jXM4U4j,A.; KIRIYANOVA2 V.M.; SIICIIEVFLEV, M.I.
Effect of inherent dislocations in alloyed p - n-junctions on the
duration of transients. Izv. vys. ucheb. zav.; fiz. 8 no.2s23-27
165- (KIRA 180)
.14 Voron'ezhakiy politekhnicheakiy institut.
YEREMIN.-S,A.; SIMDROV, A.F. (Kuybyshov)
Complete s;rstems and ba.;es in spaces of functions holomorphic
In multiplo Ifartogs regions. Volzh. mat. sbor. no,1:65-71 163.
(141m 19, 1)
11 1 ~ I I . f I , - 4 - , I . . 1 11 - . . ~ ~ c - - , ~ I - - I i - '. - . f - . n ) '- , 7 ~ -, . -
YFJMIN, S.A.j SIMELEV, M.I.
Reply by the authors. Izv.vyj3.ucheb.zav.; prib. 7 ao.6:222 164.
(WRA 18:2)
YEREMINt S.A.; SK1117ELD, M.I.
Device for maasurlng pulse charactaris tics of senicordllctor
diodes. Izv. vyn. uchob. zav.; prib. 7 no.D149-152 "64.
(MIRA 17:9)
1. Voronazhckly politokhnicheakly Institut. Rekomendavnnn
kafedroy poluprovokinikovoy fjJ.cM,ron1k1.
MIKMLYUKp T.P.;.MEMB S.F red.; LAPIDUS, M.A., red.;
I 'j .1,
'-'t V' I
OKOLELMA, Z.f.,- e-W. red.
[Work practice of production administrations) Opyt raboty
proizvodstvoMkh upravlenii. Hoskvaj Sellkbozizdatp 1963.
334 P. (Agricultural administration) (MIRA 16:12)
TEMIN, S.K. , insh.
Mechanical clamp, Transp.strol. 10 no.5:53 * 16o.
(MBA 13:7)
(Hoisting machinery)
a
_J.
TEMIN, S.K., insh.
Portable hydraulic track liner.
.n '(,n-
(RAilroad s -Track)
Transp.stroi. 10 w-7:52
(XI" 13:7)
YERIMIN, S.K., inzh.
lxcavator for salf-propelled chassis. Trakt-i sellkhozzaah. 30
no.10:31 0 '160. (MMA 13:9)
Okaavating maehinery)
BELOV.1 B.I.1 USTIVOVA, Ye.T.; YZERMIN, S.K.
Use of some thermoplastic resins for the preparation of nonwoven
fabrics with the adhesion mithod. Izv.vys.uchsb.zav.; takli.tokst.
proms no-3:98-102 163. (MIU 16:9)
1. Moskovskiy ordena Trudovogo Krasnogo Znameni institut narodnogo
khozyaystva imeni, G.V.Plekhanava.
(11onwoven, fabrics)'(Resinsj, Synthotic)
DOROFE' M, Vitaliy P'litrofanovich: IMMI Voniamin Yakovlevich.
,, inzh.; KONDRU
Prinimali uchastiye, YEREMIN __I.Ijl SEV, V.S.,
inzh - IAKMO'VSM, tekbu. nauko retoonsentl
SKugdlli~sm' L.S., inzh.,, red.; SMIIFAYY,, L.I., red.;
GARKUKWA., L.A., toklm. red.
LTesting rem-jet engines] lopytaniia vozdui3hno-roaktivmykh dvi-
gatelei. Iloakva, Gos. nauchno-tekhn. izd-vo Oborongizp 1961,
220 p. (Airplaneo-Ram-jet engines) (MIRA 15:2)
YERFMIN, T.
Inexhaustible possibilities. Prof. -tekh.cbr. 22 nc.4:255-2,7 A-_ '65.
(,v,,, ~,~ 28. 5, )
1. Tjokhovoy organizator Kurvkogo elekt-ronyparatnogo vivoda,
0
- - ---
-Labor. force. Pat.uel. 6 no.6:18-19 Je 157. . (KLRA 10:8)
I.Zarteetitell nachallnika Otdala raboahikh kadrov Itinisteretva
ugol'no.v pror7ohlennoati SSSR.
(Coal miners)
VOIIOBITXV, A., Inshener; TAMIN, T., inthener.
5'74e'
Training machine operators for the coal industry. X"t- u6. 3
no.6:3-4 Je '34. (HL" 7:7)
(Goal ulnas and mining) (Mining englusoring-OWy wA
teaching)
YEREMIN, V., mekhanik (Oholyabinek)o
Device for removing the wheel hub from the Mosky1ch automobile,
Za rule 14 no~5:18 Ag 156. (MI2A 10i1)
(Automobiles--ApparatUa apd supplies)
r z / 0, r, L,
AUTHOR: Yeremin, V., Instructor 27-10-19/21
TITLE: Technical Competition (Takhnichookaya olimpiada)
PERIODICALt Frofesaionallno - Tekhnicheskoye Obraxovaniy*, 1957, 10,
inner side of rear cover (USSR)
ABSTRACT: The Agricultural Mechanization School # 13 in the Kitov Oblast'
arranged a technical competition to increase the knowledge of
the tractor "AT-54"V and combinee"C-4" and "JIT-7",- which
yielded good results.
AVAILABLE: Library of Congreiis
Card 1/1
22 (1) SOV/27-59-3-34/37
AUTHOR: Yeremin, V., School Instructor
TITLE: An Instructive Meeting (Pouchitel,naya vstrecha)
PERIODICAL: Professionallno-tekhnic~eskoye obrazovaniye, 1959, Nr 3,
P 32 (USSR)
ABSTRAM The author describes a meeting which the students of the
Vozhgaly Technical School No 1 (Kirov Oblast ) hold with
the Chairman of the Kolkhoz "Krasnyy Oktyabr'" P#tr Alek-
8eyevich Prozorov, Hero of Socialist Labor. The kolkhoz
has at present over 46,000 hectares of lan4, including
26,000 hectares of arable land, 80 tractors, 45 automo-
bilesp many combines ftnd other machinery.
ASSOCIATION: Vozhgallskoye takhni6haskoye uchilishche No 1, Kirovskaya
oblast' (Vozhgaly Technical School No 1, Kirov Oblast
Card 1/1
,. !~,-,--,- ----
- ---- - ---- -- ---- ---- -- - -- - - --- - ---- -- -- -- --- - -- --- - - - -- - - - --- -- - --
YMMIN, T. ,
Study room for studying traGt"Gv.Arof.-tekh. obr. 17 no-7:19-20
il 1609 (MIRA 13:8)
1. Prepodavatell uchlishcha mokhanizataii sellskogo khozyaystva
Noel (11rovekaya oblast').
(Tractors-Audio-visual aide)
__rzREHjjlf-V-.-prepodavatel I
j
important topic, Prof.-tekb. obr. 19 no.6-.6 Je t62. OWA 15:7)
1. Uchilishcho makhanizataii sellskogo khozYaYstVa NO-It
Kirovolmya. obl. (Tractors)
MUIR) V.) prepodavatell
M,curslon clans. -'P--Of.-tel-h.obr. 21 no.ll:IF-49 la 164
(MTRA 18:2)
I. Ilonhig-allolcoye sellskoye I)rofetinier,,ttl-lno-to'khnichookoyb
uchillahche 110.1, Kirovokuyu obl,
yzmrvs v0 I, PA 4/43Ta
USSR/Minerais Apr 49
Lignites
Coal Call
"BIWImental Gasification of MLraganda Lignites,"
V. 1. Yeremi:n, V. I. Kostin, Engineers, 6 pp
"Z& lkcnomiyu Toplive Vol VI, No 4
Xsrs4;anda lIgnIte is a satisfactory Saa-generating
fuel'. During prolonged storage, Karaganda lignite
rapidly breabs up Into,bite unsiltable for gasi-
fica-tion. Higher indexes-were obtained in OR~I-
ficatton cf Ka-raAanda. lignite then in gasification
of MaIjabinak coal. Onw.dof iolency of Uragands,
142/149M
VM/Minereas 04=td) 4.ipr 4
0041, as a gas ~gen erat ing fuel, is tbLe small
difference between the temperature of the start of
ftsh deformation and the nelting poin-V (2oO C).
40 42/49M~
SOV/1 37-59- 3-5484
Translation from: Referativnyy zhurnal. Metallurgiya, 1959, N'r 3, p 78 IUSSR)
AUTHOR: Yeremin, V.I.
TITLE: Designs of Furnaces for Fluidized-bed Roasting and Trends of Further
Work in This Field (Konstruktsiya pechey dlya obzhiga materiatov v
kipyashchern sloye i dallneysheye napravleniye rabot v etoy oblasti)
PERIODICAL: V sb.: Materialy Soveshchaniya po vopr. raboty pechey tsvetn.
metallurgii i razvitiya pirometallurg. protsessov. Moscow, 1957,
pp-68-87
ABSTRACT: A description is given of designs of various alternate arrangements of
the following main units of furnaces for roasting in the state of fluid-
ized suspension: The air-distributing unit (a comparison is made of
existing nozzles), .1he loading devices_ the water-cooling devices for
elimination of excess heat from the flitAdized- solids bed, and the units
for unloading of scoria from the furnace, The selection of materials
used for lining and future trends in the design of fluidized-bed fur-
aces are also discussed.
Y u. 0.
Card 1/1
GIADILIN, A.A.; GWKHOV, D-B.; YMMIN, V.I*t.;_ZVEUVA, N.F.; IAPINj K.N.;
MAMOITOVA, A.S.; M&TYNOV, M.K.; CHIRKOV, N.Ye.; MIKHALICHIKOT.
P.1.; POLYACHKIII, M.A.,red,; AUTCUOT, T.F., tekba. red.
