis: of 4-LN-oxide Of 2-
-qethylimidaz0L4,5-gqu1noxaline (II) and .4#9-di-N-oxide of 2-methylirddazo
iT,5-30quinoxaline (III), the conversion,of 11 and III -into the 4-N-oxide
of 3-amino-2-hydroxyquinoxaline (IV) and 1#4-di-N-oxideaf 2-azino-3-hydr-
oxyquinoxaline (Y), the N-oxidation of 2-methylimidazOL4r,5-gpyrazine (Vla),
li-oxidation of 5,6-dimethylimidazoC4i5-b-7pyrazine (Vlb)~j the synthesis of
-benzyl-5,6-dizathylimidazoL4,glc-gp ~:no (IX j rwno.-Ji-oxido of 1-benzyl-
yra#
-$o6-dimet~.ylimidazog#5-f/pyrazine (X)j 4-N"'ox1de of 2-Intyrylimidazzo
1/2
16-
W111-ft 1-

USSR
YEUNA, A. S., et al., Khimiya Geterotsi,klicheskikh Soyedinemiyp No 9,
1972, pp 1266-i27o
quinoxaline (XI), 4,9-di-N-oxide of 2-styrylimidazo
7 /~--15--b7qulnoxaline
1), 2-(o-hydroxystMl)imidazoff,5-g~uinoxal-ine (XVII), 4-N-oxide of
2-(o-hydroxystyryl)imidaz~S#~~~uinoxaline (XVIII), the oxidation of com-
pounds I and II by seleni um dioxide deoxidation:of the styxyls XIII and XI
by. potassium manganate, the reaction of 2,3-diaminoquinoxaline with dimethyl-
formamide and the synthesis of 2--nethylimidazoC4,-5-b7auinoxaline.
2/2

USSR tMO-6210357-12166i-418(088-8)
EBERIL' v I*,, )~VA M* j SHM j V, V*# TSEYTLINt~R% Ij YURKOVI L. 1.9
GURVANOVI L. S.s WHYAGINt V. I.t FANCUM, MV B.j and.SHOTALINt A. H.
"Process of the Decomiposition ofhotive Chlorine in Solution!'
USSR Authors' Certificate No 335ZIll filed;20 Jun 60p published 15 May 72
(from Beferativnyy Zhurnal -- KhImiyat' No 8j (11)1~ 1973, Abstract No 8L254P)
Translation.- A process is patented for the dissociation of active chlorine
in solutions by means of heating# which is distinguished In thate in order to
increase the velocity of dissociation,, a. process occurs in order to maintalz
a stable pH value -for the solution equal-to 5.5 to 6.5. It Is proposed to
carry out the process by bubblirg gases which have.been pre-heated and humidi-
fied to 60-100% (relative to the temperature of theLsolutlon)~, The value of
the pH of the solution during the process starys in thm region 5.5 to 6e5 by
the addition of alkaline or alkali salts to the solution4, The temperature of
the solution Is confined to the region.60-1000C, The process is carried out
either as a batch or as a continuous systemp for exasplep for the flow of
the prt-heated solution across a st*j>-vis6_ capacitY Pattorn, The solution
is wAa alkaline at the beginning of the procesal that is, tl.,e most rapid
reduction in the PH Of the solution occurs~durjng the first 'stage of the pro-
1/2

11.1
I , 1. ~ , ! . m ~, !i i 1-111L , Ul 1:;, !~! 11 - :
,Z, V ~ 11 7-1 7. j '; , . .I
- at ;~4 12 ~ il,~ ~,i: ~-~ I i . a
mfn=~-N", min 1, - it 7"", FA ~.l - ~g., ~ I . ~ m
al~

Acd Nre
Red Code: UPI, 0301
hAeo3f~567
PRMARY.SOURCE: Voprosy Meditsyis~by,Khimii,:1970, Vol 16,
Rr 12 ppV.Q --Y&
EFFECT OF ANION SURFACE-ACTIVE SUBSTANCES ON HYALOURONIDASE
OF ST. AUREUS,
del'
Yelinov, N El'-!Sukari,
Chemical Pharmaceutical Institute, Leninprad
Anion surface-active substances inhibit 'the hyalourdnidasi!:--of S.. an,reus. The kinetics
of enzymatic action in the presence ot three anion surf ate-actii~,a substances was studied.
During the growth of cells with sub-bacteriosIatic, concentratibits of anion surface-aciive~
~.substances the enzymatic activity is significantly decreased 18,1~r after the beginning of
grovith. At the same time the inhibitioa,iof 06~0 was not detect6d.
-A
MinlEll RRUS MaRrAw

USSR UDC 576.881.252.098.31:577.1511..365/.095.18
VELIV.Ov ~r-ll Z111-StUAR11, A~, Chemico Pharmaceutical- Institute,
EL
YL - 10 d
eningrad
Lenit
The Effect of Anionic Surfactaats on the If alul-onidase of St-aphylo-
y
coccus aureus"
Moscow, vo~,.~,zsy Med-itsinskoy Khimii, Vol 16, No I., Jan/Feb 70, pp 42-46
-s on the hyaluron'daze of
Abstract: The effect of anionic surfactant.
St. aureus was studied. Study of the.kinetics of the ew~ymatic action
of hyaluronidase or, hyaluronic ae4d in the Presence of the surfactants
Na laurate, sulfonol, and tamoL N, - indicated thal: hyaluronidase activity
Was inhibited by these substances. Uponicultiv'ation of St. aurcus
in meat.-peptone broth for 1.8 hr. in theprescnce~of the surfactants irt
sub-bacteriostatic concentrations, hyaluron:'~dase,ac-ivity was reduced
Significantly.as,compared with controls*,,.while the growth of the cul-
tur6 was.not inhibited.