CIconomjv of Penza Province; a statietical collection] Harodnoe
kbozisietvo Penzenskol oblesti; statisticheskii abornik. Penza.
1958. 190 P. (MIRA 11:11)
1. PenzenRkaya oblast'. Statieticheakcrja upravleniye.(for all except
Mikhal'chikov an~ Antonov).
(Fenza Frovince-Statistics)
fe It AD Is am)
(c jw %Kos) IL C~
P, I
ML L A-
I L
AL IL r.
,= a
4
AL X
AL A. Up" It a f~.
,.L .11
A. X-
IL
to
(C AD UM)
"Mms gob""" tw ~w oooomkw ft"184 w wo alls"W" %dusuots" aftlaq 4c 7
2o"0 920kswrUa md llowhriftL OwmmwAmffl~ In. A. N. Papw
6.2 hm.
-- -
The BK-1425 tower crane. Biul.takh.-okon.inform. no.8;44-45
'59- (MIRL 13:1)
(Granns. derricks. etc.)
TXVNIVICH-CHEM. O.V.;_YZMIN, V.I.
Generator of sine-squared pulses. Alektroviail 14 no.l1s21-25 H
'160. (KMA 13;12)
(Television-Tenting) (Oncillatorn. Xleotric)
DUBININ, A,14.J. kand.tokhn.nauk,- YEPEIKN~ V.I. kand.takhn.nauk; ZAYTSLV., M.A.,
.1 Inzb.; TATARNIKOVA, N.A.-.,--k~ottAlmonauk; TOPCHIYEV, G.M.J. kand.
tekhn.nauk
Now components for high-voltage measuring dovices, Vest,olaktroprom.
33 no,2:44-49 F 162, (14M 15:2)
(Electric measurements) (Cathode ray tuboa)
(EleoWc motors)
t 1352-66 EWP(J)/EWr(m) RM UK 02"
'AC=SIOM mts "'APSOrI396 /65/000/015/0000/0080
67.k7f$3.22-42
44
a.
Ionia: Ki N V. Rot P Khx"2M&J6_1
L-Fak. ~Rjlv I
Zapol'sks dews, V. S KuprllvLu~w~: A-1
7V;7_v- ~s2p~i=_
as ev ~J Y K. A. #4140
Vb 1; ~Mtent
A mslt~ for P__ uci.*, "p"o, Id; f.M.1relass 39, to, 17340
a Irinyl chloridq
OURCE; byulletan' Isobrotenly I tovarmykh znAov, DO. 15, 1265, 90
TOPIC TAM: polyvinyl chloride, foss plastic
ABSTRACTs This Author's Cortificat*'introduces a method fo r producing polyvinyl
chloride foam by mixing polyvinyl chloride rosin with a ~Iisticlzer and additive$
and then saturating the residtant mom with Inert 969 udder Pressure and.hogtIng It
In a high-frequency current field. The processing Is made independent of the note-
Iture-content of the rosin by vacuum evaporation treatment of the plastic woo be-
fore saturation with the Inert jam.
Riii)CIATIONs ViedIALLrekly asuchno-losladovatollakly Lmtltwt alet choskikh sm6
I(vl&dhdr Scientific Research Institut Synthett Rosine)
'SUSNII-11. t I 02JM63 =1 00 VA ODIC: NT,
ar wit 000 OrMRs 000
P-7
S/169/62/000/005/014/093
D228/D307
AUTHORS: Yeremin,..V.,,K., Klenchin, N. N., Udris, K. P. and
-Stu6hevskiy, N. I.
TITLE: Geologic surveying and gecphysical operating procedure
in conditions of enclosed regions
PERIODICAL: Referativnyy zhurnal, Geofizika, no. 5, 1962, 23, ab-
stract 5A179 (V sb. Geol., metodika i tekhn. razved-
ki, labor. raboty, (5), Alma-Ata, 1961, 19-28)
TEXT: In conditions of enclosed regions geophysical research me-
thods lead in the general complex of geologic operations and begin
with regional investigations. Seismic, gravimetric, electric and
magnetic prospecting, accompanied by drilling, are used in this
stage. Complex areal investigations at a scale of 1:200,000 in
sections, outlined by the regional survey, represent the next stage
of,depth mapping. The investigational complex includes: aeromagne-
tic and aeroelectric prospecting, gravimetric prospecting, electric
,prospecting by the 13 33 (VEZ) and Aa3 (DEZ) methods, geologic our-
.-Pard 1/2.
S/169/62/000/005/014/093
.Geologic surveying and ... D228/D307
veying, drilling operations,.and geochemical investigat-ions. Com-
plex geologico-geophysical searches, including the obligatory exe-
;ution of gravimetric and magnetic prospecting operations, are made
in perspective areas, subject to mapping on a scale of 100,000.
The choice of other geophysical and geochenical metboda, and also
the volume of drilling operationst is governed by th6 concrete
g2ologic conditions and by the problems of seeking useful minerals.
Abstracterts note; Complete translation.-7
Card 2/2
YESENOVI Sh.Ye,j YEREMI
Study of closed areas in the Kazakh S.S.R. Izv. AN Kazakh. -SSF.
Ser.geol. no.30-17 162. (YJRA 15:7)
(Kazakhstan--Geology, Economic)
.ELAZUNOV, V,S.;-GALITSKIY, V,,V.,; YMUMI V.K KOSTENRUP NA; HaOM) G.TS.;
UTYUKHRI, G.F.
Resoultions of the Second Kazakhstan laterdepatrmental Conference
on the Quaternary Period and Geomorphology or Kazakhstan. IzvoAN
Kazakh.SSR. Ser.geol. no.5-'115,-119 1620 (MIRA 15.12)
1, Akademiya mmk Kazakhokoy SSR (for Bazhanov., Galitskiy.. Madoyev).
2. Mlnisterstvo geologli i okhrany nedrKam&hakoy SSR (for Teremin).
3. -Yu= Ilar Kostaxdw). 4. Srednea#atxkiy nauchno-isaledovatel*-
skly,Anstltu"~ goologii i minoraltnogo syrtya, Tashkent (for TetyukhJn).
(Kazakhstan--Geology, Stratigraphic-Co4reaBos)
(Kazakhst&n~--Goomorphology-CongresB6o)
YmmIN, InzhL
AsNOmbling reinforced concrete Oulverts. (MIRA 12:8)
Put' I put. khoz.
no.5:20 My 159.
(Culverts)
we use sectional reinforced concrete constructions*' Pat' i put.khoz.
7 no.1:13-14 163. (HIU 16:3)
1e GlavVy inzh. tonnellno-mootoiogo otryada No.2. otantoiya Kirovakan,,
Zakavkazakoy dorogi. I
(Precast concrete constructions) lRaioroads-r-Buildings and structures)
I
M. (Vet.
"Localization of larva of cavity gadflies in the area of esophagus."
SO: Veterinariya 27 (7), 1950) P- 54
Turkmen Sovkhoz Astrakhan Trust
YEM IN, V. M.
Smallpox - Prevention
Single injection of sheep with STI vaccine and aluminum hydroxide formol formol
vaccine for smallpox. lar. i Zver. 5 No. 4, 1952.
9. Monthly List of Russian Accessions, Library of Congress, Tipmawba-r 1954. Unclassified.
U0,33II/Discanes of Farn Anirals - General Problems. R-1
Abs Jour : Ref Mur - Diol., No 11, 1958, 5oi44
Author i Yormin, V.M.
Inst - -
Title Lameness in Sheep ane ',Ictli*(Is of Its Control.
OrIC Pub Karakulovodotvo i zvormloLvo, 1957, flu 4) 62
Abstract In the sand covered rc~,Ionr, of Turkmenia lameness in tfficep
was observed, anused by the occlusion of the exit ~'Iuct of
the lanolin gland (IocateO. in the cleft of the hoof) by
ninute sana particlc3 fomin.:; a pluf;. Such lanoneso is
easily climinated by the PIUG boin(; aqueaml out.
Card 1/1
2
ANASTASIYFV, Inzh;j KOZLOV, D.T.i ltlzh, ; MIIROVI
B.M.j inzh.; SAPOZHMOV, V.A., inzh.,- ROMANOV, V.G., inzh.o
Automhtic unit'for faessuring pipp longth. Mf%lh. i nvtom.proizv
19 no.3-.7-9 Mr 165. WRA 18s4)
PHASE I BOOK EXPLOITATION SOV/5822
Ar il~kxeyov, Semen X~khaylovich,, YakoY Vladl'airovlch Balkind,, Aleksandr
Aironovioh aershkovich, Veniamin Semenovich Yere'aln Alokoandr
Solomonovich Povitskiy, and Naum LIvovich Um_&_n-s-k1y-ffl
Sovremnnyyo sredetva avarlynogo pokidanlya samoleta (Modern Facilities
for the Emergency Abandonment of an Airplane) Moscow, Oborongiz,
1961. 450 p. Errata slip inserted. 4000 oopion printed.
Reviewer: A. 0. Brunov,, Ingineerlld.: A. Is Sokolov,rZnginser;
Zd, of Publishing House: A.. G.'B*levtseva;-T*ch. Idoo P. V.
Shcherbakov; Managing Rd.: S. D. Krasilln1kov.
PWPOSZ: This book is intended for engineering and technical per-
sonnelAn thsaircraft Industry scientific workers, and flying
and technical personnel of the hoviet Air ]Force.
dOVZMM;: Used on non-4oviet sourcei,, the book reviews brief ly
the development of flyers, escape equipment,, describes the con-
struation of ejection seats, and giWbs design and calealatiab
(;Sr*=I/-12
Nodern Facilities (Cant,) :80Y/5822
data for ejeation.soato and ejection-soat parachutes. Informa-
tion in Included on the calculation of the trajectory of the
ejected seatp its stabilization, and the serodynande loads In-
volved. Attention is given to methods'of escaping from aircraft
flying at high speeds and at high an4'low-altitudes.- Informa-
tion on problems connected with oxygen equipment I protective
0-othiAg,, and testing facilities Is also ineludade NO iorobn_
.alities ake sentloned, -Thd1,aQthdVfi..tHan - -A* Q,W Brunovi . Fl, D.
Tkaohev and N. f,'Aleksand.rova, Engineers, for valuable sugges-
tions; and N.A. Lobanov Candidate of Teohnioal Saienoos, for
writing Subheading 9 of 6h. III. There are 34 references$ 31
Soviet-(5 translations),, and~3'Znglish,
TABLZ Ordogum St
Foreword 3
Ch,11o 04neiral Information on Modern Zsoapo Facilities for,Air.
craft C2*ws in Distress 5
Card 2/112
ALEKSOEV v Semen Hikhay1ovich; BALMU) , Yakov Vladimirovich; GERSHKOVICH
Alekaandr Mironovich; -,_Venjamin Semenovichj POVITSKI79
Aleksandr Solomonovich; UMANSMO Na= L'vOW-cE-JFFIhyaI uchastiye
UMANOVg N.A.9 kand. tekhn. nauk; BRUNOVO A.G.v bizh.p retsenzent;
SOKOLOVv A.I.9 inzb.9 red.; BEIEWSEVA, A.G., red, izd-va; SHERBA-
KOV9 P.V., tekhn. red.
(Modern means for abandoning an airplane in an emergency] Sovremen-
nye eredstva avariinogo pokidaniia eamoleta. Moskva, Gos. nauchno-
tekhn. izd-vo Oborongizp 1961. 450 P. OMU -14:8)
(Pilot ejection seats) (Parachuting)
ypi LI-IN , Valentin U!;tinc.,vich; T.T., red.
[Treatment of patientL with chronic ini'la;:rat'O.-i
of the liver and billaz-j tract at the Truskavets if'ealt~,
Resort] Lechenie bollrwkh khronicheckinA vospali tell nyrd
zabolevanilarni pecheni i zhelchnykh putei na kurorte Tru-
skavets. Kiev,, Go=edizdat US,"X2, 2964. 51 P.
17.E)
INMIN, Valentin Us~inovicho. GLUEEMIKIY, T.T., red.: FMOTSKAYA, L.A.,
tekhred.
[Treating liver diseases at Truskavots] Lechenie zabolevenii
pechoni no karorte Truskaveta. Kiev, Goo.md,izd-vo US=, 1960o
50 P. WRA 14:2)
(LIVER--DISZASSS) (TMJMAVATS--MIKMM WATMS)
U"-
B--r?
Abs Jour: Referat Zhur Xhimiya, J4, 19571 11216
Author III, A. D. Stepukhovich and G. I. Katu
IV. A. D. Stepukhovich and G. P. Voroblyevo
V. A. D. Stepokhovich and L. V. Derevenskikh
VI. A. D. Stepukhovich, L. S. Stallmakhova,.Yeremin, V. V.
VII, A. D. Stepukhovich , L. V. Darevenskikh
Title Kinetics nnd 14-,chanism of D--oomposition of Hydrocarbonu.
III. Kinetics and M--eharliofn of Therml D-~compositim of Divinyl at Low
T~mpernturcr-
IV. Kinetics ond 1,L-chanism of D~:composition of Isobutane In the Pre-
cence of Isobutylene and Propylene as Inhibitors
V. Kinetics of Thermal IMcoupouition of Gaseous Poraffirs Ail tbe Pre-
s(~iice of Added Divinyl
VI. Kinetics of Thcm3l D,.composition of G,)scouB Forvfftnpw in the Pre-
sencb of Acetylene
VII. Kinetics and 13--chanism of Decomposition of Gaseous Alkanes in the
Presence of Mene
Orig Pub: Zhurnol fiz. khfmii, 1954, 28, Ito 7, 1l,(4-1185; Ito 6, 1361-1370; Iflo 10,
1720-1724; Ito 11, 16'76-16L-1; 1955, 29, No 12, 2129-2132
Card 1/4
I T.-
Abb :Jour: Rrfervt Zhur - Mlolyu, Ilk) 4, 1~,'57, 11216
Abstract: III. 10he velocity constant of diviny], decompoultion,
iii accordance with the equation of the reactions of second order,
,~rarics linearly, at 570-6200 and 2-30 ram Hg pressure, dleV~ndlng on
1/po (p0 -- initial pressure). Calculated were mean duration of
life of divinyl molecule in nctivat-ed state, 5.10-0 seconds, th-c
number of kinetically active dc-grees of freodom 20, arid dissoabtion
of divinyl conforms to the dintseas-Prost equation and is interpre-
ted as a chain reaction nndergoing spontaneous inhibition by de-
composition products.. Additions of divinyl accelerate decomposition of
C2116 at 6200. Accelerative action of divinyl reaches a limit at 12%
Ill, By the method of inhibiting additives (RZhKhim, 1953, 8215)
a study was made of thermolibcomposition of isobutane at pressure
of 10 mm Hg and temperatures of 548 and 5736. Addition of Q-5%
slows down the decomposition sharply, on increase of the addition from
1 to % effectiveneas of its action decreases, and with 7-109A
satu.'ration is reached Wfat, order velocity oonstant acquires constant
value). Under the same conditions inhibition by isobutylene is more
effective than by propylene.
Card 2/4
U30R/l,hysicol Chemistry - Kinetics. Combuotion, Explosives. Topochemistry B -0,
Abs Jour: Reforot Zhur - KbImiya, rio 4, 1957, 11216
Experimental data on inhibiting action of additives fit the equation:
I/W - Wo = A + BC (1), wherein W -- reaction velocity, Wo -- residual
velocity, A and B -- constants, C (add) -- -- concentration of additive,
which proves the chain nature of the decomposition. The primary effect
is decomposition of isobutnne molecule at C-C bond. Inhibitiog action
of olefins is explained by removal of H atom by active radical from mo-
lecule of additive with fmomotion of inactive unsaturated radicals. By
means of equa-don (1) were calcubted velocity constants of the reaction
of chain termination at the wall and at molecules of additive.
Activation energy of inhibitingiesetions brought Bbout by isobutylone
and propylene is, respectively, 5.6 and 8.5 kcal/mole, that of the
reaction of termination at wall, 14. 7 kaul/mole.
V. Study of kinetics of thermal decomposition of propane, butane and
isobutene, in the presence of divinyl, with initial pressure of decom-
posing hydrocarbons -10 mm Ug, and at temperatures of 510-5930. Ad-
ditions(f divinyl, which is a product of cracking of hydrocarbons, do
not inhibit decomposition of these hydrocarbons. Absence of inhibiting
Card
3/4
0
i7och-mi t y B-9
T
Ab a Jo ur Rcfernt Zhur - KIlialiYa, 110 4, 1957, 11216
action of divinyl is correlated with greater durability of C-w-
bond? in CH2 groups, at the double bond carbon, in comparison with
durability of C-11 bond in methyl groups of propylene of isubutylene.
VI. Study of kinetics of thermal decomposition of propane and butanes
in the presence of 1-20% C I at pressure o4decomposing hydrocarbons
-,J10 mo and temperatures o~ ~00-6000. Additions Of C2H2 do not
inhibit rate of decomposition. Increased vabes of decomposition velocity
constant of propane at Liressures below 10 mm, in the presence of C2H2)
are due to the fact that C2112 impedes diffusion of octive canters
to the molls. Thermal calculations have shown the possibility of a
reaction between atomic hydrogen and C2H2' with formation of highly
reactive vinyl readical which is stable under cracking conditions
VII. Additions of allene inhibit cracking of CA and iso-CI,II
but do not affect decomposition of C4Hlc;~,: Wachanism of Inhibit-Yon
resides in addition of H atoms to allene molecule with formation of
little ative allyl radicals. Absence of inhibition in the case of
C)jHl0 is due to the fact that increase of latter occures essentially
with formation of C"3 radical. Communication II, see MhKhim, 1957,
393.
Card 4/4
YEREMNI--V.Ve
elektromakhanik
Some shortcomings of the ZhR-5 radio transmitter, Avtom,,, tel=. i
svi'Pz? 7 no.2:43 Ft63. (MIRAL 16:3)
,I
1. Orskaya distantslya sAgnali sataii i svyazi Kuybyshevskoy dorogi.
(Railroads-Rlect~onic equipment) (Railroads Comminication sym4ems)
YEUMIN, Ya.
.Electromechanical omoothing Instnumnto Stroitell w#6:15 Jo
061. (NnA 14:7)
1. Instruktor proizvodstve=ogo otucheniva tresta, No.6 Omskogo
sovnarkhoza.
WArinding and poligibina)
GORMETSKIYO N,I,, kand. ekonom. nauk; TE
_~~qVt.,.Ye.,Ye,; SMARGONER, Ye.A.
Growth of labor productivity In the coking plants of the
Dnieper Economic Council. Koko I khim. no.1:6.1-64 164.
(MIRA l7s2)
L Dnepropetrovskiy khimiko-takhnologicheakiy inatitut
(for Gorodetskiyj Yeremov). 2. Dnepropetrovskiy koksokhimi-
cheskiy zavod (for Shmargoner).