Ace. Nr
9FO3439,5- O:Ref Code: 1JR 0297
PRIMARY OnICE: Antibiotiki, 19700 5, ',N
5
'r 2, pp
EFFECT OF CATIONIC. ANIONIC AND NO NOGENIC SURFACE ACTIVE
NOGF'
'40
TICS 0 SS -OF:,QYALURO-N-IDASE FROM
SUBSTANCES (SAS) AND ANTIBIO
OSS OF
C /US A R
CELLS OF STAPHYLO CUS AUREUS~
U
q
EV 6q "--~ij A
Cbem;co-Pharulaccutical Institute, Leningrad
A numlyer of sub-stances, belonging to ionic and noh-lionoff,'~Ilc ElIrlace aCti;-e 5ub-
stances, as well as to ant,"Wotics was sluditd- ~Their effect on t-he loss of gyaluronidase
from the cells of Staphy1ccoccus aureus was founrl. At the same time it was shown
that efficaev of -cationic substaiKes was higher: th-an that of anior~;c ones, while non-
ionogemc.Lwins (40,80,85) and OP-7.had~no effect.on the enzyiiie loss, though proteoted
Wie. cells from the action of arionic deter-pnts.~ An in-Dxeasre in the enzyme level in okler
edium onaddition of cationic and, nionic sorface active: substan-es and antibi(Aic5
I
n a
se
-Was due lo liberation of gyaluron!Ja- from ;dead: alls.
REEL/FRAM
E
1971-105 4

md .1;
-.Z 2 :024 UNCLASSI FIED~ PROCESSING DATE--020CT70
.....,C,IRC ACCESSION NO--AP0109552
GP-O- INTRODUCT ION OF THE SERUM INTo THE
NUTRIENT'HEDIUM CAUSED CONSIDERABLE ACCELERATION 'OF, SYNTHESIS OF
PLASMOCIAGULASE. THIS ACTION WAS RETAINED FOR SOME TIME
-AF-TER:THE REMOVAL OF THE INDUCING AGENT ONLY 13Y THE MICROBIAL CELLS
WHICH WERE IN DIRECT CONTACT WITH THE SERUM; THIS ACTION WAS LOST IN
FURTHER~TRA-NSFER ON THE MEDIA. THE ACTION OF THE -SERUtil ON COAGULASE
--SYNTHESIS,.WAS NOT ASSOCIATED WITH ITS EFFECT OF REPRODUCTION JF
STAPHYLOCOCCUS. IN ALL PROBABILITY# THE :INDUCING:IEFFECT OF THE SERUM
DEPENDED.O.14---THE PRESENCE Of PROTHROMBIN AND OF THECOAGULATION FACTOR
VII IN' IT., WHICH SERVED AS PLASMOCOAGULASE SUBSTRATES., REMOVAL OF THESE
FACTORS BY-ADSORPTION OR BY INACTIVATION BY,HEATING CONSIDERABLY REDUCED
-THE CAPACITY OF THE SERUM TO INCREASE THE:AMOUNT Of COAGULASE IN THE
CU-LTURE'.MED -S H 3 1 -1
-I.UM._ THE RATE OF FORM.ATION; OF COArULAS~ BY TAP YL C. Cr
PROVED~TU,-INCREASE IN THE PRESENCE OF IONIZED MANGANESE. THIS EFFECT
.:,WAS 14ANIFE-SIED ONLY IN THE PRESENCE~OF'.MANGANESE IN THE NUTRIE14T MEDIUM
~.AND DISAPPEARED IMMEDIATELY AFTER.ITS REMOVAL. THECONTENT OF
,PLASMOCOAGU-LASE ROSE 14 THE CELLULAR EXTRACT OF THE FUNGI GROWN ON THE
REVEALEUIN 23 OF 37 STRAINS
!.SERUM:CUNTAINING MEDIUM.' THIS EFFECT WAS':
STUD I ED r'.:'AMONG,WHICH-REPRESENTATIVES OF -VA RIOUS TAXONO~Jlc GROUPS OF
-FUNGI, iWERE PRESENTs
UNCL-ASSt IF --------- --

UDC 0-21..515.422
USSR
GOLIK, L.L., &RTOBOLEVS111AYA, YE.S., I
RInfluence Of Light On The Faramteis Of $bSJ grystals Olase To Phase Transition"
9w. 54
Radiotelkhmika i elektronika, Vol XVII, 110'6, 4une 1972 ',pP 1, 1
Abstract: Tho effoct ie studied of light (of:excess' carriers) on the iuagnitude
tho dielectric constant ( jE ) and the pyrocurrent (1p) in SbSJ crystals.
in eadItion, the temperature of cleavage (raalluloyeniye] is Culpared 14 t he
temperature oj' the I=-aximim of cu,rvas E(T) and 11)(T). The nai,,rrituda C was de-
teriained with respesit to the capa a ~ryat3l:and was ue~-Burad by a
citance of th
Ye8_21.brid a (frequency I Mz); Ip wuu.raoorded with a UIA-2 plectrometer with
a uniform heating of' the arystal at:tha r4to I-I,P dto'6-/min. Ths authors
vitskapfor furnishin the Sb$J 01-yotals 2-fig. 10 ro'. Re-
thank V-A.I~iskho
cei-70d by editors, 22 Dacembdr 19710

: !I Ifl. 1 1 1111' . i 11:11 ; I:itl: : ~ i I I'l I ~ - 1. : 1. . .