0 0 0 0 9
sib
of a
00
00
00.0
sea
10
e 010 0 0
*Too 6000000000
4 000 0 0 000 0,
4
s
0
0 0 0 0 I
0
0 0 0 0
V AS a&
I
got-CISSIS AND 0640fal.11 '"Is
.*9
The h" of by*
r
(in Cwmwn) --4)u the basis 0(%Pgctfm'opic values of the
h
t
i
h
d .00
e4
capac
t
ty an
e heists of di-.wn. of hydrogen talken
from warimm authors, E. obtaim the equstim a)" -
mum - Uss r in r + opai 71 + olU v
2M2 T. T)w equil. comts. c*d. from this equati(m
Svc* wen with The ex
l)
l
f Cl
, va
ms O
p
auque Imm low
'
1
4 ee
tu
"
and differ only M% at &09)
sibs. F. It. R. s
000
'Gee
see
as#
age
be
:60
LA
oat
...
a 0 0 JA A II fm 0 a I I V 11 1 a I
o
10 , I
"0 root
If 0 0
0
0
6
Fr
l
10
o 1
4 0
0
0
0
1 0
# 0 0 4 0 6 0 0 0 0 0 0 0 0 0
l
0000
*
*
6
*
s
ll
0 0
a a
0
P of
is Is IS
00 A a, -~ - z -
I F. a A-1 i
L &-a F- a a W U d
-
0
ki
n
and N. 1. Kabowv. Aaa Phyritioc
It'j-61(lon)(in German): J. Phys. C". W. 14. R-)
7(19M).--Oa The basis of brat-t~ity data of Bryant
06 4 (C. A. 17. 31W). H, said K. olotain for the ammonia -00
rem"'on Ar -18.w +:wnm Ting r; opaym r
0
+ Ookiniow ra - 4sim F -00
vp t, lim
thid itarlies
i *00
well w
th the 0"(1011 used by Maxted (C
.
A. is, liffin)
.
'
)ill At hicher Without It gives no "Iffwow (of the y1ol't 690
of NIL. The Inversion expily. foujul toy Masted.si high ee
temp. is quantitatively attributed to a rrwtkm of the It s
atom funned at thm high ttnlp%. with the NO mob, it) no*
the cooling sow at about ISM-l(M)", Vint apparent
but (am hi
h val
e
f
Nil
f
d
b1g 000
u
s
or
orme
g
at
,
h temp*.
F.If. Rathollsoin
o
0*0
Iso
It~i
too
A I a .$L L"914110111 CLASSIFKATION
use
t filial 04 ON* Its
I - 4 T I I ZA An I S a ad a 11 .1 It Is 0 As 4 3' a V
. . . M';T V
U M1100 ill,' criorit *a it of a ft 111 a, ill I
0 10 0 4, 0 0 41 0 9 0 0 0 0 0 0 9 0 0 0 0 6 0 0 0 0 0 0 a 0
002744 o 0 0 a 0 o g 00 '00 lop lop 000 00 0 0 0 0 0 0 0 0 & 0 0 0
0 go 0 000 0 0 0-0
*00
OOA
00
004
004
sea
Slow
.00
AS
..........
Ges
We*
00
:0 0
X W0490 -0 1 at ~v 044 FwalMe-if Oirill -amwv 'Ni-
- An A a ad 0 N 9 1 v to 9 go 0 3 9
u to
000000 go 66006966e Go***
0 0 0 ; I
6~6 -0 0 0 V, 0 0 6066016 goose *goose** * 0 o 0
0 0 0 0 6 0 Ito fif 0 111 0 @@too ~99900 ~
0 fill 0 *0 0 0 * a
I-t-U--A-jd - -D- it,-11-ji-ii
A IX M L 6 1
-11 1w 11. 1.1
-01 A Mo. III
'-00
00 Phy,koorW01. H- S. X So 347-TC)(RK11)*. 411. Ifillilwilid
If d1whijust 42.7 X 110 Its) ap"Will That
00 8T. the effectivit etwgy of diKbArge at 2.7 x to, its (ft-
gluctity, 70 wilitts find IN" Mffl- ptrvwfe is 111we than 3 if
fit"" ififtlel than Ike efifordw effetly 'it a M-1118 dil.
00 8 ba"ill of the pomp p-r. A colitilmli-4141 of lite Arliods
Of id tlw A..f?wInmmIion#rw-f.. .
No, lbrAimrn, rootio. liond do file tnergy opilluil, v. for
high slid torw lrrcptttk.v sh(mri It a Ito vulla -invrr-wifl" -4
0* flit efferthrenorwirytri thrilifill-641IM-114 y dIV-1"ISC. With
00 ji 1,,w" jwoiver the r4 thr high-Ircilurmy It%.
'ItAtKr Is Kvrdit-r: with Wall loorwer. fill lite c4nillary, the
vlTlv1Ivrrw%q IVF file lopw livilivolu*v flimbarv 14 Illeal.,
4 fle'llsell,"I .1.414 lite "iflu'ro"ll" J.'soll
file M., .-I Ill - 1,1011. 1 i's 1-11 ,
00 a 4 Isallaq. M g4q I I's. 11% the $mr a, I low Ion Jilh 1. Ill
I.Kill.
(Of 811 XA4-111111.~ illV"tiffatefl, M. %I-Millagi
UTINATW9 CLASUPKATtapi
-it
43&illl*.f
ua A, .0 as!; ; J; ; ; ; IF 4
9 u tf it K
11 :.0* 9 lp ~
0
~
0 ~ to 0 0 0 0 0 ~ 0
MOO
zoo
boo
too
I I I I ad Off, It i
Tarot.
I W
1 9
I I I lit 0 4 0 4 0 0 4 a e i
U-0 w G M - U Q V 0-0 V V V V a * as a a
I! it if -to it - .' 4 to & i it q - u - " 44
L a 41 A_ 1 1 L A I 1 11 1 1 "1 V I 1 11- A I 1 0 W 0 1
A '_' I 'I., I
(VIA- glaw discharge,
F-vo,rol". fl, .5. vaii-ey"r.7-N.
PAYl- Clitm.-fili $. S. R ) 9 4X-41- A,ja
ft. S. .1. 6. &II-wiw1h; W pfrf."lifix
00 -At frrIm 711 it. lpd) tam, prp%j#j,! aloof 71, w.,
06 d hllh'(rMmcncY (2-7 X Ill' Its) diarbarce is 3 lh,wif A, 00
dilrbulf Mottle lot *,. the -00
17f,"Clilto-. A 11,111.
00 a t _* 0
Pari*m.)* thr effects 4:1.7 x, 5 x, o x awl Ili X file Ill
1 8 (fol'iPPOCIRS 160W$ that, file effect ii I he name In All C3-A'%
00 ary"o-Ir dLw to chrrol, Froorionsinov effeg is, No fill. 60*
In ir., wraq law"ril Who'll rither intronal off =00
119.1=1 Vice Iriftleff vnf4- 11%rol. At hiab,-t wattav,* the
00 "tan. Old i4 iolplainvil at higfwr rorlatevc tiotwits. of o,.
Firtiffin limp. as drill. Ififfl) file lit IN illi. age
00 j Is joidiu-t at Vi W, IiiIIII lotelowiley IliAll of how 0
00 tfroltwlwy soul is hights *I k)W Wallace Own lot high
Wallace, and higher of UAY jammire ihain at high pttvwjrr.
00 a F If. Rathmanu goo
0
coo
see
i NOPPI its wee
uoo
too
a 10 - I L A NCIALL"(1CAL CITINAIL411 CLASSIFICATMON
6---- - - --' I I I _ _
00; II-141S.- _" - ' -- I I I - - W~
9 a a
b u IV 10 111; isit Ogg xUrt IIXKjan 1,14
* ; 0 0
0 : : 0 ;0 0 0 0 41111111114111
7'04~1 as '00 0 o o * too 000 0 00 00 0 0*0 see 0,
00 o
0 a: 11 1 4 1 1
A 0 10 11 It 11 w Is 16 If
I IL L
I All
g
0
IS
v 0
00 -
,
_
,
A
0 Spoctroactiple fairtaitigatlaa of the clettritcal otildation of
00 c (MU).-The enfixion nworunt of a glim dochafffir in Nj
410 a consmint the It pta., the I pun. ond ihir I neg. ttimp of N's
lines. In air. in adda. to lhrw. flit -t voui; of NOund. as
piresiurts vmtff than 6") "tin. fig. a (Amtuiuutll twtwcttt
The intemitfrof tlw t~mtlljulllta
fifirs fitwit list 44 the I alull dvirmawto III it It iwt iII,ing I"-
00 oure (3-40 inni.). 110th llittflill" Illifl-AW "Ith the
ruffent strength(JUJI-340111c). MtAllifilictilliwtM14
title to excited nuas. atul wily I "t 4- to rk. il"I it'ris,
of j V. 1'. A -
of
lip mile it ustoodro
1 0 a
..r a I. '*Of of ?so
-66
'0 P
ale 0
ZOO
zo 0
=00
coo
too
Soo
00
it
WAWAWAL LITIN441C CtASUFKATKO
00 9
-it
's "110111"ne! Ilra flit Met H it 1 14 so All-i-T -I-
0 0 0 0 0 a 0 9 0 0 0 0 0 0 0 0 * 0 0 0 0 0 0 fif 0 0 0 0
0 ~qep low
0 0 *g 0 0 0 0 0 If 0 0 0 * 0 0 0 0 0
f
Wokin 01 squo".
#o$Ij- - I I ddH
IKob",Ov 61"' at
of tiis --ki"It
1041. SL 223-22fi)--"o be,, in,T1110~1-
Awl VhfIrn mtxcj It. ha" pf"Ces-t:
ptr"ufrg. sits t Clack f,.Ujf,4.l hAS
-e of ur"Ure We .0 Cl (-if4 1 fit
CrrA + "I 111~~Uft~
2 Mail V$I i act -T -~Ie t.-M 11
th, -WO "ect
kInctIC ct'"'Its. CAWv thr
lance.
411 9 Al 0 e 0 *fee* 000*06*0064
A A Ufl-A-1-A-1 A_ 4--b k- _a
4 --sit -9 J.0 Fio~tls
I;iv; is nine
Formation a( acetvirsap in the afflectrocreocklag of snarth- &I die .1 (for bintf file hialtr
go A anal. I. Stalk experiments. V. N. Vermin, M. Z. A~ 1,%-- 114%1 ollplatetwIlly stvitt old in P arowl I txst
Alishialef, Z. L Kjt*y&~hUvtik. -Cnlr-V. V. Iiianin. J. directly lifftnxxtinnal tio V milli invvfsely ill 1; saituler full I
'Ijpjwoa,%1 ('A?-. 20, Ru..ililt)- A... &1,11d. -It r'1: with r'l - 2 L/15 111111~ marold 00
go The IMIAIIG'r 121141 Ifir 1114"ItICIS 411( I-fitClitivi 44 nafterot itals- 6PI allies.. A_ Ill It Affif While With
(Ills NJ l"IKI IC'" VA ' " ('111. 121 oil 2 M C.11., A 02412 No) v/I - 2 ;lip. A_ 11 M. Ifill little,, 14. still I
III All rhi- lift-, lwf"rq-ol %% Wfir 411-1 1,14-1111. vlt~fl..tr. wootir. dift'lly "I0% V Awl wills I tell to.. hwilsive
I -00
yj %tie Inoo-olegm-1 11, .4 , 1,~l I'litot ilio.k 44 V'4. A_ .4K4111 1, 11v.1tv't With r -1.1 1. 1 -
I M. '41, Vatialstal 4
! - 12 1, 4.1 6 1 . 111141vt 1.1014~1 limial lier-lutrit p 44 . V- 411i'l . %malle's Milli r - L" I
46, IM, an-I I&I allies. lilt at ctiffents s. .'140. 0.0. slut 0.9 1 It'ant 01 to ($,I, at v 1% 1 #,A). Ilo 35 anti fi,dit 41:11..
at"I"; t6if-oile .1wing I - IA, :141. Anti fill nine, (1) fit 11.11 of ciAtO. or I :01.'t title. in uJiltvil lately a Vely -light
ill"$$ o4o the dolraokof 14 the at." the orrorm.n. 'f ad hivirli'll III A- of lbo- bleth'-f #; F... SpIte'll. 1" 1w At'. roe
goaE (7111t On Volt. '; I I'l file I.I.Itirl pa,w. ohilmills A moset.. 1-t-m. mv,,~Iy I.- I, r a. 111 :Iamt to H. at
hiselle.1 4,1 'A 14'.. 1.- 4 Tell- .4 11114-fit P... " 111 41111 A -A'., 41 is Poll, 1... :01 .914-1 IA -1
711"~ With ITSIKI-I 14, file MillAl Clio) p - 3A 1:0-141.41 Ow a) its 'I'llelkal high
higher p Imet A_. if a. Ito 14-51" I'l 12 40, at p fig? et Oh"; i Cost IV affainell lit firlailitfly hqtC r jolb,"If 2
00 and UP; 1 :11)) isti-I tv,istharve fl~~ #false r,- * n"4ary to min.). as again-1 the vroy Amt r 1(1.4 titmoll ~.) int. 4111141111
o 0 allain A... 0 Im lease lortwern M anti 1141 none'). FKW%41 In lillmloir w"WIS; (b) the title rate 04 the rice.
but thriv is it.. J.1-0 At Illmilarr P.
ealsellal J... I., .111millef wislairl (4 the, 1.110 1 Ie. loillet IrArgh"I I% Illifelvil-lant 14 0'. 1 at *0
Ami Itioli, , .11CIIiII14 lialwor 9 - fillifflit 141141 fit 0; 19) ill 11111tvills-411 IMAMS, file flad kiloling The air
tit Cit.(+ Call.) its liar illifLAI gas. 0 - voted. of vipmessines mne, has a final tairoan .1 trashing frmn famixing tleftough
fafirr emoling) 'loar lit tlw frAvIi'm - pi final) /p( initimelfl, tinivrction nstremn. fdl fronts the expel, kinetic roamovemi.
otrod lit -malki Vithir, .4 file -11.ful 4-towLing" 4 - 11011 X an ill-volemor Ill A (final 7 1.6 141*~ (Utuirr '0 .35. 0 2. 1 11. 4*0
1A,111d 1 1CM411 OICII'l)(Aivillif the locirrvolage 111.3) rettifires 9.8 liev., itaidectra'sal josoln 14 11) 7 (flertmigh
'11. fra-IM. fast., Coll. I Collil. Not Ito 44k) w.1 tImq. the noedn rate 44 I'loarnaill.-to 111111111
larger VdIUv% d4 ((' Itll.ort" - 11410(l 0., the ad Call$ 11 4$.4 firtirs Its fair 4 dri.q.1topfc; tomiff p Im 1100
-cm- is star i.-Asit ad a dectlinpri. tal the Cills, anal Mo. the ratina air I.M.2 &tell lit. I. trip.: i.e,. hishart
r the rqiiality 4 the rates tit f4irmatioon metal -le. mamelffat" the .1"insipti (4) 11'.1fti msgasjn~f tie 0
=
comfort" %vilit If jet% tile nomess.. I. trachird Y. IF f"Sch" a m4io' too al.,111 M end 'Iism It"t
offammotirat t111441641 C&ASsmaKATION ..mL Us
of 'Sio-Olloodo - Ito., *')N!nv
A Its
toluci we* al"I 4( Met? 4XV M
U is A, so di-
0 0 It to to e 84 9 is at 4 of to n It
0
P~i
0 a 0 0 0 0 0 10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 *Ie 0 0 0 0 0 all, 0 0 9 0 t1
1. 08290-67 EWT(m,)-/EWPWZFTT
ACC NRs AP6032452 SOURCE CODE: UR/0129/66/000/009/0009 0011
AUTHOR: Chachin V. N.: Yeremin V, Ye 36
6-1
ORG: Physicotechnical Institute, AN BSSR (Fiziko-tokhnicheskiy in#ti-
tut, AN'--BSSR)7
TITLE: Effect of ultrasonic vibrations on the cooling capacity of a
_quenching rdium
SOURCE: Metallovedeniye L termicheskaya obrabotka ~etallov, no, 9,
1966, 9-11
TOPIC TAGSi quenching medium, cooling capacity, quenching medium
cooling capacity, ultrasonic vibration, stool hardonabilLty 1)14Frf71-
M9AWE...),Va, f10'9R1)'V-FV5
ABSTRACT: Preliminary experiments with a copper specimen showed that
ultrasonic vibrations applied to a quenching medium intensifies its
.cooling capacity. Subsequently, the effect of ultrasonic vibrations
on stool hardenability was investigated, It was found that the surface
hardness of specimeAs quenched in oil irradiated with ultrasound was
much higher than that of.specimens quenched without ultrasound (as*
89;621.78.01.0
-L-0829JO--
_A~dC NRs
jig
11
pig. 1. liardenability of cylindrical *pact-
men@ of type 45 steel
Quenching in uridisturbed oil;
quenching in agitated oil;
quenching in oil agitated by
ultrasounde
14.F ^w
)Distance from the 4
Fig. 1), It was concluded that the cooling rate and, hence, the harde
ability of steel can be controlled by ultrasound, Orige arte hass
3 figures.
SUB CODEs 11, 13/ SUBM DATEs none/ ORIC RM 004/ OTH REPs 003
21 g__ 1-3
*0
smnwsm A.L.-,7 VARMA ~ye-ff-
Nature of the ellow-green emission in tb,* oxidation of nitrogen In
the electric discbarge. Zbnr.Yis.Ddn. 26, i493-15o3 152.(XLRA 3;12)
(CA 47 no.13:6250 '53)
/V JEW
USSR/Pbysical Ch=iBtZ7 - Zlectr&kwistry, B-12
AbSt Journal: Referat Zhur - Khlmlya, No 19,, 1956,, U195
Auth or: Ianidkovskaya,,V. G.
Institution iHone
Titles On the Nature of Activation During the Reaction of Oxidatlon of
Nitrogen in Electric Discharge
Original
PerWicalt Tr. Goa. n.-i. i proyekt. in-ta azot. prom-ati, 1953, No 2, 98-110
Abstract,j A study of the influence of pressure (P) and current intensity (i)
on "equilibrium stationary concentration" (ESC) of NO during syn--
thesis of NO from air in gloving discharge. With i's 175 ma ESC of
NO at first increased sharply vith P and then having reached a
maximum (8.05% at 200 mm Hg) decreases gradually. At the same P
and IMixture consisting of 47-5% 02 and 51.9% H2 gives an ESC of
NO of 12..- With P -- 200 mm Hg ESC of NO increases with i from
50 to 500fa and at 500 me reaches 1.%. It is shown that with in-
crease of i and P., ESC of NO first increases linearly with increase
Card V2
, I
Category; USSR / Physical Chemistry
Therwdynamicvs Thermochemistry. Equilibrium. Physico-
chemical analysis. Pbase transitions. B-8
Abu Jour: Referat Zhur-laiimiya, No 9, 1957, 29885
Author Yeremin Ye. N.., Malltsev A. N.
Inst Vat Llvfie'n
Title Thermodynamically Equilibrated Concentrations of Nitrogen Oxide
;I
Orig Fab: Zh.--fiz. kbimli, 1956, 30, No 5, 1179-13-81
Abstract: On the basis of most recent data concerning bond energy of N ) 0
&n& NO and the function (FO - H 0)/T for N.,., 0,1 NO, N and M. eri-
librium, of the reaction N~ + 0-= 2NO was calculated, Vithout
and with taking into account (2) the reactions N...41- 2N and O.;,-1~7_"' 20.