USSR uDc 616-001.12
E."ISM M P
B
Y
DDecompression Disorders Af ter a Stay.Under 'Safd Pressuren or eit 'Safe Altitudes"
Moscow, Voyerjxio-~Ieditsinskiy Uvrnal, No 7,~1970# p1) 60-6:~
Abstract; A rev~iew is presented o:C literature data on doaownrezclon diziorders
associated with exposure to pressures and altitudes normally ccncidered to be
lisafe." A prolonged stay undor what is norl-maUy considertid a s-~fe prossuro,
especially when accompanied by physical effort, as well a.-i rapJA elevation to
vQerewgly aaf o altituda3, may result in the; aovolopw- rit of gas biwbIO.-I in the
organism, pain, and avun fAtalitios~lr procaluro!j aro Ro-.
occur at prosburad:as low 41; 2.25 atal or 01.6vations
employed. Such disorders
of 8,*000.

USSR UDC (546.8821-546-88'):535.651
YELUTSOIJ, S. V.
Spektrofotometriya Niobiya i Tantala (Spectrophotometry of Niobium and
Tantalum), Moscow, Atomizdat, 1973, 288 P-P
Translation of Annotation: The development of an exten,-:.ive metallurgj of
niobi'um and tantalum is related to rapid progress in the fields of nuclear
energy, rocketry, and other branches of industry requiring- the reliable and
precise methods for the deteimination and analysis of theoe eletuents. The
complexity of the niobiwin and tantalum chemistry lies ir, the fact that these
elements tend to undergo hydrolysis, polymerization, and copolymerization with
elements of neighboring grcjups, and am capable of forming camp'Lex cotnpaund,~
and colloi-d-gl solutioii,~. Tht-,,refore.? the cla~;zicai grzavi~=,.itriv wid
of Mobitim wid tantIA.1,11111 Im"d Jf"O"Lation
from Other do not; onti,W'y the requiremOn'to of ij-,Auotrial contro'.L.
An rA. ncsuit, spectrophotoraetric methods with the. application of organic
reagento have b--en widely employed for sotnQ time, lfo'wrewr) Ult" vaot material
accLmujtLte(j on til(, 6pectrophotora-2try, of nibb-1.umi and. -Winta,l'm is scattered in
the form of individual articles among, many: publications wMeh are in somc
instances not easily acces-.5ible. Thin monograph
only the accuimilated literature d,,t-- but also presents the researcb result~3
I110

J~ ~1~
USSR
YELINSON, S. V., Speh-trofotometriya Niobi.yaa i Tantala, (Spectrophotometry of
Niobium and Tantalimi), Moscow., Atomizdat, 1973, 288 pp,
ind his colleague on complex niobium and taantalim cum and
of the author L
pounds
the use of the most promising organic reagents. As u,result of these studies
it vas possible to develop precision photax-etric end di,fferential spectroplic-to-
metric methods for "he determination of niobimn and tantalimi in metals, alloys,
and other materials. These metbods are currently. being used presently in
industrial control. In order to comprehend the jjrocess(-:!s taking place in the
course of color reactions suitable for spectrophotometr--, the statef, of nic,'Dium
Y
and tantalum in solutions as function of the,structui-e of orffanic reagents caid.
their ability to produce color compounds with these ele=-ntj are described in
Chapters 1 and 2. The book describes in detail the met-hods based on tfie most
vali~able (for s tantal
pectrophotometry) tertiary (mixed) couipl(tx niablum aad U rL
compounds with metallochronnic reagents. The author seli;,cted the most PI-olftising
groups of organic cozqpo,,mds used in the spectrophotometry of niobiurq and
tantalum from the great number of organic, reagenta. Chemical awalysts
find in this book a detailed presentation of reliable and proved mothodo for
the determination of nioTjii_-P amd tantalum in ores, Metals, al-loys,
ateels, and industrial prorlucto, as well as rocommendtA.I.c.= Tor tile PLIr~)OSCJ'Ul
~zyntbesis of new rougents for niobium and.tantalum. Ddwstit: and foreign
2/10
2

1 . .
USSR
YELD4SONA S. V., Spektrofotometriya. Niobiya i Tantala (104pectrophotometry of
Hibbium and Tantalum), Moscow, Atom-izdat 288 pp

literature covering up to the first half of 1971 was ubed in this monograph.
The author thanks his colleagues who devoted much time and effort to the de-
velopment of new methods for the determination of nibbium and tantalum:
L. S..Mal'tseva, N. A. Mirzoyan, L. I. Pobedina
A. T. Ree-zove.
T. I. Nezhnoila
,
,
and V. T. Tsvetkova. The author thanks I. I. Brodskaya and T. I. ,
Nezhnova
for preparation of the manuscript. The author will gratefully accept all
suggestions with regard to this book.I:
TABLE OF CONTRITS
Foreword 3
'Introduction 5
Chapter l.. State of Niobium and Tantalumlin Solutions 8
1. Complex Compounds of Nibbium and Tantalum 22
2. Masking Effect of Oxalate., Tartrate, and,Oxalate Ions 33

.
-The Metal Indicating Method:for Evaluating the Stability
3
of Complex Compounds
- 35
4. Radioc
hemical Characteristics of Niobium.and Tantalum 39
Chapter 2. The Dependence Between the.Structure of Orgauic Reagents
and Their Ability to Produce dolor Complex.Compourid:~
With Niobium. and Tantal-am. 41
3/10

USSR
YELINSONI, S. V., Spektro-Lotometriya Nibbiya i-Tantala (Spectrophotometl~v of
....Niobium and Tantalum), Moscov, Atom3zdat, 1973):.288: pp
1. Main Factors Which Determine the Interaction of Reagents

with Inorganic Ions 41
2. 'The Structure of Organic Compounds and Their LightAbsorption
Properties 43
-thods for Improving the 'Specificity ofReagents
3. ML

1
Chapter 3. f Niobium Pnd Tantalum, With n~
Color Reactions o.L ,a c
Reagents 55
1. First Photometric Methods for the Determination of Niobium
and Tantalum 55
2. Spettrophotometric Determination of Hibbium and Tantalum in
-Reagents.
Tertiary (Mixed) Complexec; vith, OrGanic.

2
Chapter 4. (2-Pyridyla zo) re sore iiiol :(PAR) and Ttr', Derivat-1yes
as Reagents for the Spectrophotometric Dotermiration
of Niobium and Tantalum 76
1. The Role of Heterocyclic.Azo Compounds in, the Developv.~ent of
Methods of Spec trophotometri c Analysis 76
4/10
3

kL

USSR _7
YELINSON, S. V., SpektrDfotometriya Niobiya:i Tantala (SpectropLotometry of
Niobi um and Tantalum), Moscow, Atomizdat, 1973,'288 pp
2. Tne Complex-Forming Ability of PAR With Niobi
um and!
Tanta. 1.Wa
.
in the Presence of Different AddlUve6., 80
The Role of Various Molecular Groupings In PAR and Its
Derivatives in the FoiTation of,Complk Compounds With
Niobium and Tantalum go
4. Ability. of Niobium and Tantalum to F orm Complex Co-aq)ounds
with PAR Analogs Containing Different, Analysia-Active.
Groups 96
5. Composition and Structure-;of Complex.,Niol)ium,and Tantalum
Compounds with PAR Reagents',and its Analogs 107
6., Dissociation Constants and lwtability of Hidbium. Coikple,'Cor,
with. PAR ReaSents and its Analogs.,
Chapter 5- Spectrophotometric Methods for the, Determination af
Niobium and Tantalum in Metals: ~Al I oys, and 0001,
Materials vith the -Use, of PAR R6ag'ents and its
120
1. Determination of in -Peroxide, Medium 120
Deter7rdnation of Tantalum vith Methyl violet 120
5/10

m
WOR
i Tantala (Spectro otometry of
YEMMON, S. V., SpeIttrofotometriya Niobiya
Hiobi wm and Tantalum), Moscov, Atomizdat, 1971 3~~ 288 pp

2. Determination of Niobium in Oxalate Solutions 121
Determination of Niobium in Alloys with-111olybdenum
Tungsten, Uranium, and Zirconium 122
3. Determination of Nibbiura in.Tartrate Solutions
Determination of Niobium in Steels 124
Determination of Nibbium in.Tantalum and Tantabuzi Concen-
trantes 1.26
Determination of Niobium. in Alloys 129
Determination of Niobium in Complex, Alloys Based: on. Copper 130
Determination of Mobit m in Alloys Based on Zireonftml 1.31
Determination of Niobium in likignetic Alloys 133
Determination of Hiabium in Oreo 134
ium in Cassiterite. and in Ori~,,-:, P-Liolod
Determination of Niob
l
on -It 13~
Determination of Nibbium by the Differential Spectl-o
photo-
metric Method 135
4. Determination of Tantalum in Oxalate Solutions 138
6/io

USS)R
)OMMSOIN, S. V., Spektrofotometriya Riobiya i Tantala (Spectro
photometry of
Kidbium and Tantalum), Moscow, Atomizdat, 1973,: 288 pp
Determination of Tantalum in Alloys Based on Urani-L= and
'7irconium
138
.5. Determination of Tantalum in Citrate Solutions .139
Determination of TantalumAn Steels
h:FARAnalogs
6. Determination of Niabium and Tantalwa wit 142
.
-ith 5
Determination of Niobium u -Br-PAAR 6nd 5 Bt-PAt
142
Determination of Tantalum idth 5-Br-PAAR: 144
Photometric Determination of Nidbium.with TAAC Reagent 145
Cbapter 6. Complex Compounds of Xidbi:am vith_0,01 -Dioxya'zo Compounds 148
1.. Complex.Compounds of Niobium with,Bisazo Derivativias of
Cbzromotro-oic Acid 151
Sulfachlorophenol S as a Reagent for thei Determine-,tion of
Micro-Amounts of Niobium in ILetals and. Alloys 51
lomplexes
Composition,.Struicture, and Stability of Nidbiuml (I
with Bis-Azo Derivatives of.Chromotropid Acid 154
F Niobium in Metals and:Aljoy;s with Sulfo-
Determination of
chlorophenol. S l6o
-:Determination of Niobium witb Nitro.suifophenol 9 165
7/10