Calculations were earrled out in the interval 1000-5M0 X, for air
and stoichiometric mixture of N; and 0-,, at P of 1 atmosphere and
50 =- In the case of (2), in contrast with (1), the curve represent-
ing the dependence of equilibrium concentration of NO on the tespe-
rature has a mayl-lin the heigbt and position of which depend upon the
pressure.
Card 1/1 -14-
%I-
~ I ; - . . . . . 11 .
AUTHOR: Yeremin, Ye. N.
-TITLE: Attempts to Produce.Acetylone by
Methane in an Enlarged Plant
(Opyty po polucheniyu ateetilena
metana na ukrupnennoy ustanovke)
PERIODICAL: Khimichesk aya Promyshlennostl, 1958,
64-58-2-2/16
Zlectrocracking of liatural
elektrokrekingom prirodnogo
Nr 2, pp. 9-16 (USSR)
ABSTRACT: In the course of earlier laboratory works, on which occasion
Ye. It. Yeremin and others (ref 1) becan the corresponding
list of references, an enlarged experimental plant for work-
in vaccum was constructed in one of the experimental plants
of the Glavkauchuk under the direction of If. I. Kobozeva,
S. S. Vasillyeva and with the collaboration of A. R. Sarychev,
0. A. Borisova and others. The effect of the discharge
amperage on the electrocracking process was investiCated.
The used gas had in percent by volume 94.3-90,8 ~- CH 40
2-5-2.6% C2H6' 0-0.7 % 02 and 3.2 - 5-7% 1'2'
Card 1/4 The schematic representation of the plant shows the drum-
Attempts to Produce Acetylenp by Blectrocracking of Natural 64-58-2-2/16
Methane in an Enlarged Plant -
shaped reactor 460 1) constructed by Ye. N. Pitakhelaur
with the three ~arraneed at 1200) electrodes (6600 Volt) which
has a water jacket at its lower part as well as a gas
drainage through a water cooled system. Methane enters the
reactor through a line leading through the electrodes equipped
with manometer and diaphragm. A given diagram shows the electrode
with double water cooling and the centrally arranged gas tube.
The cracked gas mixture is sucked off the plant by a vacuum
pump through a water scrubber (filled with Raschig-rings).
Schematic representations of the electrode arrangements of the
reactor as well as of the arrangement of the electric measurement
,apparatus are given. From the results of analyses and
electrical measurements the coefficient of expansion of the
reaction gas, the total cracking and the cracking to acetylene
were computed. The experiments were carried out at 42, 56, 75,
100and 3.50 mm. HS. Prom the results of measurements can be seen
Calrd 2/4 that the qualitative parameters of the cracking are functions
Attempts to Produce Acetylene by "lectrocrackinC of Natural 64-58-2-2/16
Methane in an Enlarged Plant -
of specific energy, and that the amperage a3 well as the
electrode distance influences only the efficiency of the plant.
The methane cracking process seems to be selfinhibiting, the
inhibition probably caused by the hydrogen formed in the
reaction product. The best quality parameters were obtained
in the cracking at 42-46mm Hg~ and an amount of specific
energy of 3 kVlh/Nm3. The dependence of the quality parameters
of cracking on the specific energy is determined by means of
the kinetic sum scheme which had been suGgested for cracking
processes already earlier by 11. 1. Kobosev and his collaborators
(ref 3). A deduction of the first kinetic order is used for all
reactions carried out and in this a similarity with the
explanations by S. S. Vasillyev is observed. Accordine to a
mathematical deduction the "theoretical" curve of function of
the total cracking and of specific energy were registered
and compared with that of the experimental results, both
Card-3/4 agreeing with a certain experimental value. From the consirpzatiorr
Attempts to Produce Acetylene by Electrocracking of Natural 61'r-58-2-2/16
Idethane in an EWA ged Plant
made and the results obtained it is concluded that the electro-
cracking of methane to acetylene is, from the phyoico-chemical
point of view, more complete than the electro-thermal
production of acetylene from calcium carbide. Finally it is
maintained that according to a comparison of the results
obtained the qualitative parameters of electrocrackinC nro
independent from, or little dependent on the pressure in the
case of a corresponding regime of the process.
There are 5 figures, 3 tables and 9 referencesp 6 of which
are Soviet
AVAILABIZ: Library of Congress
1. Methanes--Fractir,.iation 2. Acetylene--Production
3. Electric discharges--Performance 4. Methanes--Test results
Card -1/4
YjRWaN, Ye*N,,,-, .- - ,
rments on the ma=facturs of acetylene from natural methane
3xpe dioebarge using an enlarged apparatus, =im- P 000
by an electric r
no;2:73-80 Mr '58. NIRL 110)
(Methane) (Acetylene) (Cracking process)
SOV/55-58-6-30/31
AUTHORSt Gerasimov, Ya. I.,.Ytr?2inj_.U..2.-r-Kiselevp A. V., Lebedevv
V. P., Skurat~avq S. M., Topchiyevat K. V., Shakhparonovt M. I.
TITLEs Training and Education of Teachers of - Higher Schools,
and of Scientists and Researchers /0 putyakh podgo-
tovki prepodavateley vysehey shkoly i nauohnykh rabotnikov)
PERIODICALs Vestnik Moakovskogo universiteta. Seriya matematiki, mekhaniki,
aatronomii, fiziki, khimii, 1958# fir 6p pp 235 - 238 (USSR)
ABSTRAM According to the opinion of the authors the actual training
and education of qualified specialists in the field of natural
sciences suffers from certain drawbackat They first go through
a three-years# stage as candidates. This kind of activity is
in no way a guarantee for thoroughly penetrating into all
necessary fields of theoretical and experimental work in the
domain of physics and physical chemistry, and of the other
sciences related therewith. Besides the time is too short for
defending and proving again the truth of the scientific in-
Yeatigations carried out. It is obvious that the brevity of
time prevents the candidates from ascending in their investiga-
tions from a perfunctory to a more scientific level. There is
Card 1/3 no possibility of selecting certain more interesting themes,
Training and Education of Teachers of Higher SOY/55-58-6-30/31
Schools, and of Scientists and Researchers
and the like. Finally the time is too short for giving the
candidate a sufficient pedagogical training. Consequently, it
is suggested to replace the'term of three years for candidates
by a five years' term for assietants-on-trial during which time
the practical work and the seminaries will be-conducted accord-
ing to pedagogical principles and the scientific investigations
will be carried out in accordance with the �Iana of the Chair.
The examination on the special scientific training can only
be passed, if the asaiatant-on-trial adduces the proof of having
made a number of particular scientific reparts4."and of having
passed the examination on-the fundamentals of marxiam and
leninism, as well as that of foreign'languages. After haying
completed his trial term and Saying successfully passed the
final examination, he may become candidate lecturer at his own
or at any other school. By a well-controlled guidance of the
assistant-on-trial, an excellent selection is warranted of
first-class men of science. Besideev this system will success-
fully further and advance the scientific work of the assistants-
Card 2/3 on-trial. The authors believe that the chief result of this
Training and Education of Teachers of , Higher SOV/55-58-6-30/31
Schoolst and of Scientists and Researchers
reorganisation will be a good training both in the scientific
sector and, in the Oedagogioal field, and will therefore be
the beat way of forming first-close higher school instructors.
Card 313
3-58-7-3/36
AUTHORS: Gerasimov, Ya.I.,_jgxzmjn,_jejL,_, liselev, A.V., 3kuratov, S.Y.,
Topchlyeva, K.V., Professors; 9hakhparonov, M.I., Doctor of
Chemical Sciences and Lebedov, V.P., Dotaent
TITLE: The National Economy Needs Physico-Chemists (Narodnomu kho-
zyaystvu nuzhny fiziko-khimiki)
PERIODICAL: Vestnik vysshey shkoly, 1956, Nr 7, PP 14-16 (USSR)
ABSTRACT: The authors stress the necessity of creating special faculties
on physico-chemistry in univereities. At present, faculties
train chemists whose knowledge of physics is rather limited.
The student is not trained in a special branch of chemistry,
and the shortage of time does not allow him to develop his
knowledge of practical methods.
ASSOCTATION: Moskovskiy gosudarstvennyy universitet imeni Lomonosova
(The Moscow State University imeni Lomonosov)
Card 1/1
A.V. -, LWOM. V#Po; SIMTOV,
MMSIMOV, Y
S.M.; TOPCHIYEVA. x.v.; sHijaPARokov, m*r.
Methods of preparing scientific workers and teachers of insti-
tutions of higher education. Vest.Hook.un*Seromatotmelth.gastron.,
fig-.khid- 13 no.1:235-238 158. (MIRA 12:4)
- (Science-Study and teaching)
5W SOV/76-32-10-14/39
AUTHORS: _~eremAE, 1 _4, Kobozev, N. I., Lyubkovskaya, B. G.
TITLE: The Conversion of Methane to Acetylene in the High-Voltage Are
(Prevrashcheniye metana, v atsetilen v vysokovolltnoy duge)
I. The Effect of Pressure (I. Vliyaniye davleniya)
PERIODICAL: Zhurnal fizicheskoy khimii, 19589 Vol 32, Tir 10, pp 2315-2323
,
(USSR)
ABSTRACT: The experimental data were obtained at the Gosudarstvennyy
institut azotnoy promyshlennosti (State Institute of Nitrogen
Industry). According to earlier papers (Refs 1-3) it may be
anuumed that a nilent dinchargo of the type occurring in the
Siemens ozonizer does not lead to an acetylene formation. In
the papers by Ye. N. Yeremin$ M. Z. Alitshuller, Z. I. Kirl-
yashkina and V. V. Igonin (Ref 5) and A. B. Tsentsiper (Ref 6)
it was found that discharges at low pressure and low amperages
are not efficient. D. K. Koller (Ref 4), who also worked with
i glow discharge, found 90-100 mm to be the optimum pressure
at an amperage of 100 mA. 11. P. Dozhko ot al. (Refs 7-9) showed
that in a discharge in the high-voltage are at a preanure of
Gard 1/3 35 mm up to 17 V010 acetylene may be obtained in the reaction
SOV/76-32-10-14/39
The Conversion of Methane to Acetylene in the High-Voltage Arc. I. The Effect
of Pressure
products. In the experiments by Ye. 11. Yeremin (Refs 10,16) it
-was found that the course of the reaction does not depend on
the amperage but on the "Specific Energy". The latter concept
was introduced by S. S. Vasillyev, If. I. Kobozev and Ye. ff.