4;
LISSR
YM ISON, S. V., Spelttrofotometriya Nidbiya i- Tantala (S-Pectrophotorletry of
Hidbium and Tantalum), Moscow, A'uomizdat,;: 1973 288 Pp
Determination of Niobium with Lumogallion 167
-p of Nibbium with Monoazo Derivatives
2.. Complex Coq_ ouad.
of P Salt
3.70
Determination of Niobium vith Picramin P.
Determination of Niobium with, Acid Chrome Violet K Reagent 177
~Determinatioa of Nidbium "with Magneson, Hea-gent 182
Determination of Niobium i4i th Picramin Epsilon Reegent i85
Chapter 7. Complex Compounds, of Niobiiun w:--'th Metallochromic Indi-
cators Containing Complex Groups 187
1. Niobium Complex.Comp=ids with Methyl Tymol Biu-- 189
2. I-Tibbium Complex Compounds with:Xyle.ne Oxange 196
tin
Chapter 8. Extraction Iliotometric AzAhods for, the Dete:ill ation of
Tantalum with BaBic TrIary1methane Dya 20"
1. General Physical and Chemical Prope~rties of Compl,!!x Conpounds
of Tantalum -with Triphepylpethane Dyes (MM) 2o6
2. Tripheny1methane Dyes 217
Determination of Tantalum with Mlethyl Violet 23.7
Detenaination of Tantalum vith Malachite Green 222
8/10

-USSR
YELINSON, S. V., Spektrofotometriya Nidbiya i Tantala (Spectrophotometry of
Niobium and Tantalum), Moscow, Atomizzdat, 1973 288 pp
Determination of Tantalum with Crystal Violet Reagent 23L
Determination of Tantalum with Victoria Blue B Reagent 24o
3. Xanthene Dyes 241
Detenaination of Tanta I um with Butyl Rhodamine C and
Rhodp-min 6Zh 242
Rhr ne 6 zll
Fluoranetric Determination of Tantalum vd \Oiami
246
Application of Rhodc-mines for:Concehtrat3lon of Micro-AniGunts
of Tantalum for Subseauent Determination of its Amount 'by the
etric 14e
Extraction Photom thod
24
g
Sensitvitj IiRprovements of the Extraction Photometric Mothod
"etermination of TantAikum by, SubatitiluiliLt 11,11,U)
for the L
with Rhodamines 250
Oxazine Dye:3 252
Deter=nation of Tantalum with Nile BlU(-.Reaj3en_t 253
Determination of Tantalum with.Meldol:Blue 254
Determination of Tantalum with Capri Blue 255
5. Thiazine Dyea
9/10

2/2 028 UNCLASSI FTED :OkOCE~SING DATE--30OCT70
.-GERC ACCE5SICN NC--AP0106300
~45STRACT/EXTkACT.-M GP-0- .AB.STRACT. AWX RAY CA~IERA IS DESCR13ED FOR
STUDYING OF THE ELASTIC DEFORMATIGN OF THREADLIKE, CRYSTALS BY USUNG THE
-.CHARACTERISTIC RAGIATIO.N OF THE X RAY TUBE. - REFLECTION GJF Cl) K SUB
ALPHAI RADIATION FRUM THE (3 PLANE OF A FE, WHISKER WAS PHOTOGRAPHED.
AMED BY TENSION. THE OEVICE MEASUI~ES THE CHANGE
FE WHISKER WAS DEF0.
IN INTERPLANAR CISTANCES WITH AN ACCURACY~~OF S1141LAR TU.0.01PERCENT.
FACILITYz CALINCVOST. GOS. UNIV.9 VLADIVOSTOK9 USSR.
UNCLASSIFIED

Instrumentation-and.Equipment
USSR UDC 621.791,94S4-621.375.8.037:
681.326.-3:62-ill
TYCHINSKIY, V. P., Doctor oil Technical Sciences, VISIL'YEV, K. V., Candidate
of Technical Sciences, TROHMOV, A. A., -BABENKO, V. Pr-, SUKHMEN, G. K. ,
e C,
gineers, Res ar i nstituto for:G;is Welding, ana
EnO
Cutting Machinery
-or Gas-laser Cutting of Sheet Mate ria I s
"Program- controlled 'Machine f
Moscow, Svarochiio),c Proizvocistyo, No 4, Apr 72, pp 52-53.
Abstrea. The Institute has developed a machine for cuttincy of alloy steels,
any r
oxide lasers, allowillo
titanium. and other materials using carbon di
tour to he cut in the tracking mode. Contour control of thc machine is by
a digital progravmd device using punch tape. The machine, has beer, tes-od
using various materials including 1-10 mm sheets of low-car"hon and a I I ov
steals of various t.~Tcs. Good cutting accuracy has beon nchiev'~d: parts
have been cut fro:,,i sheets tip to 3 mi-,l thick, With C"%!11 ed~'~O- aild
very. smal I zone wi: Ifficii-,"al effect n,- ar the Cut. Cuts ".'re Vory 013 11 (~-l fot".
tontlvq of a moll I h"loter) .

USSR UDC 547.26'118
YELISEYENLIKOV, T-N., PUIDOVIK, A. N., and BUREVA, N. V., Institute of Organic
and Physical Chemistry ivieni A. Ye. Arbuzov, Academy of Sciences USSR, Kazan'
"Reaction of Mixed Phosphoric Acid Anhydrides With Chloral"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 10, Oct 73, pp 2150-2153
Abstract: The reaction of chloral-with mixed anhydrides of phosphorous,
phosDhoric, th-lophosphoric and thiophosphonic acid,s.hastbeen.investigated.
it wa-s shoim that in case of the reactions with mixed ailhydrides of die-
thylphosphoric, diethylphosphorous, alkyl(diethylamido)phosphorous,
diisobutylthiophosphoric, (tetraethyldiami 0
).phosphoroqs and alkyl
~Itioaal stage
methylthiophosphonic-and phosphorous acidsj in the.trarts
there occurs principally-aa attack of chloride ion on the tetrahedral
phosphorous atom. 161hen chloral is reacted with the' anhydrides of dialkyl-
thiophosphoric and alkyl(diethylamido)phosphorous acids monothiopyro-
phosphates are formed containing 01~0-dichloro*vinyl- group as one of the
radicals.
25

USSR LWC 34P-.914661.718.1
YIN I BUREVA, N. V., and FUDOVIK, A. N., Institute of Organic
' A e
44~emisstry imeni A. Ye. Arbuzovp Acad my of Sciences USSR
"Reaction of Amidophosphites With DWkylphosphoric and Dialkylthiophosphoric
Acids"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khtdcheskaya No Sep 71,
PP 2013-2018
Abstracti The authors studied reactions of amidophosDbites and phosphorous
acid amides with d"LaDWIphosphoric and dialkylthiophosphoric acids. It was
found that these reactions reSU'tLn -the elimination of amine and the fo=a-
tion, of e3ter-amides of subphosphoric or subthiophosphoric acid. The reaction
In reversible. The resultant anhydrides react with Sulfur with evolution
of heat to give ester-amides of mono- and dithiopyroph6SPhoric acid. The
authors found a simple and convenient methodtor.the~.synthesis of these
ester-amides In one stop without elimina-tioh~qf the Intermediate anhydrides.
..... ......

USSR UDC.541.127.3:542.~938:547.26'118
and PUDOVIK, A. N.,
BEL-SKIY, V. Ye., BEZZUBOVA, N. N.,
Institute of Organic and Physical Chemistt rbuzov, USSR
y.imeni A. Ye. A
Academy of Sciences
"Kinetics of the Hydrolysis of,Mixed Esters of Methylphosphonic Acid Which
Contain P-0-C and P-S-C Bonds"
Leningrad, Zhurnal Obshchey Khimii,,.Vol XL, No 12, Dec 70, pp 2557-2560
b
Abstract:. As a continuation o u ies epn in 1,969, the.authors examined
t d
-e reactions between water and the'0111, lion and a n~rrber of the derivatives
t
h
containing P-O-C and P-S--C bonds.
It was concluded from kinetic data that the reaction~between water and the
mixed esters having the P-0-Alk and P-S-Alk groups includes breaking of rhe
G-0 bond. Further, the effect.of p,, - d.T interaction between phosphorus
and thiol sulfur on reactivity is insignificant. The linear relationship
between the rate constants of.hydrolysis for the mixed: thiolphosphonates
and:f luorides of phosphorus- containing acids of similar structure was

j,
UDC 542.91-~66i-718-1
USSR
SERKITM., N. A., mid LITATOYA, I. P.,
WMIZE NEW,- KI-Ne, T
-,e of ical auerdbtryimmi A. Ye, Aricuzo-,-, A-cadeiv of
-Ozgazzfc and P-216
Sciences, U.
-phonic and 'Phiophosphonic
"Reactions of kridaphosphites -w-ith Alkyl=thylphos
Acids"
"N 5, 1971,
Moscow,- Izvestiya Akademii Nauk SSSR, Seriya Xhim cheskaya, o
-1044
-pp~1039
Abstrac-'%J: Th eaction of al1ky1methylphosphonic and al1kyliriethy1thiophosphonic
acids on bis(die-thylar-ido)aLL-ilphosDhites and tris(diethy1wPido)phosphite ,,as
investigated. The reactions led to mixed anhydrides of methyl-Phosphonic
(thiophosphonic) and amidopbosphorous acids. The anount of diethylwiine
(80-95 percent) forned in these reactions-corresponds to the amnunt of mixed
anhydride (70-85 percent) formed,~showing the.lack ofiside reactions. The
diethylamine formed can react both with the anhydride -rormed~ as well as form
a salt with the starting acid. GH (RO)P(X)Q.H,MZt2, partially removing it from
3
the reaction. The reactions can occur 'bbth in an orgmic inert solvent, as
well as in its absence, and the yield ofreaction proalucts is not affected by
the order In which the starting reagents: acid to phds~phite or vice versa) are
1/2

USSR UDC 541. 12 7.3: 5142. 9 38:5 4 7. 26' 118
BEL'SKIY, V. Ye., BEZZUBOVA, N. N., AKAMSIN, V. D. YELISEYjjNK.04)T,I
POLOMENSKI and PUDOVIK, A.~K.i Correspo.
R! fiding Me~mber of the
_06~~;~Uences
"Reactivity of Phosphonic Acid Esters and Their Thio-Aaalogs in Alkaline
Hydrolysis"
Moscow, Doklady Akademii Nauk SSSR, Vol:197, No 1, March-April 1971, pp 85-87
Abstract: Nucleophilic substitution on'the phosphorous atoza decreases on re-
placement of the phosphoryl o.Vgeri by sulfur. This was established as a result
of studying the kinetics of hydrolysis of various esters azd acid chlorides o"
phosphoryl ovjgen. Ilowever, it still remained unclear wheLlier the reaction
rate changed to on equal extent on replacement of the P-0 by P=S for a series
ot compounds with close structure,. This,paper contains a study of the kinetics
of alkaline hydrolysis of some7esters and thio esters of substituted phospbonic
and thiophosphonic acids. The data obtained permits t:~he conclusion to be
drawn that the change in reactivity on convertin$ froin phosphoryl to thio-
phosphoryl compounds essentially deDends on the nature of the substitutions
Qn the plwsphorus, anti a decreano in, the rooction ratq constant does not
1/2
---- ----- -