Yeremin (Ref 11) and was also used by D. K. Koller (Ref 4) as
"Parameter q". A kinetic evaluation of the results obtained by
Rudder and Biedermam (Biderman) (Ref 13) by the authors of the
present paper shcwed that a 12-fold acceleration in the con-
version is obtained by a drop of the pressure from 760 to 88 mm.
(15000). Investigations were carried out in the high-voltage
arc at different pressures, especially from 70 mm to somewhat
above I atmosphere absolute pressure in a reactor the diagram
of which is given. The analyses of the Saratov gas used and
the reaction products were carried out by means of the gas
analyzer VTI. A drop in pressure considerably improves the con-
version. At a pressure of 70-100 mm and the value U/vr,--3t5
the percentage of acetylene in the gas reaches the value 16,6
and the general cracking -0,73 at an energy consumption of
11,2 kilowatt-hour/cm 3 C2H2- It was found that the "Limiting
Card 2/3 Concentration" mentioned by N. P. Bozhko does not amount to 40
SOV/76-32-10-14/39
The Conversion of Methane to Acetylene in the High-Voltage Are. I.-The jEffect
of Pressure
at atmospheric pressure but that a concentration of 12% acety-
lene may be obtained with a minimum consumption of energy.
The experimental results obtained were evaluated from the
kinetic point of view by means of the method propooed by Yeremin
(Ref 16). The pressure drop to 70-100 mm doubles the efficiency
of the high-voltage are in the reaction investigated.
There are 3 figures, 2 tables, and 16 references, 12 of which
are Soviet4
ASSOCIATIOIT: Moskovskiy gosudarstvennyy universitet im, M. V. Lomonosova
(Moscow State Uniirersit~ imeni 14, V..Lomonosov)
SUBMITTED: may 4. 1957
Card 3/3
5W SOV/76-32-11-12/32
-AUTHOR: Yeremin, Ye. 11.
TITLE: On the Problem of the Kinetics of the Electrocracking of
Methane (K voprosu o kinatike elektrokrekinga metana)
PERIODICAL: Zhurnal fizicheakoy khimii, 1958, Vol 32, Nr 11, pp 2543-2549
(USSR)
ABSTRACT: S. S. Vasillyev, He I. Kobozev, and Ye. N. Yeremin (Ref 5)
pointed out that the course of the reaction in the discharge
zone may be expressod as a function versus the flow rate of
the gas. A comparison of the experimental results by S. S.
Vasillyev (Ref 7) with the calculation results by A. B.
Tsentsiper (Ref 11) obtained for the values k Ic /U shows a
certain agreement so that it may be assumed that the value
kIc0/U determines the limiting energy yield of methane. It was
found that the amount of the reacting hydrocarbon is proportion-
al to the energy consumed in the discharge, as well as to the
residual amount of the hydrocarbon initially used. The electro-
cracking may be regarded as a reaction of first order. The
Card 1/2 constant of the rate of reaction is directly proportional to
SOY/76-32-11-12/32
On the Problem of the Kinetics of the Electrocracking of Methane
the discharge capacity and is inverse proportional to the
initial amount;-of the hydrocarbon. The oonoept of the energelic
efficiency,-of the discharge with respect to the electrocracking
of methane (amount of the hydrocarbon/energy) is introduced as
kinetic characteristic feature of the process. It was found
that the energetic efficieney of active discharge forms (with
respect to CH 4) practically does not depend on the geometrical
dimensions of the discharge, the current density and the dilu-
tion of the gas used in the beginning of the process with
hydrogen, but that it decreases with an increase in pressure.
Similar observations were also made by A. B. Tsentsiper (Ref 11)
with other hydrocarbons. There are 1 figure, 1 table, and
15 references, 10 of which are Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED: may 4P 1957
Card 2/2
5W
AUTHORS: YgXgzj..n, Ye. SO-1/76-32-12-17/32
Lyudkovskaya, B. G.
TITLE: The Conversion of Methane Into Acetylene in a High Voltage
Are (Prevrashcheniye metana v atsetilen v vysokovolltnoy duge)
II. The Effect of Hydrogen (II. Vliyaniye vodoroda)
PERIODICAL: Zhurnal fit~ichenkoy khimii, 1958, Vol 32, lir 12,
pp 2767 - 2771 (USSR)
ABSTRACT: The contradictory results of earlier experiments are dis-
cussed (Refs 2 to 11). The investigation was carried Oa to
d:etermine the effect of hy6rogen admixture on the methane
cracking in an electric arc. Experinents were carried out
by means of an alternating current high voltage arc at
atmospheric pressure; the methane and hydrogen ratios were
69-4:27.2, 59.1:37.2 and 48-8:40-4- It was found that the
general cracking of methane increases at a hydrogen ad-
mixture of up 37%, while the acety one concentration and
the chemical enerL7 yield (0 .184 mi/kYlh) remain unchanged.
In practice, this noatie that acetylene may be produced in
Card 1/2 the same apparatus with both pure nethane and -nethane
The Conversion of Methane Into Acetylene in a High SOV/76-32-12-17/32
Voltage Are. 11. The Effect of Hydrogen
containing a hydro,-1en admixture. Under thene tent conditions
hydrogen acted an an inert diluent without active in-
fluence on the nethane traneformation. There are 2 figures,
1 table, Und 12 refere"cony 7 of which are Soviet.
ASSOCIATIONT: Moskovskiy gosuderstvennyy -mivernitet im. U. V. Lomonosova
(moccow state University imeni M. V. Lomonosov)
SUBMITTED: May 4, 1957
Card 2/2
5(4)
AUTHORS: Ushakovap G~.S'.~ Yeremin, Ye_~_.N. SOY/76-33-1-42/45
TITLE: The Formation of Ozone From Dissociation Products of CO 2
in the Glow Discharge (Obrazovaniye ozona iz produktov
dissotsiataii GO 2 v t1eyushchem razryade)
PERIODICAL: Zhurnal fizicheakoy khimii, 1959, Vol 33, Nr 1, p 233 (13SSR)
ABSTRACT: The formation of ozone from CO 2 in the glow discharge has been
observed some time ago (Ref 1); although, so far, no
quantitative determinations have been carried out. In the case,
under discussion a discharge tube of the type Vud, with
aluminum electrodes, was used and the reaction products were
frozen. A 250 ma-current and a 2.4 - 2.5 kv-potential were used.
In order to reduce the dissociation of CO 2 (Ref 1) and because
of the danger of an explonion undried CO 2was used. A yiel d of
5,35 mo1% 0 3' with regard to the CO. amounts was obtained.
Card 1/2
The Formation of Ozone From SOV/76-33-1-42/45
DiBsociation Products of CO. in the Glow Discharge
Since no maximum was observed it is assumed that the maximum
yield, under the conditions given# has not been obtained.
If the time of CO2 presence in the discharge zone is extended
the 03 yield is reduced (Fig). There are I figure and
1 reference. .
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. Lt. V. Lomonosova
(Moscow Stalle University imeni M. V. Lomonosov)
SUBMITTED: July 29, 1958
Card 2/2
5(4) SOV/76-33-7-25/4o
AUTHORSt Malltsev, A. N., Yeremin, Ye. X.r Voroblyevab 1. Y.
-----------
TITLEs On Steady Concentrations of Nitrogen Oxide in Discharge. II,
Experiments With Air and a Narrow Tube
PERIODICALi Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 7,
pp 1618 - 1624 (USSR)
ABSTRACTs In a previous pa er (Ref 1) the dependence of the steady con-
,
t
rogen oxide
centration of ni
M el-Nbj., on the amperage in pro-
duction from air during smoldering discharge was investigated
in a wide vessel at different pressure. In the present case, the
authors checked the same dependence on E NO).. in a reaction
tube at an atmospheric pressure of between 50 and 300 torr.
M was synthesized within a range of electric discharge by
means of a circulation apparatus described already earlier (Ref 1).
A quartz tube was used as a reaction tube (Fig 1) which was
3 mm thick within the range of discharge (diameter of the ranges
32 mm). Measureme results indicate that there are two kinds
of dependences ofto 11010 on amperage presents 1) At 50 and
100 torr the steady (I)-concentration first increases, and then
Card 1/2 apparently approaches a final value; 2) At 200 and 300 torr
On Steady Concentrations of Nitrogen Oxide in SOV/76-33-7-25/4o
Discharge. II. Experiments With Air and a Narrow Tube
C% N03,, passes�after asharp r ise, through a maximum, In the
present tube, the concentrations of (I) are higher than in that
mentioned in reference 1; at 100 torr "hey attained 11.1%,, the
highest value ever attained in direct synthesis from air. Thas,
the non-thermal nature of activation of the reaction is con-
firmed. 14canuromentm of tho do ondonon of 061V ROL on tho pro-
duct of amperage and pressure M) showed a nature similar to
that described in reference 1. The voltage of discharge was
measured by means of S-95 and S-96 voltmetera, compared with
measurements on NOM-6 and 'NOM-10 measuring transformeral the re-
sults agreed well with one another~ It was found that thi re-
lative longitudinal potential gradients are four times lower
than in the reactor (Ref 1). The experimental results obtained
are explained from thb standpoint of a chain decomposition of
(I). There are 5 figures and 6 references, 5 of which are Soviet.