6! H:' JAW,
USSR
BELISKI
-Y' V. Ye., Doklady,.Akademii Nauk SSSR, Vol 197, No 1, '111arch-
April 1971, pp 85-87
always occur. The mechanism of~this effect is discussed, the experimental
procedure is presented, and tables of values, are: given for :the activation
energy E andthe pre-exponential fa(.tor A in:'the equation K i. A exp (-E/RT)
for the reactioa with OH-ion, and the hydr lysis ratio constants of KOH.
A definite tendency toward an increase in absolute ma$nitude of the pre-
exponential factor is noted on the replacement of oxy$en atoms by sulfur in
phosphonates. If it is considered that.nucleophilic L;ubstitution on the
phosphorus requires the formation of a pd-bond in the activated complex, the
Increase in the pre-ex-ponenrial factor Indicates htSh;availability of the
for xtucleqphilic attack.
d-orbirals of phosphorus in the chic-dekivatives
212
60

;I , i ;: ?: I [!:.
. 1 .1 1111. . -,
! , I I I --- [L-J -I,
'66i6jiiil~ 11.1-1 ~. -1. ~ 11:1 1 .1 . -h'.
i
.~igi-i-cEal .. ~n` -,

r:77- -_'-~
019 UNCLASSIFIED.: PROCESSING DATE-30OCT70
C IRC ACCESSIGN NO-AP0124566
GP-0- ABSTRACT.: THE FOLLOWING ETPt0)(ORIH, PREPD.
CON VIF NEETCHo B SUB12 60-10EGREES, 0
NTIONALLY, WERE USED CR SHOWNIZ
PF'LIMEZO 0.9865* N PRIME20 SUOD 1.4274; CL CH SIJ82 CH SUBZ* 8 SU80*2
65-60EGREESt 1.21831. L.45T8;,AND.MECSUs1C',.8 SU80.1 35DEGREES 0.99779
J..-4328. ThE LAST WAS RATHER UNSTABLE AND DECOMPD.,UN STORAGE, EVEN Iti A
LED BULB, WITH LOSS OF ME SU82C:CH SUB2. THE FOLLOWING VALUES OF AQ.
'SEA
:HYDROLYSIS RATE CONSTS. 1K TIMES, 10 PRIME6, SEC PRIIIEL NEGATIVE) (AT 98,
Ato
913ir~-80v--.AND 70DEGREES, RESP.)r ACTIVATION, ENERGY 1ACAL-4 LE) AND DELTA S
*SHOWN ON
.-PRIME PLUS OR MINUS 1E.U.) hERF REPORTEDs, RESP.r FOR.
.141CROFICHE. -RATE- CONSTS. FOR ALK. HYDROLYSIS FOR;,rHE TERT BU ESTER
WERE.: (K NA 1 MOLE SEC.). 0DEGRE-ES 0.045v 10DEGREESP 0.102s 20DEGREES
Gol9t 300EGREES 0_35# ACTIVATION ENERGY 11*2.ANO DELTA S 25 E.U.
ALTHOUGH GENERALLY THE.AQ. HYOROLYSIS RATE CONSTS. DECREASED WITH
H
LNCREASING CHAIN LENGTH AND 'BRANCHING, THE 4STERS 141TH MEETC AN NE
-C: GkOUPS 1. WERE GREATLY REACTIVE9 OWING: TO -AN Sk I HANISTiG CHANGE
_,5U$3 ~ OiEC
THE. MECHANISM AT THE C ATOM OF. THE -ALCIt' GRbUP.;i:FORj0THER ESTERS
tLEAVAGE ~Al` 11irz- P 0 LINK IS LIKELY AS!7_'IN.0JALKYL THOSPHITES.
EACI L I TY: INST. ORG. FIZ. KNIN 'IMO~ AR-BUIOVA0, KAZANt VMR.
UNCLASS I FIE0

: ~ I ~: I;, L . it.. A 1.11 H: ~--J ILI, i-714 lilt t ,

212 025 UNCLA-.'jSIFIED PkUCESSING DATE--30OCT70
CIRC ACCESSICN NO--AP0124654
-(Ul GP-0- ABSTRACT. :THE FOLLUWING VALUES OF RATE
AS.STRACT/.EXTRACT
NSIS NERE REPORTED FOR AQ. HYDROLYSIS OF INDICATED ESTERS (IN K TIMES
.10 -PRI?iE6 SEC PRIME NEGATIVEI); ISHOWN ON MECROFICHE). SINCE THE 31CL
'SUB S*TITUENT GREATLY INCREASES THE RATE-OF: Af.1-HYDRULYSIS, A FORM OF
INTRAMOL. EFFECT OF CL IN THIS POSITIONAPPEARS TO. EXIST. THE DIFFEREly
SEHAVIGR OF ESTERS IN REACTIONS WITH H'SU82 0 AND HO PRIME NEGATIVE IS
EXPLALNED BY DIFFERENT REACTION CENTERS.:.THE CALICID. ACTIVATION ENERG;ES
FOR THESE REACTIONS ARE. NOT- -ANY ~.LGWER;,FO9 ESTERS :'pIN WHICH THE INTRAMOL.
.:MCATALYSISu EXISTS THAN FOR IHOSE.IN WHIC14 IT IS ABSENT. HENCEP THE
ACCELERATION IS OUE TO INCREASED SIZE, FO: T.HE'PRE :UPo&-XNTIAL CUEFF.
Y~ GIF _HE~ A Stf I N
BY CHANGE IN POLARIZABIL11 Ir ik N 0 "STATE.
INST. URG. FIZW KHIM.; IK. ARSUZOVA, KAZAN,,,USSR.

mEMM
'LMTE-7-02:~jCT70
ACIOS -0-
D ~A T EPULL I SH F.D ------- 70
--CH i I ST RY
-,,~SUOJF CT AREAS T~
-'~-TBOJ ZTAGS--A?
M I NE DERIVATIVF9 AMMONIUM SALT. HYDROGEN CHLORIDE, JkGANIC
'-RkCtXY KF(-L/FPXME--1'!92/1570 STEP NG--UR/0079/70/340/002/0496/0!!~98
ACCESSION NO-AP0112564
UNCLASSIFIED

_F I ED :P
772 016 UNCLASST. OCESSING DATE--020CT70
Cl AC ACCESSI~IN N0-AP0 112 5 64
455TK AC T/ EXI R A%"T-- (U) GP-0- ABSTRACT. 141XING 12.4 G P(NET SUrQ) SlJR3 I
CZ 4
ANO 0:,9 G E T SUB3 N.HCL AT 80-90DEGREES.IN VACUO (WATIL. PJ PI GAVE
-,'53PERCENT (FT SUB2 N) SUB2 PCLP B SUBO.02 601)EGREES, N PRIME20 SU3D
1.4900-, SIMILARLY 17.35 G I A,40 7.7 G ET SUB2 NH.:NCL GAVE ET SJ132 NH AND
61PERCENT ( ET SUB2 N) SU82 PCL. : AT 40DEGPEES, 1.2.3 (~ I AQ 10.6 G
I'THEP(S)CF-ET SUB2 NH GAVE 10OPERGENT:ET..SUB2 NH AND 61PFRZENT (ETSUB2
11) 5U32 VGPIS)MEET, El SUB0.007-82-30EGREES, 0 PRTME20 1.0368, \1 PRIAE20
,!'-:isUPD 1.4890. SIMILARLY, 8.5 G ACOH.ET SUB3 N AND*13.1 G (ET SUB2
i P -08 Lf) S.UB2I GAVE A MIXT. CONTG. 6.7 G 1BE01 SUH2 PH0, 0.9 G (BUO)
SUB2 TOAC, AND .3.8 G ACNET SUB2. THUS9.REACTIONbF P1111) AMIDES WITH
-AP ~R F~ THE AM[NE AS FORMED MAY BE
11NE SALTS, IS. REVERSIBLE, AND EMOVAL~O
-SPLAtE THE EQUIL. IN 'T.H.E~DIRKTIONiff FORMATION OF PRODUCTS
USED -TO DI
How MOVAL OF It SUB2' NH.
N ABCVF--'BY.RE
-UNCLASSIFIED--~

ES V
A .1
Abstract: The authors investigated the hinetics of reaqtIons irith vater and
hirdroxyl anions for esters of chloroalkylphospbonic and bis(cb1oroalkyl)phosphinic
acids with various positions of the chlorine atomln the molecule., For esters
which have the chlorine atom in the y - position., an uixasual. -increase in the rate
ot hydrolysis takes place which may be'attributed to the in-bramoleaular effect of
the chlorine on the reaction center. The rate.of hydrolysis,lln water can be de-
'stribed by an equation for first-order reactions. Tbe rate,constants k were de-
termined from a graphic relationship corresponding to the equation.
-jog c o.4,-)4kt 4: conat,
ubere C is the eater concentration. The. rate constant for a4lk&line hydrolysis k2
-pit to qn:equation for
vas detemined from the slope of straight lines correspondl
,lecond-order reactions
-2/2
m

. . I ill. I i! I i's t I;,! t -Pal , . Z, A.,! 1'. t I ! ~ I , .
-11
I J , ~! 1", ~ " I I , . . , 1 1, , , ~ I , , 11 11.; I i i - * "1 -1-1 1
t .: ~ ; . .

'USSR UDC
542-538-66
:Bn, ISKIY, V.YE., MOMMLIN, G.Z. YELISEYEMOV V.N., RIZPOT-OZBMISM, N.I.,
listitute of Organic atd, Physical ChZM"7t~_ e
Ye. ~~ov, cademy of
7
ciences _LMM
ydrolysis of Erhos~hoxz Acid Esters Which Cdntain the -~E Bond
Izvestiya Akademii Nauk SSSR; Seriya Kbimicheskay Mar 70~ PP 565-
OSCOVY ai No 3)
568
Abstract. Conti=uing their investigation of the kinetics of hydrolysis of phos-
..phorus acid esters containing the P-H bond, the -~uthorr, studied hydrolysis of a
number of alkyl esters of ethylphosphinous acid of the generia foxmula (RO)C2H5F
(O)H in water at different teraperatures. It ~ms fcund that the rmte constants
for hydrolysis decrease with an increase in length and branching of the alkyl
zac'Ucals. Exceptions to this rule are aec.- and tert.-butyleesters which have a
higher rate of hydrolysis due to S111 splittering at the carbon atom in the
-0 , bond is broken . ita: the other esters by
.-alcohol group. It is probablethat.the.B
a mechanism analogouB to that observed,in dialkylphosphites~:
L

USSR UW. 547.126'116
FATTAIG-10V, G. and SERKINIA,
-YELISEYENOKOV, V. N., PU VIK, A N.
--~n, Institute o* rganic,and Physi al Chemistry imeni A. Ye.
C
Arbuzov, Academy of Sciences USSR
"Reaction of Amidophosphites.With Anzoniura Salts~of Acids
Leningrad, Zhurnal Obshchay J