ASSOCIATIONt Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTEDs January 'o, 1958
Card 2/2
B002/BO60
AUTHORBs Nekrasov, L. I., Kobozevt N. I.f_Yeremin,_L"
TITLEt Low-temperature Reactions of Atoms and Radicals.
Contribution I. Synthesis of Mdrogen Peroxide From Water
Vapor %\
PERIODIUM Vestnik Moskovsk ogo universiteta. Seriya 2, khimiya, 1960,
No. 4, pp. 12 -
18 ,/60/000/004/002/006
TEXT% Attempts were repeatedly made in the past to produce hydrogen
peroxide by electric-glow discharge in water vapor, and to achieve a high
concentration of it by freezing out with liquid nitrogen. The authors of
the present paper conducted an investigation into the dependence of the
yield on feed, water vapor pressure, construction and cooling temperature
of the traps, arrangement of the channels between discharge tube and
traps, and the intensity of discharge. A report is made here of the
influence exerted by construction and temperature of the traps. The
following conditions were chosent water vapor pressure 0.5 torr, amperage
0-135 at voltage 1000 to 1200 v. A scheme of the apparatus is shown
S1189
Card 1/2
Low-temperature Reactions of Atoms and Radicals. S/189J60/000/004/002/006
Contribution I. Synthesis of Hydrogen Peroxide B002/BO60
From Water Vapor
(Fig. 1). The usual form of trap (Fig. 2;,a) proved to be absolutely
unsuitable, since mainly water separated in the feeding channel. Better
results were achieved when the cooled trap was bulged out, and the channel
reached only onto the nitrogen level (Fig. 2, b and v). The beat results
were achieved when the feeding channel reached as far as below the
nitrogen level and was warmed by water flowing through at room temperature
to avoid ioe'formation (Fig. 2, g and d). The strict observance of these
conditions afforded a 25% molar yield and 60% concentration of hydrogen
peroxide. Several diagrams (Figs. 3 to 5) illustrate the dependence of
yield on the rate at which the water vapor is fed to the system. No
formation of hydrogen peroxide was observed at -700C. There are 5 figures
and 21 references, 7 Soviet, 7 US, 1 German, 1 Japanese, 1 French,
2 Canadian, and 2 British.
ASSOCIATIONt Kafedra fizicheskoy khimii (Chair of Physical Chemistry)
SUIBMITTEDs April 17, 1959
Card 2/2
yEREMIIJ Yeygeuly )IJXqU _vich;KOROBTSOVAl H.A. , red. j MASIENNIKOVA$
19
T.A., tekhn. red.
(Blements of gas electrochemistry] Elementy gazovoi olaktro-
khimii. Moskva, Izd-vo Mosk. univ.p 1961,, 77 Pe
. (KIRA 14t12)
(Electroohomistry)
8h 243
S/076/60/034/009/001/022
B015/BO56
AUTHORS: Kobozev, N. I., Yeremin, Ye. N,j Terekhova, M. G., and
Malltsev , A. N. -
~
TITLE: Physical IX. Study of
Chemistry of Concentrated 2.~one
Ozone Ad sorption on Silica Gel at Various Temperatures
PERIODICAL; Zhurnal fizicheskoy khimii, 1960, Vol- 34, No. 9, pp. 1893
-1899
TEXT: The adSorption of ozone on silica gel at low temperatures (from
-80' to -150 C) was Investigated by saturating the silica gel in the
gas flow at constant -temperature until adsorption equilibrium was
established, and the adsorbed gas quantity wan then determined by gas
analysis. The ozone-oxygen mixture was produced in a silent electrical
discharge; the duration of adsorption amounted to 1 - 6 h as a function
of the experimental temperature, and the rate of flow of the gas was
43-45 I/h. The experiments were carried out in a circulating apparatus
Fig;.1). The silica gel was in an adnorber cooled with liquid nitrogen
g 2, 4). The latter was cooled in a cryoutat (Fig. 3), whornan for
M
Card 1/2
84243
Physical Chemistry of Concentrated Ozone. S/076/60/034/009/001/022
IX. Study of Ozone Adsorption an Silica Gel B015/BO56
at Various Temperatures
the purpose of desorption, the cryostat was heated. The results of measure-
ment show (Table 1) that ozone adsorption on silica gel rises to 7 to 8
times its amount with a temperature drop from -120 0C to -1500C. Ozone
desorption may thus be attained by a slight increase of temperature, or
an effective separation of concentrated ozone with the aid of an adsorp-
tion;desorption cycle. For the temperatures of -1200, -1300, 440 0, and
-150 C the adsorption isothermal lines were obtained (Fig- 5), and it
was found that they differ in appearance as well as according to -.i:e
character of the dependence of adsorption on an increase of the ozone
content in the equilibrium mixture. There are 5 figures, 2 tables, and
4 non-Soviet references: 3 German and 1 Swiss.
ASSOCIATION;
SUBMITTED:
Moskovskiy gosudarstvennyy universitet im. I.T. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
July 15, 1958
Card 2/2
YEREVIN, Ye.N.
Kinetics of reactions in electric discharges. Vest.14ook.m.
Ser. 2:khim. 16 no,,3:3-20 XY6-Je 161, wnu uaw
1. Kafedra fizicheskoy Ithimii Hookovokogo gosudaretvannogo
universiteta.
(Chemical reaction, Rate of)
($1ectric discharges through gases)
3/076/61/035/002/005/015
B124/B202
AUTHORS: Pospelova,.T. A.t Kobozev, N. I., and%XtEtRILL-1!1.~
TITLE, Catalytic synthesis of hydrogen peroxide from its elements
on palladium. I. Conditions for the production of
hydrogen peroxide.
PERIODICAL: Zhurnal fizicheokoy khimiij v. 35, no. 2, 1961, 298-305
TEXT: A comparison of the free formation energies of water and hydrogen
peroxide from their elements (-56-56 kcal for liquid water, and -28.23
koal for liquid H202) shows that on catalysis the H2-02 reaction may
proceed in two directions, i.e.,
II H 0
2 2
H2 + 02 + (catalyst _Z: -4 4 111 wherep due to the low stability
I H20
of the H202 molecules in the presence of the catalyst H202 and water are
decomposed thus causing the masking of the second process. Por this
reason the authors studied the optimum conditions for the synthesis of
Card 1/k
S/076/61/035/002/005/015
Catalytic synthesis of hydrogen peroxides** B124/B202
H202 from the elements on palladium on the one hand and its decomposition
at the same catalysts on the other. The detonating gas was catalyzed in
a kinetic vessel of Shpital'skiy typo. The time dependence of the H202
yield was studied on palladium black in a mixture of XCN(O.001 N) and
sulfuric acid (0.1 N) as well as on aluminum gel (%Pd - 5.47). The gas
mixture consisted of 20% hydrogen and air; the activity of the catalyst
was measured from the absorption of 2 cm3 of the mixture. The experimental
results are given in Fig. 1. They indicate that in both cases (mainly in
Pd/A1203) the H202 yield is strongly reduced with time although the
absorption of the mixture continues ( 4V increases). In this case, the
initial yield exceeds 80% on Fd black, i.e., almost pure H202 is formed.
Hence H202 is formed as primary product of the catalysis of detonating
gas. its catalytic decomposition causes the formation of water. The
authors studied the effect of a number of acids, mixtures of KCN with
different acids, ammonia and Hg2+ solutions in H2SO4 (Table 1). Without
Introduction of catalyst poisons only water Is formed. The most efficient
inhibitor of H20 decomposition is plumbic acid, followed by dilute HClj
the'effect of the other acids is weaker while NE3 and Hg2+ solutions
Card 24 ~
S/0701/035/002/005/015
Catalytic synthesis of hydrogen peroxide.*@ B124/B202
inhibit both, formaiion-and decomposition Of H202-' In this case, the
acids do not enter an irreversible reaction and their decrease in
antity in the' reaction is caused by absorption on ihe catalyst (Table
"
), It was found that'a) the stabilizing effect of HCN (Figa 3 and
2
H01 (Fig. 4) is especially marked at low concentrations and that it
passes through an optimum; b) the optimum synthe'sis of R 02 is achieved
at a stoichiometrio ratio Of H2'02 - yieli increases with
1, C) the B202
increasing temperature.(Table 4), and d) the acid carriers S102 and W03
give higher H202 yields than'the amphoteric A1203 (Table 5). The
following scientists are. mentioned: N. I. Koboze-i and V. L. Anakhin
(Ref.'3: Z-' PhYs. Chem., Abt. B, D, No. 1-2, 1931), M. V. Polyakov and
oollab6ritors'(Refe 4; Zho fizt-khimii, J-, 453, 19331 1, 954, 19341,~,
1241, 1249t 1932; Acta phys.-chim. URSBS, 2, 211, 1935), N. D. Zelinskiy
and"M.,.B. rova (Ref. 6% Ber. 18,'1884, 1885), P.- M. Stadn'ik (Ref. 9:
'Tu
Dokl. AN SSSR, 2L, 19521 Zh. fiz. khimii, 28, 1954), N. A. Bakh (Ref. 11:
Trudy Bakha, no. 1, Abt. 2, Kap. 1, 1937), S. Levina and R. Rozentreter
(Ref. 13: Zh. fiz, khim'ii, 13, 1939), A, 1. Shlygin (Ref. 141 Uchq zap.
Kazakhsko' Unrtat 139 1951), D. V. Sokollskiy and collaborators (Ref. 15:
Card 3/0